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Use of Micro- and Nanocoating in the Evaporator to Enhance Heat Transfer in a Thermosiphon 微纳米涂层在蒸发器中的应用以增强热虹吸的传热
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525600683
N. S. Ivanov, Yu. A. Kuzma-Kichta, M. M. Alyautdinova

Experimental data on the thermal resistance of thermosiphons designed with different structural junctions (“pipe in pipe,” “flat shelve”) are obtained, and the possibility is shown to decrease it as a result of heat transfer enhancement in the evaporator by using a combined coating in the form of longitudinal grooves 0.1 mm in radius, filled with aluminum oxide nanoparticles 100–200 nm in size. The effect the coating has on the thermosiphon thermal resistance was studied in an experimental section in the form of a 100 mm long pipe 38 × 3 mm in diameter made of grade AISI304 stainless steel. As a result of applying the coating, the thermosiphon thermal resistance is decreased by 2.4–3.0 times at heat fluxes in the range 200–1700 W/m2 and evaporator slope angles 0°–30°. Experiments with slope angles equal to 0°, 10°, and 20° were carried out, and it is pointed out that the maximal effect is reached at the evaporator horizontal and slightly inclined positions. For calculating the heat transfer in a thermosiphon, a procedure based on the Yu.A. Kuzma-Kichta formula is proposed. The predicted thermosiphon thermal resistance values agree with the experimental data within 20%, a circumstance that extends the model applicability area.

获得了不同结构结(“管中管”、“平架”)设计的热虹吸管的热阻实验数据,并通过在直径为0.1 mm的纵向凹槽中填充100-200 nm大小的氧化铝纳米颗粒的组合涂层来增强蒸发器内的传热,从而降低热阻的可能性。在AISI304不锈钢直径为38 × 3mm、长100mm管的实验截面上,研究了涂层对热虹吸热阻的影响。在热流密度为200 ~ 1700 W/m2,蒸发器坡角为0°~ 30°范围内,涂覆涂层使热虹吸热阻降低了2.4 ~ 3.0倍。在0°、10°和20°的倾斜角度下进行了试验,并指出在水平和微倾斜位置蒸发器达到最大效果。为了计算热虹吸的传热,本文给出了一种基于u - a的计算方法。提出了Kuzma-Kichta公式。预测的热虹吸热阻值与实验数据的吻合度在20%以内,扩大了模型的适用范围。
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引用次数: 0
Erratum to: Study of Heating and Evaporation of Rotating Graphene Nanofluid under the Influence of Solar Radiation 在太阳辐射影响下旋转石墨烯纳米流体加热和蒸发的研究
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525190012
K. T. Chan, A. S. Dmitriev, I. A. Mikhailova, P. G. Makarov
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引用次数: 0
An Analysis of the Key Serviceability and Efficiency Conditions of Loop Heat Pipes 循环热管关键使用性能和效率条件分析
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700661
M. A. Chernysheva, Yu. F. Maydanik

Loop heat pipes (LHPs) are two-phase heat transfer devices with capillary pumping of the working fluid inside a sealed, closed loop, including an evaporator and a condenser connected by smooth-walled pipelines for separate movement of vapor and liquid, the diameter of which usually varies from 2 to 8 mm. This design feature enables easy integration of LHPs into densely packed systems. The LHP evaporator is equipped with a fine-pored capillary structure (wick) (pore radius from 1 to 20 μm), which creates high capillary pressure. Loop heat pipes are used in energy-efficient systems for utilizing low-potential heat, heating or cooling remote objects, and for uniform heat distribution over a large surface area of ​​heat sinks. Currently, the most popular area of ​​application for LHPs is electronic cooling systems operating under a wide variety of conditions. Various liquids can be used as working fluids in LHPs, depending on their operating temperature range, chemical compatibility with structural elements, and the required operating characteristics of the LHPs. This paper presents the theoretical foundations and operational conditions for LHPs. It also discusses the issue of selecting a working fluid to enhance the heat transfer capacity of LHPs. Quality criteria are proposed for assessing working fluids based on their efficiency in these devices. The results of a comparison of six different working fluids using these criteria are presented, showing that ammonia is the most effective working fluid in the operating temperature range relevant for electronics, from 40 to 70°C. Based on the p, t diagram of the working cycle of the working fluid, the thermal resistance of the “heat source–LHP–heat sink” system is visualized, as well as the thermal resistance of the main structural elements.

