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2020 IEEE 3rd International Conference on Dielectrics (ICD)最新文献

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Octa-functional POSS: An Epoxy Filler or Co-monomer? 八官能团POSS:环氧填料还是共聚单体?
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341817
S. Riarh, O. Vryonis, A. Vaughan
Particle tethering with the matrix permits property manipulation depending on the respective architecture and chemistry. However, integration of highly reactive moieties into epoxy networks may detrimentally affect the reaction stoichiometry. In this study, octa glycidyl polyhedral oligomeric silsesquioxane (OG POSS) was incorporated into an epoxy matrix (a) by considering it as a co-monomer (requiring stoichiometric compensation) and (b) by considering it as a silica-based filler (simple addition without compensation). The simple addition of OG POSS resulted in a considerable glass transition temperature (Tg) decrease due to impaired stoichiometry, while the stoichiometric addition moderated this effect. These results, supported by the dielectric data, demonstrate that OG POSS is better considered as a co-monomer.
粒子与矩阵的绑定允许根据各自的结构和化学性质进行属性操作。然而,将高活性的部分整合到环氧网络中可能会对反应的化学计量产生不利影响。在本研究中,将八乙酸甘油三酯多面体低聚硅氧烷(OG POSS)作为共聚单体(需要化学计量补偿)和(b)将其作为硅基填料(无需补偿的简单添加)掺入环氧基基体中(a)。OG POSS的简单添加导致玻璃化转变温度(Tg)显著降低,这是由于化学计量的影响,而化学计量的添加则缓和了这一影响。这些结果与介电数据相一致,表明OG POSS更适合作为共聚单体。
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引用次数: 0
Dielectric and Electrical Insulation Properties of PTFE/PP for HTS Power Apparatus Application 高温超导电力设备用聚四氟乙烯/聚丙烯的介电绝缘性能
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9342017
M.Y. Wang, B. Du, X.T. Han, Z.X. Liu, Y. Li, Y. Zhang, Jin Li, Z.L. Li, C. Han, Z. Hou
Polypropylene laminated paper (PPLP) and liquid nitrogen (LN2) is widely used as insulation and coolant, respectively, in high-temperature superconducting (HTS) cable. Dielectric loss of PPLP plays an important role in the loss of HTS transmission system. In this paper, polytetrafluoroethylene (PTFE) filter papers were chosen to take place of Kraft paper (KP) in composite insulation system. Two layers of PTFE filter paper and one layer of polypropylene (PP) film were processed into sandwich structure through hot-press method. Experimental results show that the dielectric loss can be cut to half by replacing KP with PTFE filter in AC HTS transmission system. The trap level of PTFE/PP composite insulation is shallower. The surface discharge voltage of PTFE/PP is higher than that of PPLP. PTFE/PP also has stronger ability of resisting partial discharge and shows higher partial discharge inception voltage than PPLP does. And the breakdown voltage of PTFE/PP composite insulation is higher than that of PPLP, which mainly due to the stronger resistance to discharge.
