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Role of anisotropy in understanding the molecular grounds for density scaling in dynamics of glass-forming liquids. 各向异性在理解玻璃态液体动力学密度缩放的分子基础中的作用
Pub Date : 2024-07-03 DOI: 10.1088/1361-6633/ad569d
A Grzybowski, K Koperwas, M Paluch

Molecular Dynamics (MD) simulations of glass-forming liquids play a pivotal role in uncovering the molecular nature of the liquid vitrification process. In particular, much focus was given to elucidating the interplay between the character of intermolecular potential and molecular dynamics behaviour. This has been tried to achieve by simulating the spherical particles interacting via isotropic potential. However, when simulation and experimental data are analysed in the same way by using the density scaling approaches, serious inconsistency is revealed between them. Similar scaling exponent values are determined by analysing the relaxation times and pVT data obtained from computer simulations. In contrast, these values differ significantly when the same analysis is carried out in the case of experimental data. As discussed thoroughly herein, the coherence between results of simulation and experiment can be achieved if anisotropy of intermolecular interactions is introduced to MD simulations. In practice, it has been realized in two different ways: (1) by using the anisotropic potential of the Gay-Berne type or (2) by replacing the spherical particles with quasi-real polyatomic anisotropic molecules interacting through isotropic Lenard-Jones potential. In particular, the last strategy has the potential to be used to explore the relationship between molecular architecture and molecular dynamics behaviour. Finally, we hope that the results presented in this review will also encourage others to explore how 'anisotropy' affects remaining aspects related to liquid-glass transition, like heterogeneity, glass transition temperature, glass forming ability, etc.

玻璃化液体的分子动力学 MD 模拟在揭示液体玻璃化过程的分子性质方面发挥了关键作用。其中,阐明分子间势能特性与分子动力学行为之间的相互作用是重点。我们试图通过模拟各向同性势能相互作用的球形粒子来实现这一目标。然而,当使用密度缩放方法对模拟数据和实验数据进行相同分析时,发现两者之间存在严重差异。通过分析计算机模拟获得的弛豫时间和 pVT 数据,可以确定相似的缩放指数值。相反,在对实验数据进行相同分析时,这些值却大相径庭。正如本文所详细讨论的,如果在 MD 模拟中引入分子间相互作用的各向异性,就可以实现这些结果之间的一致性。在实践中,有两种不同的方法可以实现这一点:(1) 使用盖-伯恩(Gay-Berne)类型的各向异性势能;或 (2) 用通过各向同性勒纳尔-琼斯势能相互作用的准真实多原子各向异性分子取代球形粒子。特别是,最后一种策略有望用于探索分子结构与分子动力学行为之间的关系。最后,我们希望本综述中介绍的结果也能鼓励其他人探索 "各向异性 "如何影响与液态玻璃转变相关的其他方面,如异质性、玻璃转变温度、玻璃成型能力等。
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引用次数: 0
Anomalous thermodynamic cost of clock synchronization. 时钟同步的反常热力学成本。
Pub Date : 2024-06-28 DOI: 10.1088/1361-6633/ad5867
Cheng Yang, Jiteng Sheng, Haibin Wu

Clock synchronization is critically important in positioning, navigation and timing systems. While its performance has been intensively studied in a wide range of disciplines, much less is known for the fundamental thermodynamics of clock synchronization‒what limits the precision and how to optimize the energy cost for clock synchronization. Here, we report the first experimental investigation of two stochastic autonomous clocks synchronization, unveiling the thermodynamic relation between the entropy cost and clock synchronization in an open cavity optomechanical system. Two interacting clocks are synchronized spontaneously owing to the disparate decay rates of hybrid modes by engineering the controllable cavity-mediated dissipative coupling. The measured dependence of the degree of synchronization on the overall entropy cost exhibits an unexpected non-monotonic characteristic, while the relation between the degree of synchronization and the entropy cost for the synchronization is monotonically decreasing. The investigation of transient dynamics of clock synchronization exposes a trade-off between energy and time consumption. Our results demonstrate the possibility of clock synchronization in an effective linear system, reveal the fundamental relation between clock synchronization and thermodynamics, and have a great potential for precision measurements, distributed quantum networks, and biological science.

