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A mass budget and box model of global plastics cycling, degradation and dispersal in the land-ocean-atmosphere system 陆地-海洋-大气系统中全球塑料循环、降解和扩散的大规模预算和盒子模型
Pub Date : 2022-12-19 DOI: 10.1186/s43591-022-00048-w
J. Sonke, A. Koenig, N. Yakovenko, O. Hagelskjær, H. Margenat, S. Hansson, F. De Vleeschouwer, O. Magand, G. Le Roux, Jennie L. Thomas
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引用次数: 4
Evaluation of microplastics sediment sampling techniques—efficiency of common methods and new approaches 微塑料沉积物取样技术的评价——常用方法和新方法的有效性
Pub Date : 2022-12-16 DOI: 10.1186/s43591-022-00047-x
Yasmin Adomat, Melanie Kahl, Fabian Musche, T. Grischek
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引用次数: 1
Macroplastics and Microplastics in Intertidal Sediment of Vinces and Los Tintos Rivers, Guayas Province, Ecuador 厄瓜多尔瓜亚斯省文斯河和洛斯廷托斯河潮间带沉积物中的宏观塑料和微塑料
Pub Date : 2022-12-07 DOI: 10.3390/microplastics1040045
Rebecca Talbot, M. Cárdenas-Calle, J. Mair, F. López, Guillermo Cárdenas, Beatríz Pernía, M. Hartl, Miguel Uyaguari
The composition, abundance and distribution of macroplastics (MAPs) and microplastics (MPs) in the Vinces and Los Tintos rivers were determined in three sites (Pueblo Nuevo, Santa Marianita, Los Tintos) from the low basin in the coastal province of Guayas, Ecuador. MAPS were recorded by visual census, covering a total distance of 140 m, and MPs were extracted in the intertidal sediments via density separation using a saturated NaCl solution, and these were counted using a stereomicroscope. A total of 940 plastic items were identified. The predominant debris was plastic with 85.2%, followed by manufactured materials and metals. The Vinces River contained the highest abundance of plastic in the locality of Pueblo Nuevo. The most abundant plastic was MPs. The most common MAPs were plastic bags (23%), food packaging (17%) and foamed plastic (8%). MP size classes quantified between 0.15 and 2.52 mm in intertidal, very fine sandy sediment and decreased in abundance with increasing grain size. The most common MPs were fibres (65.2%) (black (43.8%) and blue (25.8%)), and their distribution has a high correlation with population density and water flow direction: Santa Marianita 5.55 g−1, Pueblo Nuevo 7.39 g−1, Los Tintos 8.17−1. A significant abundance of fibres was identified in Pueblo Nuevo. The plastic spatial distribution revealed major plastic pollution in areas where recreational and tourism activities have been developed. Therefore, we recommend implementing awareness campaigns by educating businesses, residents and tourists on managing solid waste (especially plastic) and wastewater. Our results can serve as a baseline for future plastic monitoring in the area.
在厄瓜多尔瓜亚斯省沿海低洼盆地的三个地点(普韦布洛新埃沃、圣玛丽安娜塔、洛斯廷托斯)测定了文斯河和洛斯廷托斯河中宏观塑料(MAPs)和微塑料(MPs)的组成、丰度和分布。用目测法记录总距离为140 m的map,用饱和NaCl溶液进行密度分离提取潮间带沉积物中的MPs,并用体视显微镜进行计数。共鉴定出940件塑料制品。主要的垃圾是塑料,占85.2%,其次是人造材料和金属。在新普韦布洛地区,文斯河的塑料含量最高。最丰富的塑料是MPs。最常见的map是塑料袋(23%)、食品包装(17%)和泡沫塑料(8%)。潮间带、极细砂质沉积物的MP粒度分级在0.15 ~ 2.52 mm之间,丰度随着粒度的增加而减少。最常见的MPs是纤维(65.2%)(黑色(43.8%)和蓝色(25.8%)),它们的分布与人口密度和水流方向高度相关:Santa Marianita 5.55 g−1,Pueblo Nuevo 7.39 g−1,Los Tintos 8.17−1。在新普韦布洛发现了大量的纤维。塑料的空间分布表明,在娱乐和旅游活动发达的地区,塑料污染主要存在。因此,我们建议开展宣传活动,教育企业、居民和游客如何管理固体废物(特别是塑料)和废水。我们的研究结果可以作为该地区未来塑料监测的基线。
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引用次数: 4
A comparative investigation of the sorption of polycyclic aromatic hydrocarbons to various polydisperse micro- and nanoplastics using a novel third-phase partition method 一种新的第三相分配法对多环芳烃在各种多分散微塑料和纳米塑料上吸附的比较研究
Pub Date : 2022-12-01 DOI: 10.1186/s43591-022-00049-9
