首页 > 最新文献

Transport in Porous Media最新文献

英文 中文
Darcy–Bénard Convection in the Presence of Feedback Control and Temperature Modulation 反馈控制和温度调制下的达西-巴姆纳德对流
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-12 DOI: 10.1007/s11242-026-02293-6
Vinit Vinod Revankar, M. S. Jagadeesh Kumar

Temperature modulation effect on the linear stability analysis of Darcy–Bénard convection setup with feedback control and Robin boundary condition on temperature is investigated. The upper and lower plates are assumed to be impermeable. The combination of the Galerkin method, the Maclaurin series expansion, and the Newton–Raphson method for multiple variables is employed to calculate the stationary Rayleigh number. The differential operator method is employed to investigate the effect of temperature modulation on stability of the system. The observations from the study confirm that the effect of feedback control on the system in the presence of temperature modulation is to stabilize the motion. An increase in the Biot number signifies a transition of the thermal boundary condition from an insulating surface to an isothermal surface. This enhanced thermal coupling at the boundary promotes more efficient heat exchange, which suppresses thermal disturbances and thereby stabilizes the system.

研究了温度调制对具有反馈控制和温度Robin边界条件的darcy - b对流装置线性稳定性分析的影响。假定上下板是不透水的。采用Galerkin法、Maclaurin级数展开法和多变量牛顿-拉夫森法相结合的方法计算平稳瑞利数。采用微分算子方法研究了温度调制对系统稳定性的影响。研究结果证实,在存在温度调制的情况下,反馈控制对系统的作用是稳定运动。Biot数的增加表明热边界条件从绝缘表面向等温表面转变。这种在边界处增强的热耦合促进了更有效的热交换,从而抑制了热干扰,从而稳定了系统。
{"title":"Darcy–Bénard Convection in the Presence of Feedback Control and Temperature Modulation","authors":"Vinit Vinod Revankar,&nbsp;M. S. Jagadeesh Kumar","doi":"10.1007/s11242-026-02293-6","DOIUrl":"10.1007/s11242-026-02293-6","url":null,"abstract":"<div><p>Temperature modulation effect on the linear stability analysis of Darcy–Bénard convection setup with feedback control and Robin boundary condition on temperature is investigated. The upper and lower plates are assumed to be impermeable. The combination of the Galerkin method, the Maclaurin series expansion, and the Newton–Raphson method for multiple variables is employed to calculate the stationary Rayleigh number. The differential operator method is employed to investigate the effect of temperature modulation on stability of the system. The observations from the study confirm that the effect of feedback control on the system in the presence of temperature modulation is to stabilize the motion. An increase in the Biot number signifies a transition of the thermal boundary condition from an insulating surface to an isothermal surface. This enhanced thermal coupling at the boundary promotes more efficient heat exchange, which suppresses thermal disturbances and thereby stabilizes the system.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147338483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adaptive Time-Stepping and Machine Learning Approach for Pore-Scale Reactive Transport Simulations 孔隙尺度反应输运模拟的自适应时间步进和机器学习方法
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-12 DOI: 10.1007/s11242-026-02287-4
Micha P. Baur, Sergey V. Churakov, Nikolaos I. Prasianakis

Pore-scale reactive transport simulations are typically computationally very expensive, which limits their application to complex heterogeneous systems. To solve the computational bottleneck, an adaptive time-stepping algorithm is developed and combined with machine learning-derived surrogate models for geochemical calculations. The time-step is adapted by monitoring the evolution of the diffusion field and the precipitation reactions and by exploiting intermediate stationary states of the system. The algorithm is benchmarked on a system relevant to cement–claystone interaction with the geochemical reaction being the precipitation of Calcium-Silicate-Hydrates (C-S-H) in the pore space of a claystone. The precipitation of C-S-H is modeled as a solid solution, and it is possible to calculate and trace the local Ca/Si ratio of C-S-H, as well as the local amount of gel porosity. In the reactive transport simulations presented here, the geochemical surrogate models alone lead to acceleration factors of up to two orders of magnitude. The adaptive time-stepping algorithm leads to an additional acceleration of three to five orders of magnitude maintaining the relative deviation below 2%. The overall combined acceleration is demonstrated to be six to seven orders of magnitude having a profound impact and opening new computational avenues.

