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Determination of Temperature and Emissivity of Condensed Phase Particles during Flame Combustion of Peat in a Steam Boiler 蒸汽锅炉中泥炭火焰燃烧过程中缩合相颗粒温度和发射率的测定
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-10-22 DOI: 10.1134/S0040601525700478
I. A. Zagrai, V. A. Kuzmin, A. S. Lonshakov

The temperature of condensed phase particles formed during flame combustion of peat from Kirov oblast in a BKZ-210-140F boiler was studied using a pyrometric method. The authors elaborated an experimental-and-calculation procedure for pyrometry of the furnace enabling determination of the temperature of condensed phase particles (of coke and ash) in the gas phase transparency band. The measurements were taken using Raynger R3I 2MSC and Kelvin 2300 PLTs pyrometers having radiation receivers operating at a wavelength of 1.6 µm and in a spectral range from 1.0 to 1.6 µm, respectively. Dependences are obtained of the temperatures measured at different heights from the boiler furnace bottom to the measurement point (hereinafter referred to the boiler furnace height) (H = 9, 14, and 16 m), on the emissivity set on the pyrometers in the range from 0.1 to 1.0. Spectral and integral radiative energy flux densities sensed by the pyrometers were calculated. Brightness temperatures observed during peat combustion were determined. The software package developed by the authors was used for computational studies of the condensed phase emissivity as a function of the specified temperature considering the fuel burnout along the furnace height by solving the radiative transfer equation for a multicomponent radiating, absorbing, and scattering medium. The intersection of the experimental and predicted functions gave the emissivity and true temperatures of the condensed phase particles. According the measurements taken by the Raynger pyrometer, the particle temperature in the flame root part (H = 9 m) is equal to 1453 K; it is 1226 K in the flame middle part (H = 14 m) and 1334 K in the flame tail part (H = 16 m). For the Kelvin pyrometer, these temperatures were 1471, 1265, and 1343 K, respectively. The obtained particle temperatures enabled us to assess the risk of melting of the mineral part of the fuel and slagging of the furnace.

采用高温法研究了基洛夫州泥炭在BKZ-210-140F锅炉中火焰燃烧形成的凝聚相颗粒的温度。作者详细阐述了一种炉温法的实验和计算程序,可以测定气相透明带中凝聚相颗粒(焦炭和灰分)的温度。测量使用Raynger R3I 2MSC和Kelvin 2300 plt高温计,辐射接收器工作波长分别为1.6 μ m和光谱范围为1.0至1.6 μ m。从锅炉炉膛底部到测量点(以下简称锅炉炉膛高度)在不同高度(H = 9、14、16 m)测量的温度与高温计上设定的0.1 ~ 1.0范围内的发射率的关系。计算了高温计测得的光谱和积分辐射能量通量密度。测定了泥炭燃烧过程中观察到的亮度温度。通过求解多组分辐射、吸收和散射介质的辐射传递方程,利用作者开发的软件包计算了考虑燃料燃尽沿炉高的特定温度下凝聚相发射率的函数。实验函数和预测函数的交集给出了凝聚态粒子的发射率和真实温度。根据雷氏高温计测量,火焰根部(H = 9 m)的颗粒温度为1453 K;火焰中部(H = 14 m)为1226 K,火焰尾部(H = 16 m)为1334 K。对于开尔文高温计,这些温度分别为1471、1265和1343 K。获得的颗粒温度使我们能够评估燃料矿物部分熔化和炉渣形成的风险。
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引用次数: 0
An Analysis and Choice of the Material Embodiment of Heat Exchangers for a Thermal Oil ORC Unit (Review) 热油ORC机组换热器材料壳体的分析与选择(综述)
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-10-22 DOI: 10.1134/S0040601525700430
Yu. A. Geller, I. S. Antanenkova, M. M. Vinogradov, E. A. Gorbunova

