Pub Date : 2024-07-23DOI: 10.1021/acsfoodscitech.4c0029910.1021/acsfoodscitech.4c00299
Elkin Rojas-Orduña, María Hernández-Carrión and Andrea del Pilar Sánchez-Camargo*,
In this study, the untapped potential of coffee byproducts, specifically carotenoids present in coffee pulp, was explored. Using a Box–Behnken response surface design, microwave-assisted extraction conditions were optimized. The study varied the power, time, and ethanol: ethyl acetate solvent ratio to maximize the extraction yield, carotenoid concentration in the extract, and carotenoid recovery. Under optimized conditions (364 W, 105 s, solvent ratio 20% ethanol: ethyl acetate), an % EY of 6.54 ± 0.48%, CCE of 5.72 ± 0.51 mg β-carotene equiv/g extract, and % CR of 54.52 ± 1.69% were achieved. The optimized extract was freeze-dried and encapsulated through an emulsion with a mean particle size (Dv50) of 1.249 ± 0.210 μm. Subsequently, this extract was incorporated into a gummy formulation, which was analyzed for its textural properties. The addition of the encapsulated carotenoid extract affected the color of the gummy but not the textural properties. The findings of this research represent an alternative that could be attractive for the Colombian coffee agro-industrial sector.
{"title":"Gummies Enriched with Carotenoids Extracted from Yellow Coffee Pulp (Caturra Var.) Using Microwave-Assisted Extraction","authors":"Elkin Rojas-Orduña, María Hernández-Carrión and Andrea del Pilar Sánchez-Camargo*, ","doi":"10.1021/acsfoodscitech.4c0029910.1021/acsfoodscitech.4c00299","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00299https://doi.org/10.1021/acsfoodscitech.4c00299","url":null,"abstract":"<p >In this study, the untapped potential of coffee byproducts, specifically carotenoids present in coffee pulp, was explored. Using a Box–Behnken response surface design, microwave-assisted extraction conditions were optimized. The study varied the power, time, and ethanol: ethyl acetate solvent ratio to maximize the extraction yield, carotenoid concentration in the extract, and carotenoid recovery. Under optimized conditions (364 W, 105 s, solvent ratio 20% ethanol: ethyl acetate), an % EY of 6.54 ± 0.48%, CCE of 5.72 ± 0.51 mg β-carotene equiv/g extract, and % CR of 54.52 ± 1.69% were achieved. The optimized extract was freeze-dried and encapsulated through an emulsion with a mean particle size (Dv50) of 1.249 ± 0.210 μm. Subsequently, this extract was incorporated into a gummy formulation, which was analyzed for its textural properties. The addition of the encapsulated carotenoid extract affected the color of the gummy but not the textural properties. The findings of this research represent an alternative that could be attractive for the Colombian coffee agro-industrial sector.</p>","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-22DOI: 10.1021/acsfoodscitech.4c0029810.1021/acsfoodscitech.4c00298
Brian L. Lee, Manoj Rout, Ying Dong, Matthias Lipfert, Mark Berjanskii, Fatemeh Shahin, Dipanjan Bhattacharyya, Alyaa Selim, Rupasri Mandal and David S. Wishart*,
We report the development of MagMet-W (magnetic resonance for metabolomics of wine), a software program that can automatically determine the chemical composition of wine via 1H nuclear magnetic resonance (NMR) spectroscopy. MagMet-W is an extension of MagMet developed for the automated metabolomic analysis of human serum by 1H NMR. We identified 70 compounds suitable for inclusion into MagMet-W. We then obtained 1D 1H NMR reference spectra of the pure compounds at 700 MHz and incorporated these spectra into the MagMet-W compound library. The processing of the wine NMR spectra and profiling of the 70 wine compounds were then optimized based on manual 1H NMR analysis. MagMet-W can automatically identify 70 wine compounds in most wine samples and can quantify them to 10–15% of the manually determined concentrations, and it can analyze multiple spectra simultaneously, at 10 min per spectrum. The MagMet-W Web server is available at https://www.magmet.ca.
