Pub Date : 2023-12-01DOI: 10.22153/kej.2023.09.002
N. Al-Qazzaz, Sawal Hamid Bin Mohd Ali, Siti Anom Ahmad
The purpose of the current investigation is to distinguish between working memory ( ) in five patients with vascular dementia ( ), fifteen post-stroke patients with mild cognitive impairment ( ), and fifteen healthy control individuals ( ) based on background electroencephalography (EEG) activity. The elimination of EEG artifacts using wavelet (WT) pre-processing denoising is demonstrated in this study. In the current study, spectral entropy ( ), permutation entropy ( ), and approximation entropy ( ) were all explored. To improve the classification using the k-nearest neighbors ( NN) classifier scheme, a comparative study of using fuzzy neighbourhood preserving analysis with -decomposition ( ) as a dimensionality reduction technique and the improved binary gravitation search ( ) optimization algorithm as a channel selection method has been conducted. The NN classification accuracy was increased from 86.67% to 88.09% and 90.52% using the dimensionality reduction technique and the channel selection algorithm, respectively. According to the findings, reliably enhances discrimination of , , and participants. Therefore, WT, entropy features, IBGSA and NN classifiers provide a valid dementia index for looking at EEG background activity in patients with and .
{"title":"Working Memory Classification Enhancement of EEG Activity in Dementia: A Comparative Study","authors":"N. Al-Qazzaz, Sawal Hamid Bin Mohd Ali, Siti Anom Ahmad","doi":"10.22153/kej.2023.09.002","DOIUrl":"https://doi.org/10.22153/kej.2023.09.002","url":null,"abstract":"The purpose of the current investigation is to distinguish between working memory ( ) in five patients with vascular dementia ( ), fifteen post-stroke patients with mild cognitive impairment ( ), and fifteen healthy control individuals ( ) based on background electroencephalography (EEG) activity. The elimination of EEG artifacts using wavelet (WT) pre-processing denoising is demonstrated in this study. In the current study, spectral entropy ( ), permutation entropy ( ), and approximation entropy ( ) were all explored. To improve the classification using the k-nearest neighbors ( NN) classifier scheme, a comparative study of using fuzzy neighbourhood preserving analysis with -decomposition ( ) as a dimensionality reduction technique and the improved binary gravitation search ( ) optimization algorithm as a channel selection method has been conducted. The NN classification accuracy was increased from 86.67% to 88.09% and 90.52% using the dimensionality reduction technique and the channel selection algorithm, respectively. According to the findings, reliably enhances discrimination of , , and participants. Therefore, WT, entropy features, IBGSA and NN classifiers provide a valid dementia index for looking at EEG background activity in patients with and .\u0000 ","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"120 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138609467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-01DOI: 10.22153/kej.2023.09.004
Mahdi A. Atiyah, L. F. Abdulameer, Gaurav Narkhedel
Recently, wireless communication environments with high speeds and low complexity have become increasingly essential. Free-space optics (FSO) has emerged as a promising solution for providing direct connections between devices in such high-spectrum wireless setups. However, FSO communications are susceptible to weather-induced signal fluctuations, leading to fading and signal weakness at the receiver. To mitigate the effects of these challenges, several mathematical models have been proposed to describe the transition from weak to strong atmospheric turbulence, including Rayleigh, lognormal, Málaga, Nakagami-m, K-distribution, Weibull, Negative-Exponential, Inverse-Gaussian, G-G, and Fisher-Snedecor F distributions. This paper extensively studies and analyses different probability density functions (PDFs) that govern the FSO channel, considering various channel models. This paper aims to comprehensively understand how FSO channels can be effectively modeled using different PDFs. Accurate modeling is crucial for designing FSO systems that can operate optimally under potential environmental conditions. Selecting the appropriate PDF model plays a crucial role in determining the FSO channel's performance during system design. With a multitude of PDF models available, this study aims to identify the most effective PDF model to be employed in FSO channel modeling.
