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Investigation of dynamic compression properties of basalt fiber reactive powder concrete 玄武岩纤维活性粉末混凝土动态压缩性能研究
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2023-12-04 DOI: 10.1680/jadcr.23.00007
Haiyang Sha, Jinchun Liu, Xianwen Fu
Basalt fiber reactive powder concrete (BFRPC) was prepared by incorporating basalt fibers (BFs) instead of steel fiber into reactive powder concrete (RPC). In this study, we experimentally and numerically analyzed the impact resistance of BFRPC at different strain rates (101∼101 s1). The Φ75mm Split Hopkinson pressure bar (SHPB) was used for impact compression tests and the finite element software LS-DYNA was used for numerical simulation analysis. The results showed that the high strength BFRPC has an obvious strain rate effect and the dynamic growth factor (DIF) of compressive strength increases logarithmically with strain rate. Meanwhile, the parameters of the CEB model were refitted and the relationship between strain rate and DIF was established. By using the Johnson_Holmquist_Concrete material constitutive model (HJC model), the stress-strain curves and failure patterns obtained were consistent with the experimental results. The incorporation of BFs significantly improve the deformation properties of BFRPC.
将玄武岩纤维(BFs)代替钢纤维掺入活性粉末混凝土(RPC)中制备玄武岩纤维活性粉末混凝土(BFRPC)。在本研究中,我们通过实验和数值分析了BFRPC在不同应变速率(101 ~ 101 s1)下的抗冲击性。采用Φ75mm Split Hopkinson压杆(SHPB)进行冲击压缩试验,采用LS-DYNA有限元软件进行数值模拟分析。结果表明:高强度BFRPC具有明显的应变速率效应,抗压强度动态生长因子(DIF)随应变速率呈对数增长;同时,对CEB模型参数进行了修正,建立了应变速率与DIF之间的关系。采用Johnson_Holmquist_Concrete材料本构模型(HJC模型),得到的应力-应变曲线和破坏模式与试验结果一致。BFs的加入显著改善了BFRPC的变形性能。
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引用次数: 0
Effect of gypsum on the hydration of fused cement clinker from basic oxygen furnace slag 石膏对碱性氧炉渣水泥熟料水化的影响
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2023-11-24 DOI: 10.1680/jadcr.23.00070
Katharina Schraut, Burkart Adamczyk, Christian Adam, Dietmar Stephan, Birgit Meng, Sebastian Simon, Julia von Werder, Tamino Hirsch, Tanja Manninger
Fused cement clinker can be produced from molten basic oxygen furnace slag (BOFS) via a reductive thermochemical treatment. During the thermochemical treatment, oxidic iron is reduced to metallic iron and separated. The resulting low-iron slag has a chemical and mineralogical composition similar to ordinary Portland cement (OPC) clinker. In this study, the hydraulic reactivity of the fused clinker from BOFS (BOFS) with and without gypsum was investigated using isothermal calorimetry, differential scanning calorimetry (DSC), in-situ X-ray diffraction and powder X-ray diffraction (PXRD). Furthermore, a synthetic fused clinker without foreign ions and fused clinker produced by a mixture of both materials was studied. The hydraulic reaction of the fused clinker from BOFS was considerably slower than that of ordinary Portland cement. However, the reaction can be accelerated by adding gypsum as a sulfate carrier. Furthermore, the results showed an increased reaction rate with decreasing content of foreign ions such as Fe, P or Mn.
熔融碱性氧炉渣经还原性热化学处理可制成水泥熟料。在热化学处理过程中,氧化铁被还原为金属铁并被分离。由此产生的低铁渣具有类似于普通硅酸盐水泥(OPC)熟料的化学和矿物组成。采用等温量热法、差示扫描量热法(DSC)、原位x射线衍射法(原位x射线衍射法)和粉末x射线衍射法(PXRD)研究了含石膏和不含石膏的BOFS (BOFS)熔融熟料的水力反应性。研究了无外源离子的合成熔融熟料和两种材料混合生产的熔融熟料。BOFS熟料的水力反应明显慢于普通硅酸盐水泥。然而,加入石膏作为硫酸盐载体可以加速反应。结果表明,随着Fe、P、Mn等外源离子含量的降低,反应速率加快。
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引用次数: 0
Parametric analysis of the production of alternative sodium silicate applied in alkali-activated materials 用于碱活性材料的替代水玻璃的参数分析
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2023-11-21 DOI: 10.1680/jadcr.23.00005
Deise Trevizan Pelissaro, Suelen Cristina Vanzetto, Francisco Dalla Rosa, Pedro Domingos Marques Prietto, Adriana Augustin Silveira
Although alkali-activated materials are considered potential substitutes for Portland cement, they still present elevated costs and significant emissions of CO2. One way to partially overcome this disadvantage is the development of alternative activators, such as a sodium silicate based on the dissolution of rice husk ash (RHA). However, to maximize the mechanical performance of alkali-activated materials, the production of RHA-based sodium silicates needs to be fully understood. This article investigates the production process of an alternative RHA-based sodium silicate activator through the experimental evaluation of the following parameters: RHA grinding time, RHA dissolution time, thermal curing temperature and time. The mechanical performance was evaluated through compressive strength tests carried out on alkali-activated pastes made up of metakaolin, as a precursor, and two types of activators (RHA-based sodium silicate and commercial sodium silicate). Microstructural features were evaluated by performing X-Ray Diffraction, Scanning Electron Microscopy, and Thermogravimetry analyses. The optimized production was obtained for a grinding time of 30 minutes, a thermal curing temperature of 40°C, a dissolution time of 6 hours, and a thermal curing time of 8 hours. The results show the efficiency of the alternative alkaline activator, which may represent a technically viable solution for the larger-scale application of alkali-activated materials.