在高温超导电缆中,聚丙烯层压纸(PPLP)和液氮(LN2)分别被广泛用作绝缘和冷却剂。PPLP的介电损耗在高温超导传输系统的损耗中占有重要的地位。本文选用聚四氟乙烯(PTFE)滤纸代替牛皮纸(KP)用于复合绝缘系统。采用热压法将两层PTFE滤纸和一层聚丙烯(PP)薄膜加工成夹层结构。实验结果表明,在交流高温超导传输系统中,用聚四氟乙烯滤波器代替KP滤波器可使介质损耗降低一半。聚四氟乙烯/聚丙烯复合绝缘的疏水层较浅。PTFE/PP的表面放电电压高于PPLP。PTFE/PP抗局部放电能力更强,局部放电起始电压比PPLP高。PTFE/PP复合绝缘的击穿电压高于PPLP,这主要是由于PTFE/PP复合绝缘的抗放电能力更强。
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引用次数: 1
Effect of Pressing Mode and Pressure on Arc Ablation Performance of PTFE/BN Composites 压制方式和压力对PTFE/BN复合材料电弧烧蚀性能的影响
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341866
Zhaozi Zhang, Bingchen Song, Yongjie Nie, D. Min, Shengtao Li, Chuanchuan Wang, Tao Zhao
With the development of high voltage transmission, higher voltage is necessary. Power equipment with traditional materials can not satisfy the insulation requirement of higher voltage transmission, so excellent material is urgently needed. PTFE nozzle is important in circuit breaker which faces the problem of arc ablation, and the nozzle with better performance is helpful to improve the transmission voltage. In this paper, in order to study the influence of different pressing pressures and modes on the ablation performance of PTFE/BN composites, four pressures and two modes were adopted (cold isostatic pressing and mould pressing) to obtain 7-wt% BN doped PTFE composites. As the pressing pressure increases, the ablation amount of the specimen decreases gradually. Compared with mould pressing, the specimen prepared by cold isostatic pressing has a higher thermal conductivity and lower ablation amount, while the light reflection properties are almost the same for both preparing methods. This paper is of great significance to improve the ablation resistance of nozzle materials.
随着高压输电的发展,需要更高的电压。采用传统材料的电力设备已不能满足高压输电的绝缘要求,迫切需要优良的材料。聚四氟乙烯喷嘴在面临电弧烧蚀问题的断路器中起着重要的作用,性能较好的喷嘴有助于提高传输电压。为了研究不同压力和模式对PTFE/BN复合材料烧蚀性能的影响,采用四种压力和两种模式(冷等静压和模压)制备了掺氮量为7 wt%的PTFE复合材料。随着挤压压力的增大,试样的烧蚀量逐渐减小。与模压相比,冷等静压制备的试样具有更高的导热率和更低的烧蚀量,两种制备方法的光反射性能几乎相同。本文对提高喷嘴材料的抗烧蚀性能具有重要意义。
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引用次数: 0
Influence of Thermal Aging on the Crystallinity of EPDM Used in Power Cables Insulation 热老化对电力电缆绝缘用EPDM结晶度的影响
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9342020
D. Bouguedad, A. Mekhaldi, O. Jbara, S. Rondot, A. Hadjadj, P. Dony
In this work, ethylene propylene diene monomer (EPDM) used in power cables insulation was exposed to a thermal aging at different temperatures ranging from $80^{circ}C$ to $140^{circ}C$. Two complementary characterization techniques were used to track changes in EPDM crystalline structure during thermal aging. Differential scanning calorimetry (DSC) analysis was performed to measure the variation of the melting enthalpy $Delta H_{m}$. To highlight the modifications induced on the crystalline and amorphous fractions of the EPDM structure, we carried out X-ray diffraction (XRD) measurements. The results of both methods agree in the time and temperature dependence of the aging process. The results show that the crystallinity is improved when aging is carried out at a low temperature. When temperature increases, minor changes in the crystallinity occur at the end of the aging process. At the highest aging temperature, a drop in the crystallinity occurs from the first hours of aging, indicating a degradation of the molecular structure of the polymer.
