E. Okoronkwo, Patrick Ehi Imoisili, S. A. Olubayode, S. Olusunle
Silica from corn cob ash (CCA) was extracted via sol-gel, and nanostructured with templating concept, these resulted in silica nanoparticle. Silica and mineral contents of CCA were determined by X-ray fluorescence (XRF). X-ray diffraction (XRD) patterns revealed amorphous nature of extracted silica. Fourier transform infrared (FTIR) data indicated the presence of siloxane and silanol groups. X-ray diffraction (XRD) of nanostrurtured silica reviled average particle size of 54 nm, Scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) study indicates the particles to possess disorder morphology with the particle attached to each other through grain boundary to form agglomerated structure, and SEM analysis shows that particle size varies from 44 nm - 98 nm in diameter, with an average diameter of 55nm. EDS spectrum confirms SiO2.
{"title":"Development of Silica Nanoparticle from Corn Cob Ash","authors":"E. Okoronkwo, Patrick Ehi Imoisili, S. A. Olubayode, S. Olusunle","doi":"10.4236/ANP.2016.52015","DOIUrl":"https://doi.org/10.4236/ANP.2016.52015","url":null,"abstract":"Silica from corn cob ash (CCA) was extracted via sol-gel, and nanostructured with templating concept, these resulted in silica nanoparticle. Silica and mineral contents of CCA were determined by X-ray fluorescence (XRF). X-ray diffraction (XRD) patterns revealed amorphous nature of extracted silica. Fourier transform infrared (FTIR) data indicated the presence of siloxane and silanol groups. X-ray diffraction (XRD) of nanostrurtured silica reviled average particle size of 54 nm, Scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) study indicates the particles to possess disorder morphology with the particle attached to each other through grain boundary to form agglomerated structure, and SEM analysis shows that particle size varies from 44 nm - 98 nm in diameter, with an average diameter of 55nm. EDS spectrum confirms SiO2.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"05 1","pages":"135-139"},"PeriodicalIF":0.0,"publicationDate":"2016-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tin oxide (SnO2) nanofibers are successfully prepared by electrospinning homogeneous viscous solutions of tin acetate in polyvinylpyrrolidone (PVP). The electrospinning is carried out by applying a DC voltage to the tip of a syringe and maintaining the tip to collector distance (TCD), i.e. at DC electric field of 1.25 kV•cm–1. The electrospun nanofibers are calcined between 550℃ and 650℃ for 4 h. Both spun and heat treated nanofibers are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infra red spectroscopy (FTIR) etc. XRD analysis of calcined nanofibers confirms the formation of pure tin oxide. TEM study showed that fibers have a polycrystalline structure with multiple nano-grains.
{"title":"Preparation and Characterization of SnO 2 Nanofibers via Electrospinning","authors":"R. Rani, Seema Sharma","doi":"10.4236/ANP.2016.51006","DOIUrl":"https://doi.org/10.4236/ANP.2016.51006","url":null,"abstract":"Tin oxide (SnO2) nanofibers are successfully prepared by electrospinning homogeneous viscous solutions of tin acetate in polyvinylpyrrolidone (PVP). The electrospinning is carried out by applying a DC voltage to the tip of a syringe and maintaining the tip to collector distance (TCD), i.e. at DC electric field of 1.25 kV•cm–1. The electrospun nanofibers are calcined between 550℃ and 650℃ for 4 h. Both spun and heat treated nanofibers are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infra red spectroscopy (FTIR) etc. XRD analysis of calcined nanofibers confirms the formation of pure tin oxide. TEM study showed that fibers have a polycrystalline structure with multiple nano-grains.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"5 1","pages":"53-59"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rhodium nanoparticle-loaded carbon black (Rh/CB) was prepared by a wet method, and its activity and durability for glycerol oxidation reaction (GOR) in alkaline medium were compared with Pt, Pd and Au nanoparticle-loaded CB (Pt/CB, Pd/CB and Au/CB). In the cyclic voltammogram of the Rh/CB electrode, the redox waves due to hydrogen adsorption/desorption and the surface OH monolayer formation/reduction were observed at more negative potentials than the Pt/CB and Pd/CB electrodes. The onset and peak potentials of the GOR current densities for the Rh/CB electrode were ca. –0.55 and –0.30 V vs. Hg/HgO, respectively, which were 0.10 and 0.20 V more negative than the Pt/CB electrode whose GOR activity was the best, indicating that Rh was a fascinating metal for reducing the overpotential for GOR. In the electrostatic electrolysis with the Rh/CB and Pt/CB electrodes, the decrease in the GOR current density in the former with time was suppressed compared to that in the latter, suggesting that the tolerance to poisoning for the Rh/CB electrode was superior to that for the Pt/CB electrode.