{"title":"PDF Comparison based on Various FSO Channel Models under Different Atmospheric Turbulence","authors":"Mahdi A. Atiyah, L. F. Abdulameer, Gaurav Narkhedel","doi":"10.22153/kej.2023.09.004","DOIUrl":"https://doi.org/10.22153/kej.2023.09.004","url":null,"abstract":"Recently, wireless communication environments with high speeds and low complexity have become increasingly essential. Free-space optics (FSO) has emerged as a promising solution for providing direct connections between devices in such high-spectrum wireless setups. However, FSO communications are susceptible to weather-induced signal fluctuations, leading to fading and signal weakness at the receiver. To mitigate the effects of these challenges, several mathematical models have been proposed to describe the transition from weak to strong atmospheric turbulence, including Rayleigh, lognormal, Málaga, Nakagami-m, K-distribution, Weibull, Negative-Exponential, Inverse-Gaussian, G-G, and Fisher-Snedecor F distributions. This paper extensively studies and analyses different probability density functions (PDFs) that govern the FSO channel, considering various channel models. This paper aims to comprehensively understand how FSO channels can be effectively modeled using different PDFs. Accurate modeling is crucial for designing FSO systems that can operate optimally under potential environmental conditions. Selecting the appropriate PDF model plays a crucial role in determining the FSO channel's performance during system design. With a multitude of PDF models available, this study aims to identify the most effective PDF model to be employed in FSO channel modeling.\u0000 ","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":" 28","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138614290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.06.002
Osama Ibraheem Kadhm, Ali Hussein Hamad, Fahad Saeed
The implementation of technology in the provision of public services and communication to citizens, which is commonly referred to as e-government, has brought multitude of benefits, including enhanced efficiency, accessibility, and transparency. Nevertheless, this approach also presents particular security concerns, such as cyber threats, data breaches, and access control. One technology that can aid in mitigating the effects of security vulnerabilities within e-government is permissioned blockchain. This work examines the performance of the hyperledger fabric private blockchain under high transaction loads by analyzing two scenarios that involve six organizations as case studies. Several parameters, such as transaction send rate, blockchain size, batch timeout, organization number, and the number of clients, were modified in the two scenarios. The gradual addition of organizations was also observed to determine the impact of multi-organization on the throughput, latency, and scalability of the system. By increasing the block size to approximately 100 transactions per block, acceptable performance and latency results are attained. The throughput and latency findings are accepted for three or four organizations, but when many organizations are added, throughput and latency begin to suffer from poor performance. Also, many tests show that increased block timeout for high sending rates positively affects the throughput and latency.
{"title":"High Transaction Rates Performance Evaluation for Secure E-government Based on Private Blockchain Scheme","authors":"Osama Ibraheem Kadhm, Ali Hussein Hamad, Fahad Saeed","doi":"10.22153/kej.2023.06.002","DOIUrl":"https://doi.org/10.22153/kej.2023.06.002","url":null,"abstract":" \u0000The implementation of technology in the provision of public services and communication to citizens, which is commonly referred to as e-government, has brought multitude of benefits, including enhanced efficiency, accessibility, and transparency. Nevertheless, this approach also presents particular security concerns, such as cyber threats, data breaches, and access control. One technology that can aid in mitigating the effects of security vulnerabilities within e-government is permissioned blockchain. This work examines the performance of the hyperledger fabric private blockchain under high transaction loads by analyzing two scenarios that involve six organizations as case studies. Several parameters, such as transaction send rate, blockchain size, batch timeout, organization number, and the number of clients, were modified in the two scenarios. The gradual addition of organizations was also observed to determine the impact of multi-organization on the throughput, latency, and scalability of the system. By increasing the block size to approximately 100 transactions per block, acceptable performance and latency results are attained. The throughput and latency findings are accepted for three or four organizations, but when many organizations are added, throughput and latency begin to suffer from poor performance. Also, many tests show that increased block timeout for high sending rates positively affects the throughput and latency.","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84105055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.04.004
Marthed Wameed, Ahmed M. ALKAMACHI, E. Erçelebi
