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Influence of Heat Treatments on Martensitic Transformations and Elastocaloric Effect in Two-Phase (β + γ) NiFeGa Alloys 热处理对两相 (β + γ) NiFeGa 合金中马氏体转变和弹性效应的影响
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040040
I. D. Kurlevskaya, E. Yu. Panchenko, A. B. Tokhmetova, E. I. Yanushonite, A. S. Eftifeeva, N. Yu. Surikov, E. E. Timofeeva, Yu. I. Chumlyakov

This study reveals the impact of the formation mechanism of a two-phase (β + γ) structure during heat treatment on thermoelastic L21(B2)-10M/14M-L10 martensitic transformations and elastocaloric parameters of polycrystalline Ni54Fe19Ga27 alloy. It is experimentally shown that annealing of the as-cast Ni54Fe19Ga27 alloy in the temperature range 1173–1463 K for 0.5 h followed by water quenching leads to the precipitation of the γ phase at grain boundaries and inside grains. As the annealing temperature increases from 1173 to 1463 K, the thickness of the γ-phase layer at the grain boundaries doubles, particles inside the grains coarsen, and their volume distribution becomes nonuniform. Simultaneously, the martensitic transformation temperatures increase by 31–69 K. The nonuniform distribution of the γ-phase particles and the morphological features of martensite (refinement of its twinned structure) lead to a 5–6-fold widening of the martensitic transformation intervals in crystals annealed at 1448 K compared to the as-cast alloy. After cyclic superelastic tests with 20 to 100 loading/unloading cycles, two-phase (β + γ) polycrystals demonstrate the stable adiabatic cooling temperature ∆Tad (2.7–3.0 K) and do not crack along grain boundaries, unlike those in the as-cast state. Significant fatigue strength and a high coefficient of performance (up to 18.3) make (β + γ) Ni54Fe19Ga27 polycrystals promising for practical use in solid-state cooling.

摘要 本研究揭示了多晶镍54Fe19Ga27合金在热处理过程中两相(β+γ)结构的形成机制对其热弹性L21(B2)-10M/14M-L10马氏体转变和弹塑性参数的影响。实验表明,在 1173-1463 K 的温度范围内对铸态 Ni54Fe19Ga27 合金进行 0.5 小时的退火,然后进行水淬,会导致晶界和晶粒内部析出 γ 相。随着退火温度从 1173 K 升至 1463 K,晶界处的γ相层厚度增加了一倍,晶粒内部的颗粒变粗,其体积分布变得不均匀。γ相颗粒的不均匀分布和马氏体的形态特征(孪生结构的细化)导致在 1448 K 下退火的晶体的马氏体转变区间比铸造时的合金扩大了 5-6 倍。经过 20 至 100 次加载/卸载循环超弹性测试后,两相(β + γ)多晶体显示出稳定的绝热冷却温度 ∆Tad (2.7-3.0 K),并且不会沿晶界开裂,这与原铸态合金不同。显著的疲劳强度和较高的性能系数(高达 18.3)使 (β + γ) Ni54Fe19Ga27 多晶体有望在固态冷却中得到实际应用。
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引用次数: 0
Nitrogen-Stabilized DLC Coatings: Optimization of Properties and Deposition Parameters Using Randomized Tree and Neural Network Algorithms 氮稳定 DLC 涂层:使用随机树和神经网络算法优化性能和沉积参数
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040015
A. I. Voropaev, V. I. Kolesnikov, O. V. Kudryakov, V. N. Varavka, I. V. Kolesnikov, M. S. Lifar, S. A. Guda, A. A. Guda, A. V. Sidashov

