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Experimental investigation of nucleate pool boiling heat transfer performance of carbon nanotubes porous coating 碳纳米管多孔涂层核池沸腾换热性能实验研究
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-12 DOI: 10.1007/s10973-025-15224-2
Sudhir Kumar Singh, Deepak Sharma, Sanjay Kumar Gupta

Pool boiling is extremely effective in dissipating high heat flux at relatively low surface superheat temperatures, making it a key focus in two-phase heat transfer research and valuable for numerous thermal management applications. In the current research, the pool boiling heat transfer performance of a multi-walled carbon nanotubes (MWCNTs) porous coated surface was investigated in deionized water at saturated and atmospheric pressure state. A two-step electrochemical deposition method involving high current density for a short period (coating phase) and low current density for longer period (bonding strength phase) was used to obtain the MWCNTs porous coating. The different wettability characteristics of the surface were prepared by varying the current density to explore the surface wettability effect on boiling performance. The MWCNTs surface showed a prior onset of nucleate boiling with a maximum reduction of 37.58% in comparison with the plain surface. The coated surfaces yielded a high heat flux at lower wall superheat than the bare copper surface. The critical heat flux of MWCNTs coated surface was much higher and thereby exhibited a greater safety margin by a maximum increase of 108.5%. The heat transfer coefficient of the MWCNTs surface surpassed the bare surface across entire heat flux, representing a maximum enhancement of 113.85%. An increase in current density during the coating phase increased the hydrogen bubble evolution, leading to a greater porosity. This increased porosity contributed to higher surface roughness and improved wettability, ultimately resulting in an increased nucleation sites density and bubble release frequency.

池沸腾在相对较低的表面过热温度下能够非常有效地消散高热流密度,使其成为两相传热研究的重点,并在许多热管理应用中具有重要价值。本研究研究了饱和和常压状态下多壁碳纳米管(MWCNTs)多孔包覆表面在去离子水中的沸腾换热性能。采用短时间高电流密度(涂层阶段)和长时间低电流密度(结合强度阶段)的两步电化学沉积方法获得了MWCNTs多孔涂层。通过改变电流密度制备不同表面润湿性特性,探讨表面润湿性对沸腾性能的影响。与普通表面相比,MWCNTs表面显示出核沸腾的提前发生,最大还原率为37.58%。在低壁过热度下,涂层表面比裸铜表面产生更高的热流密度。MWCNTs涂层表面的临界热流密度要高得多,因此具有更大的安全裕度,最大增幅为108.5%。在整个热流密度上,MWCNTs表面的换热系数超过了裸露表面,最大增强幅度为113.85%。在涂层阶段,电流密度的增加增加了氢泡的演化,导致孔隙率的增加。孔隙度的增加有助于提高表面粗糙度和润湿性,最终导致成核位点密度和气泡释放频率的增加。
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引用次数: 0
Recent advances in thermophysical properties of MXene and its hybrid nanofluid for thermal application: progress, opportunities, and challenges MXene及其混合纳米流体热物理性质研究进展:进展、机遇和挑战
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-12 DOI: 10.1007/s10973-025-15210-8
Ye Zar Ni Htwe, Hussin Mamat

Nanofluids have facilitated the improvement of several current thermal application performances. The improved working fluids possess remarkable thermophysical qualities, rendering them superior alternatives to conventional working fluids. Conversely, MXenes have been demonstrated in the literature to possess the highest thermal conductivity compared to all other nanoscale materials. Consequently, when these materials are uniformly distributed in a base fluid, the resultant suspension is expected to achieve significantly greater effective thermal conductivity than its equivalent. Despite this fact, challenges remain regarding these fluids. The primary limitation is the dispersion stability of nanoparticles, which can result in the deterioration of the nanofluid’s advantageous features over time, ultimately leading to a loss of effectiveness. This paper is devoted to a comprehensive review of MXene nanofluids and their application in thermal systems common in the energy sector. This paper initially examines the synthesis methods of MXene and elucidates the production techniques for nanofluids. The stability and thermal conductivity of MXene nanofluid were examined. Furthermore, the thermophysical characteristics and thermal applications of MXene nanofluid are also examined. Finally, the issues associated with MXene nanofluid and the existing gaps in scientific understanding are presented to establish future research directions.

