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Pore-Scale Simulation of Interphase Multicomponent Mass Transfer Using a Non-Newtonian Model 利用非牛顿模型对相间多组分传质进行孔隙尺度模拟
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-23 DOI: 10.1007/s11242-024-02115-7
Alínia Rodrigues dos Santos, Matheus da Cunha Brito, Manoel Silvino Batalha de Araujo

This study investigates multiphase flow with non-Newtonian fluid at pore scale, using the Compressive Continuum Species Transfer (C-CST) method in a microchannel and 2D porous media, with emphasis on drainage and mass transfer between fluids through the Volume of Fluid (VOF) method. The object of study is the multiphase flow in oil reservoirs, where immiscible fluids coexist in the porous media. The use of recovery methods becomes relevant in scenarios of low reservoir energy or when the physical properties of the oil compromise the flow. The influence of petroleum rheology, especially heavy crude oil with non-Newtonian viscoelastic behaviour, is considered. Recovery methods, such as the injection of CO2, aim to optimize the flow by modifying the rheological properties of the fluid. This article aims to conduct a numerical analysis using the C-CST method with Direct Numerical Simulation (DNS) and volume tracking techniques to capture an interface between fluids. The main objective is to numerically implement a non-Newtonian rheological model in the linear momentum conservation equation, comparing the flow between non-Newtonian and Newtonian fluids at pore scale, and analysing the mass transfer at the flow interface with this new approach.

本研究采用压缩连续物种转移(C-CST)方法,在微通道和二维多孔介质中研究孔隙尺度非牛顿流体的多相流,重点是通过流体体积(VOF)方法研究流体之间的排水和传质。研究对象是油藏中的多相流,其中多孔介质中存在不相溶流体。在油藏能量较低或石油的物理特性影响流动的情况下,采油方法的使用就变得非常重要。本文考虑了石油流变学的影响,尤其是具有非牛顿粘弹性行为的重质原油。二氧化碳注入等采油方法旨在通过改变流体的流变特性来优化流动。本文旨在利用 C-CST 方法、直接数值模拟(DNS)和体积跟踪技术进行数值分析,以捕捉流体之间的界面。主要目的是在线性动量守恒方程中数值化非牛顿流变模型,比较非牛顿流体和牛顿流体在孔隙尺度上的流动情况,并用这种新方法分析流动界面的传质情况。
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引用次数: 0
Investigation of the Filling of a Spherical Pore Body with a Nonwetting Fluid: A Modeling Approach and Computational Fluid Dynamics analysis 用非润湿流体填充球形孔隙体的研究:建模方法与计算流体力学分析
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-23 DOI: 10.1007/s11242-024-02114-8
Amgad Salama, Jisheng Kou, Shuyu Sun, Mahmoud Hefny

Understanding the dynamics of the filling process of a pore body with a nonwetting fluid is important in the context of dynamic pore network models and others. It can justify many of the assumptions behind the different rules that describe how the network behaves during imbibition and drainage processes. It also provides insight into the different regimes pertinent to this system. The filling process starts with the contact line pinning at the pore entrance. Three regimes can be identified during the filling process that is related to how the contact line advances. In the first two regimes, the contact line pins at the pore entrance while the emerging droplet develops, and in the third one, the contact line departs the entrance of the pore and advances along the pore surface. During the first regime, which is brief, the curvature of the meniscus increases, and likewise, the corresponding capillary pressure, while in the other two regimes, the curvature decreases and so does the capillary pressure. Such behavior results in the rate at which the nonwetting fluid invades the pore to change. It initially decreases, then increases as the meniscus advances. The radius of curvature of the meniscus, eventually, increases to infinity for which the interface assumes a flat configuration. A one-dimensional modeling approach is developed that accounts for all these regimes. The model also considers the two immiscible fluids over a wide spectrum of contrast in viscosity. Information about the mean velocity of the invading fluid, the location of the contact line, the radius of curvature of the meniscus, the volume of the emerging droplet, and several others are among the details that the model provides. A computational fluid dynamics (CFD) simulation has also been considered to confirm the proposed fates of the interface and to provide a framework for comparisons. The results of the validation process show, generally, a very good match between the model and the CFD analysis.

在动态孔隙网络模型和其他模型中,了解非润湿流体填充孔隙体的动态过程非常重要。它可以证明描述孔隙网络在吸水和排水过程中行为的不同规则背后的许多假设。它还能让我们深入了解与该系统相关的不同状态。充填过程始于孔隙入口处的接触线钉合。在充填过程中,可以识别出与接触线前进方式有关的三种状态。在前两种情况下,接触线固定在孔隙入口处,同时出现液滴;在第三种情况下,接触线离开孔隙入口,沿着孔隙表面前进。在短暂的第一种情况下,半月板曲率增大,相应的毛细管压力也随之增大;而在另外两种情况下,半月板曲率减小,毛细管压力也随之减小。这种行为导致非润湿流体侵入孔隙的速度发生变化。一开始会降低,然后随着半月板的移动而升高。半月板的曲率半径最终会增大到无穷大,此时界面会呈现扁平状。我们开发了一种一维建模方法,可以考虑所有这些情况。该模型还考虑了两种不相溶流体在粘度对比范围内的情况。模型还提供了入侵流体的平均速度、接触线位置、半月板曲率半径、新出现液滴的体积等详细信息。此外,还考虑了计算流体动力学(CFD)模拟,以确认所提出的界面命运,并提供一个比较框架。验证过程的结果表明,模型与 CFD 分析之间总体上非常吻合。
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引用次数: 0
Assessment of Models for Nonlinear Oscillatory Flow Through a Hexagonal Sphere Pack 评估流经六边形球包的非线性振荡流模型
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-18 DOI: 10.1007/s11242-024-02110-y
Lukas Unglehrt, Michael Manhart

