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Quantitative study on isotope effect of rubidium clusters 铷团簇同位素效应的定量研究
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230778
Di Shu-Hong, Zhang Yang, Yang Hui-Jing, Cui Nai-Zhong, Li Yan-Kun, Liu Hui-Yuan, Li Ling-Li, Shi Feng-Liang, Jia Yu-Xuan
Because of the difficulty in measuring the cluster isotope displacement and identifying its causes, the resonance dissociation spectra, the moment shift and Zeeman energy shift of isotope cluster 87,85Rbn(n=1,2, 3,..., 13) are obtained by the combination of optical magnetic resonance and thermal dissociation techniques in this study. The quantitative calculation is carried out based on the conceptual model of the giant atom, and the results are in strict agreement with the measured results, which shows that rubidium clusters can be analyzed as giant-like atoms. Furthermore, 5s electron shell level structure of the rubidium cluster 87,85Rbn(n=1,2, 3,..., 92) is calculated using Zeeman level interval model. It is found that the main order and step distance of the 5s electron shell structure are similar to those of 3s single electron shell structure of sodium cluster in spherical symmetric. It is confirmed that the structure of the 5s electron shell of the rubidium cluster is determined by the largest energy gap of total Zeeman levels and the characteristic peaks of odd and even alternating and anomalous magnetic moments of special numbers such as n=2 are caused by the intrinsic properties of electrons and molecular structures. It is also found that 87Rbn and 85Rbn level shell structure is strictly consistent with the ratio of 3/2 magnitude relationship, and there are abnormal differences in spectral center frequency and broadening, which may be directly related to the 85,87Rb nuclide on the closed surface of the core-shell.
由于团簇同位素位移的测量和原因难以确定,同位素团簇87,85rbn (n= 1,2,3,…)的共振解离谱、矩移和塞曼能量移, 13)是本研究结合光磁共振和热解离技术得到的。根据巨原子概念模型进行了定量计算,结果与实测结果吻合较好,表明铷团簇可以作为类巨原子来分析。此外,铷原子团簇87,85rbn (n= 1,2,3,…)的5s电子壳层结构, 92),采用Zeeman水平区间模型计算。发现在球对称情况下,钠团簇的5s电子壳层结构的主序和阶距与3s单电子壳层结构相似。证实了铷原子团簇的5s电子壳层结构是由总塞曼能级的最大能隙决定的,而n=2等特殊数的奇偶交变磁矩和异常磁矩的特征峰是由电子和分子结构的固有性质引起的。还发现87Rbn和85Rbn能级壳层结构严格符合3/2量级的比值关系,且谱中心频率和展宽存在异常差异,这可能与核壳层封闭表面上的85、87Rb核素有直接关系。
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引用次数: 0
Measurement and Analysis of Debye Relaxation dynamics of n-propanol, n-butanol and n-octanol 正丙醇、正丁醇和正辛醇的德拜弛豫动力学测量与分析
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20221856
Wang Li-na, Zhao Xing-Yu, Shang Jie-Ying, Zhou Heng-Wei
Monohydroxy alcohol has a Debye relaxation process that other liquids usually do not have, and with the development of research, some new phenomena and new problems related to the process have been gradually discovered, deepening the understanding of material structure and dynamics. In order to further investigate the dynamics of Debye relaxation processes and the influence of molecular constitutions on them, the Debye processes of three primary alcohols without branched chains or side groups are studied by dielectric spectroscopy method, and some important information of the processes are revealed. A number of dynamic parameters of Debye relaxation in n-propanol, n-butanol and n-octanol almost all increase linearly with the rising number of carbon atoms in the molecules, which include the characteristic temperature, the reciprocal of Vogel-Fulcher-Tammann (VFT) temperature and the strength parameter of Debye processes as well as the activation energy and the logarithm of the intrinsic vibration frequency of relaxation units under high temperature limit. However, the values of VFT temperatures change little and have consistency, illustrating that the relaxation units of Debye processes in these three monohydroxy alcohols should be the same and further verifying the view that the Debye relaxation originates from the hydroxyl groups in hydrogen bonded molecular chains. Comparing Boiling temperatures and melting temperatures of those samples with the evolution of the above activation energy, it is shown that there is a positive correlation between the interaction among hydrogen bonds and the whole one among molecules. In addition, combined the information of the strength parameter with relevant theories, a possible perspective is gained for further investigation of liquid fragility. The comparison of those three samples with ethanol displays that the degree of separation of Debye relaxation and α relaxation is influenced by the molecular chain length, which could provide a breakthrough point to explore Debye relaxation. These results in this paper will promote further understanding and research of Debye relaxation in monohydroxy alcohols, and also provide experimental information for relevant theories.
