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Recent Advances in Microplastics Removal from Water with Special Attention Given to Photocatalytic Degradation: Review of Scientific Research 以光催化降解为重点的水中微塑料去除研究进展
Pub Date : 2023-09-04 DOI: 10.3390/microplastics2030023
N. Sacco, F. M. Zoppas, Alejandra Devard, María del Pilar González Muñoz, Gonzalo García, F. A. Marchesini
Microplastic pollution has become a global environmental concern with detrimental effects on ecosystems and human health. Effective removal of microplastics from water sources is crucial to mitigate their impacts. Advanced oxidative processes (AOPs) have emerged as promising strategies for the degradation and elimination of microplastics. This review provides a comprehensive overview of the application of AOPs in the removal of microplastics from water. Various AOPs, such as photocatalysis, ozonation, and Fenton-like processes, have shown significant potential for microplastic degradation. These processes generate highly reactive species, such as hydroxyl radicals, which can break down microplastics into smaller fragments or even mineralize them into harmless byproducts. The efficiency of photocatalytic oxidation depends on several factors, including the choice of photocatalysts, reaction conditions, and the physicochemical properties of microplastics. Furthermore, this review discusses the challenges associated with photocatalytic oxidation, such as the need for optimization of operating parameters and the potential formation of harmful byproducts. Overall, photocatalytic oxidation offers a promising avenue for the removal of microplastics from water, contributing to the preservation of aquatic ecosystems and safeguarding human health. However, further research is needed to address the limitations and optimize the implementation of this process for effective and sustainable microplastic remediation.
微塑料污染已成为一个全球性的环境问题,对生态系统和人类健康产生有害影响。从水源中有效去除微塑料对于减轻其影响至关重要。高级氧化工艺(AOPs)已成为降解和消除微塑料的有前途的策略。本文综述了AOPs在去除水中微塑料中的应用。各种AOPs,如光催化、臭氧化和芬顿样过程,已经显示出微塑料降解的巨大潜力。这些过程会产生高活性物质,如羟基自由基,它们可以将微塑料分解成更小的碎片,甚至将其矿化成无害的副产品。光催化氧化的效率取决于几个因素,包括光催化剂的选择、反应条件和微塑料的物理化学性质。此外,本文还讨论了与光催化氧化相关的挑战,如需要优化操作参数和潜在的有害副产物的形成。总的来说,光催化氧化为从水中去除微塑料提供了一条很有前途的途径,有助于保护水生生态系统和保障人类健康。然而,需要进一步的研究来解决这一过程的局限性并优化其实施,以实现有效和可持续的微塑料修复。
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引用次数: 0
Mind the gap: forest soils as a hidden hub for global micro- and nanoplastic pollution 注意差距:森林土壤是全球微塑料和纳米塑料污染的隐藏中心
Pub Date : 2023-09-01 DOI: 10.1186/s43591-023-00067-1
Collin J. Weber, Matthias C. Rillig, Moritz Bigalke
Abstract Global plastic pollution has become a major concern because of its effects on environmental and human health. A major fraction of environmental plastics is likely stored temporarily within terrestrial soils. However, even though forests represent the third most common type of land cover on Earth, almost nothing is known about plastics in forest soils. The atmospheric transport of micro- and nanoplastics provides ample opportunity for forest canopies to intercept plastic particles. These plastic particles, together with local plastic sources like litter and items used in forest management, eventually reach forest soils. In this paper we discuss the potential role of forest soils as a hub within global plastic cycles; transport processes from the atmosphere to the soil; and the integration of plastics into forest material cycles. Taken together, plastic in forests could have a major impact on sensitive ecosystems, economically important functions and global environmental plastic budgets. We also develop a roadmap for further investigation into plastics in forest soil systems.
