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Effect of Solution Conditions and Applied Potential on Ion Transport in TiO2 Nanopores 溶液条件和应用电位对二氧化钛纳米孔中离子传输的影响
IF 7.1 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-21 DOI: 10.1021/acsestengg.4c00295
Saurabh N. Misal, Donglin Li, Sangil Kim, Brian P. Chaplin
This study investigated the material and ion transport properties of TiO2 nanopores as a function of solution conditions and applied electrode potentials. Zeta potential measurements revealed that the TiO2 surface charge was highly dependent on solution conditions, which was attributed to protonation/deprotonation of surface functional groups and adsorption of ions. Ion rejection followed the absolute magnitude of the membrane surface charge and was pH-dependent, reflecting the amphoteric nature of TiO2. The rejection of NaCl was approximately symmetrical about the point of zero charge of the membrane, with the highest rejection at acidic and basic conditions. Specific adsorption of SO42– and Mg2+ under acidic and basic conditions, respectively, neutralized the membrane charge and significantly reduced ion rejection. A mathematical transport model was fit to experimental data, and the model-determined membrane charge densities as a function of solution conditions agreed with experimental zeta potential measurements. Model results also revealed that rejection was primarily attributed to the Donnan exclusion mechanism. The application of both anodic and cathodic potentials directly to the TiO2 membrane caused permselective transport under specific solution conditions.
本研究探讨了二氧化钛纳米孔的材料和离子传输特性与溶液条件和应用电极电位的函数关系。Zeta 电位测量显示,TiO2 表面电荷与溶液条件高度相关,这归因于表面官能团的质子化/去质子化和离子吸附。离子排斥与膜表面电荷的绝对值有关,并与 pH 值相关,这反映了二氧化钛的两性性质。对 NaCl 的抑制作用与膜的零电荷点大致对称,在酸性和碱性条件下抑制作用最强。在酸性和碱性条件下,分别对 SO42- 和 Mg2+ 的特定吸附中和了膜电荷,大大降低了离子抑制作用。根据实验数据拟合了一个数学传输模型,模型确定的膜电荷密度与溶液条件的函数关系与实验的 zeta 电位测量结果一致。模型结果还显示,排斥主要归因于唐南排除机制。在特定的溶液条件下,对二氧化钛膜直接施加阳极电位和阴极电位会引起全选择性迁移。
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引用次数: 0
Effect of Solution Conditions and Applied Potential on Ion Transport in TiO2 Nanopores 溶液条件和应用电位对二氧化钛纳米孔中离子传输的影响
IF 7.4 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-21 DOI: 10.1021/acsestengg.4c0029510.1021/acsestengg.4c00295
Saurabh N. Misal, Donglin Li, Sangil Kim* and Brian P. Chaplin*, 

This study investigated the material and ion transport properties of TiO2 nanopores as a function of solution conditions and applied electrode potentials. Zeta potential measurements revealed that the TiO2 surface charge was highly dependent on solution conditions, which was attributed to protonation/deprotonation of surface functional groups and adsorption of ions. Ion rejection followed the absolute magnitude of the membrane surface charge and was pH-dependent, reflecting the amphoteric nature of TiO2. The rejection of NaCl was approximately symmetrical about the point of zero charge of the membrane, with the highest rejection at acidic and basic conditions. Specific adsorption of SO42– and Mg2+ under acidic and basic conditions, respectively, neutralized the membrane charge and significantly reduced ion rejection. A mathematical transport model was fit to experimental data, and the model-determined membrane charge densities as a function of solution conditions agreed with experimental zeta potential measurements. Model results also revealed that rejection was primarily attributed to the Donnan exclusion mechanism. The application of both anodic and cathodic potentials directly to the TiO2 membrane caused permselective transport under specific solution conditions.