循环热管(LHPs)是两相传热装置,在密封的闭环内毛细管泵送工作流体,包括蒸发器和冷凝器,由光滑壁管道连接,用于蒸汽和液体的分离运动,其直径通常从2到8毫米不等。这种设计特点使lhp易于集成到密集的系统中。LHP蒸发器具有细孔毛细管结构(芯)(孔半径为1 ~ 20 μm),可产生较高的毛细管压力。循环热管用于节能系统中,用于利用低潜热,加热或冷却远程物体,以及在散热器的大表面积上均匀分配热量。目前,lhp最受欢迎的应用领域是在各种条件下运行的电子冷却系统。根据液体的工作温度范围、与结构元素的化学相容性以及lhp所需的工作特性,可以使用各种液体作为lhp的工作流体。本文介绍了lhp的理论基础和运行条件。讨论了如何选择工质来提高液压泵的换热能力。提出了根据这些装置中工质的效率来评估工质的质量标准。使用这些标准对六种不同的工作流体进行了比较,结果表明,在与电子相关的工作温度范围内,从40°C到70°C,氨是最有效的工作流体。基于工质工作循环的p、t图,可视化了“热源- lhp -散热器”系统的热阻,以及主要结构元件的热阻。
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引用次数: 0
Gas Hydrate Energy Technologies: Problems and Achievements 天然气水合物能源技术:问题与成就
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700636
P. A. Strizhak, S. V. Alekseenko, A. Yu. Manakov, E. R. Podgornaya, M. V. Shkola, N. E. Shlegel’

The article summarizes the key scientific and technological achievements in the field of applying gas hydrates in the power industry. The modern ideas about the specific features relating to the synthesis, transportation, storage, regasification, and use of hydrates for thermal conversion of low-grade fuels and waste, separation of gaseous and liquid media, as well as sequestration of anthropogenic emissions are analyzed. It is shown that the experimental data and the results of mathematical modeling and various-scale tests that have been obtained for the last years in the world’s scientific society form a basis for the development of technologies for applying natural and man-made hydrates. Concepts for integrated use of hydrates in the power systems at mines and in supply of energy resources to settlements are outlined. The technical and economic constraints connected with the development of gas hydrate technologies, their target indicators, and potential solutions of the formulated problems are determined. For the gas hydrate technologies to be efficiently introduced in the energy sector, the following so-called target business metrics (threshold indicators) should be achieved: gas content is no less than 180 vol/vol.;1 purification ratio of gas obtained after separation of smoke, natural, casing-head, and synthesized gases is no less than 90%; maximal loss of gas in storing and transporting hydrates is not more than 0.1%; hydrate storage term is up to six months; stable combustion temperature during joint low-emission combustion of hydrates with low-grade fuels (sludges, heavy coal-tar products, cakes, etc.) is not lower than 1100°С. For solving these problems, it is necessary to carry out fundamental and applied studies, as well as various-scale tests for integrating gas hydrates into modern power systems with ensuring environmental cleanliness and economic efficiency. The conditions under which essential advantages are achieved in comparison with alternative technologies in each hydrate application area have been determined.

