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Chloride penetration resistance of concrete under dual effects of leaching and stress 混凝土在浸出和应力双重作用下的抗氯化物渗透能力
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-03-11 DOI: 10.1680/jadcr.23.00227
Shaowei Wang, Wenlong Gao, Yanyu Xiao, Jiawen Wu, Qun Xia
Chloride penetration is one of the main causes for the failure of reinforced concrete structures, especially in undersea tunnels, which is also accompanied by stress and seepage water-induced calcium leaching. In this paper, the chloride penetration resistances of concrete under the single and dual effects of stress and calcium leaching were investigated, and the microscopic mechanism was explained by Scanning Electron Microscopy (SEM) and X-ray diffraction analysis (XRD). The results show that the chloride diffusion depth and chloride content linearly increase with the stress level in the tensile zone, while linearly decrease in the compressive zone, and the change is more obvious in the tensile zone. At stress levels of 15%, 30%, and 45%, the diffusion depth in the tensile zone increases by 11.4%, 36.6%, and 43.5%, respectively, and the increased ratios of chloride content are 1.2%, 11.2%, and 19.4%. There is no significant synergistic effect between stress and calcium leaching on chloride diffusion depth, but it is obvious on chloride content, especially when the tensile stress level is below 15% and the compressive stress level is above 30%, for which the differences caused by considering the synergistic effect or not are approximately 6% and 15%, respectively.
氯化物渗透是钢筋混凝土结构失效的主要原因之一,尤其是在海底隧道中,同时还伴随着应力和渗水引起的钙浸出。本文研究了混凝土在应力和钙浸出单一效应和双重效应下的抗氯化物渗透性能,并通过扫描电子显微镜(SEM)和 X 射线衍射分析(XRD)解释了其微观机理。结果表明,在拉伸区,氯化物扩散深度和氯化物含量随应力水平的增加呈线性增加,而在压缩区则呈线性减少,且拉伸区的变化更为明显。当应力水平为 15%、30% 和 45% 时,拉伸区的扩散深度分别增加了 11.4%、36.6% 和 43.5%,氯化物含量的增加比率分别为 1.2%、11.2% 和 19.4%。应力和钙浸出对氯化物扩散深度没有明显的协同效应,但对氯化物含量有明显的协同效应,特别是当拉伸应力水平低于 15%、压缩应力水平高于 30%时,考虑协同效应与否造成的差异分别约为 6%和 15%。
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引用次数: 0
Influence of thermochemical high-temperature reconstruction on mechanical properties and activity of stainless steel slag 热化学高温重构对不锈钢渣机械性能和活性的影响
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-02-24 DOI: 10.1680/jadcr.23.00083
Pengjie Xu, Jintao Fan, Rongjin Liu, Ping Chen, Jiazhan Wei, Yi Yang, Xiaochun Tang
The stainless steel slag's low activity, primarily attributed to its high γ-C2S and low C3S content, impedes its effective utilization. This study employs a thermochemical high-temperature reconstruction method utilizing lime and bauxite as tempering agents to regulate the mineral phase. Through an array of tests and analytical techniques, including compressive strength test, activity index, XRD, SEM, and hydration heat analysis, the impact of Ca/Si ratio and sintering temperature on the mechanical properties and activity of reconstituted stainless steel slag mortar is examined. The findings indicate that at a Ca/Si ratio of 4.2 and a sintering temperature of 1290°C, the reconstructed slag demonstrates optimal mechanical properties and activity, yielding compressive strengths of 43.69 MPa and 62.58 MPa at 7 days and 28 days, respectively, with remarkable 28 day activity index of 143.49%. The proposed thermochemical high-temperature reconstruction method ingeniously employs high temperature to increase the content of C3S while rapid cooling prevents the alteration of the C2S crystalline structure. This innovation significantly enhances the mechanical properties and activity of the stainless steel slag, offering promising avenues to increase its utilization rate.
