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Magneto-Permeability Effect in Ferrofluid Flow Through Porous Media Studied via Multiparticle Collision Dynamics 通过多粒子碰撞动力学研究铁流体流经多孔介质时的磁渗透效应
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-04-06 DOI: 10.1007/s11242-024-02077-w
Patrick Ilg

As more and more promising applications of magnetic nanoparticles in complicated environments are explored, their flow properties in porous media are of increasing interest. We here propose a hybrid approach based on the multiparticle collision dynamics method extended to porous media via friction forces and coupled with Brownian dynamics simulations of the rotational motion of magnetic nanoparticles’ magnetic moment. We simulate flow in planar channels homogeneously filled with a porous medium and verify our implementation by reproducing the analytical velocity profile of the Darcy–Brinkman model in the non-magnetic case. In the presence of an externally applied magnetic field, the non-equilibrium magnetization and friction forces lead to field-dependent velocity profiles that result in effective, field-dependent permeabilities. We provide a theoretical expression for this magneto-permeability effect in analogy with the magneto-viscous effect. Finally, we study the flow through planar channels, where only the walls are covered with a porous medium. We find a smooth crossover from the Poiseuille profile in the center of the channel to Brinkman–Darcy flow in the porous layers. We propose a simple estimate of the thickness of the porous layer based on the flow rate and maximum flow velocity.

随着人们探索磁性纳米粒子在复杂环境中越来越多的应用前景,人们对其在多孔介质中的流动特性越来越感兴趣。我们在此提出了一种基于多粒子碰撞动力学方法的混合方法,该方法通过摩擦力扩展到多孔介质,并与磁性纳米粒子磁矩旋转运动的布朗动力学模拟相结合。我们模拟了多孔介质均匀填充的平面通道中的流动,并通过再现非磁性情况下达西-布林克曼模型的分析速度曲线验证了我们的实现。在存在外加磁场的情况下,非平衡磁化和摩擦力会导致随磁场变化的速度曲线,从而产生随磁场变化的有效渗透率。我们为这种磁渗透效应提供了一个与磁粘性效应类似的理论表达式。最后,我们研究了流经平面通道的情况,在这种情况下,只有通道壁被多孔介质覆盖。我们发现,在多孔层中,从通道中心的波伊塞尔剖面到布林克曼-达西流动有一个平滑的交叉。我们提出了一种基于流速和最大流速的多孔层厚度简单估算方法。
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引用次数: 0
On the Berman Slip-Flow in a Parallel-Sided Channel with Porous Boundaries 关于多孔边界平行边水道中的伯曼滑移流
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-04-05 DOI: 10.1007/s11242-024-02078-9
Eugen Magyari

The title problem which has recently been addressed in this journal is revisited in the present paper under a new point of view. It is shown that the joint effect of the Berman suction or injection normal to the boundaries and the velocity slip along the boundaries is equivalent to the sole effect of an oblique suction or injection of the fluid. The solution of the corresponding boundary value problem is given by a Maclaurin series expansion of the similar stream function to powers of the scaled transverse coordinate y/h. Compared to the classical Berman problem, the existence of several new solution branches of the oblique suction/injection problem is reported. Subsequently, the physical and mathematical aspects of the mentioned equivalence are discussed in the paper in some detail. It is pointed out that the vanishing midplane velocity represents the crossover from the physically feasible unidirectional flows to the unfeasible bidirectional flow configurations, where in the neighborhood of the midplane of the channel reverse flows occur.

本文从一个新的角度重新探讨了最近在本刊上发表过的标题问题。研究表明,边界法线上的伯曼吸力或注入力以及沿边界的速度滑移的共同作用等同于流体斜吸力或注入力的单独作用。相应边界值问题的解由类似流函数的 Maclaurin 级数展开给出,它是缩放横向坐标 y/h 的幂。与经典的伯曼问题相比,报告指出斜吸入/注入问题存在几个新的求解分支。随后,论文详细讨论了上述等效性的物理和数学方面。论文指出,中面速度的消失代表着从物理上可行的单向流向不可行的双向流配置的交叉,在通道中面附近会出现反向流。
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引用次数: 0
Design of Biomimetic Porous Scaffolds for Bone Tissue Engineering 设计用于骨组织工程的仿生多孔支架
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-04-03 DOI: 10.1007/s11242-024-02082-z