单羟基醇具有其他液体通常不具备的德拜弛豫过程,随着研究的深入,与该过程相关的一些新现象和新问题逐渐被发现,加深了对物质结构和动力学的认识。为了进一步研究德拜弛豫过程的动力学及分子结构对德拜弛豫过程的影响,采用介电光谱方法研究了无支链和侧基的三种伯醇的德拜弛豫过程,揭示了德拜弛豫过程的一些重要信息。正丙醇、正丁醇和正辛醇中的许多Debye弛豫动力学参数几乎都随着分子中碳原子数的增加而线性增加,包括特征温度、VFT温度倒数、Debye过程强度参数以及高温极限下弛豫单元固有振动频率的活化能和对数。而VFT温度变化不大且具有一致性,说明这三种单羟基醇的德拜弛豫单元应该是相同的,进一步验证了德拜弛豫来源于氢键分子链中羟基的观点。将这些样品的沸点温度和熔点温度与上述活化能的演化进行比较,表明氢键之间的相互作用与分子间的整体相互作用呈正相关。此外,将强度参数信息与相关理论相结合,为进一步研究液体脆性提供了可能的视角。将这三种样品与乙醇进行比较,发现Debye弛豫与α弛豫的分离程度受分子链长度的影响,为进一步探索Debye弛豫提供了突破口。这些结果将促进对单羟基醇德拜弛豫的进一步认识和研究,并为相关理论提供实验资料。
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引用次数: 0
A Novel TMOSFET Ternary Inverter Based on Hybrid Conduction Mechanism 一种基于混合导通机制的新型TMOSFET三元逆变器
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230819
Ma Xin, Lu Bin, Dong Linpeng, MiaoYuanhao
With the continuous development of CMOS technology, the feature size of MOSFETs is continuously shrunk, the short channel effects become more and more serious, which makes the static power consumption increase and now the static power consumption becomes the main source of the power consumption of the integrated circuits. At present, the performance of CMOS binary logic processors is nearly reaching the bottleneck; therefore the study of ternary logic becomes a research hotspot to promote the development of high performance and low power integrated circuits. Compared with binary logic, ternary logic possesses stronger data expression ability, which can not only improve the data density, but also reduce the circuit power consumption and the system complexity. However, using binary devices to build ternary logic circuits requires a large number of components, and even requires the passive components, which cannot exploit the advantages of ternary logic. The other method of implementing ternary logic is through the utilization of innovative two-dimensional materials. This method requires a small number of components and obviates the need for passive components, but it faces the problem that the fabrication process is not mature and can’t be mass-produced. To solve these issues, this paper combines the tunneling and the drift diffusion mechanism, proposed tunneling metal-oxide-semiconductor field-effect transistor (TMOSFET) which three-state characteristics make it highly suitable for ternary logic design. Compared with other ternary logic schemes, the ternary inverter based on TMOSFET has the same circuit structure with binary inverter, which can simplify the circuit design. In this paper, the operational mechanism of this ternary inverter is studied, and the condition of three-state output of inverter is analyzed. It is found that when the operating voltage VDD and the device turning voltage Vturn satisfy VDD/Vturn≈1.4, the input voltage ranges of the three output states are equivalent. In addition, the impact of TMOSFET transfer characteristic on this ternary inverter is also analyzed. This has certain reference significance for the future design and research of ternary logic circuits.
随着CMOS技术的不断发展,mosfet的特征尺寸不断缩小,短通道效应越来越严重,使得静态功耗增加,现在静态功耗已成为集成电路功耗的主要来源。目前,CMOS二进制逻辑处理器的性能已接近瓶颈;因此,三元逻辑的研究成为推动高性能、低功耗集成电路发展的研究热点。与二进制逻辑相比,三元逻辑具有更强的数据表达能力,不仅可以提高数据密度,还可以降低电路功耗和系统复杂性。然而,利用二进制器件构建三元逻辑电路需要大量元件,甚至需要无源元件,无法发挥三元逻辑的优势。实现三元逻辑的另一种方法是利用创新的二维材料。该方法所需元件数量少,避免了对无源元件的需求,但面临着制造工艺不成熟,无法批量生产的问题。为了解决这些问题,本文结合隧道效应和漂移扩散机制,提出了隧道金属氧化物半导体场效应晶体管(TMOSFET),其三态特性使其非常适合三元逻辑设计。与其他三元逻辑方案相比,基于TMOSFET的三元逆变器具有与二元逆变器相同的电路结构,可以简化电路设计。本文研究了该三元逆变器的工作机理,分析了逆变器的三态输出条件。研究发现,当工作电压VDD和器件转动电压Vturn满足VDD/Vturn≈1.4时,三种输出状态的输入电压范围相等。此外,还分析了TMOSFET转移特性对该三元逆变器的影响。这对今后三元逻辑电路的设计和研究具有一定的参考意义。
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引用次数: 0
Improved parameter optimization method for measurement device independent protocol 改进的测量设备独立协议参数优化方法
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230179
Zhou Jiang-Ping, Zhou Yuan-Yuan, Zhou Xue-Jun