E. E. Emecheta, Diana Borda Borda, Patrizia Pfohl, W. Wohlleben, C. Hutzler, A. Haase, Alexander Roloff
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引用次数: 2
State of the Art Offshore In Situ Monitoring of Microplastic 海洋微塑料原位监测技术现状
Pub Date : 2022-11-02 DOI: 10.3390/microplastics1040044
D. Calore, N. Fraticelli
Microplastics make up a significant amount of the overall quantity of plastic debris that is present in seawater. However, their detection and monitoring at sea is cost-inefficient and challenging; typically, it consists of water sampling with special manta nets, followed by long (i.e., weeks) laboratory analysis to obtain valid results. The analysis of the state-of-the-art technologies capable of monitoring/detecting microplastics in the sea (typically in coastal areas) presented in this paper shows that there are currently no specific tools to obtain quick measurements. The classic multiparametric probes are useless and the contribution of their relative chemical–physical parameters to determine the presence of microplastics in water is insignificant. The evolution in the last decade of hardware and software tools for capturing hologram images and related post-processing seems to be one of the most effective methods available currently for the rapid detection of microplastics in seawater. In particular, some results of monitoring campaigns carried out in the Adriatic Sea using this type of technology are reported. The acquired data are analyzed and discussed, highlighting their strengths and weaknesses, with indications of the possible methodologies that could be used to improve these systems.
微塑料占海水中塑料碎片总量的很大一部分。然而,它们在海上的探测和监测成本低且具有挑战性;通常,它包括用特殊的蝠鲼网进行水样取样,然后进行长时间(即数周)的实验室分析以获得有效的结果。本文对能够监测/检测海洋(通常在沿海地区)微塑料的最先进技术的分析表明,目前没有特定的工具来获得快速测量。经典的多参数探针是无用的,它们的相对化学-物理参数对确定水中微塑料存在的贡献是微不足道的。在过去十年中,用于捕获全息图像和相关后处理的硬件和软件工具的发展似乎是目前可用于快速检测海水中微塑料的最有效方法之一。特别报告了在亚得里亚海使用这种技术进行的监测运动的一些结果。对获得的数据进行分析和讨论,突出其优点和缺点,并指出可用于改进这些系统的可能方法。
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引用次数: 2
Microfibers: Environmental Problems and Textile Solutions 微纤维:环境问题和纺织解决方案
Pub Date : 2022-11-01 DOI: 10.3390/microplastics1040043
J. Weis, F. De Falco
Microplastics have become a topic of considerable concern and intensive study over the past decade. They have been found everywhere in the oceans, including the deepest trenches and remotest parts of the Arctic. They are ingested by many animals and some are incorporated into tissues. There is considerable effort in studying what effects they have on marine life. It has become clear that when water samples are collected in ways that prevent most long thin particles from escaping through pores of a net, the most abundant type of microplastics found in water and sediments are microfibers (fibers with dimensions less than 5 mm). The major source of these pollutants is synthetic textiles, such as polyester or polyamides, which shed microfibers during their entire life cycle. Microfibers are released during textile manufacturing, everyday activities (e.g., washing, drying, wearing) and final disposal. The complexity of microfiber release mechanisms and of the factors involved make the identification and application of ways to reduce the inputs of microfibers very challenging. A comprehensive approach is strongly needed, taking into account solutions at a number of levels, such as re-engineering textiles to minimize shedding, applying washing machine filters, developing advanced wastewater treatment plants and improving the management of textile wastes. To harmonize and make mandatory the solutions identified, a variety of potential government policies and regulations is also needed.