Abstract

The fluid flow dynamics on the porous scaffolds and their static responses on the adjacent bone are very crucial parameters for bone adaptation. Researchers are trying to develop different algorithms to design biomimetic porous scaffolds incorporating bone tissue engineering. In this present work, three types of biomimetic heterogeneous porous scaffolds (HPS) were designed with the help of the Voronoi tessellation method and Swarm Intelligence and those were analysed under fluid perfusion as well as under static loading conditions. In computational fluid dynamics (CFD) analysis, the wall shear stress (WSS) and the permeability of the porous scaffolds were compared to the natural trabecular bone to understand their hydrodynamic responses. In static analysis, the von Mises stresses of the Ti6Al4V scaffolds were checked to ensure no-yield condition. The strain energy density (SED) distributions were also studied on the neighbouring bone region of the femur greater trochanter to obtain stress shielding (SS) patterns and these findings were then compared with the natural trabecular bone at the same anatomical region. The outcome parameters, viz. the induced WSS, von Mises stress, the permeability, and SS of the scaffold, are found to be independent of the scaffold architecture. The von Mises stress and permeability increased with an increase in porosities, while the induced WSS and SS nature of the scaffolds showed the reverse trend. The results showed that the HPS designed based on the Swarm Intelligence incorporating Physarum Polycephalum algorithm offered the least SS level of 41.096 for 75% porous HPS, which may be considered the most promising result. Considering all the parameters, the novel designed scaffold based on Swarm Intelligence showed the most trabecular bone mimicking nature compared to the other scaffolds.

摘要 多孔支架上的流体流动动力学及其对邻近骨骼的静态响应是骨骼适应性的关键参数。研究人员正试图开发不同的算法来设计结合骨组织工程的仿生多孔支架。在本研究中,利用 Voronoi 网格法和蜂群智能法设计了三种仿生异质多孔支架(HPS),并在流体灌注和静态加载条件下对其进行了分析。在计算流体动力学(CFD)分析中,多孔支架的壁剪应力(WSS)和渗透性与天然骨小梁进行了比较,以了解它们的流体动力响应。在静态分析中,检查了 Ti6Al4V 支架的 von Mises 应力,以确保无屈服状态。还研究了股骨大转子邻近骨区的应变能密度(SED)分布,以获得应力屏蔽(SS)模式,然后将这些结果与同一解剖区域的天然骨小梁进行比较。结果参数,即支架的诱导 WSS、von Mises 应力、渗透性和 SS,与支架结构无关。冯米斯应力和渗透性随着孔隙率的增加而增加,而支架的诱导 WSS 和 SS 性质则呈现相反的趋势。结果表明,对于 75% 多孔 HPS 而言,基于蜂群智能(Swarm Intelligence)结合多孔体算法设计的 HPS 的 SS 水平最低,为 41.096,可视为最有前途的结果。考虑到所有参数,与其他支架相比,基于蜂群智能设计的新型支架显示出最大的骨小梁模拟特性。
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引用次数: 0
Asymptotic-Poroelastic Model for Reservoir Compaction Damage Management in Fractured Oil Wells with Stress-Dependent Permeability 应力依赖渗透率的断裂油井储层压实损害管理渐近-透射弹性模型
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-04-01 DOI: 10.1007/s11242-024-02068-x
Fernando Bastos Fernandes, E. Gildin, Arthur M. B. Braga, Antônio Cláudio Soares

The adequate management of the damage caused by effective permeability loss in stress-sensitive reservoirs becomes essential to productivity maintenance. This paper proposes a new unsteady-state poroelastic solution for the nonlinear hydraulic diffusivity equation in Biot’s effective stress-sensitive reservoirs fully penetrated by fractured oil wells. The hydraulic fracture in the proposed mathematical modeling is finite with tip effects and crosses the whole reservoir net pay. The NHDE is expanded in a first-order asymptotic series, and a poroelastic integro-differential solution coupled with a Green’s function (GF) is used to represent the source/sink term. A set of pore pressure and permeability data is used from geomechanical literature and transformed into effective stress through Biot’s equation. The effect of the Biot’s coefficient, overburden stress, oil flow rate, fracture’s tip, and proppant porosity arrangements is simulated. The results show that these parameters are essential to minimize formation damage. The accuracy, ease of implementation, and low computational costs constitute the main advantages of the model addressed in this paper. Hence, it may be a valuable and attractive mathematical tool to identify flow regimes, providing permeability loss control and supporting well–reservoir management. Hence, the proposed modeling becomes a useful and attractive tool for forecasting and monitoring permeability loss, oil flow rate specification, and reservoir history matching.

