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2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)最新文献

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Perspectives of Exploring ZnO Nanoparticles on the Active Layer Surface of Organic Solar Cells 有机太阳能电池活性层表面ZnO纳米粒子的研究进展
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568531
O. Cardozo, Sajid Farooq, R. D. de Araujo
In this work, we investigate the use of zinc oxide (ZnO) semiconductor nanospheres on the top surface of a 200 nm thick P3HT:PCBM film to improve the optical efficiency of organic solar cells. 3D full-wave computational modeling was explored to investigate the interaction of light with the semiconductor nanospheres and P3HT:PCBM film. The obtained results demonstrate that 160 nm diameter ZnO nanospheres scatter light predominately into the active layer, enhancing the light absorption of the organic material. The results were obtained by covering 25% of the organic solar cell active layer surface with ZnO nanospheres. At 550nm the absorption enhancement value reachs 12%. At 650 nm the absorption enhancement reachs up to 35x. The findings indicate that ZnO nanospheres can improve the performance of organic solar cells.
在这项工作中,我们研究了在200 nm厚的P3HT:PCBM薄膜的上表面使用氧化锌半导体纳米球来提高有机太阳能电池的光学效率。利用三维全波计算模型研究了光与半导体纳米球和P3HT:PCBM薄膜的相互作用。结果表明,160 nm直径的ZnO纳米球将光主要散射到活性层中,增强了有机材料的光吸收。结果表明,在有机太阳能电池活性层表面覆盖25%的ZnO纳米球。在550nm处,吸收增强值达到12%。在650 nm处,吸收增强达到35倍。研究结果表明,ZnO纳米球可以提高有机太阳能电池的性能。
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引用次数: 0
Features of Intercalation Processes in Polymer Nanocomposites Based on Oligoethylene Glycol and Organoclay 低聚乙二醇与有机粘土基聚合物纳米复合材料插层过程特征
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568615
E. Lysenkov, S. Bilyi, V. Klepko, L. Klymenko
The structure features and intercalation processes in oligoethylene glycol (OEG)-based systems and organoclay were studied using X-ray diffraction analysis. It is established that after the introduction of surfactants, the interlayer distance in montmorillonite (MMT) increased. This indicates the intercalation process of surfactant molecules into the interlayer space of the MMT. After introduction to polymer matrix the increase in the interlayer distance is observed. This indicates the intercalation of two monolayers of OEG and the formation of quasibilayer structures. It is shown that the structure of OEG-based systems significantly depends on the content of the nanofiller. Partial processes of intercalation are observed in OEG-organoclay nanocomposites.
利用x射线衍射分析研究了低聚乙二醇(OEG)基体系和有机粘土的结构特征和插层过程。结果表明,表面活性剂的加入使蒙脱土的层间距离增大。这表明表面活性剂分子进入MMT层间空间的嵌入过程。引入聚合物基体后,观察到层间距离增加。这表明了两层单层OEG的嵌入和准双层结构的形成。研究表明,纳米填料的含量对oeg基体系的结构有很大的影响。在oeg -有机粘土纳米复合材料中观察到部分插层过程。
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引用次数: 1
The Energy and Ion Flux Control in MISSS for Nanostructure Coating Synthesis 纳米结构涂层的MISSS能量和离子通量控制
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568535
A. Zykov, N. Yefymenko, V. Korneenkov, S. Dudin, S. Yakovin
The paper presents characteristics of combined Magnetron-Ion-Source Sputtering System (MISSS) with impact on the joint operation of magnetron discharge the ion source giving detailed dependencies of the system parameters on gas pressure, magnetic field strength and topology, and input power. Spatial distribution of particle fluxes and ion energy spectra in different operating modes of the system are presented as well.
本文介绍了磁控管-离子源复合溅射系统(MISSS)的特点及其对磁控管放电离子源联合工作的影响,详细介绍了系统参数与气体压力、磁场强度和拓扑结构以及输入功率的依赖关系。给出了系统不同运行模式下粒子通量和离子能谱的空间分布。
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引用次数: 0
Some Aspects of the Process of Obtaining Coumarone-Indene-Carbazole Modifier for Wear-Resistant Bituminous Road Materials 沥青路面耐磨材料用香豆素-茚-咔唑改性剂制备工艺的若干问题
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568564
Guri Isaiah Borbeyiyong, Y. Prysiazhnyi, S. Pyshyev, Yu.V. Lypko
some aspects of the process of obtaining coumarone-indene-carbazole resin as a modifier of road bitumens have been studied. In particular, the influence of the conditions of separation of unreacted raw materials from the polymer on the thermoplastic and adhesive properties of the resin and modified bitumen
本文研究了以香豆素-茚-咔唑树脂作为道路沥青改性剂的制备工艺。特别是,未反应原料与聚合物分离的条件对树脂和改性沥青的热塑性和粘接性能的影响
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引用次数: 1
Nanoscale Origin of Conductance Dips in Point-Contact Spectra of Superconductors 超导体点接触光谱中电导衰减的纳米级起源
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568572
E. Zhitlukhina, V. Tarenkov, V. Dmitrenko, M. Belogolovskii
In this contribution, we summarize current progress in identifying the origin of above-gap ‘anomalous’ features regularly observed in point-contact spectra of superconducting materials. It is shown that their origin can be associated with a nanoscale degraded coating whose contact with the superconducting bulk is imperfect. To verify this hypothesis, we have performed control measurements of differential conductance – versus – voltage bias dependences for point contacts based on Pb, thoroughly studied superconductor with a single energy gap, and a novel two-band superconducting MgB2 compound. Calculated characteristics well describe experimental findings for these two fundamentally different materials.
