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Formation of a Natural Composite Structure in Hadfield Steel under Superplastic Deformation. Part 1 超塑性变形下Hadfield钢自然复合组织的形成。第1部分
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601647
V. A. Shabashov, K. A. Kozlov, N. V. Kataeva

An austenitic natural composite structure reinforced with nanosized carbides (Fe100– xMnx)3C was first formed in classical Hadfield steel (Fe–13Mn–1.1C) under superplastic deformation. The mechanism and kinetics of dynamic strain aging of the steel under high-pressure torsion in Bridgman anvils were revealed. It was shown that increasing the strain and temperature of deformation caused an anomalous acceleration of dynamic strain aging of the steel with the formation of nanosized carbides (Fe100–xMnx)3C.

在经典Hadfield钢(Fe-13Mn-1.1C)的超塑性变形下,首先形成了以纳米碳化物(Fe100 - xMnx)3C增强的奥氏体自然复合结构。揭示了高压扭转下Bridgman砧钢动态应变时效的机理和动力学。结果表明:随着变形应变和温度的升高,钢的动态应变时效异常加速,形成纳米碳化物(Fe100-xMnx)3C;
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引用次数: 0
Nonadiabatic Dynamics of Atoms and Electroplastic Effect in Metals 原子的非绝热动力学和金属中的电塑性效应
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601556
Yu. A. Khon

The electroplastic effect is a sharp decrease in the deformation stress of metals under the action of an electric pulse. The mechanism of the electroplastic effect is still unclear. There is no explanation for the accumulated experimental data. In this paper, we propose a new mechanism of the electroplastic effect in metals, which is governed by athermal displacements of pinned dislocations during nonadiabatic Landau–Zener transitions of atoms in an open system of nuclei and electrons. The electric pulse action causes additional displacements of atoms in the specimen volume, increases the velocity of athermal displacements of dislocations and the plastic strain rate, which leads to a drop in the deformation stress. An explanation is provided for the experimental pattern of electroplastic deformation.

电塑性效应是金属在电脉冲作用下变形应力的急剧下降。电塑性效应的机理尚不清楚。对积累的实验数据没有解释。在本文中,我们提出了一种新的金属电塑性效应机制,该机制是由原子核和电子的开放系统中原子在非绝热朗道-齐纳跃迁过程中钉住位错的非热位移所控制的。电脉冲作用引起试样体积内原子的额外位移,增加了位错的非热位移速度和塑性应变速率,从而导致变形应力下降。对电塑性变形的实验模式进行了解释。
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引用次数: 0
Development of an Earing Model with Consideration for the Crystallographic Texture of Sheet Metal During Axisymmetric Drawing 轴对称拉深过程中考虑板料晶体织构的拉深模型的建立
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601696
Ya. A. Erisov, F. V. Grechnikov, S. V. Suridin, V. A. Razzhivin, E. V. Aryshenskii, S. V. Konovalov

A calculation model is developed for earing during cylindrical drawing of metallic materials, which is based on the phenomenological criterion of plasticity taking into account the crystallographic texture of the material. The model was verified by comparing the calculated earing defects with those observed in drawing tests on an aluminum preform. Further modeling shows that deformation orientations ({112}<111>, {110}<112>, {123}<634>, and {100}<011>) lead to earing at an angle of 45° to the rolling direction, while recrystallization orientations ({100}<001> and {110}<001>) lead to earing in the rolling and transverse directions. Crystallographic orientation {110}<001> gives maximum earing, while orientation {123}<634> causes minimum one. In all the cases, the contribution of plastic anisotropy and yield stress anisotropy to earing is almost the same, with a slight predominance of the latter. The earing behavior is shown by the example of materials with a two-component ({112}<111> + {100}<001) texture: as the fraction of the {112}<111> orientation grows, ears in the rolling and transverse directions are reduced, while they form at an angle of 45° to the rolling direction. Considering such influence, the earing coefficient is minimum at 55–60% of the {112}<111> component.

