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Assessment of the Potential for Decarbonization of the Russian Thermal Power Industry Based on Bat Implementation 基于蝙蝠计划实施情况的俄罗斯火电行业脱碳潜力评估
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S004060152470040X
P. V. Roslyakov, A. V. Sergeeva, T. V. Guseva, V. V. Rudomazin

Thermal energy is one of the main sources of anthropogenic greenhouse gas emissions. To fulfill Russia’s obligations to reduce greenhouse gas emissions under the Paris Climate Agreement, it is planned to focus in the energy sector on the development and implementation of cleaner technologies for the use of energy fuels, hydrogen and hydrogen-containing mixtures, the decommissioning of obsolete equipment, and the accelerated introduction of new efficient energy plants. As part of the study, an assessment was made of the real possibilities of decarbonization of the Russian heat and power industry through the implementation of priority measures provided for in the Strategy for the Socio-Economic Development of Russia with Low Greenhouse Gas Emissions until 2050. For this purpose, a comparison was made of the carbon intensity of various technologies for generating electrical and thermal energy, taking into account the type of thermal power engineering enterprises and the efficiency of power steam turbine, gas turbine, and combined-cycle gas plants burning various types of fuel. Possibilities for reducing CO2 emissions were assessed due to improving the quality of solid fuel, the transition from burning coal to burning natural gas, the introduction of combined-cycle gas plants, increasing the efficiency of power plants, decommissioning obsolete equipment, and the use of hydrogen-containing gases and pure hydrogen as fuel.

热能是人为温室气体排放的主要来源之一。为履行《巴黎气候协定》规定的俄罗斯减少温室气体排放的义务,计划在能源领域重点开发和实施使用能源燃料、氢气和含氢混合物的清洁技术,淘汰陈旧设备,加快引进新型高效能源工厂。作为研究的一部分,通过实施《2050 年前俄罗斯温室气体低排放社会经济发展战略》中规定的优先措施,对俄罗斯热电行业脱碳的实际可能性进行了评估。为此,考虑到热电工程企业的类型以及燃烧各种燃料的蒸汽轮机、燃气轮机和联合循环燃气发电厂的效率,对各种发电和热能技术的碳强度进行了比较。对减少二氧化碳排放的可能性进行了评估,包括提高固体燃料的质量、从烧煤过渡到烧天然气、引进联合循环燃气发电厂、提高发电厂的效率、淘汰过时的设备以及使用含氢气体和纯氢作为燃料。
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引用次数: 0
A Study of Thermal Cycle Circuits of NPPs Combined with Fossil Fueled Power Installations 核电站与化石燃料发电装置相结合的热循环回路研究
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700344
V. O. Kindra, I. A. Maksimov, D. V. Patorkin, I. I. Komarov, O. V. Zlyvko

The need to adapt the world’s industry and economy to constantly tightening climatic standards, as well as a constant growth of energy consumption, facilitate the development of carbon-free electricity generation technologies. Renewable energy and nuclear power plants are referred to energy sources having almost zero carbon dioxide emissions into the atmosphere. However, in view of an insufficient amount of renewable energy resources near large electricity consumers, NPPs play the most important role in the potential transition to the carbon-free economy of Russia. However, they do have certain drawbacks, such as comparatively low energy efficiency, poor maneuverability, and also high specific capital outlays. Combined use of nuclear and fossil fuel may become one of ways for partially removing these drawbacks. The article addresses a thermodynamic analysis of using fossil fuel at an NPP in an external steam superheater with subsequently expanding a part of the steam in a high-temperature turbine. A process circuit solution is proposed whose use makes it possible to obtain an expanded power unit load adjustment range. It has been shown from thermodynamic analysis results that, by subjecting a certain amount of steam from the steam generator to external superheating, it becomes possible to increase the nuclear power unit’s power output and efficiency: the maximal increase in the electric power output can total 338, 382, and 426 MW and that of net electrical efficiency of 0.73, 1.08, and 1.43% at steam superheating temperatures equal to 560, 600, and 640°С, respectively. The hybrid unit employing nuclear and hydrocarbon fuel that operates according to the proposed process cycle circuit includes a smaller amount of main equipment and features wider load adjustment ranges in comparison with standalone NPP and steam turbine thermal power plant: 102.3–132.7, 103.0–136.9, and 103.6–141.2% with respect to the reference process cycle circuit at steam superheating temperatures equal to 560, 600, and 640°С, respectively.