{"title":"Automatic Chemical Profiling of Wine by Proton Nuclear Magnetic Resonance Spectroscopy","authors":"Brian L. Lee, Manoj Rout, Ying Dong, Matthias Lipfert, Mark Berjanskii, Fatemeh Shahin, Dipanjan Bhattacharyya, Alyaa Selim, Rupasri Mandal and David S. Wishart*, ","doi":"10.1021/acsfoodscitech.4c0029810.1021/acsfoodscitech.4c00298","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00298https://doi.org/10.1021/acsfoodscitech.4c00298","url":null,"abstract":"<p >We report the development of MagMet-W (magnetic resonance for metabolomics of wine), a software program that can automatically determine the chemical composition of wine via <sup>1</sup>H nuclear magnetic resonance (NMR) spectroscopy. MagMet-W is an extension of MagMet developed for the automated metabolomic analysis of human serum by <sup>1</sup>H NMR. We identified 70 compounds suitable for inclusion into MagMet-W. We then obtained 1D <sup>1</sup>H NMR reference spectra of the pure compounds at 700 MHz and incorporated these spectra into the MagMet-W compound library. The processing of the wine NMR spectra and profiling of the 70 wine compounds were then optimized based on manual <sup>1</sup>H NMR analysis. MagMet-W can automatically identify 70 wine compounds in most wine samples and can quantify them to 10–15% of the manually determined concentrations, and it can analyze multiple spectra simultaneously, at 10 min per spectrum. The MagMet-W Web server is available at https://www.magmet.ca.</p>","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsfoodscitech.4c00298","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-22DOI: 10.1021/acsfoodscitech.4c00298
Brian L. Lee, Manoj Rout, Ying Dong, Matthias Lipfert, Mark Berjanskii, Fatemeh Shahin, Dipanjan Bhattacharyya, Alyaa Selim, Rupasri Mandal, David S. Wishart
We report the development of MagMet-W (magnetic resonance for metabolomics of wine), a software program that can automatically determine the chemical composition of wine via 1H nuclear magnetic resonance (NMR) spectroscopy. MagMet-W is an extension of MagMet developed for the automated metabolomic analysis of human serum by 1H NMR. We identified 70 compounds suitable for inclusion into MagMet-W. We then obtained 1D 1H NMR reference spectra of the pure compounds at 700 MHz and incorporated these spectra into the MagMet-W compound library. The processing of the wine NMR spectra and profiling of the 70 wine compounds were then optimized based on manual 1H NMR analysis. MagMet-W can automatically identify 70 wine compounds in most wine samples and can quantify them to 10–15% of the manually determined concentrations, and it can analyze multiple spectra simultaneously, at 10 min per spectrum. The MagMet-W Web server is available at https://www.magmet.ca.
{"title":"Automatic Chemical Profiling of Wine by Proton Nuclear Magnetic Resonance Spectroscopy","authors":"Brian L. Lee, Manoj Rout, Ying Dong, Matthias Lipfert, Mark Berjanskii, Fatemeh Shahin, Dipanjan Bhattacharyya, Alyaa Selim, Rupasri Mandal, David S. Wishart","doi":"10.1021/acsfoodscitech.4c00298","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00298","url":null,"abstract":"We report the development of MagMet-W (magnetic resonance for metabolomics of wine), a software program that can automatically determine the chemical composition of wine via <sup>1</sup>H nuclear magnetic resonance (NMR) spectroscopy. MagMet-W is an extension of MagMet developed for the automated metabolomic analysis of human serum by <sup>1</sup>H NMR. We identified 70 compounds suitable for inclusion into MagMet-W. We then obtained 1D <sup>1</sup>H NMR reference spectra of the pure compounds at 700 MHz and incorporated these spectra into the MagMet-W compound library. The processing of the wine NMR spectra and profiling of the 70 wine compounds were then optimized based on manual <sup>1</sup>H NMR analysis. MagMet-W can automatically identify 70 wine compounds in most wine samples and can quantify them to 10–15% of the manually determined concentrations, and it can analyze multiple spectra simultaneously, at 10 min per spectrum. The MagMet-W Web server is available at https://www.magmet.ca.","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141779041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-18DOI: 10.1021/acsfoodscitech.4c00364
Joshua Moskowitz, Betsy Jean Yakes, John P. Roetting, II, Katherine L. Fiedler
In this work, a rapid lateral flow immunoassay is used to detect opiate alkaloids on poppy seeds. This assay is a qualitative limit (pass/fail) test that can detect morphine and codeine on poppy seeds. Our results demonstrate that the lateral flow immunoassay is highly effective at discriminating poppy seeds with total morphine plus codeine concentrations of ≥40 μg/g from poppy seeds with relatively lower concentrations of these opiate alkaloids. All poppy seed samples were also analyzed via liquid chromatography-tandem mass spectrometry to quantify opiate alkaloid concentrations on poppy seed samples and to evaluate the performance of the rapid lateral flow immunoassay. Rapid, low-cost, and portable detection of opiate alkaloids on poppy seeds may provide both the food industry and regulatory officials with a simple and easy-to-use method for ensuring the safety of poppy seeds intended for human consumption.
