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2020 IEEE 3rd International Conference on Dielectrics (ICD)最新文献

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PD-Activity in Generator Stator Bar insulation versus Voltage Frequency and Temperature 发电机定子棒绝缘的pd活性随电压、频率和温度的变化
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341874
T. Aakre, E. Ildstad
Condition assessment of generators is today performed at various voltage frequencies and test temperatures. The main purpose of this paper is to compare measured PD results from sections of generator bars with that of similar tests performed on laboratory made test objects with void enclosures of known geometry. The test objects were subjected to ac voltage in the frequency range from 0.1 to 300 Hz, increasing in steps up to a maximum of 10 kV. The measured values of partial discharge inception voltages (PDIV), apparent charge magnitude and number of PDs were compared to estimated values in the temperature range of 20° to $155^{circ}mathrm{C}$ using an impedance abcmodel, including both conduction and dielectric response. It was found that the capacitive abc-model sufficiently accurately describes the observed PDIV values at temperatures below $100^{circ}mathrm{C}$ and test frequencies below 50 Hz. At temperatures higher temperatures the measured PDIV values were found to decrease with increasing temperature, particularly so at the lowest test frequencies. This is in agreement with the assumption of increased conductivity and higher rate of polarization at increased temperatures. The high number of low magnitude PDs, strongly indicating that several discharges are needed for a complete discharge of a void surface.
发电机的状态评估目前在各种电压频率和测试温度下进行。本文的主要目的是比较发电机棒部分的测量PD结果与在实验室制造的具有已知几何形状的空洞外壳的测试对象上进行的类似测试的结果。测试对象承受0.1至300 Hz频率范围内的交流电压,逐步增加,最高可达10 kV。在20°~ 155^{circ} mathm {C}$的温度范围内,利用阻抗abcmodel(包括传导和介电响应)将局部放电起始电压(PDIV)、视电荷大小和局部放电数的测量值与估计值进行了比较。结果表明,电容式abc模型能够充分准确地描述温度低于$100^{circ} mathm {C}$和测试频率低于50 Hz时观测到的PDIV值。在较高的温度下,PDIV值随着温度的升高而降低,特别是在最低的测试频率下。这与在温度升高时电导率增加和极化率提高的假设是一致的。大量的低量级脉冲放电,强烈表明需要多次放电才能使空洞表面完全放电。
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引用次数: 0
New chemistry for impregnation of HV machines: influence of compatibility between resin and mica tapes 高压浸渍机的新化学:树脂与云母带相容性的影响
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341930
M. Ferraris, T. J. Murray, M. Viola
European regulation changes have pushed electric machine manufacturers to request new materials suitable for impregnation of High Voltage motors and generators that are also compliant with European health restrictions. Until now, the most widely used materials for coils insulation are a blend of epoxy resin and anhydride that impregnates mica tapes, containing an epoxy binder with a Zinc naphthenate catalyst, which has the advantage of stability in storage tanks and good thermal and electrical properties. The development of a new impregnating resin, made with a hybrid epoxy-polyester chemistry, highlighted the need to find a way to improve compatibility with mica tapes. This new resin / tape combination has been visually evaluated, as first step, and then tested on bars, observing how dissipation factor versus voltage change after thermal ageing at high temperatures. Test bars made with new resin/tape combination withstood thermal ageing for a longer time than reference materials, confirming that compatibility between impregnating resin and mica tapes is a crucial factor influencing thermal resistance of a coil main wall insulation system.