孔隙尺度反应输运模拟通常在计算上非常昂贵,这限制了它们在复杂非均质系统中的应用。为了解决计算瓶颈,开发了一种自适应时间步进算法,并将其与机器学习衍生的地球化学计算代理模型相结合。通过监测扩散场和沉淀反应的演变以及利用系统的中间稳定状态来调整时间步长。该算法的基准是与水泥-粘土岩相互作用有关的系统,地球化学反应是粘土岩孔隙中钙硅酸盐水合物(C-S-H)的沉淀。C-S-H的析出模型为固溶体,可以计算和跟踪C-S-H的局部Ca/Si比以及局部凝胶孔隙率。在这里提出的反应性输运模拟中,仅地球化学替代模型就导致加速因子高达两个数量级。采用自适应时间步进算法可使系统的附加加速度提高3 ~ 5个数量级,使相对误差保持在2%以下。总体的综合加速度被证明是6到7个数量级,具有深远的影响,并开辟了新的计算途径。
{"title":"Adaptive Time-Stepping and Machine Learning Approach for Pore-Scale Reactive Transport Simulations","authors":"Micha P. Baur,&nbsp;Sergey V. Churakov,&nbsp;Nikolaos I. Prasianakis","doi":"10.1007/s11242-026-02287-4","DOIUrl":"10.1007/s11242-026-02287-4","url":null,"abstract":"<div><p>Pore-scale reactive transport simulations are typically computationally very expensive, which limits their application to complex heterogeneous systems. To solve the computational bottleneck, an adaptive time-stepping algorithm is developed and combined with machine learning-derived surrogate models for geochemical calculations. The time-step is adapted by monitoring the evolution of the diffusion field and the precipitation reactions and by exploiting intermediate stationary states of the system. The algorithm is benchmarked on a system relevant to cement–claystone interaction with the geochemical reaction being the precipitation of Calcium-Silicate-Hydrates (C-S-H) in the pore space of a claystone. The precipitation of C-S-H is modeled as a solid solution, and it is possible to calculate and trace the local Ca/Si ratio of C-S-H, as well as the local amount of gel porosity. In the reactive transport simulations presented here, the geochemical surrogate models alone lead to acceleration factors of up to two orders of magnitude. The adaptive time-stepping algorithm leads to an additional acceleration of three to five orders of magnitude maintaining the relative deviation below 2%. The overall combined acceleration is demonstrated to be six to seven orders of magnitude having a profound impact and opening new computational avenues.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147338591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Penetrative Electrothermal Convection in Anisotropic Porous Media: Role of Velocity and Thermal Boundary Conditions 各向异性多孔介质中的渗透电热对流:速度和热边界条件的作用
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-026-02286-5
B. Arpitha Raju, C. E. Nanjundappa, I. S. Shivakumara

This study examines penetrative electrothermal convection driven by uniform internal heat generation in a horizontal layer of dielectric fluid-saturated anisotropic Brinkman porous medium subjected to a uniform AC electric field. Anisotropy in permeability and thermal diffusivity is incorporated, with the vertical permeability fixed at twice the horizontal value, while the thermal anisotropy parameter is varied. The boundaries are taken to be either rigid or stress-free, with an adiabatic lower surface and an upper surface subject to a Robin thermal condition. A linear stability analysis yields a generalized eigenvalue problem, which is solved numerically using a Galerkin method. The principle of exchange of stabilities is shown to hold for rigid–rigid, rigid–free and free–free boundary combinations. Increasing the AC electric Rayleigh number and the Darcy number advances the onset of convection, whereas larger thermal anisotropy and Biot numbers delay instability. Velocity boundary conditions exert a significant quantitative influence, with rigid boundaries being the most stabilizing. As a limiting case, pure electroconvection in the absence of buoyancy is also considered. Although the qualitative trends remain similar to those in the coupled electrothermal regime, substantially higher critical AC electric Rayleigh numbers and wavenumbers are required to trigger instability, reflecting the need for electric forcing alone to overcome viscous and porous dissipation.

本研究考察了在均匀交流电场作用下介电流体饱和的各向异性布林克曼多孔介质水平层由均匀内热驱动的渗透电热对流。考虑渗透率和热扩散系数的各向异性,垂直渗透率固定为水平渗透率的两倍,而热各向异性参数是变化的。边界要么是刚性的,要么是无应力的,下表面是绝热的,上表面是受Robin热条件约束的。线性稳定性分析得到一个广义特征值问题,用伽辽金方法对其进行数值求解。稳定性交换原理适用于刚性-刚性、刚性-自由和自由-自由边界组合。增大交流电瑞利数和达西数可促进对流的发生,而增大热各向异性和Biot数可延缓不稳定性。速度边界条件具有显著的定量影响,其中刚性边界最稳定。作为一种极限情况,也考虑了无浮力的纯电对流。尽管定性趋势与耦合电热状态下的趋势相似,但需要更高的临界交流电瑞利数和波数来触发不稳定性,这反映了需要单独的电强迫来克服粘性和多孔耗散。
{"title":"Penetrative Electrothermal Convection in Anisotropic Porous Media: Role of Velocity and Thermal Boundary Conditions","authors":"B. Arpitha Raju,&nbsp;C. E. Nanjundappa,&nbsp;I. S. Shivakumara","doi":"10.1007/s11242-026-02286-5","DOIUrl":"10.1007/s11242-026-02286-5","url":null,"abstract":"<div><p>This study examines penetrative electrothermal convection driven by uniform internal heat generation in a horizontal layer of dielectric fluid-saturated anisotropic Brinkman porous medium subjected to a uniform AC electric field. Anisotropy in permeability and thermal diffusivity is incorporated, with the vertical permeability fixed at twice the horizontal value, while the thermal anisotropy parameter is varied. The boundaries are taken to be either rigid or stress-free, with an adiabatic lower surface and an upper surface subject to a Robin thermal condition. A linear stability analysis yields a generalized eigenvalue problem, which is solved numerically using a Galerkin method. The principle of exchange of stabilities is shown to hold for rigid–rigid, rigid–free and free–free boundary combinations. Increasing the AC electric Rayleigh number and the Darcy number advances the onset of convection, whereas larger thermal anisotropy and Biot numbers delay instability. Velocity boundary conditions exert a significant quantitative influence, with rigid boundaries being the most stabilizing. As a limiting case, pure electroconvection in the absence of buoyancy is also considered. Although the qualitative trends remain similar to those in the coupled electrothermal regime, substantially higher critical AC electric Rayleigh numbers and wavenumbers are required to trigger instability, reflecting the need for electric forcing alone to overcome viscous and porous dissipation.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the Stability of Triple-Diffusive Convection in a Voigt Fluid-Saturated Darcy–Brinkman Porous Medium Voigt流体饱和Darcy-Brinkman多孔介质中三扩散对流的稳定性
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-026-02289-2
K. R. Raghunatha,  Sangamesh, C. Pragathi, I. S. Shivakumara