The article presents a review of the embodiments, in terms of construction material used (or shortly material embodiments), of the main heat transfer devices, namely, a vapor generator, condenser, and regenerative heat exchanger in the case of their optimal—in the authors’ opinion—use in the design of a thermal oil ORC unit. A shell-and-tube type device was considered for implementing both the thermal oil heated vapor generator and the water cooled condenser. A semi-welded plate device was also considered as an alternative to the latter. For an air cooled condenser, the material embodiment versions of devices with finned tube and microchannel heat transfer surface, and for the regenerative heat exchanger, versions with a plate-and-finned surface were studied. The choice of the most rational heat transfer, thermal insulation, and structural materials is substantiated with due regard to the specific features of the working media used. The currently-in-force regulatory documents stipulating the material embodiment of heat exchangers with suitable process operating conditions are analyzed, and an attempt is made to put the information in a systematic order using the experience of manufacturers as a basis. It has been found that the published catalogs of industrial equipment do not contain sufficient data on the materials used, technologies for connecting heat transfer elements (tubes with the tube sheet, plates, and heat exchanger components), and working media. As regards the proposals on the choice of material embodiment, they are limited to just one or two solutions. On the contrary, the regulatory documents present more various versions of materials. In the scientific-technical literature, materials that have not been yet put in operation and have not been included in standards are considered; however, they form promising ways for the development of this area. The performed analysis of all of the above-mentioned information sources enabled us to draw up recommendations on the optimal material embodiments for each of the devices considered, which ensure compliance with the unit’s operating conditions, including the temperature ones.

本文根据所使用的建筑材料(或简称材料实施例)对主要传热装置的实施例进行了回顾,即蒸汽发生器、冷凝器和蓄热式热交换器,在作者看来,它们在热油ORC装置设计中的最佳使用情况。考虑了一种同时实现热油加热蒸汽发生器和水冷冷凝器的管壳式装置。半焊接板装置也被认为是后者的替代方案。针对风冷式冷凝器,研究了带翅片管和微通道传热面器件的材料实施形式,以及蓄热式换热器,研究了带板翅片表面器件的材料实施形式。在选择最合理的传热、隔热和结构材料时,应充分考虑所使用的工作介质的具体特点。分析了现行有效的规定热交换器材料体现形式和适宜工艺操作条件的规范性文件,并试图以制造商的经验为基础,将这些信息系统化。人们发现,已公布的工业设备目录中没有足够的数据,包括所使用的材料、连接传热元件(管与管板、板和热交换器组件)和工作介质的技术。关于选择材料实施方案的建议,仅限于一种或两种解决方案。相反,规范性文件提供的材料版本更多。在科技文献中,考虑尚未投入使用和未纳入标准的材料;然而,它们为该地区的发展形成了有希望的途径。对上述所有信息源进行的分析使我们能够就所考虑的每个设备的最佳材料实施方案提出建议,以确保符合设备的操作条件,包括温度条件。
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引用次数: 0
Russia’s New Energy Strategy Could Lead to Withdrawal from the Paris Agreement 俄罗斯新能源战略可能导致退出《巴黎协定》
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-10-22 DOI: 10.1134/S004060152570048X
V. V. Klimenko, A. V. Klimenko, A. G. Tereshin

An analysis of greenhouse gas emissions from Russian energy sector was carried out in accordance with the Energy Strategy until 2050, and they were compared with the target indicators of the Low-Carbon Development Strategy of Russia until 2050. It was shown that fundamental trends in the development of global energy—the energy transition associated with the decarbonization of the global economy—were not taken into account when developing the Energy Strategy. The actual refusal to develop renewable energy sources and the failure to use carbon dioxide capture and storage technologies make it impossible to achieve the goal of carbon neutrality for the national economy by 2060, even taking into account the new increased estimates of carbon absorption by Russian forests. Ignoring the global trend towards abandoning coal fuel, recorded by authoritative national and foreign energy agencies (the Institute for Energy Research of the Russian Academy of Sciences, the International Energy Agency), has led to inflated estimates of Russian exports of this type of fuel, the world trade of which will decrease several times by 2050. Refined estimates of methane leaks during oil and gas production in Russia correspond in specific values to the indicators of other major producers of oil and gas resources (the United States and Canada), but are approximately two times lower than those obtained from the Earth’s remote sensing data. The main provisions of the two strategic documents on Russia’s development until the middle of the century contradict each other to a certain extent and, therefore, cannot be implemented simultaneously. The result of these contradictions could be Russia’s refusal to fulfill its pledges to decarbonize the economy and its withdrawal from the Paris Agreement, which will undoubtedly exacerbate the confrontation with growing global trends.