在这项工作中,将用于电力电缆绝缘的乙丙二烯单体(EPDM)在$80^{circ}C$至$140^{circ}C$的不同温度下进行热老化。两种互补的表征技术用于跟踪EPDM在热老化过程中晶体结构的变化。用差示扫描量热法(DSC)测定了熔点焓$ δ H_{m}$的变化。为了突出对EPDM结构的结晶和非晶部分的修饰,我们进行了x射线衍射(XRD)测量。两种方法的结果在时效过程的时间和温度依赖性方面是一致的。结果表明,低温时效可以提高合金的结晶度。当温度升高时,在时效过程结束时结晶度会发生微小的变化。在最高的老化温度下,结晶度从老化的头几个小时开始下降,表明聚合物分子结构的退化。
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引用次数: 0
Improved Moisture Barrier Properties of High Temperature Vulcanized Silicone Rubber by Direct Fluorination 直接氟化法改善高温硫化硅橡胶的防潮性能
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9342007
K. Chen, Z. An, W. Huang, X. Wang, F. Zheng, Y. Zhang
Our previous results have shown that surface hydrophobicity of a high temperature vulcanized silicone rubber can be significantly enhanced by direct fluorination. In this report, the surface fluorinated sample together with the virgin sample as a reference have been investigated on their water vapor barrier properties at $30^{circ}C$ or $60^{circ}C$ in a humidity environment of 75% or 97% RH. The experimental results show that the fluorinated surface layer has a high barrier to water vapor ingress into the interior of the SIR, so that the surface fluorinated sample has a much lower absorption of moisture in comparison with the virgin sample under the same conditions. SEM images show that the fluorination leads to the formation of a fluorinated surface layer with a thickness of 0.56 $mu m$ and a nanostructured surface. The improvement of the barrier properties is attributed to a decrease in free volume of the surface layer as well as the increase in surface hydrophobicity by the fluorination, as indicated by contact angle measurements and ATR-IR and XPS analyses.
我们之前的研究结果表明,直接氟化可以显著提高高温硫化硅橡胶的表面疏水性。在本报告中,研究了表面氟化样品以及作为参考的原始样品在相对湿度为75%或97%的环境中,在30^{circ}C$或60^{circ}C$下的水蒸气阻隔性能。实验结果表明,氟化表面层对水蒸气进入SIR内部具有很高的阻隔性,因此在相同条件下,表面氟化样品的吸湿率远低于原始样品。SEM图像显示,氟化导致形成厚度为0.56 μ m的氟化表面层和纳米结构表面。接触角测量和ATR-IR和XPS分析表明,阻隔性能的改善归因于表面层自由体积的减少以及氟化引起的表面疏水性的增加。
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引用次数: 0
Inherent Correlation Between the Breakdown Strength and the Surface Flashover Performance of Epoxy Resin in N2 Atmosphere N2气氛中环氧树脂击穿强度与表面闪络性能的内在相关性
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341968
Haoming Xu, Wenfeng Liu, Zhen Li, Farooq Aslam, Shengtao Li
Surface flashover and breakdown are two typical failures of insulations, which inhibit the stability and downsizing of electrical apparatus. The two phenomena were traditional considered be affected by different factors. However, in the present study, the inherent correlation between surface flashover and gas breakdown strength was revealed. Experimentally epoxy resin composites with a thickness of 1 mm and diameter of 50 mm were prepared. Surface flashover voltages were measured for DC voltage in different pressure and temperature. Gas breakdown voltages were tested in a same condition. With temperature decreases or pressure increases, both gas breakdown voltage and surface flashover voltage increase. However, the growth rate is different for the two voltages. Gas breakdown voltage increases faster than surface flashover voltage. The ratio of flashover voltage to gas breakdown voltage decrease with gas pressure increase. This work investigates the relationship between surface flashover and gas breakdown by considering gas adsorption. It was found that sample gas adsorption capacity can affect the surface flashover voltage, but a saturation point exists. When the adsorbed gas molecules of samples reach saturation, the effect of adsorption on surface flashover performance is less than the effect of pressure on gas breakdown voltage.