The optimal selection of parameters in practical quantum key distribution can greatly improve the key generation rate and maximum transmission distance of the system. Due to the high cost of global search algorithm, local search algorithm is widely used. However, there are two vulnerabilities in local search algorithm, one is that the solution obtained is not always the global optimal solution, the other is that the effectiveness of the algorithm is greatly dependent on the choice of initial value. It is different from the previous article that this paper uses the Monte Carlo method to prove whether the key generation rate function is convex, and also simulates and analyzes the projection of key generation rate function on each dimension of the parameter. In order to eliminate the effect of the initial value, this paper proposes the particle swarm local search optimization algorithm which is combining particle swarm optimization algorithm and local search algorithm. The first step is using the particle swarm optimization to find a valid parameter which leads to nonzero key generation rate, the second step is using the parameter as the initial value of local search algorithm to derive the global optimal solution. Then, the two algorithms are simulated and compared. The results show that the key generation rate function is non-convex because it does not satisfy the definition of a convex function, however, since the key generation rate function has only one non-zero stagnation point, the LSA algorithm can still obtain the global optimal solution with a proper initial value, when the transmission distance is relatively long, the local search algorithm is invalid because it is difficult to obtain an effective initial value by random value method. Particle swarm optimization algorithm can overcome this shortcoming and improve the maximum transmission distance of the system at the cost of slightly increasing the complexity of the algorithm.
在实际的量子密钥分配中,参数的优化选择可以大大提高密钥的生成速率和系统的最大传输距离。由于全局搜索算法的成本较高,局部搜索算法被广泛使用。然而,局部搜索算法存在两个漏洞,一是得到的解并不总是全局最优解,二是算法的有效性很大程度上依赖于初始值的选择。与前一篇文章不同的是,本文采用蒙特卡罗方法来证明密钥生成率函数是否为凸,并模拟分析了密钥生成率函数在参数各维上的投影。为了消除初始值的影响,本文提出了将粒子群优化算法与局部搜索算法相结合的粒子群局部搜索优化算法。第一步是利用粒子群算法寻找一个有效的参数,使密钥生成率达到非零,第二步是利用该参数作为局部搜索算法的初始值,推导出全局最优解。然后,对两种算法进行了仿真和比较。结果表明,由于密钥生成速率函数不满足凸函数的定义,因此它是非凸的,但由于密钥生成速率函数只有一个非零的驻点,因此LSA算法仍然可以获得具有适当初始值的全局最优解,当传输距离较长时,局部搜索算法由于难以通过随机值方法获得有效的初始值而无效。粒子群优化算法可以克服这一缺点,以略微增加算法复杂度为代价提高系统的最大传输距离。
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引用次数: 0
The Study of Photon Acceleration Driven by the Near-forward Scattering in the Intense Laser Under-dense Plasma Interaction 强激光低密度等离子体相互作用中近前向散射驱动光子加速的研究
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20222014
Yue Dong-Ning, Dong Quan-Li, Chen Min, Zhao Yao, Geng Pan-Fei, Yuan Xiao-hui, Sheng Zheng-Ming, Zhang Jie
The mechanism of photon acceleration driven by the near-forward scattering (NFS) in intense laser under-dense plasma interaction has been studied by particle-in-cell (PIC) simulation. This mechanism utilizes tunneling ionization effect to stimulate electron plasma waves when the intense laser pulse propagates in under-dense plasmas. The electron plasma density is inhomogeneous both in longitudinal and transverse direction. In longitudinal direction, a steep ionized electron density front is generated by incident laser ionizing the helium gas. Around the ionization front, the incident laser interacts with electron plasma waves and generates the first kind of NFS waves. The frequency of NFS waves increases compared to the laser frequency. This is the first characteristic peak in the frequency spectrum. In transverse direction, the electron plasma waves have different phase velocities which makes the incident laser pulse undergoes NFS process and upshifts its frequency. This is the second characteristic peak in the frequency spectrum. Due to that the electron density inhomogeneity is much larger than the electron density perturbation of electron plasma wave, the scattering model and dispersion relationships, which are based on perturbation theory like the stimulated Raman scattering, are no longer applicable in this case. Our further study shows that the incident laser, electron density plasma waves and NFS waves still satisfy the energy conservation and momentum conservation which leads to the three-waves matching conditions of NFS process for inhomogeneous electron density. This can explain the appearance of two characteristic peaks in the frequency spectrum and their growth in the wave-vector space. This study has significant reference for the spectrum evolution when the intense laser pulse propagates in under-dense plasmas.