Hand gestures are currently considered one of the most accurate ways to communicate in many applications, such as sign language, controlling robots, the virtual world, smart homes, and the field of video games. Several techniques are used to detect and classify hand gestures, for instance using gloves that contain several sensors or depending on computer vision. In this work, computer vision is utilized instead of using gloves to control the robot's movement. That is because gloves need complicated electrical connections that limit user mobility, sensors may be costly to replace, and gloves can spread skin illnesses between users. Based on computer vision, the MediaPipe (MP) method is used. This method is a modern method that is discovered by Google. This method is described by detecting and classifying hand gestures by identifying 21 three-dimensional points on the hand, and by comparing the dimensions of those points. This is how the hand gestures are classified. After detecting and classifying the hand gestures, the system controls the tracked robot through hand gestures in real time, as each hand gesture has a specific movement that the tracked robot performs. In this work, some important paragraphs concluded that the MP method is more accurate and faster in response than the Deep Learning (DL) method, specifically the Convolution Neural Network (CNN). The experimental results shows the accuracy of this method in real time through the effect of environmental elements decreases in some cases when environmental factors change. Environmental elements are such light intensity, distance, and tilt angle (between the hand gesture and camera).The reason for this is that in some cases, the fingers are closed together, and some fingers are not fully closed or opened and the accuracy of the camera used is not good with the changing environmental factors. This leads to the inability of the algorithm used to classify hand gestures correctly (the classification accuracy decrease), and thus response time of the tracked robot's movement increases. That does not present possibility for the system to determine whether the finger is closed or opened.
{"title":"Tracked Robot Control with Hand Gesture Based on MediaPipe","authors":"Marthed Wameed, Ahmed M. ALKAMACHI, E. Erçelebi","doi":"10.22153/kej.2023.04.004","DOIUrl":"https://doi.org/10.22153/kej.2023.04.004","url":null,"abstract":"Hand gestures are currently considered one of the most accurate ways to communicate in many applications, such as sign language, controlling robots, the virtual world, smart homes, and the field of video games. Several techniques are used to detect and classify hand gestures, for instance using gloves that contain several sensors or depending on computer vision. In this work, computer vision is utilized instead of using gloves to control the robot's movement. That is because gloves need complicated electrical connections that limit user mobility, sensors may be costly to replace, and gloves can spread skin illnesses between users. Based on computer vision, the MediaPipe (MP) method is used. This method is a modern method that is discovered by Google. This method is described by detecting and classifying hand gestures by identifying 21 three-dimensional points on the hand, and by comparing the dimensions of those points. This is how the hand gestures are classified. After detecting and classifying the hand gestures, the system controls the tracked robot through hand gestures in real time, as each hand gesture has a specific movement that the tracked robot performs. In this work, some important paragraphs concluded that the MP method is more accurate and faster in response than the Deep Learning (DL) method, specifically the Convolution Neural Network (CNN). The experimental results shows the accuracy of this method in real time through the effect of environmental elements decreases in some cases when environmental factors change. Environmental elements are such light intensity, distance, and tilt angle (between the hand gesture and camera).The reason for this is that in some cases, the fingers are closed together, and some fingers are not fully closed or opened and the accuracy of the camera used is not good with the changing environmental factors. This leads to the inability of the algorithm used to classify hand gestures correctly (the classification accuracy decrease), and thus response time of the tracked robot's movement increases. That does not present possibility for the system to determine whether the finger is closed or opened.","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85420352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.06.001
Estapraq Ameen Taki, Sami D. Salman
In the recent years the research on the activated carbon preparation from agro-waste and byproducts have been increased due to their potency for agro-waste elimination. This paper presents a literature review on the synthesis of activated carbon from agro-waste using microwave irradiation method for heating. The applicable approach is highlighted, as well as the effects of activation conditions including carbonization temperature, retention period, and impregnation ratio. The review reveals that the agricultural wastes heated using a chemical process and microwave energy can produce activated carbon with a surface area that is significantly higher than that using the conventional heating method.