本研究探讨了二氧化钛纳米孔的材料和离子传输特性与溶液条件和应用电极电位的函数关系。Zeta 电位测量显示,TiO2 表面电荷与溶液条件高度相关,这归因于表面官能团的质子化/去质子化和离子吸附。离子排斥与膜表面电荷的绝对值有关,并与 pH 值相关,这反映了二氧化钛的两性性质。对 NaCl 的抑制作用与膜的零电荷点大致对称,在酸性和碱性条件下抑制作用最强。在酸性和碱性条件下,分别对 SO42- 和 Mg2+ 的特定吸附中和了膜电荷,大大降低了离子抑制作用。根据实验数据拟合了一个数学传输模型,模型确定的膜电荷密度与溶液条件的函数关系与实验的 zeta 电位测量结果一致。模型结果还显示,排斥主要归因于唐南排除机制。在特定的溶液条件下,对二氧化钛膜直接施加阳极电位和阴极电位会引起全选择性迁移。
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引用次数: 0
Dual-Crosslinking Polydopamine/Poly(imide dioxime) Porous Network Membrane Enables Efficient and Selective Gold Recovery from e-Waste 双交联聚多巴胺/聚(亚胺二氧肟)多孔网络膜可从电子垃圾中高效、选择性地回收黄金
IF 7.4 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-20 DOI: 10.1021/acsestengg.4c0026310.1021/acsestengg.4c00263
Xueqin Zhang, Huaimeng Li*, Zhenzhen Liu, Zhen Fu, Haimin Zhang, Guozhong Wang and Yunxia Zhang*, 

With the sharp increase in electronic and electrical equipment as well as concomitant electronic waste, it is imperative to recover precious metals from secondary resources from the perspective of environment protection and sustainable development. Herein, a free-standing, dual-cross-linking polydopamine (PDA) in conjunction with poly(imide dioxime) (PIDO) porous membrane (denoted as PDA/PIDO) is fabricated via a facile interfacial polymerization method for gold recovery. As expected, the constructed PDA/PIDO membrane features a hierarchical porous structure, ample active sites, and excellent hydrophilicity, endowing it with an ultrahigh gold capture capacity (3368 mg g–1), fast equilibrium time (35 min), superior recovery selectivity (separation factor of Au/Cu = 5.4 × 105, Au/Ni = 3.9 × 105), high flux (1050 L m2 h–1), and high retention rate (98%). Furthermore, the proposed PDA/PIDO membrane is also competent for selective gold recovery from the central processing unit leachate with remarkable efficiency in a continuous-flowing filtration system, highlighting its huge potential in practical large-scale gold recovery from e-waste.

随着电子电气设备以及随之产生的电子废弃物的急剧增加,从环境保护和可持续发展的角度出发,从二次资源中回收贵金属势在必行。本文通过一种简便的界面聚合方法,制备了一种独立的双交联聚多巴胺(PDA)与聚(亚胺二氧肟)(PIDO)多孔膜(简称 PDA/PIDO),用于金的回收。正如预期的那样,所制备的 PDA/PIDO 膜具有分层多孔结构、充足的活性位点和优异的亲水性,因而具有超高的金捕获能力(3368 mg g-1)、快速的平衡时间(35 分钟)、优异的回收选择性(Au/Cu = 5.4 × 105,Au/Ni = 3.9 × 105)、高通量(1050 L m2 h-1)和高截留率(98%)。此外,所提出的 PDA/PIDO 膜还能在连续流动的过滤系统中从中央处理单元浸出液中选择性地回收金,且效率显著,这凸显了其在实际大规模回收电子垃圾中的巨大潜力。
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引用次数: 0
Dual-Crosslinking Polydopamine/Poly(imide dioxime) Porous Network Membrane Enables Efficient and Selective Gold Recovery from e-Waste 双交联聚多巴胺/聚(亚胺二氧肟)多孔网络膜可从电子垃圾中高效、选择性地回收黄金
IF 7.1 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-20 DOI: 10.1021/acsestengg.4c00263
Xueqin Zhang, Huaimeng Li, Zhenzhen Liu, Zhen Fu, Haimin Zhang, Guozhong Wang, Yunxia Zhang
With the sharp increase in electronic and electrical equipment as well as concomitant electronic waste, it is imperative to recover precious metals from secondary resources from the perspective of environment protection and sustainable development. Herein, a free-standing, dual-cross-linking polydopamine (PDA) in conjunction with poly(imide dioxime) (PIDO) porous membrane (denoted as PDA/PIDO) is fabricated via a facile interfacial polymerization method for gold recovery. As expected, the constructed PDA/PIDO membrane features a hierarchical porous structure, ample active sites, and excellent hydrophilicity, endowing it with an ultrahigh gold capture capacity (3368 mg g–1), fast equilibrium time (35 min), superior recovery selectivity (separation factor of Au/Cu = 5.4 × 105, Au/Ni = 3.9 × 105), high flux (1050 L m2 h–1), and high retention rate (98%). Furthermore, the proposed PDA/PIDO membrane is also competent for selective gold recovery from the central processing unit leachate with remarkable efficiency in a continuous-flowing filtration system, highlighting its huge potential in practical large-scale gold recovery from e-waste.