在过去的十年中,微塑料已经成为一个备受关注和深入研究的话题。它们在海洋中随处可见,包括最深的海沟和北极最偏远的地区。它们被许多动物摄入,有些被组织吸收。人们在研究它们对海洋生物的影响方面付出了相当大的努力。很明显,如果收集水样的方法是防止大多数长而细的颗粒从网孔中逸出,那么在水和沉积物中发现的最丰富的微塑料类型是微纤维(尺寸小于5毫米的纤维)。这些污染物的主要来源是合成纺织品,如聚酯或聚酰胺,这些纺织品在其整个生命周期中都会脱落微纤维。微纤维在纺织品制造、日常活动(如洗涤、干燥、穿着)和最终处理过程中释放出来。由于超细纤维释放机制及其所涉及因素的复杂性,确定和应用减少超细纤维输入的方法非常具有挑战性。迫切需要采取综合办法,考虑到若干层面的解决办法,例如重新设计纺织品以尽量减少脱落、使用洗衣机过滤器、发展先进的废水处理厂和改进对纺织废料的管理。为了协调和强制执行所确定的解决方案,还需要各种潜在的政府政策和法规。
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引用次数: 2
Opening Space for Plastics—Why Spatial, Soil and Land Use Data Are Important to Understand Global Soil (Micro)Plastic Pollution 为塑料打开空间——为什么空间、土壤和土地利用数据对了解全球土壤(微)塑料污染很重要
Pub Date : 2022-10-08 DOI: 10.3390/microplastics1040042
C. Weber, M. Bigalke
After five years of research on microplastic pollution of soils it becomes obvious that soil systems act as a reservoir for microplastics on global scales. Nevertheless, the exact role of soils within global microplastic cycles, plastic fluxes within soils and environmental consequences are so far only partly understood. Against the background of a global environmental plastic pollution, the spatial reference, spatial levels, sampling approaches and documentation practices of soil context data becomes important. Within this review, we therefore evaluate the availability of spatial MP soil data on a global scale through the application of a questionnaire applied to 35 case studies on microplastics in soils published since 2016. We found that the global database on microplastics in soils is mainly limited to agricultural used topsoils in Central Europe and China. Data on major global areas and soil regions are missing, leading to a limited understanding of soils plastic pollution. Furthermore, we found that open data handling, geospatial data and documentation of basic soil information are underrepresented, which hinders further understanding of global plastic fluxes in soils. Out of this context, we give recommendations for spatial reference and soil context data collection, access and combination with soil microplastic data, to work towards a global and free soil microplastic data hub.
经过五年对土壤微塑料污染的研究,土壤系统在全球范围内显然是微塑料的储存库。然而,迄今为止,土壤在全球微塑料循环中的确切作用、土壤中的塑料通量和环境后果只是部分了解。在全球环境塑料污染的背景下,土壤背景数据的空间参考、空间水平、采样方法和文献实践变得非常重要。因此,在这篇综述中,我们通过对2016年以来发表的35个土壤微塑料案例研究的问卷调查,评估了全球范围内空间MP土壤数据的可用性。我们发现,全球土壤微塑料数据库主要局限于中欧和中国的农业表层土壤。全球主要地区和土壤区域的数据缺失,导致对土壤塑料污染的了解有限。此外,我们发现开放数据处理、地理空间数据和基本土壤信息文献的代表性不足,这阻碍了对全球土壤塑性通量的进一步了解。在此背景下,我们提出了空间参考和土壤背景数据收集、获取和结合土壤微塑料数据的建议,以努力建立一个全球和自由的土壤微塑料数据中心。
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引用次数: 5
Effects of Silica Fume and Micro Silica on the Properties of Mortars Containing Waste PVC Plastic Fibers 硅粉和微二氧化硅对含废PVC塑料纤维砂浆性能的影响
Pub Date : 2022-10-07 DOI: 10.3390/microplastics1040041
R. Mahmood, N. Kockal
Investigations on the usability of waste plastics as a new generation of construction materials have become one of the main concerns of researchers and engineers in recent decades. Waste plastics can be used either as aggregate replacement or as fiber reinforcement to enhance the properties of cementitious mixtures. This study focuses on the properties of waste PVC fiber-reinforced mortars containing silica fume and micro silica. Plastic fibers were added to the mortar mixes by volume fractions of 0%, 1%, 2%, and 3%. Cement was replaced by micro silica and silica fume by 5%, 10%, and 15% by weight of cement, respectively. In total, 28 different groups of mortars were produced. The results showed an enhanced ductility and deformation behavior of mortars upon the addition of waste PVC plastic fibers. It can be seen that fibers restricted crack propagation and maintained integrity, hence improving the ductility of the mortars. On the other hand, the addition of fibers led to a reduction in the physical and mechanical properties of the mortar samples. The compressive strength of the mortar samples decreased gradually by increasing the fiber content. Cement replacement by silica fume improved mechanical and microstructural properties of the mortars. The results also demonstrated that silica fume significantly decreased the porosity and water absorption capacity of mortar samples.