为使世界工业和经济适应不断收紧的气候标准,以及能源消耗的持续增长,促进了无碳发电技术的发展。可再生能源和核电站指的是向大气中几乎零排放二氧化碳的能源。然而,鉴于用电大户附近的可再生能源资源不足,核电站在俄罗斯向无碳经济过渡的潜在过程中发挥着最重要的作用。然而,它们也有一些缺点,如能效相对较低、可操作性差,以及具体资本支出较高。核燃料和化石燃料的联合使用可能是部分消除这些缺点的方法之一。文章对核电厂在外部蒸汽过热器中使用化石燃料,并随后在高温涡轮机中膨胀部分蒸汽进行了热力学分析。文章提出了一种工艺回路解决方案,使用该方案可以扩大功率单位负荷调节范围。热力学分析结果表明,通过对蒸汽发生器中的一定量蒸汽进行外部过热,可以提高核电机组的功率输出和效率:在蒸汽过热温度分别为 560、600 和 640°С时,电力输出的最大增幅分别为 338、382 和 426 兆瓦,净电力效率分别为 0.73、1.08 和 1.43%。与独立的核电厂和蒸汽轮机热电厂相比,根据拟议的工艺循环回路运行的采用核燃料和碳氢化合物燃料的混合机组的主要设备数量较少,负荷调节范围较宽:与参考工艺循环回路相比,在蒸汽过热温度等于 560、600 和 640°С 时,负荷调节范围分别为 102.3-132.7、103.0-136.9 和 103.6-141.2%。
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引用次数: 0
Simulation Modelling of Cycle Chemistry Monitoring of Water and Steam Quality at Thermal Power Plants 火力发电厂水和蒸汽质量的循环化学监测仿真建模
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700332
O. V. Egoshina, S. K. Lukutina

Cycle chemistry monitoring systems are intended for online comprehensive automatic monitoring, analysis, diagnostics, and prediction of the water chemistry in power equipment in all regimes of its operation, including startups and shutdowns, as well as for remote automatic control of one or several processes in the serviced process facility. Basic requirements for cycle chemistry monitoring systems are formulated. Mathematical models, which are based on the material balance, ionic composition of the coolant, and recurrent neural networks, have been developed and studied. They enable us to predict the concentration of impurities along the power unit’s path to prevent failures of the water chemistry. An algorithm has been developed for online quality assessment, based on dimensionless coefficients that provide fair information on the water-chemistry conditions and help to detect failures affecting the water chemistry. A simulation model with a user interface has been developed based on a set of algorithms considering the requirements for cycle chemistry monitoring systems, such as visualization, interactivity, reporting, customization, scalability, continuity, and simplicity. The model facilitates the activities performed by the operational personnel of power plants as to decision-making and prevention of failures of the water chemistry of the power unit, enables us to monitor the process parameters of the power unit in real time, analyze statistical data, predict parameters using algorithms on the basis of the material balance, ionic equilibriums, and neural networks. A user manual has been prepared to help one to understand the program interface. The manual contains a brief description of the system structure, including information and diagnostic functions, basic elements of the mnemonic diagram, and a set of control buttons.

循环化学监控系统用于对电力设备在所有运行状态下(包括启动和停机)的水化学进行在线综合自动监控、分析、诊断和预测,以及对所服务工艺设备中的一个或多个工艺过程进行远程自动控制。制定了循环化学监测系统的基本要求。基于物料平衡、冷却剂离子成分和递归神经网络的数学模型已被开发和研究。通过这些数学模型,我们可以预测机组运行过程中的杂质浓度,从而防止水化学失效。基于无量纲系数,我们开发了一种在线质量评估算法,该算法可提供有关水化学条件的公平信息,并有助于检测影响水化学的故障。考虑到循环化学监测系统的要求,如可视化、交互性、报告、定制、可扩展性、连续性和简易性,基于一套算法开发了一个带有用户界面的模拟模型。该模型有助于电厂运行人员进行决策和预防电厂机组水化学故障,使我们能够实时监测电厂机组的工艺参数,分析统计数据,使用基于物料平衡、离子平衡和神经网络的算法预测参数。为帮助用户了解程序界面,我们还编写了用户手册。手册中简要介绍了系统结构,包括信息和诊断功能、记忆图的基本要素以及一组控制按钮。
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引用次数: 0
Optimization of Radiator Design for Immersion Cooling of a Powerful Thyristor 优化散热器设计,为大功率晶闸管提供浸入式冷却
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700381
T. V. Ryabin, G. G. Yankov, V. I. Artemov, V. V. Ryabin