The linear and weakly nonlinear instability of triple-diffusive convection in a Darcy–Brinkman porous layer saturated with a Navier–Stokes–Voigt fluid is investigated analytically. The instability is driven by competing thermal and solutal buoyancy forces in the presence of viscoelastic stresses arising from a Voigt-type strain-rate regularization. Linear instability analysis reveals that the Kelvin–Voigt parameter plays a decisive role in oscillatory convection, exerting either stabilizing or destabilizing effects depending on the solute Darcy–Rayleigh number. A distinctive feature of the system is the emergence, under certain parametric conditions, of a disconnected closed oscillatory instability branch separate from the stationary one. In this regime, the neutral stability boundary is defined by three distinct thermal Darcy–Rayleigh numbers, in sharp contrast to the single threshold that characterizes the corresponding double-diffusive system. A weakly nonlinear stability analysis yields a cubic complex Landau amplitude equation governing the evolution of the disturbance amplitude, suggesting the possibility of subcritical bifurcations under certain parametric conditions. Heat and mass transport are quantified using time- and area-averaged Nusselt and Sherwood numbers, which increase with the Darcy–Prandtl number but decrease with increasing Darcy number and the effective heat capacity group, while variations in the Kelvin–Voigt parameter induce crossover behavior in the transport characteristics. These results clarify the subtle interplay between buoyancy, diffusion, and viscoelastic effects in regulating convection in triply diffusive porous media.

用解析方法研究了饱和Navier-Stokes-Voigt流体的Darcy-Brinkman多孔层中三扩散对流的线性和弱非线性不稳定性。在voigt型应变率正则化引起的粘弹性应力存在的情况下,热力和溶质浮力相互竞争驱动了不稳定性。线性不稳定性分析表明,Kelvin-Voigt参数在振荡对流中起着决定性的作用,根据溶质达西-瑞利数的不同发挥稳定或不稳定的作用。该系统的一个显著特征是,在一定的参数条件下,出现了一个与平稳分支分离的断开的封闭振荡不稳定分支。在这种情况下,中性稳定边界由三个不同的热达西-瑞利数定义,与对应的双扩散系统的单一阈值形成鲜明对比。弱非线性稳定性分析得到一个控制扰动振幅演变的三次复朗道振幅方程,表明在某些参数条件下存在亚临界分岔的可能性。利用时间平均和面积平均的Nusselt数和Sherwood数量化热量和质量输运,二者随Darcy - prandtl数的增加而增加,随Darcy数和有效热容群的增加而减少,而Kelvin-Voigt参数的变化会引起输运特性的交叉行为。这些结果阐明了浮力、扩散和粘弹性效应在调节三扩散多孔介质对流中的微妙相互作用。
{"title":"On the Stability of Triple-Diffusive Convection in a Voigt Fluid-Saturated Darcy–Brinkman Porous Medium","authors":"K. R. Raghunatha,&nbsp; Sangamesh,&nbsp;C. Pragathi,&nbsp;I. S. Shivakumara","doi":"10.1007/s11242-026-02289-2","DOIUrl":"10.1007/s11242-026-02289-2","url":null,"abstract":"<div><p>The linear and weakly nonlinear instability of triple-diffusive convection in a Darcy–Brinkman porous layer saturated with a Navier–Stokes–Voigt fluid is investigated analytically. The instability is driven by competing thermal and solutal buoyancy forces in the presence of viscoelastic stresses arising from a Voigt-type strain-rate regularization. Linear instability analysis reveals that the Kelvin–Voigt parameter plays a decisive role in oscillatory convection, exerting either stabilizing or destabilizing effects depending on the solute Darcy–Rayleigh number. A distinctive feature of the system is the emergence, under certain parametric conditions, of a disconnected closed oscillatory instability branch separate from the stationary one. In this regime, the neutral stability boundary is defined by three distinct thermal Darcy–Rayleigh numbers, in sharp contrast to the single threshold that characterizes the corresponding double-diffusive system. A weakly nonlinear stability analysis yields a cubic complex Landau amplitude equation governing the evolution of the disturbance amplitude, suggesting the possibility of subcritical bifurcations under certain parametric conditions. Heat and mass transport are quantified using time- and area-averaged Nusselt and Sherwood numbers, which increase with the Darcy–Prandtl number but decrease with increasing Darcy number and the effective heat capacity group, while variations in the Kelvin–Voigt parameter induce crossover behavior in the transport characteristics. These results clarify the subtle interplay between buoyancy, diffusion, and viscoelastic effects in regulating convection in triply diffusive porous media.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Time-Resolved X-ray and Neutron Imaging of Brine Percolation and Liquefaction in an Ultra-Soft Sandstone 超软砂岩卤水渗流和液化的时间分辨x射线和中子成像
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-025-02284-z
Fazel Mirzaei, Mukul Jaiswal, Jessica Ann Zeman, Kim Robert Tekseth, Benoît Cordonnier, Nicolaine Agofack, Pierre Cerasi, François Renard, Basab Chattopadhyay, Dag Werner Breiby

