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Experimental Investigation of Forced Flow Heat-Transfer Enhancement in a Minichannel 微型通道中强制流换热增强的实验研究
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700320
A. V. Belyaev, N. E. Sidel’nikov, E. I. Gareev, A. V. Dedov

The results of the investigation into heat-transfer enhancement at increasing critical heat flux due to modification of a wall’s inner surface are presented. The greater need for new, compact, and energy-efficient heat exchangers on the basis of minichannels for high-tech industries makes this investigation urgent. The potential for application of small diameter channels in systems where various dielectric liquids or freons at moderate and high reduced pressures can be used as a coolant is being actively investigated today. The experiments were performed in a heated vertical minichannel. The wall was modified by the rolling method, which has not yet been used in small diameter channels. The experiments were performed with a forced flow of R125 refrigerant at high reduced pressures of 0.43 and 0.56 in the range of mass flowrates from 200 to 1200 kg/(m2 s), which is the most applicable range for minichannel heat exchangers. Heat transfer during forced convection and flow boiling was studied. The experimental setup and the minichannel inner wall modification method are described. Experimental data on forced convection and flow boiling heat-transfer coefficients, critical heat fluxes, and pressure drops are presented. The heat-transfer data were compared with the results obtained previously with the inner surface modified by the action of laser pulses on the outer wall. The convective heat-transfer coefficient in a minichannel with the inner surface modified by rolling was found to be much greater than that in a smooth channel. The obtained convective heat-transfer coefficients are compared with the predictions by empirical formulas derived for large-diameter pipes with the wall surface modified by rolling.

本文介绍了在临界热通量增加时,通过改变壁的内表面来提高传热效果的研究结果。高科技产业对基于微型通道的新型、紧凑、高能效热交换器的需求越来越大,这使得这项研究迫在眉睫。目前正在积极研究小直径通道在各种介质液体或氟利昂系统中的应用潜力,这些介质液体或氟利昂可在中等或较高的减压条件下用作冷却剂。实验是在一个加热的垂直微型通道中进行的。通过滚动方法对通道壁进行了改良,这种方法尚未在小直径通道中使用过。实验中,R125 制冷剂在 0.43 和 0.56 的高减压下强制流动,质量流量范围为 200 至 1200 kg/(m2 s),这是微型通道热交换器最适用的范围。研究了强制对流和流动沸腾过程中的热传递。介绍了实验装置和微型通道内壁改造方法。介绍了强制对流和流动沸腾传热系数、临界热通量和压降的实验数据。这些传热数据与之前通过激光脉冲作用于外壁对内表面进行改性所获得的结果进行了比较。结果发现,内表面经滚动修正的微型通道中的对流换热系数远大于光滑通道中的对流换热系数。所获得的对流换热系数与根据经验公式推导出的通过滚动修正管壁表面的大直径管道的预测值进行了比较。
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引用次数: 0
An Analysis of Lead Oxidation Mechanisms in the Volume of Vapor Bubbles 气泡体积中的铅氧化机制分析
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700393
M. V. Vorivonchik, D. A. Nazarov, D. S. Sinitsyn, N. A. Mosunova, A. A. Sorokin

The article presents a kinetic model describing the lead vapor oxidation in the vapor bubble volume to produce lead oxide and hydrogen with their subsequent dissolution in the lead melt volume. The model is implemented in the approximation of homogeneous distribution of reagents and oxidation reaction products in the bubble volume. An analytical solution for stationary oxidation conditions is obtained. It is shown that vapor bubbles in the lead melt volume are a sort of chemical “microreactors” producing lead oxide and hydrogen, which subsequently dissolve in the melt volume. However, such hydrogen generation mechanism does not pose any threat for the primary coolant circuit of fast lead cooled reactors in terms of hydrogen accumulation and explosion hazard in view of essentially low intensity of the hydrogen generation source. The article presents the results of water to hydrogen conversion assessments carried out with the use of a homogeneous kinetic model for interaction of water vapor with lead vapor in the vapor bubble volume. The model incorporates mechanisms governing lead evaporation into the bubble volume, oxidation of lead vapor as it interacts with water vapor in the bubble volume, and dissolution of reaction products in the lead melt surrounding the bubble. One more important result of equilibrium thermodynamic computations is connected with a possible change in the composition of iron oxides in the melt after the injection of water from the steam generator leak into the melt. The ingress of water into the lead melt may cause a change in the composition of iron oxides, thereby increasing the fraction of hematite and decreasing the fraction of magnetite. This may entail a change in the composition of the protective oxide film on the structural steel surface to make it more brittle.