采用粒子池(PIC)模拟研究了强激光低密度等离子体相互作用中近前向散射(NFS)驱动光子加速的机理。该机制利用隧道电离效应刺激强激光脉冲在低密度等离子体中传播时产生的电子等离子体波。电子等离子体密度在纵向和横向上都是不均匀的。在纵向上,入射激光电离氦气产生一个陡峭的电离电子密度锋。在电离锋附近,入射激光与电子等离子体波相互作用,产生第一类NFS波。NFS波的频率相对于激光频率增大。这是频谱中的第一个特征峰。在横向上,电子等离子体波具有不同的相速度,使入射激光脉冲发生NFS过程,使其频率上升。这是频谱中的第二个特征峰。由于电子密度的不均匀性远大于电子等离子体波的电子密度摄动,基于受激拉曼散射等摄动理论的散射模型和色散关系在这种情况下不再适用。进一步的研究表明,入射激光、电子密度等离子体波和NFS波仍然满足能量守恒和动量守恒,这导致了非均匀电子密度的NFS过程的三波匹配条件。这可以解释频谱中两个特征峰的出现及其在波矢量空间中的增长。该研究对强激光脉冲在低密度等离子体中传播时的光谱演化具有重要的参考意义。
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引用次数: 0
High-efficient particle-in-cell/Monte Carlo collision model for complex solution domain and the simulation of anode layer ion source 复杂解域的高效细胞内粒子/蒙特卡罗碰撞模型及阳极层离子源模拟
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20222394
Cui Sui-Han, Zuo Wei, Huang Jian, Li Xi-Teng, Chen Qiu-Hao, Guo Yu-Xiang, Yang Chao, Wu Zhong-Can, Ma Zheng-Yong, Ricky K Y Fu, Tian Xiu-Bo, Paul K. Chu, Wu Zhong-Zhen
Plasma simulation is important to study the plasma discharge systematically, especially for the anode layer ion source which has the complex geometrical characteristics of the discharge structures. However, owing to the complex solution domain formed by the geometric profile of the anode and cathode, the traditional simulation models show extremely small computational efficiency and poor convergence. This paper presents a separated simulation for the ion source structure and the plasma discharge, respectively, where the cathode geometric parameters (including the size, the shape and the relative position of the inner and outer cathodes) are simplified to two magnetic mirror parameters (the magnetic mirror ratio Rm and the magnetic induction intensity at the center of the magnetic mirror B 0) firstly and a high-efficient particle-in-cell/Monte Carlo collision (PIC/MCC) model is established to improve the computational efficiency and stability of the plasma simulation later. As a result, the convergence time of the plasma simulation is shortened significantly from 1 μs to 0.45 μs, and by which the influences of the geometrical characteristics of the discharge structure on the plasma properties are systematically studied. The simulation results reveal that magnetic mirror with Rm=2.50 and B 0=36 mT can constraint the plasma at the centre zone between the inner and outer cathode. When the discharge center of the plasma is consistent with the magnetic mirror center, the anode layer ion source presents both high density output of ion beam current and significantly reduced cathode etching, suggesting the best balance obtained between the output and cathode etching.
等离子体模拟对于系统地研究等离子体放电具有重要意义,特别是对于放电结构几何特征复杂的阳极层离子源。然而,由于阳极和阴极几何轮廓形成复杂的解域,传统的仿真模型计算效率极低,收敛性差。本文分别对离子源结构和等离子体放电进行了分离模拟,其中阴极几何参数(包括尺寸、首先将内外阴极的形状和相对位置简化为两个磁镜参数(磁镜比Rm和磁镜中心磁感应强度b0),并建立了高效的粒子池/蒙特卡罗碰撞(PIC/MCC)模型,提高了等离子体模拟的计算效率和稳定性。结果表明,等离子体模拟的收敛时间由原来的1 μs大幅缩短至0.45 μs,并系统地研究了放电结构几何特性对等离子体特性的影响。仿真结果表明,Rm=2.50、b0 =36 mT的磁反射镜可以将等离子体约束在内外阴极之间的中心区域。当等离子体放电中心与磁镜中心一致时,阳极层离子源既能高密度输出离子束电流,又能显著减少阴极蚀刻,表明输出和阴极蚀刻达到了最佳平衡。
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引用次数: 0
Electron-spin polarization effect in Rashba spin-orbit coupling modulated single-layered semiconductor nanostructure Rashba自旋轨道耦合调制单层半导体纳米结构中的电子自旋极化效应
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20221381
He Ya-Ping, Chen Ming-Xia, Pan Jie-Feng, Li Dong, Lin Gang-Jun, Huang Xin-Hong
Nanothick semiconductors can grow orderly along a desired direction with the help of modern materials growth technology such as molecular beam epitaxy, which allows researchers to fabricate the so-called layered semiconductor nanostructure (LSN) in experiments. Due to the broken structure inversion symmetry by the layered form in the LSN, the electron spins interact tightly with its momentums, in literatures referred to as the spin-orbit coupling (SOC) effect, which can be modulated well by the interfacial confining electric field or the stain engineering. These significant SOC effects can effectively eliminate the spin degeneracy of the electrons in semiconductor materials, induce the spin splitting phenomenon at the zero magnetic field and generate the electron-spin polarization in the semiconductors. In recent years, the spin-polarized transport for electrons