{"title":"Rhodium Nanoparticle-Loaded Carbon Black Electrocatalyst for the Glycerol Oxidation Reaction in Alkaline Medium","authors":"B. Lam, Masanobu Chiku, E. Higuchi, H. Inoue","doi":"10.4236/ANP.2016.51007","DOIUrl":"https://doi.org/10.4236/ANP.2016.51007","url":null,"abstract":"Rhodium nanoparticle-loaded carbon black (Rh/CB) was prepared by a wet method, and its activity and durability for glycerol oxidation reaction (GOR) in alkaline medium were compared with Pt, Pd and Au nanoparticle-loaded CB (Pt/CB, Pd/CB and Au/CB). In the cyclic voltammogram of the Rh/CB electrode, the redox waves due to hydrogen adsorption/desorption and the surface OH monolayer formation/reduction were observed at more negative potentials than the Pt/CB and Pd/CB electrodes. The onset and peak potentials of the GOR current densities for the Rh/CB electrode were ca. –0.55 and –0.30 V vs. Hg/HgO, respectively, which were 0.10 and 0.20 V more negative than the Pt/CB electrode whose GOR activity was the best, indicating that Rh was a fascinating metal for reducing the overpotential for GOR. In the electrostatic electrolysis with the Rh/CB and Pt/CB electrodes, the decrease in the GOR current density in the former with time was suppressed compared to that in the latter, suggesting that the tolerance to poisoning for the Rh/CB electrode was superior to that for the Pt/CB electrode.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"5 1","pages":"60-66"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nano-crystalline CrxCoFe2–xO4 (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) ferrites were synthesized by sol-gel method. The X-ray diffraction patterns of all the samples provide information about the existence of single phase spinel structure. The SEM and TEM micrographs show the uniform particle distribution and SAED pattern represents the polycrystalline nature of the resultant ferrite nano-particles. High purity of the sample is confirmed by energy dispersive X-ray analysis. The FTIR spectra show two strong absorption bands in the range of 600 - 400 cm–1, which confirm the presence of M-O stretching band in ferrites. The magnetic properties of the synthesized samples were investigated by using vibrating sample magnetometer at room temperature. According to VSM reports the main magnetic parameters like saturation magnetization (Ms), coercivity (Hc) were found to decrease with the substitution of Cr3+ content. Possible mechanisms which are responsible for the results are scrutinized minutely in this paper.
{"title":"Structural and Magnetic Properties of Cr-Co Nanoferrite Particles","authors":"Mamilla Lakshmi, K. Kumar, K. Thyagarajan","doi":"10.4236/ANP.2016.51012","DOIUrl":"https://doi.org/10.4236/ANP.2016.51012","url":null,"abstract":"Nano-crystalline CrxCoFe2–xO4 (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) ferrites were synthesized by sol-gel method. The X-ray diffraction patterns of all the samples provide information about the existence of single phase spinel structure. The SEM and TEM micrographs show the uniform particle distribution and SAED pattern represents the polycrystalline nature of the resultant ferrite nano-particles. High purity of the sample is confirmed by energy dispersive X-ray analysis. The FTIR spectra show two strong absorption bands in the range of 600 - 400 cm–1, which confirm the presence of M-O stretching band in ferrites. The magnetic properties of the synthesized samples were investigated by using vibrating sample magnetometer at room temperature. According to VSM reports the main magnetic parameters like saturation magnetization (Ms), coercivity (Hc) were found to decrease with the substitution of Cr3+ content. Possible mechanisms which are responsible for the results are scrutinized minutely in this paper.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"5 1","pages":"103-113"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mimusops elengi (Maulsari) is a medicinal plant (showing; antioxidant, antimycotic, antidiabetic, analgesic activity, etc.). Conventional UV-visible spectrophotometric technique in the presence of CTAB and transmission electron microscopic technique both in the presence and absence of CTAB were used to determine the morphology of silver nanoplates (AgNP) using Mimusops elengi (Maulsari) aqueous leaves extract for the first time. Cetyltrimethylammonium bromide (CTAB) has no significant effect on the shape of the spectra and position of SPR bands. Effects of various CTAB were also discussed in the green extra-cellular synthesis of AgNP using Mimusops elengi (Maulsari) leaves extract.