根据《俄罗斯至2050年能源战略》对俄罗斯能源部门温室气体排放进行分析,并与《俄罗斯至2050年低碳发展战略》的目标指标进行比较。报告显示,在制定能源战略时没有考虑到全球能源发展的基本趋势- -与全球经济脱碳有关的能源转型。实际上拒绝开发可再生能源和未能使用二氧化碳捕获和储存技术,使得到2060年实现国民经济碳中和的目标不可能实现,即使考虑到俄罗斯森林碳吸收的新增加估计。无视国内外权威能源机构(俄罗斯科学院能源研究所、国际能源署)记录的全球放弃煤炭燃料的趋势,导致对俄罗斯这类燃料出口的高估,到2050年,世界贸易将减少几倍。俄罗斯石油和天然气生产过程中甲烷泄漏的精确估计值在具体数值上与其他主要石油和天然气生产国(美国和加拿大)的指标相符,但比从地球遥感数据获得的估计值低约两倍。到本世纪中叶为止,两份关于俄罗斯发展的战略文件的主要规定在一定程度上相互矛盾,因此不能同时实施。这些矛盾的结果可能是俄罗斯拒绝履行其对经济脱碳的承诺并退出《巴黎协定》,这无疑将加剧与日益增长的全球趋势的对抗。
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引用次数: 0
Control of the Bulk Condensation Rate in a Radial-Type Refrigeration Turbine Stage by Changing the Flow-Expansion Ratio 通过改变流胀比控制辐射式制冷涡轮级的冷凝速率
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-10-22 DOI: 10.1134/S0040601525700466
A. A. Sidorov, A. K. Yastrebov

The problem of deep purification of industrial gases of various impurities is urgent. The purification is usually performed using adsorption and absorption technologies, which are implemented using two-phase turbomachines with bulk condensation of the impurity in the flow path. The study is devoted to numerical simulation of the process of bulk condensation in the flow path of a radial-type refrigeration turbomachine, which is controlled by changing the flow-expansion ratio in the turbine. It is a direct continuation of the work wherein control of the process by changing the initial flow temperature was investigated. The working fluid was a mixture of air as an incondensable gas carrier and carbon dioxide as an impurity. It has been demonstrated that the process of bulk condensation proper and its depth can be controlled by changing the flow-expansion ratio. The conditions have been determined at which the process is localized predominantly in the impeller channels thereby reducing the risk of erosive wear and subsequent damage to the stage elements. For the first time, the reduction in the isentropic efficiency caused by condensation controlled by changing the flow-expansion ratio was numerically estimated for refrigeration turbomachines. The obtained data are close to the values for wet steam turbines presented in the literature. A procedure for calculating the characteristic and analyzing the results has been developed. It yields the optimal regimes using a multicriteria search with the requirements for the region where the phase transition should occur, and for the mean radius of the particles. It is shown that changing the expansion ratio may be insufficient to meet the specified requirements for the degree of condensation and isentropic efficiency offering deep purification of gases of impurities. Therefore, assessment is required as to whether the process rate can be controlled by changing the expansion ratio, the initial flow temperature, and the impeller speed.