欧洲法规的变化促使电机制造商要求使用适用于高压电机和发电机浸渍的新材料,这些材料也符合欧洲卫生限制。到目前为止,最广泛用于线圈绝缘的材料是环氧树脂和浸渍云母带的酸酐的混合物,其中含有环氧粘合剂和环烷酸锌催化剂,其优点是在储罐中稳定,并且具有良好的热学和电学性能。一种新型浸渍树脂的开发,由环氧-聚酯混合化学制成,强调需要找到一种方法来改善与云母带的兼容性。作为第一步,我们对这种新型树脂/胶带组合进行了视觉评估,然后在棒上进行了测试,观察高温热老化后耗散系数与电压的变化情况。用新型树脂/胶带组合制成的测试棒比参考材料耐热老化时间更长,证实了浸渍树脂与云母胶带的相容性是影响线圈主壁保温系统热阻的关键因素。
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引用次数: 1
Ageing Behaviours of Superhydrophobic and Icephobic Coatings on Overhead Line Systems 架空线路系统超疏水和疏冰涂层的老化行为
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341809
Chengxing Lian, Xu Zhang, C. Emersic, I. Cotton
The accretion of ice and pollution can lead to serious damage and failure of overhead line systems during icing events. CIGRE TB361 has detailed a family of advanced coatings which claim to be superhydrophobic or ice repellent and which can be deployed on power system equipment to reduce ice accumulation. This paper examines the performance of a commercial superhydrophobic coating NeverWet on aluminium alloy substrates. This coating achieved an average contact angle of 169.5° and the lowest sliding angle of 1.5°. A series of ageing tests were designed and conducted, including thermal ageing/cycling, corona exposure, ultraviolet exposure, and ambient outdoor exposure. The superhydrophobicity of samples was retained after all ageing tests with the exception of corona exposure.
在结冰事件中,冰的增加和污染会导致架空线路系统的严重损坏和故障。CIGRE TB361详细介绍了一系列先进的涂层,这些涂层声称是超疏水或防冰的,可以部署在电力系统设备上,以减少积冰。本文研究了一种商用超疏水涂层NeverWet在铝合金基板上的性能。该涂层的平均接触角为169.5°,最低滑动角为1.5°。设计并进行了一系列老化测试,包括热老化/循环、日冕暴露、紫外线暴露和室外环境暴露。除日冕暴露外,所有老化试验均保留样品的超疏水性。
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引用次数: 2
Research Progress on Modification of Epoxy Resin Materials for High-Voltage Electrical Equipment 高压电器用环氧树脂材料改性研究进展
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341831
Y. Wang, Ang Li, J. Li, W. Zhang, Q. Du, M. M. Zhang, Z. H. Wang, H. C. Liang, B. Du
With the increase of transmission voltage and capacity, epoxy resin for high-voltage electrical equipment was facing great challenges, and the modification of resin materials has become an important topic in current research. This paper summarized the modification methods of epoxy resin for high-voltage electrical apparatus in recent years and introduced the progress of epoxy resin in toughening modification, high heat resistance, high thermal conductivity, and electrical property regulation, and respectively discussed the modification methods of epoxy resin. The modification methods of epoxy resin were studied, which provide a certain reference for developing the epoxy resin with excellent performance.
随着输电电压和输电容量的增加,用于高压电气设备的环氧树脂面临着巨大的挑战,树脂材料的改性已成为当前研究的重要课题。综述了近年来高压电器用环氧树脂的改性方法,介绍了环氧树脂在增韧改性、高耐热性、高导热性和电性能调节方面的进展,并分别对环氧树脂的改性方法进行了讨论。研究了环氧树脂的改性方法,为开发性能优良的环氧树脂提供了一定的参考。
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引用次数: 1
Epoxy composite with hBN fillers compatible with industrial application in electrical equipment 环氧复合材料与hBN填料兼容的工业应用在电气设备
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341949
S. Haller, Damien Bachellerie, S. Pruvost, Loriane Desmars, S. Iglesias, J. Galy, G. Robert, Christian Lao, A. Girodet, M. Henriksen
Hexagonal Boron Nitride (hBN) has been used as secondary filler in an epoxy formulation in gas insulated substation (GIS) demonstrating higher electrical performance under HVAC stress, while being compatible with industrial process and constraints. A synergetic effect between hBN and alumina has been observed regarding thermal and electrical properties. A 500% increase in the thermal conductivity could be achieved with a limited impact on viscosity increase. Breakdown strength has been measured in flat sheets in oil and with embedded electrodes under divergent field simulating a defect. The breakdown strengths resulting from these different experimental setups show an interesting barrier effect from hBN even at low ratio in the formulation. Both results can be correlated with increased lifetime under thermoelectrical stress.
