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Atomistic-scale investigation of self-healing mechanism in Nano-silica modified asphalt through molecular dynamics simulation 分子动力学模拟纳米二氧化硅改性沥青自愈机制的原子尺度研究
Pub Date : 2022-03-03 DOI: 10.1186/s43065-022-00049-2
Long, Zhengwu, Tang, Xianqiong, Guo, Nanning, Ding, Yanhuai, Ma, Wenbo, You, Lingyun, Xu, Fu
As one of the most widely used nanomaterials in asphalt modification, the nano-silica (nano-SiO2) can significantly improve the self-healing behavior of asphalt eco-friendly. However, understanding of the self-healing mechanism of nano-SiO2 in asphalt is still limited. The objective of the study is to reveal the self-healing mechanism of nano-SiO2 in asphalt by using molecular dynamics (MD) simulations from the nanoscale. A 10 Å (Å) vacuum pad was added between the two same stable asphalt models to represent the micro-cracks inside the asphalt. The self-healing process of virgin asphalt, oxidation aging asphalt, and nano-SiO2 modified asphalt was studied using density evolution, relative concentration, diffusion coefficient, activation energy, and pre-exponential factor. The simulation results conclude that nano-SiO2 improves the self-healing ability of asphalt by increasing the diffusion rate of molecules with aromatic structures without alkyl side chains and molecules with structures with longer alkyl chains. The self-healing capability of asphalt may be principally determined by the diffusion of light components such as saturate, while nano-SiO2 only plays an inducing role. The research findings could provide insights to understand the self-healing mechanism of nano-SiO2 in asphalt for promoting the sustainability of bitumen pavements while increasing their durability.
纳米二氧化硅(nano-SiO2)是沥青改性中应用最广泛的纳米材料之一,可以显著改善沥青生态友好型的自修复行为。然而,对纳米sio2在沥青中的自愈机制的了解仍然有限。本研究的目的是通过纳米尺度的分子动力学(MD)模拟来揭示纳米sio2在沥青中的自修复机制。在两个相同的稳定沥青模型之间添加一个10 Å (Å)的真空垫块来表示沥青内部的微裂缝。采用密度演化、相对浓度、扩散系数、活化能和指前因子等指标研究了原生沥青、氧化老化沥青和纳米sio2改性沥青的自愈过程。模拟结果表明,纳米sio2通过提高无烷基侧链芳香结构分子和烷基链较长结构分子的扩散速率,提高了沥青的自愈能力。沥青的自愈能力可能主要取决于饱和度等轻组分的扩散,而纳米sio2仅起诱导作用。研究结果可为理解纳米sio2在沥青中的自愈机制,促进沥青路面的可持续性,提高其耐久性提供依据。
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引用次数: 14
Mechanical performance of strain-hardening cementitious composites (SHCC) with bacterial addition 细菌加入应变硬化胶凝复合材料(SHCC)的力学性能
Pub Date : 2022-02-22 DOI: 10.1186/s43065-022-00048-3
Zhang, Zhigang, Liu, Dawei, Ding, Yuanzhao, Wang, Shuping
Incorporation of bacteria can realize self-healing and enhance strength of concrete, which has been drawn extensive attention in past decades. The studies focused on the properties of fiber reinforced concrete with bacterial addition are still very limited. In this paper, mechanical performance of strain hardening cementitious composites (SHCC) with directly adding vegetative bacterial cells was investigated. The experimental results revealed that the compressive, first cracking, and tensile strength of SHCCs was increased due to the addition of bacteria, while the tensile strain capacity tended to decline. At micro-scale level, the matrix containing bacteria has relative higher fracture toughness to that of reference mix. Interestingly, the bacteria notably lowered chemical bond between PVA fiber and its surrounding hydrates; on the other hand, the frictional bond was enhanced. The findings in this study can provide a reference for modifying the surface of hydrophilic fibers.