{"title":"A review on Activated Carbon Prepared from Agricultural Waste using Conventional and Microwave Activation","authors":"Estapraq Ameen Taki, Sami D. Salman","doi":"10.22153/kej.2023.06.001","DOIUrl":"https://doi.org/10.22153/kej.2023.06.001","url":null,"abstract":"In the recent years the research on the activated carbon preparation from agro-waste and byproducts have been increased due to their potency for agro-waste elimination. This paper presents a literature review on the synthesis of activated carbon from agro-waste using microwave irradiation method for heating. The applicable approach is highlighted, as well as the effects of activation conditions including carbonization temperature, retention period, and impregnation ratio. The review reveals that the agricultural wastes heated using a chemical process and microwave energy can produce activated carbon with a surface area that is significantly higher than that using the conventional heating method.","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87041970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.05.001
Abdulrahman B. Khudhair, Furat I. Hussein, M. Obeidi
يتطلب نظام الحماية الكاثودية للتيار القسري (ICCP) قياسات كميات منخفضة للغاية من الخصائص الكهربائية. استخدم العمل التجريبي الحالي وحدة مستشعر Adafruit INA219 للحصول على قيم الجهد والتيار وقدرة الحمل الافتراضي الذي يستهلك طاقة منخفضة جدًا تحاكي نظام ICCP. تكمن المشكلة الرئيسية في تكييف مستشعر INA219 مع بيئة LabVIEW بسبب عدم وجود مكتبة المستشعر هذا. تم تخصيص هذا العمل لتكييف وحدة استشعار Adafruit INA219 في بيئة LabVIEW من خلال إنشاء Sub VI وتطويره واختباره بنجاح ليكون جاهزًا للعمل في نظام ICCP. تمت مراقبة إخراج المستشعر باستخدام متحكم Arduino Uno ومجموعة أدوات البرامج الثابتة LabVIEW Linx. تم تطبيق تقنية تعديل عرض النبض (Pulse Width Modulation (PWM) ، والتي تتراوح من 0٪ إلى 100٪ ، بواسطة Arduino لتزويد متحكم الجهد l298N من أجل تنظيم إدخال الجهد للحمل. تم استخدام مرشح متوسط متحرك لقياس متوسط جهد التموج ، وتم استخدام مرشح متوسط لتثبيت القراءات. تقوم دائرة المرشح بتنعيم جهد PWM قبل تزويده الى الحمل. أظهرت النتائج من بيئة MATLAB-Simulink أن تردد القطع عند 2.33 هرتز ، و جهد التموج من اعلى قيمة الى اقل قيمة كان 41.1 مللي فولت وزمن استقرار قدره 0.157 ثانية. أظهرت النتائج التي تمت معايرتها لمستشعر وحدة INA219 عدم دقة الجهد المطلق بحوالي 2.3٪ على النطاق الكامل. بالإضافة إلى ذلك ، كانت قيمة الخطأ المطلق في التيار بنسبة 2.2٪ عند 25 مللي أمبير ويزداد تدريجيا بازدياد قيمة التيار حيث قيمة الخطأ المطلق التيار إلى 7٪ عند 43 مللي أمبير ، بينما كانت أعلى قيمة خطأ مطلق لمقياس القدرة على النطاق الكامل عند 5.8٪.
{"title":"Creating a LabVIEW Sub VI for the INA219 sensor for detecting extremely low-level electrical quantities","authors":"Abdulrahman B. Khudhair, Furat I. Hussein, M. Obeidi","doi":"10.22153/kej.2023.05.001","DOIUrl":"https://doi.org/10.22153/kej.2023.05.001","url":null,"abstract":"يتطلب نظام الحماية الكاثودية للتيار القسري (ICCP) قياسات كميات منخفضة للغاية من الخصائص الكهربائية. استخدم العمل التجريبي الحالي وحدة مستشعر Adafruit INA219 للحصول على قيم الجهد والتيار وقدرة الحمل الافتراضي الذي يستهلك طاقة منخفضة جدًا تحاكي نظام ICCP. تكمن المشكلة الرئيسية في تكييف مستشعر INA219 مع بيئة LabVIEW بسبب عدم وجود مكتبة المستشعر هذا. تم تخصيص هذا العمل لتكييف وحدة استشعار Adafruit INA219 في بيئة LabVIEW من خلال إنشاء Sub VI وتطويره واختباره بنجاح ليكون جاهزًا للعمل في نظام ICCP. تمت مراقبة إخراج المستشعر باستخدام متحكم Arduino Uno ومجموعة أدوات البرامج الثابتة LabVIEW Linx. تم تطبيق تقنية تعديل عرض النبض (Pulse Width Modulation (PWM) ، والتي تتراوح من 0٪ إلى 100٪ ، بواسطة Arduino لتزويد متحكم الجهد l298N من أجل تنظيم إدخال الجهد للحمل. تم استخدام مرشح متوسط متحرك لقياس متوسط جهد التموج ، وتم استخدام مرشح متوسط لتثبيت القراءات. تقوم دائرة المرشح بتنعيم جهد PWM قبل تزويده الى الحمل. أظهرت النتائج من بيئة MATLAB-Simulink أن تردد القطع عند 2.33 هرتز ، و جهد التموج من اعلى قيمة الى اقل قيمة كان 41.1 مللي فولت وزمن استقرار قدره 0.157 ثانية. أظهرت النتائج التي تمت معايرتها لمستشعر وحدة INA219 عدم دقة الجهد المطلق بحوالي 2.3٪ على النطاق الكامل. بالإضافة إلى ذلك ، كانت قيمة الخطأ المطلق في التيار بنسبة 2.2٪ عند 25 مللي أمبير ويزداد تدريجيا بازدياد قيمة التيار حيث قيمة الخطأ المطلق التيار إلى 7٪ عند 43 مللي أمبير ، بينما كانت أعلى قيمة خطأ مطلق لمقياس القدرة على النطاق الكامل عند 5.8٪. \u0000 \u0000 ","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"35 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81341619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.03.003