表面闪络和击穿是两种典型的绝缘故障,严重影响电气设备的稳定性和小型化。传统上认为这两种现象受不同因素的影响。然而,在本研究中,揭示了表面闪络与气体击穿强度之间的内在相关性。实验制备了厚度为1 mm、直径为50 mm的环氧树脂复合材料。测量了直流电压在不同压力和温度下的表面闪络电压。在相同的条件下测试了气体击穿电压。随着温度的降低或压力的增加,气体击穿电压和表面闪络电压均升高。然而,两种电压的增长率是不同的。气体击穿电压比表面闪络电压增长快。随着气体压力的增大,闪络电压与气体击穿电压之比减小。本文从气体吸附的角度研究了表面闪络与气体击穿的关系。发现样品气体吸附量对表面闪络电压有影响,但存在饱和点。当样品的吸附气体分子达到饱和时,吸附对表面闪络性能的影响小于压力对气体击穿电压的影响。
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引用次数: 0
Analysis of Suppressing Methods and Influencing Factors of High Voltage Cable Circulating Current Based on ATP-EMTP 基于ATP-EMTP的高压电缆环流抑制方法及影响因素分析
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341884
Hongbao Zong, Yong Liu, Cheng Zhao
With the high-speed development of urban power system in China, the application of single-core cables in urban transmission and distribution grids is more and more extensive. Excessive circulating currents, generated on the metal sheath of single-core high-voltage cable, bring massive loss which will reduce cable transmission efficiency and safe operating lifetime. In this paper, the cable with cross-bonding mode was established based on ATP-EMTP. Through the simulation analysis, the relationships between the circulating current and the arrangement, segment and core current were obtained. The variations of circulating current and sheath voltage in case of the cable faults (short circuit, open circuit, commutation failure) were discussed. And the suppressing methods by using the series resistance, inductance and impedance were proposed to restrain the circulating currents. The results obtained show that the circulating currents are linearly related to the section length, arrangement and core current, which change significantly in case of short circuit, open circuit and commutation failure. The series resistance and inductance have effective suppressing effects not only on the steady state circulating currents but also on the transient circulating currents. The series inductance can make the circulating currents change smoothly
随着中国城市电力系统的高速发展,单芯电缆在城市输配网中的应用越来越广泛。单芯高压电缆的金属护套上产生过多的循环电流,会带来巨大的损耗,降低电缆的传输效率和安全使用寿命。本文建立了基于ATP-EMTP的交叉键合模式电缆。通过仿真分析,得到了循环电流与排流、分段电流和铁心电流之间的关系。讨论了在电缆发生短路、断路、换相故障时,回路电流和护套电压的变化。提出了采用电阻、电感和阻抗串联抑制回路电流的方法。结果表明,回路电流与截面长度、排列方式和铁芯电流呈线性相关,在短路、开路和换相失效情况下,回路电流变化显著。电阻和电感串联不仅对稳态循环电流有有效的抑制作用,而且对瞬态循环电流也有有效的抑制作用。串联电感可以使循环电流变化平稳
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引用次数: 3
Trap Distribution and Space Charge Behavior of PP/ULDPE/ Radical Scavenger Composites for HVDC Cable Insulation 高压直流电缆绝缘用PP/ULDPE/自由基清除剂复合材料的陷阱分布和空间电荷行为
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341829
Z. Hou, B. Du, Z. L. Li, Jin Li, C. Han, R. Xu, M. Y. Wang, C. Liu
Space charge and breakdown behavior are important factors in the design of high voltage dc (HVDC) cables. Since the working temperature together with additives has a great influence on the insulation performance of the composites, the temperature effect investigation would be highly beneficial. In this paper, the space charge test of the polypropylene (PP) /ultralow density polyethylene (ULDPE) blends and its radical scavenger modified composites are performed at 30, 60 and 90 °C, respectively. The trap distribution in the radical scavenger and the composites are investigated based on Quantum chemistry calculation and isothermal discharge current (IDC) test. The radical scavenger can introduce traps with different energy levels, which has greatly inhibited the space charge accumulation aggravated by the increasing temperature in the PP/ULDPE (PU) blends. The PP/ULDPE blends with 0.3 wt% radical scavenger exhibit great space charge performance for HVDC cable insulation.