文章提出了一个动力学模型,描述了铅蒸气在蒸气泡体积中氧化生成氧化铅和氢,随后在铅熔体体积中溶解的过程。该模型是在试剂和氧化反应产物在气泡体积中均匀分布的近似条件下实现的。得到了固定氧化条件下的解析解。结果表明,铅熔体中的气泡是一种化学 "微反应器",会产生氧化铅和氢气,随后溶解在熔体中。不过,鉴于氢产生源的强度基本上很低,这种氢产生机制不会对快速铅冷反应堆的初级冷却剂回路造成氢积累和爆炸危险。文章介绍了使用均相动力学模型对水蒸气与铅蒸汽在蒸汽泡体积中的相互作用进行水氢转化评估的结果。该模型包含了铅蒸发到气泡中的机制、铅蒸气与气泡中水蒸气相互作用时的氧化机制以及反应产物在气泡周围铅熔体中的溶解机制。平衡热力学计算的另一个重要结果与蒸汽发生器泄漏的水注入熔体后熔体中铁氧化物成分的可能变化有关。水进入铅熔体可能会导致铁氧化物的成分发生变化,从而增加赤铁矿的比例,减少磁铁矿的比例。这可能导致结构钢表面保护氧化膜的成分发生变化,使其变得更脆。
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引用次数: 0
Ensuring Technological Indicators for Nitrogen Oxide Emissions during Solid-Fuel Combustion in a High-Power Steam Boiler 确保大功率蒸汽锅炉固体燃料燃烧过程中氮氧化物排放的技术指标
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700368
V. B. Prokhorov, V. S. Kirichkov, S. L. Chernov, M. V. Fomenko

Organic fuel combustion products are one of the main sources of air pollution. When burning fossil fuels, pollutants harmful to human health, such as nitrogen and sulfur oxides, fly ash with particles of unburned fuel, carbon oxides, polycyclic aromatic hydrocarbons, and metal oxides, are released into the atmosphere. The largest emissions of pollutants into the atmosphere are accompanied by the combustion of solid fuels. In 2014, significant changes took place in the environmental legislation of the Russian Federation [1], which oblige energy enterprises to comply not only with sanitary and hygienic standards but also with technical and technological standards. To maintain technological indicators for specific NOx emissions on boiler equipment at the regulatory level, it will be necessary to fully apply primary methods for suppressing the formation of nitrogen oxides, use low-toxic burners and fuel combustion schemes, and, in some cases, expensive gas purification from NOx will be required. Based on statistical data, the BKZ-420-140 (E-420-140) boiler was selected as a prototype for research. When BKZ-420-140 boilers in the factory version operate using vortex burners when burning brown coal, the concentration of nitrogen oxides in the flue gases is more than 800 mg/m3, which significantly exceeds current standards. In order to reduce emissions of nitrogen oxides while ensuring high operating efficiency of boiler equipment, a solid-fuel combustion scheme using direct-flow burners and nozzles has been proposed for this boiler. It is shown that it will be possible to increase the economic and environmental efficiency of BKZ-420-140 boilers’ operation by implementing the developed solid-fuel combustion scheme using direct-flow burners and nozzles on them.

有机燃料燃烧产物是空气污染的主要来源之一。燃烧化石燃料时,会向大气中排放对人类健康有害的污染物,如氮氧化物和硫氧化物、带有未燃烧燃料颗粒的飞灰、碳氧化物、多环芳烃和金属氧化物。固体燃料燃烧时向大气排放的污染物最多。2014 年,俄罗斯联邦的环境立法发生了重大变化[1],要求能源企业不仅要遵守卫生标准,还要遵守技术和工艺标准。为了使锅炉设备的氮氧化物具体排放技术指标保持在规定水平,必须充分应用抑制氮氧化物形成的初级方法,使用低毒燃烧器和燃料燃烧方案,在某些情况下,还需要进行昂贵的氮氧化物气体净化。根据统计数据,BKZ-420-140(E-420-140)锅炉被选为研究原型。当工厂版 BKZ-420-140 锅炉使用涡流燃烧器燃烧褐煤时,烟气中的氮氧化物浓度超过 800 mg/m3,大大超过了现行标准。为了减少氮氧化物的排放,同时确保锅炉设备的高运行效率,我们为该锅炉提出了使用直流燃烧器和喷嘴的固体燃料燃烧方案。研究表明,通过在 BKZ-420-140 锅炉上实施所开发的使用直流燃烧器和喷嘴的固体燃料燃烧方案,可以提高锅炉运行的经济效益和环境效益。
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引用次数: 0
Calculation of Reactor Characteristics and Techno-Economic Assessment of a System for Hydrogen Production from Biomass Using Gasification in Chemical Cycles 利用化学循环气化从生物质制氢系统的反应器特性计算和技术经济评估
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700277
G. A. Ryabov, D. S. Litun, O. M. Folomeev