Mohamed I. Fahad, Ahmed Z. M. Shammari, Ramdziah binti Md Nasir
Incremental sheet forming (ISF) process offers a high degree of flexibility in the manufacturing of different sheet parts, which makes it an ideal candidate for prototype parts as well as efficient at fabricating various customized products at low production costs compared to traditionally used processes. However, parts produced in this process exhibit notable geometrical inaccuracy and considerable thickness reduction. In this paper, the single point incremental sheet forming variant of the process has been implemented to manufacture a highly customized cranial implant starting from the computed tomography (CT) scan data of the patient's anatomy. A methodology, from the modeling to the realization of the implant, is presented and discussed. The primary aim of the research was to analyze and study the effect of the multistage toolpath strategy compared to the traditional single-stage toolpath in terms of geometrical accuracy and thickness distribution. The final results show that the part formed in the multistage toolpath strategy exhibited a more uniform thickness distribution compared to the single-stage approach. Regarding the geometrical accuracy, the deviation analysis between the nominal and actual data has revealed that the multistage forming has significantly enhanced the final geometrical accuracy of the formed part.
{"title":"A Study on the Effect of Multistage Toolpath in Fabricating a Customized Cranial Implant in Incremental Sheet Metal Forming","authors":"Mohamed I. Fahad, Ahmed Z. M. Shammari, Ramdziah binti Md Nasir","doi":"10.22153/kej.2023.03.003","DOIUrl":"https://doi.org/10.22153/kej.2023.03.003","url":null,"abstract":"Incremental sheet forming (ISF) process offers a high degree of flexibility in the manufacturing of different sheet parts, which makes it an ideal candidate for prototype parts as well as efficient at fabricating various customized products at low production costs compared to traditionally used processes. However, parts produced in this process exhibit notable geometrical inaccuracy and considerable thickness reduction. In this paper, the single point incremental sheet forming variant of the process has been implemented to manufacture a highly customized cranial implant starting from the computed tomography (CT) scan data of the patient's anatomy. A methodology, from the modeling to the realization of the implant, is presented and discussed. The primary aim of the research was to analyze and study the effect of the multistage toolpath strategy compared to the traditional single-stage toolpath in terms of geometrical accuracy and thickness distribution. The final results show that the part formed in the multistage toolpath strategy exhibited a more uniform thickness distribution compared to the single-stage approach. Regarding the geometrical accuracy, the deviation analysis between the nominal and actual data has revealed that the multistage forming has significantly enhanced the final geometrical accuracy of the formed part.","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84262269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.02.002
A. M. Shakorfow, Najah Al Mhanna, M. Atiya, Ahmed K. Hassan, Fatimah Q. Kadhim, Zainab A. Mahmoud, Azza Hashim Abbas