Numerical modeling of the thermal state of the T283-1600 thyristor with various radiators, on the surface of which boiling of the 3M Novec 649 liquid dielectric occurs, was carried out. Calculations were performed in the “in-house” CFD code ANES. Heat-transfer coefficients for nucleate and transition boiling, as well as critical heat flux, were calculated using the formulas of  V.V. Yagov. The change in boiling mode from nucleate to transition was carried out with equal heat flux calculated using the corresponding formulas: approximately 110 kW/m2, which is 17% lower than the critical heat flux predicted by Yagov’s formula for technically smooth surfaces. This led to slightly higher calculated temperatures of radiators on surface fragments with a transient boiling regime compared to temperatures during nucleate boiling over the entire cooling surface. The proportion of the surface area covered by the transition boiling regime did not exceed 3.2% of the total radiator area. Various forms of radiators were studied: in the form of fins from several disks and rectangular parallelepipeds with vertical slotted channels. At the same time, the geometric parameters of the fins and channels and their number and dimensions of the radiators were varied. As a result of numerical optimization, a radiator design was determined that meets the required conditions for the maximum temperature of the thyristor on the surface of contact with the radiator. To validate the results of numerical modeling, an experimental setup was created containing an assembly of thyristors with radiators immersed in a 3M Novec 649 dielectric. In normal operation, measuring the temperature of one of the radiators near the contact with the thyristor showed good agreement with the results of numerical simulation.

对带有各种散热器的 T283-1600 晶闸管的热状态进行了数值建模,3M Novec 649 液体介质在散热器表面发生沸腾。计算在 "内部 "CFD 代码 ANES 中进行。使用 V.V. Yagov 的公式计算了成核沸腾和过渡沸腾的传热系数以及临界热通量。从成核沸腾到过渡沸腾的沸腾模式变化是在使用相应公式计算出的同等热通量下进行的:约 110 kW/m2,比 Yagov 公式预测的技术上光滑表面的临界热通量低 17%。这导致瞬态沸腾表面碎片上散热器的计算温度略高于整个冷却表面成核沸腾时的温度。过渡沸腾状态覆盖的表面积比例不超过散热器总面积的 3.2%。研究了各种形式的散热器:由多个圆盘组成的散热片和带有垂直槽道的矩形平行管。同时,散热片和通道的几何参数及其数量和尺寸也发生了变化。经过数值优化,确定了一种散热器设计,它能满足晶闸管与散热器接触面上最高温度的要求条件。为了验证数值建模的结果,我们创建了一个实验装置,其中包含浸入 3M Novec 649 电介质的晶闸管和散热器组件。在正常运行时,测量其中一个与晶闸管接触附近的散热器的温度,结果显示与数值模拟结果非常吻合。
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引用次数: 0
Investigations on Thermo-Fluid Performance of a Milti-pass Shell-and-Tube Heat Exchanger with a Novel Trapezoidal Deflector-Type Baffle Plate 带有新型梯形偏转式挡板的小型管壳式热交换器的热流体性能研究
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S004060152470037X
Md Atiqur Rahman,  Sushil Kumar Dhiman