This work discusses the predictable control of plasma-assisted physical vapor deposition (PVD) of coatings. The multiple process parameters and the instability of the nonequilibrium ion plasma system create substantial obstacles to the wide industrial application of promising multicomponent functional coatings. Here we propose a solution to this problem, which includes: creation of a database of diamond-like carbon (DLC) coatings to identify a limited set of adjustable process control parameters, determination of how these parameters affect the coating properties, analysis of the revealed effects using statistical methods and neural network algorithms, and use of the results for the predictable tuning of specified coating properties. The object of research is original DLC coatings whose structure is stabilized with nitrogen instead of conventionally used hydrogen. The experimental database of DLC coatings is created based on our previous studies and includes structural, morphological and architectural characteristics of coatings, various types of substrates, sublayers, physical, mechanical and tribological properties, and various combinations of coating deposition parameters. A specific problem is solved to determine the influence of deposition parameters such as chamber pressure P, stabilizer content (% nitrogen), ion flux rate (coil current λ) and deposition time t on hardness H and elastic modulus E of coatings. Based on the results obtained, the deposition parameters are optimized so as to obtain predictable strength values of the formed carbon coating. The optimization procedure is developed using both classical statistical methods and modern algorithms of ridge regression, randomized trees (ExtraTrees), and a fully connected neural network (multilayer perceptron MLP).

摘要 本文讨论了涂层的等离子体辅助物理气相沉积(PVD)的可预测性控制。多工艺参数和非平衡离子等离子体系统的不稳定性给前景广阔的多组分功能涂层的广泛工业应用造成了巨大障碍。在此,我们提出了解决这一问题的方案,其中包括:建立类金刚石碳(DLC)涂层数据库,以确定一组有限的可调工艺控制参数;确定这些参数如何影响涂层特性;使用统计方法和神经网络算法分析所揭示的影响;以及利用结果对特定涂层特性进行可预测的调整。研究对象是原始的 DLC 涂层,其结构用氮气而不是传统的氢气来稳定。DLC 涂层的实验数据库是根据我们以前的研究建立的,其中包括涂层的结构、形态和构造特征,各种类型的基底、底层,物理、机械和摩擦学特性,以及涂层沉积参数的各种组合。本研究解决了一个具体问题,即确定沉积参数(如腔室压力 P、稳定剂含量(氮%)、离子通量率(线圈电流 λ)和沉积时间 t)对涂层硬度 H 和弹性模量 E 的影响。根据获得的结果,对沉积参数进行了优化,以获得可预测的已形成碳涂层的强度值。优化程序的开发既使用了经典统计方法,也使用了脊回归、随机树(ExtraTrees)和全连接神经网络(多层感知器 MLP)等现代算法。
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引用次数: 0
Wear and Failure Analysis of Ti-6Al-4V Titanium Alloy with a Protective Coating during High-Speed Erosion 带保护涂层的 Ti-6Al-4V 钛合金在高速腐蚀过程中的磨损和失效分析
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040039
S. A. Atroshenko, R. Z. Valiev, N. F. Morozov, R. R. Valiev, Ya. N. Savina, M. N. Antonova, A. D. Evstifeev

An experimental study is presented on the wear and failure of initial coarse-grained and modified ultrafine-grained Ti-6Al-4V alloy with a TiN protective coating, subjected to high-speed dynamic erosion by solid corundum particles with an average size of 109 μm in an air flow at a speed of 150 m/s and an erosion time of 30, 60, 180, 300 and 600 s. The experimental results are used to determine the erosive wear rate and the shear area percentage, as well as to measure the worn layer depth and erosion-induced changes in microhardness and structure of the alloy near the coated and uncoated surface. It is shown that all alloy samples are prone to wear and failure under the given high-speed erosion conditions, but their behavior is closely related to the erosion time and the structure of the substrate. The protective coating deposited onto the surface of ultrafine-grained Ti-6Al-4V titanium alloy significantly reduces the erosive wear rate compared to a similar coating on as-received coarse-grained alloy.