This study investigates the possibility of removing ciprofloxacin (CIP) using three types of adsorbent based on green-prepared iron nanoparticles (Fe.NPs), copper nanoparticles (Cu. NPS), and silver nanoparticles (Ag. NPS) from synthesized aqueous solution. They were characterized using different analysis methods. According to the characterization findings, each prepared NPs has the shape of a sphere and with ranges in sizes from of 85, 47, and 32 nanometers and a surface area of 2.1913, 1.6562, and 1.2387 m2/g for Fe.NPs, Cu.NPs and Ag.NPs, respectively. The effects of various parameters such as pH, initial CIP concentration, temperature, NPs dosage, and time on CIP removal were investigated through batch experiments. The results showed that 10 mg/L CIP was removed by 100%, 92% and 79% within 180 min using Fe.NPs, Cu.NPs, and Ag.NPs respectively. In addition to this, kinetic models of the adsorption and mechanism of CIP removal were studied. The cinematic analysis demonstrated that adsorption is a physics adsorption mechanism with an energy of 0.846 kJ.mol-1, 1.720 kJ.mol-1, and 3.872 kJ.mol-1, while the low activation energies of 17.660 kJ.mol-1, 13.221 kJ.mol-1, and 14.060 kJ.mol-1 for Fe.NPs, Cu.NPs, and Ag.NPs respectively. The kinetic removal process follows a pseudo-first-order model following a physical diffusion-controlled reaction. The data on adsorption was analyzed using the Langmuir, Freundlich, Temkin, and Dubinin models, as well as thermodynamic factors, indicating that the process is appropriate and endothermic sorption. The most practical adsorbent was Fe.NPs
{"title":"Removal of Ciprofloxacin Antibiotic from Synthesized Aqueous Solution Using Three Different Metals Nanoparticles Synthesized Through the Green Method","authors":"A. M. Shakorfow, Najah Al Mhanna, M. Atiya, Ahmed K. Hassan, Fatimah Q. Kadhim, Zainab A. Mahmoud, Azza Hashim Abbas","doi":"10.22153/kej.2023.02.002","DOIUrl":"https://doi.org/10.22153/kej.2023.02.002","url":null,"abstract":"This study investigates the possibility of removing ciprofloxacin (CIP) using three types of adsorbent based on green-prepared iron nanoparticles (Fe.NPs), copper nanoparticles (Cu. NPS), and silver nanoparticles (Ag. NPS) from synthesized aqueous solution. They were characterized using different analysis methods. According to the characterization findings, each prepared NPs has the shape of a sphere and with ranges in sizes from of 85, 47, and 32 nanometers and a surface area of 2.1913, 1.6562, and 1.2387 m2/g for Fe.NPs, Cu.NPs and Ag.NPs, respectively. The effects of various parameters such as pH, initial CIP concentration, temperature, NPs dosage, and time on CIP removal were investigated through batch experiments. The results showed that 10 mg/L CIP was removed by 100%, 92% and 79% within 180 min using Fe.NPs, Cu.NPs, and Ag.NPs respectively. In addition to this, kinetic models of the adsorption and mechanism of CIP removal were studied. The cinematic analysis demonstrated that adsorption is a physics adsorption mechanism with an energy of 0.846 kJ.mol-1, 1.720 kJ.mol-1, and 3.872 kJ.mol-1, while the low activation energies of 17.660 kJ.mol-1, 13.221 kJ.mol-1, and 14.060 kJ.mol-1 for Fe.NPs, Cu.NPs, and Ag.NPs respectively. The kinetic removal process follows a pseudo-first-order model following a physical diffusion-controlled reaction. The data on adsorption was analyzed using the Langmuir, Freundlich, Temkin, and Dubinin models, as well as thermodynamic factors, indicating that the process is appropriate and endothermic sorption. The most practical adsorbent was Fe.NPs\u0000 ","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74776924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.22153/kej.2023.02.003
Zahraa A. Najm, A. M. Shakorfow, Najah Al Mhanna, Ahmed K. Hassan, Mohammed A. Atyia
This study uses an environmentally friendly and low-cost synthesis method to manufacture zinc oxide nanoparticles (ZnO NPs) by using zinc sulfate. Eucalyptus leaf extract is an effective chelating and capping agent for synthesizing ZnO NPs. The structure, morphology, thermal behavior, chemical composition, and optical properties of ZnO nanoparticles were studied utilizing FT-IR, FE-SEM, EDAX, AFM, and Zeta potential analysis. The FE-SEM pictures confirmed that the ZnO NPs with a size range of (22-37) nm were crystalline and spherical. Two methods were used to prepare ZnO NPs. The first method involved calcining the resulting ZnO NPs, while the second method did not. The prepared ZnO NPs were used as adsorbents for removing acid black 210 dye (AB210) from simulated wastewater. The removal efficiency using calcinated and uncalcinated ZnO NPs was 57 % and 59 %, respectively.