The calculation method developed by the authors is supplemented by the heat balance of a circulating fluidized bed (CFB) reactor for burning coke residue in a CFB reactor‒gas-generator system. The following options are examined: with the supply of additional dried fuel to the reactor as an alternative method for keeping the required gasification temperature of particles at the CFB reactor outlet and application as a fuel of a mixture of wood biomass and Kuznetsk coal benefication products. The thermal cycle of the plant has been modified as applicable, and the calculation results are presented. It has been demonstrated that gasification of a mixture of biomass and coal benefication enables increasing the overall system capacity (production of hydrogen + electricity) without a considerable growth in the biomass consumption. In this case, the hydrogen production decreases, and the hydrogen production efficiency drops but the efficiency of electricity generation rises. The hydrodynamic calculation of CFB reactors was performed to attain the specified flowrates of circulating material required to maintain proper temperatures in the reactors. The flowrate of circulating particles can be increased by increasing the pressure difference (loading level or weight of material in the reactors). The overall dimensions of the reactors have been determined, and their layout is presented. A procedure for calculating capital and operating expenditures is outlined, and these expenditure components are estimated. The cost of hydrogen production using biomass without CO2 emission over the life cycle of the plant was estimated (USD 1.45/kg). Approximately 2/3 of the formed CO2 is already ready for storage. Therefore, we have only to remove CO2 from the flue gas flow from the CFB reactor of the gas generator. This level corresponds to available foreign data on similar plants operating on natural gas and is lower than that provided by the widely used technology of steam reforming of natural gas with CO2 capture.

作者开发的计算方法得到了循环流化床(CFB)反应器热平衡的补充,该反应器用于在 CFB 反应器-燃气-发电机系统中燃烧焦炭残渣。对以下方案进行了研究:向反应器供应额外的干燥燃料,作为保持 CFB 反应器出口颗粒所需气化温度的替代方法,以及将木质生物质和库兹涅茨克煤炭选矿产品的混合物用作燃料。该装置的热循环已根据实际情况进行了修改,并给出了计算结果。结果表明,生物质和选煤混合物的气化可以在不大幅增加生物质消耗量的情况下提高整个系统的产能(制氢+发电)。在这种情况下,制氢量减少,制氢效率下降,但发电效率上升。对 CFB 反应器进行流体力学计算,以达到保持反应器内适当温度所需的指定循环材料流速。循环颗粒的流速可通过增加压差(反应器中的装料水平或物料重量)来提高。反应器的总体尺寸已经确定,并介绍了其布局。概述了计算资本和运营支出的程序,并对这些支出部分进行了估算。估算了利用生物质生产氢气而不排放二氧化碳的成本(1.45 美元/千克)。形成的二氧化碳中约有 2/3 已准备好储存。因此,我们只需从气体发生器 CFB 反应器的烟气流中去除二氧化碳即可。这一水平符合国外同类天然气发电厂的现有数据,也低于广泛使用的天然气蒸汽转化与二氧化碳捕集技术所提供的水平。
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引用次数: 0
Results of Testing Olivine Sand As a Filler for a Furnisher with a Fluidized Bed When Burning Sunflower Husks 在燃烧葵花籽时将橄榄石砂作为流化床燃烧器填料的测试结果
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700265
O. Yu. Milovanov, D. V. Klimov, S. N. Kuzmin, S. V. Grigoriev, V. S. Kokh-Tatarenko, F. Tabet