应力敏感油藏中有效渗透率损失所造成的损害的适当管理对于保持生产力至关重要。本文提出了一种新的非稳态孔弹性解法,用于求解压裂油井完全渗透的 Biot 有效应力敏感油藏中的非线性水力扩散方程。在所提出的数学模型中,水力裂缝是有限的,具有尖端效应,并穿过整个油藏净付油层。NHDE在一阶渐近序列中展开,并使用与格林函数(GF)耦合的孔弹性积分微分解来表示源/汇项。从地质力学文献中提取了一组孔隙压力和渗透率数据,并通过 Biot 方程转化为有效应力。模拟了 Biot 系数、覆盖层应力、油流速、裂缝顶端和支撑剂孔隙度排列的影响。结果表明,这些参数对减少地层损害至关重要。精度高、易于实施、计算成本低是本文所研究模型的主要优点。因此,它可能是一种有价值、有吸引力的数学工具,可用于识别流动机制、提供渗透损失控制和支持油藏管理。因此,本文提出的模型将成为预测和监测渗透率损失、石油流速规范和油藏历史匹配的有用和有吸引力的工具。
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引用次数: 0
Immiscible Two-Phase Flow in Porous Media: Effective Rheology in the Continuum Limit 多孔介质中的不溶两相流:连续极限中的有效流变学
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-03-25 DOI: 10.1007/s11242-024-02073-0

Abstract

We consider steady-state immiscible and incompressible two-phase flow in porous media. It is becoming increasingly clear that there is a flow regime where the volumetric flow rate depends on the pressure gradient as a power law with an exponent larger than one. This occurs when the capillary forces and viscous forces compete. At higher flow rates, where the viscous forces dominate, the volumetric flow rate depends linearly on the pressure gradient. This means that there is a crossover pressure gradient that separates these two flow regimes. At small enough pressure gradient, the capillary forces dominate. If one or both of the immiscible fluids percolate, the volumetric flow rate will then depend linearly on the pressure gradient as the interfaces will not move. If none of the fluids percolate, there will be a minimum pressure gradient threshold to mobilize the interfaces and thereby get the fluids moving. We now imagine a core sample of a given size. The question we pose is what happens to the crossover pressure gradient that separates the power-law regime from the high-flow rate linear regime and the threshold pressure gradient that blocks the flow at low pressure gradients when the size of the core sample is increased. Based on analytical calculations using the capillary bundle model and on numerical simulations using a dynamical pore-network model, we find that the crossover pressure gradient and the threshold pressure gradient decrease with two distinct power laws in the size. This means that the power-law regime disappears in the continuum limit where the pores are infinitely small compared to the sample size.

摘要 我们考虑了多孔介质中的稳态不相溶和不可压缩两相流。人们越来越清楚地认识到,存在这样一种流动状态,即体积流量与压力梯度呈指数大于 1 的幂律关系。当毛细力和粘性力发生竞争时,就会出现这种情况。在粘滞力占主导地位的较高流速下,体积流量与压力梯度呈线性关系。这意味着这两种流动状态之间存在一个交叉压力梯度。在压力梯度足够小的情况下,毛细力占主导地位。如果不相溶流体中的一种或两种都发生渗透,由于界面不会移动,体积流量将与压力梯度成线性关系。如果所有流体都不渗流,则会有一个最小压力梯度阈值来调动界面,从而使流体流动。现在,我们设想一个给定大小的岩心样本。我们提出的问题是,当岩心样品的尺寸增大时,将幂律机制与高流速线性机制区分开来的交叉压力梯度以及在低压梯度下阻止流动的阈值压力梯度会发生什么变化。根据使用毛细管束模型进行的分析计算和使用动态孔隙网络模型进行的数值模拟,我们发现交叉压力梯度和阈值压力梯度随着尺寸的两个不同幂律而减小。这意味着,在孔隙与样品尺寸相比无限小的连续极限中,幂律机制消失了。
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引用次数: 0
Stochastic Periodic Microstructures for Multiscale Modelling of Heterogeneous Materials 用于多尺度异质材料建模的随机周期微结构
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-03-19 DOI: 10.1007/s11242-024-02074-z
Evan John Ricketts