纳米流体促进了几种当前热应用性能的改善。改进后的工质具有显著的热物理特性,是传统工质的优良替代品。相反,与所有其他纳米级材料相比,MXenes在文献中已被证明具有最高的导热性。因此,当这些材料均匀分布在基液中时,所得到的悬浮液的有效导热系数有望显著高于同等材料。尽管如此,这些流体仍然存在挑战。主要的限制是纳米颗粒的分散稳定性,这可能导致纳米流体的优势特性随着时间的推移而恶化,最终导致有效性的丧失。本文全面综述了MXene纳米流体及其在能源部门常见的热系统中的应用。本文对MXene的合成方法进行了初步研究,并对纳米流体的生产技术进行了阐述。考察了MXene纳米流体的稳定性和导热性。此外,还研究了MXene纳米流体的热物理特性和热应用。最后,提出了与MXene纳米流体相关的问题和存在的科学认识空白,以确定未来的研究方向。
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引用次数: 0
Thermal error control technology for high-speed motorized spindles: a review 高速电主轴热误差控制技术综述
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-12 DOI: 10.1007/s10973-025-15251-z
Yaonan Cheng, Yongjian Cui, Shenhua Jin, Wenjie Zhai, Xingwei Zhou

The high-speed motorized spindle is the fundamental component of computerized numerical control (CNC) machine tools. During the working process, the components within the motorized spindle exhibit varying degrees of thermal elongation due to differing coefficients of thermal expansion, which in turn lead to the generation of thermal errors. Thermal error is a crucial determinant of the motorized spindle’s machining precision. With the continuous improvement of industrial automation levels and the increasing complexity of machining requirements, controlling thermal error has emerged as a critical focus in the study of motorized spindles. Unlike previous reviews, which typically focused solely on one aspect of thermal error control, this paper proposes a comprehensive and systematic review framework that integrates the analysis of three key technologies: motorized spindle cooling technology, thermal error compensation technology, and motorized spindle materials. This integrated approach offers a comprehensive perspective on thermal error control, highlighting the respective strengths and limitations of various technologies. Firstly, the cooling technology for the motorized spindle is categorized and analyzed. Secondly, the key steps of thermal error compensation technology are explored. The impact of various materials on the performance of motorized spindles is then discussed. The novelty of this review lies in its integration and comparative analysis of recent advances across these three domains, alongside a critical examination of their respective strengths, weaknesses, and applicability, thereby illuminating the combined impact of these diverse technologies. Finally, the analysis summarizes the shortcomings of thermal error control technology at this stage, outlines the outlook, and elaborates on the future research direction, offering theoretical guidance and technical assistance for the advancement of thermal error control technology in high-speed motorized spindles, thereby enhancing the precision machining capabilities of CNC machine tools.