细菌的掺入可以实现混凝土的自愈,提高混凝土的强度,在过去的几十年里受到了广泛的关注。目前对细菌掺入纤维混凝土性能的研究还很有限。研究了直接加入营养细菌细胞的应变硬化胶凝复合材料(SHCC)的力学性能。实验结果表明,细菌的加入提高了shcc的抗压强度、初裂强度和抗拉强度,但拉伸应变能力有下降的趋势。在微观尺度上,含菌基质的断裂韧性高于对照基质。有趣的是,这种细菌显著降低了聚乙烯醇纤维与其周围水合物之间的化学键;另一方面,摩擦键增强。本研究结果可为亲水性纤维的表面改性提供参考。
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引用次数: 9
Carbon-based nanomaterials engineered cement composites: a review 碳基纳米材料工程水泥复合材料研究进展
Pub Date : 2022-01-19 DOI: 10.1186/s43065-021-00045-y
Lu, Dong, Zhong, Jing
Carbon-based nanomaterials (CNMs) have been extensively used to modify cement matrix thanks to their extraordinary specific surface area, high aspect ratio, and high strength and modulus. This review focuses on the current status of research on CNMs modified cement composites, especially the progress made in the past decade (from 2011 to 2021). At first, the primary properties of typical CNMs used for manufacturing cement composites, the treatments used to effectively disperse CNMs in water and cement matrix, and the corresponding characterization methods are reviewed. And then, the effects of introducing CNMs on the properties of cement composites (both fresh and hardened) are also discussed in this work. Finally, the knowledge gaps and remaining challenges for future work are discussed.
碳基纳米材料(CNMs)由于其非凡的比表面积、高纵横比、高强度和高模量而被广泛用于水泥基体的改性。本文综述了CNMs改性水泥复合材料的研究现状,特别是近十年(2011年至2021年)的研究进展。首先,综述了用于制造水泥复合材料的典型cnm的主要性能、有效分散cnm在水和水泥基体中的处理方法以及相应的表征方法。然后,本文还讨论了cnm的引入对水泥复合材料(新鲜和硬化)性能的影响。最后,讨论了知识差距和未来工作面临的挑战。
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引用次数: 30
Model development and prediction of anti-icing longevity of asphalt pavement with salt-storage additive 含盐添加剂沥青路面抗冰寿命模型建立与预测
Pub Date : 2022-01-04 DOI: 10.1186/s43065-021-00047-w
Zhang, Yan, Deng, Yong, Shi, Xianming
This study established a systematic simulation framework to predict the anti-icing longevity of a thin overlay of asphalt pavement with salt-storage additive (APSSA). The water and chloride transport in the overlay when subjected to varying precipitation, temperature, thermal cracking, and fatigue cracking over time were modeled using a Finite Element Method based software. The simulation included two parts: water transport followed by chloride transport. Water transport that obeys the law of conservation of mass was modeled using the phase transport in porous media (phtr) interface of COMSOL, while chloride transport based on Fick’s second law was modeled with the transport of diluted species (tds) interface. The simulation results show that the anti-icing function of a 16-mm thick overlay was fully effective in 2 years and 5 years for the minimum pavement temperature above -3.4 °C and -2.4 °C, respectively. These two pavement temperatures are equivalent to 97.4-percentile and 96.3-percentile of historical hourly pavement temperature near Pullman, Washington.