六方氮化硼(hBN)已被用作气体绝缘变电站(GIS)环氧树脂配方的二次填料,在暖通空调应力下具有更高的电气性能,同时与工业过程和约束相兼容。hBN和氧化铝在热学和电学性能方面具有协同效应。在对粘度增加影响有限的情况下,热导率可以增加500%。在模拟缺陷的发散场下,测量了油中的平板和嵌入电极的击穿强度。从这些不同的实验装置得到的击穿强度表明,即使在配方中的低比例下,hBN也有有趣的势垒效应。这两个结果都与热电应力下寿命的增加有关。
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引用次数: 0
Interfacial E-field Regulating Insulator for DC Gas-solid Insulating System 直流气固绝缘系统界面电场调节绝缘子
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341966
Hucheng Liang, B. Du, Jin Li, R. Zhao, Zehua Wang, Miaomiao Zhang, Ang Li, Q. Du
To reduce the electric field (E-field) distortion in a gassolid insulating system, a centrifugation technique is proposed to fabricate the interfacial E-field regulating (IER) insulator. During the curing process of the liquid epoxy/SiC mixture in the mold, a centrifugal force was used to force the SiC particles to the insulator surface, forming a uniform thin surface layer of nonlinear conductivity. After fabrication, electrical evaluations, including numerical simulations and flashover tests, were conducted to verify the E-field regulating effect of the novel insulator. As the thickness of the nonlinear-conductivity layer increases, the maximum E-field in the flashover region of the novel insulator declines and converges to a stable value, but the surface conduction loss continues growing. The flashover voltages of the novel insulator are improved by ~13% and ~21% under positive and negative voltages, respectively. By applying such novel insulators, a higher reliability and compacter structure can be realized for the DC-GIL.
为了减小气固绝缘系统中的电场畸变,提出了用离心分离法制备界面电场调节绝缘子的方法。液态环氧树脂/SiC混合物在模具内固化过程中,利用离心力将SiC颗粒强制到绝缘子表面,形成均匀的非线性导电薄表面层。制作完成后,进行了电学评价,包括数值模拟和闪络试验,以验证新型绝缘子的电场调节效果。随着非线性导电层厚度的增加,新型绝缘子闪络区的最大电场减小并收敛到一个稳定值,但表面导电损耗继续增大。在正电压和负电压下,新型绝缘子的闪络电压分别提高了13%和21%。采用这种新型绝缘子,可以使DC-GIL具有更高的可靠性和更紧凑的结构。
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引用次数: 0
Characterization of Electrical Treeing in XLPE versus Temperature Gradients 交联聚乙烯的电树特性与温度梯度的关系
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341977
Xin Zhao, Siyi Zhang, Cheng-lu Lin, Zhi Yang, Zhonglei Li, T. Han
Cross-linked polyethylene (XLPE) plays a significant role in AC power cables. In the cables, the difference in temperatures of conductor and surrounding environment produces a temperature gradient in XLPE, and the electrical and thermal aging accelerate the degradation. When defects exist in the dielectric, an electrical tree may be initiated. Hence, it is necessary to research the electrical tree in XLPE under the temperature gradient. In this paper, XLPE samples were tested under 50 Hz AC voltage with multiple temperature gradients, and the electrical tree was recorded by a digital microscope. To simulate an electrical stress concentration, a pair of needle-plate electrodes was utilized in this experiment. There are two types of temperature gradients in this experiment, one is to set the needle electrode temperature to 100 °C and increase the ground electrode temperature from 30 to 70 °C, and the other is the opposite. The tree structure, growth process, fractal dimension, accumulated damage and tree length were recorded and analyzed. The experiment results indicate that the temperature gradient affects the growth rate and the structure of trees. When the ground electrode temperature is higher than the needle tip, the tree grows faster. The fractal dimension and the accumulated damage increase as the temperature gradient increases.