不锈钢渣的活性较低,主要原因是其γ-C2S 含量较高,而 C3S 含量较低,这阻碍了其有效利用。本研究采用热化学高温重构法,利用石灰和铝矾土作为调质剂来调节矿物相。通过一系列测试和分析技术,包括抗压强度测试、活性指数、XRD、SEM 和水化热分析,研究了 Ca/Si 比和烧结温度对重组不锈钢渣砂浆机械性能和活性的影响。研究结果表明,在 Ca/Si 比为 4.2 和烧结温度为 1290°C 的条件下,重构矿渣具有最佳的机械性能和活性,7 天和 28 天的抗压强度分别为 43.69 兆帕和 62.58 兆帕,28 天活性指数高达 143.49%。所提出的热化学高温重构方法巧妙地利用高温来增加 C3S 的含量,同时快速冷却以防止 C2S 晶体结构的改变。这一创新大大提高了不锈钢渣的机械性能和活性,为提高其利用率提供了广阔的前景。
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引用次数: 0
Effects of stream curing on the pore structure of recycled aggregate concrete 流水养护对再生骨料混凝土孔隙结构的影响
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-02-19 DOI: 10.1680/jadcr.22.00092
Yuzhi Chen, Yingjie Ning, Xudong Chen, Weihong Xuan, Yuzhu Guo
Pore in steam-cured concrete affect its strength and durability, and the optimization of steaming system can improve the pore structure to some extent. However, the influence mechanism of evaporation on recycled aggregate concrete (RCA) remains unclear. In this paper, the effects of curing temperature (20°C, 40°C, 60°C and 80°C), steam curing time (6h, 9h and 12h) and pozzolans (slag powder and fly ash) on the compressive strength and pore structure of RAC were studied. The microstructure characteristics such as pore size and pore size distribution were analyzed by the mercury injection porosimetry. The results shown that steam curing can significantly improve the compressive strength and reduce the most probable aperture and average pore sizes of RAC. Moreover, the effect of slag powder on RAC pore structure is better than that of fly ash. And there is a linear correlation between the compressive strength and the average pore size of steam-cured RAC. This can be an important parameter for constructing future steam cured RAC strength prediction models.
蒸养混凝土中的孔隙会影响其强度和耐久性,优化蒸养系统可在一定程度上改善孔隙结构。然而,蒸发对再生骨料混凝土(RCA)的影响机理尚不清楚。本文研究了养护温度(20°C、40°C、60°C 和 80°C)、蒸气养护时间(6 小时、9 小时和 12 小时)和胶凝剂(矿渣粉和粉煤灰)对再生骨料混凝土抗压强度和孔隙结构的影响。孔隙大小和孔隙分布等微观结构特征由汞注射孔隙测定法进行分析。结果表明,蒸汽固化能显著提高 RAC 的抗压强度,降低其最大可能孔径和平均孔径。此外,矿渣粉对 RAC 孔隙结构的影响优于粉煤灰。而且,蒸汽固化 RAC 的抗压强度与平均孔径之间存在线性关系。这可以作为未来构建蒸汽固化 RAC 强度预测模型的一个重要参数。
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引用次数: 0
Enhancing piezoresistivity of cement sensor with supplementary materials and carbonation curing 利用补充材料和碳化固化提高水泥传感器的压阻系数
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-02-08 DOI: 10.1680/jadcr.23.00202
Daeik Jang, Jinho Bang, Haemin Jeon
This study explores the fabrication of cement-based sensors blended with supplementary cementitious materials (SCM) using carbonation curing. The effects of SCM types (i.e. fly ash or slag) and curing conditions on CO2 uptake degree, compressive strength, electrical conductivity, and piezoresistive sensing capability were systematically examined. The results indicate that the inclusion of fly ash or slag enhances CO2 uptake degree. However, it is also found that the excessive carbonation curing negatively affects compressive strength. Electrical resistivity is increased after carbonation curing due to carbonation-induced hydrate formation disrupting CNT-based conductive networks. The piezoresistive sensing capability is influenced by binder types and curing conditions, with higher sensitivity observed in samples blended with fly ash.