高速电主轴是数控机床的基本部件。在工作过程中,由于不同的热膨胀系数,电主轴内的部件表现出不同程度的热伸长,从而导致热误差的产生。热误差是决定电主轴加工精度的重要因素。随着工业自动化水平的不断提高和加工要求的日益复杂,热误差控制已成为电主轴研究的重点。与以往的综述不同,以往的综述通常只关注热误差控制的一个方面,本文提出了一个全面而系统的综述框架,集成了三个关键技术的分析:电主轴冷却技术、热误差补偿技术和电主轴材料。这种集成的方法为热误差控制提供了一个全面的视角,突出了各种技术各自的优势和局限性。首先对电主轴的冷却技术进行了分类和分析。其次,探讨了热误差补偿技术的关键步骤。然后讨论了各种材料对电主轴性能的影响。这篇综述的新颖之处在于它对这三个领域的最新进展进行了整合和比较分析,同时对它们各自的优势、劣势和适用性进行了批判性检查,从而阐明了这些不同技术的综合影响。最后,分析总结了现阶段热误差控制技术存在的不足,并对其进行了展望,阐述了未来的研究方向,为高速电主轴热误差控制技术的发展提供理论指导和技术支持,从而提高数控机床的精密加工能力。
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引用次数: 0
Enhancing thermo-aerodynamic performance of solar chimney power plants 提高太阳能烟囱电厂的热气动性能
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-12 DOI: 10.1007/s10973-025-15258-6
Omar Ben Elkhettab Mokrani, Belkhir Settou, Med Hassen Sellami, Abderrahmane Benhamza, Erdem Cuce

Renewable energy technologies, including Solar Chimney Power Plants (SCPP), harness natural resources to produce clean energy. SCPPs use solar energy to heat air, generating an upward flow that drives turbines to produce electricity. This study, conducted at the University of Ouargla, Algeria, explores design improvements to enhance SCPP performance. The study found that a collector opening height of 0.05 m provided the highest efficiency, achieving an air velocity of 5.8 m s−1 and a maximum collector temperature of 68.3 °C, with a temperature difference of 51.2 °C relative to the ambient air. In comparison, opening heights of 0.15 m and 0.20 m resulted in lower airflow velocities of 4.2 m s−1 and 3.8 m s−1, respectively, causing heat loss. The use of a curved junction between the collector and chimney improved airflow, reaching 6.7 m s−1 at the chimney entrance, outperforming straight junctions. Incorporating an air guide further enhanced airflow, with a peak velocity of 6.7 m s−1 for a guide height of 1.0 m. The innovative helical collector design extended the airflow path to 10 m, improving energy output. When combined with an air guide, the helical collector system achieved the highest air velocity of 7.2 m s−1. These findings demonstrate that thoughtful structural enhancements significantly boost SCPP performance.

可再生能源技术,包括太阳能烟囱发电厂(SCPP),利用自然资源生产清洁能源。SCPPs利用太阳能加热空气,产生向上的气流,驱动涡轮机发电。这项由阿尔及利亚瓦尔格拉大学进行的研究,探讨了提高SCPP性能的设计改进。研究发现,当集热器开口高度为0.05 m时,效率最高,风速为5.8 m s - 1,集热器最高温度为68.3℃,相对于环境空气温差为51.2℃。相比之下,开口高度为0.15 m和0.20 m时,流速较低,分别为4.2 m s−1和3.8 m s−1,造成热损失。集热器和烟囱之间的弯曲连接处的使用改善了气流,在烟囱入口处达到6.7 m s - 1,优于直连接处。采用导风板进一步增强气流,导风板高度为1.0 m时,峰值速度为6.7 m s - 1。创新的螺旋收集器设计将气流路径扩展到10米,提高了能量输出。当与空气导流器相结合时,螺旋收集器系统达到了7.2 m s−1的最高空气速度。这些发现表明,深思熟虑的结构增强显著提高了SCPP的性能。
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引用次数: 0
Image-based assessment of high-temperature degradation of fibre-reinforced sustainable concrete 基于图像的纤维增强可持续混凝土高温降解评价
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-12 DOI: 10.1007/s10973-025-15267-5
Samudrala Krishna Priya Rao, Valishetty Bharath, Tezeswi Tadepalli