本研究建立了一个系统的模拟框架,以预测盐储存添加剂(APSSA)薄加铺层沥青路面的抗冰寿命。利用基于有限元法的软件对覆盖层中水分和氯化物在不同降水、温度、热开裂和疲劳开裂条件下的运移进行了建模。模拟包括两个部分:水输运和氯输运。遵循质量守恒定律的水输运采用COMSOL多孔介质中的相输运(phtr)界面进行建模,基于菲克第二定律的氯输运采用稀释物质输运(tds)界面进行建模。仿真结果表明,当路面最低温度分别高于-3.4℃和-2.4℃时,16mm厚加铺层的防冰作用在2年和5年内完全有效。这两个路面温度相当于华盛顿普尔曼附近历史每小时路面温度的97.4百分位和96.3百分位。
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引用次数: 7
Seismic collapse risk of RC-timber hybrid building with different energy dissipation connections considering NBCC 2020 hazard. 考虑NBCC 2020危害的不同耗能连接rc -木混合结构建筑地震倒塌风险
Pub Date : 2022-01-01 Epub Date: 2022-11-06 DOI: 10.1186/s43065-022-00061-6
Ikenna Odikamnoro, Prakash S Badal, Henry Burton, Solomon Tesfamariam

The 2020 National Building Code of Canada (NBCC) seismic hazard model (SHM) marks a comprehensive update over its predecessor (NBCC 2015). For different regions in Canada, this will have an impact on the design of new buildings and performance assessment of existing ones. In the present study, a recently developed hybrid building system with reinforced concrete (RC) moment-resisting frames and cross-laminated timber (CLT) infills is assessed for its seismic performance against the latest SHM. The six-story RC-CLT hybrid system, designed using the direct displacement-based method, is located in Vancouver, Canada. Along with very high seismicity, southwestern British Columbia is characterized by complex seismotectonics, consisting of subduction, shallow crustal, and in-slab faulting mechanisms. A hazard-consistent set of 40 ground motion pairs is selected from the PEER and KiK-net databases, and used to estimate the building's seismic performance. The effects of using steel slit dampers (associated with large hysteresis loops) and flag-shaped energy dissipators (associated with the recentering capability) are investigated. The results indicate that the hybrid system has good seismic performance with a probability of collapse of 2-3% at the 2475-year return period shaking intensity. The hybrid building with steel slit dampers exhibits a collapse margin ratio of 2.8, which increases to 3.5-3.6 when flag-shaped dissipators are used. The flag-shaped dissipators are found to significantly reduce the residual drift of the hybrid building. Additionally, the seismic performance of the hybrid building equipped with flag-shaped dissipators is found to improve marginally when the recentering ratio is increased.

2020年加拿大国家建筑规范(NBCC)地震危险模型(SHM)标志着其前身(NBCC 2015)的全面更新。对于加拿大的不同地区,这将对新建筑的设计和现有建筑的性能评估产生影响。在本研究中,最近开发的钢筋混凝土(RC)抗弯矩框架和交叉层压木材(CLT)填充的混合建筑体系对最新SHM的抗震性能进行了评估。这座六层的RC-CLT混合系统位于加拿大温哥华,采用直接基于位移的方法设计。不列颠哥伦比亚省西南部地震活动性非常强,地震构造复杂,包括俯冲、浅层地壳和板内断裂机制。从PEER和KiK-net数据库中选择了一组危险一致的40对地面运动对,并用于估计建筑物的抗震性能。研究了钢缝阻尼器(与大磁滞回线有关)和旗形能量耗散器(与重入能力有关)的影响。结果表明,该混合体系具有良好的抗震性能,在2475年重现周期的震动强度下,其倒塌概率为2-3%。采用钢缝阻尼器的混合结构的倒塌裕度比为2.8,采用旗形阻尼器的混合结构的倒塌裕度比为3.5 ~ 3.6。旗形消能器可以显著降低混合结构的残余漂移。此外,旗形减振器混合结构的抗震性能随着重入比的增加而略有改善。
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引用次数: 2
Optimal overlays for preservation of concrete in cold climate: decision-making by the method of fuzzy comprehensive evaluation combined with AHP 寒冷气候下混凝土养护最优覆盖层:模糊综合评价与层次分析法相结合的决策方法
Pub Date : 2021-12-01 DOI: 10.1186/s43065-021-00046-x
Zhipeng Li, Yudong Dang, Zhen Tang, Ning Xie, Shuang Lu, X. Shi
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引用次数: 2
Investigation of flexible pavement maintenance patching factors using a finite element model 基于有限元模型的柔性路面养护修补因素研究
Pub Date : 2021-11-06 DOI: 10.1186/s43065-021-00044-z
Lu, Yujia, Hajj, Ramez
Patching of flexible pavements is one of the most important functions of pavement maintenance. Although finite element modeling has become commonplace in the world of pavement engineering, modeling has not yet been significantly leveraged for maintenance applications which improve safety, ride quality, and pavement service life. The objective of this study was to model viscoelastic properties of pavement and patching materials to determine the effect of various repair factors on pavement performance using the finite element method. Specifically, surface permanent deformation, local shear stress concentration, and horizontal strain distribution were investigated. Two types of models were simulated; the first model applied static loading to a surface layer fixed on a plate and the second model applied cyclic traffic loading to a two-layered flexible pavement system. The results demonstrate the importance of patching using a semi-permanent method. The results also demonstrated the accumulated effect of repeated loading using a time-dependent material response. Results also indicated that a larger patching area resulted in less influence of the shape of the area, while a circular area proved superior to a conventional rectangular patch for sizes near the tire footprint and smaller than it. Different responses were observed depending on the type of patching material modeled, demonstrating the effect of material choice in maintenance applications. Finally, mesh optimization was performed to ensure appropriate mesh sizes are used in future studies to accurately represent the pavement layers and patches.