Russia is one of the world leaders in the production of sunflower oil, and the utilization of sunflower husks seems to be a very pressing problem. The husk has low humidity (4.4‒12.2%) and a fairly high calorific value (16–19 MJ/kg), but its ash contains a significant amount of potassium, calcium, and magnesium compounds, which cause slagging of the boiler furnace and rapid growth of ash deposits on its convective heating surfaces. Agglomeration and slagging are especially acute when burning crop waste in a fluidized bed of quartz sand, causing defluidization of the layer. This leads to frequent boiler shutdowns to clean the furnaces. Alternative materials to quartz sand are known, but the literature contains little data on their commercial application. The operation of a combustion device with a fluidized bed of quartz sand and olivine as part of a 2-MW heat-generating installation when burning sunflower husks is analyzed. The chemical composition of agglomerates is studied and the mechanism of their formation is described. The experiment on burning husks in a layer of olivine lasted continuously for 600 h. When carrying out periodic measurements of the fractional composition of the olivine layer, the concentrations of carbon oxide, dioxide, and oxygen in the flue gases and the formation of agglomerates was not detected.

俄罗斯是世界上葵花籽油生产大国之一,而葵花籽壳的利用似乎是一个非常紧迫的问题。葵花籽壳的湿度较低(4.4-12.2%),热值较高(16-19 兆焦/千克),但其灰分中含有大量的钾、钙和镁化合物,会导致锅炉炉膛结渣,对流加热面上的灰分沉积也会迅速增加。在石英砂流化床中焚烧农作物废料时,结块和结渣现象尤为严重,导致料层脱流。这导致锅炉经常停机清理炉子。石英砂的替代材料是已知的,但文献中有关其商业应用的数据很少。本文分析了石英砂和橄榄石流化床燃烧装置在燃烧葵花籽壳时的运行情况,该装置是 2 兆瓦发热装置的一部分。研究了团聚体的化学成分并描述了其形成机理。在橄榄石层中燃烧葵花籽壳的实验持续了 600 小时。在定期测量橄榄石层的分数组成时,没有检测到烟气中氧化碳、二氧化物和氧气的浓度以及团聚体的形成。
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引用次数: 0
Study of Acoustic Barriers with an Cylindrical Top Edge for Reducing the Noise of Power Equipment 用于降低电力设备噪音的圆柱形顶边隔声屏障研究
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700290
V. B. Tupov, A. B. Mukhametov

Acoustic barriers are used to reduce the noise of power equipment. To increase their efficiency, an cylindrical top edge is installed, which is an add-on on the top edge of the barrier. To study the acoustic properties of the cylindrical top edge, a mathematical model of a 3-m high barrier was built in the COMSOL Multiphysics program. The mathematical model of the barrier without an cylindrical top edge was verified using the Kurze calculation method. The acoustic characteristics of a superstructure in the form of an cylindrical top edge have been studied. It has been determined that the acoustic efficiency of the cylindrical top edge depends both on the position relative to the upper edge of the barrier and on the distance from the noise source to the barrier. The calculation results show that the greatest changes in sound pressure levels when installing an cylindrical top edge are observed at high frequencies, and the minimum at low frequencies. The acoustic efficiency of the cylindrical top edge at geometric mean frequencies corresponding to low frequencies is approximately 1–2 dB and it can reach up to 25 dB at geometric mean frequencies corresponding to high frequencies. The acoustic characteristics of an cylindrical top edge with different installation angles have been studied. It has been shown that the cylindrical top edge with an installation angle of 0° has the highest acoustic efficiency (8–10 dBA) at a distance from the noise source to the barrier of up to 2 m. At distances from 2 to 5 m, the highest acoustic efficiency (4–8 dBA) is observed when using an antidiffraction device with an installation angle of 90°. Using an cylindrical top edge with an installation angle 180° is advisable when the barrier is located next to the design point at a distance from the barrier to it of less than 5 m. When installing an antidiffraction device, a significantly greater acoustic effect is achieved than when increasing the height of the barrier. The results obtained during the research are recommended to be taken into account when implementing noise reduction measures when choosing the location of an acoustic barrier with an cylindrical top edge relative to the noise source and the design point.