本文综述了天然气水合物在电力工业应用领域的关键科技成果。分析了水合物的合成、运输、储存、再气化、用于低品位燃料和废物的热转化、气体和液体介质的分离以及人为排放的封存等具体特征的现代观点。研究表明,世界科学界多年来获得的实验数据和数学建模及各种规模试验的结果,为开发应用天然和人造水合物的技术奠定了基础。概述了在矿井电力系统和向住区供应能源方面综合利用水合物的概念。确定了与天然气水合物技术发展有关的技术和经济制约因素、其目标指标和拟定问题的潜在解决办法。为了在能源部门有效地引进天然气水合物技术,应达到以下所谓的目标业务指标(阈值指标):气体含量不低于180 vol/vol;1烟气、天然气、套管气、合成气分离后所得气体的净化比不小于90%;水合物储运过程中最大气体损失不大于0.1%;水合物储存期长达6个月;水合物与低品位燃料(污泥、重质煤焦油制品、油饼等)联合低排放燃烧时的稳定燃烧温度不低于1100°С。为了解决这些问题,有必要开展基础研究和应用研究,并进行各种规模的试验,以确保天然气水合物与现代电力系统的清洁和经济效益。已经确定了在每个水合物应用领域与替代技术相比取得本质优势的条件。
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引用次数: 0
Experimental Study of Salt Melt Heat Transfer in a Vertical Round Channel in Transition and Turbulent Flow Regimes 转捩和湍流条件下垂直圆形通道内盐液换热的实验研究
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700648
A. G. Khizhnyak, S. V. Khomyakov, I. S. Belousov, N. A. Solov’ev

The article presents the results of experimental studies aimed at determining the dimensionless heat transfer coefficient (the Nusselt criterion) in a round tube during forced upward motion of salt melt. The relevance of this problem is substantiated by the presented review of literature sources, which has shown that there is an insufficient scope of experimental data on heat transfer for the flow of salt melts against the gravitation forces in laminar ant transition regimes in the temperature range 230–350°C. The experiments were carried out in transition and turbulent flow regimes in the range of Reynolds numbers 2600–23 000 with the applied heat fluxes 70–670 kW/m2 and Prandtl numbers 8.9–14.7. A melt of 50% NaNO3–50% KNO3 (in molar fractions) salt was used as working medium. The experimental values of heat transfer coefficients are in good agreement with the data obtained using the well-known relationships, such as the correlations proposed by Petukhov–Kirillov, Sieder–Tate, Gnielinsky, and Hausen. Based on the authors’ own data and an analysis of existing correlations, a new empirical formula is proposed for calculating the Nusselt number in the range of Reynolds numbers from 4000 to 10 000. For the developed turbulent flow regime, the Hausen correlation has shown the best agreement with the experimental values: the maximal mismatch does not exceed 7%, due to which this correlation can be recommended for carrying out calculations in the studied ranges of the parameters.

本文介绍了在圆管中确定盐熔体被迫向上运动时的无因次换热系数(努塞尔准则)的实验研究结果。这一问题的相关性得到了文献来源的证实,文献来源表明,在温度范围为230-350°C的层流过渡状态下,盐熔体在重力作用下流动的传热实验数据范围不够。实验在雷诺数为2600 ~ 23000的转捩流态和湍流流态下进行,热流通量为70 ~ 670 kW/m2,普朗特数为8.9 ~ 14.7。采用50% NaNO3-50% KNO3(摩尔分数)盐的熔体作为工作介质。换热系数的实验值与利用Petukhov-Kirillov、siider - tate、Gnielinsky和Hausen等人提出的关系式得到的数据吻合得很好。根据作者自己的数据和对已有相关性的分析,提出了一个新的计算4000 ~ 10000雷诺数范围内努塞尔数的经验公式。对于已发展的湍流流态,Hausen相关性与实验值吻合最好:最大失配不超过7%,因此可以推荐该相关性在所研究的参数范围内进行计算。
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引用次数: 0
The Influence of Temperature Conditions at the Metallic Melt Layer Boundaries on the Heat Flux Focusing in a Stratified Molten Corium Pool during a Severe Accident in Nuclear Power Facilities 核设施重大事故中金属熔层边界温度条件对分层熔池热流聚焦的影响
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700612
V. D. Loktionov, Ya. A. Gorbunova, E. S. Mukhtarov

