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2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)最新文献

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Composition and Structure of Meningioma Psammoma Bodies 脑膜瘤沙粒体的组成和结构
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568556
A. Denysenko, A. Piddubnyi, Yevgen Kuzenko, O. Pylypenko, R. Moskalenko
This paper is devoted to the microstructure, morphology, and elemental composition of pathological minerals in dural-based neoplasms. It was found that pathological crystallin inclusions in meningiomas are represented by calcium apatite.
本文对硬脑膜肿瘤病理矿物的显微结构、形态和元素组成进行了研究。发现脑膜瘤的病理性结晶蛋白包涵体以磷灰石钙为代表。
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引用次数: 0
F- and P-enriched Coatings for Mg Implants by Low Energy PEO Process 低能PEO法制备富F、富p镁植入物涂层
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568602
Y. Husak, O. Oleshko, J. Michalska, V. Korniienko, O. Solodovnyk, Bohdan Dryhval
Degradable implants occupy the significant position in orthopedic industry. Magnesium is an appropriate degradable material due to its good biocompatibility and degradability properties in addition to advantageous mechanical properties. Improving the material quality, especially corrosion resistance and surface active, could be occur through the chemicals and parameters of the Plasma Electrolytic Oxidation process. Voltage reduction could reduce cost involved and make more environmentally friendly. Doubling the concentration of the sodium phosphate worked at low voltage. The surface morphology showed well-developed structure. Obtained coatings were without cracks and with good thickness size. Increasing wettability point to enhancing bioactive properties.
可降解植入物在骨科行业中占有重要地位。镁除具有良好的力学性能外,还具有良好的生物相容性和可降解性,是一种合适的可降解材料。通过等离子体电解氧化工艺的化学成分和参数,可以提高材料的质量,特别是耐腐蚀性和表面活性。降低电压可以降低成本,使产品更加环保。磷酸钠的浓度加倍在低电压下起作用。表面形貌结构发达。所得涂层无裂纹,厚度尺寸好。增加润湿性是为了提高生物活性。
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引用次数: 0
Nano-sized Polymer-Silicate Thermal Stabilizers Of Polyvinyl Chloride Materials 聚氯乙烯材料的纳米聚合物硅酸盐热稳定剂
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568628
A. Masyuk, V. Levytskyi, D. Katruk, U. Khromiak, B. Kulish
Peculiarities of obtaining and modifying Ba, Zn-containing polymer-silicate thermal stabilizers of polyvinyl chloride have been studied. The influence of macromolecular modifiers on the morphology and surface characteristics of thermal stabilizers is shown. The influence of fine Ba, Zn-containing polymer silicate thermal stabilizers on the processes of destruction (weight loss, thermal effect), physical-mechanical (surface hardness, elasticity) and thermophysical (Vicat softening point) properties of polyvinyl chloride materials is revealed.
研究了含钡、含锌聚合物硅酸盐聚氯乙烯热稳定剂的制备和改性的特点。研究了大分子改性剂对热稳定剂形貌和表面特性的影响。揭示了精细含Ba、zn聚合物硅酸盐热稳定剂对聚氯乙烯材料的破坏(失重、热效应)、物理力学(表面硬度、弹性)和热物理(维卡软化点)性能的影响。
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引用次数: 0
Growth Kinetics of CVD Diamond Films Deposited in Glow Discharge Plasma Using a Pulsed Power Supply 脉冲电源在辉光放电等离子体中沉积CVD金刚石膜的生长动力学
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568611
K. Koshevoy, Yu.Ya. Volkov, E. Reshetnyak, V. Strel’nitskij
The influence of the parameters of a pulsed power supply of a glow discharge and the substrate temperature on the growth kinetics of CVD polycrystalline diamond films have been studied. It was found that an increase in the pulse frequency from 13 to 50 kHz and a decrease in the pulse duty cycle from 90 to 80% promotes an increase in the films growth rate by 1.5 – 2 times. The non-monotonous character of the dependence of the film growth rate on the deposition temperature upon pulsed excitation of a glow discharge is similar to that characteristic by direct current. In the optimal pulse mode the maximum film growth rate is near a temperature of 1050°C. With an increase in the deposition time, an increase in the average growth rate of the diamond film is observed. When the synthesis process lasts more than 6 hours, the deposition rate reaches 11 μm / hour. The power consumption in the pulsed mode of diamond films synthesis is 0.3 kW / μm, which is 3 times lower than when using a DC power source.