各种杂质工业气体的深度净化问题迫在眉睫。净化通常使用吸附和吸收技术进行,这是使用两相涡轮机器实现的,杂质在流路中进行大量冷凝。本文研究了通过改变涡轮内流胀比控制的辐射式制冷涡轮机流路中凝结过程的数值模拟。这是通过改变初始流动温度来控制过程的工作的直接延续。工作流体是空气(不可冷凝气体载体)和二氧化碳(杂质)的混合物。研究表明,通过改变流胀比可以控制体积凝结的过程和深度。已经确定的条件是,该过程主要集中在叶轮通道中,从而降低侵蚀磨损的风险和随后对级元件的损坏。首次对制冷涡轮机组通过改变流胀比控制冷凝引起的等熵效率降低进行了数值估计。所得数据接近文献中湿式汽轮机的数值。提出了一种计算特性和分析结果的方法。它产生的最佳制度,使用多准则搜索的要求,在该地区的相变应该发生,并为平均半径的粒子。结果表明,改变膨胀比可能不足以满足规定的冷凝程度和等熵效率的要求,从而对含杂质气体进行深度净化。因此,需要评估是否可以通过改变膨胀比、初始流动温度和叶轮转速来控制过程速率。
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引用次数: 0
Quantification of Cooled Film Thermal Protection Using Net Heat Flux Reduction within Transonic Environments 在跨音速环境中使用净热通量减少来量化冷膜热防护
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-10-22 DOI: 10.1134/S0040601524601062
P. Ligrani, N. Knox

Considered are NHFR or net heat flux reduction data in order to illustrate and quantify turbulent thermal convection phenomena within a unique and intricate cooled film environment along the extremity end of a transonic turbine airfoil with a rim in the form of a squealer. Of particular focus are the consequences of modifying the magnitude of GAP (tip gap magnitude) which is adjacent to the outer end of the airfoil. Data are given for a variety of cooled film ratio of blowing conditions, as the coolant film is provided by two separate plenums that are connected to a row of holes which are located along the top segment of the concave surface of the blade, as well as to two dusting cooled film holes located on the end extremity of the blade. Line-averaged NHFR data show different dependence upon RoBu and RoBd ratios of blowing, depending upon the magnitude of GAP. Especially for the trailing edge portion of the squealer tip surface of the airfoil, NHFR data vary significantly with aft ratio of blowing RoBd for the 1.2 mm or smaller GAP arrangement, whereas very little variation with RoBd is present for the 2.0 mm or larger GAP environment. Here, GAP is the thickness of the flow gap at the blade tip. In addition, line-averaged NHFR data associated with the smaller GAP are often higher than values associated with the larger GAP, when compared for the same squealer surface airfoil tip locations, and at the same approximate RoBu and RoBd ratios of blowing. The flow and local static pressure variations within tip gap regions, which vary as the magnitude of GAP is changed, are less influential in regard to the data associated with the top portion of the concave surface of the two-dimensional airfoil. The impact of the present arrangements and configuration is new and unique NHFR results for different GAP values for complex boundary layer and separation flow environments, which are different from all other data which are available within the archival literature.

考虑到NHFR或净热通量减少数据,以说明和量化湍流热对流现象在一个独特的和复杂的冷却膜环境沿跨音速涡轮翼型的末端与边缘的形式尖叫。特别关注的是修改幅度的差距(尖端差距的大小),这是相邻的翼型的外端后果。给出了各种吹气条件的冷却膜比的数据,因为冷却膜是由两个独立的整流体提供的,这两个整流体连接到位于叶片凹表面顶部的一排孔,以及位于叶片末端的两个除尘冷却膜孔。线平均NHFR数据显示,根据GAP的大小,对吹气的RoBu和RoBd比率的依赖性不同。特别是对于翼型尖尖表面的后缘部分,NHFR数据在1.2毫米或更小的间隙布置下随着吹气罗比比的后比而显著变化,而在2.0毫米或更大的间隙环境下,与罗比比的变化非常小。这里,GAP是叶尖处流动间隙的厚度。此外,线平均NHFR数据相关的较小的差距往往高于与较大的差距相关的值,当比较相同的尖叫表面翼型尖端位置,并在相同的近似RoBu和RoBd吹风的比率。叶尖间隙区域内的流动和局部静压变化,随着间隙大小的变化而变化,对于与二维翼型凹表面顶部相关的数据影响较小。在复杂边界层和分离流环境下,不同GAP值的NHFR结果不同于现有文献中的所有其他数据。
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引用次数: 0
Directions of Development of Combustion Technology of Liquid Hydrocarbon Fuel in Burner Devices in the Presence of Superheated Water Vapor 液体碳氢燃料在过热水蒸气存在下燃烧器燃烧技术的发展方向
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-10-22 DOI: 10.1134/S0040601525700442
I. A. Sharina, E. P. Kopyev, L. N. Perepechko