{"title":"Rapid, Low-Cost, and Portable Detection of Morphine and Codeine on Poppy Seeds via a Lateral Flow Immunoassay","authors":"Joshua Moskowitz, Betsy Jean Yakes, John P. Roetting, II, Katherine L. Fiedler","doi":"10.1021/acsfoodscitech.4c00364","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00364","url":null,"abstract":"In this work, a rapid lateral flow immunoassay is used to detect opiate alkaloids on poppy seeds. This assay is a qualitative limit (pass/fail) test that can detect morphine and codeine on poppy seeds. Our results demonstrate that the lateral flow immunoassay is highly effective at discriminating poppy seeds with total morphine plus codeine concentrations of ≥40 μg/g from poppy seeds with relatively lower concentrations of these opiate alkaloids. All poppy seed samples were also analyzed via liquid chromatography-tandem mass spectrometry to quantify opiate alkaloid concentrations on poppy seed samples and to evaluate the performance of the rapid lateral flow immunoassay. Rapid, low-cost, and portable detection of opiate alkaloids on poppy seeds may provide both the food industry and regulatory officials with a simple and easy-to-use method for ensuring the safety of poppy seeds intended for human consumption.","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141742942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-18DOI: 10.1021/acsfoodscitech.4c0036410.1021/acsfoodscitech.4c00364
Joshua Moskowitz, Betsy Jean Yakes, John P. Roetting II and Katherine L. Fiedler*,
In this work, a rapid lateral flow immunoassay is used to detect opiate alkaloids on poppy seeds. This assay is a qualitative limit (pass/fail) test that can detect morphine and codeine on poppy seeds. Our results demonstrate that the lateral flow immunoassay is highly effective at discriminating poppy seeds with total morphine plus codeine concentrations of ≥40 μg/g from poppy seeds with relatively lower concentrations of these opiate alkaloids. All poppy seed samples were also analyzed via liquid chromatography-tandem mass spectrometry to quantify opiate alkaloid concentrations on poppy seed samples and to evaluate the performance of the rapid lateral flow immunoassay. Rapid, low-cost, and portable detection of opiate alkaloids on poppy seeds may provide both the food industry and regulatory officials with a simple and easy-to-use method for ensuring the safety of poppy seeds intended for human consumption.
{"title":"Rapid, Low-Cost, and Portable Detection of Morphine and Codeine on Poppy Seeds via a Lateral Flow Immunoassay","authors":"Joshua Moskowitz, Betsy Jean Yakes, John P. Roetting II and Katherine L. Fiedler*, ","doi":"10.1021/acsfoodscitech.4c0036410.1021/acsfoodscitech.4c00364","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00364https://doi.org/10.1021/acsfoodscitech.4c00364","url":null,"abstract":"<p >In this work, a rapid lateral flow immunoassay is used to detect opiate alkaloids on poppy seeds. This assay is a qualitative limit (pass/fail) test that can detect morphine and codeine on poppy seeds. Our results demonstrate that the lateral flow immunoassay is highly effective at discriminating poppy seeds with total morphine plus codeine concentrations of ≥40 μg/g from poppy seeds with relatively lower concentrations of these opiate alkaloids. All poppy seed samples were also analyzed via liquid chromatography-tandem mass spectrometry to quantify opiate alkaloid concentrations on poppy seed samples and to evaluate the performance of the rapid lateral flow immunoassay. Rapid, low-cost, and portable detection of opiate alkaloids on poppy seeds may provide both the food industry and regulatory officials with a simple and easy-to-use method for ensuring the safety of poppy seeds intended for human consumption.</p>","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-17DOI: 10.1021/acsfoodscitech.4c00246
Carlo R. Hinojosa-Avila, Tomás García-Cayuela
This study aimed to optimize brewing conditions for enhanced probiotic viability in beer. Twenty-one commercial and potential probiotic lactic acid bacteria (LAB) strains were assessed for ethanol and hop resistance, with selected strains further analyzed for synergistic stress effects, beer fermentation performance with varying hop concentrations, and the impact of divalent cations supplementation. Results revealed strain-specific responses to stressors, with certain strains (LA3, LA5, 299v, GG, and BIOTEC011) showing resilience under specific beer conditions. These strains performed optimally in nonhopped Gueuze-style beer fermentation, achieving over 8 log colony forming units/mL. However, hop presence was only tolerated up to 2 International Bitterness Units. Magnesium and manganese salt additions were not optimal for LAB viability, suggesting alternative strategies may be needed. Overall, this study provides valuable insights into the complex dynamics of probiotic-enriched beer production, warranting further research to refine brewing techniques and meet consumer demand for functional beverages.