隔声屏障用于降低电力设备的噪音。为了提高隔声屏障的效率,在隔声屏障的顶部边缘安装了一个圆柱形顶边。为了研究圆柱形顶缘的声学特性,我们在 COMSOL Multiphysics 程序中建立了一个 3 米高隔声屏障的数学模型。使用 Kurze 计算方法验证了不带圆柱形顶边的屏障数学模型。对圆柱形顶边上部结构的声学特性进行了研究。研究结果表明,圆柱形上边缘的声学效率取决于与护栏上边缘的相对位置以及噪声源到护栏的距离。计算结果表明,安装圆柱形顶边时,高频声压级的变化最大,低频声压级的变化最小。在低频对应的几何平均频率下,圆柱形顶边的声学效率约为 1-2 dB,而在高频对应的几何平均频率下,声学效率可达 25 dB。对不同安装角度的圆柱形顶边的声学特性进行了研究。结果表明,安装角度为 0° 的圆柱形顶缘在噪声源到屏障的距离为 2 米时具有最高的声学效率(8-10 分贝),而在距离为 2 至 5 米时,使用安装角度为 90° 的防衍射装置则具有最高的声学效率(4-8 分贝)。当隔离栅位于设计点旁边,且隔离栅与设计点的距离小于 5 米时,建议使用安装角为 180° 的圆柱形顶边。建议在实施降噪措施时,在选择顶部边缘为圆柱形的隔声屏障与噪声源和设计点的相对位置时,考虑研究得出的结果。
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引用次数: 0
Analysis of the Effectiveness of Cooling a High-Temperature Surface with a Dispersed Coolant Flow 利用分散冷却剂流冷却高温表面的效果分析
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700253
D. A. Groo, A. S. Demidov, A. V. Zakharenkov, A. L. Tupotilov, A. T. Komov

The results of practical work on cooling heated targets of research modules of various designs with a dispersed coolant flow are presented. A brief description of the experimental stand and its main systems, nozzle designs and modules are given, allowing for the implementation of different cooling schemes: with parallel and perpendicular arrangement of the nozzle end and the target surface. Temperature fields of heated targets were obtained depending on thermal loads and water and air flow rates. Primary processing of experimental data was carried out, during which the temperature values on the heating and cooling surfaces were determined. Graphs of the dependence of the temperatures of these surfaces on the supplied thermal power for research modules of various designs are shown. The heat-flux density from the cooled surface of the heated target to the dispersed coolant flow and the heat-transfer coefficient were estimated. The dependences of the heat-flux density and heat-transfer coefficient on the temperature difference between the wall and liquid for different designs of cooling systems are shown graphically. An assessment was made of the proportion of heat removed from the heat-loaded elements of the proposed structures through a phase transition. It is shown that the mutual orientation of the nozzle and the heated surface significantly affects the limiting value of the heat-flux density removed from the target in the thermal stabilization mode. It has been established that the cooling efficiency of a dispersed coolant flow with a perpendicular arrangement of the nozzle end and the target surface depends to a large extent on the timely opening of the spray plume, determined mainly by the operating parameters and the distance from the nozzle end to the target.

本文介绍了利用分散冷却剂流冷却各种设计的研究模块加热目标的实际工作成果。简要介绍了实验台及其主要系统、喷嘴设计和模块,以便实施不同的冷却方案:喷嘴末端与目标表面平行和垂直布置。根据热负荷以及水和空气的流速,获得了被加热目标的温度场。对实验数据进行了初步处理,确定了加热和冷却表面的温度值。图表显示了这些表面的温度与不同设计的研究模块所提供的热功率的关系。对从加热目标的冷却表面到分散冷却剂流的热流密度和传热系数进行了估算。不同设计的冷却系统的热流密度和传热系数与壁面和液体之间的温差的关系用图表表示。对拟议结构的热负荷元件通过相变带走的热量比例进行了评估。结果表明,在热稳定模式下,喷嘴和受热表面的相互取向对从目标移除的热流密度的极限值有很大影响。研究证实,喷嘴末端与目标表面垂直布置的分散冷却剂流的冷却效率在很大程度上取决于喷雾羽流的及时打开,这主要由操作参数和喷嘴末端到目标的距离决定。
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引用次数: 0
Regularities of Stable Film Boiling of a Subcooled Liquid 过冷液体稳定薄膜沸腾的规律性
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700307
M. M. Vinogradov, I. A. Molotova, A. R. Zabirov, V. V. Yagov