交联聚乙烯(XLPE)在交流电源线中起着重要的作用。在电缆中,导体和周围环境的温差使交联聚乙烯产生温度梯度,电老化和热老化加速了交联聚乙烯的老化。当电介质中存在缺陷时,可以启动电气树。因此,有必要对温度梯度下XLPE的电树进行研究。本文对XLPE样品在50 Hz交流电压下进行了多个温度梯度的测试,并通过数码显微镜记录了电树。为了模拟电应力集中,实验中使用了一对针板电极。本实验有两种温度梯度,一种是将针电极温度设置为100℃,将地电极温度从30℃提高到70℃,另一种则相反。对树的结构、生长过程、分形维数、累积损伤和树长进行了记录和分析。实验结果表明,温度梯度会影响树木的生长速度和结构。当地电极温度高于针尖时,树生长得更快。分形维数和累积损伤随温度梯度的增大而增大。
{"title":"Characterization of Electrical Treeing in XLPE versus Temperature Gradients","authors":"Xin Zhao, Siyi Zhang, Cheng-lu Lin, Zhi Yang, Zhonglei Li, T. Han","doi":"10.1109/ICD46958.2020.9341977","DOIUrl":"https://doi.org/10.1109/ICD46958.2020.9341977","url":null,"abstract":"Cross-linked polyethylene (XLPE) plays a significant role in AC power cables. In the cables, the difference in temperatures of conductor and surrounding environment produces a temperature gradient in XLPE, and the electrical and thermal aging accelerate the degradation. When defects exist in the dielectric, an electrical tree may be initiated. Hence, it is necessary to research the electrical tree in XLPE under the temperature gradient. In this paper, XLPE samples were tested under 50 Hz AC voltage with multiple temperature gradients, and the electrical tree was recorded by a digital microscope. To simulate an electrical stress concentration, a pair of needle-plate electrodes was utilized in this experiment. There are two types of temperature gradients in this experiment, one is to set the needle electrode temperature to 100 °C and increase the ground electrode temperature from 30 to 70 °C, and the other is the opposite. The tree structure, growth process, fractal dimension, accumulated damage and tree length were recorded and analyzed. The experiment results indicate that the temperature gradient affects the growth rate and the structure of trees. When the ground electrode temperature is higher than the needle tip, the tree grows faster. The fractal dimension and the accumulated damage increase as the temperature gradient increases.","PeriodicalId":6795,"journal":{"name":"2020 IEEE 3rd International Conference on Dielectrics (ICD)","volume":"23 1","pages":"25-28"},"PeriodicalIF":0.0,"publicationDate":"2020-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78032953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Partial Discharge Erosion of Polypropylene/Elastomer Blends Characterized with Multi-Sensors under AC Voltage 交流电压下多传感器表征聚丙烯/弹性体共混物局部放电侵蚀
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341807
Jinjing Peng, Yu Gao, Jing Li, Xuri Xu, Zheng Song, B. Du
Polypropylene (PP) has been considered as a promising insulation material for power cable in both AC and DC systems because of its excellent insulation performance and recyclability. The exposure to partial discharge gives rise to the deterioration of the material that threatens the safe operation of cable. Therefore, it is of great significance to understand the mechanism of partial discharge of PP and its blends subjected to AC voltage. In this work, PP/elastomer blends with thickness of $150 mu mathrm{m}$ were prepared as samples. A needle-plane electrode system was employed to introduce partial discharge by applying an AC voltage with 5 kVrms for 2 hours. The erosion behavior was characterized through multi-sensors system, including high frequency current transformer (HFCT), optical recorder and gas sensor. To better understand the erosion mechanism, isothermal surface potential decay (ISPD) method was used to analyze trap characteristics. The results showed that the trap center became shallower with the increase of elastomer content for both ethylene-octene copolymer elastomer (EOC) and polypropylene based elastomer (PBE). Compared with pure PP, the addition of elastomer improved the resistance of partial discharge and PP with 20 wt% loading percent of EOC presented better resistance to partial discharge compared with PP with 20 wt% loading percent of PBE.
聚丙烯(PP)由于其优良的绝缘性能和可回收性,被认为是一种很有前途的交、直流电力电缆绝缘材料。暴露在局部放电环境下会导致材料劣化,威胁电缆的安全运行。因此,了解PP及其共混物在交流电压作用下局部放电的机理具有重要意义。本研究制备了厚度为$150 mu mathm {m}$的PP/弹性体共混物作为样品。采用针平面电极系统,施加5 kVrms交流电压2小时,引起局部放电。利用高频电流互感器(HFCT)、光学记录仪和气体传感器等多传感器系统对腐蚀行为进行了表征。为了更好地了解侵蚀机理,采用等温表面电位衰减(ISPD)方法分析了陷阱特征。结果表明,随着弹性体含量的增加,乙烯-辛烯共聚物弹性体(EOC)和聚丙烯基弹性体(PBE)的陷阱中心变浅;与纯PP相比,弹性体的加入提高了PP的局部放电性能,而含20%重量% EOC的PP比含20%重量% PBE的PP具有更好的局部放电性能。