The article presents an analysis of the effect the aspect number A (the ratio of the melt layer height to the reactor pressure vessel inner diameter) and the temperature conditions at the boundaries of the cylindrical steel melt layer heated at its lower surface have on the heat flux focusing on its lateral surface. Such layer corresponds to the metallic layer in the stratified corium melt pool that is produced in the nuclear reactor pressure vessel during a severe accident, and the heat flux of which affects the pressure vessel, causing its heating and partial melting. The pressure vessel ability to retain high-temperature melt inside of it in the course of a severe accident in using external cooling of the vessel depends on the heat fluxes acting on it from the high-temperature corium side. If the metallic melt is stratified, a heat flux focusing effect emerges in the area of melt upper layer, which determines the most dangerous and thermally stressed place, the heat flux in which may exceed 1.5 MW/m2. The possibility to promptly and adequately estimate the influence of heat fluxes on the reactor pressure vessel is an important objective in elaborating severe accident management measures. The article proposes a procedure for determining the heat flux focusing factor on the steel melt layer lateral surface, which is based on applying the previously obtained modified formulas for calculating the Nusselt number and the melt layer bulk temperature. The newly developed procedure was used to perform a parametric analysis of the influence of the layer geometrical parameters and the temperature conditions at its boundary surfaces on the focusing effect. The analysis results have shown that the heat flux focusing effect depends on the temperature conditions at the layer boundaries and on the layer thickness. Thus, variations of differences between the temperatures of layer lower and upper surfaces, and also between the temperatures of its lateral and lower surfaces may entail a several-time increase/decrease of heat flux intensities acting at the melt layer surface and on the reactor pressure vessel during a severe accident. The heat flux focusing factor depends most essentially on the temperature conditions at the layer boundaries at the aspect ratio A values not larger than 0.4, which should be taken into account in elaborating severe accident management strategies. In the subsequent, it is worthwhile to perform experimental studies to confirm the validity of the newly developed procedure for determining the heat flux focusing effect in the relevant scenarios and under real severe accident progression conditions, as well as with model media (melts) having properties close to those of the materials forming the corium melt bath in nuclear power facilities during accidents of a similar class.

本文分析了在圆柱形钢熔体层下表面受热的截面数A(熔体层高度与反应堆压力容器内径之比)和其边界温度条件对集中在其侧面的热流密度的影响。该层对应于核反应堆压力容器在严重事故中产生的层状堆芯熔池中的金属层,其热流通量影响压力容器,导致压力容器加热和部分熔化。在使用外部冷却的压力容器发生严重事故时,压力容器内部保持高温熔体的能力取决于从高温堆芯一侧作用在其上的热流。如果金属熔体分层,在熔体上层区域出现热流密度聚焦效应,确定了最危险和热应力最大的区域,其热流密度可能超过1.5 MW/m2。能否及时、充分地估计热流对反应堆压力容器的影响,是制定严重事故管理措施的一个重要目标。本文提出了一种计算钢熔体层侧表面热流聚焦系数的方法,该方法是在应用先前得到的修正的努塞尔数和熔体层体温度计算公式的基础上确定的。利用新开发的程序对层的几何参数及其边界温度条件对聚焦效果的影响进行了参数化分析。分析结果表明,热流密度聚焦效应与层边界温度条件和层厚度有关。因此,在一次严重事故中,熔体层表面和反应堆压力容器表面的热流密度的变化可能导致熔体层表面和反应堆压力容器表面热流密度的几次增加/减少。热流聚焦系数主要取决于长径比A不大于0.4时层边界处的温度状况,在制定严重事故管理策略时应考虑到这一点。接下来,有必要进行实验研究,以确认新开发的程序在相关情景和实际严重事故进展条件下确定热通量聚焦效应的有效性,以及在类似级别事故中与核电设施中形成堆芯熔池的材料性质接近的模型介质(熔体)的有效性。
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引用次数: 0
Numerical Simulation of Hydrodynamic Effects of Internal Structural Parameters in a Steam-Water Mixing Heater 蒸汽-水混合加热器内部结构参数对水动力影响的数值模拟
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601524600974
Xuebing Zhu, Zhaoying Xu, Jiangtao Zhang, Deqing Liu, Haiyan Li, Jinlei Wang, Bin Zheng

Steam-water injectors are widely utilized in various industrial applications and production processes, particularly for their ability to enhance energy efficiency, reduce emissions, lower energy consumption, and facilitate energy reuse. In this study, computational fluid dynamics (CFD) is employed to investigate the impact of internal geometric parameters on the performance of steam injectors. Key internal flow characteristics are analyzed, focusing on the effects of the orifice injection angle, dilatation inclination, throat size, and the presence of a porous medium within the mixing chamber. The results reveal that an injection angle of 45°, a dilatation inclination between 0.9° and 1.1°, and a throat diameter of 14–16 mm significantly enhance steam-water phase mixing, leading to superior heat exchange efficiency. While including a porous medium does not improve heating performance, it substantially reduces noise levels within the system. By optimizing the full set of internal geometric parameters, the study demonstrates a marked improvement in the injector’s entrainment capacity. These findings provide a valuable reference for the continued research, development, and optimization of steam–water mixing heaters, offering practical insights for enhancing performance in industrial applications.