The inherent instability and risk of liquefaction associated with unstable glaciomarine clay are both scientifically intriguing and societally important. Stabilizing sensitive soils is increasingly necessary with the unfolding climate crisis, which leads to wilder and wetter weather. The relevant length scales extend from nanometer-sized pores to kilometer-sized geological features. Laboratory experiments are important for gaining a better understanding of these phenomena. Here, we present a study of the ultra-soft sandstone Saltwash South, which essentially consists of quartz particles glued together by clay, as a proxy for nanoscopically fine-grained sensitive soil to facilitate time-resolved imaging of the onset of activation and liquefaction. By employing in situ time-resolved combined X-ray and neutron computed tomography (CT), we visualize the structural deformation caused by the presence of water and salts. While neutron imaging was sensitive to the presence of normal and heavy water, simultaneous X-ray imaging was used to measure the porous structure, swelling, and initial liquefaction response of the consolidated rock. Uniform expansion was observed in regions exposed to water, reflecting clay swelling and disaggregation. In tightly confined samples, the swelling and disaggregation were suppressed. Finally, we discuss future perspectives of this promising approach to studying liquefaction phenomena in porous media.

与不稳定冰川期海洋黏土相关的固有不稳定性和液化风险在科学上和社会上都具有重要意义。随着气候危机的发展,稳定敏感的土壤变得越来越必要,气候危机导致了更恶劣和更潮湿的天气。相关的长度尺度从纳米级的孔隙到千米级的地质特征。实验室实验对于更好地理解这些现象是很重要的。在这里,我们提出了一项研究超软砂岩盐水南,它基本上由粘土粘在一起的石英颗粒组成,作为纳米级细粒度敏感土壤的代表,以促进激活和液化开始的时间分辨成像。通过使用现场时间分辨组合x射线和中子计算机断层扫描(CT),我们可视化了由水和盐的存在引起的结构变形。中子成像对正常水和重水的存在很敏感,同时使用x射线成像来测量固结岩石的孔隙结构、膨胀和初始液化响应。在接触水的区域观察到均匀的膨胀,反映了粘土的膨胀和分解。在密闭的样品中,膨胀和分解被抑制。最后,我们讨论了这种有前途的方法在多孔介质中研究液化现象的未来前景。
{"title":"Time-Resolved X-ray and Neutron Imaging of Brine Percolation and Liquefaction in an Ultra-Soft Sandstone","authors":"Fazel Mirzaei,&nbsp;Mukul Jaiswal,&nbsp;Jessica Ann Zeman,&nbsp;Kim Robert Tekseth,&nbsp;Benoît Cordonnier,&nbsp;Nicolaine Agofack,&nbsp;Pierre Cerasi,&nbsp;François Renard,&nbsp;Basab Chattopadhyay,&nbsp;Dag Werner Breiby","doi":"10.1007/s11242-025-02284-z","DOIUrl":"10.1007/s11242-025-02284-z","url":null,"abstract":"<div><p>The inherent instability and risk of liquefaction associated with unstable glaciomarine clay are both scientifically intriguing and societally important. Stabilizing sensitive soils is increasingly necessary with the unfolding climate crisis, which leads to wilder and wetter weather. The relevant length scales extend from nanometer-sized pores to kilometer-sized geological features. Laboratory experiments are important for gaining a better understanding of these phenomena. Here, we present a study of the ultra-soft sandstone <i>Saltwash South</i>, which essentially consists of quartz particles glued together by clay, as a proxy for nanoscopically fine-grained sensitive soil to facilitate time-resolved imaging of the onset of activation and liquefaction. By employing in situ time-resolved combined X-ray and neutron computed tomography (CT), we visualize the structural deformation caused by the presence of water and salts. While neutron imaging was sensitive to the presence of normal and heavy water, simultaneous X-ray imaging was used to measure the porous structure, swelling, and initial liquefaction response of the consolidated rock. Uniform expansion was observed in regions exposed to water, reflecting clay swelling and disaggregation. In tightly confined samples, the swelling and disaggregation were suppressed. Finally, we discuss future perspectives of this promising approach to studying liquefaction phenomena in porous media.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11242-025-02284-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SLM-Fabricated CuCrZr TPMS Heat Exchangers: Influence of Structural Design on Fluid Transport Characteristics slm制造CuCrZr TPMS换热器:结构设计对流体输运特性的影响
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-026-02288-3
Xiaoqing Yang, Yaqin Yang, Chao Suo, Bin Liu, Xueli Chen, Zezhou Kuai, Yaoxian Zhang, Yuan Gao, Zhonghua Li, Rui Wang