An axial flow tubular heat exchanger has been experimentally investigated to augment the heat transfer rate with a novel swirl flow of air past the heated tubes. The novel design has been made on the circular baffle plates provided with trapezoidal air deflectors of various inclination angles α, which is the angle made by the deflector surface with baffle plane. The arrangement of tubes, which were supported on baffle plates, was kept the same throughout the experiment analogy with the peripheral longitudinal air flow directed on it. All the tubes were maintained at constant heat flux condition over the entire surface. There were four deflectors developed on each of the baffle plate each deflector with equal inclination angle which generates air swirls inside the circular duct carrying the heated tubes that increase air side turbulence and hence the surface heat transfer rate. For every Re the baffle plates were placed equidistant from each other at different pitch ratios (PR = 0.6, 0.8, 1.0, and 1.2). The Reynolds number Re was kept in the range of 93 500–160 500. The effect of pitch ratios and the inclination angles on the thermo-fluid performance of the heat exchanger has been studied. The investigations reveal an average improvement of 25.1% in the thermo-fluid performance for a heat exchanger provided with the deflector baffle plates (DBP) having an inclination angle of 50° and a pitch ratio of 1.2 compared to that of a heat exchanger with a segmental baffle plate (SBP) tested under similar conditions of operation.

通过实验研究了一种轴流管式热交换器,该热交换器采用新颖的漩涡气流通过加热管来提高热传导率。这种新颖的设计是在圆形挡板上装有梯形空气导流板,导流板表面与挡板平面成不同的倾角 α。在整个实验过程中,支撑在障板上的管子的布置保持不变,周围的纵向气流直接流向管子。所有管子的整个表面都保持恒定的热通量状态。每块障板上都安装了四个导流板,每个导流板的倾斜角度相等,这就在承载加热管的圆形管道内产生了空气漩涡,增加了空气侧湍流,从而提高了表面传热速率。在每个雷诺数下,以不同的间距比(PR = 0.6、0.8、1.0 和 1.2)等距离放置挡板。雷诺数 Re 保持在 93 500-160 500 之间。研究了螺距比和倾角对热交换器热流体性能的影响。研究结果表明,与在类似运行条件下测试的带有分段挡板(SBP)的热交换器相比,带有倾斜角为 50°、间距比为 1.2 的导流挡板(DBP)的热交换器的热流体性能平均提高了 25.1%。
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引用次数: 0
Reshaping the Rotor Hub of a 1.5-stage Axial Turbine to Reduce Pressure Losses by a Parametric Groove 通过参数槽重塑 1.5 级轴流式涡轮机的转子毂以减少压力损失
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700356
Hayder M. B. Obaida,  Aldo Rona

The interaction among the vortices that develop over an axial turbine passage hub leads to pressure losses and, consequently, to a decrease in the stage isentropic efficiency. The turbine performs better if flow separation and secondary flows are reduced. To achieve this, this paper explores by computational fluid dynamics the application of rotor hub contouring to a one-and-a-half-stage axial turbine, the “Aachen Turbine.” The pressure side arm of the rotor horseshoe vortex is guided by a groove in the end-wall rotor hub surface, which is defined parametrically using non-uniform rational B-splines (NURBS). This novel rotor hub groove runs from the leading edge of the rotor blade to the trilling edge of the rotor blade. A three-dimensional steady Reynolds Averaged Navier–Stokes (RANS) k–ω-SST model of the one-and-half-stage turbine with axisymmetric end-walls is validated against reference experimental measurement from the Institute of Jet Propulsion and Turbomachinery at RWTH Aachen in Germany. By contouring the hub of the upstream stator and of the rotor, the overall pressure loss coefficient predicted by openFOAM computational fluid dynamics is reduced by 5.2%, using Kriging optimized groove shape parameters.

在轴流式涡轮机轮毂上形成的涡流之间的相互作用会导致压力损失,进而降低级等熵效率。如果能减少流体分离和二次流,涡轮机的性能就会更好。为了实现这一目标,本文通过计算流体动力学探讨了转子轮毂轮廓在单级半轴流式涡轮机 "亚琛涡轮机 "中的应用。转子马蹄涡旋的压力侧臂由转子轮毂端壁表面的凹槽引导,凹槽采用非均匀有理 B 样条(NURBS)参数定义。这种新颖的转子轮毂凹槽从转子叶片的前缘一直延伸到转子叶片的后缘。根据德国亚琛工业大学喷气推进和透平机械研究所的参考实验测量结果,对带有轴对称端壁的一级半涡轮机的三维稳定雷诺平均纳维-斯托克斯(RANS)k-ω-SST 模型进行了验证。通过对上游定子和转子的轮毂进行轮廓处理,使用克里金优化槽形参数,openFOAM 计算流体动力学预测的整体压力损失系数降低了 5.2%。
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引用次数: 0
Experimental Investigation of Forced Flow Heat-Transfer Enhancement in a Minichannel 微型通道中强制流换热增强的实验研究
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700320
A. V. Belyaev, N. E. Sidel’nikov, E. I. Gareev, A. V. Dedov