由于塑料污染对环境和人类健康的影响,全球塑料污染已成为人们关注的焦点。很大一部分环境塑料可能暂时储存在陆地土壤中。然而,尽管森林是地球上第三大最常见的土地覆盖类型,但人们对森林土壤中的塑料几乎一无所知。微塑料和纳米塑料的大气运输为森林树冠拦截塑料颗粒提供了充足的机会。这些塑料颗粒,连同当地的塑料来源,如垃圾和森林管理中使用的物品,最终到达森林土壤。在本文中,我们讨论了森林土壤作为全球塑料循环枢纽的潜在作用;从大气到土壤的运输过程;以及将塑料融入森林材料循环。总之,森林中的塑料可能对敏感的生态系统、重要的经济功能和全球环境塑料预算产生重大影响。我们还为进一步研究森林土壤系统中的塑料制定了路线图。
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引用次数: 0
Detection of Secondary Microplastics in an Aquatic Mesocosm by Means of Object-Based Image Analysis 基于目标的图像分析方法检测水生环境中次生微塑料
Pub Date : 2023-08-07 DOI: 10.3390/microplastics2030022
Dahlia E. Carmona-Valdivieso, T. Valdivieso, V. Carmona-Galindo
When plastics are discarded, they do not biodegrade and instead break down over time into progressively smaller particles, termed secondary microplastics, which adversely impact biota and human health as well as persist in the environment for centuries. Our research objective was to evaluate the capabilities of object-based image analyses in detecting compositionally varied microplastics suspended in an aquatic mesocosm under no-slip and turbulent water conditions. We found that the presence of polypropylene, polyethylene terephthalate, and low-density polyethylene microplastic pollution in both single-type and mixed-type suspensions was not detectable by either average red (R), average blue (B), average green (G), or average RBG pixel intensities, but was significantly detectable by means of total RBG pixel intensity from digital imagery of the surface-water. Our findings suggest that object-based image analyses of surface waters to quantify pixel information is better suited for monitoring the presence and absence of suspended microplastics, rather than for the stepwise determination of microplastic concentrations. We propose the development of a smartphone application to facilitate citizen-science monitoring of microplastic contamination as well as comment on future applications utilizing drone imagery to boost cloud-based mapping spatiotemporal plumes.
当塑料被丢弃时,它们不能生物降解,而是随着时间的推移分解成越来越小的颗粒,称为次级微塑料,它们对生物群和人类健康产生不利影响,并在环境中持续存在几个世纪。我们的研究目的是评估基于物体的图像分析在无滑移和湍流水条件下检测悬浮在水生中游环境中成分变化的微塑料的能力。我们发现,在单一类型和混合类型悬浮液中,聚丙烯、聚对苯二甲酸乙二醇酯和低密度聚乙烯微塑料污染的存在,通过平均红色(R)、平均蓝色(B)、平均绿色(G)或平均RBG像素强度都无法检测到,但通过地表水数字图像的总RBG像素强度可以明显检测到。我们的研究结果表明,基于物体的地表水图像分析来量化像素信息更适合于监测悬浮微塑料的存在和不存在,而不是逐步确定微塑料浓度。我们建议开发一款智能手机应用程序,以促进微塑料污染的公民科学监测,并对利用无人机图像促进基于云的时空羽流测绘的未来应用程序进行评论。
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引用次数: 1
Characterization of Microplastics and Mesoplastics and Presence of Biofilms, Collected in the Gualí Wetland Cundinamarca, Colombia 哥伦比亚Cundinamarca Gualí湿地中微塑料和中塑料的特征及生物膜的存在
Pub Date : 2023-08-01 DOI: 10.3390/microplastics2030021
Maria Alejandra Porras-Rojas, Cristina Charry-Vargas, Jorge Leonardo Muñoz-Yustres, Paula Martínez-Silva, Luis David Gómez-Méndez
Wetlands are being contaminated by housing developments, effluents, industrial areas, and poor sanitation, resulting in the presence of plastic polymers and the development of biofilms on these materials, which represent an elevated risk to freshwater fauna and flora. The objective of this study was to characterize mesoplastics and microplastics, collected in the Gualí Wetland, Colombia, as well as to verify the presence of biofilms on such polymers. Nine water samples (36 L per sample) were evaluated at three points of the wetland; the size of the particles was determined by image analysis, the type of polymer through FTIR, and the presence of biofilms by microscopy. A total of 79 items/0.135 m3 were collected, 2 macroplastic items, 53 mesoplastic items, and 24 microplastic items. The presence of fragments (70%) and pellets (41%), with transparent (40%) and white (30%) being the predominant ones, was outstanding. Among the polymers, high-density polyethylene (HDPE) dominated, followed by expanded polystyrene. The results of SEM demonstrated the presence of diatoms on the surface of the plastic polymers. Furthermore, the results showed a greater amount of HDPE mesoplastics and microplastics in the shape of fragments and pellets. In addition, the presence of biofilms on these plastic particles can increase the adsorption of contaminants, negatively affecting this ecosystem. The outcome of this study can be used to identify bacteria that reside in biofilms associated with microplastics and mesoplastics.