The article presents the results of an analysis of applied and fundamental research carried out by leading global universities and companies on burner devices designed for burning liquid hydrocarbon fuels in the presence of superheated water vapor used in thermal power engineering, including those developed taking into account patent information. Directions for increasing the efficiency of burner devices and their main developers and manufacturers have been identified. On the market of liquid fuel burners used in thermal power engineering, there are universal burners designed for burning different fuels, including substandard ones. Such burners are difficult to maintain, and their operation is accompanied by loud noise and emissions of harmful substances into the atmosphere. Despite the significant shortcomings of liquid fuel burners offered on the market, steam burners are not being introduced into industry, remaining at the stage of pilot industrial samples. Improvement of burner devices is aimed at solving such problems as energy saving, reduction of emissions of harmful substances, simplicity of devices, and their versatility in the type and quality of fuel burned. Companies in the United States, Japan, China, the Republic of Korea, and Russia are conducting research and actively filing patents for burner devices, with the Kutateladze Institute of Thermophysics (Siberian Branch, Russian Academy of Sciences (IT SB RAS)) being among the top ten patent holders. Steam burners are patented for use in 25 areas of technology, primarily in the field of “thermal processes and apparatuses.” Moreover, patent-holding companies hardly sell patents for burner devices and their elements and do not provide licenses for their use but use them in their own production. The work carried out by the authors allows us to determine the level of third-party technologies in comparison with the technologies of the Kutateladze Institute of Thermophysics (Siberian Branch, Russian Academy of Sciences) and to develop recommendations for further research based on patent, scientific, and other published information.

本文介绍了全球领先的大学和公司对用于火电工程中存在过热水蒸气的液态碳氢燃料燃烧的燃烧器装置进行的应用和基础研究的分析结果,包括考虑专利信息开发的燃烧器装置。确定了提高燃烧器装置效率的方向及其主要开发商和制造商。在火电工程中使用的液体燃料燃烧器市场上,有针对不同燃料设计的通用燃烧器,也有不合格的通用燃烧器。这种燃烧器很难维护,而且它们的运行伴随着巨大的噪音和向大气中排放有害物质。尽管市场上提供的液体燃料燃烧器有明显的缺点,但蒸汽燃烧器并没有被引入工业,仍然处于试点工业样品阶段。改进燃烧器装置的目的是为了解决节能、减少有害物质排放、装置简单、燃烧燃料种类和质量多样化等问题。美国、日本、中国、韩国、俄罗斯等国的公司正在研究并积极申请燃烧器装置专利,其中库塔泰拉泽热物理研究所(俄罗斯科学院西伯利亚分院)是前十大专利持有者之一。蒸汽燃烧器在25个技术领域获得专利,主要是在“热过程和设备”领域。此外,拥有专利的公司几乎不出售燃烧器及其元件的专利,也不提供使用许可,而是在自己的生产中使用。作者开展的工作使我们能够确定第三方技术的水平,并与库塔泰拉泽热物理研究所(俄罗斯科学院西伯利亚分院)的技术进行比较,并根据专利、科学和其他公开信息制定进一步研究的建议。
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引用次数: 0
Development of a Software System for Estimating the Steam Turbine Condenser Performance 汽轮机凝汽器性能评估软件系统的开发
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-09-16 DOI: 10.1134/S0040601525700399
A. G. Shempelev, D. M. Suvorov