in the LSN has attracted a lot of research interests, thanks to itself scientific importance and potential applications as spin polarized sources in the research field of semiconductor spintronics. Adopting the theoretical analysis combined with the numerical calculation, we investigate the spin-polarized transport induced by the Rashba-type SOC effect for electrons in a single-layered semiconductor nanostructure (SLSN)-InSb. The research objective is to explore the new way for generating and manipulating spin current in semiconductor materials without any magnetic field, and focus on developing new electron-spin filter for semiconductor spintronics device applications. The improved transfer matrix method (ITMM) is exploited to exactly solve Schrödinger equation for an electron in the SLSN-InSb device, which allows us to calculate the spin-dependent transmission coefficient and the spin polarization ratio. Due to a strong Rashba-type SOC, a considerable electron-spin polarization effect appears in the SLSN-InSb device. Because of the effective potential experienced by the electrons in the SLSN-InSb device, the spin polarization ratio is associated with the electron energy and the in-plane wave vector. In particular, the spin polarization ratio can be manipulated effectively by an externally-applied electric field or the semiconductor-layer thickness, owing to the dependence of the effective potential felt by the electrons in the SLSN-InSb device on the electric field or the layer thickness. Therefore, such a SLSN-InSb device can serve as a controllable electron-spin filter as a manipulable spin-polarized source for the research area of semiconductor spintronics.
在分子束外延等现代材料生长技术的帮助下,纳米厚半导体可以沿着期望的方向有序生长,这使得研究人员可以在实验中制造出所谓的分层半导体纳米结构(LSN)。由于层状结构破坏了LSN的结构反演对称性,电子自旋与动量紧密相互作用,在文献中称为自旋-轨道耦合(SOC)效应,这种效应可以通过界面约束电场或染色工程进行调制。这些显著的SOC效应可以有效消除半导体材料中电子的自旋简并,在零磁场下诱导自旋分裂现象,在半导体中产生电子-自旋极化。近年来,LSN中电子的自旋极化输运由于其科学重要性和作为自旋极化源在半导体自旋电子学研究领域的潜在应用,引起了人们的广泛关注。采用理论分析与数值计算相结合的方法,研究了单层半导体纳米结构(SLSN)-InSb中rashba型SOC效应对电子的自旋极化输运。研究目标是探索在半导体材料中无磁场产生和控制自旋电流的新方法,并重点开发用于半导体自旋电子器件的新型电子自旋滤波器。利用改进的传递矩阵法(ITMM)精确求解了SLSN-InSb器件中电子的Schrödinger方程,从而计算出自旋相关透射系数和自旋极化比。由于具有较强的rashba型SOC, SLSN-InSb器件中出现了相当大的电子自旋极化效应。由于SLSN-InSb器件中电子所经历的有效电位,自旋极化比与电子能量和面内波矢量有关。特别是,由于SLSN-InSb器件中电子感受到的有效电位依赖于电场或半导体层厚度,因此可以通过外加电场或半导体层厚度有效地控制自旋极化比。因此,这种SLSN-InSb器件可以作为半导体自旋电子学研究领域的可控电子自旋滤波器和可操纵自旋极化源。
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引用次数: 1
Various current-dependent intersystem crossing and reverse intersystem crossing processes induced by different charge balances in exciplex-based OLEDs 不同电荷平衡诱导的不同电流依赖系统间交叉和反向系统间交叉过程
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230765
Zhao Xi, Chen Jing, Peng Teng, Liu Jun-Hong, Wang bo, Chen Xiao-Li, Xiong Zu-Hong
Intersystem crossing (ISC) and reverse ISC (RISC) between singlet and triplet polaron-pair and exciplex states are important spin-mixing processes in exciplex-based organic light-emitting diodes (EB-OLEDs). These two processes usually show normal current dependencies which weaken with increasing the bias-current. This is because the increase in the bias-current is realized by improving the device bias-voltage. When the bias-voltage rises, the electric field within the device enhances, which facilitates the electric-field-induced dissociation of polaron-pair and exciplex states and then reduces their lifetime. That is, less polaron-pair and exciplex states participate in the ISC and RISC processes leading to the reduction of these two processes. Here, magneto-electroluminescence (MEL) is used as a fingerprint probing tool to observe various current-dependent ISC and RISC processes in EB-OLEDs with different charge balances via modifying the device hole-injection layer. Interestingly, current-dependent MEL traces of the unbalanced device display a conversion from normal ISC (1-25 mA) to abnormal ISC (25-200 mA) processes, whereas those of the balanced device show conversions from normal ISC (1-5 mA) to abnormal RISC (10-50 mA) and then to normal RISC (50-150 mA) and finally to abnormal ISC (200-300 mA) processes. By fitting and decomposing the current-dependent MEL traces of the unbalanced and balanced devices, we find that the ISC and RISC