湿地受到住房开发、污水、工业区和卫生条件差的污染,导致塑料聚合物的存在和这些材料上生物膜的形成,这对淡水动植物构成了更高的风险。本研究的目的是表征在哥伦比亚Gualí湿地收集的中塑料和微塑料,并验证这些聚合物上存在生物膜。在湿地的三个点对9个水样(每个水样36 L)进行了评估;通过图像分析确定颗粒的大小,通过FTIR确定聚合物的类型,并通过显微镜确定生物膜的存在。共收集79个/0.135 m3,其中大塑性2个,中塑性53个,微塑性24个。以透明(40%)和白色(30%)居多,可见碎片(70%)和微球(41%)。聚合物中以高密度聚乙烯(HDPE)居多,其次为膨胀聚苯乙烯。扫描电镜结果表明,硅藻存在于塑料聚合物表面。此外,结果显示,HDPE中塑料和微塑料的碎片和颗粒形状的数量更多。此外,这些塑料颗粒上生物膜的存在会增加污染物的吸附,对生态系统产生负面影响。本研究结果可用于鉴定与微塑料和中塑料相关的生物膜中存在的细菌。
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引用次数: 0
A practical primer for image-based particle measurements in microplastic research 用于微塑料研究中基于图像的颗粒测量的实用引物
Pub Date : 2023-08-01 DOI: 10.1186/s43591-023-00064-4
U. Schnepf, Maria Anna Lioba von Moers-Meßmer, F. Brümmer
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引用次数: 0
Microplastics in Lampanyctus crocodilus (Risso 1810, Myctophidae), a Common Lanternfish Species from the Ibiza Channel (Western Mediterranean) 伊比沙海峡(西地中海)常见灯笼鱼——Lampanyctus crocodilus (Risso 1810, Myctophidae)的微塑料研究
Pub Date : 2023-07-18 DOI: 10.3390/microplastics2030020
Olga Novillo-Sanjuan, Sergio Gallén, J. Raga, J. Tomás
Microplastics’ presence in the pelagic environment is still largely unknown due to the difficulty of sampling in this part of the ocean. In this study, we quantify microplastics’ exposure in a pelagic lanternfish species from the western Mediterranean, Lampanyctus crocodilus (Risso 1810), which occupies an intermediate position in the marine food web. L. crocodilus were captured in the Ibiza Channel by a trawling vessel and microplastics were extracted by digestion of their gastrointestinal systems. Almost half of the analysed lanternfish contained microplastics, mostly blue and black fibres (40.9% and 34.66%, respectively). In fishes with at least one microplastic, the median was 3 MPs/fish (CI 95% = 3.46–6.8), similar to other studies performed in other fish species in the area. Biometric parameters of fish, such as total length and body condition, were not correlated with the number of microplastics. Data presented here contribute to quantifying the severity of microplastic pollution in the pelagic environment and in a wild, non-commercial species.
由于在海洋的这一部分取样困难,微塑料在远洋环境中的存在在很大程度上仍然未知。在这项研究中,我们量化了来自西地中海的一种远洋灯笼鱼——lamanyctus鳄鱼(Risso 1810)的微塑料暴露,该物种在海洋食物网中处于中间位置。一艘拖网渔船在伊比沙海峡捕获了鳄鱼,并通过消化其胃肠道系统提取了微塑料。几乎一半的分析灯笼鱼含有微塑料,主要是蓝色和黑色纤维(分别为40.9%和34.66%)。在至少含有一种微塑料的鱼类中,中位数为3 MPs/鱼(CI 95% = 3.46-6.8),与该地区其他鱼类进行的其他研究相似。鱼类的生物特征参数,如总长度和身体状况,与微塑料的数量无关。这里提供的数据有助于量化远洋环境和野生非商业物种中微塑料污染的严重程度。
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引用次数: 0
Microplastics on Beaches in the Nautla-Vega de Alatorre Turtle Nesting Area, Veracruz 韦拉克鲁斯州纳特拉-维加德阿拉托雷海龟筑巢区海滩上的微塑料
Pub Date : 2023-07-14 DOI: 10.3390/microplastics2030019
C. I. Ruíz-Reyes, F. Lango-Reynoso, M. Castañeda-Chávez, Ángel Morán-Silva
The low cost of production and the widespread use of plastics has brought about a problem that is difficult to measure; microplastics are considered emerging pollutants because their presence can pose a risk to the environment. This study focuses on the characterization of microplastics (MPs) in the nesting area of green (Chelonia mydas) and Kemp’s ridley (Lepidochelys kempii) sea turtles, on the coastal municipalities of Nautla and Vega de Alatorre, Veracruz, Mexico. Five beaches along 15.5 km of coastline were analyzed and samples were taken in the intertidal zone. In this work, only microplastics in sizes from one to five mm were analyzed. A characterization of the potential sources of microplastics at the basin level was carried out and 94% of the samples analyzed presented MPs, the greatest amount was at site Playa Navarro (B32) (1.2 Item/kg dw), and in the high tide zone (4.86 ± 2.79 Item/kg dw). The predominant color of the MPs was white (42%), the most representative form were fragments (31%), while most of the MPs presented sizes of 4–5 mm (35%) followed by 1–2 mm (34%). The chemical composition of most of the MPs was polyethylene (55%). Regarding the sources of the MPs generation, livestock, agriculture, fishing, tourism, wastewater discharges, urban solid waste and, to a lesser extent, the plastic industry were identified. The mobilization factors of the MPs turned out to be the Colipa and Misantla rivers with runoff from the basin, wind, waves and marine currents.
