Pub Date : 2024-07-01DOI: 10.1007/s12274-024-6789-9
Ziyang Huang, Zhenghua Wang, Lei Zhou, Jun Pu
Lithium-sulfur (Li-S) batteries hold the potential to revolutionize energy storage due to the high theoretical capacity and energy density. However, the commercialization process is seriously hindered by the rapid capacity decay and low utilization of sulfur, caused by the inevitable slow dynamics and the “shuttle effect”. The incorporation of metal-based electrocatalysts into sulfur cathodes shows promise in promoting the conversion of lithium polysulfides (LiPSs), reducing the “shuttle effect”, and enhancing cell kinetics and cycle life. Among these, Fe-based materials, characterized by environmental friendliness, low cost, abundant reserves, and high activity, are extensively used in sulfur cathode modification. This article reviews the advancements of Fe-based materials in enhancing Li-S batteries in recent years. Starting from single/multi-component Fe-based metal compounds and single/bimetallic atoms, the influence of different Fe coordination environments on the conversion mechanism of LiPSs is analyzed. It is hoped that this review and the proposed prospects can further stimulate the development and application of the Fe element in Li-S batteries in the future.
{"title":"Research progress in performance improvement strategies and sulfur conversion mechanisms of Li-S batteries based on Fe series nanomaterials","authors":"Ziyang Huang, Zhenghua Wang, Lei Zhou, Jun Pu","doi":"10.1007/s12274-024-6789-9","DOIUrl":"https://doi.org/10.1007/s12274-024-6789-9","url":null,"abstract":"<p>Lithium-sulfur (Li-S) batteries hold the potential to revolutionize energy storage due to the high theoretical capacity and energy density. However, the commercialization process is seriously hindered by the rapid capacity decay and low utilization of sulfur, caused by the inevitable slow dynamics and the “shuttle effect”. The incorporation of metal-based electrocatalysts into sulfur cathodes shows promise in promoting the conversion of lithium polysulfides (LiPSs), reducing the “shuttle effect”, and enhancing cell kinetics and cycle life. Among these, Fe-based materials, characterized by environmental friendliness, low cost, abundant reserves, and high activity, are extensively used in sulfur cathode modification. This article reviews the advancements of Fe-based materials in enhancing Li-S batteries in recent years. Starting from single/multi-component Fe-based metal compounds and single/bimetallic atoms, the influence of different Fe coordination environments on the conversion mechanism of LiPSs is analyzed. It is hoped that this review and the proposed prospects can further stimulate the development and application of the Fe element in Li-S batteries in the future.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1007/s12274-024-6762-7
Yanming Wang, Junrong Zhang, Tianhua Ren, Meng Xia, Long Fang, Xiangyi Wang, Xingwang Zhang, Kai Zhang, Junyong Wang
Electrical modulation of luminescence is significant to modern light-emitting devices. Monolayer transition metal dichalcogenides are emerging direct-bandgap luminescent materials with unique excitonic properties, and the multiple exciton complexes provide new opportunities to modulate the property of luminescence in atomically thin semiconductors. Here, we report an electrical control of exciton emission in the oscillator strength and spatial distribution of excitons in a monolayer WS2. Effective modulation of excitonic emission intensity with a degree of modulation of ~ 92% has been demonstrated by an electric field at room temperature. The spatial carrier redistribution tuned by a lateral electric field results in distinct excitonic emission patterns by design. The modulation approach to exciton oscillator strength and distribution provides an efficient way to investigate the exciton diffusion dynamics and to construct electrically tunable optoelectronic devices.