随着电子电气设备以及随之产生的电子废弃物的急剧增加,从环境保护和可持续发展的角度出发,从二次资源中回收贵金属势在必行。本文通过一种简便的界面聚合方法,制备了一种独立的双交联聚多巴胺(PDA)与聚(亚胺二氧肟)(PIDO)多孔膜(简称 PDA/PIDO),用于金的回收。正如预期的那样,所制备的 PDA/PIDO 膜具有分层多孔结构、充足的活性位点和优异的亲水性,因而具有超高的金捕获能力(3368 mg g-1)、快速的平衡时间(35 分钟)、优异的回收选择性(Au/Cu = 5.4 × 105,Au/Ni = 3.9 × 105)、高通量(1050 L m2 h-1)和高截留率(98%)。此外,所提出的 PDA/PIDO 膜还能在连续流动的过滤系统中从中央处理单元浸出液中选择性地回收金,且效率显著,这凸显了其在实际大规模回收电子垃圾中的巨大潜力。
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引用次数: 0
Plant Polyphenol-Driven Polymerization-Confinement Strategy toward Ultrahighly Loaded Atomically Dispersed FeCo Bimetallic Catalysts for Singlet Oxygen-Dominated Fenton-like Reactions 植物多酚驱动的聚合-强化战略:超高负载原子分散铁钴双金属催化剂用于单线态氧主导的类芬顿反应
IF 7.4 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-18 DOI: 10.1021/acsestengg.4c0023710.1021/acsestengg.4c00237
Yue Wang, Zhenglong Liu, Weilu Kang, Tielong Li* and Haitao Wang*, 

Recent progress has brought carbon-confined transition metal catalysts to the forefront as effective agents for Fenton-like reactions. However, achieving a stable integration of densely loaded and well-dispersed transition metals onto carbon support poses significant challenges. Herein, we introduce a plant polyphenol-driven polymerization-confinement method for the synthesis of a highly dispersed FeCo bimetallic catalyst (FeCo@NGB). Utilizing the chelating effect of tea polyphenols with metal ions and their subsequent polymerization and confinement offers a durable solution for stabilizing the FeCo bimetallic sites. The resulting FeCo@NGB demonstrates exceptional performance in activating peroxymonosulfate (PMS) for the swift degradation of tetracycline (TC), with a 99.5% reduction achieved in just 30 min, predominantly through a singlet oxygen (1O2)-driven pathway. Experimental and theoretical calculations highlight the pivotal role of atomically dispersed FeN4–CoN3 sites in facilitating rapid electron transfer between the catalyst and PMS, thereby enhancing 1O2 production. This work not only advances the development of high-performance multiphase catalysts but also introduces a compelling strategy for water purification leveraging nonradical oxidative pathways.

最近的研究进展使碳封闭过渡金属催化剂成为芬顿类反应的有效催化剂。然而,在碳载体上实现过渡金属的高密度负载和良好分散的稳定整合是一项重大挑战。在此,我们介绍了一种植物多酚驱动的聚合-封闭方法,用于合成高度分散的铁钴双金属催化剂(FeCo@NGB)。利用茶多酚与金属离子的螯合作用以及随后的聚合和封闭为稳定铁钴双金属位点提供了一种持久的解决方案。由此产生的 FeCo@NGB 在激活过一硫酸盐(PMS)以快速降解四环素(TC)方面表现出卓越的性能,主要通过单线态氧(1O2)驱动的途径,仅在 30 分钟内就实现了 99.5% 的降解。实验和理论计算突出表明,原子分散的 FeN4-CoN3 位点在促进催化剂和 PMS 之间的快速电子传递方面起着关键作用,从而提高了 1O2 的产生。这项工作不仅推动了高性能多相催化剂的发展,还为利用非自由基氧化途径进行水净化提出了一个引人注目的策略。
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引用次数: 0
Plant Polyphenol-Driven Polymerization-Confinement Strategy toward Ultrahighly Loaded Atomically Dispersed FeCo Bimetallic Catalysts for Singlet Oxygen-Dominated Fenton-like Reactions 植物多酚驱动的聚合-强化战略:超高负载原子分散铁钴双金属催化剂用于单线态氧主导的类芬顿反应
IF 7.1 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-18 DOI: 10.1021/acsestengg.4c00237
Yue Wang, Zhenglong Liu, Weilu Kang, Tielong Li, Haitao Wang
Recent progress has brought carbon-confined transition metal catalysts to the forefront as effective agents for Fenton-like reactions. However, achieving a stable integration of densely loaded and well-dispersed transition metals onto carbon support poses significant challenges. Herein, we introduce a plant polyphenol-driven polymerization-confinement method for the synthesis of a highly dispersed FeCo bimetallic catalyst (FeCo@NGB). Utilizing the chelating effect of tea polyphenols with metal ions and their subsequent polymerization and confinement offers a durable solution for stabilizing the FeCo bimetallic sites. The resulting FeCo@NGB demonstrates exceptional performance in activating peroxymonosulfate (PMS) for the swift degradation of tetracycline (TC), with a 99.5% reduction achieved in just 30 min, predominantly through a singlet oxygen (1O2)-driven pathway. Experimental and theoretical calculations highlight the pivotal role of atomically dispersed FeN4–CoN3 sites in facilitating rapid electron transfer between the catalyst and PMS, thereby enhancing 1O2 production. This work not only advances the development of high-performance multiphase catalysts but also introduces a compelling strategy for water purification leveraging nonradical oxidative pathways.