低成本的生产和塑料的广泛使用带来了一个难以衡量的问题;微塑料被认为是新兴污染物,因为它们的存在会对环境构成威胁。本研究重点研究了墨西哥韦拉克鲁斯州纳特拉和维加德阿拉托雷沿海城市绿海龟(Chelonia mydas)和肯普雷德利海龟(Lepidochelys kempii)筑巢区微塑料(MPs)的特征。对15.5公里海岸线上的5个海滩进行了分析,并在潮间带取样。在这项工作中,只分析了1到5毫米大小的微塑料。分析结果表明,94%的样品存在MPs,其中以Playa Navarro (B32) (1.2 Item/kg dw)和高潮区(4.86±2.79 Item/kg dw)含量最高。MPs的主要颜色为白色(42%),最具代表性的形式为碎片(31%),而大多数MPs的大小为4-5 mm(35%),其次是1-2 mm(34%)。大多数MPs的化学成分为聚乙烯(55%)。关于产生MPs的来源,确定了牲畜,农业,渔业,旅游业,废水排放,城市固体废物,以及较小程度上的塑料工业。国会议员的动员因素是来自盆地的径流,风,波浪和海流的科里帕河和米桑特拉河。
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引用次数: 1
Status quo of operation procedures for soil sampling to analyze microplastics 土壤取样分析微塑料的操作程序现状
Pub Date : 2023-07-13 DOI: 10.1186/s43591-023-00063-5
Kristof Dorau, M. Hoppe, Daniel Rückamp, J. Köser, G. Scheeder, Katrin Scholz, E. Fries
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引用次数: 0
Tyre and road wear particles from source to sea 从源头到海洋的轮胎和道路磨损颗粒
Pub Date : 2023-07-03 DOI: 10.1186/s43591-023-00060-8
K. Mattsson, Juliana Aristéia de Lima, T. Wilkinson, Ida Järlskog, Elisabet Ekstrand, Yvonne Andersson Sköld, M. Gustafsson, M. Hassellöv
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引用次数: 2
Preliminary Assessment into the Prevalence and Distribution of Microplastics in North and South Pacific Island Beaches 北太平洋和南太平洋岛屿海滩微塑料流行和分布的初步评估
Pub Date : 2023-06-29 DOI: 10.3390/microplastics2030018
M. Bleszynski, E. Clark
Microplastic pollution has become an increasing danger to marine wildlife and ecosystems worldwide. The continued increase in the production of plastic products has caused microplastic pollution to become more distributed, especially along shorelines. Therefore, to better assess the pervasiveness of microplastics around the Pacific Islands, in this work, we conducted a preliminary investigation into the pervasiveness of microplastics along eight different North and South Pacific Island beaches located in New Zealand and Hawaii. Microplastic prevalence was investigated as a function of beach location, sand type, and microplastic type. Our analysis found that all eight locations contained some level of microplastics, and sheltered fine-grained sand beaches contained the highest level of microplastics, with the largest particle size distribution. In addition, spectroscopy analysis was conducted to assess the plastic type, which showed that nylon and polypropylene were the most common types of microplastics among the tested samples. The results of this study offer a preliminary insight into the microplastic accumulation among different beaches, indicating that sheltered fine-grained beaches and ecosystems may be more susceptible to microplastic accumulation.
微塑料污染已成为全球海洋野生动物和生态系统日益严重的威胁。塑料制品生产的持续增加导致微塑料污染变得更加分散,特别是沿着海岸线。因此,为了更好地评估太平洋岛屿周围微塑料的普遍性,在这项工作中,我们对位于新西兰和夏威夷的八个不同的北太平洋和南太平洋岛屿海滩的微塑料的普遍性进行了初步调查。研究了微塑性流行率与海滩位置、沙质类型和微塑性类型的关系。我们的分析发现,所有8个地点都含有一定程度的微塑料,而隐蔽的细粒沙滩含有的微塑料含量最高,粒径分布最大。此外,对塑料类型进行了光谱分析,结果表明,尼龙和聚丙烯是测试样品中最常见的微塑料类型。本研究的结果为不同海滩之间的微塑料积累提供了初步的见解,表明受庇护的细粒海滩和生态系统可能更容易受到微塑料积累的影响。
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引用次数: 0
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Microplastics and nanoplastics
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