时钟同步在定位、导航和定时系统中至关重要。虽然各学科对时钟同步的性能进行了深入研究,但人们对时钟同步的基本热力学知之甚少--是什么限制了时钟同步的精度,以及如何优化时钟同步的能量成本。在这里,我们首次报告了两个随机自主时钟同步的实验研究,揭示了开腔光机械系统中熵成本与时钟同步之间的热力学关系。由于混合模式的衰减率不同,两个相互作用的时钟通过可控腔介导的耗散耦合自发同步。测得的同步程度对整体熵成本的依赖呈现出意想不到的非单调特性,而同步程度与同步熵成本之间的关系则是单调递减的。对时钟同步瞬态动态的研究揭示了能量和时间消耗之间的权衡。我们的研究结果证明了在有效线性系统中实现时钟同步的可能性,揭示了时钟同步与热力学之间的基本关系,在精密测量、分布式量子网络和生物科学领域具有巨大潜力。
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引用次数: 0
Corrigendum: The measurement of surface gravity (2013Rep. Prog. Phys.76 046101). 更正:地表重力测量(2013Rep.Prog.Phys.76 046101)。
Pub Date : 2024-06-24 DOI: 10.1088/1361-6633/ad573b
David Crossley, Jacques Hinderer, Umberto Riccardi
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引用次数: 0
A statistical primer on classical period-finding techniques in astronomy. 天文学经典周期搜索技术统计入门。
Pub Date : 2024-06-20 DOI: 10.1088/1361-6633/ad4586
Naomi Giertych, Ahmed Shaban, Pragya Haravu, Jonathan P Williams

The aim of our paper is to investigate the properties of the classical phase-dispersion minimization (PDM), analysis of variance (AOV), string-length (SL), and Lomb-Scargle (LS) power statistics from a statistician's perspective. We confirm that when the data are perturbations of a constant function, i.e. under the null hypothesis of no period in the data, a scaled version of the PDM statistic follows a beta distribution, the AOV statistic follows an F distribution, and the LS power follows a chi-squared distribution with two degrees of freedom. However, the SL statistic does not have a closed-form distribution. We further verify these theoretical distributions through simulations and demonstrate that the extreme values of these statistics (over a range of trial periods), often used for period estimation and determination of the false alarm probability (FAP), follow different distributions than those derived for a single period. We emphasize that multiple-testing considerations are needed to correctly derive FAP bounds. Though, in fact, multiple-testing controls are built into the FAP bound for these extreme-value statistics, e.g. the FAP bound derived specifically for the maximum LS power statistic over a range of trial periods. Additionally, we find that all of these methods are robust to heteroscedastic noise aimed to mimic the degradation or miscalibration of an instrument over time. Finally, we examine the ability of these statistics to detect a non-constant periodic function via simulating data that mimics a well-detached binary system, and we find that the AOV statistic has the most power to detect the correct period, which agrees with what has been observed in practice.

本文旨在从统计学家的角度研究经典的相位离散最小化(PDM)、方差分析(AOV)、弦长(SL)和伦布-斯卡格尔(LS)幂级数统计的特性。我们证实,当数据是恒定函数的扰动时,即在数据中无周期的零假设下,PDM 统计量的缩放版本遵循贝塔分布,AOV 统计量遵循 F 分布,LS 功率遵循具有两个自由度的秩方分布。然而,SL 统计量并没有封闭形式的分布。我们通过模拟进一步验证了这些理论分布,并证明了这些统计量的极值(在一系列试验周期内)(通常用于周期估计和确定误报概率 (FAP))所遵循的分布与单周期得出的分布不同。我们强调,要正确推导 FAP 边界,必须考虑多重测试。尽管事实上,多重测试控制已经内置于这些极值统计量的 FAP 边界中,例如,专门针对一系列试验期的最大 LS 功率统计量推导出的 FAP 边界。此外,我们还发现所有这些方法对旨在模拟仪器随时间退化或误判的异方差噪声都很稳健。最后,我们通过模拟数据来检验这些统计量检测非恒定周期函数的能力,我们发现 AOV 统计量检测到正确周期的能力最强,这与实际观察到的结果一致。
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引用次数: 0
Pioneering research has a new home in a trusted place. 开拓性研究在一个值得信赖的地方有了新的归宿。
Pub Date : 2024-06-20 DOI: 10.1088/1361-6633/ad543a
David Gevaux

After 90 years of publishing authoritative reviews, Reports on Progress in Physics is today publishing its first primary research papers. The beginning, we hope, of the journal's evolution into a showcase of the most impactful, ground-breaking and just fascinating physical-science research; a journal that builds trust through rigorous peer review and gives back to the communities we serve. Investing 100% of our funds back into science, we are committed to achieving all of this on a not-for-profit basis that puts science and scientists first.