{"title":"Enhancing Probiotic Viability in Beer Fermentation: Selection of Stress-Resistant Lactic Acid Bacteria and Alternative Approaches","authors":"Carlo R. Hinojosa-Avila, Tomás García-Cayuela","doi":"10.1021/acsfoodscitech.4c00246","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00246","url":null,"abstract":"This study aimed to optimize brewing conditions for enhanced probiotic viability in beer. Twenty-one commercial and potential probiotic lactic acid bacteria (LAB) strains were assessed for ethanol and hop resistance, with selected strains further analyzed for synergistic stress effects, beer fermentation performance with varying hop concentrations, and the impact of divalent cations supplementation. Results revealed strain-specific responses to stressors, with certain strains (LA3, LA5, 299v, GG, and BIOTEC011) showing resilience under specific beer conditions. These strains performed optimally in nonhopped Gueuze-style beer fermentation, achieving over 8 log colony forming units/mL. However, hop presence was only tolerated up to 2 International Bitterness Units. Magnesium and manganese salt additions were not optimal for LAB viability, suggesting alternative strategies may be needed. Overall, this study provides valuable insights into the complex dynamics of probiotic-enriched beer production, warranting further research to refine brewing techniques and meet consumer demand for functional beverages.","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141742943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-15DOI: 10.1021/acsfoodscitech.4c0031010.1021/acsfoodscitech.4c00310
Cheng Li, Wei Wu, Michael Tilley, Richard Chen, Xiuzhi Susan Sun, Weiqun Wang and Yonghui Li*,
Natural antioxidants, specifically phenolic compounds and bioactive peptides obtained through dietary sources, have gained interest for their potential to modulate cellular oxidative stress. In this study, arabinoxylan and proteins from two types of wheat bran were extracted and subjected to enzymatic hydrolysis to obtain xylo-oligosaccharides (XOS) and protein hydrolysates, respectively. Then, antioxidant capacities of XOS and protein hydrolysates were characterized, and their inhibitory effects were evaluated against collagenase, elastase, and hyaluronidase. The results demonstrated that the XOS and protein hydrolysates, obtained after proper extraction and enzymatic hydrolysis, exhibited promising antioxidant capacity and pronounced inhibition of the aforementioned enzymes. The total phenolic contents of XOS extracted from hard and soft wheat bran were determined to be 39.63 and 32.06 mg GAE/g, respectively. The XOS derived from hard wheat bran showed the highest hyaluronidase inhibition activity, reaching 49.9% at 0.5 mg/mL concentration among samples. The wheat bran extracts possess great potential to be used in the production of functional ingredients aimed at antioxidant and cosmetic application purposes.