基于塑性现象学判据,考虑材料的晶体织构,建立了金属材料圆柱拉伸过程中裂纹的计算模型。通过将计算得到的耳损缺陷与铝预制件拉拔试验中观察到的耳损缺陷进行比较,验证了该模型的正确性。进一步的建模表明,变形取向({112}<111>;、{110}<112>;、{123}<634>;和{100}<;011>)导致与轧制方向成45°角的磨损,而再结晶取向({100}<001>;和{110}<;001>)导致轧制方向和横向方向的磨损。晶体取向{110}<;001>;产生最大的耳廓,而取向{123}<;634>;产生最小的耳廓。在所有情况下,塑性各向异性和屈服应力各向异性对变形的贡献几乎相同,后者略占优势。双组份织构({112}<111> + {100}<001)材料的耳形行为表明:随着{112}<;111>;取向分数的增加,滚动方向和横向方向的耳形减少,耳形形成方向与滚动方向成45°角。考虑到这种影响,在{112}<;111>;分量的55-60%处,耳响系数最小。
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引用次数: 0
On the Cyclic Fracture Toughness Parameter, Ks, from the Standpoint of Fracture Physics and Mechanics 从断裂物理力学的角度谈循环断裂韧性参数Ks
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601684
L. R. Botvina, M. R. Tyutin, K. Prasad

The paper analyzes the stages and kinetic features of fatigue crack growth. Particular attention is paid to fatigue stage II consisting of two substages, namely, IIa and IIb. The stress intensity factor KS is proposed to determine the boundary between them (corresponds to the stable crack length aS under plane-strain conditions) and to characterize the cyclic fracture toughness. It is assumed that KS corresponds to the stress intensity factor KGY estimated by the cyclic yield stress and the length of a focal fatigue crack. Enlargement of the plastic zone at the crack tip and a transition to the plane-stress state at KKS change the fatigue fracture pattern, which manifests itself as knee points in the Kmax dependences of acoustic emission parameters, phase transformation rate in metastable steel, and fatigue striation spacing: after reaching KS, the fatigue crack grows by the striation-per-cycle pattern. In addition, it is shown that the value of K = KS corresponds to the pivot point of the crack growth curve plotted for the steel tested in mixed loading modes.

分析了疲劳裂纹扩展的阶段和动力学特征。特别注意的是疲劳阶段II,它由两个子阶段组成,即IIa和IIb。提出了应力强度因子KS来确定它们之间的边界(对应于平应变条件下的稳定裂纹长度aS)并表征循环断裂韧性。假设KS对应于由循环屈服应力和局部疲劳裂纹长度估算的应力强度因子KGY。裂纹尖端塑性区的扩大和K≥KS时向平面应力状态的过渡改变了疲劳断裂模式,在声发射参数、亚稳钢相变速率和疲劳条纹间距的Kmax依赖关系中表现为膝点:到达KS后,疲劳裂纹以每循环条纹的方式扩展。此外,K = KS值对应于混合加载模式下试件裂纹扩展曲线的轴心点。
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引用次数: 0
Effect of the Structural-Phase Composition on the Mechanical Properties and Biocompatibility of Nanostructured Ti-15Mo Alloy 结构-相组成对纳米Ti-15Mo合金力学性能和生物相容性的影响
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601672
V. V. Polyakova, S. A. Gatina, K. M. Novruzov, N. Yu. Anisimova, M. M. Kiselevskiy, N. A. Enikeev

The paper is concerned with the effect of high-pressure torsion (HPT) on phase transformations and structure formation in near-β titanium alloy Ti-15Mo (wt.%) as well as with the dependence of the elastic modulus E and mechanical properties of the nanostructured alloy in the temperature range of 250–600°C. It is revealed that room-temperature nanostructuring of the β-quenched Ti-15Mo alloy to the von Mises strain ε ≈ 200 results in a homogeneous microstructure with a high defect density and the size of structural elements less than 100 nm. Formation of the nanostructure ensures an 80% increase in the ultimate tensile strength (UTS) of the Ti-15Mo alloy (UTS = 1550 MPa, El. = 7%) compared to that of the β-quenched alloy. It is shown that, after aging of the quenched and deformed Ti-15Mo alloy, the metastable β solid solution undergoes isothermal decomposition, resulting in the formation of the ω- and α-phases. The high defect density of the nanostructured alloy shifts the temperature range of the α-phase precipitation to lower temperatures (by 120°C on average) and has a significant effect on the volume fraction and morphology of α-phase precipitates. The latter have an equiaxed shape compared to the needle-like α-phase that precipitates during aging of the quenched coarse-grained alloy. After aging at 600°C, an equiaxed α + β structure with the average size of structural elements 380 nm is formed in the deformed alloy. Analysis of the mechanical properties after aging showed that the precipitation of dispersed ω-phase particles makes a significant contribution to precipitation hardening of Ti-15Mo alloy, significantly increases the microhardness (by 50%) compared to the quenched and deformed alloy, and can be considered as a macromechanical cause of the embrittlement of the alloy. The formation of an equiaxed α + β structure during HPT and aging at 550°C contributes to a balance between strength and ductility (UTS = 1270 MPa, El. = 10%). Changes in the structural-phase composition and phase ratios result in a nonmonotonic behavior of the elastic properties of the Ti-15Mo alloy. Studies of biological activity showed that both coarse-grained and nanostructured states of the Ti-15Mo alloy do not exhibit in vitro cytotoxicity towards blood leukocytes, indicating that these specimens are biocompatible. However, the nanostructured specimens demonstrated a pronounced inhibition of surface adhesion of S. aureus bacteria, which may potentially reduce the risk of postsurgical infectious complications following implantation of orthopedic metal devices based on the Ti-15Mo alloy in this structural state.