The hydrodynamic performance of porous structures is paramount for the efficiency of compact heat exchangers. This study investigates the fluid transport characteristics of three types of triply periodic minimal surface (TPMS) structures (Diamond, Primitive, and IWP) fabricated from CuCrZr alloy via selective laser melting (SLM). Combining computational fluid dynamics (CFD) simulations with experimental validation, we systematically elucidate the influence of structure and unit cell density on key performance metrics, including pressure drop, friction factor, and permeability. Results reveal that the Diamond structure, with the lowest inlet porosity (23.07%), exhibits the most complex flow patterns—characterized by significant flow separation, enhanced vorticity, and superior flow uniformity—leading to the highest pressure drop and friction factor, but the lowest permeability. In contrast, the primitive and IWP structures, with higher inlet porosities (46.34% and 50.07%, respectively), offer lower flow resistance. Furthermore, increasing the unit cell count for a fixed overall porosity amplifies these effects, resulting in a higher pressure drop per unit length and reduced permeability due to more frequent flow disturbances. The experimental measurements of pressure drop align well with numerical predictions, with discrepancies attributed to a reduction in effective functional porosity caused by adherent unmelted particles during the SLM process. This work provides fundamental insights into the structure-transport relationships in TPMS architectures and offers practical guidelines for designing high-performance heat exchangers for applications under extreme conditions, such as deep-sea thermal management.

多孔结构的水动力性能对紧凑式换热器的效率至关重要。研究了CuCrZr合金选择性激光熔化(SLM)制备的三种三周期最小表面结构(Diamond、Primitive和IWP)的流体输运特性。结合计算流体动力学(CFD)模拟和实验验证,我们系统地阐明了结构和单胞密度对关键性能指标的影响,包括压降、摩擦系数和渗透率。结果表明,进口孔隙度最低(23.07%)的菱形结构表现出最复杂的流动模式,具有明显的流动分离、涡度增强和较好的流动均匀性,导致压降和摩擦系数最高,但渗透率最低。相比之下,原始结构和IWP结构具有较高的进口孔隙率(分别为46.34%和50.07%),其流动阻力较小。此外,在总孔隙度固定的情况下,增加井芯数量会放大这些影响,导致单位长度的压降更高,并且由于更频繁的流动干扰而降低渗透率。压降的实验测量结果与数值预测结果吻合得很好,差异归因于在SLM过程中附着的未熔化颗粒导致的有效功能孔隙率降低。这项工作为TPMS体系结构中的结构-传输关系提供了基本的见解,并为在极端条件下(如深海热管理)设计高性能热交换器提供了实用指南。
{"title":"SLM-Fabricated CuCrZr TPMS Heat Exchangers: Influence of Structural Design on Fluid Transport Characteristics","authors":"Xiaoqing Yang,&nbsp;Yaqin Yang,&nbsp;Chao Suo,&nbsp;Bin Liu,&nbsp;Xueli Chen,&nbsp;Zezhou Kuai,&nbsp;Yaoxian Zhang,&nbsp;Yuan Gao,&nbsp;Zhonghua Li,&nbsp;Rui Wang","doi":"10.1007/s11242-026-02288-3","DOIUrl":"10.1007/s11242-026-02288-3","url":null,"abstract":"<div><p>The hydrodynamic performance of porous structures is paramount for the efficiency of compact heat exchangers. This study investigates the fluid transport characteristics of three types of triply periodic minimal surface (TPMS) structures (Diamond, Primitive, and IWP) fabricated from CuCrZr alloy via selective laser melting (SLM). Combining computational fluid dynamics (CFD) simulations with experimental validation, we systematically elucidate the influence of structure and unit cell density on key performance metrics, including pressure drop, friction factor, and permeability. Results reveal that the Diamond structure, with the lowest inlet porosity (23.07%), exhibits the most complex flow patterns—characterized by significant flow separation, enhanced vorticity, and superior flow uniformity—leading to the highest pressure drop and friction factor, but the lowest permeability. In contrast, the primitive and IWP structures, with higher inlet porosities (46.34% and 50.07%, respectively), offer lower flow resistance. Furthermore, increasing the unit cell count for a fixed overall porosity amplifies these effects, resulting in a higher pressure drop per unit length and reduced permeability due to more frequent flow disturbances. The experimental measurements of pressure drop align well with numerical predictions, with discrepancies attributed to a reduction in effective functional porosity caused by adherent unmelted particles during the SLM process. This work provides fundamental insights into the structure-transport relationships in TPMS architectures and offers practical guidelines for designing high-performance heat exchangers for applications under extreme conditions, such as deep-sea thermal management.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stability of Double-diffusive Mixed Convection in a Vertical Pipe Filled by Porous Medium 多孔介质垂直管内双扩散混合对流的稳定性
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-025-02276-z
Saurabh Kapoor, Durgaprasad Nayak