本研究探讨了利用碳化固化法制造掺有辅助胶凝材料(SCM)的水泥基传感器。系统研究了 SCM 类型(即粉煤灰或矿渣)和固化条件对二氧化碳吸收率、抗压强度、电导率和压阻传感能力的影响。结果表明,加入粉煤灰或矿渣可提高二氧化碳吸收率。但同时也发现,过度碳化固化会对抗压强度产生负面影响。碳化固化后电阻率增加,这是由于碳化引起的水合物形成破坏了基于 CNT 的导电网络。压阻传感能力受粘合剂类型和固化条件的影响,与粉煤灰混合的样品灵敏度更高。
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引用次数: 0
Enhancing piezoresistivity of cement sensor with supplementary materials and carbonation curing 利用补充材料和碳化固化提高水泥传感器的压阻系数
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-02-08 DOI: 10.1680/jadcr.23.00202
Daeik Jang, Jinho Bang, Haemin Jeon
This study explores the fabrication of cement-based sensors blended with supplementary cementitious materials (SCM) using carbonation curing. The effects of SCM types (i.e. fly ash or slag) and curing conditions on CO2 uptake degree, compressive strength, electrical conductivity, and piezoresistive sensing capability were systematically examined. The results indicate that the inclusion of fly ash or slag enhances CO2 uptake degree. However, it is also found that the excessive carbonation curing negatively affects compressive strength. Electrical resistivity is increased after carbonation curing due to carbonation-induced hydrate formation disrupting CNT-based conductive networks. The piezoresistive sensing capability is influenced by binder types and curing conditions, with higher sensitivity observed in samples blended with fly ash.
本研究探讨了利用碳化固化法制造掺有辅助胶凝材料(SCM)的水泥基传感器。系统研究了 SCM 类型(即粉煤灰或矿渣)和固化条件对二氧化碳吸收率、抗压强度、电导率和压阻传感能力的影响。结果表明,加入粉煤灰或矿渣可提高二氧化碳吸收率。但同时也发现,过度碳化固化会对抗压强度产生负面影响。碳化固化后电阻率增加,这是由于碳化引起的水合物形成破坏了基于 CNT 的导电网络。压阻传感能力受粘合剂类型和固化条件的影响,与粉煤灰混合的样品灵敏度更高。
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引用次数: 0
Preparation of alkali-free liquid accelerator with fluorine-containing silicon residue and its accelerating mechanism 含氟硅残留物的无碱液体促进剂的制备及其促进机理
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-01-19 DOI: 10.1680/jadcr.23.00151
Dinghu Wu, Xiaotong Liu, Yuan Liu, Anxu Yang, Lin Yang
Fluorine-containing silicon residue is a solid waste that is harmful to the environment. A new Al2(SO4)3 base alkali-free liquid accelerator (LAFS) was prepared by using fluorine-containing silicon residue. The LAFS shortens the setting time and significantly improves the early strength. When the content of LAFS reaches 8.0 %, the initial setting time and final setting time of cement are 2.48 min and 11.83 min respectively, and the 1d compressive strength reaches 14.6 MPa, which is 200 % of the mortar without LAFS. In this paper, the mechanism of action of LAFS was studied by the isothermal calorimeter test, XRD, TG, SEM, and other analytical methods. The results show that the LAFS rapidly generates a large amount of ettringite in cement paste. Moreover, the LAFS promotes the formation of calcium silicate hydrate in cement paste. Finally, a conceptual model of the early hydration process of the cement paste with LAFS was established based on the analytical results.