在发表了90年的权威评论之后,《物理学进展报告》今天将发表它的第一篇主要研究论文。我们希望,这将是该杂志向最具影响力、最具突破性和最吸引人的物理科学研究展示的开始;这将是一份通过严格的同行评审建立信任并回馈我们所服务的社区的杂志。我们将 100% 的资金投入到科学领域,致力于在非盈利的基础上实现这一切,将科学和科学家放在首位。
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引用次数: 0
Divergence beneath the Brillouin sphere and the phenomenology of prediction error in spherical harmonic series approximations of the gravitational field. 布里渊球下的发散与引力场球面谐波数列近似的预测误差现象学。
Pub Date : 2024-06-20 DOI: 10.1088/1361-6633/ad44d5
M Bevis, C Ogle, O Costin, C Jekeli, R D Costin, J Guo, J Fowler, G V Dunne, C K Shum, K Snow

The Brillouin sphere is defined as the smallest sphere, centered at the origin of the geocentric coordinate system, that incorporates all the condensed matter composing the planet. The Brillouin sphere touches the Earth at a single point, and the radial line that begins at the origin and passes through that point is called the singular radial line. For about 60 years there has been a persistent anxiety about whether or not a spherical harmonic (SH) expansion of the external gravitational potential,V, will converge beneath the Brillouin sphere. Recently, it was proven that the probability of such convergence is zero. One of these proofs provided an asymptotic relation, called Costin's formula, for the upper bound,EN, on the absolute value of the prediction error,eN, of a SH series model,VN(θ,λ,r), truncated at some maximum degree,N=nmax. When the SH series is restricted to (or projected onto) a particular radial line, it reduces to a Taylor series (TS) in1/r. Costin's formula isEN≃BN-b(R/r)N, whereRis the radius of the Brillouin sphere. This formula depends on two positive parameters:b, which controls the decay of error amplitude as a function ofNwhenris fixed, and a scale factorB. We show here that Costin's formula derives from a similar asymptotic relation for the upper bound,Anon the absolute value of the TS coefficients,an, for the same radial line. This formula,An≃Kn-k, depends on degree,n, and two positive parameters,kandK, that are analogous tobandB. We use synthetic planets, for which we can compute the potential,V, and also the radial component of gravitational acceleration,gr=∂V/∂r, to hundreds of significant digits, to validate both of these asymptotic formulas. Let superscriptVrefer to asymptotic parameters associated with the coefficients and prediction errors for gravitational potential, and superscriptgto the coefficients and predictions errors associated withgr. For polyhedral planets of uniform density we show thatbV=kV=7/2andbg=kg=5/2almost everywhere. We show that the frequency of oscillation (around zero) of the TS coefficients and the series prediction errors, for a given radial line, is controlled by the geocentric angle,α, between that radial line and the singular radial line. We also derive useful identities connectingKV,BV,Kg, andBg. These identities are expressed in terms of quotients of the various scale factors. The only other quantities involved in these identities areαandR. The phenomenology of 'series divergence' and prediction error (whenr < R) can be described as a function of the truncation degree,N, or the depth,d, beneath the Brillouin sphere. For a fixedr⩽R, asNincreases from very low values, the upper error boundENshrinks until i