{"title":"Electrical control of excitonic oscillator strength and spatial distribution in a monolayer semiconductor","authors":"Yanming Wang, Junrong Zhang, Tianhua Ren, Meng Xia, Long Fang, Xiangyi Wang, Xingwang Zhang, Kai Zhang, Junyong Wang","doi":"10.1007/s12274-024-6762-7","DOIUrl":"https://doi.org/10.1007/s12274-024-6762-7","url":null,"abstract":"<p>Electrical modulation of luminescence is significant to modern light-emitting devices. Monolayer transition metal dichalcogenides are emerging direct-bandgap luminescent materials with unique excitonic properties, and the multiple exciton complexes provide new opportunities to modulate the property of luminescence in atomically thin semiconductors. Here, we report an electrical control of exciton emission in the oscillator strength and spatial distribution of excitons in a monolayer WS<sub>2</sub>. Effective modulation of excitonic emission intensity with a degree of modulation of ~ 92% has been demonstrated by an electric field at room temperature. The spatial carrier redistribution tuned by a lateral electric field results in distinct excitonic emission patterns by design. The modulation approach to exciton oscillator strength and distribution provides an efficient way to investigate the exciton diffusion dynamics and to construct electrically tunable optoelectronic devices.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Iron–nitrogen–carbon single-atom catalysts (Fe–N–C SACs) are widely acknowledged for their effective oxygen reduction activity, however, their activity requires further enhancement. Meanwhile, additional structural optimization is necessary to enhance mass transport and achieve higher power density in practical applications. Herein, using ZIF-8 as a template, we synthesized yolk–shell catalysts featuring complex sites of Fe single atoms and Cu nanoclusters (y-FeCu/NC) via partial etching and liquid-phase loading. The synthesized y-FeCu/NC catalyst exhibits high specific surface area and mesoporous volume. Combined with the advantages of highly active sites and yolk–shell structure, the y-FeCu/NC catalyst demonstrated outstanding catalytic performance in the oxygen reduction reaction, achieving a half-wave potential (E1/2) of 0.97 V in 0.1 M KOH. As a practical energy device, Zn-air battery (ZAB) assembled with y-FeCu/NC catalyst achieved a remarkable power density of 356.3 mW·cm−2, representing an improvement of approximately 28.5% compared to its solid FeCu/NC counterpart. Furthermore, it showcased impressive stability, surpassing all control samples.
{"title":"Yolk–shell FeCu/NC electrocatalyst boosting high-performance zinc-air battery","authors":"Chen Liang, Tianyu Zhang, Shilun Sun, Aijuan Han, Zenghui Qiu, Haijun Xu, Junfeng Liu","doi":"10.1007/s12274-024-6766-3","DOIUrl":"https://doi.org/10.1007/s12274-024-6766-3","url":null,"abstract":"<p>Iron–nitrogen–carbon single-atom catalysts (Fe–N–C SACs) are widely acknowledged for their effective oxygen reduction activity, however, their activity requires further enhancement. Meanwhile, additional structural optimization is necessary to enhance mass transport and achieve higher power density in practical applications. Herein, using ZIF-8 as a template, we synthesized yolk–shell catalysts featuring complex sites of Fe single atoms and Cu nanoclusters (y-FeCu/NC) via partial etching and liquid-phase loading. The synthesized y-FeCu/NC catalyst exhibits high specific surface area and mesoporous volume. Combined with the advantages of highly active sites and yolk–shell structure, the y-FeCu/NC catalyst demonstrated outstanding catalytic performance in the oxygen reduction reaction, achieving a half-wave potential (<i>E</i><sub>1/2</sub>) of 0.97 V in 0.1 M KOH. As a practical energy device, Zn-air battery (ZAB) assembled with y-FeCu/NC catalyst achieved a remarkable power density of 356.3 mW·cm<sup>−2</sup>, representing an improvement of approximately 28.5% compared to its solid FeCu/NC counterpart. Furthermore, it showcased impressive stability, surpassing all control samples.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Covalent triazine frameworks (CTFs) are a class of unique two-dimensional nitrogen-rich triazine framework with adjustable chemical and electronic structures, rich porosity, good stability and excellent semiconductivity, which enable great various applications in efficient gas/molecular adsorption and separation, energy storage and conversion, especially photo- and electro-catalysis. Different synthesis strategies strongly affect the morphology of CTFs and play an important role in their structure and properties. In this concept, we provide a comprehensive and systematic review of the synthesis methods such as ionothermal synthesis, phosphorus pentoxide catalytic method, polycondensation and ultra-strong acid catalyzed method, and applications of CTFs in photo- and electro-catalysis. Finally we offer some insights into the future development progress of CTFs materials for catalytic applications.
