Powder Metallurgy and Metal Ceramics最新文献

Pressed porous glass-ceramic carbon fiber biocomposites were produced from hydroxyapatite/glass and nanostructured carbon fibers. The specific features of the production process, as well as the composition, macrostructure, microstructure, and porosity of these biocomposites, were studied. The prospects for their medical applications, particularly in surgical osteoplasty, were identified. The starting materials included calcium phosphate glass ceramics derived from biogenic hydroxyapatite, featuring both bound and migrating glass phases, and activated nanostructured carbon fibers. The glass ceramics with a bound glass phase were produced by sintering powder mixtures of biogenic hydroxyapatite and sodium borosilicate glass, while those with a migrating glass phase were produced through mechanical mixing of biogenic hydroxyapatite and sodium borosilicate glass powders. The fine activated nanostructured carbon fibers used in the biocomposites were obtained by the mechanical grinding of a woven material from activated nanostructured carbon fibers. This material resulted from the controlled stepwise pyrolysis of hydrocellulose fabrics, followed by high-temperature vapor activation of the nanostructured fiber surface. To make cylindrical biocomposite samples, the fine activated nanostructured carbon fibers were blended with moistened mixtures of biogenic hydroxyapatite glass ceramics with bound and migrating glass phases and subjected to semidry pressing and incremental sintering with holding at 800°C. The selected process parameters enabled the production of pressed carbon fiber biocomposites with the desired composition and showed the ability to control their porous structure, achieving a relative density of 0.36–0.41, by regulating the behavior of the glass phases and the sintering of the reinforcing component. The biocomposite structures were examined by scanning electron microscopy. Energy-dispersive X-ray analysis was conducted to determine the chemical composition of the samples. The structures of the composites were analyzed and compared on the basis of their sorption capacities, determined from benzene adsorption–desoprtion isotherms using the gravimetric method. Analysis of the macrostructure, microstructure, and surface morphology of transverse and longitudinal sections of the biocomposites revealed a multiporous amorphous-crystalline microstructure, arising from the varying behavior of the glass phases, the presence of chaotically oriented short fine nanostructured carbon monofibers with diameters of several microns and a developed system of micro- and macropores on their surface, and spatial multidirectional hollow channels formed through the complete or partial combustion of the fibers.

Conglomerated (Ti, Cr)B₂–NiAlCrWCoMoTi composite powders for thermal spraying and deposition through sintering followed by milling were produced. The main processes stages in the production of powders, such as mixing, grinding, sintering, milling, and classification, were optimized. The effect of briquette sintering temperature on the milling efficiency and finished powder yield was determined. Solid-phase sintering was found to be feasible at temperatures 200–300ºC lower than the liquid-phase formation temperature. The influence exerted by the ratio of the refractory to metal components on the technological properties of the powders was studied. The flowability of the powders increased nonlinearly with a higher content of the metal component and greater particle sizes. The influence exerted by the ratio of the refractory to metal components on the morphology of powder particles was analyzed. The powder particles had a fragmentary elongated shape with a higher content of the refractory (Ti, Cr)B₂ component, while they acquired a more oval shape with a greater amount of the metal component. The composition and microstructure of individual powder particles were examined. They showed a heterophase microstructure. The uniform distribution of structural components in individual powder particles was found to depend on the mixing and grinding modes for powder mixtures. The uniform distribution of structural components in individual particles requires that particles of the starting powder components be significantly smaller (one-fifth or even less) than particles of the finished composite powder. The difference in the starting particle sizes for refractory and metal components should be no more than 2–3 times.

The thermal processes involved in the recrystallization within porous ultrapure iron compacts heated after cold pressing in a steel die were experimentally studied. The temperatures of recrystallization stages were shown to correspond to the heating behavior of metals and alloys. Depending on the heating rate of compacted powdered iron, various types of thermokinetic behavior were identified, indicating the nonlinear nature of interactions within the deformed powder body. Stages with both nonlinear and linear thermal behavior were present, as evidenced by the competition between several processes leading to the emergence of wave-like transfer of energy, accumulated while powdered iron deformed during cold pressing. The thermokinetic patterns observed in the heating of compacts, especially those made of pure iron, allowed all stages of relaxation in the deformed metal to be identified. The temperature profile in the heating process generally reflects the thermal state of the powdered metal, influenced by the additional release of energy accumulated in deformation. At some stages, heat release led to nonlinear processes, resulting in the occurrence of thermal waves. Both asynchronous and synchronous temperature changes were observed. In asynchronous behavior, nonlinear waves emerged. The superposition of relaxation processes in the generation of thermal waves is possible. At specific heating rates, the maximum amount of energy is simultaneously released in the relaxation and recrystallization processes, as testified by an increase in temperature to 550°C. The relaxation processes involve less energy compared to the recrystallization processes and the transition to the annealed state. In addition, after complete recrystallization, the onset of the sintering process was observed under temperature oscillations with damping.