{"title":"Role of Cetyltrimethylammonium Bromide in the Green Synthesis of Silver Nanoparticles Using Mimusops elengi , Linn. (Maulsari) Leaf Extract","authors":"R. Ahmad, Sajjad Hussain Parrey, Q. Faisal","doi":"10.4236/ANP.2016.51005","DOIUrl":"https://doi.org/10.4236/ANP.2016.51005","url":null,"abstract":"Mimusops elengi (Maulsari) is a medicinal plant (showing; antioxidant, antimycotic, antidiabetic, analgesic activity, etc.). Conventional UV-visible spectrophotometric technique in the presence of CTAB and transmission electron microscopic technique both in the presence and absence of CTAB were used to determine the morphology of silver nanoplates (AgNP) using Mimusops elengi (Maulsari) aqueous leaves extract for the first time. Cetyltrimethylammonium bromide (CTAB) has no significant effect on the shape of the spectra and position of SPR bands. Effects of various CTAB were also discussed in the green extra-cellular synthesis of AgNP using Mimusops elengi (Maulsari) leaves extract.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"327 1","pages":"44-52"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Precursor foam based Co incorporated α-Fe2O3 (AFC) was successfully synthesized at 600℃ calcination temperature by simple solution method using PVA. The formation of α-Fe2O3 nanoparticles was confirmed by X-ray diffraction measurement and reduction in crystallite size was found after cobalt incorporation. Field emission scanning electron microscopy revealed the existence of pyramidal shaped iron oxide in AFC. FTIR and Raman spectra also confirmed the presence of α-Fe2O3. Photocatalytic activity study showed that the cobalt incorporated α-Fe2O3 was better photocatalyst than pure α-Fe2O3. The cobalt incorporated iron oxide nanoparticles could be used for drug delivery application and this simple preparation method could be adopted for the synthesis of other transition metal oxides.
{"title":"Cobalt Incorporated Pyramidal Shaped α -Fe 2 O 3 Nanoparticles from Poly-vinyl Alcohol Based Precursor","authors":"A. Naskar, S. Bera, A. Mallik, S. Jana","doi":"10.4236/ANP.2016.51002","DOIUrl":"https://doi.org/10.4236/ANP.2016.51002","url":null,"abstract":"Precursor foam based Co incorporated α-Fe2O3 (AFC) was successfully synthesized at 600℃ calcination temperature by simple solution method using PVA. The formation of α-Fe2O3 nanoparticles was confirmed by X-ray diffraction measurement and reduction in crystallite size was found after cobalt incorporation. Field emission scanning electron microscopy revealed the existence of pyramidal shaped iron oxide in AFC. FTIR and Raman spectra also confirmed the presence of α-Fe2O3. Photocatalytic activity study showed that the cobalt incorporated α-Fe2O3 was better photocatalyst than pure α-Fe2O3. The cobalt incorporated iron oxide nanoparticles could be used for drug delivery application and this simple preparation method could be adopted for the synthesis of other transition metal oxides.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"05 1","pages":"9-17"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this report, a new nanocomposite based on chitosan/polyvinyl alcohol/nanocrystalline cellulose (Cts/PVA/NCC) was synthesized. The morphology and particle size of NCC and nanocomposites were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD) analysis and Fourier transform infrared (FT-IR) spectroscopy. According to XRD results, the size of NCC was found to be at the range of 15 - 17 nm. SEM images showed the rod-like shape of NCC whiskers. Finally, biodegradation and swelling studies were performed on Cts/PVA/NCC nanocomposites.
{"title":"Synthesis and Characterization of New Biodegradable Chitosan/Polyvinyl Alcohol/Cellulose Nanocomposite","authors":"A. Samzadeh‐Kermani, Negin Esfandiary","doi":"10.4236/ANP.2016.51003","DOIUrl":"https://doi.org/10.4236/ANP.2016.51003","url":null,"abstract":"In this report, a new nanocomposite based on chitosan/polyvinyl alcohol/nanocrystalline cellulose (Cts/PVA/NCC) was synthesized. The morphology and particle size of NCC and nanocomposites were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD) analysis and Fourier transform infrared (FT-IR) spectroscopy. According to XRD results, the size of NCC was found to be at the range of 15 - 17 nm. SEM images showed the rod-like shape of NCC whiskers. Finally, biodegradation and swelling studies were performed on Cts/PVA/NCC nanocomposites.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"61 1","pages":"18-26"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Chitturi, Aparna Yaramma, Ramchander Merugu, Ravinder Dachepalli, Jaipal Kandhadi
Exploitation of green chemistry approach for the synthesis of Indium Oxide nanoparticles using green synthesis has received a great attention in the field of nanotechnology. To demonstrate a biogenic method that involves the Katira gum (Astragalus gummifer) leading to the formation of different morphological In2O3 using the precursor Indium (III) Acetylacetonate and TG-DTA is characterised for calcination temperature and it is found to be above 500℃. Different techniques such as XRD, UV-VIS, SEM and EDAX have been used for the characterisation of In2O3 nanoparticles. The average crystallite size of Indiumoxide nanoparticles is determined as 19 nm by using Scherrer’s Equation and PSA and studying optical properties.