Abstract

Plurigaussian simulation is a method of discrete random field generation that can be used to generate many complex geometries depicting real world structures. Whilst it is commonly applied at larger scales to represent geological phenomena, the highly flexible approach is suitable for generating structures at all scales. Here, an extension of plurigaussian simulation to periodic plurigaussian simulation (P-PGS) is presented, such that the resulting fields are periodic in nature. By using periodic Gaussian random fields as components of the method, periodicity is enforced in the generated structures. To substantiate the use of P-PGS in capturing complex heterogeneities in a physically meaningful way, the pore-scale microstructure of cement paste was represented such that its effective properties can be calculated through a computational homogenisation approach. The finite element method is employed to model the diffusion of heat through the medium under dry and saturated pore conditions, where numerical homogenisation is conducted to calculate the effective thermal conductivity of the medium. Comparison of the calculated values with experimental observations indicated that the generated microstructures are suitable for pore-scale representation, given their close match. A maximal error of 1.38% was observed in relation to the numerically determined effective thermal conductivity of mortar paste with air filled pores, and 0.41% when considering water filled pores. As the assumption of a periodic domain is often an underlying feature of numerical homogenisation, this extension of plurigaussian simulation enables a path for its integration into such computational schemes.

Article Highlights

  • Integrating P-PGS into numerical homogenisation frameworks enhances complex heterogeneous material representation

  • The flexibility of P-PGS enables a wide range of material microstructures to be represented accurately

  • Use of the generated structures allows material properties to be estimated accurately through numerical homogenisation

摘要普鲁里高斯模拟是一种离散随机场生成方法,可用于生成许多描绘现实世界结构的复杂几何图形。虽然它通常应用于较大尺度的地质现象,但这种高度灵活的方法适用于生成各种尺度的结构。本文介绍了将多高斯模拟扩展到周期多高斯模拟(P-PGS)的方法,从而使生成的场具有周期性。通过使用周期性高斯随机场作为该方法的组成部分,生成的结构具有周期性。为了证实 P-PGS 能够以一种有物理意义的方式捕捉复杂的异质性,对水泥浆的孔隙尺度微观结构进行了表示,以便通过计算均质化方法计算其有效特性。采用有限元法模拟干燥和饱和孔隙条件下热量在介质中的扩散,并通过数值均质化计算介质的有效热导率。计算值与实验观测值的比较表明,生成的微观结构与孔隙尺度非常接近,因此适合用于表示孔隙尺度。根据数值计算得出的砂浆膏的有效导热率,在充满空气的孔隙中,最大误差为 1.38%,而在充满水的孔隙中,最大误差为 0.41%。文章亮点将 P-PGS 集成到数值均质化框架中可增强复杂异质材料的表示P-PGS 的灵活性可准确表示各种材料的微观结构使用生成的结构可通过数值均质化准确估算材料特性
{"title":"Stochastic Periodic Microstructures for Multiscale Modelling of Heterogeneous Materials","authors":"Evan John Ricketts","doi":"10.1007/s11242-024-02074-z","DOIUrl":"https://doi.org/10.1007/s11242-024-02074-z","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Plurigaussian simulation is a method of discrete random field generation that can be used to generate many complex geometries depicting real world structures. Whilst it is commonly applied at larger scales to represent geological phenomena, the highly flexible approach is suitable for generating structures at all scales. Here, an extension of plurigaussian simulation to periodic plurigaussian simulation (P-PGS) is presented, such that the resulting fields are periodic in nature. By using periodic Gaussian random fields as components of the method, periodicity is enforced in the generated structures. To substantiate the use of P-PGS in capturing complex heterogeneities in a physically meaningful way, the pore-scale microstructure of cement paste was represented such that its effective properties can be calculated through a computational homogenisation approach. The finite element method is employed to model the diffusion of heat through the medium under dry and saturated pore conditions, where numerical homogenisation is conducted to calculate the effective thermal conductivity of the medium. Comparison of the calculated values with experimental observations indicated that the generated microstructures are suitable for pore-scale representation, given their close match. A maximal error of 1.38% was observed in relation to the numerically determined effective thermal conductivity of mortar paste with air filled pores, and 0.41% when considering water filled pores. As the assumption of a periodic domain is often an underlying feature of numerical homogenisation, this extension of plurigaussian simulation enables a path for its integration into such computational schemes.</p><h3 data-test=\"abstract-sub-heading\">\u0000<b>Article Highlights</b>\u0000</h3><ul>\u0000<li>\u0000<p>Integrating P-PGS into numerical homogenisation frameworks enhances complex heterogeneous material representation</p>\u0000</li>\u0000<li>\u0000<p>The flexibility of P-PGS enables a wide range of material microstructures to be represented accurately</p>\u0000</li>\u0000<li>\u0000<p>Use of the generated structures allows material properties to be estimated accurately through numerical homogenisation</p>\u0000</li>\u0000</ul>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":null,"pages":null},"PeriodicalIF":2.7,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140170136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Transition from Darcy to Nonlinear Flow in Heterogeneous Porous Media: I—Single-Phase Flow 异质多孔介质中从达西流到非线性流的过渡:I - 单相流
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-03-14 DOI: 10.1007/s11242-024-02070-3
Sepehr Arbabi, Muhammad Sahimi