本文研究了高压扭转(HPT)对近β钛合金Ti-15Mo (wt.%)相变和组织形成的影响,以及250 ~ 600℃范围内纳米合金弹性模量E和力学性能的依赖关系。结果表明,在von Mises应变ε≈200下对Ti-15Mo合金进行室温纳米化处理,得到了缺陷密度高、结构元素尺寸小于100 nm的均匀组织。纳米结构的形成确保Ti-15Mo合金的极限抗拉强度(UTS = 1550 MPa, El。= 7%),与β淬火合金相比。结果表明,淬火变形后的Ti-15Mo合金时效后,亚稳态β固溶体发生等温分解,形成ω-相和α-相。纳米结构合金的高缺陷密度使α相析出的温度范围向较低的温度范围移动(平均降低120℃),并对α相析出的体积分数和形貌有显著影响。与淬火后粗晶合金时效时析出的针状α-相相比,后者具有等轴形状。在600℃时效后,变形合金中形成平均尺寸为380 nm的等轴α + β组织。时效后力学性能分析表明,分散的ω相颗粒的析出对Ti-15Mo合金的析出硬化有显著的促进作用,其显微硬度较淬火和变形合金显著提高(提高50%),可以认为是合金脆化的宏观力学原因。在550°C高温高温时效过程中形成等轴α + β结构,有助于达到强度和塑性的平衡(UTS = 1270 MPa, El。= 10%)。组织相组成和相比的变化导致Ti-15Mo合金弹性性能的非单调行为。生物活性研究表明,Ti-15Mo合金的粗粒度和纳米结构状态在体外对血液白细胞都没有细胞毒性,表明这些样品具有生物相容性。然而,纳米结构的标本显示出对金黄色葡萄球菌表面粘附的明显抑制,这可能潜在地降低在这种结构状态下基于Ti-15Mo合金的骨科金属装置植入后的术后感染并发症的风险。
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引用次数: 0
Dynamics of Horizontal Shear Waves Propagating in Size-Dependent Sandwich Plates Using Consistent Couple Stress Theory 基于一致耦合应力理论的水平剪切波在尺寸相关夹层板中的传播动力学
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601660
M. Kaur, S. Kumar, V. Sharma

Sandwich structures with thin, stiff and heavy facings compared to the core are employed in civil and aerospace engineering, while those with thick, soft and lighter facings are preferred in precipitator plate applications. Insights gained into the behavior of horizontally polarized shear (SH) waves in sandwich structures can guide the design of more resilient and efficient composites, enhancing their performance under dynamic loading conditions. The dynamic behavior of a sandwich structure with symmetric facings is rigorously analyzed within the framework of the consistent couple stress model of elasticity. Harmonic wave solutions are derived, provided that they satisfy either traction-free or fixed boundary conditions on the faces, while maintaining continuity of tractions and displacements at the interfaces between the core and facings. This analysis uses the size-dependent consistent couple stress elasticity, which incorporates a length parameter (characteristic length) assumed to be of the same order as the internal microstructures of the material. Dispersion relations for the propagation of SH waves are calculated under both stress-free and fixed boundary conditions. Detailed mathematical results are provided, accompanied by graphical illustrations that show the impacts of characteristic length parameters and thicknesses of the core and facings on the phase velocity under both symmetrical and skew-symmetrical conditions.