{"title":"Covalent triazine frameworks materials for photo- and electro-catalysis","authors":"Aoji Liang, Wenbin Li, Anbai Li, Hui Peng, Guofu Ma, Lei Zhu, Ziqiang Lei, Yuxi Xu","doi":"10.1007/s12274-024-6779-y","DOIUrl":"https://doi.org/10.1007/s12274-024-6779-y","url":null,"abstract":"<p>Covalent triazine frameworks (CTFs) are a class of unique two-dimensional nitrogen-rich triazine framework with adjustable chemical and electronic structures, rich porosity, good stability and excellent semiconductivity, which enable great various applications in efficient gas/molecular adsorption and separation, energy storage and conversion, especially photo- and electro-catalysis. Different synthesis strategies strongly affect the morphology of CTFs and play an important role in their structure and properties. In this concept, we provide a comprehensive and systematic review of the synthesis methods such as ionothermal synthesis, phosphorus pentoxide catalytic method, polycondensation and ultra-strong acid catalyzed method, and applications of CTFs in photo- and electro-catalysis. Finally we offer some insights into the future development progress of CTFs materials for catalytic applications.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141505785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
As a new water treatment technology, Fenton-like reaction has great potential. In this study, we successfully prepared an excellent Fenton-like catalyst, which is composed of cobalt monoatoms and asymmetric subnanoclusters (labeled CoSA/Clu-C2N), and exhibits excellent peroxymonosulfate (PMS) activation reactivity. By directly comparing the catalytic properties of CoSA-C2N and CoSA/Clu-C2N, the synergistic effects of coasymmetric Co subclusters and Co atoms on the activation of PMS and degradation of organic micropollutants were investigated. The results showed that CoSA/Clu-C2N had higher degradation rates of carbamazepine (CBZ), antipyrine (AT) and chlorobenzoic acid (CA) when combined with active oxidant PMS. The cyclic frequency of CBZ was 5.4 min−1, which was twice as high as the catalytic constant of CoSA-C2N (2.4 min−1). The results show that CoSA/Clu-C2N cobalt subnanoclusters and cobalt single atom can synergistically improve the catalytic performance of activated PMS oxidation of micropollutants in water. In addition, electron paramagnetic resonance (EPR) technology has proved that the introduction of Co subnano clusters in CoSA/Clu-C2N is conducive to the production of singlet oxygen (1O2), thereby improving the efficiency of pollutant oxidation. This work lays a solid foundation for the future design of advanced multifunctional catalysts by carefully regulating and combining monmetallic atoms and metal subnanoclusters.
{"title":"Synergy enhancement of Co single atoms and asymmetric subnanoclusters for Fenton-like activation","authors":"Ming Ma, Zhiyi Sun, Ziwei Deng, Xiang Li, Fang Zhang, Wenxing Chen","doi":"10.1007/s12274-024-6792-1","DOIUrl":"https://doi.org/10.1007/s12274-024-6792-1","url":null,"abstract":"<p>As a new water treatment technology, Fenton-like reaction has great potential. In this study, we successfully prepared an excellent Fenton-like catalyst, which is composed of cobalt monoatoms and asymmetric subnanoclusters (labeled CoSA/Clu-C<sub>2</sub>N), and exhibits excellent peroxymonosulfate (PMS) activation reactivity. By directly comparing the catalytic properties of CoSA-C<sub>2</sub>N and CoSA/Clu-C<sub>2</sub>N, the synergistic effects of coasymmetric Co subclusters and Co atoms on the activation of PMS and degradation of organic micropollutants were investigated. The results showed that CoSA/Clu-C<sub>2</sub>N had higher degradation rates of carbamazepine (CBZ), antipyrine (AT) and chlorobenzoic acid (CA) when combined with active oxidant PMS. The cyclic frequency of CBZ was 5.4 min<sup>−1</sup>, which was twice as high as the catalytic constant of CoSA-C<sub>2</sub>N (2.4 min<sup>−1</sup>). The results show that CoSA/Clu-C<sub>2</sub>N cobalt subnanoclusters and cobalt single atom can synergistically improve the catalytic performance of activated PMS oxidation of micropollutants in water. In addition, electron paramagnetic resonance (EPR) technology has proved that the introduction of Co subnano clusters in CoSA/Clu-C<sub>2</sub>N is conducive to the production of singlet oxygen (<sup>1</sup>O<sub>2</sub>), thereby improving the efficiency of pollutant oxidation. This work lays a solid foundation for the future design of advanced multifunctional catalysts by carefully regulating and combining monmetallic atoms and metal subnanoclusters.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-27DOI: 10.1007/s12274-024-6781-4