最近的研究进展使碳封闭过渡金属催化剂成为芬顿类反应的有效催化剂。然而,在碳载体上实现过渡金属的高密度负载和良好分散的稳定整合是一项重大挑战。在此,我们介绍了一种植物多酚驱动的聚合-封闭方法,用于合成高度分散的铁钴双金属催化剂(FeCo@NGB)。利用茶多酚与金属离子的螯合作用以及随后的聚合和封闭为稳定铁钴双金属位点提供了一种持久的解决方案。由此产生的 FeCo@NGB 在激活过一硫酸盐(PMS)以快速降解四环素(TC)方面表现出卓越的性能,主要通过单线态氧(1O2)驱动的途径,仅在 30 分钟内就实现了 99.5% 的降解。实验和理论计算突出表明,原子分散的 FeN4-CoN3 位点在促进催化剂和 PMS 之间的快速电子传递方面起着关键作用,从而提高了 1O2 的产生。这项工作不仅推动了高性能多相催化剂的发展,还为利用非自由基氧化途径进行水净化提出了一个引人注目的策略。
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引用次数: 0
Applications of AFM in Membrane Characterization and Fouling Analysis 原子力显微镜在膜表征和污垢分析中的应用
IF 7.1 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-18 DOI: 10.1021/acsestengg.4c00111
Qi Liu, Xiaoqi Zhu, Baoliang Chen, Xiaoying Zhu
Atomic force microscopy (AFM), as a type of scanning probe microscopy (SPM), possesses formidable capabilities for nanoscale imaging and force spectroscopy. Due to its advantages such as high resolution, nondestructive detection, minimal environmental restrictions, strong versatility, and real-time in situ analysis, AFM has become an indispensable tool in surface science and materials research, finding extensive applications in the study of the membrane separation and fouling processes. The tremendous advantages of AFM in characterization applications stem from its diverse tip functionalization techniques. This review encompasses the preparation of AFM probe tips and the modification techniques of special tips, including carbon nanotube (CNT) probes, metal nanowire probes, colloidal probes, and single-cell/molecule probes. Furthermore, it highlights the applications and advancements of AFM and probe modification techniques in membrane technology research. With the continuous development of tip modification techniques, the analytical capabilities of AFM will be further expanded, promising broader prospects for its application in the study of membrane fouling mechanisms and the development of antifouling membrane materials.