Using extensive numerical simulation of the Navier–Stokes equations, we study the transition from the Darcy’s law for slow flow of fluids through a disordered porous medium to the nonlinear flow regime in which the effect of inertia cannot be neglected. The porous medium is represented by two-dimensional slices of a three-dimensional image of a sandstone. We study the problem over wide ranges of porosity and the Reynolds number, as well as two types of boundary conditions, and compute essential features of fluid flow, namely, the strength of the vorticity, the effective permeability of the pore space, the frictional drag, and the relationship between the macroscopic pressure gradient ({varvec{nabla }}P) and the fluid velocity v. The results indicate that when the Reynolds number Re is low enough that the Darcy’s law holds, the magnitude (omega _z) of the vorticity is nearly zero. As Re increases, however, so also does (omega _z), and its rise from nearly zero begins at the same Re at which the Darcy’s law breaks down. We also show that a nonlinear relation between the macroscopic pressure gradient and the fluid velocity v, given by, (-{varvec{nabla }}P=(mu /K_e)textbf{v}+beta _nrho |textbf{v}|^2textbf{v}), provides accurate representation of the numerical data, where (mu) and (rho) are the fluid’s viscosity and density, (K_e) is the effective Darcy permeability in the linear regime, and (beta _n) is a generalized nonlinear resistance. Theoretical justification for the relation is presented, and its predictions are also compared with those of the Forchheimer’s equation.

通过对纳维-斯托克斯方程进行大量数值模拟,我们研究了流体在无序多孔介质中缓慢流动时从达西定律向非线性流动机制的过渡,在非线性流动机制中,惯性的影响是不可忽略的。多孔介质由砂岩三维图像的二维切片表示。我们研究了孔隙率和雷诺数以及两种边界条件的宽范围问题,并计算了流体流动的基本特征,即涡度强度、孔隙空间的有效渗透率、摩擦阻力以及宏观压力梯度 ({varvec{nabla }}P) 和流体速度 v 之间的关系。结果表明,当雷诺数 Re 低到达西定律成立时,涡度的大小 (omega _z) 几乎为零。然而,随着雷诺数的增大,涡度也会增大,而且涡度从近乎零开始上升的起点与达西定律崩溃的雷诺数相同。我们还证明了宏观压力梯度与流体速度 v 之间的非线性关系,即 (-{varvecnabla }}P=(mu /K_e)textbf{v}+beta _nrho |textbf{v}|^2textbf{v})、其中,(mu) 和(rho) 是流体的粘度和密度,(K_e) 是线性体系中的有效达西渗透率,(beta _n)是广义非线性阻力。本文提出了这一关系的理论依据,并将其预测结果与福克海默方程的预测结果进行了比较。
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引用次数: 0
Mechanisms of Pore-Clogging Using a High-Resolution CFD-DEM Colloid Transport Model 利用高分辨率 CFD-DEM 胶体输送模型分析孔隙积水机理
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-03-13 DOI: 10.1007/s11242-024-02072-1
Shitao Liu, Igor Shikhov, Christoph Arns