Thermal gradients in many natural environments, such as undersea hot springs and hydrothermal vents, are often accompanied by variations in the concentration of chemical compounds carried into the surrounding seawater. This interaction gives rise to a phenomenon known as thermosolutal mixed convection. To investigate the underlying physical mechanisms in such systems, a vertical pipe filled with saline water through a porous medium is considered. The non-Darcy Brinkman–Forchheimer extended model is employed, assuming that the saturated porous medium is in a thermal equilibrium state. The instability boundary curve reveals three distinct regimes: (i) the Rayleigh–Taylor (R–T) phenomenon, (ii) a nonlinear variation of mixed convection on a log–log scale and (iii) a linear variation on a log–log scale in the pipe. These regimes occur at specific Reynolds numbers. The instability mechanism of the base flow is examined using the spectral collocation technique. The present study focuses on the instability of a dense porous medium, where the Darcy–Forchheimer drag is incorporated in the momentum equation. A linear stability analysis is performed for a wide range of Darcy numbers ((10^{-8}) to (10^{-5})). Similar to cross-diffusive free convection in a vertical slot, a relationship is observed between the solutal Rayleigh number ((Ra_S)) and the thermal Rayleigh number ((Ra_T)). A hyperbolic relationship between the threshold values of (Ra_S) and Da is found at (Re = 1000) for the upper limit of (Ra_S) in the first regime, expressed as (Ra_S) Da =4.9 x (10^{-4}). Simulations of secondary flow profiles are also presented at the critical state for all three regimes.

在许多自然环境中,如海底温泉和热液喷口,温度梯度往往伴随着进入周围海水的化合物浓度的变化。这种相互作用产生了一种称为热溶质混合对流的现象。为了研究这些系统中潜在的物理机制,考虑了通过多孔介质填充盐水的垂直管道。采用非达西Brinkman-Forchheimer扩展模型,假设饱和多孔介质处于热平衡状态。不稳定性边界曲线揭示了三种不同的状态:(i)瑞利-泰勒(R-T)现象,(ii)对数-对数尺度上混合对流的非线性变化,以及(iii)管道中对数-对数尺度上的线性变化。这些状态发生在特定的雷诺数下。利用谱配点法分析了基流的失稳机理。本研究的重点是致密多孔介质的不稳定性,其中Darcy-Forchheimer阻力被纳入动量方程。线性稳定性分析进行了大范围的达西数((10^{-8})至(10^{-5}))。与垂直槽内的交叉扩散自由对流类似,溶质瑞利数((Ra_S))与热瑞利数((Ra_T))之间存在一定的关系。(Ra_S)和Da的阈值之间的双曲关系是在(Re = 1000)中发现的,在第一状态中(Ra_S)的上限,表示为(Ra_S) Da =4.9 x (10^{-4})。文中还对三种状态下的二次流进行了模拟。
{"title":"Stability of Double-diffusive Mixed Convection in a Vertical Pipe Filled by Porous Medium","authors":"Saurabh Kapoor,&nbsp;Durgaprasad Nayak","doi":"10.1007/s11242-025-02276-z","DOIUrl":"10.1007/s11242-025-02276-z","url":null,"abstract":"<div><p>Thermal gradients in many natural environments, such as undersea hot springs and hydrothermal vents, are often accompanied by variations in the concentration of chemical compounds carried into the surrounding seawater. This interaction gives rise to a phenomenon known as thermosolutal mixed convection. To investigate the underlying physical mechanisms in such systems, a vertical pipe filled with saline water through a porous medium is considered. The non-Darcy Brinkman–Forchheimer extended model is employed, assuming that the saturated porous medium is in a thermal equilibrium state. The instability boundary curve reveals three distinct regimes: (i) the Rayleigh–Taylor (R–T) phenomenon, (ii) a nonlinear variation of mixed convection on a log–log scale and (iii) a linear variation on a log–log scale in the pipe. These regimes occur at specific Reynolds numbers. The instability mechanism of the base flow is examined using the spectral collocation technique. The present study focuses on the instability of a dense porous medium, where the Darcy–Forchheimer drag is incorporated in the momentum equation. A linear stability analysis is performed for a wide range of Darcy numbers (<span>(10^{-8})</span> to <span>(10^{-5})</span>). Similar to cross-diffusive free convection in a vertical slot, a relationship is observed between the solutal Rayleigh number (<span>(Ra_S)</span>) and the thermal Rayleigh number (<span>(Ra_T)</span>). A hyperbolic relationship between the threshold values of <span>(Ra_S)</span> and <i>Da</i> is found at <span>(Re = 1000)</span> for the upper limit of <span>(Ra_S)</span> in the first regime, expressed as <span>(Ra_S)</span> <i>Da</i> =4.9 x <span>(10^{-4})</span>. Simulations of secondary flow profiles are also presented at the critical state for all three regimes.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11242-025-02276-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Near-surface Winds and Soil Pore Air Pressure Fluctuations on Intra-soil Gas Transport Mechanisms 近地面风和土壤孔隙气压波动对土壤内气体输送机制的影响
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-026-02292-7
Junguo Hu, Taolve Chen, Lingxia Feng, Junjie Jiang, Chao Zhu, Wei Jiang

Soil carbon flux is the main source of atmospheric CO2. An accurate understanding of the soil CO2 transport process is of substantial significance for the study of global carbon flux and the prediction of future climate change. In this study, data on CO2 concentrations over time in five media under the influence of surface winds and pore air pressure fluctuations were analysed using (1) an analytical solution of the dispersive transport model and (2) a numerical solution of the advection transport model to accurately delineate the transport mechanisms that control soil gas transport. For loam and sandy soils, gas transport is mainly dominated by diffusion, and in highly permeable sand, gas transport changes from diffusion–dispersion transport to advection transport dominated by wind speed and pore air pressure fluctuations. The effects of surface wind and pore pressure fluctuations on advection velocity differed with depth. The pore pressure fluctuations had a stronger penetrating power. The ratio of the enhanced diffusion coefficient (De) to advection velocity(v) was effective in determining the transport mechanism driving gas transport within the medium, which is conducive to accurately modelling the release of CO2 from soils to improve the understanding and assessment of the global carbon cycle.