含氟硅渣是一种对环境有害的固体废物。利用含氟硅渣制备了一种新型 Al2(SO4)3 碱无碱液体促进剂(LAFS)。LAFS 可缩短凝结时间,显著提高早期强度。当 LAFS 含量达到 8.0 % 时,水泥的初凝时间和终凝时间分别为 2.48 min 和 11.83 min,1d 抗压强度达到 14.6 MPa,是不含 LAFS 的砂浆的 200%。本文通过等温量热仪试验、XRD、TG、SEM 等分析方法研究了 LAFS 的作用机理。结果表明,LAFS 能迅速在水泥浆中生成大量的乙曲石。此外,LAFS 还能促进水泥浆中硅酸钙水合物的形成。最后,根据分析结果建立了含 LAFS 水泥浆早期水化过程的概念模型。
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引用次数: 0
Utilization of local raw materials and mine waste to manufacture cement in Northwest Territories, Canada 在加拿大西北地区利用当地原材料和矿山废料生产水泥
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-01-19 DOI: 10.1680/jadcr.23.00195
Guangping Huang, Jian Zhao, G. L. Dzemua, Scott Cairns, Philippe Normandeau, W. Liu
Currently, all the cement consumed in Northwest Territories (NWT), Canada, is imported from other provinces (e.g., Alberta) by long-distance (∼1,800 km) truck freight. Transporting cement over long distances not only raises its cost, but also results in a higher carbon footprint. Locally producing cement is a potential low-carbon and economic solution for the local industry. However, it is unknown if the local raw materials are suitable for cement manufacturing; and there is a lack of a critical raw material—Iron ore—for cement manufacturing. Instead of iron ore, there are iron-rich tailings from a local rare earth element (REE) mine. Towards low-carbon and circular economy, this study explored the use of local raw materials (i.e., limestone, clay, and gypsum) and mine waste (REE tailings) to manufacture cement in the NWT and successfully produced the first bag of cement in the history of the NWT. The results showed that concrete samples made with NWT cement achieved comparable strength of commercial OPC-based concrete. An emission estimation suggested that locally producing cement in the NWT has the potential to reduce 3.0%–61.7% of CO2 emissions when compared with importing cement from other provinces.
目前,加拿大西北地区(NWT)消耗的所有水泥都是通过长途(1,800 公里)卡车货运从其他省份(如阿尔伯塔省)进口的。长途运输水泥不仅会提高成本,还会造成更高的碳足迹。在当地生产水泥对当地工业来说是一种潜在的低碳经济解决方案。然而,当地的原材料是否适合生产水泥尚不得而知,而且当地缺乏生产水泥的关键原材料--铁矿石。代替铁矿石的是当地稀土元素(REE)矿的富含铁的尾矿。为了实现低碳和循环经济,本研究探索了利用当地原材料(即石灰石、粘土和石膏)和矿山废料(稀土元素尾矿)在西北地区制造水泥的方法,并成功生产出西北地区历史上第一袋水泥。结果表明,使用西北地区水泥制成的混凝土样品的强度与基于商品 OPC 的混凝土相当。排放量估算表明,与从其他省份进口水泥相比,在西北地区本地生产水泥有可能减少 3.0%-61.7% 的二氧化碳排放量。
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引用次数: 0
Evaluation of compressive strength and chloride permeability of cement-based materials with high-volume compound mineral admixtures 使用高容量复合矿物掺合料评估水泥基材料的抗压强度和氯离子渗透性
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-01-19 DOI: 10.1680/jadcr.23.00185
Nannan Zhang, Qionglin Fu, Junfeng Wang, Liulei Lu, Qi Luo, Feng Xing
Ground granulated blast furnace slag (GGBFS) is well known as the capable of improving the performance of cement-based materials, but few studies focus on the impact of its large dosage on concrete containing basalt powder. In this study, the compressive strength and chloride permeability of cement-based materials with compound mineral admixtures (CMAs) containing the high-volume GGBFS, basalt powder, and desulfurization gypsum were investigated. The results showed that the mortar strengths at 3, 7, and 28 days decreased with increasing GGBFS content, but that at 56 and 84 days increased with the addition of 45 wt.% GGBFS. This is because the activity of GGBFS at early stage has not been stimulated and the pozzolanic effect is exerted at later stage. Moreover, cement replacement with up to 55 wt.% GGBFS caused a significant decrease in the chloride diffusion coefficient of the mortar and concrete. Furthermore, the incorporation of GGBFS led to a remarkable refinement in pore structure of the hardened paste due to the pozzolanic and filler effects. Therefore, the partial replacement of cement with high CMA contents (≥ 70 wt.%) in concrete is desirable for ocean projects requiring low chloride permeability and significantly reduces carbon emissions.