Colloidal transport and clogging in porous media is a phenomenon of critical importance in many branches of applied sciences and engineering. It involves multiple types of interactions that span from the sub-colloid scale (electrochemical interactions) up to the pore-scale (bridging), thus challenging the development of representative modelling. So far published simulation results of colloidal or particulate transport are based on either reduced set of forces or spatial dimensions. Here we present an approach enabling to overcome both computational and physical limitations posed by a problem of 3D colloidal transport in porous media. An adaptive octree mesh is introduced to a coupled CFD and DEM method while enabling tracking of individual colloids. Flow fields are calculated at a coarser scale throughout the domain, and at fine-scale around colloids. The approach accounts for all major interactions in such a system: elastic, electrostatic, and hydrodynamic forces acting between colloids, as well as colloids and the collector surface. The method is demonstrated for a single throat model made of four spherical segments, and the impact of clogging is reported in terms of the evolution of the critical path diameter for percolation and permeability. We identified four stages of clogging development depending on position and time of individual colloid entrapment, which in turn correlates to a cluster evolution and local transport.

多孔介质中的胶体迁移和堵塞现象在应用科学和工程学的许多分支中都至关重要。它涉及从亚胶体尺度(电化学相互作用)到孔隙尺度(架桥)的多种类型的相互作用,因此对开发具有代表性的模型提出了挑战。迄今为止,已发表的胶体或微粒传输模拟结果都是基于力或空间维度的缩减集。在此,我们提出一种方法,可以克服多孔介质中三维胶体迁移问题带来的计算和物理限制。我们将自适应八叉网格引入耦合 CFD 和 DEM 方法,同时实现对单个胶体的跟踪。流场在整个域中以较粗的尺度计算,在胶体周围以较细的尺度计算。该方法考虑到了此类系统中的所有主要相互作用:胶体之间的弹性力、静电力和流体动力,以及胶体和收集器表面。该方法在由四个球形部分组成的单喉管模型中进行了演示,并从渗流和渗透性临界路径直径的演变角度报告了堵塞的影响。我们确定了堵塞发展的四个阶段,这取决于单个胶体被截留的位置和时间,进而与集束演变和局部传输相关联。
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引用次数: 0
Microscopic Localisation of Hydrophilically Oriented Pore Bodies and Throats in Hydrophobised Porous Materials 亲水性多孔材料中亲水方向孔体和孔口的显微定位
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-03-08 DOI: 10.1007/s11242-024-02069-w
Daan Deckers, Yanshen Zhu, Erin Koos, Hans Janssen

Internal insulation of the building envelope is a prime topic in building physics, due to the risk of moisture problems that this technique entails. As a remedy to these problems, the application of a water-repellent agent, which reduces the amount of absorbed wind-driven rain, has become popular in recent years. When such an agent is applied on a building material, it penetrates the pore network of the material, hereby attaching itself to the pore surfaces and rendering them hydrophobic. It is generally believed that some smaller pores can remain hydrophilic due to the inability of the agent to enter. An in-depth microscopic investigation towards these hydrophilic pores, however, has never been performed. Since direct visualisation of the polymer chains was proven impossible, this paper locates the hydrophilic (parts of) pores in a material, hydrophobised with 3 different water-repellent agents, by imaging the moisture storage at pore level using X-ray computed tomography images at different stages of the desaturation process. While completely hydrophilic pore bodies and throats are not found in the studied material, water storage remains possible in hydrophilic corners of hydrophobised pore bodies and throats. These corner islands are less present than in hydrophilic media and do not form a continuous liquid flow path. Therefore, they provide possible locations for little moisture storage but do not contribute notably to moisture flow.