土壤碳通量是大气CO2的主要来源。准确认识土壤CO2输运过程对研究全球碳通量和预测未来气候变化具有重要意义。本研究利用(1)色散输运模式的解析解和(2)平流输运模式的数值解,分析了地表风和孔隙气压波动影响下5种介质中CO2浓度随时间变化的数据,以准确描绘控制土壤气体输运的输运机制。在壤土和沙土中,气体输运主要以扩散输运为主,在高渗透性砂土中,气体输运由扩散-分散输运转变为以风速和孔隙气压波动为主的平流输运。地表风和孔隙压波动对平流速度的影响随深度不同而不同。孔隙压力波动具有较强的穿透力。增强扩散系数(De)与平流速度(v)之比可以有效地确定驱动介质内气体输运的输运机制,这有利于准确模拟土壤中CO2的释放,提高对全球碳循环的认识和评估。
{"title":"Effects of Near-surface Winds and Soil Pore Air Pressure Fluctuations on Intra-soil Gas Transport Mechanisms","authors":"Junguo Hu,&nbsp;Taolve Chen,&nbsp;Lingxia Feng,&nbsp;Junjie Jiang,&nbsp;Chao Zhu,&nbsp;Wei Jiang","doi":"10.1007/s11242-026-02292-7","DOIUrl":"10.1007/s11242-026-02292-7","url":null,"abstract":"<div><p>Soil carbon flux is the main source of atmospheric CO<sub>2</sub>. An accurate understanding of the soil CO<sub>2</sub> transport process is of substantial significance for the study of global carbon flux and the prediction of future climate change. In this study, data on CO<sub>2</sub> concentrations over time in five media under the influence of surface winds and pore air pressure fluctuations were analysed using (1) an analytical solution of the dispersive transport model and (2) a numerical solution of the advection transport model to accurately delineate the transport mechanisms that control soil gas transport. For loam and sandy soils, gas transport is mainly dominated by diffusion, and in highly permeable sand, gas transport changes from diffusion–dispersion transport to advection transport dominated by wind speed and pore air pressure fluctuations. The effects of surface wind and pore pressure fluctuations on advection velocity differed with depth. The pore pressure fluctuations had a stronger penetrating power. The ratio of the enhanced diffusion coefficient (<i>D</i><sub><i>e</i></sub>) to advection velocity(<i>v</i>) was effective in determining the transport mechanism driving gas transport within the medium, which is conducive to accurately modelling the release of CO<sub>2</sub> from soils to improve the understanding and assessment of the global carbon cycle.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Backward Similarity Solution of the Boussinesq Groundwater Equation Boussinesq地下水方程的后向相似解
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-01 DOI: 10.1007/s11242-025-02285-y
Shuntaro Togo, Koichi Unami

Groundwater flow in an unconfined aquifer resting on a horizontal impermeable layer with a boundary condition of a rapid increase in the source water level is considered in this work. The newly introduced condition, referred to as the backward power law head condition, represents a situation where the water level in the adjacent water body increases more rapidly than do conventional problems, which can only represent a situation akin to a traveling wave under rising water level conditions, given its consideration of infinite time. This problem admits the similarity transformation which allows the nonlinear partial differential equation to be converted into a nonlinear ordinary differential equation via the Boltzmann transformation. The reduced boundary value problem is interpreted as the initial value problem for a system of ordinary differential equations, which can be numerically solved via Shampine’s method. The numerical solutions are in good agreement with Kalashinikov’s special solution, which is also introduced into the Boussinesq equation. We find that the solution is consistent with the limit of the forward power law head condition. The new approximate analytical solution and the associated wetting front position are derived by assuming that the solution has the form of quadratic polynomials, which enables the description of the time progression of a real front position. The obtained approximation is compared to Shampine’s solution to check the accuracy. Furthermore, the finite element method is applied to the original partial differential equation, which validates Shampine’s solution for use as a benchmark.