柔性路面的修补是路面养护的重要功能之一。尽管有限元建模在路面工程领域已经变得司空见惯,但建模还没有被显著地用于提高安全性、乘坐质量和路面使用寿命的维护应用。本研究的目的是利用有限元方法模拟路面和修补材料的粘弹性特性,以确定各种修补因素对路面性能的影响。具体而言,研究了表面永久变形、局部剪应力集中和水平应变分布。模拟了两种模型;第一个模型对固定在板上的面层施加静荷载,第二个模型对两层柔性路面系统施加循环交通荷载。结果表明,使用半永久性方法修补的重要性。结果也证明了累积效应的重复加载使用时间相关的材料响应。结果还表明,较大的修补面积对区域形状的影响较小,而圆形区域证明优于传统的矩形区域,尺寸接近轮胎足迹,比它小。根据不同类型的修补材料模型,观察到不同的反应,证明了材料选择在维护应用中的影响。最后,进行了网格优化,以确保在未来的研究中使用合适的网格尺寸来准确地表示路面层和斑块。
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引用次数: 1
Time impacts of treating pervious concrete with sodium bicarbonate 碳酸氢钠处理透水混凝土的时间影响
Pub Date : 2021-10-30 DOI: 10.1186/s43065-021-00043-0
Almeida, Nara, Haselbach, Liv
Magnesium chloride (MgCl2) deicers applications onto pervious concrete pavements can deteriorate the material, and studies investigate treatments to increase the concrete resistance to MgCl2 attacks. In this paper, pervious concrete specimens are subjected to a treatment with Sodium Bicarbonate (NaHCO3) solution, which seems to accelerate concrete carbonation and might hamper chemical reactions between MgCl2 deicer and hydroxides in cement mortar. All specimens had their compressive strength tested and the time frames before and after treatment varied. Results show that at least 2 months should be given post curing before treatment to not harm the concrete, and longer post treatment periods may be beneficial.
在透水混凝土路面上使用氯化镁(MgCl2)除冰剂会使材料恶化,因此研究了提高混凝土抗MgCl2侵蚀能力的处理方法。在本文中,透水混凝土试件采用碳酸氢钠(NaHCO3)溶液处理,该溶液似乎加速了混凝土的碳化,并可能阻碍水泥砂浆中MgCl2除冰剂和氢氧化物之间的化学反应。所有试件都进行了抗压强度测试,处理前后的时间框架有所不同。结果表明,养护后至少要有2个月的时间才能对混凝土产生损伤,而较长的养护后时间可能是有益的。
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引用次数: 0
Gene-editable materials for future transportation infrastructure: a review for polyurethane-based pavement 用于未来交通基础设施的基因可编辑材料:聚氨酯基路面研究进展
Pub Date : 2021-10-19 DOI: 10.1186/s43065-021-00039-w
Hong, Bin, Lu, Guoyang, Li, Tianshuai, Lin, Jiao, Wang, Dawei, Liang, Dong, Oeser, Markus
With the rapid development of society and industry, novel technologies and materials related to pavement engineering are constantly emerging. However, with the continuous improvement of people’s demands, pavement engineering also faces more and more enormous challenges that the pavement materials must have excellent engineering properties and environmental benefits. Meanwhile, the intelligence is the mainstream development direction of modern society, and the development trend of future transportation infrastructure. Materials Genome Initiative, a program for the development of new materials that materials design is conducted by up-front simulations and predictions, followed by key validation experiments, the rapid development of science and technology and AI toolset (big data and machine learning) provide new opportunities and strong technical supports for pavement materials development that shorten the development-application cycle of new material, reduce cost and promote the application of new carriers such as intelligent sensing components in transportation engineering, to achieve the intelligence of transportation engineering. However, traditional