processes in these two devices first enhance but then weaken as the bias-current increases. These non-monotonic current-dependent ISC and RISC processes are attributed to the competition between the increased number and the reduced lifetime of polaron-pair and exciplex states during improving the bias-current. Furthermore, the RISC process in the balanced device is stronger than that in the unbalanced device. This is because the balanced carrier injection can facilitate the formation of triplet exciplex states and weaken the triplet-charge annihilation (TQA) process between triplet exciplex states and excessive charge carriers, which leads to the increased number of triplet exciplex states. That is, more triplet exciplex states can convert into singlet exciplex states through the RISC process, causing a higher external quantum efficiency of the balanced device than that of the unbalanced device. Obviously, this work not only deepens the understandings of current-dependent ISC and RISC processes in EB-OLEDs, but also provides insights of device physics for designing and fabricating high-efficiency EB-OLEDs.
单线态和三重态极化子对与激复态之间的系统间交叉(ISC)和反向激复态交叉(RISC)是激复态有机发光二极管(ib - oled)中重要的自旋混合过程。这两个过程通常表现出正常的电流依赖性,随着偏置电流的增加而减弱。这是因为偏置电流的增加是通过提高器件偏置电压来实现的。当偏置电压升高时,器件内电场增强,促进了极化子对和激复态的电场诱导解离,从而缩短了它们的寿命。也就是说,参与ISC和RISC过程的极化子对和外络合物态减少,导致这两个过程的减少。本文利用磁电致发光(MEL)作为指纹探测工具,通过修改器件的空穴注入层,观察了具有不同电荷平衡的eb - oled中各种电流依赖的ISC和RISC过程。有趣的是,不平衡器件的电流依赖MEL迹线显示从正常ISC (1-25 mA)到异常ISC (25-200 mA)过程的转换,而平衡器件的迹线显示从正常ISC (1-5 mA)到异常RISC (10-50 mA),然后到正常RISC (50-150 mA),最后到异常ISC (200-300 mA)过程的转换。通过拟合和分解不平衡和平衡器件的电流相关MEL迹线,我们发现随着偏置电流的增加,这两种器件中的ISC和RISC过程先增强后减弱。这些非单调的电流依赖性ISC和RISC过程归因于在提高偏置电流过程中极化子对和激复态的数量增加和寿命减少之间的竞争。此外,平衡装置中的RISC工艺比不平衡装置中的RISC工艺更强。这是因为平衡载流子注入可以促进三重态外复态的形成,减弱三重态外复态与过量载流子之间的三重电荷湮灭(triple -charge湮灭,TQA)过程,导致三重态外复态的数量增加。即通过RISC工艺可以将更多的三重态外工态转换为单重态外工态,使得平衡器件的外部量子效率高于非平衡器件。显然,这项工作不仅加深了对eb - oled中电流依赖的ISC和RISC工艺的理解,而且为设计和制造高效eb - oled提供了器件物理学的见解。
{"title":"Various current-dependent intersystem crossing and reverse intersystem crossing processes induced by different charge balances in exciplex-based OLEDs","authors":"Zhao Xi, Chen Jing, Peng Teng, Liu Jun-Hong, Wang bo, Chen Xiao-Li, Xiong Zu-Hong","doi":"10.7498/aps.72.20230765","DOIUrl":"https://doi.org/10.7498/aps.72.20230765","url":null,"abstract":"Intersystem crossing (ISC) and reverse ISC (RISC) between singlet and triplet polaron-pair and exciplex states are important spin-mixing processes in exciplex-based organic light-emitting diodes (EB-OLEDs). These two processes usually show normal current dependencies which weaken with increasing the bias-current. This is because the increase in the bias-current is realized by improving the device bias-voltage. When the bias-voltage rises, the electric field within the device enhances, which facilitates the electric-field-induced dissociation of polaron-pair and exciplex states and then reduces their lifetime. That is, less polaron-pair and exciplex states participate in the ISC and RISC processes leading to the reduction of these two processes. Here, magneto-electroluminescence (MEL) is used as a fingerprint probing tool to observe various current-dependent ISC and RISC processes in EB-OLEDs with different charge balances via modifying the device hole-injection layer. Interestingly, current-dependent MEL traces of the unbalanced device display a conversion from normal ISC (1-25 mA) to abnormal ISC (25-200 mA) processes, whereas those of the balanced device show conversions from normal ISC (1-5 mA) to abnormal RISC (10-50 mA) and then to normal RISC (50-150 mA) and finally to abnormal ISC (200-300 mA) processes. By fitting and decomposing the current-dependent MEL traces of the unbalanced and balanced devices, we find that the ISC and RISC processes in these two devices first enhance but then weaken as the bias-current increases. These non-monotonic current-dependent ISC and RISC processes are attributed to the competition between the increased number and the reduced lifetime of polaron-pair and exciplex states during improving the bias-current. Furthermore, the RISC process in the balanced device is stronger than that in the unbalanced device. This is because the balanced carrier