{"title":"Synthesis and Characterisation of In 2 O 3 Na-noparticles from Astragalus gummifer","authors":"K. Chitturi, Aparna Yaramma, Ramchander Merugu, Ravinder Dachepalli, Jaipal Kandhadi","doi":"10.4236/ANP.2016.51013","DOIUrl":"https://doi.org/10.4236/ANP.2016.51013","url":null,"abstract":"Exploitation of green chemistry approach for the synthesis of Indium Oxide nanoparticles using green synthesis has received a great attention in the field of nanotechnology. To demonstrate a biogenic method that involves the Katira gum (Astragalus gummifer) leading to the formation of different morphological In2O3 using the precursor Indium (III) Acetylacetonate and TG-DTA is characterised for calcination temperature and it is found to be above 500℃. Different techniques such as XRD, UV-VIS, SEM and EDAX have been used for the characterisation of In2O3 nanoparticles. The average crystallite size of Indiumoxide nanoparticles is determined as 19 nm by using Scherrer’s Equation and PSA and studying optical properties.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"05 1","pages":"114-122"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the present work Pure and Cobalt (Co) doped Zinc Oxide (ZnO) Nanoparticles were synthesized by Sol-gel method. The effect of Co doping on structural and optical properties of Nanoparticles were investigated using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) spectroscopic characterization techniques. The XRD spectrum revealed the formation of Wurtzite structure of ZnO. The structural properties of nanoparticles including particle size and lattice strain were calculated from XRD data. SEM shows the morphology of Nanoparticles. The presence of functional groups was analyzed from FTIR spectra. The properties of Cobalt doped zinc oxide nanoparticles prepared through simple cost effective, Sol-gel method can be used in optoelectronics and thermally stable devices.
{"title":"Effect of Co Doping on Structural and Optical Properties of Zinc Oxide Nanoparticles Synthesized by Sol-Gel Method","authors":"A. Vanaja, K. Rao","doi":"10.4236/ANP.2016.51010","DOIUrl":"https://doi.org/10.4236/ANP.2016.51010","url":null,"abstract":"In the present work Pure and Cobalt (Co) doped Zinc Oxide (ZnO) Nanoparticles were synthesized by Sol-gel method. The effect of Co doping on structural and optical properties of Nanoparticles were investigated using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) spectroscopic characterization techniques. The XRD spectrum revealed the formation of Wurtzite structure of ZnO. The structural properties of nanoparticles including particle size and lattice strain were calculated from XRD data. SEM shows the morphology of Nanoparticles. The presence of functional groups was analyzed from FTIR spectra. The properties of Cobalt doped zinc oxide nanoparticles prepared through simple cost effective, Sol-gel method can be used in optoelectronics and thermally stable devices.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"5 1","pages":"83-89"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
We analyse the influence of Brownian motion and thermophoresis on a nonlinearly permeable stretching sheet in a nanofluid. The governing partial differential equations are reduced into a system of ordinary differential equations using similarity transformation and then solved numerically using the Runge-Kutta with shooting technique. Effects of Brownian motion and thermophoresis on the flow, concentration, temperature, and mass transfer and heat transfer characteristics are investigated. The local Nusselt number and the local Sherwood numbers are presented and compared with existing results and are found to be in good agreement.
{"title":"Effect of Brownian Motion and Thermophoresis on a Nonlinearly Stretching Permeable Sheet in a Nanofluid","authors":"A. Falana, O. A. Ojewale, T. B. Adeboje","doi":"10.4236/ANP.2016.51014","DOIUrl":"https://doi.org/10.4236/ANP.2016.51014","url":null,"abstract":"We analyse the influence of Brownian motion and thermophoresis on a nonlinearly permeable stretching sheet in a nanofluid. The governing partial differential equations are reduced into a system of ordinary differential equations using similarity transformation and then solved numerically using the Runge-Kutta with shooting technique. Effects of Brownian motion and thermophoresis on the flow, concentration, temperature, and mass transfer and heat transfer characteristics are investigated. The local Nusselt number and the local Sherwood numbers are presented and compared with existing results and are found to be in good agreement.","PeriodicalId":71264,"journal":{"name":"纳米粒子(英文)","volume":"449 1","pages":"123-134"},"PeriodicalIF":0.0,"publicationDate":"2016-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70338220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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