夹层结构采用薄、硬、重的面与核心相比,在土木和航空航天工程中,而厚、软、轻的面是首选在除尘器板的应用。对夹层结构中水平极化剪切(SH)波行为的深入了解可以指导设计更具弹性和高效的复合材料,提高其在动态加载条件下的性能。在弹性一致耦合应力模型框架下,对对称面夹层结构的动力特性进行了严格的分析。在满足无牵引力或面上固定边界条件的情况下,推导出谐波解,同时保持核心和面之间界面处牵引力和位移的连续性。该分析使用尺寸相关的一致耦合应力弹性,其中包含假定与材料内部微观结构具有相同顺序的长度参数(特征长度)。计算了无应力和固定边界条件下SH波传播的色散关系。给出了详细的数学结果,并配以图形说明了对称和偏对称条件下,特征长度参数、岩心和饰面的厚度对相速度的影响。
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引用次数: 0
Effect of Hafnium on the Microstructure Formation during High-Temperature Treatment of High-Magnesium Aluminum Alloys Microalloyed with Scandium and Zirconium 铪对钪锆微合金化高镁铝合金高温热处理组织形成的影响
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601702
A. A. Ragazin, E. V. Aryshenskii, V. Yu. Aryshenskii, D. Yu. Rasposienko, A. A. Lukyanchuk, S. V. Konovalov

The paper studies the effect of hafnium additives on the microstructure and mechanical properties during high-temperature annealing of high-magnesium aluminum alloys microalloyed with scandium and zirconium. The objects of investigation are two cast aluminum alloys alloyed and unalloyed with hafnium. The alloys are heat treated at 440°C for 48 h. The cast and heat-treated material is studied in mechanical tests, as well as under optical scanning and transmission microscopes. The structural-phase composition of these alloys is examined, and the effect of hafnium on the mechanical properties is analyzed. Atom probe tomography is used for a more detailed investigation of the internal structure of Al3Sc nanoparticles. It is shown that both alloys lack discontinuous precipitation of the supersaturated solid solution. The addition of hafnium decreases the size of Al3Sc nanoparticles. Like zirconium, hafnium forms a thermostabilizing shell around Al3Sc particles, thus preventing the growth of particles and contributing to their fine dispersion.

研究了添加铪对钪、锆微合金化高镁铝合金高温退火过程中组织和力学性能的影响。研究对象是两种含铪和未含铪的铸铝合金。合金在440°C下热处理48小时。在机械测试以及光学扫描和透射显微镜下研究了铸件和热处理材料。研究了这些合金的组织相组成,分析了铪元素对合金力学性能的影响。原子探针层析成像用于对Al3Sc纳米颗粒的内部结构进行更详细的研究。结果表明,两种合金均缺乏过饱和固溶体的不连续析出。铪的加入减小了Al3Sc纳米颗粒的尺寸。和锆一样,铪在Al3Sc粒子周围形成一个热稳定壳,从而阻止了粒子的生长,并有助于它们的精细分散。
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引用次数: 0
Effect of Delamination of Low Shear Strength Materials on Fracture and Test Results under Three-Point Bending 低抗剪强度材料分层对三点弯曲断裂及试验结果的影响
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S102995992460157X
A. V. Khokhlov, S. N. Galyshev, B. I. Atanov, V. I. Orlov

The paper reports the data of bending tests, microstructural and fractographic studies of specimens made of new unidirectional composites with the aluminum matrix reinforced with carbon fibers. These composites have increased specific strength compared to alloys and high crack resistance compared to carbon plastics due to the targeted formation of a sufficiently weak interface during their production. This is achieved by alloying the matrix with elements modifying the fiber–matrix contact layer and providing its low shear strength, as well as by optimizing parameters of the two-stage production technology. The problem under study is the influence of some production parameters on the microstructure, mechanical properties, and fracture mechanisms of the developed composites to find their optimum values ensuring higher strength and crack resistance. Consideration is given to the fracture mechanism of low shear strength materials under bending and the effect of their delamination (delamination cascade) on the fracture scenario and a significant decrease in the tensile strength revealed in bending tests. It is shown that delamination in the most loaded zone has an avalanche-like pattern, causing a very rapid increase in normal stresses and the number of fibers under maximum stress, i.e. the initiation of numerous fracture sites and rapid fracture of the entire specimen in the cross section under force. The data of three-point bending tests on specimens with different span lengths were used to propose a method for determining the shear strength-to-tensile strength ratio for a homogeneous isotropic material. The approach is also applicable to various composites with low interlaminar shear strength, in particular, to carbon-aluminum composites.