尽管碱活化材料被认为是波特兰水泥的潜在替代品,但它们仍然存在成本较高和大量二氧化碳排放的问题。部分克服这一缺点的一种方法是开发替代活化剂,例如基于稻壳灰(RHA)溶解的水玻璃。然而,为了最大限度地发挥碱活化材料的力学性能,需要充分了解rhaa基硅酸钠的生产。本文通过对RHA研磨时间、RHA溶解时间、热固化温度和时间等参数的实验评价,研究了一种替代RHA基水玻璃活化剂的生产工艺。通过对以偏高岭土为前驱体和两种类型的活化剂(基于rhaa的水玻璃钠和商用水玻璃钠)组成的碱活化膏体进行抗压强度试验,评估了其力学性能。显微结构特征通过x射线衍射,扫描电子显微镜和热重分析进行评估。研磨时间为30分钟,热固化温度为40℃,溶解时间为6小时,热固化时间为8小时,得到了最佳产品。结果表明,替代碱性活化剂的有效性,为碱活性材料的大规模应用提供了技术上可行的解决方案。
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引用次数: 0
Hydration properties of the composite cementitious materials containing steel slag under steam curing condition 含钢渣复合胶凝材料在蒸汽养护条件下的水化性能
IF 2 4区 工程技术 Q2 Engineering Pub Date : 2023-11-17 DOI: 10.1680/jadcr.23.00102
Maosen Li, Xiao Liang, Long Chen, Shuhua Liu
Steel slag (SS) is a by-product of steel industry, and its recycling is of great significance. In this study, the influence of SS fineness and curing regimes on the hydration properties of cement and the effects of SS content on the compressive strength of pastes were investigated. The hydration products and microstructure of pastes were further explored through X-ray diffraction (XRD) and Scanning electron microscopy (SEM). The results show that the compressive strength decreases gradually with the increase of SS, and increases with the increase of the specific surface area of SS. The compressive strength of paste after steam curing is improved, and the compressive strength of the paste mixed with 30% SS can reach more than 50 MPa after 90 days of steam curing. The hydration products of paste mixed with SS is not significantly different from that of cement, which is mainly composed of Ca(OH)2 and C-S-H gel, accompanied by a small amount of CaCO3. SS has secondary hydration in long-term age and can fill and refine the pore structure, according to SEM. Using SS as supplementary material is beneficial to reducing cement cost and lowering CO2 emission.