Different models of stable film boiling of liquids that give heat-transfer characteristics under these conditions are examined. The existing models have been demonstrated to have disadvantages associated with a consideration of certain limiting cases. The model of subcooled liquid film boiling, developed by a research group including the authors of this paper in 2017, takes into account the velocity of natural convection at the liquid/vapor interface. This model demonstrates good agreement with experimental data on cooling of spheres and cylinders, but the expression for the heat-transfer coefficient (HTC) contains an empirical coefficient. A new model of heat transfer during subcooled liquid film boiling based on the Bromley assumptions is proposed. An analysis of the contribution of radiation to heat transfer during film boiling has demonstrated that, according to a rough estimate, the contribution of this factor can be as high as 10% during cooling of high-temperature bodies in water when their surface is superheated to 1000 K. The applicability of the new model of stable film boiling of subcooled liquids and the models examined in this paper was validated by comparison with the authors’ experimental data. The test pieces were spheres and cylinders made of different metals (such as stainless steel, nickel, copper, titanium, FeCrAl alloy, zirconium). They were cooled in saturated or subcooled liquids with different thermophysical properties (such as water, ethanol, water-ethanol mixtures of various concentrations, FC-72, nitrogen) at different system pressures. The experimental data agree best of all with the predictions by the newly developed model. The performed comparisons have demonstrated that this model is more accurate (by 10%) compared to other models of heat transfer during cooling of spheres and cylinders in various liquids (such as water, ethanol, FC-72, isopropanol) in the subcooling range from 10 to 180 K at system pressures from 0.02 to 1.00 MPa.

研究了不同的液体稳定膜沸腾模型,这些模型给出了这些条件下的传热特性。事实证明,现有模型存在与考虑某些限制情况相关的缺点。包括本文作者在内的研究小组于 2017 年开发的过冷液体膜沸腾模型考虑了液体/蒸汽界面的自然对流速度。该模型与球体和圆柱体冷却的实验数据显示出良好的一致性,但传热系数(HTC)的表达式包含一个经验系数。基于布罗姆利假设,提出了过冷液膜沸腾过程中传热的新模型。对薄膜沸腾过程中辐射对传热的贡献进行了分析,结果表明,根据粗略估计,当高温体表面过热至 1000 K 时,辐射对其在水中冷却过程中的贡献可高达 10%。试验品是由不同金属(如不锈钢、镍、铜、钛、铁铬铝合金、锆)制成的球体和圆柱体。它们在具有不同热物理性质的饱和或过冷液体(如水、乙醇、不同浓度的水乙醇混合物、FC-72、氮气)中以不同的系统压力进行冷却。实验数据与新开发模型的预测结果最为吻合。比较结果表明,在 10 至 180 K 的过冷度范围内,在 0.02 至 1.00 MPa 的系统压力下,该模型与其他球体和圆柱体在各种液体(如水、乙醇、FC-72、异丙醇)中冷却时的传热模型相比,准确度更高(10%)。
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引用次数: 0
Method for Determining the Characteristics of a Radial Turbo Expander for Mixed Working Fluids in Nondesign Modes 在非设计模式下确定混合工作流体径向涡轮膨胀机特性的方法
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700289
A. A. Sidorov, A. K. Yastrebov

The work is devoted to determining the characteristics of turbine stages in off-design modes that arise when pressures and temperatures change before or after the stage, a transition to a different rotation speed, or, for example, when the composition of the working fluid changes. As part of the project, a quasi-one-dimensional method for calculating the characteristics of a turboexpander assembly (TEA) stage when changing operating parameters and/or working fluid has been developed, which differs from known methods by using the equations of the state of real gas, adaptation to purely radial stages, and a simplified approach to determining the pressure at the outlet of the guide vane for assessing the degree of reactivity and the ability to switch to another working fluid, including a mixed one. The analytical methodology was verified by comparison with the experimental data of other authors and the results of calculations using CFD methods for radial-axial stages as well as with approaches to the calculation of purely radial turbomachines due to the lack of experimental data for this type of TEA in the public domain. An extended characteristic of a radial stage operating in air (turbo map) was constructed, and the dependences of the isentropic efficiency, degree of reactivity, mass flow and power of the stage on the relative circumferential speed were assessed. An assessment was made of the impact of switching to another working fluid (for example, switching from air to methane was chosen). It is shown that the characteristics do not change qualitatively but they shift from one another along the axis of the relative peripheral velocity. Further development of the technique involves taking into account possible phase transitions (volume condensation) in the flow part.