pavement materials possess several unavoidable shortcomings, indicating that it is exceedingly difficult for them to meet the above requirements for future pavement materials. Therefore, the development of future new pavement materials, which can be designed on-demand as well as possessing enough mechanical properties, high durability, practical functionality, and high environmental protection, is urgent. In recent years, as a “designable” polymer material with various excellent engineering performances, polyurethane (PU) has been widely applied in pavement practices by changing the chemical structures of raw materials and their mix proportions, for instance pavement repairing material, permeable pavement material, tunnel paving material and bridge deck paving materials, etc. Although PU material has been widely applied in practices, a systematically summarization is still quite necessary for further understanding the working mechanism of PU materials and optimization it’s engineering applications. To fill the gap, this article puts forward the special requirements for future transportation infrastructure materials, and introduces the basic properties and working mechanism of PU materials in order to make up for the defects of conventional road materials. Based on this, this article also summarizes the engineering performances and environmental benefits of applying PU as the binder for different road infrastructure materials in recent years. Considering the gene-editable nature of polyurethane, further research of the on-demand design principles of PU pavement materials is recommended. The establishment of raw material gene database, material terminal performance database and their structure-activity relationship are highlighted. The current research is essential to the practice guidance and furthe
随着社会和工业的快速发展,与路面工程相关的新技术、新材料不断涌现。然而,随着人们需求的不断提高,路面工程也面临着越来越大的挑战,路面材料必须具有优异的工程性能和环境效益。同时,智能化是现代社会的主流发展方向,也是未来交通基础设施的发展趋势。材料基因组计划是一项新材料开发计划,通过前期模拟和预测进行材料设计,然后进行关键验证实验,科学技术和人工智能工具集(大数据和机器学习)的快速发展为路面材料开发提供了新的机遇和强大的技术支持,缩短了新材料的开发应用周期。降低成本,推动智能传感元件等新型载体在交通运输工程中的应用,实现交通运输工程的智能化。然而,传统的路面材料存在着一些不可避免的缺点,这表明它们很难满足对未来路面材料的上述要求。因此,开发未来新型路面材料,既能按需设计,又具有足够的力学性能、高耐久性、实用功能和高环保性,迫在眉睫。近年来,聚氨酯(PU)作为一种具有各种优良工程性能的“可设计”高分子材料,通过改变原材料的化学结构及其配比,在路面修补材料、透水路面材料、隧道铺装材料、桥面铺装材料等方面得到了广泛的应用。尽管聚氨酯材料在实践中得到了广泛的应用,但系统的总结对于进一步了解聚氨酯材料的工作机理和优化其工程应用仍是十分必要的。为了填补这一空白,本文提出了对未来交通基础设施材料的特殊要求,并介绍了PU材料的基本性能和工作机理,以期弥补常规道路材料的缺陷。在此基础上,本文还总结了近年来应用PU作为不同道路基础设施材料粘结剂的工程性能和环境效益。考虑到聚氨酯的基因可编辑性,建议进一步研究聚氨酯路面材料的按需设计原则。重点介绍了原料基因数据库、原料终端性能数据库的建立及其构效关系。本研究对道路基础设施聚氨酯材料的实践指导和进一步优化具有重要意义,符合未来的碳中和政策。
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引用次数: 14
Deformation superposition effect of asphalt mixture based on experiments and micromechanical modeling 基于实验和微观力学模型的沥青混合料变形叠加效应
Pub Date : 2021-10-15 DOI: 10.1186/s43065-021-00041-2
Chun Li, Xin Bian, Qifeng Dong, Huining Xu
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引用次数: 0
期刊
Journal of infrastructure preservation and resilience
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