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Citric Acid Production: Raw Material, Microbial Production, Fermentation Strategy and Global Market: Critical Review 柠檬酸生产:原料,微生物生产,发酵策略和全球市场:评论
Pub Date : 2023-06-05 DOI: 10.22153/kej.2023.12.002
Ramzi A. Abd Alsaheb, Malik Mustafa Mohammed, Jaafar Kamil Abdullah, Azza Hashim Abbas
Citric acid is an essential ingredient for the manufacture of (12) key industrial chemicals. Citric acid use is increasing steadily with a high annual growth rate as a result of the development of ever more sophisticated applications. Citric acid is widely utilized in the food and pharmaceutical industries due to its low toxicity when compared to other acidulous. Other uses for citric acid can be found in cleaning supplies and detergents. Based on information from a review of the literature, Citric acid production substrates and methods for surface fermentation, submerged fermentation, solid-state fermentation, and international market expansion are all covered in the current review study. Finally, there is still much to learn about the circumstances of the production of citric acid from raw materials, microorganisms, and fermentation techniques to achieve the best production in terms of cost and quality.
柠檬酸是制造关键工业化学品的必要成分。由于越来越复杂的应用的发展,柠檬酸的使用正以高的年增长率稳步增长。柠檬酸因其毒性较低而被广泛应用于食品和制药工业。柠檬酸的其他用途可以在清洁用品和洗涤剂中找到。根据文献综述的信息,本综述研究涵盖了柠檬酸生产的底物和方法,包括表面发酵、深层发酵、固态发酵和国际市场拓展。最后,关于从原料、微生物和发酵技术生产柠檬酸的情况,要在成本和质量方面实现最佳生产,还有很多需要了解的地方。
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引用次数: 0
A Review of the Stereo lithography 3D Printing Process and the Effect of Parameters on Quality 立体光刻3D打印工艺及参数对打印质量的影响
Pub Date : 2023-06-05 DOI: 10.22153/kej.2023.04.003
Tiba Raed Mhmood, Nazar Kais AL-Karkhi
Stereo lithography (SLA) three-dimensional (3D) printing process is a type of additive manufacturing techniques that uses digital models from computer-aided design to automatically produce customized 3D objects. Around 30 years, it has been widely utilized in the manufacturing, design, engineering, industrial sectors and its applications in dentistry for manufacturing prosthodontics are very important. The stereo lithography technology is highly regarded because it can produce items with excellent precision especially when selecting the best process parameters. This review article offers a useful and scientific summary of SLA three-dimensional printing technology and its brief history. The specific type of 3D printers which is SLA type based on light curing resin and material overview is also presented. Moreover, the survey was conducted to gain substantial knowledge of the various advantages and disadvantages of SLA 3D printing. According to this study, a summary has been specified on the accuracy of SLA 3D printers and various factors that affected its accuracy and dimension measurement namely layer thickness, normal exposure time, bottom or top exposure time, post processing and room temperature. The majority of works in the literatures conducted till date are on improving the physical part attributes like dimensional accuracy and surface roughness but the improving of the mechanical properties have received less attention and need more focusing in the future works.
立体光刻(SLA)三维(3D)打印工艺是一种使用计算机辅助设计的数字模型自动生成定制3D对象的增材制造技术。近30年来,它已广泛应用于制造、设计、工程、工业等部门,其在牙科领域的应用对于制造口腔修复学具有十分重要的意义。立体光刻技术因其加工精度高而受到高度重视,特别是在选择最佳工艺参数时。本文对SLA三维打印技术及其发展简史进行了有益而科学的综述。介绍了基于光固化树脂和材料的SLA型3D打印机的具体类型。此外,调查的进行是为了获得大量的知识,各种优势和劣势的SLA 3D打印。根据本研究,总结了SLA 3D打印机的精度,以及影响其精度和尺寸测量的各种因素,即层厚、正常曝光时间、底部或顶部曝光时间、后期处理和室温。到目前为止,文献中的大部分工作都是在提高零件的尺寸精度和表面粗糙度等物理属性上,而对力学性能的提高关注较少,今后的工作需要更多的关注。
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引用次数: 1
Treatment of Petroleum Refinery Wastewater by Sono Fenton Process Utilizing the in-Situ Generated Hydrogen Peroxide 利用原位生成过氧化氢处理炼油废水的索诺Fenton法研究
Pub Date : 2023-06-05 DOI: 10.22153/kej.2023.04.002
Marwa M. Jiad, A. Abbar
Combining ultrasonic irradiation and the Fenton process as a sono-Fenton process, the chemical oxygen demand (COD) in refinery wastewater was successfully eliminated using response surface methodology (RSM) with central composite design (CCD). The impact of two main influential operational parameters (iron dosage and reaction time) on the COD removal from wastewater generated by an Iraqi petroleum refinery facility was explored. Removal of 85.81% was attained under the optimal conditions of 21 minutes and 0.289 mM of  concentration. Additionally, the results revealed that the concentration of has the highest effect on the COD elimination, followed by reaction time. The high R2 value (96.40%) validated the strong fit of the model equation and the successful adopting RSM in the treatment of wastewaters from petroleum refineries. Furthermore, a comparison among sono-Fenton, sono-Fenton with addition of  externally, classical Fenton and sonolysis processes showed that the combined process of sono-Fenton is better than individual processes and the external addition of  .