{"title":"Green Fabrication and Characterization of Zinc Oxide Nanoparticles using Eucalyptus Leaves for Removing Acid Black 210 Dye from an Aqueous Medium","authors":"Zahraa A. Najm, A. M. Shakorfow, Najah Al Mhanna, Ahmed K. Hassan, Mohammed A. Atyia","doi":"10.22153/kej.2023.02.003","DOIUrl":"https://doi.org/10.22153/kej.2023.02.003","url":null,"abstract":"This study uses an environmentally friendly and low-cost synthesis method to manufacture zinc oxide nanoparticles (ZnO NPs) by using zinc sulfate. Eucalyptus leaf extract is an effective chelating and capping agent for synthesizing ZnO NPs. The structure, morphology, thermal behavior, chemical composition, and optical properties of ZnO nanoparticles were studied utilizing FT-IR, FE-SEM, EDAX, AFM, and Zeta potential analysis. The FE-SEM pictures confirmed that the ZnO NPs with a size range of (22-37) nm were crystalline and spherical. Two methods were used to prepare ZnO NPs. The first method involved calcining the resulting ZnO NPs, while the second method did not. The prepared ZnO NPs were used as adsorbents for removing acid black 210 dye (AB210) from simulated wastewater. The removal efficiency using calcinated and uncalcinated ZnO NPs was 57 % and 59 %, respectively.","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87202927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-06-05DOI: 10.22153/kej.2023.03.002
Khatab Emad Talib, S. D. Salman
Activated carbon derived from Ficus Binjamina agro-waste synthesized by pyro carbonic acid microwave method and treated with silicon oxide (SiO2) was used to enhance the adsorption capability of the malachite green (MG) dye. Three factors of concentration of dye, time of mixing, and the amount of activated carbon with four levels were used to investigate their effect on the MG removal efficiency. The results show that 0.4 g/L dosage, 80 mg/L dye concentration, and 40 min adsorption duration were found as an optimum conditions for 99.13% removal efficiency. The results also reveal that Freundlich isotherm and the pseudo-second-order kinetic models were the best models to describe the equilibrium adsorption data.
{"title":"Removal of Malachite Green from Aqueous Solution using Ficus Benjamina Activated Carbon-Nonmetal Oxide synthesized by pyro Carbonic Acid Microwave","authors":"Khatab Emad Talib, S. D. Salman","doi":"10.22153/kej.2023.03.002","DOIUrl":"https://doi.org/10.22153/kej.2023.03.002","url":null,"abstract":"Activated carbon derived from Ficus Binjamina agro-waste synthesized by pyro carbonic acid microwave method and treated with silicon oxide (SiO2) was used to enhance the adsorption capability of the malachite green (MG) dye. Three factors of concentration of dye, time of mixing, and the amount of activated carbon with four levels were used to investigate their effect on the MG removal efficiency. The results show that 0.4 g/L dosage, 80 mg/L dye concentration, and 40 min adsorption duration were found as an optimum conditions for 99.13% removal efficiency. The results also reveal that Freundlich isotherm and the pseudo-second-order kinetic models were the best models to describe the equilibrium adsorption data.\u0000 ","PeriodicalId":7637,"journal":{"name":"Al-Khwarizmi Engineering Journal","volume":"126 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73085203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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