研究了辉光放电脉冲电源参数和衬底温度对CVD多晶金刚石薄膜生长动力学的影响。结果表明,将脉冲频率从13 kHz提高到50 kHz,将脉冲占空比从90%降低到80%,可使薄膜的生长速率提高1.5 ~ 2倍。在辉光放电的脉冲激励下,薄膜生长速率对沉积温度的依赖性的非单调性与直流电的特性相似。在最佳脉冲模式下,薄膜的最大生长速率在1050℃附近。随着沉积时间的延长,金刚石膜的平均生长速率增大。当合成过程持续6小时以上时,沉积速率达到11 μm /小时。脉冲方式合成金刚石薄膜的功耗为0.3 kW / μm,比使用直流电源时低3倍。
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引用次数: 0
Biodegradable Nanostructured Nerve Conductors: Electrical Properties And Adsorption Kinetic Models 可生物降解的纳米结构神经导体:电学性质和吸附动力学模型
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568605
M. Kumeda, L. Sukhodub, L. Sukhodub, O. Potapov, Oleksandr Tsyndrenko, Olexii Kmyta
Model samples of nerve conductors with incorporated particles of inorganic origin: chitosan (CS), ZnO, Fullerene C60, dopped with Fe3+ ions multi-walled carbon nanotubes (MWCNTs+Fe) were successfully synthesized and investigated. The inclusion of inorganic particles in the alginate (Alg)-based composites reduces hydration (swelling) degree and affects the material’s resistance, leading to a decrease in the electrical conductivity. The MWCNTs+Fe-containing sample shows the highest electrical conductivity, mainly due to iron ions. ZnO and fullerene C60-containing samples have the lowest electrical conductivity due to high density and lower ability to hydrate. The mechanisms of Trp adsorption on the experimental samples were determined with Langmuir, Freundlich, Slips, and Henri isotherms equations. Sips isotherm model, which predicts the heterogeneity of the adsorption system, provides the best correlation of all experimental sample data, and the $text{r}^{2}$ values of about 99% confirm that. The adsorption on the ZnO-containing sample is well fitted to the Freundlich isotherm model (1/n<1), which means that reversible and non-ideal adsorption is favorable. The heterogeneity of the Alg-ZnO surface, as well as the exponential distribution of the active energies sites, takes place.
成功地合成并研究了多壁碳纳米管(MWCNTs+Fe)神经导体模型样品,该模型样品由无机来源的壳聚糖(CS)、ZnO、富勒烯C60掺杂Fe3+离子。海藻酸盐(Alg)基复合材料中无机颗粒的掺入降低了水化(膨胀)程度,影响了材料的电阻,导致电导率下降。MWCNTs+Fe-containing样品表现出最高的导电性,主要是由于铁离子。含ZnO和富勒烯c60的样品由于密度大,水合能力低,电导率最低。采用Langmuir, Freundlich, Slips和Henri等温线方程确定了色氨酸在实验样品上的吸附机理。Sips等温线模型预测了吸附体系的非均质性,提供了所有实验样品数据的最佳相关性,约99%的$text{r}^{2}$值证实了这一点。在含zno样品上的吸附很好地符合Freundlich等温模型(1/n<1),有利于进行可逆和非理想吸附。Alg-ZnO表面呈现非均质性,活性能位呈指数分布。
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引用次数: 0
Physico-Geometric Approach to the Processes of Thermal Decomposition of the Guinea Fowl (Numida meleagris) Eggshell’s Bionanocomposites 珍珠鸡蛋壳生物纳米复合材料热分解过程的物理几何方法研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568520
O. Bordunova, Y. Samokhina, R. Dolbanosova, Lyudmila S. Patreva, N. Cherniy, Oleksandr O. Chekh, V. Loboda, S. Danilchenko, V. Chivanov
Using the physico-geometric approach in the thermal programmed desorption mass spectrometry (TPD-MS method), the possibility of indirect estimation of the three-dimensional structure of a multilayer heterogeneous composite of “calcium carbonate (calcite) – protein” type of eggshells of a guinea fowl (Numida meleagris) eggs. The method is based on the difference in rates of thermal decomposition rates of calcium carbonate depending on the peculiarities 3-D micro-, nanostructure of each layer. Increased porosity and reduction in the density of crystallite packing in