摘要 本文对带有 TiN 保护涂层的初始粗晶粒和改性超细晶粒 Ti-6Al-4V 合金的磨损和失效情况进行了实验研究。在速度为 150 m/s、侵蚀时间为 30、60、180、300 和 600 s 的气流中,平均粒度为 109 μm 的固体刚玉颗粒对合金进行高速动态侵蚀。实验结果用于确定侵蚀磨损率和剪切面积百分比,以及测量磨损层深度和侵蚀引起的涂层和未涂层表面附近合金微硬度和结构的变化。结果表明,在给定的高速侵蚀条件下,所有合金样品都容易发生磨损和失效,但其行为与侵蚀时间和基体结构密切相关。在超细晶粒 Ti-6Al-4V 钛合金表面沉积的保护涂层与在粗晶粒合金表面沉积的类似涂层相比,可显著降低侵蚀磨损率。
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引用次数: 0
A Function-on-Function Regression Model for Monitoring the Manufacturing Process Performance with Application in Friction Stir Welding 用于监控制造过程性能的功能对功能回归模型在搅拌摩擦焊中的应用
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S102995992404009X
F. Ramezankhani, R. Noorossana, M. R. M. Aliha

Friction stir welding is a relatively new way to join solid materials without melting using a nonconsumable tool, which has many applications in different industries including automotive, shipbuilding, and aerospace. Destructive testing is an integral part of engineering science, which costs a lot. Reducing the number of destructive tests via numerical calculations to determine the quality of welded parts is valuable. On the other hand, advances in computer technology and embedded sensing systems in different domains have made it possible to collect a variety of data in huge volume at an unbelievable velocity, which provides an opportunity and at the same time a challenge to engineers and practitioners to utilize this rich source of information efficiently. Functional data as a rich form of structured data allows for high dimensionality modeling and analysis of the data. In this paper, we develop a fully functional linear regression model to quantify and predict the quality of the process outputs by reducing the number of destructive tests and presenting a change-point detection model to avoid using the model when a change has occurred in one of the components of the process. Important issues such as autocorrelation and correlation are taken into account in the presented model. The functional variables of the model are solved by polynomial basis function expansions. The results of the experimental tests indicate that the proposed method performs well in detecting out-of-control conditions as well as estimating the change-point location. The obtained value of the multiple correlation coefficient 0.98 and the corresponding F-value equal to 652.95 support these results.

摘要 搅拌摩擦焊是一种使用非消耗性工具在不熔化的情况下连接固体材料的相对较新的方法,在汽车、造船和航空航天等不同行业有许多应用。破坏性测试是工程科学不可或缺的一部分,其成本很高。通过数值计算来确定焊接件的质量,从而减少破坏性试验的次数,这是非常有价值的。另一方面,计算机技术和嵌入式传感系统在不同领域的发展,使得以难以置信的速度收集各种海量数据成为可能,这为工程师和从业人员有效利用这些丰富的信息来源提供了机遇,同时也带来了挑战。功能数据作为结构化数据的一种丰富形式,可以对数据进行高维建模和分析。在本文中,我们开发了一个全功能线性回归模型,通过减少破坏性测试的数量来量化和预测流程输出的质量,并提出了一个变化点检测模型,以避免在流程的某个组件发生变化时使用该模型。所提出的模型考虑到了自相关性和相关性等重要问题。模型的函数变量通过多项式基函数展开求解。实验测试结果表明,所提出的方法在检测失控条件和估计变化点位置方面表现良好。多重相关系数 0.98 和相应的 F 值 652.95 均支持这些结果。
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引用次数: 0
Investigation on Thermomechanical Bending of Functionally Graded Sandwich Plates Using a Novel Combined 2D Integral Plate Model 使用新型组合二维积分板模型研究功能分级三明治板的热力学弯曲问题
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040118
H. Belarbi, B. Boucham, F. Bourada, A. Kaci, M. Bourada, A. Tounsi

This study presents the flexural analysis of Ti-6A1-4V/ZrO2 functionally graded (FG) sandwich plates under combined thermal and mechanical loading via exponential-cubic-sinusoidal integral shear deformation theory. The current formulation used in the modeling provides a parabolic distribution of transverse shear stresses without requiring additional factors in the formulation. Various sandwich plate models with different layer thicknesses and material types are considered. The FG layers vary continuously and smoothly according to exponential and power-law functions. The governing differential equations of the system are derived and solved analytically using the virtual work principle and Navier’s approach. Benchmark comparisons are performed to validate and show the accuracy of the proposed model. Various parametric examples are presented to illustrate the effect of the geometry, dimensions, FG sandwich type and material gradient on the static flexural response of the studied structure.