蒸汽水喷射器广泛应用于各种工业应用和生产过程,特别是因为它们具有提高能源效率、减少排放、降低能耗和促进能源再利用的能力。本文采用计算流体力学(CFD)方法研究了内部几何参数对注汽器性能的影响。分析了关键的内部流动特性,重点分析了孔喷射角、扩张倾角、喉道尺寸和混合室内多孔介质存在的影响。结果表明:当注入角为45°、膨胀倾角为0.9°~ 1.1°、喉道直径为14 ~ 16 mm时,蒸汽-水相混合明显增强,换热效率较高;虽然包括多孔介质并不能改善加热性能,但它大大降低了系统内的噪音水平。通过优化全套内部几何参数,研究表明,注入器的携射能力有了显著提高。这些发现为蒸汽-水混合加热器的进一步研究、开发和优化提供了有价值的参考,为提高蒸汽-水混合加热器在工业应用中的性能提供了实用的见解。
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引用次数: 0
Simulation of R-245fa Vapor Condensation in an Inclined Tube Using the VOF Method in Conjugate Problem Statement 用共轭问题表述的VOF法模拟R-245fa蒸汽在倾斜管内的凝结
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700624
G. G. Yan’kov, V. I. Artemov, A. P. Zheleznov, O. O. Mil’man, K. B. Minko

For designing facilities operating on organic working fluid according to the Rankine cycle, reliable methods for calculating organic coolant condensation processes in channels, including inclined ones, are required. In this regard, the problem of special importance is to determine condensation heat transfer in the cases when the heat transfer intensity on the coolant side is commensurable with that on the condensation side. The article describes the results of the activity aimed at studying the condensation of R-245fa (considered as a promising coolant) in horizontal and inclined tubes using the Volume of Fluid (VOF) method. By using this method, supplemented with the model of heat and mass transfer at the phase interface, one can visualize the flow structure and obtain data on the local heat transfer characteristics. The prediction results are compared with the experimental data obtained on the experimental setup at the CJSC Turbokon, intended for studying heat and mass transfer processes during condensation of various promising working media. The predicted data have been compared with the experimental data obtained in condensation regimes in a 2 m long copper tube 32 × 2 mm in diameter at mass fluxes up to 27 kg/(m2 s) and tube inclination angles up to ‒24.3°. For simulating the processes at the phase interface, the Lee model was used with automatically calculating the relaxation constant based on the working fluid properties and computation mesh parameters. All calculations were carried out using the in-house CFD code ANES. The article presents data on the distribution of heat transfer coefficients along the tube inner surface. The prediction results are in good agreement with the experimental data, which have shown that the heat transfer coefficient increases significantly even at a small tube inclination. The accomplished study helps gain deeper insight into the condensation heat transfer processes in horizontal and inclined tubes, which is of importance for designing heat transfer apparatuses, such as air and water cooled condensers of the vapors of refrigerants, petroleum products, and other chemical substances. The obtained results can be used for improving the accuracy of engineering calculations and elaborating new design solutions for condensers with taking into account local flow features.