local areas of the shell is accompanied by a shift of maximum peaks in the complex curves of the dependence of carbon dioxide release during process of thermal destruction (thermograms) in the direction of low temperatures. The TPD-MS makes it possible to determine of quality level and mechanical properties of the eggshells in cases where traditional methods of microscopy don’t give reliable results. Thus, this study shows the presence of reliable structural differences in different areas of the nanocomposite layers of the eggshell of guinea fowl (Numida meleagris), distinguished by increased strength. These experimental and theoretical results can be the methodological basis for the development of a new method for assessing the quality of food eggshells, which is needed to prevent losses and prevent contamination with Salmonella.
利用热程序解吸质谱法(TPD-MS)中的物理几何方法,间接估计了珍珠鸡蛋壳“碳酸钙(方解石)-蛋白质”型多层非均相复合物的三维结构的可能性。该方法基于碳酸钙热分解速率的差异,这取决于每层的三维微、纳米结构的特性。随着孔隙度的增加和壳局部区域晶填料密度的降低,热破坏过程中二氧化碳释放依赖性复杂曲线(热图)的最大峰向低温方向移动。在传统的显微镜方法不能给出可靠结果的情况下,TPD-MS可以确定蛋壳的质量水平和机械性能。因此,这项研究表明,珍珠鸡(Numida meleagris)蛋壳的纳米复合层的不同区域存在可靠的结构差异,其特征是强度增加。这些实验和理论结果可以为开发一种新的食品蛋壳质量评估方法提供方法学基础,这是防止损失和防止沙门氏菌污染所需要的。
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引用次数: 2
Multiphysics Modeling of Magnetic Scaffolds for Biomedical Applications 生物医学磁性支架的多物理场建模
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568562
M. B. Lodi, A. Fanti
Magneto-responsive biomaterials can play a key role in several biomedical applications, from therapeutic to diagnostic. Despite the several efforts for synthesizing and characterizing bioceramics doped with magnetic ions or polymers loaded with magnetic nanoparticles, there is lack of mathematical and numerical models capable of filling the gap between nanomaterial science and engineering. This work reviews and propose numerical, multiphysics models for studying the use of magnetic scaffolds for the hyperthermia treatment of bone tumors and for magnetically targeted drug delivery.
磁响应生物材料可以在几个生物医学应用中发挥关键作用,从治疗到诊断。尽管在合成和表征掺杂磁性离子的生物陶瓷或装载磁性纳米粒子的聚合物方面做出了一些努力,但缺乏能够填补纳米材料科学与工程之间空白的数学和数值模型。本研究综述并提出了用于研究磁性支架在骨肿瘤热疗和磁性靶向药物递送中的应用的数值多物理场模型。
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引用次数: 0
Nickel Ferrites Nanopowders as Catalysts for Hydrogen Production through NaBH4 Hydrolysis 纳米铁氧体镍粉作为NaBH4水解制氢催化剂的研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568586
I. Ivanenko, S.M. Lesik
the two series of ferrites were synthesized. The first series was obtained by the traditional method of coprecipitation. The second series was synthesized by the new improved method which was named the coprecipitation with overheating. FTIR spectra had shown the tetrahedral and octahedral metals ions sites, and the XRD pattern confirmed the formation of cube structure with the stable lattice constant of ferrites in obtained nanopowders. The high catalytic activity of all synthesized nanoferrite catalysts in the sodium borohydride hydrolysis reaction was proved. But Nickel ferrites synthesized by a new method of coprecipitation with overheating showed significantly higher catalytic activity in the studied process of hydrogen production. The possibility of nickel ferrite nanopowders using for hydrogen production by hydrolysis of sodium borohydride has been shown and confirmed.