钢渣是钢铁工业的副产物,其回收利用具有重要意义。研究了SS细度和养护制度对水泥水化性能的影响,以及SS含量对膏体抗压强度的影响。通过x射线衍射(XRD)和扫描电镜(SEM)进一步研究了膏体的水化产物和微观结构。结果表明,抗压强度随SS含量的增加而逐渐降低,随SS比表面积的增加而增加,膏体蒸汽养护后抗压强度得到提高,掺30% SS的膏体经过90天的蒸汽养护后抗压强度可达到50 MPa以上。掺入SS的膏体水化产物与水泥水化产物无显著差异,水泥水化产物主要由Ca(OH)2和C-S-H凝胶组成,并伴有少量CaCO3。扫描电镜显示,SS在长期龄期具有二次水化作用,可以填充和细化孔隙结构。采用SS作为补充材料,有利于降低水泥成本,降低CO2排放。
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引用次数: 0
Processing of calcium sulfoaluminate eco-cement coatings containing microencapsulated phase change materials 含微胶囊化相变材料的硫铝酸钙生态水泥涂料的制备
4区 工程技术 Q2 Engineering Pub Date : 2023-11-11 DOI: 10.1680/jadcr.23.00077
Andrea Romero-Espinosa, Susana G. Sanfélix, Alejandro Morales-Cantero, Ana Cuesta, Anna-Lena Kjøniksen, Miguel A. G. Aranda, Angeles G. De la Torre, Isabel Santacruz
On the one hand, calcium sulfoaluminate (CSA) eco-cements release about 40% less carbon dioxide (CO 2 ) than Portland cement during fabrication; on the other hand, phase change materials dispersed in a cementitious matrix can help to optimise the indoor temperature of buildings, reducing carbon dioxide emissions related to heating/air conditioning. However, this is only economically viable if it is used as a thin layer (a coating). In addition, the combination of both materials supposes a double environmental benefit. Consequently, the main objective of this work is the preparation of a suitable homogeneous and well-adhered bilayer sample, composed of CSA and CSA-MPCM. To achieve this, in the first step, the effect of pH, temperature and stirring was studied for microencapsulated phase change material (MPCM) aqueous suspensions (47.3 wt%); second, the MPCM (45 wt% with respect to dry cement) was dispersed in a CSA paste; then, in a third step, a homogeneous well-adhered coating of CSA-MPCM, with undamaged MPCM, was obtained on a CSA matrix. This was achieved through rheological measurements and checked by microscopy. Finally, the corresponding CSA and CSA-MPCM mortars were characterised through their mechanical properties (compression) (70 and 13 MPa at 7 days, respectively) and thermal conductivity (2.06 and 1.19 W/mK, respectively).
一方面,硫铝酸钙(CSA)生态水泥在制造过程中释放的二氧化碳(CO 2)比波特兰水泥少约40%;另一方面,分散在胶凝基质中的相变材料可以帮助优化建筑物的室内温度,减少与供暖/空调相关的二氧化碳排放。然而,这只有在作为薄层(涂层)使用时才具有经济可行性。此外,两种材料的结合具有双重的环境效益。因此,本工作的主要目的是制备一种合适的均匀且粘附良好的双层样品,由CSA和CSA- mpcm组成。为了实现这一目标,在第一步,研究了pH、温度和搅拌对微胶囊化相变材料(MPCM)水溶液悬浮液(47.3% wt%)的影响;其次,将MPCM(相对于干水泥的45%)分散在CSA膏体中;然后,在第三步中,在CSA基体上获得均匀且粘附良好的CSA-MPCM涂层,其中MPCM未损坏。这是通过流变学测量和显微镜检查实现的。最后,对相应的CSA和CSA- mpcm砂浆的力学性能(压缩)(7 d时分别为70和13 MPa)和导热系数(分别为2.06和1.19 W/mK)进行表征。
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引用次数: 0
Effect of use of retardant chemical additives in concrete on rebar corrosion 混凝土中使用阻燃化学添加剂对钢筋腐蚀的影响
4区 工程技术 Q2 Engineering Pub Date : 2023-11-11 DOI: 10.1680/jadcr.22.00189
Behçet Dündar, Emriye Çinar Resuloğlulari, Turhan Can Karci
Reinforced concrete (RC) is one of the most widely used building materials. However, RC, especially in coastal seaside or humid environments, can suffer reinforcement corrosion with the result that the reinforcement fails to perform its function over time. The effect of a retarder additive used to eliminate loss of consistency in hot, windy and humid weather on the corrosion of RC elements was investigated in this work. Four different concrete types were assessed, with 0%, 1%, 1.5% and 2% additions of the chemical additive. Along with accelerated corrosion and pressure tests, physical properties such as electrical resistivity, water absorption, porosity, unit weight and capillary water absorption were also determined. The results of this work indicate that the use of up to 2% of the setting retarder did not pose a problem in terms of the physical and mechanical properties of the concrete. However, in terms of the frequently encountered corrosion problem, the use of 1.5% is more appropriate. Many chemical additives are used for different purposes in concrete and it is suggested that, alongside physical and mechanical properties, durability characteristics should also be examined when determining the suitable ratios of these additives.