本文研究了在水平不透水层上的无承压含水层中,以源水位快速上升为边界条件下的地下水流动问题。新引入的条件被称为后向幂律水头条件,它代表了相邻水体中水位比常规问题上升得更快的情况,考虑到无限时间,它只能代表类似于水位上升条件下的行波的情况。这个问题允许相似变换,使得非线性偏微分方程可以通过玻尔兹曼变换转化为非线性常微分方程。将边值化简问题解释为常微分方程组的初值问题,用香平方法对其进行数值求解。数值解与卡拉什尼科夫特解很好地吻合,卡拉什尼科夫特解也被引入到Boussinesq方程中。我们发现解符合正幂律头部条件的极限。在假定解具有二次多项式形式的前提下,导出了新的近似解析解和相应的润湿锋面位置,从而能够描述真实锋面位置的时间进程。将得到的近似值与shammpine的解进行比较,以检验其准确性。将有限元法应用于原偏微分方程,验证了shammpine的解作为基准。
{"title":"Backward Similarity Solution of the Boussinesq Groundwater Equation","authors":"Shuntaro Togo,&nbsp;Koichi Unami","doi":"10.1007/s11242-025-02285-y","DOIUrl":"10.1007/s11242-025-02285-y","url":null,"abstract":"<div><p>Groundwater flow in an unconfined aquifer resting on a horizontal impermeable layer with a boundary condition of a rapid increase in the source water level is considered in this work. The newly introduced condition, referred to as the backward power law head condition, represents a situation where the water level in the adjacent water body increases more rapidly than do conventional problems, which can only represent a situation akin to a traveling wave under rising water level conditions, given its consideration of infinite time. This problem admits the similarity transformation which allows the nonlinear partial differential equation to be converted into a nonlinear ordinary differential equation via the Boltzmann transformation. The reduced boundary value problem is interpreted as the initial value problem for a system of ordinary differential equations, which can be numerically solved via Shampine’s method. The numerical solutions are in good agreement with Kalashinikov’s special solution, which is also introduced into the Boussinesq equation. We find that the solution is consistent with the limit of the forward power law head condition. The new approximate analytical solution and the associated wetting front position are derived by assuming that the solution has the form of quadratic polynomials, which enables the description of the time progression of a real front position. The obtained approximation is compared to Shampine’s solution to check the accuracy. Furthermore, the finite element method is applied to the original partial differential equation, which validates Shampine’s solution for use as a benchmark.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11242-025-02285-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis and Comparison of Natural Shear and Induced Tensile Fractures for Caprock Leakage Assessment 天然剪切裂缝与诱发张性裂缝在盖层渗漏评价中的分析与比较
IF 2.6 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-01-14 DOI: 10.1007/s11242-025-02283-0
Sahyuo Achuo Dze, Tomos Phillips, Reza Najafi-Silab, Sarah Perez, Tom Bultreys, Vladimir Novak, Christian M. Schlepütz, Veerle Cnudde, Florian Doster, Kamaljit Singh, Kevin Bisdom, Andreas Busch

The comparison between laboratory-induced and subsurface fractures, and their corresponding flow is still unclear. Here, we examine three natural shear fractures and two induced tensile fractures from the same low-permeability lithology. Using high-resolution synchrotron imaging, we extracted three-dimensional fracture void geometries to analyse aperture distributions, surface roughness, and spatial correlation patterns. We then compared measured fracture transmissivities against theoretical predictions from parallel-plate models (cubic law) and direct numerical simulations (DNS) of flow to evaluate consistency and uncertainties. We find that despite differences in heterogeneity, induced tensile and natural shear fractures can generally yield similar flow in caprocks. Our comparisons further indicate that the choice of flow estimation method can introduce more uncertainty than the fracture opening mode.

实验室诱发裂缝与地下裂缝的对比及其相应的流量尚不清楚。在这里,我们研究了来自同一低渗透岩性的三条天然剪切裂缝和两条诱导张性裂缝。利用高分辨率同步加速器成像,我们提取了三维裂缝孔隙几何形状,以分析孔径分布、表面粗糙度和空间相关模式。然后,我们将测量到的裂缝透射率与平行板模型(三次定律)和直接数值模拟(DNS)的理论预测进行了比较,以评估一致性和不确定性。我们发现,尽管非均质性存在差异,但在盖层中,诱导拉伸裂缝和天然剪切裂缝通常可以产生相似的流动。我们的比较进一步表明,流量估计方法的选择比裂缝张开方式带来的不确定性更大。
{"title":"Analysis and Comparison of Natural Shear and Induced Tensile Fractures for Caprock Leakage Assessment","authors":"Sahyuo Achuo Dze,&nbsp;Tomos Phillips,&nbsp;Reza Najafi-Silab,&nbsp;Sarah Perez,&nbsp;Tom Bultreys,&nbsp;Vladimir Novak,&nbsp;Christian M. Schlepütz,&nbsp;Veerle Cnudde,&nbsp;Florian Doster,&nbsp;Kamaljit Singh,&nbsp;Kevin Bisdom,&nbsp;Andreas Busch","doi":"10.1007/s11242-025-02283-0","DOIUrl":"10.1007/s11242-025-02283-0","url":null,"abstract":"<p>The comparison between laboratory-induced and subsurface fractures, and their corresponding flow is still unclear. Here, we examine three natural shear fractures and two induced tensile fractures from the same low-permeability lithology. Using high-resolution synchrotron imaging, we extracted three-dimensional fracture void geometries to analyse aperture distributions, surface roughness, and spatial correlation patterns. We then compared measured fracture transmissivities against theoretical predictions from parallel-plate models (cubic law) and direct numerical simulations (DNS) of flow to evaluate consistency and uncertainties. We find that despite differences in heterogeneity, induced tensile and natural shear fractures can generally yield similar flow in caprocks. Our comparisons further indicate that the choice of flow estimation method can introduce more uncertainty than the fracture opening mode.</p>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"153 2","pages":""},"PeriodicalIF":2.6,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11242-025-02283-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145983244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Transport in Porous Media
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1