injection can facilitate the formation of triplet exciplex states and weaken the triplet-charge annihilation (TQA) process between triplet exciplex states and excessive charge carriers, which leads to the increased number of triplet exciplex states. That is, more triplet exciplex states can convert into singlet exciplex states through the RISC process, causing a higher external quantum efficiency of the balanced device than that of the unbalanced device. Obviously, this work not only deepens the understandings of current-dependent ISC and RISC processes in EB-OLEDs, but also provides insights of device physics for designing and fabricating high-efficiency EB-OLEDs.","PeriodicalId":6995,"journal":{"name":"物理学报","volume":"57 10 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78043960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Research On Time-space United Coding Spread Spectrum Single Photon Counting Imaging Method 时空联合编码扩频单光子计数成像方法研究
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20221438
Shanshan Shen, Guo Hua Gu, Chen Qian, He Rui qing, Cao qing qing
In this paper, we demonstrate a new imaging architecture called time-space united coding spread spectrum single photon counting imaging technique by combining the space coding based single-pixel imaging technology and spread spectrum time coding based scanning imaging technology. This method has the advantages of avoiding range ambiguity and large time bandwidth product. Under the interference of noise this method can accurately restore depth images. In this paper, the time-space united correlation nonlinear detection model based on single photon detection, forward imaging model and Signal-to-Noise Ratio model is derived, and the depth image is restored by convex optimization inversion algorithm. The theoretical model and simulation experiments show that, compared with the traditional single pixel imaging method based on spatial coding, this method improves the quality of scene reconstruction. Using m-sequence as time coding,imaging has higher noise robustness. In addition, compared with the traditional space coding single pixel imaging technology, the imaging mean square error of the proposed method is reduced by 5 times and the imaging mean squared error is reduced by 10 times after introducing the second correlated method. The proposed imaging architecture in this paper may provide a new path for non-scanning lidar imaging methods.
本文将基于空间编码的单像素成像技术与基于扩频时间编码的扫描成像技术相结合,提出了一种新的成像体系结构——时空联合编码扩频单光子计数成像技术。该方法具有避免距离模糊和时间带宽积大的优点。在噪声干扰下,该方法能准确地恢复深度图像。本文推导了基于单光子探测、正演成像模型和信噪比模型的时空联合相关非线性探测模型,并采用凸优化反演算法恢复深度图像。理论模型和仿真实验表明,与传统的基于空间编码的单像素成像方法相比,该方法提高了场景重建的质量。采用m序列作为时间编码,成像具有更高的噪声鲁棒性。此外,与传统的空间编码单像素成像技术相比,引入二次相关方法后,该方法的成像均方误差减小了5倍,成像均方误差减小了10倍。本文提出的成像结构为非扫描激光雷达成像方法提供了一条新的途径。
{"title":"The Research On Time-space United Coding Spread Spectrum Single Photon Counting Imaging Method","authors":"Shanshan Shen, Guo Hua Gu, Chen Qian, He Rui qing, Cao qing qing","doi":"10.7498/aps.72.20221438","DOIUrl":"https://doi.org/10.7498/aps.72.20221438","url":null,"abstract":"In this paper, we demonstrate a new imaging architecture called time-space united coding spread spectrum single photon counting imaging technique by combining the space coding based single-pixel imaging technology and spread spectrum time coding based scanning imaging technology. This method has the advantages of avoiding range ambiguity and large time bandwidth product. Under the interference of noise this method can accurately restore depth images. In this paper, the time-space united correlation nonlinear detection model based on single photon detection, forward imaging model and Signal-to-Noise Ratio model is derived, and the depth image is restored by convex optimization inversion algorithm. The theoretical model and simulation experiments show that, compared with the traditional single pixel imaging method based on spatial coding, this method improves the quality of scene reconstruction. Using m-sequence as time coding,imaging has higher noise robustness. In addition, compared with the traditional space coding single pixel imaging technology, the imaging mean square error of the proposed method is reduced by 5 times and the imaging mean squared error is reduced by 10 times after introducing the second correlated method. The proposed imaging architecture in this paper may provide a new path for non-scanning lidar imaging methods.","PeriodicalId":6995,"journal":{"name":"物理学报","volume":"48 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80030702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Bayesian geoacoustic inversion based on modal dispersions of water wave and ground wave 基于水波和地波模态色散的贝叶斯地球声反演