A software system for estimating the performance of a steam turbine condenser has been developed on the basis of its mathematical model, which takes into account the condenser interaction with the main ejector. The software system performs a number of key functions for diagnostics of condensing installations; in particular, it ranks the factors causing a growth of pressure in the condenser in comparison with its standard value in their significance and determines the decrease of electric power output resulting from deviation of each of the factors from their standard values. A distinctive feature of the developed software system is that it takes into account the interaction between the condensers and main ejectors in a wide range of steam loads and air in-leakages in the vacuum system, and the effect of this interaction on the turbine unit technical and economic indicators. It has been determined that, according to the results of the accomplished comparison between the predicted and standard data (i.e., verification), the accuracy of computation according to the mathematical models is more than sufficient for settling matters concerned with operational diagnostics of the condensing installation considered. By using the software system, one can analyze the steam turbine unit condenser performance, reveal the main factors causing degradation of its performance indicators, and make provisions for the measures on removing the revealed drawbacks and adjusting the most efficient condenser operation modes. By using the software system, it is also possible to construct the condenser standard and actual characteristics in the entire really permissible range of influencing parameters, diagnose the condenser heat transfer surface condition for any steam turbine units at combined heat and power plants (CHPPs) when specifying the necessary and sufficient input data on the design parameters of condensers and ejectors, and after carrying out the verification.

在考虑了凝汽器与主喷射器相互作用的数学模型的基础上,开发了汽轮机凝汽器性能评估软件系统。该软件系统执行冷凝装置诊断的一些关键功能;特别地,它将引起冷凝器压力增长的因素与其标准值的重要性进行排序,并确定由于每个因素偏离其标准值而导致的电力输出的减少。所开发的软件系统的一个显著特点是,它考虑了真空系统中大范围蒸汽负荷和空气泄漏情况下冷凝器和主喷射器之间的相互作用,以及这种相互作用对汽轮机组技术经济指标的影响。根据已完成的预测数据与标准数据的比较(即验证)的结果,可以确定,根据数学模型计算的准确性足以解决所考虑的冷凝装置的运行诊断问题。通过软件系统,可以对汽轮机组凝汽器性能进行分析,揭示导致凝汽器性能指标下降的主要因素,并提出消除缺点和调整凝汽器最高效运行方式的措施。通过软件系统,还可以在整个真正允许的影响参数范围内构建凝汽器的标准和实际特性,在确定凝汽器和喷射器设计参数的必要和充分的输入数据并进行验证后,诊断热电联产任一汽轮机组的凝汽器换热面状况。
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引用次数: 0
Design Calculation of a Shell-and-Tube Condenser in the ORC Unit Operating on Pentane 戊烷ORC机组壳管式冷凝器的设计计算
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-09-16 DOI: 10.1134/S0040601525700351
I. S. Antanenkova, A. A. Antanenkov, V. I. Kuznetsov, D. S. Pisarev

Units implementing the organic Rankine cycle (ORC) can utilize dozens of low-boiling substances, also called freons or refrigerants, as the working fluid. However, the classic solution for this cycle is the application of pentane and, therefore, this technology is sometimes called pentanoic. One of the main elements of the ORC unit circuit is the condenser, which is often a shell-and-tube heat exchanger cooled with circulating water. In spite of wide application of such apparatuses in steam turbine units, the elaboration of their design on the basis of the pentane technology is a challenging problem. For a prototype of this apparatuses, the KTR shell-and-tube condenser, which was previously often employed in refrigeration units with R12 refrigerant, is adopted in this work. Since chlorofluorocarbons and hydrochlorofluorocarbons have been phased out, equipment items intended for their application are also no longer manufactured by industry, which resulted in a shortage of information on their design and peculiarities of their design process. Hence, the authors carried out a search for and analysis of information about such apparatuses and developed and verified a procedure of design calculation of this equipment. In addition, models for calculating the heat-transfer coefficient during pentane condensation on tube bundles with rolled fins were reviewed, and these models were verified against experimental data on the condensation of propane, one of the closest homologues of pentane. The model proposed by A. Briggs and J.W. Rose has been found to yield the highest accuracy in engineering calculations of pentane condensers. Other models are also examined, which describe the effects of vapor shear and inundation of the lower tubes in the bundle on the heat-transfer coefficient during pentane condensation. It has been demonstrated that considering these effects during condensation of pentane and its homologues in the examined apparatus is impractical. The results of the design calculation of shell-and-tube condensers of pentane with a capacity of 173- and 2280-kW are presented. Recommendations for further optimization calculations are formulated.