天然抗氧化剂,特别是通过膳食来源获得的酚类化合物和生物活性肽,因其调节细胞氧化应激的潜力而备受关注。本研究从两种小麦麸皮中提取阿拉伯木聚糖和蛋白质,并进行酶水解,分别得到木寡糖(XOS)和蛋白质水解物。然后表征了 XOS 和蛋白质水解物的抗氧化能力,并评估了它们对胶原酶、弹性蛋白酶和透明质酸酶的抑制作用。结果表明,经过适当提取和酶水解后得到的 XOS 和蛋白质水解物具有良好的抗氧化能力,对上述酶有明显的抑制作用。经测定,从硬麦麸和软麦麸中提取的 XOS 的总酚含量分别为 39.63 和 32.06 毫克 GAE/克。从硬麦麸中提取的 XOS 显示出最高的透明质酸酶抑制活性,在 0.5 毫克/毫升浓度下达到 49.9%。麦麸提取物在生产抗氧化和化妆品功能成分方面具有巨大的应用潜力。
{"title":"In Vitro Antioxidant Properties of Wheat Bran Extracts and Their Inhibitory Effects on Collagenase, Elastase, and Hyaluronidase","authors":"Cheng Li, Wei Wu, Michael Tilley, Richard Chen, Xiuzhi Susan Sun, Weiqun Wang and Yonghui Li*, ","doi":"10.1021/acsfoodscitech.4c0031010.1021/acsfoodscitech.4c00310","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00310https://doi.org/10.1021/acsfoodscitech.4c00310","url":null,"abstract":"<p >Natural antioxidants, specifically phenolic compounds and bioactive peptides obtained through dietary sources, have gained interest for their potential to modulate cellular oxidative stress. In this study, arabinoxylan and proteins from two types of wheat bran were extracted and subjected to enzymatic hydrolysis to obtain xylo-oligosaccharides (XOS) and protein hydrolysates, respectively. Then, antioxidant capacities of XOS and protein hydrolysates were characterized, and their inhibitory effects were evaluated against collagenase, elastase, and hyaluronidase. The results demonstrated that the XOS and protein hydrolysates, obtained after proper extraction and enzymatic hydrolysis, exhibited promising antioxidant capacity and pronounced inhibition of the aforementioned enzymes. The total phenolic contents of XOS extracted from hard and soft wheat bran were determined to be 39.63 and 32.06 mg GAE/g, respectively. The XOS derived from hard wheat bran showed the highest hyaluronidase inhibition activity, reaching 49.9% at 0.5 mg/mL concentration among samples. The wheat bran extracts possess great potential to be used in the production of functional ingredients aimed at antioxidant and cosmetic application purposes.</p>","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-12DOI: 10.1021/acsfoodscitech.4c00238
Jaloliddin Khushvakov, Sebastian E. W. Opitz, Nadja Plüss, Jasmin Sun, Linda Josefine Manthey, Heiko Rischer, Chahan Yeretzian
With global demand for coffee on the rise, coffee cultivation faces multiple challenges, e.g. ensuring supply and reducing their environmental impact. To address these, alternatives to traditional coffee (TC) are proposed such as coffee substitutes and cell-cultured coffees (CC). To assess similarities and differences between traditional and alternative coffees, a three-step analysis is introduced, encompassing precursor analysis in unroasted, aroma in roasted, and sensory in brew. Unroasted CC has higher monosaccharide, lower amino acids and lipids content, and different organic acid profile. Chlorogenic acids, caffeine and trigonelline, were low to absent. Roasted CC revealed lower aroma compound intensity in S- and N-containing compounds, Strecker aldehydes and guaiacols. Nevertheless, furfurals, higher homologous aldehydes, and hydrocarbons were abundant. This provides a protocol for mapping out the performance of alternatives to TC and guiding their optimization.