The work applies an imaging-based approach to evaluate the degradation of concrete subject to high-temperature conditions, providing information on non-destructive assessment methodologies based on colour characteristics. Specifically, it investigates the potential of using the hue, saturation, and intensity (HSI) colour space to quantify the thermal deterioration of ordinary Portland cement concrete (OPCC) of M30 grade, multi-component binder-based cement concrete (MBCC), and fibre-reinforced multi-component binder-based cement concrete (FRMBCC). Concrete cube specimens of OPCC, MBCC, and FRMBCC are cured for 28 days and exposed to various temperatures like ambient room temperature, 100 °C, 400 °C, 600 °C, and 800 °C. These specimens are photographed under medium light indoor (MLI) lighting conditions for analysis. Digital images of the concrete surfaces are captured and analyzed using ImageJ software to extract RGB values, then converted into HSI colour parameters. The compressive strength of the specimens is evaluated at different temperature exposures to establish correlations between the HSI values and the residual compressive strength. The results demonstrate that the hue parameter exhibits strong correlations with residual compressive strength for OPCC and MBCC, while FRMBCC showed a moderate correlation. The saturation parameter displayed a moderate correlation for OPCC, MBCC, and FRMBCC. The intensity parameter displayed an excellent correlation for OPCC and a reasonably moderate correlation for MBCC and FRMBCC. The study demonstrates the application of the hue–saturation–intensity (HSI) colour space for evaluating concrete deterioration, with different concrete types showing varying levels of fit between data points and polynomial curves. These findings support imaging-based non-destructive evaluation techniques for assessing the condition of concrete structures based on their colour attributes, which could lead to more efficient and cost-effective inspection and maintenance practices.

这项工作应用了基于成像的方法来评估高温条件下混凝土的降解,提供了基于颜色特征的非破坏性评估方法的信息。具体来说,它研究了使用色调、饱和度和强度(HSI)色彩空间来量化M30级普通波特兰水泥混凝土(OPCC)、多组分粘合剂基水泥混凝土(MBCC)和纤维增强多组分粘合剂基水泥混凝土(FRMBCC)的热劣化的潜力。OPCC、MBCC、FRMBCC混凝土立方体试件在室温、100℃、400℃、600℃、800℃等不同温度下养护28天。这些标本在中光室内(MLI)照明条件下拍摄以供分析。利用ImageJ软件对混凝土表面的数字图像进行捕获和分析,提取RGB值,然后转换为HSI颜色参数。试件的抗压强度在不同温度下进行评估,以建立HSI值与残余抗压强度之间的相关性。结果表明,色相参数与OPCC和MBCC的残余抗压强度具有较强的相关性,而FRMBCC的残余抗压强度具有中等相关性。饱和度参数与OPCC、MBCC和FRMBCC呈中等相关性。强度参数与OPCC表现出良好的相关性,与MBCC和FRMBCC表现出适度的相关性。该研究展示了色彩饱和度-强度(HSI)色彩空间用于评估混凝土劣化的应用,不同的混凝土类型在数据点和多项式曲线之间显示出不同的拟合水平。这些发现支持基于图像的无损评估技术,基于其颜色属性来评估混凝土结构的状况,这可能导致更有效和更具成本效益的检查和维护实践。
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引用次数: 0
Advanced thermal characterization of MHD couple-stress nanofluid flow with bioconvection and radiation over a stretching cylinder 基于生物对流和辐射的MHD耦合应力纳米流体在拉伸圆柱体上流动的高级热表征
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-11 DOI: 10.1007/s10973-025-15029-3
M. Nasir, M. Salman Kausar, M. Waqas, Nurnadiah Zamri

This research accounts bioconvection influence in convectively heated magnetized couple-stress material confined by cylindrical stratified regime. The mathematical modeling includes Brownian diffusive together with thermophoretic aspects, while suspension stability is ensured by considering bioconvection features owing to gyrotactic microorganisms. Robin-type thermosolutal conditions are deployed to elaborate heat–mass transmission at the magnetized cylindrical surface subject to suction/injection (wall transpiration). The investigation further considers radiation impact in energy expression. The governing mathematical (partial differential) expressions are transmuted into nonlinear ordinary differential equations (ODEs) by implementing apposite variables. These ODEs are computed analytically by utilizing homotopy scheme, assuring convergence via selection of suitable auxiliary variables. The influences of key variables on non-dimensional profiles are systematically scrutinized. The velocity exhibits an increasing trend when curvature, mixed convection and injection parameters are escalated. However, it demonstrates opposite behavior when Reynolds number, Hartman number, couple stress, and bioconvection variables are increased. The outcomes provide valuable perception into nanofluidic transportation in state-of-the-art coating technologies, bio-microsystems, and thermal energy mechanisms where magnetized nanomaterials are considered subject to bioconvection phenomena.