在这篇文章中,我们总结了目前在确定超导材料点接触光谱中经常观察到的间隙以上“异常”特征的起源方面的进展。结果表明,它们的起源可能与纳米级降解涂层与超导体接触不完美有关。为了验证这一假设,我们对基于Pb的点接触的差分电导与电压偏置依赖性进行了控制测量,深入研究了具有单能隙的超导体,以及一种新的双带超导MgB2化合物。计算出的特性很好地描述了这两种完全不同的材料的实验结果。
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引用次数: 0
Melanin-based Organic-inorganic Structures for Sensor Application 基于黑色素的有机-无机结构传感器应用
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568626
T. Obukhova, M. Dusheiko, A. Shams, D. Volynskyi, Dmytro Mazulenko, Bohdan Soloshchuk, Davidenko Stanislav
Melanin-silicon structures are promising organic-inorganic materials that combine the benefits of biopolymer and conventional semiconductors. In diode-like mode, the rectification factor is up to 500 and depends on melanin deposition time. Melanin-silicon structures could be used for glucose and volatile organic compounds vapors detection with sensitivity up to 18 mA/% and 0.23 A∙g/cm-3 respectively.
黑色素-硅结构是很有前途的有机-无机材料,它结合了生物聚合物和传统半导体的优点。在类二极管模式下,整流系数高达500,取决于黑色素沉积时间。黑色素硅结构可用于葡萄糖和挥发性有机化合物的检测,灵敏度分别高达18 mA/%和0.23 A∙g/cm-3。
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引用次数: 1
Nanostructural AlNiCoFeCrTi High-Entropy Coatings Performed by Cold Spraying 冷喷涂制备纳米结构AlNiCoFeCrTi高熵涂层
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568613
S. Nakonechnyi, A. Yurkova
In this study the high-entropy alloy (HEA) coatings was sprayed by cold spraying (CS) method on steel substrate from AlNiCoFeCrTi HEA powder fabricated by short-time mechanical alloying (MA) and annealing. It was determined that in the MA of powder mixture forming metastable nanostructured bcc solid solution which changes to ordered bcc solid solution (B2 phase) after annealing and vice versa after additional grinding. Also after annealing AlNiCoFeCrTi HEA powder contains intermetallic σ-phase and TiC particles which retain in powder after its grinding. So, before deposition the feedstock powder consists of disordered bcc solid solution, an intermetallic σ-phase, and TiC carbide. Mean thickness of deposited coatings is about 450 μm. Due to low temperature of CS process, AlFeNiCoCrTi coating has same phase composition and nanostructural state as a feedstock powder. The Vickers hardness of AlFeNiCoCrTi HEA coating is 10.3±0.3 GPa. Coating has very low porosity (<1%) and good adhesion to the steel substrate. High strength characteristics of the coating are provided by the high characteristics of feedstock powder and its strengthening mechanisms, as well as impact hardening during spraying at a supersonic speed at low temperature.
以短时间机械合金化(MA)和退火法制备的AlNiCoFeCrTi HEA粉末为基体,采用冷喷涂(CS)方法在钢基体上喷涂高熵合金(HEA)涂层。结果表明,混合粉末MA中形成亚稳的纳米结构bcc固溶体,退火后变为有序的bcc固溶体(B2相),外加研磨后变为有序的bcc固溶体(B2相)。退火后的AlNiCoFeCrTi HEA粉末中含有金属间σ相和TiC颗粒,这些颗粒在磨削后仍保留在粉末中。因此,沉积前的原料粉末由无序的bcc固溶体、金属间σ相和TiC碳化物组成。镀层的平均厚度约为450 μm。由于CS工艺温度较低,AlFeNiCoCrTi涂层与原料粉末具有相同的相组成和纳米结构状态。AlFeNiCoCrTi HEA涂层的维氏硬度为10.3±0.3 GPa。涂层孔隙率极低(<1%),与钢基体附着力好。涂层的高强度特性是由原料粉末的高特性及其强化机制以及低温超音速喷涂过程中的冲击硬化提供的。
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引用次数: 1
Characteristics of Metallized Polymeric Raw Materials 金属化高分子原料的特性
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568393
A. Kucherenko, Olena Nikitchuk, N. Baran, Ľ. Dulebová, M. Kuznetsova, V. Moravskyi
On the example of metal-filled polyvinyl chloride composites obtained by processing metallized polymer granules, the need to develop an additional indicator that will better characterize the properties of polymer composites is shown. The proposed hand takes into account the change in the size of the polymer granules used for metallization and characterizes the metallized raw material by the number of granules required to obtain a material with a metal content of 1%. The use of such an indicator allows explaining the different behavior of metal-filled composites with the same metal content in them. The developed indicator is informative and easy to use and define.