随着全球对咖啡需求的不断增长,咖啡种植面临着多重挑战,如确保供应和减少对环境的影响。为此,人们提出了传统咖啡(TC)的替代品,如咖啡替代品和细胞培养咖啡(CC)。为评估传统咖啡和替代咖啡的异同,引入了三步分析法,包括未烘焙咖啡的前体分析、烘焙咖啡的香气分析和冲泡咖啡的感官分析。未烘焙 CC 的单糖含量较高,氨基酸和脂类含量较低,有机酸含量也不同。绿原酸、咖啡因和三尖杉酯碱含量较低甚至没有。烘焙 CC 的含 S 和 N 化合物、Strecker 醛和愈创木酚的香气强度较低。不过,呋喃类、高同源醛类和碳氢化合物含量丰富。这为绘制三氯乙烷替代品的性能图和指导其优化提供了一个方案。
{"title":"Analytical Platform to Determine Similarities and Dissimilarities between Cell-Cultured Coffee and Farm-Grown Coffee","authors":"Jaloliddin Khushvakov, Sebastian E. W. Opitz, Nadja Plüss, Jasmin Sun, Linda Josefine Manthey, Heiko Rischer, Chahan Yeretzian","doi":"10.1021/acsfoodscitech.4c00238","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00238","url":null,"abstract":"With global demand for coffee on the rise, coffee cultivation faces multiple challenges, e.g. ensuring supply and reducing their environmental impact. To address these, alternatives to traditional coffee (TC) are proposed such as coffee substitutes and cell-cultured coffees (CC). To assess similarities and differences between traditional and alternative coffees, a three-step analysis is introduced, encompassing precursor analysis in unroasted, aroma in roasted, and sensory in brew. Unroasted CC has higher monosaccharide, lower amino acids and lipids content, and different organic acid profile. Chlorogenic acids, caffeine and trigonelline, were low to absent. Roasted CC revealed lower aroma compound intensity in S- and N-containing compounds, Strecker aldehydes and guaiacols. Nevertheless, furfurals, higher homologous aldehydes, and hydrocarbons were abundant. This provides a protocol for mapping out the performance of alternatives to TC and guiding their optimization.","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141611815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-12DOI: 10.1021/acsfoodscitech.4c0023810.1021/acsfoodscitech.4c00238
Jaloliddin Khushvakov*, Sebastian E. W. Opitz, Nadja Plüss, Jasmin Sun, Linda Josefine Manthey, Heiko Rischer* and Chahan Yeretzian*,
With global demand for coffee on the rise, coffee cultivation faces multiple challenges, e.g. ensuring supply and reducing their environmental impact. To address these, alternatives to traditional coffee (TC) are proposed such as coffee substitutes and cell-cultured coffees (CC). To assess similarities and differences between traditional and alternative coffees, a three-step analysis is introduced, encompassing precursor analysis in unroasted, aroma in roasted, and sensory in brew. Unroasted CC has higher monosaccharide, lower amino acids and lipids content, and different organic acid profile. Chlorogenic acids, caffeine and trigonelline, were low to absent. Roasted CC revealed lower aroma compound intensity in S- and N-containing compounds, Strecker aldehydes and guaiacols. Nevertheless, furfurals, higher homologous aldehydes, and hydrocarbons were abundant. This provides a protocol for mapping out the performance of alternatives to TC and guiding their optimization.
随着全球对咖啡需求的不断增长,咖啡种植面临着多重挑战,如确保供应和减少对环境的影响。为此,人们提出了传统咖啡(TC)的替代品,如咖啡替代品和细胞培养咖啡(CC)。为评估传统咖啡和替代咖啡的异同,引入了三步分析法,包括未烘焙咖啡的前体分析、烘焙咖啡的香气分析和冲泡咖啡的感官分析。未烘焙 CC 的单糖含量较高,氨基酸和脂类含量较低,有机酸含量也不同。绿原酸、咖啡因和三尖杉酯碱含量较低甚至没有。烘焙 CC 的含 S 和 N 化合物、Strecker 醛和愈创木酚的香气强度较低。不过,呋喃类、高同源醛类和碳氢化合物含量丰富。这为绘制三氯乙烷替代品的性能图和指导其优化提供了一个方案。
{"title":"Analytical Platform to Determine Similarities and Dissimilarities between Cell-Cultured Coffee and Farm-Grown Coffee","authors":"Jaloliddin Khushvakov*, Sebastian E. W. Opitz, Nadja Plüss, Jasmin Sun, Linda Josefine Manthey, Heiko Rischer* and Chahan Yeretzian*, ","doi":"10.1021/acsfoodscitech.4c0023810.1021/acsfoodscitech.4c00238","DOIUrl":"https://doi.org/10.1021/acsfoodscitech.4c00238https://doi.org/10.1021/acsfoodscitech.4c00238","url":null,"abstract":"<p >With global demand for coffee on the rise, coffee cultivation faces multiple challenges, e.g. ensuring supply and reducing their environmental impact. To address these, alternatives to traditional coffee (TC) are proposed such as coffee substitutes and cell-cultured coffees (CC). To