Han Gao, ChunLian Zhan, Tianqi Zhao, Jianzhong Zheng
Optical materials with circularly polarized luminescence (CPL) features have attracted a growing interest due to their crucial role in biological sensing, display, spintronics, information storage, and so forth. However, CPL emissions in hybrid nanoparticle systems, in particular, chirality transfer induced CPL from chiral plasmonic nanoparticles, have rarely been explored due to a lack of effective bottom-up synthesis method. Herein, we creatively take advantage of the newly introduced chiral plasmonic nanoparticles-gold nanohelicoid (GNH) to excite the CPL of achiral Rhodamine 6G (R6G). The fabricated GNH@R6G-SiO2 shows obvious CPL signals with ∣glum∣ up to 0.014. Compared with the single GNH, the photoluminescence (PL) dissymmetry factor of the single GNH@R6G-SiO2 is similar, but with 25 folds higher PL intensities under different circular polarization. Our research not only offers an effective and feasible method to fabricate single-particle level CPL-active materials, but also provides guidelines on how to regulate the CPL of achiral luminophores from chiral plasmonic nanostructures, thereby enlarging the category and quantity of CPL-active materials that can be applied for photonic technologies and visualization biosensing, especially some intracellular chirality related detection.
{"title":"Chirality transfer induced circularly polarized luminescence of achiral dye molecules by plasmonic nanohelicoid","authors":"Han Gao, ChunLian Zhan, Tianqi Zhao, Jianzhong Zheng","doi":"10.1007/s12274-024-6781-4","DOIUrl":"https://doi.org/10.1007/s12274-024-6781-4","url":null,"abstract":"<p>Optical materials with circularly polarized luminescence (CPL) features have attracted a growing interest due to their crucial role in biological sensing, display, spintronics, information storage, and so forth. However, CPL emissions in hybrid nanoparticle systems, in particular, chirality transfer induced CPL from chiral plasmonic nanoparticles, have rarely been explored due to a lack of effective bottom-up synthesis method. Herein, we creatively take advantage of the newly introduced chiral plasmonic nanoparticles-gold nanohelicoid (GNH) to excite the CPL of achiral Rhodamine 6G (R6G). The fabricated GNH@R6G-SiO<sub>2</sub> shows obvious CPL signals with ∣<i>g</i><sub>lum</sub>∣ up to 0.014. Compared with the single GNH, the photoluminescence (PL) dissymmetry factor of the single GNH@R6G-SiO<sub>2</sub> is similar, but with 25 folds higher PL intensities under different circular polarization. Our research not only offers an effective and feasible method to fabricate single-particle level CPL-active materials, but also provides guidelines on how to regulate the CPL of achiral luminophores from chiral plasmonic nanostructures, thereby enlarging the category and quantity of CPL-active materials that can be applied for photonic technologies and visualization biosensing, especially some intracellular chirality related detection.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
With the continuous tightening of automotive emission regulations and the increasing promotion of energy-efficient hybrid vehicles, new challenges have arisen for the low-temperature performance of three-way catalysts (TWCs). To guide the design of next-generation TWCs, it is essential to further develop our understanding of the relationships between microstructure and catalytic performance. Here, Rh/CeO2–ZrO2 catalysts were synthesized with different Rh metal dispersion by using a combination of the wet impregnation method and reduction treatment. These catalysts included Rh single-atom catalysts, cluster catalysts, and nanoparticle catalysts. The results showed that the Rh nanoparticle catalyst, with an average size of 1.9 nm, exhibited superior three-way catalytic performance compared to the other catalysts. Based on the catalytic activity in a series of simple reaction atmospheres such as CO + O2, NO + CO, and hydrocarbons (HCs) + O2 and operando infrared spectroscopy, we found that metallic Rh sites on Rh nanoparticles are the key factor responsible for the low-temperature catalytic performance.