空间电荷和击穿行为是高压直流电缆设计中的重要因素。由于工作温度和添加剂对复合材料的绝缘性能有很大的影响,因此研究温度效应是非常有益的。本文对聚丙烯(PP) /超低密度聚乙烯(ULDPE)共混物及其自由基清除剂改性复合材料分别在30℃、60℃和90℃下进行了空间电荷测试。基于量子化学计算和等温放电电流(IDC)测试,研究了自由基清除剂和复合材料中的陷阱分布。自由基清除剂可以引入不同能级的陷阱,极大地抑制了PP/ULDPE (PU)共混物中因温度升高而加剧的空间电荷积累。含有0.3 wt%自由基清除剂的PP/ULDPE共混物在高压直流电缆绝缘中表现出良好的空间电荷性能。
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引用次数: 0
Feasibility study of flexible gas-insulated transmission line using CF3I gas mixture CF3I混合气柔性气体绝缘输电线路的可行性研究
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341911
Takuto Kobayashi, T. Shioiri, S. Matsuoka, A. Kumada, K. Hidaka
In these days, a large number of offshore wind-farms projects are planned. For power delivery from such an offshore wind-farm with large amounts of energy, a gas-insulated transmission line (GIL) is expected to offer a solution owing to its low capacitance. In this paper, a test model of 22 kV-class flexible GIL (FGIL) system is designed, which has the same or more flexibility as a cable system has. In this article, we propose a FGIL utilizing atmospheric pressure CF3 I gas, which is one of SF6 alternatives, as insulating medium. Its feasibility is evaluated from the viewpoint of withstand voltage.
如今,大量的海上风电场项目正在规划中。对于这样一个拥有大量能源的海上风电场的电力输送,由于其低电容,气体绝缘输电线路(GIL)有望提供一种解决方案。本文设计了一种具有与电缆系统相同或更高柔性的22kv级柔性GIL (FGIL)系统的试验模型。在本文中,我们提出了一种利用常压cf3i气体(SF6的替代品之一)作为绝缘介质的FGIL。从耐压角度对其可行性进行了评价。
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引用次数: 0
Effect of liquid condition on moisture saturation coefficients in synthetic and natural esters 液体条件对合成酯和天然酯中水分饱和系数的影响
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341877
P. Livesey, A. Gyore, James Reid
The liquid specific moisture saturation coefficients A and B are required for accurate use of thin film capacitance moisture sensors. These have been previously produced and evaluated for new liquids including synthetic and natural esters. In-use synthetic and natural esters have not yet been evaluated. This paper aims to demonstrate the difference in results of aged esters compared to new, as well as demonstrating the effect on results which can be caused by using improper methods in these liquids. The results highlight the importance of using liquids with high enough initial moisture content and also demonstrate that the moisture saturation curve is mostly unchanged by changing the temperatures used in calculation. The results also show that ageing the synthetic ester in different ways did not significantly affect the moisture saturation curve, however ageing the natural ester open to air led to an increase in measured saturation limit at all temperatures when it was heavily oxidised. It is hypothesised that this is due to the presence of oxidation products other than acid in the natural ester.
液体比湿饱和系数A和B是精确使用薄膜电容式水分传感器所必需的。这些之前已经生产并评估了新的液体,包括合成和天然酯。目前尚未对使用中的合成酯和天然酯进行评价。本文旨在证明老化酯与新酯在结果上的差异,以及证明在这些液体中使用不当方法可能对结果造成的影响。结果表明,使用足够高的初始含水率的液体的重要性,也表明,在改变计算中使用的温度时,水分饱和度曲线基本不变。结果还表明,不同老化方式对合成酯的水分饱和度曲线没有显著影响,而天然酯在空气中老化导致在所有温度下,当它被严重氧化时,测量的饱和极限都增加。据推测,这是由于天然酯中存在除酸以外的氧化产物。
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引用次数: 0
期刊
2020 IEEE 3rd International Conference on Dielectrics (ICD)
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