布里渊球被定义为以地心坐标系的原点为中心,包含组成地球的所有凝聚态物质的最小球体。布里渊球与地球只接触一点,从原点开始经过该点的径向线被称为奇异径向线。大约 60 年来,人们一直担心外部引力势 V 的球谐波(SH)扩展是否会在布里渊球下方汇聚。最近,有人证明了这种收敛的概率为零。其中一个证明提供了一个渐近关系,即科斯丁公式,用于计算在某个最大度(N=nmax)处截断的 SH 序列模型 VN(θ,λ,r)的预测误差 eN 的绝对值上限 EN。当 SH 级数被限制在(或投影到)一条特定的径向线上时,它就会简化为 1/r 内的泰勒级数 (TS)。科斯丁公式为 EN≃BN-b(R/r)N,其中 R 是布里渊球的半径。该公式取决于两个正参数:一个是 b,它控制着误差振幅随固定值 N 的衰减;另一个是比例因子 B。我们在此说明,科斯丁的计算公式来自于类似的渐近关系,即同一径向线的 TS 系数绝对值 an 的上限。这个公式An≃Kn-k取决于度数n和两个正参数k和K,这两个参数类似于B和B。我们使用合成行星来验证这两个渐近公式,我们可以计算出合成行星的势能 V 以及重力加速度的径向分量 gr=∂V/∂r ,精确到几百位有效数字。对于密度均匀的多面体行星,我们证明几乎在所有地方bV=kV=7/2和bg=kg=5/2。我们证明,对于给定的径向线,TS 系数和系列预测误差的振荡频率(在零附近)受该径向线和奇异径向线之间的地心角 α 控制。我们还推导出连接 KV、BV、Kg 和 Bg 的有用等式。这些等式用各种比例因子的商来表示。这些等式中涉及的其他量只有α和R。序列发散 "和预测误差(r R 时)的现象可以描述为截断度 N 或布里渊球下深度 d 的函数。对于固定的 r⩽R,当 Nin 从很低的值开始增加时,误差上限值 EN 会缩小,直到 N 达到某个特定值或最佳值 Nopt 时,误差上限值 EN 达到最小(最佳)值。当 N>Nopt 时,预测误差会随着 N 的不断增大而增大。最终,当 N ≫Nopt 时,预测误差会随着 N 的增加呈指数增长。如果我们固定 N 的值,并允许 R/r 变化,那么我们会发现布里渊球下自由空间中的预测误差会随着布里渊球下深度 d 的增加而呈指数增长。由于 bg=bV-1 无处不在,因此发散驱动的预测误差对gr 的增强速度比对 V 的增强速度更快,两者都取决于 N 和 dd。如果我们固定 Nandd,并关注预测误差的 "横向 "变化,我们就会发现,当我们接近高振幅地形时,发散和预测误差趋于增加(B 也是如此)。
{"title":"Divergence beneath the Brillouin sphere and the phenomenology of prediction error in spherical harmonic series approximations of the gravitational field.","authors":"M Bevis, C Ogle, O Costin, C Jekeli, R D Costin, J Guo, J Fowler, G V Dunne, C K Shum, K Snow","doi":"10.1088/1361-6633/ad44d5","DOIUrl":"10.1088/1361-6633/ad44d5","url":null,"abstract":"<p><p>The Brillouin sphere is defined as the smallest sphere, centered at the origin of the geocentric coordinate system, that incorporates all the condensed matter composing the planet. The Brillouin sphere touches the Earth at a single point, and the radial line that begins at the origin and passes through that point is called the singular radial line. For about 60 years there has been a persistent anxiety about whether or not a spherical harmonic (SH) expansion of the external gravitational potential,<i>V</i>, will converge beneath the Brillouin sphere. Recently, it was proven that the probability of such convergence is zero. One of these proofs provided an asymptotic relation, called Costin's formula, for the upper bound,<i>E<sub>N</sub></i>, on the absolute value of the prediction error,<i>e<sub>N</sub></i>, of a SH series model,VN(θ,λ,r), truncated at some maximum degree,N=nmax. When the SH series is restricted to (or projected onto) a particular radial line, it reduces to a Taylor series (TS) in1/r. Costin's formula isEN≃BN-b(R/r)N, where<i>R</i>is the radius of the Brillouin sphere. This formula depends on two positive parameters:<i>b</i>, which controls the decay of error amplitude as a function of<i>N</i>when<i>r</i>is fixed, and a scale factor<i>B</i>. We show here that Costin's formula derives from a similar asymptotic relation for the upper bound,<i>A<sub>n</sub></i>on the absolute value of the TS coefficients,<i>a<sub>n</sub></i>, for the same radial line. This formula,An≃Kn-k, depends on degree,<i>n</i>, and two positive parameters,<i>k</i>and<i>K</i>, that are analogous to<i>b</i>and<i>B</i>. We use synthetic planets, for which we can compute the potential,<i>V</i>, and also the radial component of gravitational acceleration,gr=∂V/∂r, to hundreds of significant digits, to validate both of these asymptotic formulas. Let superscript<i>V</i>refer to asymptotic parameters associated with the coefficients and prediction errors for gravitational potential, and superscript<i>g</i>to the coefficients and predictions errors associated with<i>g<sub>r</sub></i>. For polyhedral planets of uniform density we show thatbV=kV=7/2andbg=kg=5/2almost everywhere. We show that the frequency of oscillation (around zero) of the TS coefficients and the series prediction errors, for a given radial line, is controlled by the geocentric angle,<i>α</i>, between that radial line and the singular radial line. We also derive useful identities connectingKV,BV,Kg, and<i>B<sup>g</sup></i>. These identities are expressed in terms of quotients of the various scale factors. The only other quantities involved in these identities are<i>α</i>and<i>R</i>. The phenomenology of 'series divergence' and prediction error (when<i>r</i> < <i>R</i>) can be described as a function of the truncation degree,<i>N</i>, or the depth,<i>d</i>, beneath the Brillouin sphere. For a fixedr⩽R, as<i>N</i>increases from very low values, the upper error bound<i>E<sub>N</sub></i>shrinks until i","PeriodicalId":74666,"journal":{"name":"Reports on progress in physics. Physical Society (Great Britain)","volume":"87 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141428422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Extracting the speed of sound in quark-gluon plasma with ultrarelativistic lead-lead collisions at the LHC. 在大型强子对撞机上利用超相对论铅铅对撞提取夸克-胶子等离子体中的声速。
Pub Date : 2024-06-20 DOI: 10.1088/1361-6633/ad4b9b