钢筋混凝土是应用最广泛的建筑材料之一。然而,钢筋混凝土,特别是在沿海海边或潮湿环境中,可能会遭受钢筋腐蚀,导致钢筋随着时间的推移而无法发挥其功能。本文研究了在高温、多风和潮湿天气中用于消除稠度损失的缓凝剂添加剂对钢筋混凝土构件腐蚀的影响。对四种不同类型的混凝土进行了评估,分别添加0%、1%、1.5%和2%的化学添加剂。随着加速腐蚀和压力测试,还确定了电阻率、吸水率、孔隙率、单位重量和毛管吸水率等物理性能。这项工作的结果表明,使用高达2%的凝结缓凝剂不会对混凝土的物理和机械性能造成问题。但是,对于经常遇到的腐蚀问题来说,使用1.5%更为合适。许多化学添加剂在混凝土中用于不同的目的,建议在确定这些添加剂的合适比例时,除了物理和机械性能外,还应检查耐久性特性。
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引用次数: 0
Effects of thermal activation on the hydration performance of lithium slag-cement composite binder 热活化对锂矿渣-水泥复合粘结剂水化性能的影响
4区 工程技术 Q2 Engineering Pub Date : 2023-11-10 DOI: 10.1680/jadcr.23.00068
Yan He, Chunyang You, Shuhua Liu, Mingjing Jiang, Pengcheng Shi
In order to enhance the utilization efficiency of lithium slag (LS) in cement-based materials, calcificated and thermal activation of LS were conducted, and the activation mechanism have been analyzed. Results showed that gypsum and spodumene in LS decomposed at high temperature via calcificated and thermal activation, and spodumene as well as limestone calcination decomposed at high temperature, to generate more CS, CA and other mineral phases. Calcificated and thermal activation could enhance the activity of LS to participate in pozzolanic reaction, and generate the formation of more hydration products. After calcificated and thermal activation of LS, the hydration exothermic peak, the total amount of hydration heat, and hydration production of LS composite binder were significantly increased. The hardened matrix was more compact with less porosity. Compared with cement mortar incorporated with raw LS, the incorporation of calcificated and thermal activated LS enhanced the compressive strength of cement mortar at 3d, 7d, and 28d by 25.8%, 13.4%, and 20.5%, respectively.
为了提高锂渣在水泥基材料中的利用效率,对锂渣进行了钙化和热活化,并对其活化机理进行了分析。结果表明:LS中的石膏和锂辉石在高温下通过钙化和热活化进行分解,而锂辉石和石灰石在高温下煅烧分解,生成更多的CS、CA等矿相。钙化和热活化可以增强LS参与火山灰反应的活性,生成更多水化产物。LS经钙化和热活化后,LS复合粘结剂的水化放热峰、水化总热量和水化产率均显著提高。硬化后的基体更致密,孔隙率更低。与掺入生料LS相比,掺入钙化LS和热活化LS可使水泥砂浆在3d、7d和28d的抗压强度分别提高25.8%、13.4%和20.5%。
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引用次数: 0
Effects of waste magnesia powder as partial cement replacement on self-compacting concrete 废氧化镁粉部分替代水泥对自密实混凝土的影响
4区 工程技术 Q2 Engineering Pub Date : 2023-11-08 DOI: 10.1680/jadcr.22.00126
Songül Can, Ali Sariisik, Tayfun Uygunoğlu
This experimental study investigated the performance of self-compacting concrete (SCC) mixes with magnesia (MgO) waste. In the series produced with a water/binder ratio of 0.40, cement was replaced by magnesia waste at 2%, 4% and 10% by weight in the SCC. Le Chatelier test, slump flow, compressive strength, flexural strength, depth of penetration of water under pressure, ultrasonic pulse velocity and water absorption by capillary testing was conducted to assess sample performance. X-ray diffraction, thermogravimetric analysis, mercury intrusion porosimetry, differential thermal analysis and scanning electron microscopy were used for the microstructural analysis and quantification of phases within each sample. The results indicated that concrete with magnesia waste contains magnesium silicate hydrate (M–S–H) and brucite ((Mg(OH) 2 ) products. Brucite causes strength loss in concrete. Up to 90 days, specimens with magnesia showed increasing compressive and flexural strength. As the amount of magnesia waste increased, the porosity, depth of water penetration under pressure and water absorption by capillary increased. Incorporating more than 10% of magnesia waste in the SCC mixtures resulted in declining strength. The addition of magnesia waste enhanced the expansion of SCC. An optimum dosage (2%) of magnesia waste was the most advantageous to the strength of SCC.