采用响应面法(RSM)结合中心复合设计(CCD),将超声辐照与Fenton工艺结合为sono-Fenton工艺,成功地去除了炼油废水中的化学需氧量(COD)。探讨了两个主要影响操作参数(铁投加量和反应时间)对伊拉克某炼油厂废水COD去除率的影响。在浓度0.289 mM、时间21 min的条件下,去除率为85.81%。此外,结果表明,浓度对COD去除的影响最大,其次是反应时间。较高的R2值(96.40%)验证了模型方程的强拟合性和采用RSM处理炼油厂废水的成功。此外,通过对sono-Fenton、外部添加的sono-Fenton、经典Fenton和声溶工艺的比较,表明sono-Fenton组合工艺优于单个工艺和外部添加的sono-Fenton。
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引用次数: 3
Extraction of Bovine Serum Albumin by Aqueous Two-Phase System Using PEG4000/Sodium Citrate and PEG8000/Sodium Phosphate PEG4000/柠檬酸钠和PEG8000/磷酸钠双水相萃取牛血清白蛋白
Pub Date : 2023-06-05 DOI: 10.22153/kej.2023.04.001
Hawraa A. Mahdi, K. Hameed, Abdul-Jabbar A. Ali
Aqueous Two Phase System (ATPS) or liquid-liquid extraction is used in biotechnology to recover valuable compounds from raw sources. In Aqueous Two-Phase Systems, many factors influence the Partition coefficient, K, (which is the ratio of protein concentration in the top phase to that in the bottom phase) and the Recovery percentage (Rec%). In this research, two systems of ATPS were used: first, polyethylene glycol (PEG) 4000/Sodium citrate (SC), and the second, PEG8000/ Sodium phosphate (SPH), for the extraction of Bovine Serum Albumin (BSA). The behavior of Rec% and K of pure (BSA) in ATPS has been investigated throughout the study by the effects of five parameters: temperature, concentration of polyethylene glycol (PEG4000 and PEG8000), the concentration of Sodium citrate or Sodium phosphate, pH, and the addition of sodium chloride as a supporting agent. The recovery percentage of BSA and its partition coefficient are significantly influenced by these factors to various degrees. The most influential variable in this study is PEG concentration for both systems. In addition to the PEG concentration, the stabilizing impact of NaCl is a crucial factor. The interaction between biomolecules and PEG gets more hydrophobic as the PEG concentration is raised. In the first system (PEG4000/SC), the maximum recovery percentage and partition coefficient were 98.99% and 97.69, respectively, at 31°C, PEG4000 concentration 1.5g/10 ml, Sodium citrate concentration 2.7 g/10 ml, pH 10, and 0.5 M NaCl concentration. While in the second system (PEG8000/SPH), the maximum recovery percentage and partition coefficient was 98.93% and 92.12, respectively, at 31oC, PEG8000 concentration 1.5 g/10 ml, Sodium phosphate concentration 2.4 g/10 ml, pH 10, and concentration of NaCl 0.5 M.