实施有机朗肯循环(ORC)的装置可以利用几十种低沸点物质,也称为氟利昂或制冷剂,作为工作流体。然而,这种循环的经典解决方案是应用戊烷,因此,这种技术有时被称为戊烷。ORC机组回路的主要元件之一是冷凝器,它通常是一个壳管式热交换器,用循环水冷却。尽管这些装置在汽轮机组中得到了广泛的应用,但基于戊烷技术对其进行详细的设计是一个具有挑战性的问题。对于该装置的原型,本工作采用了以前常用于R12制冷剂制冷机组的KTR壳管式冷凝器。由于氯氟烃和氢氯氟烃已被逐步淘汰,工业也不再生产用于这两种化合物的设备项目,这导致缺乏关于其设计及其设计过程特点的信息。因此,作者对这种设备的资料进行了查找和分析,并制定和验证了该设备的设计计算程序。此外,综述了戊烷在带卷翅片的管束上缩聚的传热系数计算模型,并与戊烷最接近的同系物之一丙烷的缩聚实验数据进行了验证。布里格斯(A. Briggs)和罗斯(J.W. Rose)提出的模型在戊烷冷凝器的工程计算中具有最高的精度。本文还研究了其他模型,这些模型描述了在戊烷冷凝过程中蒸汽剪切和下层管的淹没对传热系数的影响。它已经证明,考虑这些影响在缩合戊烷及其同系物在检查装置是不切实际的。介绍了容量分别为173和2280kw的戊烷管壳式冷凝器的设计计算结果。提出了进一步优化计算的建议。
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引用次数: 0
An Analysis of Possible Mechanisms of Lead Oxide Vapor Formation in the Vapor Bubble Volume 汽泡体积中氧化铅蒸汽形成的可能机理分析
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-09-16 DOI: 10.1134/S0040601525700429
M. V. Vorivonchik, N. A. Mosunova, A. A. Sorokin

A kinetic model is presented describing the formation of lead oxide vapor in the volume of a vapor bubble in the lead melt with its subsequent dissolution in the lead melt and crystallization in the bubble. The model is implemented in the approximation of homogeneous distribution of reagents and oxidation reaction products in the bubble volume. It is shown that vapor bubbles in the lead melt volume may be considered as chemical “microreactors” producing lead oxide vapor and nanoparticles in the bubble volume. The paper presents the results of calculation by a homogeneous model of the lead oxide vapor concentration in the bubble volume as a function of time and of the conditions for the possible formation of a soluble oxide shell on the bubble surface. The model includes mechanisms controlling lead evaporation and oxidation of lead vapor as it interacts with water vapor in the bubble volume and crystallization of lead vapor on the bubble inside surface with formation of a solid phase shell. Partial transformation of vapor bubbles into gas–vapor bubbles with an oxide shell could potentially affect their further behavior in the lead coolant. However, subsequent transport of the bubbles in the coolant circuit will lead to the dissolution of the oxide shell in the sections with the coolant at a higher temperature that will neutralize this negative effect. Moreover, formation of an oxide shell around the vapor bubbles can cause temporary trapping of hydrogen in the bubble volume.