Ultrarelativistic nuclear collisions create a strongly interacting state of hot and dense quark-gluon matter that exhibits a remarkable collective flow behavior with minimal viscous dissipation. To gain deeper insights into its intrinsic nature and fundamental degrees of freedom, we determine the speed of sound in an extended volume of quark-gluon plasma using lead-lead (PbPb) collisions at a center-of-mass energy per nucleon pair of 5.02 TeV. The data were recorded by the CMS experiment at the CERN LHC and correspond to an integrated luminosity of 0.607 nb-1. The measurement is performed by studying the multiplicity dependence of the average transverse momentum of charged particles emitted in head-on PbPb collisions. Our findings reveal that the speed of sound in this matter is nearly half the speed of light, with a squared value of0.241±0.002(stat)±0.016(syst)in natural units. The effective medium temperature, estimated using the mean transverse momentum, is219±8(syst)MeV. The measured squared speed of sound at this temperature aligns precisely with predictions from lattice quantum chromodynamic (QCD) calculations. This result provides a stringent constraint on the equation of state of the created medium and direct evidence for a deconfined QCD phase being attained in relativistic nuclear collisions.

超相对论核碰撞产生了一种强相互作用的热致密夸克-胶子物质状态,这种物质表现出显著的集体流动行为,粘性耗散极小。为了更深入地了解其内在性质和基本自由度,我们利用每核子对质量中心能量为 5.02 TeV 的铅铅 (PbPb) 对撞,测定了夸克-胶子等离子体扩展体积中的声速。这些数据由欧洲核子研究中心大型强子对撞机上的 CMS 实验记录,对应于 0.607 nb-1 的综合光度。测量是通过研究正面 PbPb 对撞中发射的带电粒子平均横动量的倍率依赖性进行的。我们的研究结果表明,这种物质的声速几乎是光速的一半,其平方值为自然单位 0.241±0.002(stat)±0.016(syst)。利用平均横动量估算的有效介质温度为 219±8(syst)MeV 。在这一温度下测得的声速平方与晶格量子色动力学(QCD)计算的预测值精确吻合。这一结果为被造介质的状态方程提供了严格的约束,也为相对论核碰撞中达到去约束 QCD 阶段提供了直接证据。
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引用次数: 0
Symmetry-preserving quadratic Lindbladian and dissipation driven topological transitions in Gaussian states. 高斯态中的对称保全二次林德布拉甸和耗散驱动拓扑转变。
Pub Date : 2024-06-20 DOI: 10.1088/1361-6633/ad44d4
Liang Mao, Fan Yang, Hui Zhai

The dynamical evolution of an open quantum system can be governed by the Lindblad equation of the density matrix. In this paper, we propose to characterize the density matrix topology by the topological invariant of its modular Hamiltonian. Since the topological classification of such Hamiltonians depends on their symmetry classes, a primary issue we address is determining the requirement for the Lindbladian operators, under which the modular Hamiltonian can preserve its symmetry class during the dynamical evolution. We solve this problem for the fermionic Gaussian state and for the modular Hamiltonian being a quadratic operator of a set of fermionic operators. When these conditions are satisfied, along with a nontrivial topological classification of the symmetry class of the modular Hamiltonian, a topological transition can occur as time evolves. We present two examples of dissipation-driven topological transitions where the modular Hamiltonian lies in the AIII class withU(1) symmetry and the DIII class withoutU(1) symmetry. By a finite size scaling, we show that this density matrix topology transition occurs at a finite time. We also present the physical signature of this transition.