The results of the investigation into heat-transfer enhancement at increasing critical heat flux due to modification of a wall’s inner surface are presented. The greater need for new, compact, and energy-efficient heat exchangers on the basis of minichannels for high-tech industries makes this investigation urgent. The potential for application of small diameter channels in systems where various dielectric liquids or freons at moderate and high reduced pressures can be used as a coolant is being actively investigated today. The experiments were performed in a heated vertical minichannel. The wall was modified by the rolling method, which has not yet been used in small diameter channels. The experiments were performed with a forced flow of R125 refrigerant at high reduced pressures of 0.43 and 0.56 in the range of mass flowrates from 200 to 1200 kg/(m2 s), which is the most applicable range for minichannel heat exchangers. Heat transfer during forced convection and flow boiling was studied. The experimental setup and the minichannel inner wall modification method are described. Experimental data on forced convection and flow boiling heat-transfer coefficients, critical heat fluxes, and pressure drops are presented. The heat-transfer data were compared with the results obtained previously with the inner surface modified by the action of laser pulses on the outer wall. The convective heat-transfer coefficient in a minichannel with the inner surface modified by rolling was found to be much greater than that in a smooth channel. The obtained convective heat-transfer coefficients are compared with the predictions by empirical formulas derived for large-diameter pipes with the wall surface modified by rolling.

本文介绍了在临界热通量增加时,通过改变壁的内表面来提高传热效果的研究结果。高科技产业对基于微型通道的新型、紧凑、高能效热交换器的需求越来越大,这使得这项研究迫在眉睫。目前正在积极研究小直径通道在各种介质液体或氟利昂系统中的应用潜力,这些介质液体或氟利昂可在中等或较高的减压条件下用作冷却剂。实验是在一个加热的垂直微型通道中进行的。通过滚动方法对通道壁进行了改良,这种方法尚未在小直径通道中使用过。实验中,R125 制冷剂在 0.43 和 0.56 的高减压下强制流动,质量流量范围为 200 至 1200 kg/(m2 s),这是微型通道热交换器最适用的范围。研究了强制对流和流动沸腾过程中的热传递。介绍了实验装置和微型通道内壁改造方法。介绍了强制对流和流动沸腾传热系数、临界热通量和压降的实验数据。这些传热数据与之前通过激光脉冲作用于外壁对内表面进行改性所获得的结果进行了比较。结果发现,内表面经滚动修正的微型通道中的对流换热系数远大于光滑通道中的对流换热系数。所获得的对流换热系数与根据经验公式推导出的通过滚动修正管壁表面的大直径管道的预测值进行了比较。
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引用次数: 0
An Analysis of Lead Oxidation Mechanisms in the Volume of Vapor Bubbles 气泡体积中的铅氧化机制分析
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700393
M. V. Vorivonchik, D. A. Nazarov, D. S. Sinitsyn, N. A. Mosunova, A. A. Sorokin

The article presents a kinetic model describing the lead vapor oxidation in the vapor bubble volume to produce lead oxide and hydrogen with their subsequent dissolution in the lead melt volume. The model is implemented in the approximation of homogeneous distribution of reagents and oxidation reaction products in the bubble volume. An analytical solution for stationary oxidation conditions is obtained. It is shown that vapor bubbles in the lead melt volume are a sort of chemical “microreactors” producing lead oxide and hydrogen, which subsequently dissolve in the melt volume. However, such hydrogen generation mechanism does not pose any threat for the primary coolant circuit of fast lead cooled reactors in terms of hydrogen accumulation and explosion hazard in view of essentially low intensity of the hydrogen generation source. The article presents the results of water to hydrogen conversion assessments carried out with the use of a homogeneous kinetic model for interaction of water vapor with lead vapor in the vapor bubble volume. The model incorporates mechanisms governing lead evaporation into the bubble volume, oxidation of lead vapor as it interacts with water vapor in the bubble volume, and dissolution of reaction products in the lead melt surrounding the bubble. One more important result of equilibrium thermodynamic computations is connected with a possible change in the composition of iron oxides in the melt after the injection of water from the steam generator leak into the melt. The ingress of water into the lead melt may cause a change in the composition of iron oxides, thereby increasing the fraction of hematite and decreasing the fraction of magnetite. This may entail a change in the composition of the protective oxide film on the structural steel surface to make it more brittle.