水两相系统(ATPS)或液-液萃取在生物技术中用于从原料中回收有价值的化合物。在双水相体系中,许多因素影响分配系数K(即上相与下相的蛋白质浓度之比)和回收率(Rec%)。本研究采用聚乙二醇4000/柠檬酸钠(SC)和聚乙二醇8000/磷酸钠(SPH)两种ATPS体系提取牛血清白蛋白(BSA)。在整个研究过程中,通过温度、聚乙二醇(PEG4000和PEG8000)浓度、柠檬酸钠或磷酸钠浓度、pH和氯化钠作为支撑剂的加入等五个参数的影响,研究了纯(BSA)在atp中的Rec%和K的行为。这些因素对牛血清白蛋白的回收率及其分配系数均有不同程度的显著影响。本研究中影响最大的变量是两种体系的PEG浓度。除PEG浓度外,NaCl的稳定作用也是关键因素。随着聚乙二醇浓度的提高,生物分子与聚乙二醇的相互作用变得更加疏水。在31℃、PEG4000浓度为1.5g/10 ml、柠檬酸钠浓度为2.7 g/10 ml、pH为10、NaCl浓度为0.5 M的条件下,PEG4000/SC体系的回收率为98.99%,分配系数为97.69。在31℃、PEG8000浓度1.5 g/10 ml、磷酸钠浓度2.4 g/10 ml、pH 10、NaCl浓度0.5 M条件下,PEG8000/SPH体系的回收率和分配系数分别为98.93%和92.12。
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引用次数: 0
Fabrication and Analysis of Denture Plate Using Single Point Incremental Sheet Forming 单点增量板成形义齿钢板的制作与分析
Pub Date : 2023-06-05 DOI: 10.22153/kej.2023.02.001
H. Saad, Ahmed Z. M. Shammari, S. S. A. AlKareem
Incremental sheet forming (ISF) is a metal forming technology in which small incremental deformations determine the final shape. The sheet is deformed by a hemispherical tool that follows the required shape contour to deform the sheet into the desired geometry. In this study, single point incremental sheet forming (SPIF) has been implemented in dentistry to manufacture a denture plate using two types of stainless steel, 304 and 316L, with an initial thickness of 0.5mm and 0.8mm, respectively. Stainless steel was selected due to its biocompatibility and reasonable cost. A three-dimensional (3D) analysis procedure was conducted to evaluate the manufactured part's geometrical accuracy and thickness distribution. The obtained results confirm the capability of SPIF to produce thin-walled biomedical components with satisfactory dimensional accuracy, as geometrical deviations between the developed and the actual models are predominantly in the range of ±0.25mm.
渐进式板料成形(ISF)是一种微小的渐进式变形决定最终形状的金属成形技术。用半球形工具按照所需的形状轮廓将板材变形成所需的几何形状。本研究采用单点增量板成形(SPIF)技术在牙科中制造义齿板,采用304和316L两种不锈钢,初始厚度分别为0.5mm和0.8mm。选用了生物相容性好、成本合理的不锈钢材料。采用三维分析方法对零件的几何精度和厚度分布进行了评价。得到的结果证实了SPIF能够以令人满意的尺寸精度生产薄壁生物医学部件,因为开发的模型与实际模型之间的几何偏差主要在±0.25mm范围内。
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引用次数: 0
Determination of the Optimum Conditions for Removal of Congo Red Dye by Peroxidase Enzyme Plant 过氧化物酶植物脱除刚果红染料最佳工艺条件的确定
Pub Date : 2023-06-05 DOI: 10.22153/kej.2023.03.001
Aula. I. Ridha, Mohanad J. M-Ridha
The pollution producing from textile industries effluents is growing since the years, due to at discharged lots of it in water without treatment. The resulting effluent is colourful, highly toxic, and poses a significant environmental hazard. This problem can be solved by using enzymic biological treatment, where the Congo red dye was used with concentrations (100,200,300,500) mg /L, pH values (3,4,5,6,7,8), and variable temperatures (25,35,45)°C, the best removal of Congo red (CR) dye  under optimum conditions for degradation was at  concentration of 100 mg/L, at (pH 6, 25 °C) with efficiency of 99.85 % using the peroxidase enzyme extracted from red radish plant, while the removal percentage decreased when increase dye concentration .