IF 1 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20221717
Hao Wang, Duan Rui, Yang Kun-De
Most shallow water geoacoustic inversions based on modal dispersion cannot reliably estimate the deep geoacoustic parameters. Because these studies focus on the dispersions of water waves but ignore the dispersions of ground waves. Therefore, this paper studied a Bayesian geoacoustic inversion based on wideband modal dispersions of water waves and ground waves. Firstly, the modal dispersion curves with Airy phase components were discussed. Secondly, the Bayesian inversion theory and a novel sample-efficient inference algorithm, namely Variational Bayesian Monte Carlo, were introduced briefly. In the Bayesian inversion, the posterior probability densities of unknown parameters are inferred, which can provide the prediction closest to the observation data and the uncertainty of the prediction. Considering that the forward acoustic model is computationally intensive, the posterior analysis is carried out by using the Variational Bayesian Monte Carlo method. It is performed by finding the variational distribution closest to the target distribution and requires less computation time than the Markov chain Monto Carlo method. In the simulation study, a range-independent two-layer seabed, including the sediment layer and basement layer, is modeled, assuming that the water column is homogeneous. The function of shear wave in waveguide was ignored. The compressional sound speed of the sediment layer varied linearly from c1U to c1L between 0 and h1, while other geoacoustic parameters were constant. By comparing the inversion results with and without the information of ground waves for different signal-to-noise ratios, it can be concluded that the deep geoacoustic parameters are more sensitive to the dispersions of ground waves. And then, a shallow-water experimental study was carried out in the Bohai Sea of China. The average water depth was about 20m. The wideband pulse signals were recorded by a hydrophone with a sensitivity of -170dB re 1V/μPa. The received signals included well-defined Airy phase components, and the modal dispersion curves of water waves and ground waves were extracted accurately. The experimental results indicated that the Bayesian inversion combining water and ground wave dispersions can not only estimate the deep geoacoustic parameters reliably, but also reduce the inversion uncertainties of other model parameters, such as the shallow geoacoustic parameters, water depth, and so on. The estimated source-receiver range and water sound speed are close to their measured values. The modal dispersion curves predicted by the posterior mean samples were in good agreement with those extracted from the experimental data at different ranges. In addition, the well forecast of transmission loss also demonstrated the reliability of the joint inversion.
大多数基于模态频散的浅水地声反演不能可靠地估计深水地声参数。因为这些研究主要集中在水波的频散上,而忽略了地波的频散。因此,本文研究了基于水波和地波宽带模态色散的贝叶斯地球声反演方法。首先,讨论了含Airy相位分量的模态色散曲线。其次,简要介绍了贝叶斯反演理论和一种新的样本高效推理算法——变分贝叶斯蒙特卡罗。在贝叶斯反演中,通过推断未知参数的后验概率密度,可以提供最接近观测数据的预测和预测的不确定性。考虑到前向声学模型计算量大,采用变分贝叶斯蒙特卡罗方法进行后验分析。它通过寻找最接近目标分布的变分分布来实现,与马尔可夫链蒙特卡罗方法相比,计算时间更少。在模拟研究中,假设水柱是均匀的,模拟了一个距离无关的两层海床,包括沉积层和基底层。忽略波导中横波的作用。在0 ~ h1之间,沉积层压缩声速从c1U到c1L呈线性变化,而其他地声参数不变。通过对比不同信噪比下含和不含地波信息的反演结果,可以得出深部地声参数对地波色散更为敏感的结论。然后,在渤海进行了浅水实验研究。平均水深约20米。采用灵敏度为-170dB / 1V/μPa的水听器记录宽带脉冲信号。接收信号具有明确的Airy相位分量,准确提取了水波和地波的模态色散曲线。实验结果表明,水波与地波频散相结合的贝叶斯反演不仅可以可靠地估计深层地声参数,而且可以减小浅层地声参数、水深等其他模型参数的反演不确定性。估计的源-接收机距离和水声速度与实测值接近。后验平均样本预测的模态色散曲线与实验数据在不同范围内的模态色散曲线吻合较好。此外,对输电损耗的良好预测也证明了联合反演的可靠性。
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引用次数: 0
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物理学报
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