开放量子系统的动态演化可由密度矩阵的林德布拉德方程控制。在本文中,我们建议通过其模块化哈密顿的拓扑不变量来描述密度矩阵的拓扑特征。由于这种哈密顿的拓扑分类取决于其对称性类别,我们要解决的一个主要问题是确定林德布拉德算子的要求,在此要求下,模块哈密顿在动力学演化过程中可以保持其对称性类别。我们解决了费米高斯态和模块哈密顿是一组费米算子的二次算子的问题。当这些条件得到满足时,再加上模态哈密顿对称类的非难拓扑分类,拓扑转变就会随着时间的演化而发生。我们给出了两个耗散驱动拓扑转变的例子,其中模块哈密顿分别位于具有 U(1) 对称性的 AIII 类和不具有 U(1) 对称性的 DIII 类。通过有限尺寸缩放,我们证明了这种密度矩阵拓扑转变发生在有限时间内。我们还提出了这一转变的物理特征。
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引用次数: 0
Active many-particle systems and the emergent behavior of dense ant collectives. 活跃的多粒子系统和密集蚂蚁集体的突发行为。
Pub Date : 2024-05-28 DOI: 10.1088/1361-6633/ad49b4
C Anderson, A Fernandez-Nieves

This article discusses recent work with fire ants,Solenopisis invicta, to illustrate the use of the framework of active matter as a base to rationalize their complex collective behavior. We review much of the work that physicists have done on the group dynamics of these ants, and compare their behavior to two minimal models of active matter, and to the behavior of the synthetic systems that have served to test and drive these models.

本文讨论了最近有关火蚁(Solenopisis invicta)的研究,以说明如何利用活动物质框架作为基础来合理解释火蚁复杂的集体行为。我们回顾了物理学家在这些蚂蚁的群体动力学方面所做的大量工作,并将它们的行为与活性物质的两个最小模型以及用于测试和推动这些模型的合成系统的行为进行了比较。
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引用次数: 0
Nucleic acid liquids. 核酸液体
Pub Date : 2024-05-20 DOI: 10.1088/1361-6633/ad4662
Gabrielle R Abraham, Aria S Chaderjian, Anna B N Nguyen, Sam Wilken, Omar A Saleh

The confluence of recent discoveries of the roles of biomolecular liquids in living systems and modern abilities to precisely synthesize and modify nucleic acids (NAs) has led to a surge of interest in liquid phases of NAs. These phases can be formed primarily from NAs, as driven by base-pairing interactions, or from the electrostatic combination (coacervation) of negatively charged NAs and positively charged molecules. Generally, the use of sequence-engineered NAs provides the means to tune microsopic particle properties, and thus imbue specific, customizable behaviors into the resulting liquids. In this way, researchers have used NA liquids to tackle fundamental problems in the physics of finite valence soft materials, and to create liquids with novel structured and/or multi-functional properties. Here, we review this growing field, discussing the theoretical background of NA liquid phase separation, quantitative understanding of liquid material properties, and the broad and growing array of functional demonstrations in these materials. We close with a few comments discussing remaining open questions and challenges in the field.

近年来,人们发现了生物分子液体在生命系统中的作用,同时也发现了精确合成和修饰核酸(NAs)的现代能力,这一切促使人们对核酸液相产生了浓厚的兴趣。这些液相主要由核酸在碱基配对相互作用的驱动下形成,或由带负电荷的核酸和带正电荷的分子的静电结合(共轭)形成。一般来说,使用序列工程化的 NA 可以调整微观粒子的特性,从而在生成的液体中注入特定的、可定制的行为。通过这种方式,研究人员利用 NA 液体解决了有限价软材料物理学中的基本问题,并创造出具有新结构和/或多功能特性的液体。在此,我们将对这一不断发展的领域进行回顾,讨论 NA 液体相分离的理论背景、对液体材料特性的定量理解,以及这些材料中广泛且不断增长的功能展示。最后,我们还将讨论该领域尚待解决的问题和面临的挑战。
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引用次数: 0
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Reports on progress in physics. Physical Society (Great Britain)
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