{"title":"Partial Discharge Erosion of Polypropylene/Elastomer Blends Characterized with Multi-Sensors under AC Voltage","authors":"Jinjing Peng, Yu Gao, Jing Li, Xuri Xu, Zheng Song, B. Du","doi":"10.1109/ICD46958.2020.9341807","DOIUrl":"https://doi.org/10.1109/ICD46958.2020.9341807","url":null,"abstract":"Polypropylene (PP) has been considered as a promising insulation material for power cable in both AC and DC systems because of its excellent insulation performance and recyclability. The exposure to partial discharge gives rise to the deterioration of the material that threatens the safe operation of cable. Therefore, it is of great significance to understand the mechanism of partial discharge of PP and its blends subjected to AC voltage. In this work, PP/elastomer blends with thickness of $150 mu mathrm{m}$ were prepared as samples. A needle-plane electrode system was employed to introduce partial discharge by applying an AC voltage with 5 kVrms for 2 hours. The erosion behavior was characterized through multi-sensors system, including high frequency current transformer (HFCT), optical recorder and gas sensor. To better understand the erosion mechanism, isothermal surface potential decay (ISPD) method was used to analyze trap characteristics. The results showed that the trap center became shallower with the increase of elastomer content for both ethylene-octene copolymer elastomer (EOC) and polypropylene based elastomer (PBE). Compared with pure PP, the addition of elastomer improved the resistance of partial discharge and PP with 20 wt% loading percent of EOC presented better resistance to partial discharge compared with PP with 20 wt% loading percent of PBE.","PeriodicalId":6795,"journal":{"name":"2020 IEEE 3rd International Conference on Dielectrics (ICD)","volume":"95 1","pages":"890-893"},"PeriodicalIF":0.0,"publicationDate":"2020-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85723348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Volatile Acid and Polymer Formation in Various Insulation Liquids Upon Accelerated Thermal Ageing 加速热老化过程中各种绝缘液体中挥发性酸和聚合物的形成
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9342021
E. Matić, M. Meissner, S. Schober, M. Mittelbach
Insulation liquids perform a vital role in protecting power equipment, such as transformers, from thermal, electrical and environmental stress. Considering the poor fire-safety properties and low biodegradability of mineral oil as the leading kind of insulation liquid, alternative insulation liquids are of high interest for their implementation in power equipment. In this experiment we aimed to simulate the processes occurring in faulty power equipment by ageing four different kinds of insulation liquids (mineral oil, GTL-insulation liquid, synthetic ester and natural ester) under laboratory conditions. The use of optimized analytical routine methods has allowed us to monitor as well as quantify volatile acid and polymer formations upon ageing of insulation liquids. The ageing process under aerated conditions has led to the formation of formic, acetic and propionic acid, especially in natural ester, alongside notable polymerization effects. All other types of insulation liquids showed significantly lower amounts of volatile acids. Per contra, the experiments conducted under oxygen-free conditions resulted in minimal volatile acid and polymer build-ups in all four insulation liquids.
绝缘液体在保护电力设备(如变压器)免受热、电和环境应力的影响方面起着至关重要的作用。矿物油作为主要的绝缘液,由于其防火性能差、生物降解性低等特点,替代绝缘液在电力设备中的应用备受关注。在本实验中,我们旨在通过在实验室条件下老化四种不同的绝缘液(矿物油、gtl绝缘液、合成酯和天然酯)来模拟故障电力设备发生的过程。使用优化的分析常规方法使我们能够监测和量化绝缘液体老化时挥发性酸和聚合物的形成。在曝气条件下的老化过程导致甲酸、乙酸和丙酸的形成,特别是在天然酯中,伴随着显著的聚合效应。所有其他类型的绝缘液体的挥发性酸含量明显较低。相反,在无氧条件下进行的实验导致所有四种绝缘液体中挥发性酸和聚合物的累积最小。
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引用次数: 1
Effect of sPP Content on Dielectric Relaxation and Trap Level Characteristics of PP blend insulation sPP含量对PP共混绝缘介电弛豫和陷阱能级特性的影响
Pub Date : 2020-07-05 DOI: 10.1109/ICD46958.2020.9341925
M. Fan, Zhonglei Li, B. Du, S. Zhou
Polypropylene (PP) is regarded as a recyclable alternative to XLPE for cable insulation on account of its higher heat resistance and higher electrical resistivity. The dielectric relaxation and trap level characteristics of isotactic PP (iPP), syndiotactic PP (sPP) as well as atactic PP (aPP) blends are investigated. The associations between polymer polarization response and traps level characteristics of PP blends are discussed. Frequency-domain dielectric spectroscopy (FDS) methods are used to analyze the polarization response of five PP blends at 50, 70 and 90 0C. Isothermal surface potential decay (ISPD) tests are performed to acquire the traps level distribution and the influences of traps level characteristics on the dielectric response are discussed. The polymer polarization behaviours a and $delta$ of five samples is closely related to segmental movements and carriers hopping behaviours, separately. The intensity of a relaxation strength ($Deltavarepsilon_{a}$) declines with the increase of sPP content, because the related coefficient (g) between PP molecular chains is reduced. The calculated energy $E_{tau}$ for $delta$ process is in proportion to the shallow traps level, because the shallow traps with a higher level increase the potential barriers of carriers hopping behaviors. The increase in temperature causes the dipole to undergo intense Brownian motion in the electric field, resulting in a decrease in $Deltavarepsilon_{a}$ with increasing temperature. The thermal motion of the charge increases the mobility of carriers in the PP and causes $Deltavarepsilon_{delta}$ to increasewith increasingtemperature.