众所周知,磨细高炉矿渣(GGBFS)能够改善水泥基材料的性能,但很少有研究关注其大掺量对含有玄武岩粉的混凝土的影响。在这项研究中,研究了含有高掺量 GGBFS、玄武岩粉和脱硫石膏的复合矿物掺合料(CMA)的水泥基材料的抗压强度和氯离子渗透性。结果表明,随着 GGBFS 含量的增加,砂浆在 3 天、7 天和 28 天时的强度降低,但在 56 天和 84 天时,GGBFS 的添加量增加。这是因为 GGBFS 在早期阶段的活性没有被激发出来,而在后期阶段才发挥出了水合作用。此外,用最高达 55 wt.% 的 GGBFS 替代水泥会显著降低灰浆和混凝土的氯离子扩散系数。此外,由于水青石和填料的作用,掺入 GGBFS 后硬化浆料的孔隙结构明显改善。因此,对于要求低氯离子渗透率的海洋工程来说,在混凝土中用高 CMA 含量(≥ 70 wt.%)的水泥部分替代水泥是可取的,并能显著减少碳排放。
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引用次数: 0
Characteristics of the corrosion products of steel bars in modified magnesium oxysulfide cement containing chloride salts 含有氯盐的改性氧化镁水泥中钢筋腐蚀产物的特征
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-01-12 DOI: 10.1680/jadcr.23.00141
Mingfang Ba, Siyi Fang, Zhirui Xu, Gaoke Yu, Danlei Zhang
The effects of chlorides on the corrosion of steel bars within a matrix comprising modified magnesium oxysulfide (MMOS) cementitious materials was investigated in this study, containing the phase composition, morphology, and distribution of steel corrosion products. The results showed that there was basically no corrosion of the steel bars in MMOS cement without chlorides. The presence of high chloride content and a high water-cement ratio in MMOS matrix had adverse effects on the corrosion of steel bars. The primary product of steel corrosion in MMOS was FeOOH and Fe2O3, while FeO was only observed at low water cement ratios, indicating a lower degree of oxidation. Moreover, the presence of Fe2(CO)9 at high water cement ratios suggests a higher degree of oxidation. At lower water-cement ratios, rust products readily diffused; Conversely, at higher ratios, these products accumulated in proximity to the steel bars, forming a compact structure.
本研究调查了氯化物对由改性氧化镁(MMOS)水泥基材料组成的基体中钢筋腐蚀的影响,包括钢筋腐蚀产物的相组成、形态和分布。结果表明,在不含氯化物的 MMOS 水泥中,钢筋基本上没有腐蚀。高氯化物含量和高水灰比的 MMOS 基体对钢筋的腐蚀有不利影响。在 MMOS 中钢筋锈蚀的主要产物是 FeOOH 和 Fe2O3,而只有在低水灰比时才能观察到 FeO,这表明氧化程度较低。此外,高水灰比时出现的 Fe2(CO)9 表明氧化程度较高。在较低的水灰比下,锈产物很容易扩散;相反,在较高的水灰比下,这些产物聚集在钢筋附近,形成紧密的结构。
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引用次数: 0
Advances in Cement Research: Referees 2023 水泥研究进展》:参考文献 2023
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2024-01-01 DOI: 10.1680/jadcr.2024.36.1.45
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引用次数: 0
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Advances in Cement Research
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