近年来,由于大量纺织工业废水未经处理直接排入水体,造成的污染日益严重。由此产生的废水是彩色的,剧毒的,并对环境造成重大危害。该问题可以通过酶生物处理来解决,其中刚果红染料的浓度为(100,200,300,500)mg/L, pH值为(3,4,5,6,7,8),温度为(25,35,45)°C,在最佳降解条件下,使用红萝卜植物中提取的过氧化物酶去除刚果红(CR)染料的最佳浓度为100 mg/L, pH值为6,25°C,效率为99.85%。随着染料浓度的增加,去除率降低。
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引用次数: 0
Expired Colxacillin, Amoxicillin, and Ceflaxin Drugs as Inhibitors for Low Carbon Steel Corrosion in Sodium Chloride 过期的柯西林、阿莫西林和头孢拉西林药物在氯化钠中作为低碳钢腐蚀抑制剂
Pub Date : 2023-03-01 DOI: 10.22153/kej.2023.11.003
A. Jawad, Shatha K. Muallah, K. Hammud
The ability to inhibit corrosion of low carbon steel in a salt solution (3.5%NaCl) has been checked with three real expired drugs (Cloxacillin, Amoxicillin, Ceflaxin) with variable concentrations (0, 250, 500, 750) mg/L were examined in the weight loss. The inhibition efficiency of the Cloxacillin 750 mg/L showed the highest value (82.8125 %) and the best inhibitor of the rest of the antibiotics. The different concentrations of Cloxacillin drug (0, 250, 500, 750) mg/L and temperature (25, 35, 45, 55) oC were studied as variables with potentiodynamic polarization, Scanning Electron Microscopy (SEM) for surface morphology and electrochemical impedance spectroscopy (EIS) depending on current values and the resistance of charge to calculate the inhibition efficiency. The main observations of these tests were that polarization curves showed a mixed-type inhibition of expired Cloxacillin. The inhibition efficiency increased with increasing Cloxacillin concentration but not with increasing temperature.
用三种不同浓度(0、250、500、750)mg/L的实际过期药物(氯西林、阿莫西林、头孢拉西林)测定了低碳钢在盐溶液(3.5%NaCl)中的抗腐蚀能力。氯氯西林750 mg/L的抑菌率最高(82.8125%),是其余抗生素的最佳抑制剂。以氯西林药物浓度(0、250、500、750)mg/L和温度(25、35、45、55)oC为变量,通过动电位极化、扫描电镜(SEM)表面形貌和电化学阻抗谱(EIS)根据电流值和电荷电阻计算抑菌效率。这些试验的主要观察结果是极化曲线显示出对过期氯西林的混合型抑制。抑菌率随氯西林浓度的增加而增加,但不随温度的升高而增加。
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引用次数: 0
A Methodology for Evaluating and Scheduling Preventive Maintenance for a Thermo-Electric Unit Using Artificial Intelligence 基于人工智能的热电机组预防性维护评估与调度方法
Pub Date : 2023-03-01 DOI: 10.22153/kej.2023.10.001
Wasan Mahmood Ahmed, A. Ahmed, Osamah Abdulateef
Flow-production systems whose pieces are connected in a row may not have maintenance scheduling procedures fixed because problems occur at different times (electricity plants, cement plants, water desalination plants). Contemporary software and artificial intelligence (AI) technologies are used to fulfill the research objectives by developing a predictive maintenance program. The data of the fifth thermal unit of the power station for the electricity of Al Dora/Baghdad are used in this study. Three stages of research were conducted. First, missing data without temporal sequences were processed. The data were filled using time series hour after hour and the times were filled as system working hours, making the volume of the data relatively high for 2015-2016-2017. 2018 was utilized as a test year to assess the modeling work and validate the experimental results. In the second step, the artificial neural networks approach employs the python program as an AI, and the affinity ratio of real data using the performance measurement of the mean absolute error (MAE) was 0.005. To improve and reduce the value of absolute error, the genetic algorithm uses the python program and the convergence ratio became 0.001. It inferred that the algorithm is efficient in improving results. Thus, the genetic algorithm provided better results with fewer errors than the neural network alone. This concludes that the shown network has superior performance over others and the possibility of its long-term predictions for 2030. A Sing time series helped detect future cases by reading and inferring system data. The development of appropriate work plans will lower internal and external expenses of the systems and help integrate other capabilities by giving correct data sources of raw materials, costs, etc. To facilitate prediction for maintenance workers, an interface has been created that facilitates users to apply them using the python program represented by entering the times, an hour, a day, a month, a year, to predict the type and place of failure.