摘要 本研究通过指数-立方-正弦积分剪切变形理论,对热和机械联合加载下的 Ti-6A1-4V/ZrO2 功能分级(FG)夹层板进行了弯曲分析。目前用于建模的公式提供了横向剪应力的抛物线分布,而无需在公式中加入额外的因素。考虑了不同层厚和材料类型的各种夹层板模型。FG 层根据指数函数和幂律函数连续平稳地变化。利用虚功原理和纳维方法推导并分析解决了系统的支配微分方程。进行了基准比较,以验证和显示所提模型的准确性。此外,还介绍了各种参数示例,以说明几何形状、尺寸、FG 夹层类型和材料梯度对所研究结构的静态弯曲响应的影响。
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引用次数: 0
One of the Scenarios for Supershear Earthquakes 超剪切地震场景之一
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040064
A. M. Budkov, S. B. Kishkina

This paper is a part of the study on the rupture propagation and seismic wave emission during the movement along the fault, whose fracture surface in different regions is made of geomaterials with different frictional properties. The slip surface of the fault is frictionally heterogeneous. It contains weakening zones (asperities), strengthening zones (barriers), and “background” zones that are almost neutral with respect to velocity and displacement. The scenario of a seismogenic rupture is determined precisely by the presence, number, and size of such zones with different dynamics of frictional characteristics. The study deals with the mechanics of supershear earthquakes, in which the rupture propagates with an unusually high velocity exceeding the shear wave velocity of the medium. Numerical simulation results confirm the existence of two different mechanisms governing the transition of an earthquake to the supershear regime. A model of the so-called “weak” fault is considered, for which the rupture velocity continuously increases from the sub-Rayleigh velocity CR to the shear wave velocity Cs and quickly exceeds it without any jump. This scenario is typical for faults with the measure of strength S under 0.8. The solved problem is not only of fundamental importance for understanding the earthquake mechanics, but also can find application in engineering seismology and the study of earthquake-induced rupture processes, because unlike an ordinary earthquake, supershear or fast ruptures cause strong shaking at a much greater distance from the source of the event (from the fault). This is confirmed by direct data on near-field ground motion obtained in recent years by research groups from different countries.

摘要 本文是关于沿断层运动过程中断裂传播和地震波发射的研究的一部分,断层在不同区域的断裂面由具有不同摩擦特性的岩土材料构成。断层的滑动面具有摩擦异质性。它包含减弱区(尖角)、加强区(屏障)以及在速度和位移方面几乎保持中立的 "背景 "区。地震破裂的情况正是由这些具有不同摩擦动力学特征的区域的存在、数量和大小决定的。本研究涉及超剪切地震的力学原理,在超剪切地震中,破裂传播速度异常之快,超过了介质的剪切波速度。数值模拟结果证实,地震过渡到超剪切机制存在两种不同的机制。我们考虑了所谓的 "弱 "断层模型,在该模型中,破裂速度从亚雷利波速度 CR 持续上升到剪切波速度 Cs,并迅速超过该速度,没有任何跳跃。这种情况在强度 S 小于 0.8 的断层中很典型。所解决的问题不仅对理解地震力学具有根本性的重要意义,而且可以应用于工程地震学和地震诱发破裂过程的研究,因为与普通地震不同,超剪切或快速破裂会在距离事件源(断层)更远的地方引起强烈震动。各国研究小组近年来获得的近场地面运动直接数据证实了这一点。
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引用次数: 0
Grain Interaction and Elastic Strain Distribution in Polycrystalline Materials 多晶材料中的晶粒相互作用和弹性应变分布
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040076
V. E. Shavshukov