{"title":"The structure–activity relationships of Rh/CeO2–ZrO2 catalysts based on Rh metal size effect in the three-way catalytic reactions","authors":"Dongming Chen, Weixin Zhao, Zihao Xu, Zheng Zhao, Juanyu Yang, Yongke Hou, Yongqi Zhang, Zongyu Feng, Meisheng Cui, Xiaowei Huang","doi":"10.1007/s12274-024-6643-0","DOIUrl":"https://doi.org/10.1007/s12274-024-6643-0","url":null,"abstract":"<p>With the continuous tightening of automotive emission regulations and the increasing promotion of energy-efficient hybrid vehicles, new challenges have arisen for the low-temperature performance of three-way catalysts (TWCs). To guide the design of next-generation TWCs, it is essential to further develop our understanding of the relationships between microstructure and catalytic performance. Here, Rh/CeO<sub>2</sub>–ZrO<sub>2</sub> catalysts were synthesized with different Rh metal dispersion by using a combination of the wet impregnation method and reduction treatment. These catalysts included Rh single-atom catalysts, cluster catalysts, and nanoparticle catalysts. The results showed that the Rh nanoparticle catalyst, with an average size of 1.9 nm, exhibited superior three-way catalytic performance compared to the other catalysts. Based on the catalytic activity in a series of simple reaction atmospheres such as CO + O<sub>2</sub>, NO + CO, and hydrocarbons (HCs) + O<sub>2</sub> and <i>operando</i> infrared spectroscopy, we found that metallic Rh sites on Rh nanoparticles are the key factor responsible for the low-temperature catalytic performance.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141531984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To improve the synergistic effect between dielectric and magnetic loss is a practical and effective way in optimizing electromagnetic wave absorbing materials. The composites of metal particles and carbon ligands derived from metal organic frameworks have gained wide attention. In this study, Co particles and multiwalled carbon nanotubes (CNT) were successfully synthesized covering the surface of silicon carbide (SiC) fibers, and the morphology, interfaces and electromagnetic wave absorption performance were explored. For sample SiC@Co/CNT, the minimum reflection loss value can reach -70.22 dB at 11.21 GHz with the thickness of 2.12 mm. The effective absorbing bandwidth can reach up to 6.03 GHz with the thickness of 1.71 mm, which covers the entire Ku band. It brings more interfaces between Co particles and CNTs as well as SiC fibers and Co/C nanosheets. The interfacial polarization has been hugely enhanced, and the microwave absorbing properties have been improved. This article reports on the impedance matching of magnetic and non-magnetic components and the heterointerface engineering, which can be effective strategy and inspiration to illustrate the relationship between components, structures and functions of electromagnetic wave absorbing materials.
提高介电损耗和磁损耗之间的协同效应是优化电磁波吸收材料的一种实用而有效的方法。由金属有机框架衍生的金属颗粒与碳配体的复合材料受到广泛关注。本研究成功合成了覆盖在碳化硅(SiC)纤维表面的 Co 粒子和多壁碳纳米管(CNT),并对其形貌、界面和电磁波吸收性能进行了探讨。对于厚度为 2.12 mm 的 SiC@Co/CNT 样品,在 11.21 GHz 频率下的最小反射损耗值可达 -70.22 dB。厚度为 1.71 mm 时,有效吸收带宽可达 6.03 GHz,覆盖了整个 Ku 波段。它为 Co 粒子和 CNT 以及 SiC 纤维和 Co/C 纳米片之间带来了更多的界面。界面极化大大增强,微波吸收性能也得到改善。本文报告了磁性和非磁性元件的阻抗匹配以及异界面工程,这对于说明电磁波吸收材料的元件、结构和功能之间的关系是一种有效的策略和启发。
{"title":"Synergistic effect and heterointerface engineering of cobalt/carbon nanotubes enhancing electromagnetic wave absorbing properties of silicon carbide fibers","authors":"Zixiang Zhao, Zheyipei Ma, Zizhao Ding, Yanqiong Liu, Mingwei Zhang, Chao Jiang","doi":"10.1007/s12274-024-6780-5","DOIUrl":"https://doi.org/10.1007/s12274-024-6780-5","url":null,"abstract":"<p>To improve the synergistic effect between dielectric and magnetic loss is a practical and effective way in optimizing electromagnetic wave absorbing materials. The composites of metal particles and carbon ligands derived from metal organic frameworks have gained wide attention. In this study, Co