由于问题发生在不同的时间(发电厂、水泥厂、海水淡化厂),部件连成一排的流动生产系统可能没有固定的维护调度程序。现代软件和人工智能(AI)技术通过开发预测性维护程序来实现研究目标。本研究使用Al Dora/Baghdad电站第五热电机组的数据。研究进行了三个阶段。首先,对无时间序列的缺失数据进行处理。数据采用逐小时时间序列填充,时间以系统工作时间填充,因此2015-2016-2017年数据量较大。2018年作为测试年,评估模型工作并验证实验结果。第二步,人工神经网络方法采用python程序作为AI,使用平均绝对误差(MAE)的性能度量得到真实数据的亲和比为0.005。为了提高和降低绝对误差的值,遗传算法使用python程序,收敛比变为0.001。结果表明,该算法在改进结果方面是有效的。因此,遗传算法比单独的神经网络提供了更好的结果和更少的误差。结论是,所展示的网络具有优于其他网络的性能,并且有可能对2030年进行长期预测。Sing时间序列通过读取和推断系统数据来帮助检测未来的病例。制定适当的工作计划将降低系统的内部和外部费用,并通过提供原材料、成本等的正确数据来源,帮助整合其他能力。为了便于对维护人员进行预测,已经创建了一个界面,方便用户使用python程序来应用它们,通过输入时间(一小时、一天、一个月、一年)来预测故障的类型和位置。
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引用次数: 1
Mechanical PropertiesInvestigation of Unidirectional Woven Carbon Fiber Reinforced Epoxy Matrix Composite 单向编织碳纤维增强环氧基复合材料的力学性能研究
Pub Date : 2023-03-01 DOI: 10.22153/kej.2023.12.001
Naznaz Jalal Awla, Younis K. Khdir
In this study, the mechanical properties of an epoxy and unidirectional woven carbon with fiberglass composite were experimentally investigated. When preparing the composite samples, American Society for Testing and Materials (ASTM)standard was used. Tensile, impact and flexural test were conducted to investigate the mechanical properties of the new produced epoxy Unidirectional Woven Carbon and Epoxy Fiberglass composites. The outcome showed that the strength of the produced samples increased with the increase in the number of unidirectional woven carbon layers added. Two methods were utilized: (1) woven carbon composite with glass fiber (2) woven carbon composite). The two methods of composite were compared with each other.  The results explained that woven carbon composite had  higher mechanical resistance. While  in impact test the toughness of the sample  increased with adding layers of mixture of Fiber glass with unidirectional woven carbon and epoxy.
实验研究了环氧树脂与单向编织碳纤维复合材料的力学性能。制备复合材料样品时,采用美国材料试验协会(ASTM)标准。通过拉伸、冲击和弯曲试验,研究了新制备的环氧单向编织碳纤维和环氧玻璃纤维复合材料的力学性能。结果表明,随着单向编织碳层添加量的增加,所得样品的强度有所提高。采用两种方法:(1)玻璃纤维编织碳复合材料(2)编织碳复合材料)。并对两种复合方法进行了比较。结果表明,机织碳复合材料具有较高的机械阻力。在冲击试验中,玻璃纤维与单向编织碳和环氧树脂混合层的加入使试样的韧性有所提高。
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引用次数: 0
Design a radio receiver for solar activity observation in VLF band 设计了一种用于VLF波段太阳活动观测的无线电接收机
Pub Date : 2023-03-01 DOI: 10.22153/kej.2023.11.002
A. A. Al- Banna
Solar activity monitoring is important in our life because of its direct or indirect influence on our life, not only on ionospheric communications. To study solar activity, researchers need measuring and monitoring instruments, these instruments are mostly expensive and are not available in all universities. In this paper, a very low frequency radio receiver had been designed and implemented with components available in most markets to support the researchers, college students, and radio astronomy amateurs with a minimum input voltage less than 100µV, an output voltage less than 135 m V with no distortion and an overall gain of 34dB. A comparison had been done between two circuit structures using a workbench software program and experimentally done in the lab. Two antennas were experimentally tested and a loop antenna was chosen. The whole system was connected and tested to receive signals in the Lab and monitored on computer using HDSDR software program. Another experiment done outside the lab (at home), and the result was not good because of many high level interference noises. 
太阳活动监测不仅对电离层通信有直接或间接的影响,而且对我们的生活也有重要意义。为了研究太阳活动,研究人员需要测量和监测仪器,这些仪器大多是昂贵的,并不是所有的大学都有。本文设计并实现了一种极低频无线电接收机,使用大多数市场上可用的组件,以支持研究人员,大学生和射电天文学业余爱好者,最小输入电压小于100 μ V,输出电压小于135 m V,无失真,总增益为34dB。利用工作台软件程序和实验室实验对两种电路结构进行了比较。对两种天线进行了实验测试,选择了一种环形天线。整个系统在实验室进行了连接和测试,并在计算机上使用HDSDR软件程序进行了监控。在实验室外(家里)做了另一个实验,由于有很多高水平的干扰噪声,结果并不好。
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引用次数: 0
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Al-Khwarizmi Engineering Journal
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