Statistical distributions of the elastic strain and stress tensor components in the grains of polycrystalline materials are necessary to calculate the probabilities of various local critical events, such as damage and others, which are of random origin due to the stochastic grain structure. Many experimental and computational studies suggest that these distributions can be approximated by a normal distribution. The normal distribution parameters are determined from histogram-like plots obtained experimentally or by computer simulation. Most published histogram distributions are highly skewed, in contrast to the normal distribution. Here we present a new direct calculation method for the probability densities of the elastic strain tensor components. The method uses an integral equation for strains in heterogeneous solids, which reduces the solution of the boundary value problem of polycrystal deformation to the sum of solutions of some problems for neighboring grains. The focus is on the influence of random grain interactions on the strain distribution. Calculations are carried out for polycrystals with different elastic symmetries and degrees of grain anisotropy. All probability densities are finite, asymmetric, and noticeably different from Gaussian ones. It is shown that very few particularly located neighboring grains (of dozens) have a much greater effect on the distribution pattern and limiting values of the strain tensor components than all the others.

摘要多晶材料晶粒中弹性应变和应力张量分量的统计分布对于计算各种局部临界事件(如损伤等)的概率是必要的,这些事件由于随机的晶粒结构而具有随机性。许多实验和计算研究表明,这些分布可以用正态分布来近似。正态分布参数是通过实验或计算机模拟获得的直方图确定的。与正态分布相比,大多数已发表的直方图分布高度倾斜。在此,我们介绍一种直接计算弹性应变张量分量概率密度的新方法。该方法使用了异质固体应变积分方程,将多晶体变形边界值问题的解简化为相邻晶粒某些问题的解之和。重点是随机晶粒相互作用对应变分布的影响。计算针对具有不同弹性对称性和晶粒各向异性程度的多晶体。所有的概率密度都是有限的、不对称的,并且与高斯概率密度明显不同。研究表明,极少数位置特殊的相邻晶粒(多达数十个)对应变张量分量的分布模式和极限值的影响远大于其他所有晶粒。
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引用次数: 0
Damping Characteristics of Nonlocal Strain Gradient Waves in Thermoviscoelastic Graphene Sheets Subjected to Nonlinear Substrate Effects 受非线性基底效应影响的热弹性石墨烯薄片中的非局部应变梯度波的阻尼特性
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040106
R. Selvamani, T. Prabhakaran, F. Ebrahimi

The present study explores dispersion characteristics of thermal, viscoelastic and mechanical waves in graphene sheets subjected to uniform thermal loading and supported by the visco-Pasternak foundation. Kinematic relations for graphene sheets are deduced within two-variable refined higher-order plate theory. Damping effects of the viscoelastic medium are modeled using the Kelvin–Voigt model. The research extensively investigates the size-dependent behavior of graphene sheets by incorporating nonlocal strain gradient theory. Nonlocal governing equations are formulated under Hamilton’s principle and solved analytically to determine wave frequency values. To validate the results, a comparative analysis is conducted, and the outcomes are tabulated to confirm the effectiveness of the approach. Finally, graphical representations are employed to depict the influence of each parameter on the wave propagation responses of graphene sheets.

摘要 本研究探讨了石墨烯片在均匀热载荷和粘弹性-帕斯捷尔纳克基础支撑下的热波、粘弹性波和机械波的弥散特性。根据二变量精炼高阶板理论推导了石墨烯片的运动学关系。粘弹性介质的阻尼效应使用 Kelvin-Voigt 模型进行建模。研究结合非局部应变梯度理论,广泛研究了石墨烯片的尺寸依赖行为。根据汉密尔顿原理制定了非局部治理方程,并通过分析求解确定了波频值。为验证结果,进行了对比分析,并将结果列表以确认该方法的有效性。最后,采用图形表示法描述了各参数对石墨烯片波传播响应的影响。
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引用次数: 0
Investigation of Thermal Impacts and Different Gradient Elasticity Theories on Wave Propagation through the Polymer Matrix Incorporated Carbon Nanotube Walls 热影响和不同梯度弹性理论对穿透聚合物基质碳纳米管壁的波传播的影响研究
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S102995992404012X
K. Antar, Kh. Amara, A. Besseghier