particles and multiwalled carbon nanotubes (CNT) were successfully synthesized covering the surface of silicon carbide (SiC) fibers, and the morphology, interfaces and electromagnetic wave absorption performance were explored. For sample SiC@Co/CNT, the minimum reflection loss value can reach -70.22 dB at 11.21 GHz with the thickness of 2.12 mm. The effective absorbing bandwidth can reach up to 6.03 GHz with the thickness of 1.71 mm, which covers the entire Ku band. It brings more interfaces between Co particles and CNTs as well as SiC fibers and Co/C nanosheets. The interfacial polarization has been hugely enhanced, and the microwave absorbing properties have been improved. This article reports on the impedance matching of magnetic and non-magnetic components and the heterointerface engineering, which can be effective strategy and inspiration to illustrate the relationship between components, structures and functions of electromagnetic wave absorbing materials.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-27DOI: 10.1007/s12274-024-6683-5
Xiaoyuan Ji, Binbin Chu, Xiaofeng Wu, Zhiming Xia, Airui Jiang, Chenyu Wang, Zhiming Chen, Danni Zhong, Qiaolin Wei, Bin Song, Wanlin Li, Yiling Zhong, Houyu Wang, Fenglin Dong, Min Zhou, Yao He
Despite sufficient studies performed in non-primate animal models, there exists scanty information obtained from pilot trials in non-human primate animal models, severely hindering nanomaterials moving from basic research into clinical practice. We herein present a pioneering demonstration of nanomaterials based optical imaging-guided surgical operation by using macaques as a typical kind of non-human primate-animal models. Typically, taking advantages of strong and stable fluorescence of the small-sized (diameter: ~ 5 nm) silicon-based nanoparticles (SiNPs), lymphatic drainage patterns can be vividly visualized in a real-time manner, and lymph nodes (LN) are able to be sensitively detected and precisely excised from small animal models (e.g., rats and rabbits) to non-human primate animal models (e.g., cynomolgus macaque (Macaca fascicularis) and rhesus macaque (Macaca mulatta)). Compared to clinically used invisible near-infrared (NIR) lymphatic tracers (i.e., indocyanine green (ICG); etc.), we fully indicate that the SiNPs feature unique advantages for naked-eye visible fluorescence-guided surgical operation in long-term manners. Thorough toxicological analysis in macaque models further provides confirming evidence of favorable biocompatibility of the SiNPs probes. We expect that our findings would facilitate the translation of nanomaterials from the laboratory to the clinic, especially in the field of cancer treatment.
{"title":"Naked-eye visualization of lymph nodes using fluorescence nanoprobes in non-human primate-animal models","authors":"Xiaoyuan Ji, Binbin Chu, Xiaofeng Wu, Zhiming Xia, Airui Jiang, Chenyu Wang, Zhiming Chen, Danni Zhong, Qiaolin Wei, Bin Song, Wanlin Li, Yiling Zhong, Houyu Wang, Fenglin Dong, Min Zhou, Yao He","doi":"10.1007/s12274-024-6683-5","DOIUrl":"https://doi.org/10.1007/s12274-024-6683-5","url":null,"abstract":"<p>Despite sufficient studies performed in non-primate animal models, there exists scanty information obtained from pilot trials in non-human primate animal models, severely hindering nanomaterials moving from basic research into clinical practice. We herein present a pioneering demonstration of nanomaterials based optical imaging-guided surgical operation by using macaques as a typical kind of non-human primate-animal models. Typically, taking advantages of strong and stable fluorescence of the small-sized (diameter: ~ 5 nm) silicon-based nanoparticles (SiNPs), lymphatic drainage patterns can be vividly visualized in a real-time manner, and lymph nodes (LN) are able to be sensitively detected and precisely excised from small animal models (e.g., rats and rabbits) to non-human primate animal models (e.g., <i>cynomolgus macaque</i> (<i>Macaca