文章提出了一个动力学模型,描述了铅蒸气在蒸气泡体积中氧化生成氧化铅和氢,随后在铅熔体体积中溶解的过程。该模型是在试剂和氧化反应产物在气泡体积中均匀分布的近似条件下实现的。得到了固定氧化条件下的解析解。结果表明,铅熔体中的气泡是一种化学 "微反应器",会产生氧化铅和氢气,随后溶解在熔体中。不过,鉴于氢产生源的强度基本上很低,这种氢产生机制不会对快速铅冷反应堆的初级冷却剂回路造成氢积累和爆炸危险。文章介绍了使用均相动力学模型对水蒸气与铅蒸汽在蒸汽泡体积中的相互作用进行水氢转化评估的结果。该模型包含了铅蒸发到气泡中的机制、铅蒸气与气泡中水蒸气相互作用时的氧化机制以及反应产物在气泡周围铅熔体中的溶解机制。平衡热力学计算的另一个重要结果与蒸汽发生器泄漏的水注入熔体后熔体中铁氧化物成分的可能变化有关。水进入铅熔体可能会导致铁氧化物的成分发生变化,从而增加赤铁矿的比例,减少磁铁矿的比例。这可能导致结构钢表面保护氧化膜的成分发生变化,使其变得更脆。
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引用次数: 0
Ensuring Technological Indicators for Nitrogen Oxide Emissions during Solid-Fuel Combustion in a High-Power Steam Boiler 确保大功率蒸汽锅炉固体燃料燃烧过程中氮氧化物排放的技术指标
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-10-27 DOI: 10.1134/S0040601524700368
V. B. Prokhorov, V. S. Kirichkov, S. L. Chernov, M. V. Fomenko

Organic fuel combustion products are one of the main sources of air pollution. When burning fossil fuels, pollutants harmful to human health, such as nitrogen and sulfur oxides, fly ash with particles of unburned fuel, carbon oxides, polycyclic aromatic hydrocarbons, and metal oxides, are released into the atmosphere. The largest emissions of pollutants into the atmosphere are accompanied by the combustion of solid fuels. In 2014, significant changes took place in the environmental legislation of the Russian Federation [1], which oblige energy enterprises to comply not only with sanitary and hygienic standards but also with technical and technological standards. To maintain technological indicators for specific NOx emissions on boiler equipment at the regulatory level, it will be necessary to fully apply primary methods for suppressing the formation of nitrogen oxides, use low-toxic burners and fuel combustion schemes, and, in some cases, expensive gas purification from NOx will be required. Based on statistical data, the BKZ-420-140 (E-420-140) boiler was selected as a prototype for research. When BKZ-420-140 boilers in the factory version operate using vortex burners when burning brown coal, the concentration of nitrogen oxides in the flue gases is more than 800 mg/m3, which significantly exceeds current standards. In order to reduce emissions of nitrogen oxides while ensuring high operating efficiency of boiler equipment, a solid-fuel combustion scheme using direct-flow burners and nozzles has been proposed for this boiler. It is shown that it will be possible to increase the economic and environmental efficiency of BKZ-420-140 boilers’ operation by implementing the developed solid-fuel combustion scheme using direct-flow burners and nozzles on them.