合成了这两个系列的铁氧体。第一个系列是用传统的共沉淀法得到的。第二系采用改进后的方法合成,命名为过热共沉淀法。FTIR光谱显示了金属离子的四面体和八面体位置,XRD谱图证实了制备的纳米粉体具有稳定的铁氧体晶格常数,形成了立方体结构。结果表明,合成的纳米铁氧体催化剂在硼氢化钠水解反应中具有较高的催化活性。而采用过热共沉淀法合成的镍铁氧体在制氢过程中表现出更高的催化活性。研究证实了纳米铁氧体镍粉用于硼氢化钠水解制氢的可能性。
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引用次数: 0
Biomedical Applications of Nanodiamonds and Nanotoxicity Problems 纳米金刚石的生物医学应用和纳米毒性问题
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568571
L. Batyuk, N. Kizilova, Oksana Muraveinik
Nanodiamonds (NDs) attract much attention due to their unique chemical and physical properties, and numerous applications in medicine and biology. Nevertheless the problem of their invasion and accumulation in the cells, and mechanisms of their extraction from the organisms are not clear. In this paper a detailed review of literature on biotoxicity of NDs and their influence on cells and tissues is presented. It is shown, the effects are dose- and size-dependent, and depend on the administration type (puerperal, intratracheal, etc.). Besides, the opposite effects (both cytotoxic and non-toxic) have been observed on the same animals by different authors. Radio protective ability and cytotoxicity of the NDs with sizes 210 nm have been studied on rats with different type of administration with food of aqueous suspensions of NDs homogenized by ultrasound treatment followed by X-ray exposition (5.8g, 5 min). It was shown, administration of NDs produce no cytotoxic influence. Radioprotective influence of NDs have also been confirmed.
纳米金刚石因其独特的化学和物理性质,在医学和生物学上有着广泛的应用,备受关注。然而,它们在细胞内的侵入和积累问题以及从生物体中提取它们的机制尚不清楚。本文对NDs的生物毒性及其对细胞和组织的影响进行了综述。结果表明,影响是剂量和大小依赖的,并取决于给药类型(产褥期、气管内等)。此外,不同的作者在同一动物身上观察到相反的作用(细胞毒性和无毒)。用不同给药方式的大鼠研究了粒径为210 nm的NDs的放射保护能力和细胞毒性,这些NDs的水悬浮液经超声处理均匀后,x射线照射(5.8g, 5 min)。结果表明,服用NDs不产生细胞毒性影响。NDs的辐射防护作用也已得到证实。
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引用次数: 0
The Influence of Laser Irradiation on the Formation of n-n+ Transitions in Heterosystems with Significant Mismatch of Lattice Parameters 激光辐照对晶格参数不匹配的异质体系中n-n+跃迁形成的影响
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568583
O. Dan’kiv, O. Kuzyk, I. Stolyarchuk
The theory of the formation of n-n+ transitions in three-layer heterosystems with significant mismatch of lattice parameters of contacting materials exposed to intense laser or radiation irradiation is developed. Within the framework of the developed model, the concentration of conduction electrons was calculated. It is established that the concentration profile of conduction electrons depends on the average concentration of dot defects, the mismatch parameter and the geometric size of the heterostructure.
提出了接触材料在强激光或强辐射照射下晶格参数明显不匹配的三层异质体系中n-n+跃迁形成的理论。在建立的模型框架内,计算了传导电子的浓度。建立了导电电子的浓度分布取决于点缺陷的平均浓度、失配参数和异质结构的几何尺寸。
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引用次数: 0
期刊
2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)
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