fascicularis</i>) and <i>rhesus macaque</i> (<i>Macaca mulatta</i>)). Compared to clinically used invisible near-infrared (NIR) lymphatic tracers (i.e., indocyanine green (ICG); etc.), we fully indicate that the SiNPs feature unique advantages for naked-eye visible fluorescence-guided surgical operation in long-term manners. Thorough toxicological analysis in macaque models further provides confirming evidence of favorable biocompatibility of the SiNPs probes. We expect that our findings would facilitate the translation of nanomaterials from the laboratory to the clinic, especially in the field of cancer treatment.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-27DOI: 10.1007/s12274-024-6747-6
Jingyue Yan, Diana D. Kang, Chang Wang, Xucheng Hou, Shi Du, Siyu Wang, Yonger Xue, Zhengwei Liu, Haoyuan Li, Yichen Zhong, Binbin Deng, David W. McComb, Yizhou Dong
Activated fibroblasts are major mediators of pulmonary fibrosis. Fibroblasts are generally found in the connective tissue but upon activation can generate excess extracellular matrix (ECM) in the lung interstitial section. Therefore, fibroblasts are one of the most targeted cells for treating idiopathic pulmonary fibrosis (IPF). Here, we develop an anti-fibrotic platform that can modulate both the lysophosphatidic acid receptor 1 (LPA1) and the inflammatory pathway through tumor necrosis factor α-induced protein 3 (TNFAIP3, also known as A20) in fibroblasts. First, we synthesized a series of LPA1 antagonists, AM095 and AM966, derived amino lipids (LA lipids) which were formulated into LA-lipid nanoparticles (LA-LNPs) encapsulating mRNA. Specifically, LA5-LNPs, with AM966 head group and biodegradable acetal lipid tails, showed efficient A20 mRNA delivery to lung fibroblasts in vitro (80.2% ± 1.5%) and ex vivo (17.2% ± 0.4%). When treated to primary mouse lung fibroblasts (MLF), this formulation inhibited fibroblast migration and collagen production, thereby slowing the progression of IPF. Overall, LA5-LNPs encapsulated with A20 mRNA is a novel platform offering a potential approach to regulate fibroblast activation for the treatment of IPF.
{"title":"LPA1 antagonist-derived LNPs deliver A20 mRNA and promote anti-fibrotic activities","authors":"Jingyue Yan, Diana D. Kang, Chang Wang, Xucheng Hou, Shi Du, Siyu Wang, Yonger Xue, Zhengwei Liu, Haoyuan Li, Yichen Zhong, Binbin Deng, David W. McComb, Yizhou Dong","doi":"10.1007/s12274-024-6747-6","DOIUrl":"https://doi.org/10.1007/s12274-024-6747-6","url":null,"abstract":"<p>Activated fibroblasts are major mediators of pulmonary fibrosis. Fibroblasts are generally found in the connective tissue but upon activation can generate excess extracellular matrix (ECM) in the lung interstitial section. Therefore, fibroblasts are one of the most targeted cells for treating idiopathic pulmonary fibrosis (IPF). Here, we develop an anti-fibrotic platform that can modulate both the lysophosphatidic acid receptor 1 (LPA<sub>1</sub>) and the inflammatory pathway through tumor necrosis factor <i>α</i>-induced protein 3 (TNFAIP3, also known as A20) in fibroblasts. First, we synthesized a series of LPA<sub>1</sub> antagonists, AM095 and AM966, derived amino lipids (LA lipids) which were formulated into LA-lipid nanoparticles (LA-LNPs) encapsulating mRNA. Specifically, LA5-LNPs, with AM966 head group and biodegradable acetal lipid tails, showed efficient A20 mRNA delivery to lung fibroblasts <i>in vitro</i> (80.2% ± 1.5%) and <i>ex vivo</i> (17.2% ± 0.4%). When treated to primary mouse lung fibroblasts (MLF), this formulation inhibited fibroblast migration and collagen production, thereby slowing the progression of IPF. Overall, LA5-LNPs encapsulated with A20 mRNA is a novel platform offering a potential approach to regulate fibroblast activation for the treatment of IPF.\u0000</p>","PeriodicalId":713,"journal":{"name":"Nano Research","volume":null,"pages":null},"PeriodicalIF":9.9,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}