这项工作致力于确定涡轮级在非设计模式下的特性,当涡轮级前后的压力和温度发生变化、过渡到不同的转速或工作流体成分发生变化时,都会出现非设计模式。作为该项目的一部分,已开发出一种准一维方法,用于计算涡轮膨胀机组件(TEA)级在改变运行参数和/或工作流体时的特性,该方法与已知方法的不同之处在于使用了实际气体状态方程,适用于纯径向级,并采用简化方法确定导叶出口处的压力,以评估反应程度和切换到另一种工作流体(包括混合工作流体)的能力。通过与其他作者的实验数据、径向-轴向级的 CFD 计算结果以及纯径向涡轮机械的计算方法进行比较,验证了该分析方法。构建了在空气中运行的径向级的扩展特性(涡轮图),并评估了该级的等熵效率、反应度、质量流量和功率与相对圆周速度的关系。对切换到另一种工作流体(例如,从空气切换到甲烷)的影响进行了评估。结果表明,这些特性并没有发生质的变化,但它们沿着相对圆周速度的轴线相互移动。该技术的进一步发展包括考虑流动部分可能发生的相变(体积凝结)。
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引用次数: 0
Development of Sorbent Compositions from TPP Water-Treatment Facility Waste for Gaseous Fuel Desulfurization 利用 TPP 水处理设施废料开发用于气体燃料脱硫的吸附剂成分
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700241
A. A. Filimonova, A. Yu. Vlasova, A. R. Gizzatullin, N. D. Chichirova

Development of sorbent compositions from industrial waste is a promising and economically feasible method for solving environmental problems. Power industry enterprises experience an acute need for the development of new environmentally friendly and cheap sorbents for gaseous fuel desulfurization purposes. Owing to removal of sulfur compounds from the fuel, the latter becomes less corrosive in nature, due to which it becomes possible to increase the equipment’s service life and also to decrease the deposits of sulfides on the surfaces of power installations. Based on a review of literature sources, the most important developments for sorbents consisting of industrial waste were determined. The waste of a thermal power plant (TPP) water-treatment facility (WTF) in the form of sludge water is of the greatest interest for removing sulfur compounds from fuel. Sludge water has a complex composition, which depends directly on the source water quality and water-treatment technology. Sludge water is produced at the natural water pretreatment stage, during which suspended matter is removed from source water by adding coagulants, flocculants, and other chemical agents that are specified by the process regulation. The article presents the composition of a sorbent produced from the WTF sludge at one of the Kazan combined heat and power plants (CHPP) for gaseous fuel desulfurization. Laboratory experiments were carried out with this sorbent, as a result of which the sulfur compound absorption efficiency and the strength characteristics of the prepared and formed sorbent were determined. A new method for indicating the extent to which the adsorbent absorption efficiency is decreased by using an indicating sorbent is also proposed. It is very difficult to monitor the level of sulfur compounds in purified gas by means of automatic sensors in view of a high measurement error, due to which an inaccurate result is obtained. An indicating sorbent composition that makes it possible to detect nonadsorbed sulfuric compositions by showing a color change from light to deep yellow is proposed. A method for using this indicating sorbent is described, and experimental data on its ability to absorb sulfur compounds are given.

从工业废料中开发吸附剂成分是解决环境问题的一种前景广阔且经济可行的方法。电力工业企业急需开发环保、廉价的新型吸附剂,用于气态燃料脱硫。由于燃料中硫化合物的脱除,后者的腐蚀性降低,因此可以延长设备的使用寿命,并减少硫化物在电力设备表面的沉积。根据对文献资料的审查,确定了由工业废料组成的吸附剂的最重要发展。火力发电厂(TPP)水处理设施(WTF)中以污泥水形式存在的废料对于去除燃料中的硫化物具有最大的意义。污泥水成分复杂,直接取决于原水水质和水处理技术。污泥水是在天然水预处理阶段产生的,在这一阶段,通过添加混凝剂、絮凝剂和工艺规定的其他化学制剂来去除原水中的悬浮物质。文章介绍了喀山一家热电联产厂(CHPP)利用 WTF 污泥生产的气体燃料脱硫吸附剂的成分。使用这种吸附剂进行了实验室实验,结果确定了硫化合物吸收效率以及制备和形成的吸附剂的强度特性。此外,还提出了一种使用指示吸附剂来显示吸附剂吸收效率下降程度的新方法。使用自动传感器监测净化气体中硫化合物的含量非常困难,因为测量误差大,得到的结果不准确。本文提出了一种指示吸附剂成分,它可以通过显示从浅黄色到深黄色的颜色变化来检测未吸附的硫化物。文中介绍了使用这种指示吸附剂的方法,并给出了其吸附硫化合物能力的实验数据。
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引用次数: 0
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Thermal Engineering
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