以加工金属化聚合物颗粒获得的金属填充聚氯乙烯复合材料为例,说明需要开发一种能更好地表征聚合物复合材料性能的附加指标。提出的方法考虑了用于金属化的聚合物颗粒尺寸的变化,并通过获得金属含量为1%的材料所需的颗粒数量来表征金属化原料。使用这种指标可以解释金属含量相同的金属填充复合材料的不同行为。所开发的指标信息丰富,易于使用和定义。
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引用次数: 2
Influence of Cu+↔Ag+ Cationic Substitution on Electrical Properties of Ceramics Based on (Cu1-x Agx)7GeSe5I Nanopowders Cu+↔Ag+阳离子取代对(Cu1-x Agx)7GeSe5I纳米粉体陶瓷电性能的影响
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568575
I. Shender, V. Studenyak, A. Pogodin, Michael Filep, T. Malakhovska, O. Kokhan, I. Studenyak
Ceramic samples on the basis of nanocrystalline powders $mathrm{c}_{mathrm{u}1-mathrm{x}} A mathrm{g}_{mathrm{x}})_{7}$GeSe5I(x=0,0.25,0.5,0.75,1) were made by cold pressing technique at a pressure of $sim$0.4 GPa with further annealing during 36 hours at 873 K. The size of ceramic materials crystallites is determined by the method of microstructural analysis. Investigation of electrical properties of ceramics based on (Cu1-xA$mathrm{g}_{mathrm{x}})_{7}$GeSe5I mixed crystals were carried out by the method of impedance spectroscopy in the temperature range 293-383K and in the frequency range from 10 Hz to 300 kHz. Analysis of Nyquist plots allowed to determine the ionic and electronic components of electrical conductivity, the temperature dependence of which in Arrhenius coordinates has a linear character, which indicates their thermoactivation mechanism. Compositional behaviour of both components of electrical conductivity (ionic and electronic) and their activation energies were estimated. Their nonlinear character is explained by both the complex process of recrystallization and Cu+$leftrightarrow$ Ag+ cationic substitution.
以纳米晶粉末$mathrm{c}_{mathrm{u}1-mathrm{x}} A mathrm{g}_{mathrm{x}})_{7}$ GeSe5I(x=0,0.25,0.5,0.75,1)为基础,在$sim$ 0.4 GPa的压力下,采用冷压技术制备陶瓷样品,并在873 K下退火36小时。用显微结构分析方法确定陶瓷材料的晶粒尺寸。采用阻抗谱法研究了(Cu1-xA $mathrm{g}_{mathrm{x}})_{7}$ GeSe5I混合晶体陶瓷在293 ~ 383k温度范围和10 Hz ~ 300 kHz频率范围内的电性能。Nyquist图的分析可以确定电导率的离子和电子成分,它们在Arrhenius坐标下对温度的依赖具有线性特征,这表明它们的热活化机制。估计了电导率(离子和电子)组分的组成行为及其活化能。它们的非线性特性可以用Cu+ $leftrightarrow$ Ag+阳离子取代和复杂的再结晶过程来解释。
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引用次数: 0
Study of Thermal Annealing on Morphology, Structure and Optical Properties Of CdSe Thin Films at Different Annealing Temperatures 不同退火温度下CdSe薄膜形貌、结构和光学性能的热退火研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568623
S. Najim, A. M. Muhammed, A. Pogrebnjak
CdSe thin films were deposited on the glass substrate by chemical bath deposition and annealed at various temperatures (373, 573, 773, and 873 K). Scanning electron microscopy (SEM) was used to study the surface of hexagonal structure and the grains with different sizes increasing with annealing temperature. X-ray diffraction (XRD) spectra with a distinguish peak (002) for CdSe films with a hexagonal structure and annealed films were polycrystalline. The crystallinity was improved at 873 K. The bandgap for CdSe films was 2.2 eV, which decreased with increasing annealing temperature.
采用化学浴沉积方法在玻璃基板上沉积CdSe薄膜,并在不同温度(373、5773、773、873 K)下进行退火,利用扫描电镜(SEM)研究了薄膜表面呈六边形结构,晶粒大小随退火温度的升高而增大。具有六方结构的CdSe薄膜和退火后的CdSe薄膜的x射线衍射(XRD)光谱具有分辨峰(002)。结晶性在873 K时得到改善。CdSe薄膜的带隙为2.2 eV,随退火温度的升高而减小。
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引用次数: 0
期刊
2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)
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