本文提出了一个动力学模型,描述了铅熔体汽泡体积中氧化铅蒸汽的形成及其随后在铅熔体中的溶解和气泡中的结晶过程。该模型的实现近似于气泡体积中试剂和氧化反应产物的均匀分布。结果表明,铅熔体中的汽泡可视为化学“微反应器”,在汽泡体中产生氧化铅蒸汽和纳米颗粒。本文给出了用均匀模型计算气泡体积中氧化铅蒸气浓度随时间和气泡表面可能形成可溶氧化壳条件的函数的结果。该模型包括控制铅蒸发和铅蒸气氧化的机制,因为铅蒸气与气泡体积中的水蒸气相互作用,铅蒸气在气泡内表面结晶并形成固相壳。汽泡部分转化为带有氧化壳的气-汽泡可能会影响其在铅冷却剂中的进一步行为。然而,随后在冷却剂回路中输送的气泡将导致冷却剂在更高温度下溶解部分中的氧化壳,从而抵消这种负面影响。此外,在蒸汽气泡周围形成氧化壳会导致氢在气泡体积中暂时被捕获。
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引用次数: 0
Selective Noncatalytic NOx Reduction System at MSW Energy Waste Recycling Plants in Moscow Oblast: Justification of Decisions Made 莫斯科州城市生活垃圾能源废物回收厂的选择性非催化NOx还原系统:所作决定的合理性
IF 1 Q4 ENERGY & FUELS Pub Date : 2025-09-16 DOI: 10.1134/S0040601525700363
V. S. Kireenko, A. N. Tugov, V. A. Bezrukov

Due to the continuous growth of municipal solid waste (MSW) volumes, their disposal with minimal negative impact on the environment is becoming a very urgent task. Thermal recycling of MSW is one of the most effective methods of their disposal because it allows not only to significantly reduce the volume of waste but also to obtain thermal and electrical energy. However, this process is accompanied by the formation of nitrogen oxides (NOx), which contribute to the formation of smog and acid rain and negatively affect the environmental situation and public health. Therefore, the reduction of NOx emissions is an important task for enterprises burning MSW with the release of electricity and heat to consumers. The article discusses selective noncatalytic reduction (SNCR) technologies used to reduce NOx emissions at factories in Moscow oblast. The rationale for key technical decisions is presented, including the choice of reducing agent (urea), transport agent (air), and the reagent-injection system through nozzles arranged in three tiers. The results of calculations of the trajectories of the urea–air mixture jets in the cross-flow of flue gases are presented, confirming the effectiveness of the proposed configuration of the reducing agent supply system. It is shown that the use of air as a transporting agent in combination with the adopted nozzle placement scheme ensures uniform distribution of the reagent in the high-temperature zone, which increases the efficiency of NOx reduction. The obtained results of the calculation studies can be used for further optimization of the SNCR system operation as well as for conducting operational tests at facilities engaged in MSW utilization.

随着城市生活垃圾(MSW)数量的不断增长,如何将其对环境的负面影响降到最低已成为一项非常紧迫的任务。都市固体废物的热回收是其中一种最有效的处置方法,因为它不仅可以大大减少废物的体积,而且还可以获得热能和电能。然而,这一过程伴随着氮氧化物(NOx)的形成,氮氧化物有助于烟雾和酸雨的形成,对环境状况和公众健康产生负面影响。因此,减少氮氧化物排放是城市生活垃圾焚烧企业的一项重要任务,并向消费者释放电力和热量。本文讨论了选择性非催化还原(SNCR)技术用于减少莫斯科州工厂的氮氧化物排放。介绍了关键技术决策的基本原理,包括还原剂(尿素)、运输剂(空气)的选择,以及通过三层喷嘴的试剂注入系统。本文给出了烟气横流中尿素-空气混合射流轨迹的计算结果,证实了所提出的还原剂供给系统配置的有效性。结果表明,采用空气作为输送剂,配合所采用的喷嘴布置方案,保证了试剂在高温区分布均匀,提高了NOx还原效率。计算研究的结果可用于进一步优化SNCR系统的运行,以及在从事城市固体废物利用的设施进行运行试验。
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引用次数: 0
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Thermal Engineering
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