废塑料作为新一代建筑材料的可用性研究已成为近几十年来研究人员和工程师关注的主要问题之一。废塑料既可用作骨料替代品,也可用作纤维增强剂来提高胶凝混合物的性能。研究了含硅灰和微二氧化硅的废PVC纤维增强砂浆的性能。塑料纤维按0%、1%、2%和3%的体积分数加入砂浆混合物中。微二氧化硅和硅灰分别取代水泥重量的5%、10%和15%。总共生产了28组不同的迫击炮。结果表明,废聚氯乙烯塑料纤维的加入提高了砂浆的延性和变形性能。可见,纤维抑制了砂浆的裂纹扩展,保持了砂浆的完整性,从而提高了砂浆的延性。另一方面,纤维的加入导致砂浆样品的物理力学性能降低。随着纤维含量的增加,砂浆试样的抗压强度逐渐降低。硅灰替代水泥改善了砂浆的力学性能和微观结构性能。结果还表明,硅灰显著降低了砂浆样品的孔隙率和吸水能力。
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引用次数: 3
Detection and Analysis of Microfibers and Microplastics in Wastewater from a Textile Company 某纺织企业废水中微纤维和微塑料的检测与分析
Pub Date : 2022-10-03 DOI: 10.3390/microplastics1040040
Sinem Hazal Akyildiz, R. Bellopede, H. Sezgin, I. Yalcin-Enis, B. Yalçın, S. Fiore
Textile wastewater is polluted by inorganic/organic substances, polymers, dyes, and microfibers (MFs), which are microplastics (MPs) and natural fibers. This work is aimed at the preliminary investigation of MFs and MPs in textile industrial wastewater, and at evaluating the removal efficiency of an on-site wastewater treatment plant (WWTP). Ten samples of inflows and outflows of the WWTP of a textile company (applying a physic-chemical process) have been analyzed. Firstly, the samples underwent a pretreatment with 15% hydrogen peroxide at 25 °C for 5 days to remove organic compounds. Secondly, the MFs were recovered from the aqueous phase by pre-screening centrifugation, density separation, and filtration as alternative options. Filtration obtained the best performances, compared to the other recovery processes. Thirdly, the MFs were counted through optical microscopy and the MPs were identified through micro-FTIR. The MFs amount in the inflow samples was in the range of 893–4452 MFs/L. The outflow samples (310–2404 MFs/L) exhibited a 38–65% reduction compared to the inflows, demonstrating that up to 62% of residual MFs can enter the sewer network or the receiving water body. Cotton and wool, and numerous MPs (acrylic, polyester, polypropylene, polyamide, and viscose/rayon) were identified in the inflow and outflow samples (with the only exception of “dense” viscose (rayon), not detected in the outflows, and probably retained by the WWTP with the sludge). This study, even if just preliminary, offers interesting hints for future research on MFs/MPs detection in textile wastewater, and on the performance of a full-scale WWT process for their removal.
纺织废水受到无机/有机物质、聚合物、染料和微纤维(MFs)的污染,微纤维是微塑料(MPs)和天然纤维。本研究旨在对纺织工业废水中多聚物(MFs)和多聚物(MPs)进行初步调查,并对现场污水处理厂(WWTP)的去除率进行评价。本文分析了某纺织公司(采用物理化学法)污水处理厂的10个流入和流出样本。首先,样品在25℃下用15%过氧化氢预处理5天,去除有机化合物。其次,通过预筛选离心、密度分离和过滤等方法从水相中回收MFs。与其他回收工艺相比,过滤工艺的性能最好。第三步,通过光学显微镜对MFs进行计数,并通过显微ftir对MPs进行鉴定。流入样品的MFs量在893-4452 MFs/L之间。流出样品(310-2404 MFs/L)与流入样品相比减少了38-65%,表明高达62%的剩余MFs可以进入下水道网络或接收水体。在流入和流出的样品中发现了棉花和羊毛,以及许多MPs(丙烯酸、聚酯、聚丙烯、聚酰胺和粘胶/人造丝)(唯一的例外是“致密”粘胶(人造丝),在流出的样品中未检测到,可能被污水处理系统与污泥一起保留了下来)。这项研究,即使只是初步的,为未来研究纺织废水中MFs/MPs的检测,以及全面的污水处理过程去除它们的性能提供了有趣的提示。
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引用次数: 5
Microplastics in Namibian river sediments – a first evaluation 纳米比亚河流沉积物中的微塑料——首次评估
Pub Date : 2022-09-27 DOI: 10.1186/s43591-022-00043-1
L. Faulstich, J. Prume, R. Arendt, Christian Reinhardt-Imjela, P. Chifflard, A. Schulte
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引用次数: 8
期刊
Microplastics and nanoplastics
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