This research focuses on the synthesis and characterization of glass compositions containing Bi2O3 as a dopant for enhanced radiation shielding capabilities. The compositions, formulated as (80-x)B2O3 + 10Na2O + 10BaCl2 + xBi2O3 with x values of 0, 15, 30, and 45 mol%, were subjected to X-ray diffraction analysis to examine their structural properties. The X-ray diffraction analysis indicated that samples Bi0.0 and Bi0.15 exhibit an amorphous structure, while samples Bi0.30 and Bi0.45 display crystallization. Furthermore, the density of the samples was determined using the Archimedes method and the results reveled an increase from 2.5 to 5.4 g/cm3. The optical properties of the prepared glass samples were measured using UV–VIS spectrophotometer within the spectral range of 200–1200 nm. The efficiency of radiation shielding was evaluated through the Phy-x program software, providing insights into the attenuation of radiation across the different Bi2O3 doping levels. The findings illustrate a notable rise in the mass attenuation coefficient from 13.32 to 87.74 cm2/g correlating with the increased Bi2O3 content. Additionally, the effective atomic number exhibited an escalation from 30.75 to 76.96 cm2/g. The effective electron density demonstrated an increase in the glass samples, rising from 10.3 × 1023 to 13.2 × 1023 el/g for samples Bi0.0 and Bi0.15. In contrast, the effective electron density exhibited a decrease in the Bi0.30 and Bi0.45 samples, declining from 10.3 × 1023 to 8.2 × 1023 el/g. Simultaneously, the half-value layer witnessed a decrease from 0.021 to 0.001 cm, while the mean free path concurrently decreased from 0.030 to 0.002 cm. Moreover, the fast neutron removal cross section was examined, the results show the values fluctuating between 0.093 and 0.105 for glass samples.
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