本文报道了新型碳纤维增强铝基单向复合材料的弯曲试验、显微组织和断口形貌研究数据。与合金相比,这些复合材料具有更高的比强度,与碳塑料相比,由于在生产过程中形成了足够弱的界面,因此具有更高的抗裂性。这是通过改变纤维基体接触层的元素来合金化基体,并提供其低剪切强度,以及通过优化两阶段生产技术的参数来实现的。研究的问题是一些生产参数对所研制的复合材料的组织、力学性能和断裂机制的影响,以找到它们的最佳值,从而保证更高的强度和抗裂性。考虑了低抗剪强度材料在弯曲作用下的断裂机理,以及其分层(分层级联)对断裂的影响和弯曲试验中显示的抗拉强度的显著降低。结果表明,在最大加载区,分层具有雪崩样的模式,导致法向应力和最大应力下纤维数量的快速增加,即在力的作用下,整个试样在截面上产生大量断裂位点和快速断裂。利用不同跨长试件的三点弯曲试验数据,提出了一种确定均质各向同性材料抗剪抗拉强度比的方法。该方法也适用于各种低层间抗剪强度的复合材料,特别是碳铝复合材料。
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引用次数: 0
Formation of a Dispersion-Hardened Structure in Hadfield Steel Under Friction. Part 2 摩擦作用下哈德菲尔钢弥散硬化组织的形成。第2部分
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-28 DOI: 10.1134/S1029959924601659
V. A. Shabashov, K. A. Kozlov, N. V. Kataeva, А. Е. Zamatovskii

The gradient structure formed in the surface layers of Hadfield steel under dry sliding friction was studied using Mössbauer spectroscopy and electron microscopy. Structural-phase transitions are established in the contact stress zone on the steel surface. The 20-μm-thick surface layers reveal deformation-induced short-range ordering with an increased number of neighboring manganese and carbon atoms. Thinner (up to 1 μm) layers are composed of nanocrystalline carbides of the (Fe,Mn)3C type.

利用Mössbauer能谱和电子显微镜研究了干滑动摩擦作用下哈德菲尔德钢表层形成的梯度结构。钢表面的接触应力区形成了结构相变。20 μm厚的表面层随着相邻锰原子和碳原子数量的增加而呈现出变形诱导的短程有序。较薄(1 μm)层由(Fe,Mn)3C型纳米碳化物组成。
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引用次数: 0
In Situ SAXS-WAXS Temperature Evolution Study of the Nanostructure of Self-Reinforced Ultrahigh Molecular Weight Polyethylene 自增强超高分子量聚乙烯纳米结构的原位SAXS-WAXS温度演化研究
IF 2 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-06-30 DOI: 10.1134/S1029959924601490
E. S. Statnik, Yu. E. Gorshkova, A. I. Salimon, D. D. Zherebtsov, S. D. Kaloshkin, A. M. Korsunsky

Ultrahigh molecular weight polyethylene (UHMWPE) is a thermoplastic high-performance polymer, which is in high demand in biomedicine, ship and machine building, production of anthropomorphic robots and smart prostheses. Highly oriented UHMWPE fibers possess record specific strength and may be used for the fabrication of self-reinforced PE-PE composites (SRPECs). The temperature evolution study of the small-angle X-ray scattering (SAXS) signature of the supramolecular structure of UHMWPE can help reveal their important role in the mechanism of the shape memory effect in SRPECs. The laboratory XEUSS 3.0 SAXS-WAXS beamline was used for in situ studies of the nanostructure parameters in unidirectional SRPEC. In particular, the radius of gyration and the dimensionality factor were derived from 2D SAXS patterns using several fitting algorithms. These parameters change significantly in the temperature ranges corresponding to the initiation of the shape memory effect and melting. The relationship between the material anisotropy and 2D SAXS patterns is discussed in the context of the supramolecular structure evolution.

超高分子量聚乙烯(UHMWPE)是一种热塑性高性能聚合物,在生物医药、船舶和机械制造、拟人机器人和智能假肢的生产中有着很高的需求。高取向超高分子量聚乙烯纤维具有创纪录的比强度,可用于制造自增强PE-PE复合材料(srpec)。超高分子量聚乙烯超分子结构的小角x射线散射(SAXS)特征的温度演化研究有助于揭示其在srpec中形状记忆效应机理中的重要作用。采用实验室XEUSS 3.0 SAXS-WAXS光束线对单向SRPEC的纳米结构参数进行了原位研究。特别地,利用几种拟合算法从二维SAXS模式中获得了旋转半径和维数因子。这些参数在形状记忆效应开始和熔化所对应的温度范围内变化显著。在超分子结构演化的背景下,讨论了材料各向异性与二维SAXS模式的关系。
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引用次数: 0
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Physical Mesomechanics
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