本文研究了受圆柱形层状约束的对流加热磁化耦合应力材料的生物对流影响。数学模型考虑了布朗扩散和热泳特性,同时考虑了陀螺效应微生物的生物对流特性,保证了悬浮稳定性。采用罗宾式热溶质条件,在吸力/注入(壁面蒸腾)作用下,在磁化圆柱表面进行热质传递。研究进一步考虑了辐射对能量表达的影响。控制数学(偏微分)表达式转化为非线性常微分方程(ode)通过实现适当的变量。利用同伦格式解析计算这些ode,通过选择合适的辅助变量保证其收敛性。系统地研究了关键变量对无量纲轮廓的影响。随着曲率、混合对流和注入参数的增大,速度呈增大趋势。然而,当雷诺数、哈特曼数、耦合应力和生物对流变量增加时,则表现出相反的行为。这些结果为纳米流体在最先进的涂层技术、生物微系统和热能机制中的传输提供了有价值的见解,其中磁化纳米材料被认为受生物对流现象的影响。
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引用次数: 0
Comprehensive investigation of heat transfer performance in polymer heat exchangers with gyroid layers: a definitive experimental and computational study 具有旋转层的聚合物换热器传热性能的综合研究:一个明确的实验和计算研究
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-10 DOI: 10.1007/s10973-025-14982-3
Selvan Pugalenthi, Suraboopathy Karuppasamy

Polymeric heat exchangers are alternatives to traditionally made steel heat exchangers to reduce corrosion and increase longevity. Chemical industries typically employ polymer-based heat exchangers to heat and cool concentrated acids as well as alkaline solutions. Primarily, polyethylene terephthalate glycol (PETG) exhibits excellent chemical inertness and is resistant to corrosion, thereby reducing the fouling factor. However, it has low thermal conductivity. This work enables the fused deposition additive manufacturing (AM) technique to produce PETG-based polymer heat exchangers (PHE) with gyroid structures to achieve a high heat transfer rate by reducing the wall thickness and increasing the surface area of the material. By varying the process parameters, such as volume flow rate and the geometry of the heat exchanger, the heat transfer coefficient (HTC) is enhanced by 287.81% at 1 lpm compared to conventional double pipe heat exchangers. On comparing the effectiveness of the proposed heat exchanger with the conventional one, the enhancement is 240.37% at 1 lpm. Validation studies using CFD were also done and compared with experimental results, which are found to be in agreement. Hot fluid temperature drops by 16 °C. The thermal enhancement factor of the proposed heat exchanger is also very high (3.40) when compared to the other exchangers. This leads to the compactification of the heat exchanger.

聚合物热交换器是传统钢制热交换器的替代品,可以减少腐蚀并延长使用寿命。化学工业通常使用基于聚合物的热交换器来加热和冷却浓酸以及碱性溶液。首先,聚对苯二甲酸乙二醇酯(PETG)具有优异的化学惰性,耐腐蚀,从而减少了污染因素。然而,它的导热系数很低。这项工作使熔融沉积增材制造(AM)技术能够生产具有旋转结构的聚乙二醇聚合物热交换器(PHE),通过减少壁厚和增加材料表面积来实现高传热率。通过改变工艺参数,如体积流量和换热器的几何形状,在1lpm时,传热系数(HTC)比传统的双管换热器提高了287.81%。与传统换热器相比,该换热器在1 lpm时的效率提高了240.37%。利用CFD进行了验证研究,并与实验结果进行了比较,结果一致。热流体温度下降16°C。与其他换热器相比,该换热器的热增强系数也很高(3.40)。这就导致了热交换器的致密化。
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引用次数: 0
Investigation of combustion and emission of ethanol-diesel blended fuel in diesel engine using CFD 乙醇-柴油混合燃料在柴油机内燃烧与排放的CFD研究
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-10 DOI: 10.1007/s10973-025-15227-z
Abhijeet Ganesh Ghogare, Vijay Panchore, Upendra Rajak, Tikendra Nath Verma