The potential for amplifying tunnel magnetoresistance and magnetoimpedance in island nanofilms without energy consumption or the use of amplifying devices was studied. Such amplification was observed for the films deposited on a Gd₂O₃ layer instead of a glass substrate. The enhancement is due to the f–d exchange interaction established between atoms with unfilled f- and d-electron shells, present in both Fe and Gd₂O₃. The f–d exchange interaction enhances the ordering of the magnetic structure within the Fe ferromagnetic layer, increases its magnetization, and subsequently improves the properties that depend on this magnetization. Iron and Gd₂O₃ were selected because the magnetic moments of Fe in the iron group and Gd in the lanthanide series are among the highest effective ones: μ_Fe = 7.13 μ_B and μ_Gd = 7.95 μ_B. This, according to theory, determines the high energy of the f–d exchange interaction. The island morphology of Fe films deposited on a Gd₂O₃ layer enabled electron tunneling under the influence of the f–d exchange interaction. This allowed the study of tunnel magnetoresistance under direct current and magnetoimpedance under alternating current influenced by the f–d exchange interaction. The frequency dependence of the active component Z', the reactive component Z'', and the total impedance Z of Fe films on glass and Gd₂O₃ substrates, without and under a constant magnetic field of 7500 Oe, was analyzed. These characteristics are used to determine the frequency dependence of tunnel magnetoimpedance and estimate tunnel magnetoresistance for Fe island films on glass and Gd₂O₃ substrates. These characteristics were found to be 55 % higher, on average, for Fe deposited on Gd₂O₃ than for Fe on glass, both at a low frequency of 0.1 Hz for tunnel magnetoresistance and at higher frequencies of 1–10⁵ Hz for tunnel magnetoimpedance. This results from the influence of f–d exchange interaction on electron tunneling between the iron islands.

In this study, the creep behavior, mechanical properties, and microstructure evolution of AA 1050/SiC/Cu composite strips fabricated by accumulative roll bonding (ARB) process are experimentally investigated. All specimens were fabricated with different SiC wt.% with a maximum of eight cumulative cycles of ARB. The study of creep behavior and mechanical properties showed the formation of a 17 μm atomic diffusion layer at the interface during ARB under three creep loading conditions, namely 35 MPa at 225°C, 35 MPa at 275°C, and 30 MPa at 225°C. An intermetallic compound formed near Al, resulting in a 40% increase in interface thickness with increasing temperature at constant stress. However, the creep failure time decreased by 44% and the stress level decreased by 13% at a constant temperature without any significant effect on the interface thickness. In different conditions, it was observed that at a constant temperature with an increase in stress level, the second steady state creep rate of the creep curve reaches to 39%, while it decreases to 2% with a small increase in temperature. It can be concluded that the applied temperature and stress affect the creep properties and especially lead to an increase in the steady-state creep rate of the creep curves with higher stresses. This trend was the opposite for the creep temperature at higher temperature levels. Furthermore, dynamic recrystallization was observed through the crystalline structure of the samples.

The tribotechnical properties of the Cu–(4–6) wt.% Ni–(1–1.5) wt.% Ti–(7–10) wt.% Al–(0.5–0.8) wt.% Si‒(5–8) wt.% CaF₂ antifriction composite were studied. The effect of tribofilms that form and evolve in the friction process in air at loads of 2.0 MPa and rotational speeds from 5,000 to 15,000 rpm on the tribological properties was analyzed. The evolution of dissipative tribofilms and the counterface occurs through a bifurcation mechanism with a transition to one of two attractors, depending directly on the high-speed loading modes. At speeds of 5,000–13,000 rpm, a continuous homogeneous lubricating layer forms on the contacting surfaces. Electron microscopy and elemental mapping of the tribofilm confirmed that the distribution of elements was uniform, promoting high antifriction properties and a sustained self-lubrication mode. With increase in the rotational speed to 15,000 rpm, the system exhibits a self-organization effect in the formation of a coarse heterogeneous tribofilm. This tribofilm loses its continuity and is an accumulation of phases, leading to a sharp decline in antifriction properties. The dual formation of tribofilms is decisively influenced by operating conditions, particularly the intensity of external energy. Depending on this energy, tribofilms show different structures and manifest in two functionally opposite types, transforming from antifriction films to friction ones, resulting in significantly different tribotechnical properties. Copper-based antifriction composites can be recommended as an effective alternative to cast bronzes for operation at rotational speeds of 5,000–13,000 rpm and loads of 2.0 MPa in the friction units of forming, printing, and offset cylinders in high-speed printing equipment.

Experimental studies were conducted to refine the theoretical provisions concerning the mechanism and kinetics of penetration for a metal melt consisting of destructive reagents, such as gallium, indium, tin, and zinc (destructive composition), along the grain boundaries in unstressed metal samples. It was experimentally confirmed that the penetration rate of the destructive composition was limited by processes at the liquid phase front, including dissolution of intergranular boundary areas, recrystallization to form solid solution crystals, and opening of new crack areas under the pressure of growing crystals. The experimental findings indicated a significant decrease in the strength of aluminum alloys resulting from the effect of the destructive composition. Analytical dependences and corresponding empirical coefficients characterizing the effects of the destructive composition on structural aluminum alloy elements under tensile loads were derived. These empirical coefficients enable the determination of conditions under which aluminum alloy structures fail under the influence of destructive compounds, considering the tensile stresses. The effect of the destructive alloy on the onset of fatigue damage and the durability of aluminum alloy structures under asymmetric cyclic stresses was examined. Significant reduction in the fatigue strength of aluminum structures under the influence of the destructive composition was experimentally confirmed.