原子力显微镜(AFM)是扫描探针显微镜(SPM)的一种,具有强大的纳米级成像和力谱分析能力。由于原子力显微镜具有高分辨率、无损检测、环境限制小、通用性强和实时原位分析等优点,已成为表面科学和材料研究领域不可或缺的工具,在膜分离和污垢过程研究中得到了广泛应用。原子力显微镜在表征应用中的巨大优势源于其多样化的针尖功能化技术。本综述涵盖原子力显微镜探针针尖的制备和特殊针尖的改性技术,包括碳纳米管(CNT)探针、金属纳米线探针、胶体探针和单细胞/分子探针。此外,报告还重点介绍了原子力显微镜和探针改性技术在膜技术研究中的应用和进展。随着探针修饰技术的不断发展,原子力显微镜的分析能力将得到进一步拓展,在膜污垢机理研究和防污膜材料开发方面的应用前景将更加广阔。
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引用次数: 0
Applications of AFM in Membrane Characterization and Fouling Analysis 原子力显微镜在膜表征和污垢分析中的应用
IF 7.4 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-18 DOI: 10.1021/acsestengg.4c0011110.1021/acsestengg.4c00111
Qi Liu, Xiaoqi Zhu, Baoliang Chen and Xiaoying Zhu*, 

Atomic force microscopy (AFM), as a type of scanning probe microscopy (SPM), possesses formidable capabilities for nanoscale imaging and force spectroscopy. Due to its advantages such as high resolution, nondestructive detection, minimal environmental restrictions, strong versatility, and real-time in situ analysis, AFM has become an indispensable tool in surface science and materials research, finding extensive applications in the study of the membrane separation and fouling processes. The tremendous advantages of AFM in characterization applications stem from its diverse tip functionalization techniques. This review encompasses the preparation of AFM probe tips and the modification techniques of special tips, including carbon nanotube (CNT) probes, metal nanowire probes, colloidal probes, and single-cell/molecule probes. Furthermore, it highlights the applications and advancements of AFM and probe modification techniques in membrane technology research. With the continuous development of tip modification techniques, the analytical capabilities of AFM will be further expanded, promising broader prospects for its application in the study of membrane fouling mechanisms and the development of antifouling membrane materials.

原子力显微镜(AFM)是扫描探针显微镜(SPM)的一种,具有强大的纳米级成像和力谱分析能力。由于原子力显微镜具有高分辨率、无损检测、环境限制小、通用性强和实时原位分析等优点,已成为表面科学和材料研究领域不可或缺的工具,在膜分离和污垢过程研究中得到了广泛应用。原子力显微镜在表征应用中的巨大优势源于其多样化的针尖功能化技术。本综述涵盖原子力显微镜探针针尖的制备和特殊针尖的改性技术,包括碳纳米管(CNT)探针、金属纳米线探针、胶体探针和单细胞/分子探针。此外,报告还重点介绍了原子力显微镜和探针改性技术在膜技术研究中的应用和进展。随着探针修饰技术的不断发展,原子力显微镜的分析能力将得到进一步拓展,在膜污垢机理研究和防污膜材料开发方面的应用前景将更加广阔。
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引用次数: 0
Optimal Management Strategy for Salt Adsorption Capacity in Machine Learning-Based Flow-Electrode Capacitive Deionization Process 基于机器学习的流电极电容式去离子工艺中盐吸附容量的优化管理策略
IF 7.1 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-17 DOI: 10.1021/acsestengg.4c00142
Sung Il Yu, Junbeom Jeon, Yong-Uk Shin, Hyokwan Bae
Flow-electrode capacitive deionization (FCDI) has created a breakthrough toward a more stable desalination performance by adopting a flow-electrode compared to existing capacitive deionization and membrane capacitive deionization as a promising electrochemical water treatment technology. However, the FCDI technology requires investigation of various mechanisms pertaining to flow-electrode materials to achieve system optimization. Further, studies on applying machine learning to the FCDI technology have been scarcely reported. Our study aims to explore optimal algorithms via machine learning for predicting the salt adsorption capacity of FCDI processes and evaluate the feasibility of optimization applications. Concurrently, a comparative analysis was conducted through the performance model indicators of mean absolute error (MAE), mean squared error, and R2 for support vector machine, random forest, and artificial neural network (ANN) algorithms. Herein, we demonstrated that the optimal ANN-based model exhibited the highest predictive performance, achieving R2 and MAE values of 0.996 and 0.21 mg/g, respectively. Additionally, the Shapley additive explanations (SHAP) confirmed a trend in the contribution of influent concentration, aligning closely with the results of statistical analysis. Specifically, the change in voltage of the FCDI process serves as a key factor in determining salt adsorption efficiency. Moreover, a parallel comparison of the Pearson correlation coefficient and SHAP analyses suggests that the impact of voltage entails a nonlinear contribution within the realm of machine learning. Finally, to deploy a machine learning-driven ANN model system, we present multiple factors (e.g., weight of flow-electrodes, influent concentration, and voltages) as a reinforcement learning model for decision-making. This offers valuable insights and guidance for future operations of the FCDI process.