assess similarities and differences between traditional and alternative coffees, a three-step analysis is introduced, encompassing precursor analysis in unroasted, aroma in roasted, and sensory in brew. Unroasted CC has higher monosaccharide, lower amino acids and lipids content, and different organic acid profile. Chlorogenic acids, caffeine and trigonelline, were low to absent. Roasted CC revealed lower aroma compound intensity in S- and N-containing compounds, Strecker aldehydes and guaiacols. Nevertheless, furfurals, higher homologous aldehydes, and hydrocarbons were abundant. This provides a protocol for mapping out the performance of alternatives to TC and guiding their optimization.</p>","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsfoodscitech.4c00238","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-10DOI: 10.1021/acsfoodscitech.4c00274
Sumin Ma, Caixia Ding, Haiming Shi, Hong Zhang, Yanlan Bi and Xuebing Xu*,
The impact of water during processing on the sensory properties and aroma-active aldehyde composition of roasted peanut oils was investigated. Peanut kernels with varying initial water contents undergo a roasting and pressing process to produce roasted peanut oil. Almost all volatile compounds decreased in content with an increasing water content, except for benzeneacetaldehyde (BA), hexanal, (E,E)-2,4-decadienal, and (E)-2-octenal. Additionally, with the increasing water content, the intensity of the sweet, steamed, and raw-peanut flavor attributes of the peanut oil was enhanced. The BA content increased by a factor of 7.26, as the water content increased from 4.20 to 52.55% in peanut kernels. Furthermore, the mechanism of BA formation induced by water in the phenylalanine and glucose system was experimentally confirmed using a H2O isotope model experiment. The results indicated that H2O donated one oxygen atom to the aldehyde group of BA. Ultimately, water can significantly alter the release of flavor compounds, thereby influencing the overall flavor and sensory properties of the oil.
研究了加工过程中水分对烘焙花生油的感官特性和芳香活性醛成分的影响。不同初始含水量的花生仁经过焙烧和压榨过程后生产出焙烧花生油。除了苯乙醛(BA)、己醛、(E,E)-2,4-癸二烯醛和(E)-2-辛烯醛之外,几乎所有挥发性化合物的含量都随着含水量的增加而减少。此外,随着含水量的增加,花生油的甜味、蒸味和生花生味的强度都有所提高。随着花生仁含水量从 4.20% 增加到 52.55%,BA 含量增加了 7.26 倍。此外,还利用 H2O 同位素模型实验证实了水在苯丙氨酸和葡萄糖体系中诱导 BA 形成的机理。结果表明,H2O 向 BA 的醛基提供了一个氧原子。最终,水能显著改变风味化合物的释放,从而影响油的整体风味和感官特性。
{"title":"Impact of the Water Content in Peanut Kernels on the Generation of Benzeneacetaldehyde in Roasted Peanut Oils","authors":"Sumin Ma, Caixia Ding, Haiming Shi, Hong Zhang, Yanlan Bi and Xuebing Xu*, ","doi":"10.1021/acsfoodscitech.4c00274","DOIUrl":"10.1021/acsfoodscitech.4c00274","url":null,"abstract":"<p >The impact of water during processing on the sensory properties and aroma-active aldehyde composition of roasted peanut oils was investigated. Peanut kernels with varying initial water contents undergo a roasting and pressing process to produce roasted peanut oil. Almost all volatile compounds decreased in content with an increasing water content, except for benzeneacetaldehyde (BA), hexanal, (<i>E</i>,<i>E</i>)-2,4-decadienal, and (<i>E</i>)-2-octenal. Additionally, with the increasing water content, the intensity of the sweet, steamed, and raw-peanut flavor attributes of the peanut oil was enhanced. The BA content increased by a factor of 7.26, as the water content increased from 4.20 to 52.55% in peanut kernels. Furthermore, the mechanism of BA formation induced by water in the phenylalanine and glucose system was experimentally confirmed using a H<sub>2</sub>O isotope model experiment. The results indicated that H<sub>2</sub>O donated one oxygen atom to the aldehyde group of BA. Ultimately, water can significantly alter the release of flavor compounds, thereby influencing the overall flavor and sensory properties of the oil.</p>","PeriodicalId":72048,"journal":{"name":"ACS food science & technology","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141586464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}