有机燃料燃烧产物是空气污染的主要来源之一。燃烧化石燃料时,会向大气中排放对人类健康有害的污染物,如氮氧化物和硫氧化物、带有未燃烧燃料颗粒的飞灰、碳氧化物、多环芳烃和金属氧化物。固体燃料燃烧时向大气排放的污染物最多。2014 年,俄罗斯联邦的环境立法发生了重大变化[1],要求能源企业不仅要遵守卫生标准,还要遵守技术和工艺标准。为了使锅炉设备的氮氧化物具体排放技术指标保持在规定水平,必须充分应用抑制氮氧化物形成的初级方法,使用低毒燃烧器和燃料燃烧方案,在某些情况下,还需要进行昂贵的氮氧化物气体净化。根据统计数据,BKZ-420-140(E-420-140)锅炉被选为研究原型。当工厂版 BKZ-420-140 锅炉使用涡流燃烧器燃烧褐煤时,烟气中的氮氧化物浓度超过 800 mg/m3,大大超过了现行标准。为了减少氮氧化物的排放,同时确保锅炉设备的高运行效率,我们为该锅炉提出了使用直流燃烧器和喷嘴的固体燃料燃烧方案。研究表明,通过在 BKZ-420-140 锅炉上实施所开发的使用直流燃烧器和喷嘴的固体燃料燃烧方案,可以提高锅炉运行的经济效益和环境效益。
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引用次数: 0
Calculation of Reactor Characteristics and Techno-Economic Assessment of a System for Hydrogen Production from Biomass Using Gasification in Chemical Cycles 利用化学循环气化从生物质制氢系统的反应器特性计算和技术经济评估
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2024-09-26 DOI: 10.1134/S0040601524700277
G. A. Ryabov, D. S. Litun, O. M. Folomeev

The calculation method developed by the authors is supplemented by the heat balance of a circulating fluidized bed (CFB) reactor for burning coke residue in a CFB reactor‒gas-generator system. The following options are examined: with the supply of additional dried fuel to the reactor as an alternative method for keeping the required gasification temperature of particles at the CFB reactor outlet and application as a fuel of a mixture of wood biomass and Kuznetsk coal benefication products. The thermal cycle of the plant has been modified as applicable, and the calculation results are presented. It has been demonstrated that gasification of a mixture of biomass and coal benefication enables increasing the overall system capacity (production of hydrogen + electricity) without a considerable growth in the biomass consumption. In this case, the hydrogen production decreases, and the hydrogen production efficiency drops but the efficiency of electricity generation rises. The hydrodynamic calculation of CFB reactors was performed to attain the specified flowrates of circulating material required to maintain proper temperatures in the reactors. The flowrate of circulating particles can be increased by increasing the pressure difference (loading level or weight of material in the reactors). The overall dimensions of the reactors have been determined, and their layout is presented. A procedure for calculating capital and operating expenditures is outlined, and these expenditure components are estimated. The cost of hydrogen production using biomass without CO2 emission over the life cycle of the plant was estimated (USD 1.45/kg). Approximately 2/3 of the formed CO2 is already ready for storage. Therefore, we have only to remove CO2 from the flue gas flow from the CFB reactor of the gas generator. This level corresponds to available foreign data on similar plants operating on natural gas and is lower than that provided by the widely used technology of steam reforming of natural gas with CO2 capture.

作者开发的计算方法得到了循环流化床(CFB)反应器热平衡的补充,该反应器用于在 CFB 反应器-燃气-发电机系统中燃烧焦炭残渣。对以下方案进行了研究:向反应器供应额外的干燥燃料,作为保持 CFB 反应器出口颗粒所需气化温度的替代方法,以及将木质生物质和库兹涅茨克煤炭选矿产品的混合物用作燃料。该装置的热循环已根据实际情况进行了修改,并给出了计算结果。结果表明,生物质和选煤混合物的气化可以在不大幅增加生物质消耗量的情况下提高整个系统的产能(制氢+发电)。在这种情况下,制氢量减少,制氢效率下降,但发电效率上升。对 CFB 反应器进行流体力学计算,以达到保持反应器内适当温度所需的指定循环材料流速。循环颗粒的流速可通过增加压差(反应器中的装料水平或物料重量)来提高。反应器的总体尺寸已经确定,并介绍了其布局。概述了计算资本和运营支出的程序,并对这些支出部分进行了估算。估算了利用生物质生产氢气而不排放二氧化碳的成本(1.45 美元/千克)。形成的二氧化碳中约有 2/3 已准备好储存。因此,我们只需从气体发生器 CFB 反应器的烟气流中去除二氧化碳即可。这一水平符合国外同类天然气发电厂的现有数据,也低于广泛使用的天然气蒸汽转化与二氧化碳捕集技术所提供的水平。
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Thermal Engineering
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