为了设计按朗肯循环运行的有机工质设施,需要可靠的方法来计算有机冷却剂在通道(包括倾斜通道)中的冷凝过程。在这方面,特别重要的问题是在冷却剂侧的换热强度与冷凝侧的换热强度相当的情况下确定冷凝换热。本文介绍了利用流体体积(VOF)方法研究R-245fa(被认为是一种有前途的冷却剂)在水平和倾斜管中的冷凝的活动结果。利用该方法,结合相界面传热传质模型,可以可视化流动结构,获得局部传热特性数据。预测结果与在CJSC Turbokon实验装置上获得的实验数据进行了比较,该实验装置用于研究各种有前途的工质在冷凝过程中的传热传质过程。在质量通量为27 kg/(m2 s)、管道倾角为-24.3°的情况下,在直径为32 × 2mm的2 m长铜管中获得的冷凝实验数据与预测数据进行了比较。为了模拟相界面上的过程,采用Lee模型,根据工作流体性质和计算网格参数自动计算松弛常数。所有计算均使用内部CFD代码ANES进行。本文给出了沿管内表面传热系数分布的数据。预测结果与实验数据吻合较好,实验结果表明,当管倾角较小时,换热系数也显著增大。完成的研究有助于更深入地了解水平管和倾斜管中的冷凝换热过程,这对于设计制冷剂蒸气、石油产品和其他化学物质的空气和水冷式冷凝器等换热设备具有重要意义。所得结果可用于提高工程计算的精度,并为考虑局部流动特征的冷凝器设计提供新的解决方案。
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引用次数: 0
Simulation of Thermohydrodynamic Processes during an SBO Accident with the Externally Cooled Vessel of a VVER-I Integral Small Modular Reactor vver - 1整体式小型模块化反应堆外冷容器SBO事故热流体动力学过程模拟
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700600
M. M. Bedretdinov, O. E. Stepanov, N. V. Ivanova, M. A. Bykov

The development of small modular reactors (SMRs) attracts increasingly growing interest both in Russia and abroad in connection with the trend toward decreasing of greenhouse gas emissions and diversification of energy sources. Small nuclear power plants (SNPPs) could occupy their niche in the field of electricity production in remote regions, in which there is no demand for large power capacity. It is exactly for this reason that great attention is presently paid to the development of SMRs and SNPPs as a whole. Given that there is no demand for large capacity NPPs, and with more stringent requirements for safety systems based on fully passive principles of their operation, and also in view of the fact that there has been no assessment of decreasing the prime cost of electricity in putting the SNPP equipment in mass scale manufacture, the problem of their development is becoming increasingly more relevant. The article presents the results of calculations of thermohydrodynamic processes in the new integral modular small capacity reactor plant (RP) with natural coolant circulation called VVER-I as applied to a beyond design basis accident involving the power unit long-term blackout. For the VVER-I RP, all safety systems relating to defense-in-depth levels two and three are based on the passive principle of their operation, also with the use of natural circulation, without the need of power supply and operator’s intervention for quite a long period of time. The calculations were carried out using the KORSAR/GP computer code certified for analyzing the safety of NPPs with VVERs. The possibility of reliable decay heat removal from the core in the natural circulation mode with the reactor pressure vessel externally cooled with water has been confirmed. The passive safety systems incorporated in the design ensure reliable heat removal from the core under the conditions of all NPP power supply sources lost for a long period of time without intervention of the operational personnel. The study results can be used in elaborating new designs of VVER type RPs with natural coolant circulation, including those with passive safety systems.

随着温室气体排放的减少和能源多样化的趋势,小型模块化反应堆(SMRs)的发展在俄罗斯国内外引起了越来越大的兴趣。小型核电站(SNPPs)可以在没有大容量电力需求的偏远地区的电力生产领域占据一席之地。正是由于这个原因,目前人们对smr和snp的整体发展给予了极大的关注。鉴于没有对大容量核电站的需求,以及对基于完全被动运行原则的安全系统的更严格要求,也考虑到在大规模生产SNPP设备时没有对降低主要电力成本的评估,它们的发展问题变得越来越重要。本文介绍了采用自然冷却剂循环的新型整合式模块化小容量反应堆(RP) (VVER-I)热流动力过程的计算结果,并将其应用于一起涉及机组长期停电的超出设计基础的事故。对于VVER-I型RP来说,所有与纵深防御二级和三级相关的安全系统都是基于被动原理运行的,同样是利用自然循环,不需要电源和操作员的干预相当长一段时间。计算采用经认证的KORSAR/GP计算机代码进行,用于分析具有vver的核电站的安全性。在反应堆压力容器外部用水冷却的自然循环模式下,可靠地从堆芯排出衰变热的可能性已经得到证实。设计中包含的被动安全系统确保在所有核电站电源长时间丢失的情况下,在没有操作人员干预的情况下,可靠地从堆芯排出热量。研究结果可用于设计具有自然冷却剂循环的VVER型RPs,包括具有被动安全系统的RPs。
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引用次数: 0
Corrosion Product Generation Processes in the Circuits of Nuclear Power Facilities 核电设施回路中腐蚀产物的产生过程
IF 1 Q4 ENERGY & FUELS Pub Date : 2026-01-27 DOI: 10.1134/S0040601525700673
B. A. Gusev, L. N. Moskvin, A. A. Efimov, S. V. Blinov, A. N. Maksimova