本试验研究了氧化镁(MgO)废料对自密实混凝土(SCC)性能的影响。在水胶比为0.40的系列中,在SCC中,氧化镁废物的重量分别为2%、4%和10%,取代了水泥。通过勒夏特列试验、坍落度流动、抗压强度、抗折强度、承压下水侵彻深度、超声脉冲速度和毛细管吸水率试验对样品性能进行评价。采用x射线衍射、热重分析、压汞孔隙分析、差热分析和扫描电镜对样品进行微观结构分析和物相定量。结果表明,镁渣混凝土中含有水化硅酸镁(M-S-H)和水镁石((Mg(OH) 2)产物。水石膏引起混凝土强度损失。在90天内,含镁试样的抗压和抗折强度均有所提高。随着废镁量的增加,孔隙率、压水渗透深度和毛管吸水率均增大。在SCC混合物中加入超过10%的氧化镁废料导致强度下降。氧化镁废液的加入促进了SCC的膨胀。氧化镁废的最佳投加量(2%)对SCC的强度最有利。
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引用次数: 0
Expansion properties of concrete-filled steel tubes with circulating fluidized bed fly ash 循环流化床粉煤灰对钢管混凝土膨胀性能的影响
4区 工程技术 Q2 Engineering Pub Date : 2023-10-17 DOI: 10.1680/jadcr.23.00088
Ruizhen Yan, Guoju Ke, Dongxiao Han
In the context of green and low-carbon materials development, the influence of replacing cement with circulating fluidised bed fly ash (CFBFA) on the expansion properties of paste under different curing conditions was first systematically investigated. Then, self-compacting concretes (SCCs) with recycled aggregate (RA) and CFBFA were prepared for filling steel tubes. The experimental results showed that, because of its unique physicochemical properties, the incorporation of CFBFA significantly increased the water requirement needed to achieve standard consistency of the paste and the pore structure was optimised by a reduction in the number of large pores due to the formation of more expansion components (ettringite, gypsum and portlandite are the main expansive products of CFBFA–cement paste). The influence of factors such as curing condition, age and CFBFA on the expansion effect was notable. With a 40% CFBFA content, the RA SCC in the steel tube showed an expansion of 41 μm/m, while the 28-day compressive strength reached 48.9 MPa.
在绿色低碳材料发展的背景下,首次系统研究了循环流化床粉煤灰(CFBFA)替代水泥对不同养护条件下膏体膨胀性能的影响。然后,制备了含再生骨料和CFBFA的自密实混凝土(SCCs),用于填充钢管。实验结果表明,由于CFBFA独特的物理化学性质,CFBFA的掺入显著提高了膏体达到标准稠度所需的需水量,并且由于形成了更多的膨胀成分(钙矾石、石膏和硅酸盐是CFBFA -水泥膏体的主要膨胀产物),孔隙结构得到了优化,减少了大孔隙的数量。养护条件、龄期、CFBFA等因素对膨胀效果影响显著。当CFBFA含量为40%时,钢管中的RA SCC膨胀率为41 μm/m, 28天抗压强度达到48.9 MPa。
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引用次数: 0
Characterization of cement loaded with magnetically aligned nano-magnetite 磁性排列纳米磁铁矿负载水泥的表征
4区 工程技术 Q2 Engineering Pub Date : 2023-10-16 DOI: 10.1680/jadcr.22.00193
Taha M. Jassam, Bonnie Lau, Jason Ng Yang-Zhi, Kow Kien-Woh, Ramez A. Al-Mansob, Bariş Erdil, Wenjie Luo
In this study, the effect on the compressive strength of cement with the addition of 1-5 wt% nano-magnetite particles (nano-Fe 3 O 4 ) has been identified at the age of 7 days and 28 days curing. In addition, an approach of aligning these nano-magnetite particles within cement using an external magnetic field was presented, where the orientation of nano-magnetite particles was aligned parallel to the compressive load. The effect of the compressive strength on cement mortar with the aligned nano-magnetite particles has also been compared with the non-aligned samples. Both aligned and non-aligned samples showed positive effects on the compressive strengths as compared to the control samples, where the cement mortar with aligned nano-magnetite showed significant improvement on compressive strength up to 21%. This study also showed that the addition of 3 wt% nano-magnetite particles into cement mortar was the optimal amount to achieve maximum enhancement of compressive strengths.
在本研究中,研究了在龄期7天和养护28天时,添加1-5 wt%的纳米磁铁矿颗粒(纳米fe3o4)对水泥抗压强度的影响。此外,提出了一种利用外部磁场在水泥中对齐这些纳米磁铁矿颗粒的方法,其中纳米磁铁矿颗粒的方向与压缩载荷平行。对比了纳米磁铁矿排列后对水泥砂浆抗压强度的影响。与对照样品相比,排列和未排列的样品对抗压强度都有积极的影响,其中纳米磁铁矿排列的水泥砂浆的抗压强度显著提高了21%。该研究还表明,在水泥砂浆中添加3wt %的纳米磁铁矿颗粒是获得最大抗压强度增强的最佳量。
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引用次数: 0
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Advances in Cement Research
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