建筑围护结构的内部隔热是建筑物理学中的一个重要课题,因为这种技术有可能带来潮湿问题。为了解决这些问题,近年来流行使用憎水剂,这种憎水剂可以减少风吹雨淋的吸收量。当在建筑材料上使用这种憎水剂时,它会渗透到材料的孔隙网络中,从而附着在孔隙表面,使其具有憎水性。一般认为,由于药剂无法进入,一些较小的孔隙可以保持亲水性。然而,对这些亲水孔隙的深入微观研究还从未进行过。由于无法对聚合物链进行直接观察,本文使用 X 射线计算机断层扫描图像,在脱饱和过程的不同阶段对孔隙水平的水分储存情况进行成像,从而确定了使用 3 种不同憎水剂进行憎水处理的材料中亲水孔隙(部分)的位置。虽然在所研究的材料中没有发现完全亲水的孔体和孔喉,但在疏水孔体和孔喉的亲水角落仍有可能储水。与亲水介质相比,这些角岛的存在较少,而且不会形成连续的液体流动路径。因此,它们可以提供少量的水分存储位置,但不会对水分流动产生显著影响。
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引用次数: 0
Pore-Scale and Upscaled Investigations of Release and Transport of Lithium in Organic-Rich Shales 富有机页岩中锂的释放和迁移的孔隙尺度和放大研究
IF 2.7 3区 工程技术 Q2 Chemical Engineering Pub Date : 2024-03-08 DOI: 10.1007/s11242-024-02071-2
Jiahui You, Kyung Jae Lee

To meet the extensive demand for lithium (Li) for rechargeable batteries, it is crucial to enhance Li production by diversifying its resources. Recent studies have found that produced water from shale reservoirs contains various organic and inorganic components, including a significant amount of Li. In this study, findings from hydrothermal reaction experiments were analyzed to fully understand the release of Li from organic-rich shale rock. Subsequently, numerical algorithms were developed for both pore-scale and continuum-scale models to simulate the long-term behavior of Li in shale brines. The experimental conditions considered four different hydrothermal solutions, including the solutions of KCl, MgCl2, CaCl2, and NaCl with various concentrations under the temperature of 130 °C, 165 °C, and 200 °C. The release of Li from shale rock into fluid was regarded as a chemical interaction of cation exchange between rock and fluid. The reactive transport pore-scale and upscaled continuum-scale models were developed by coupling the chemical reaction model of Li interaction between rock and fluid. The model was first implemented to investigate the release and transport of Li in the pore scale. Continuum-scale properties, such as effective diffusivity coefficients and Li release rate, were obtained as the field-averaged pore-scale modeling results. These properties were used as the input data for the upscaled continuum-scale simulation. The findings of this study are expected to provide new insight into the production of Li from shale brines by elucidating the release, fate, and transport of Li in subsurface formations.

为了满足可充电电池对锂(Li)的广泛需求,通过多样化的资源来提高锂的产量至关重要。最近的研究发现,页岩储层的产水含有各种有机和无机成分,其中包括大量的锂。本研究分析了热液反应实验的结果,以全面了解富含有机物的页岩释放锂的情况。随后,开发了孔隙尺度和连续尺度模型的数值算法,以模拟锂在页岩盐水中的长期行为。实验条件考虑了四种不同的热液溶液,包括不同浓度的 KCl、MgCl2、CaCl2 和 NaCl 溶液,温度分别为 130 ℃、165 ℃ 和 200 ℃。锂从页岩释放到流体中被视为岩石与流体之间阳离子交换的化学作用。通过耦合锂在岩石和流体之间相互作用的化学反应模型,建立了反应输运孔隙尺度和放大连续尺度模型。该模型首先用于研究 Li 在孔隙尺度上的释放和迁移。根据现场平均孔隙尺度建模结果,获得了连续尺度属性,如有效扩散系数和锂释放率。这些属性被用作放大连续尺度模拟的输入数据。通过阐明锂在地下地层中的释放、归宿和迁移,这项研究的结果有望为页岩盐水中锂离子的生产提供新的见解。
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引用次数: 0
期刊
Transport in Porous Media
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