The problem of improving the corrosion conditions during operation of a nuclear power facility (NPF) is directly connected with increasing the corrosion resistance of structural steels to general (uniform) corrosion, chemical transformation and mass transfer of corrosion products in water coolant in conducting different water chemistry (WC) versions. The article gives a description of the generation processes and chemical transformations of the initial ionic forms of structural steel corrosion products at the initial stage of the general corrosion process followed by the generation of the precursors of solid phase oxide-hydroxide particles (sludge and crud) dispersed in coolant and generation of final solid phase forms of corrosion products such as suspensions, deposits, and corrosion oxide films in the nuclear power facility circuits under the conditions of reduction and oxidative water chemistries. The article proposes a physicochemical model of mass exchange and mass transfer of corrosion products in the steel–water coolant system with taking into account the chemical transformations of corrosion product ionic forms up to the generation of solid phase products in water coolant and on the corroding steel surface, on which a two-layer (with topotaxic and epitaxic layers) oxide film of a local origin is produced. On this film, dense corrosion product deposits from the coolant are formed along with loose (dissipative, weakly fixed) corrosion product deposits that are in equilibrium between the circuit surfaces and coolant. The chemical composition of all product existence forms is determined by the compounds of iron with admixtures of structural steel alloying elements, and the radionuclide composition is determined by the activation products of reactor materials (58Co, 60Co, 54Mn, 59Fe, and 51Cr) and other, more short-lived radionuclides. The proposed body of mathematics can be used for determining the numerical values of the indicators characterizing different corrosion process stages – from metal ionization to generation of final corrosion products on the surfaces and in the coolant of the nuclear power facility circuits under the conditions of different water chemistries.

改善核电设施运行过程中腐蚀条件的问题,直接关系到提高结构钢的抗一般(均匀)腐蚀能力、水冷剂中腐蚀产物的化学转化和传质能力。本文描述了在一般腐蚀过程的初始阶段,钢结构腐蚀产物的初始离子形式的生成过程和化学转化,随后是分散在冷却剂中的固相氧化氢氧化物颗粒(污泥和污垢)前体的生成,以及腐蚀产物的最终固相形式的生成,如悬浮液、沉积物、并腐蚀氧化膜在核电设施回路条件下的还原和氧化水化学反应。本文提出了钢-水冷却剂系统中腐蚀产物的质量交换和传质的物理化学模型,考虑了腐蚀产物离子形态的化学转变,直到水冷剂中固相产物的产生和腐蚀钢表面上的腐蚀产物,在腐蚀钢表面上产生了一层本地来源的两层(具有拓扑层和外延层)氧化膜。在这层膜上,来自冷却剂的致密腐蚀产物沉积与松散的(耗散的、弱固定的)腐蚀产物沉积一起形成,这些腐蚀产物沉积在电路表面和冷却剂之间处于平衡状态。所有产品存在形式的化学组成是由铁与结构钢合金元素外加剂的化合物决定的,放射性核素组成是由反应堆材料(58Co、60Co、54Mn、59Fe和51Cr)和其他寿命较短的放射性核素的活化产物决定的。所提出的数学体系可用于确定表征不同腐蚀过程阶段的指标的数值-从金属电离到在不同水化学条件下在核电设施回路表面和冷却剂中产生最终腐蚀产物。
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Thermal Engineering
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