聚丙烯(PP)由于其更高的耐热性和更高的电阻率,被认为是一种可回收的替代交联聚乙烯(XLPE)用于电缆绝缘的材料。研究了等规PP (iPP)、共规PP (sPP)和无规PP (aPP)共混物的介电弛豫和阱能级特性。讨论了聚丙烯共混物的极化响应与陷阱能级特性之间的关系。采用频域介电光谱(FDS)方法分析了5种PP共混物在50、70和90℃时的极化响应。通过等温表面电位衰减(ISPD)测试获得了阱能级分布,并讨论了阱能级特性对介质响应的影响。五种样品的聚合物极化行为a和$delta$分别与节段运动和载流子跳跃行为密切相关。随着sPP含量的增加,弛豫强度($Deltavarepsilon_{a}$)的强度减小,这是由于PP分子链之间的相关系数(g)减小所致。计算出$delta$过程的能量$E_{tau}$与浅阱能级成正比,因为高能级的浅阱增加了载流子跳跃行为的势垒。温度的升高使偶极子在电场中发生强烈的布朗运动,导致$Deltavarepsilon_{a}$随温度的升高而减小。电荷的热运动增加了PP中载流子的迁移率,并导致$Deltavarepsilon_{delta}$随温度升高而增加。
{"title":"Effect of sPP Content on Dielectric Relaxation and Trap Level Characteristics of PP blend insulation","authors":"M. Fan, Zhonglei Li, B. Du, S. Zhou","doi":"10.1109/ICD46958.2020.9341925","DOIUrl":"https://doi.org/10.1109/ICD46958.2020.9341925","url":null,"abstract":"Polypropylene (PP) is regarded as a recyclable alternative to XLPE for cable insulation on account of its higher heat resistance and higher electrical resistivity. The dielectric relaxation and trap level characteristics of isotactic PP (iPP), syndiotactic PP (sPP) as well as atactic PP (aPP) blends are investigated. The associations between polymer polarization response and traps level characteristics of PP blends are discussed. Frequency-domain dielectric spectroscopy (FDS) methods are used to analyze the polarization response of five PP blends at 50, 70 and 90 0C. Isothermal surface potential decay (ISPD) tests are performed to acquire the traps level distribution and the influences of traps level characteristics on the dielectric response are discussed. The polymer polarization behaviours a and $delta$ of five samples is closely related to segmental movements and carriers hopping behaviours, separately. The intensity of a relaxation strength ($Deltavarepsilon_{a}$) declines with the increase of sPP content, because the related coefficient (g) between PP molecular chains is reduced. The calculated energy $E_{tau}$ for $delta$ process is in proportion to the shallow traps level, because the shallow traps with a higher level increase the potential barriers of carriers hopping behaviors. The increase in temperature causes the dipole to undergo intense Brownian motion in the electric field, resulting in a decrease in $Deltavarepsilon_{a}$ with increasing temperature. The thermal motion of the charge increases the mobility of carriers in the PP and causes $Deltavarepsilon_{delta}$ to increasewith increasingtemperature.","PeriodicalId":6795,"journal":{"name":"2020 IEEE 3rd International Conference on Dielectrics (ICD)","volume":"43 1","pages":"431-434"},"PeriodicalIF":0.0,"publicationDate":"2020-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86911218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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2020 IEEE 3rd International Conference on Dielectrics (ICD)
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