The TC4 (Ti6Al4V) titanium alloy fabricated by Selective Laser Melting (SLM) has gained significant attention in recent years due to its exceptional properties, including high strength-toweight ratio, excellent corrosion resistance, and biocompatibility. This study examines the effect of heat treatment on the microstructure, phase composition, and mechanical properties of SLMfabricated TC4 alloy, to provide a more comprehensive understanding of the material's behavior under varying thermal conditions. Experimental results demonstrated that the as-deposited TC4 alloy has a relative density above 0.99. The as-deposited TC4 alloy was mainly composed of closepacked hexagonal structure α/ α′ phases. In addition, a small amount of β-phase was also detected. After annealing treatment, the TC4 alloy showed a similar phase composition. The microstructure of the as-deposited TC4 alloy was composed of acicular martensite a′phase accompanied by α-phase in β-matrix. After annealing treatment, the acicular α′ martensite decomposed, transforming the microstructure into a lamellar structure consisting of α- and β-phases. The microhardness was to 351.7 HV_0.2, the tensile strength was approximately 1,120 MPa, and the yield strength comprised approximately 1,080 MPa of the TC4 alloy fabricated by SLM. The tensile fracture surface of the asdeposited alloy demonstrated a mixture of brittle and ductile fracture. A quasi-cleavage river pattern and a small amount of irregular dimples can be observed. After annealing treatment, the elongation increased to 16.5% due to a slight decrease in hardness and tensile strength. The Vickers hardness was 323.1 HV_0.2, the tensile strength was approximately 960 MPa, and the yield strength was about 925 MPa, respectively. The amounts and the size of dimples increased significantly and displayed typical ductile fracture. This research would provide valuable insights into optimizing the performance of SLM-fabricated TC4 alloys for various engineering applications.

The paper presents a comprehensive analysis of leading trends in nickel powder production techniques. The physical and technological properties of nickel powders are systematized according to chemical composition, average size and morphology of particles and their agglomerates, specific surface area, and apparent density. These data will be useful to potential consumers for the optimal design of functional properties of nickel powder products. The review compares industrial and modern techniques, focusing on their key advantages and disadvantages. The development of new process methods and techniques, such as reduction of nickel oxides with hydrogen in fluidized bed reactors and rotary furnaces, is demonstrated. Various methods for synthesizing nanosized nickel powders for special applications, being at the laboratory research stage, are considered. These methods include deposition and thermal decomposition from solutions using various precursors, synthesis under microwave radiation, laser ablation, plasma chemical synthesis, green synthesis, etc. The properties of powders produced by the reduction of nickel precursors with hydrazine, alkali metal borohydrides, polyols, urotropine, polystyrene, etc. are analyzed. Environmetal and human health concerns related to nickel powder production methods are briefly discussed. Carbonyl, electrolytic, and hydrometallurgical methods allow the production of nickel powders in large quantities but involve high energy consumption and production toxicity. Wet chemistry methods for producing nanosized nickel powders use various toxic chemical reagents, potentially causing environmental issues when implemented industrially. Hydrogen reduction of nickel oxide, as an environmentally friendly method, offers unconditional advantages, including reduced greenhouse gas emissions and zero solvent waste.

The thermal processes of recrystallization in porous copper compacts heated after cold pressing in a steel die were experimentally studied. The recrystallization stages, with temperatures corresponding to data determined with metallographic and other research methods, were identified. Only the first tempering stage was found to occur uniformly throughout the entire volume at a heating temperature of 190°C. Upon further heating, a linear stage ensued, where the temperature remained consistent throughout the entire volume of the material, persisting until the next stage. This was accompanied with energy release, as confirmed by a zero temperature gradient across all regions within the sample. With an increase in temperature to 210–215°C, a thermal surge was observed and visible temperature asynchronization was noted in individual volumes of the sample. However, this was followed by a temperature gradient between individual volumes. At this stage, asynchronized thermal behavior within the sample was observed for the first time, as evidenced by the emergence of thermal waves. Subsequent stages demonstrated nonlinear thermal behavior, evidenced by several competing processes leading to the wave-like transfer of energy accumulated as the copper powders deformed during cold pressing. Like recrystallization processes with first-order reactions in the high-temperature synthesis of intermetallic and other compounds, the emergence of thermal waves was due to several competing processes. Thus, if microplastic deformation processes occurred during recrystallization, then traveling waves could arise in the system, which was actually revealed. This could lead to thermal interference and subsequently to local buildup of thermal energy, potentially causing a sharp increase in temperature in individual areas of the wires deformed during switching and, as a result, their ignition. The temperature surges observed were likely to cause the combustion of insulating materials. Therefore, this can explain the causes of accidents that occur in the operation of complex mechanisms with numerous electrical circuits.