Mixing ethanol into pure diesel fuel has significant promise for enhancing engine performance and reducing hazardous emissions in Compression Ignition Engines (CIEs). A comprehensive numerical analysis using a well-validated single-cylinder, water-cooled CIE model to evaluate the impact of ethanol–diesel blends at different ratios (0%, 5%, 10%, 15%, and 20%) on performance and emission has been carried out in this study. The analyzed key parameters include temperature, pressure of the cylinder, rate of heat release, and gas temperature at exhaust and emissions of pollutants, including NOx, soot, CO, CO₂, and others. Findings indicate that a 5% ethanol blend provides excellent improvements, significantly improving combustion efficiency and lowering exhaust gas temperature while maintaining emission quality. Although these higher blends reduce the overall advantages of lower emissions, these emissions are much lower compared to pure diesel combustion, with a 20% blend resulting in a 91.7% decrease in NOx emissions. Blending ethanol up to 20% shows significant potential for improving performance and reducing emissions in CIEs, with a 5% blend exhibiting the lowest emission characteristics with acceptable performance characteristics.

在压缩点火发动机(CIEs)中,将乙醇混合到纯柴油燃料中对于提高发动机性能和减少有害排放具有重要的前景。本研究使用经过验证的单缸水冷CIE模型进行了全面的数值分析,以评估不同比例(0%,5%,10%,15%和20%)的乙醇-柴油混合物对性能和排放的影响。分析的关键参数包括温度、气缸压力、热量释放速度、排气温度以及NOx、烟尘、CO、CO₂等污染物的排放量。研究结果表明,5%乙醇混合物提供了出色的改进,显著提高了燃烧效率,降低了废气温度,同时保持了排放质量。虽然这些更高的混合物降低了低排放的整体优势,但与纯柴油燃烧相比,这些排放要低得多,20%的混合物导致氮氧化物排放量减少91.7%。将乙醇混合至20%,在CIEs中显示出改善性能和减少排放的巨大潜力,5%的混合物显示出最低的排放特性和可接受的性能特性。
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引用次数: 0
Significance of nanolayers in enhanced thermal conductivity of nanofluid: an application for solar energy optimization 纳米层在增强纳米流体导热性中的意义:在太阳能优化中的应用
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-10 DOI: 10.1007/s10973-025-15173-w
N. Sandeep, S. Lingamurthy, Shivanjali Shukla, K. Anantha Kumar

In modern eons, improving the thermal conductivity of conventional liquids has become a significant challenge in various nanotechnology applications. The present study tackles this issue by investigating how nanolayers contribute to enhancing the heat transfer capability of base fluids. For this, we considered the flow over a curved stagnation region and suspended the base liquid with sphere and cylinder-shaped magnetite (Fe3O4) nanoparticles. To calculate the augmented thermal conductivity, we considered the nanolayer formed around the sphere and cylinder-shaped nanometer-sized particles and discussed it in detail with the help of simultaneous outcomes. We also considered the magnetic field, radiative, Ohmic heating, and uneven temperature sink/source effects for physical relevance and modeled the problem accordingly. The computational outcomes of flow and thermal fields are obtained using the bvp5c MATLAB technique. The nanolayer formed around the nanoparticles has a significant impact on the momentum and thermal boundary layers. Additionally, the nanolayer formed around spherical-shaped nanoparticles exhibited a significant increase in the heat transport rate compared to that formed around cylindrical-shaped nanoparticles. This study applies to solar energy generation through nano-coating.