This paper explores the vibrational properties of double-walled carbon nanotubes embedded in a polymer matrix within different gradient elasticity theories. The study considers how the mechanical behavior of double-walled carbon nanotubes and the polymer matrix changes with temperature. The research highlights the significance of scale effects on wave propagation in double-walled carbon nanotubes and shows that certain characteristics of transverse vibrations in double-walled carbon nanotubes are affected by temperature variations. In addition, the paper derives consistent governing equations for modeling free transverse vibrations of double-walled carbon nanotubes using the nonlocal Euler–Bernoulli beam model, considering the effects of temperature and Van der Waals forces between the inner and outer nanotubes.

摘要 本文根据不同的梯度弹性理论探讨了嵌入聚合物基体中的双壁碳纳米管的振动特性。研究考虑了双壁碳纳米管和聚合物基体的机械行为如何随温度变化。研究强调了尺度效应对双壁碳纳米管中波传播的重要影响,并表明双壁碳纳米管中横向振动的某些特性会受到温度变化的影响。此外,考虑到温度和内外纳米管之间范德华力的影响,论文利用非局部欧拉-伯努利梁模型推导出了双壁碳纳米管自由横向振动建模的一致控制方程。
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引用次数: 0
Mechanical Properties of the Al3(TiTaZrNbHf) High Entropy Intermetallic Compound: A Molecular Dynamic Study Al3(TiTaZrNbHf) 高熵金属间化合物的力学性能:分子动力学研究
IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2024-08-23 DOI: 10.1134/S1029959924040088
A. Ostovari Moghaddam, R. Fereidonnejad, D. V. Mikhailov, M. Naseri, E. A. Trofimov

Deformation mechanisms of the Al3(TiTaZrNbHf) high entropy intermetallic compound under tensile loading were studied using molecular dynamic simulations. To this end, the site occupancy of the five constituent atoms that form the high entropy sublattice of Al3(TiTaZrNbHf) was first determined by simulating the near-equilibrium melting/crystallization process. It is shown that nuclei of intrinsic stacking faults are formed under early plastic deformation due to dislocation nucleation and glide, which further contribute to the formation and growth of twin boundaries. Twinning and 1/6<112> Shockley partial dislocations are key components in the plastic deformation of Al3(TiTaZrNbHf) at room and elevated temperatures, which is in good agreement with the experimental observations for D022-structured materials. The tensile strength of Al3(TiTaZrNbHf) is 4.6 GPa at 300 K and slightly decreases to 4.34 GPa at 1000 K, highlighting the unique properties of high entropy intermetallic compounds in retaining their mechanical properties at elevated temperatures. The derived results provide grounds for understanding the atomic-scale origin of deformation mechanisms in high entropy intermetallic compounds. They also show potentials for tailoring the chemical composition of intermetallic compounds to overcome the problem of low ductility, paving the way to their industrial applications.

摘要利用分子动力学模拟研究了 Al3(TiTaZrNbHf)高熵金属间化合物在拉伸载荷作用下的变形机制。为此,首先通过模拟近平衡熔化/结晶过程确定了构成 Al3(TiTaZrNbHf)高熵亚晶格的五个组成原子的位点占有率。结果表明,在早期塑性变形过程中,由于位错成核和滑行,形成了本征堆积断层核,进一步促进了孪晶边界的形成和生长。孪晶和 1/6<112> 肖克利部分位错是室温和高温下 Al3(TiTaZrNbHf)塑性变形的关键成分,这与 D022 结构材料的实验观察结果十分吻合。Al3(TiTaZrNbHf) 的拉伸强度在 300 K 时为 4.6 GPa,在 1000 K 时略微下降至 4.34 GPa,突出了高熵金属间化合物在高温下保持其机械性能的独特特性。推导结果为理解高熵金属间化合物变形机制的原子尺度起源提供了依据。这些结果还显示了调整金属间化合物化学成分以克服低延展性问题的潜力,为金属间化合物的工业应用铺平了道路。
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引用次数: 0
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