与现有的电容式去离子法和膜电容去离子法相比,流动电极电容式去离子法(FCDI)通过采用流动电极,在实现更稳定的海水淡化性能方面取得了突破性进展,是一种前景广阔的电化学水处理技术。然而,FCDI 技术需要研究与流动电极材料有关的各种机制,以实现系统优化。此外,将机器学习应用于 FCDI 技术的研究也鲜有报道。我们的研究旨在通过机器学习探索预测 FCDI 过程盐吸附能力的最佳算法,并评估优化应用的可行性。同时,通过支持向量机、随机森林和人工神经网络(ANN)算法的平均绝对误差(MAE)、平均平方误差和 R2 等性能模型指标进行了比较分析。结果表明,基于人工神经网络的最优化模型具有最高的预测性能,其 R2 和 MAE 值分别为 0.996 和 0.21 mg/g。此外,夏普利加法解释(SHAP)证实了进水浓度的贡献趋势,与统计分析结果密切吻合。具体而言,FCDI 过程的电压变化是决定盐吸附效率的关键因素。此外,对皮尔逊相关系数和 SHAP 分析的平行比较表明,电压的影响在机器学习领域内具有非线性贡献。最后,为了部署机器学习驱动的 ANN 模型系统,我们将多个因素(如流电极重量、进水浓度和电压)作为强化学习模型进行决策。这为 FCDI 流程的未来运行提供了宝贵的见解和指导。
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引用次数: 0
Optimal Management Strategy for Salt Adsorption Capacity in Machine Learning-Based Flow-Electrode Capacitive Deionization Process 基于机器学习的流电极电容式去离子工艺中盐吸附容量的优化管理策略
IF 7.4 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-17 DOI: 10.1021/acsestengg.4c0014210.1021/acsestengg.4c00142
Sung Il Yu, Junbeom Jeon, Yong-Uk Shin* and Hyokwan Bae*, 

Flow-electrode capacitive deionization (FCDI) has created a breakthrough toward a more stable desalination performance by adopting a flow-electrode compared to existing capacitive deionization and membrane capacitive deionization as a promising electrochemical water treatment technology. However, the FCDI technology requires investigation of various mechanisms pertaining to flow-electrode materials to achieve system optimization. Further, studies on applying machine learning to the FCDI technology have been scarcely reported. Our study aims to explore optimal algorithms via machine learning for predicting the salt adsorption capacity of FCDI processes and evaluate the feasibility of optimization applications. Concurrently, a comparative analysis was conducted through the performance model indicators of mean absolute error (MAE), mean squared error, and R2 for support vector machine, random forest, and artificial neural network (ANN) algorithms. Herein, we demonstrated that the optimal ANN-based model exhibited the highest predictive performance, achieving R2 and MAE values of 0.996 and 0.21 mg/g, respectively. Additionally, the Shapley additive explanations (SHAP) confirmed a trend in the contribution of influent concentration, aligning closely with the results of statistical analysis. Specifically, the change in voltage of the FCDI process serves as a key factor in determining salt adsorption efficiency. Moreover, a parallel comparison of the Pearson correlation coefficient and SHAP analyses suggests that the impact of voltage entails a nonlinear contribution within the realm of machine learning. Finally, to deploy a machine learning-driven ANN model system, we present multiple factors (e.g., weight of flow-electrodes, influent concentration, and voltages) as a reinforcement learning model for decision-making. This offers valuable insights and guidance for future operations of the FCDI process.

与现有的电容式去离子法和膜电容去离子法相比,流动电极电容式去离子法(FCDI)通过采用流动电极,在实现更稳定的海水淡化性能方面取得了突破性进展,是一种前景广阔的电化学水处理技术。然而,FCDI 技术需要研究与流动电极材料有关的各种机制,以实现系统优化。此外,将机器学习应用于 FCDI 技术的研究也鲜有报道。我们的研究旨在通过机器学习探索预测 FCDI 过程盐吸附能力的最佳算法,并评估优化应用的可行性。同时,通过支持向量机、随机森林和人工神经网络(ANN)算法的平均绝对误差(MAE)、平均平方误差和 R2 等性能模型指标进行了比较分析。结果表明,基于人工神经网络的最优化模型具有最高的预测性能,其 R2 和 MAE 值分别为 0.996 和 0.21 mg/g。此外,夏普利加法解释(SHAP)证实了进水浓度的贡献趋势,与统计分析结果密切吻合。具体而言,FCDI 过程的电压变化是决定盐吸附效率的关键因素。此外,对皮尔逊相关系数和 SHAP 分析的平行比较表明,电压的影响在机器学习领域内具有非线性贡献。最后,为了部署机器学习驱动的 ANN 模型系统,我们将多个因素(如流电极重量、进水浓度和电压)作为强化学习模型进行决策。这为 FCDI 流程的未来运行提供了宝贵的见解和指导。
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引用次数: 0
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ACS ES&T engineering
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