在现代,提高传统液体的导热性已成为各种纳米技术应用中的重大挑战。本研究通过研究纳米层如何有助于提高基础流体的传热能力来解决这一问题。为此,我们考虑了在弯曲停滞区域的流动,并用球形和圆柱形磁铁矿(Fe3O4)纳米颗粒悬浮在基液上。为了计算增广热导率,我们考虑了球形和圆柱形纳米颗粒周围形成的纳米层,并借助同步结果对其进行了详细讨论。我们还考虑了磁场、辐射、欧姆加热和不均匀温度汇/源效应的物理相关性,并相应地对问题进行了建模。利用bvp5c MATLAB技术获得了流场和热场的计算结果。纳米颗粒周围形成的纳米层对动量边界层和热边界层有显著影响。此外,围绕球形纳米颗粒形成的纳米层的热传递率明显高于围绕圆柱形纳米颗粒形成的纳米层。本研究将纳米涂层应用于太阳能发电。
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引用次数: 0
Temperature rise caused by shear action in melting process of PE: effect of viscosity 聚乙烯熔融过程中剪切作用引起的温升:粘度的影响
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-10 DOI: 10.1007/s10973-025-15231-3
Chenchao Fu, Run Zhang, Mingfei Liu, Zetian Hua, Lin Jiang, Ping Xue, Jianchen Cai, Jinyun Jiang

The temperature rise caused by shear action during melting for high molecular polymer is widespread and difficult to control, especially for the co-rotating twin-screw extrusion (CRTSE) process. Considering the very small gap between the screw and the barrel, it is difficult to in-line measure and control the value of materials’ temperature along the extrusion direction. Consequently, a co-rotating twin-rotor mixing apparatus with a high-precision temperature sensor is employed to explore the temperature variation of polyethylene (PE) with different average molecular weights (Mw) from solid to melt, similar with the CRTSE process, but the material will not be conveyed forward. The experiment’s result indicates that a higher rotor speed and a lower meshing clearance result in a higher temperature rise. Meanwhile, unexpectedly, an interesting experimental phenomenon is observed: the temperature rise caused by shear action in high-viscosity PE increases with the rotor speed, while it enlarges initially and then stabilizes in low-viscosity PE as the increased rotor speed. Therefore, it is speculated that the temperature rise during the processing strongly depends on the viscosity. Simulation studies based on Ludovic software by actively varying the consistency index and power-law exponent confirm the correctness of the experimental conjecture under a wider screw speed and viscosity range. This study has theoretical and practical implications for a deeper understanding of the temperature rise caused by shear action in polymeric materials during extrusion.

高分子聚合物熔炼过程中剪切作用引起的温升普遍存在且难以控制,特别是在同向旋转双螺杆挤压(CRTSE)过程中。由于螺杆与料筒之间的间隙很小,物料沿挤出方向的温度值难以在线测量和控制。因此,采用带有高精度温度传感器的同向旋转双转子混合装置,研究了不同平均分子量(Mw)聚乙烯(PE)从固体到熔体的温度变化,与CRTSE过程类似,但材料不会向前输送。实验结果表明,转子转速越高,啮合间隙越小,温升越高。同时,意外地观察到一个有趣的实验现象:在高粘度PE中,剪切作用引起的温升随着转子转速的增加而增加,而在低粘度PE中,随着转子转速的增加,剪切作用引起的温升先增大后趋于稳定。因此,推测加工过程中的温升很大程度上取决于粘度。基于Ludovic软件的模拟研究通过主动改变一致性指数和幂律指数证实了实验猜想在更宽的螺杆转速和粘度范围下的正确性。该研究对深入了解聚合物材料挤压过程中剪切作用引起的温升具有理论和实践意义。
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Journal of Thermal Analysis and Calorimetry
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