We review models for unsteady porous media flow in the volume-averaging framework and we discuss the theoretical relations between the models and the definition of the model coefficients (and the uncertainty therein). The different models are compared against direct numerical simulations of oscillatory flow through a hexagonal sphere pack. The model constants are determined based on their definition in terms of the Stokes flow, the potential flow and steady nonlinear flow. Thus, the discrepancies between the model predictions and the simulation data can be attributed to shortcomings of the models’ parametrisation. We found that an extension of the dynamic permeability model of Pride et al. (PRB 47(9):4964–4978, 1993) with a Forchheimer-type nonlinearity performs very well for linear flow and for nonlinear flow at low and medium frequencies, but the Forchheimer term with a coefficient obtained from the steady-state overpredicts the nonlinear drag at high frequencies. The model reduces to the unsteady Forchheimer equation with an acceleration coefficient based on the static viscous tortuosity for low frequencies. The unsteady Forchheimer equation with an acceleration coefficient based on the high-frequency limit of the dynamic tortuosity has large errors for linear flow at medium and high frequencies, but low errors for nonlinear flow at all frequencies. This is explained by an error cancellation between the inertial and the nonlinear drag.

我们回顾了体积平均框架下的非稳态多孔介质流模型,并讨论了模型之间的理论关系以及模型系数(及其不确定性)的定义。我们将不同的模型与通过六边形球包的振荡流动的直接数值模拟进行了比较。模型常数是根据斯托克斯流、势流和稳定非线性流的定义确定的。因此,模型预测与模拟数据之间的差异可归因于模型参数化的缺陷。我们发现,Pride 等(PRB 47(9):4964-4978,1993 年)的动态渗透模型扩展了 Forchheimer 型非线性,在低频和中频的线性流和非线性流中表现很好,但带有稳态系数的 Forchheimer 项在高频时对非线性阻力的预测过高。在低频情况下,该模型简化为带有基于静态粘性湍流的加速度系数的非稳态福赫海默方程。对于中高频率的线性流动,加速度系数基于动态曲率的高频极限的非稳态福克海默方程误差较大,但对于所有频率的非线性流动,误差较小。这是因为惯性阻力和非线性阻力之间存在误差抵消。
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引用次数: 0
Transient Flow in Porous Electrosprays 多孔电纺丝中的瞬态流动
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-18 DOI: 10.1007/s11242-024-02113-9
Peter L. Wright, Richard E. Wirz

Porous ionic electrospray emitters have received significant interest for space propulsion due to their performance and operational simplicity. We have developed a diffusion equation for describing the transient flow response in a porous electrospray emitter, which allows for the prediction of the settling time for flow in the porous emitter. This equation accounts for both the change in liquid storage at exposed pores on the emitter with pressure and viscous diffusion through Darcy’s law. Transient flow solutions are provided for the most common emitter topologies: pillar, cone, and wedge. Transient flow solutions describe the settling time and magnitude of current overshoot from porous electrosprays, while providing useful guidelines for reducing transient response time through emitter design. Comparing diffusion of pressure to the onset delay model for electrospray emission shows that diffusion is most relevant at higher voltages and when a porous reservoir is used. Accounting for multiple emission sites on the wedge geometry shows that emission sites settle in proportion to emission site spacing to the power − 1.74.

多孔离子电喷雾发射器由于其性能和操作简便性,在太空推进方面受到了极大的关注。我们开发了一个描述多孔电喷雾发射器中瞬态流动响应的扩散方程,可以预测多孔发射器中流动的沉降时间。该方程既考虑了辐射器上暴露孔隙中液体存储量随压力的变化,也考虑了通过达西定律进行的粘性扩散。瞬态流解决方案适用于最常见的发射器拓扑结构:柱形、锥形和楔形。瞬态流解决方案描述了多孔电喷雾器的沉淀时间和电流过冲幅度,同时为通过发射器设计缩短瞬态响应时间提供了有用的指导。将压力扩散与电喷雾发射的起始延迟模型进行比较后发现,在电压较高和使用多孔储层时,压力扩散最为重要。对楔形几何体上的多个发射点进行核算后发现,发射点的沉降与发射点间距成正比,功率为 -1.74。
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引用次数: 0
Pore-Scale Simulation for the Fully-Developed Flow Through a Fixed-Bed Reactor Regularly Packed with Mono-Sized Spheres with Extension to Random Packing 固定床反应器中规则填料单粒径球体的充分发展流动的孔隙尺度模拟,并扩展至随机填料
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-16 DOI: 10.1007/s11242-024-02100-0
Liangcheng Cheng, S. Wong
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引用次数: 0
Image-Based Multi-scale Reconstruction of Unresolved Microporosity in 3D Heterogeneous Rock Digital Twins Using Cross-Correlation Simulation and Watershed Algorithm 利用交叉相关模拟和分水岭算法,基于图像多尺度重建三维异质岩石数字孪晶中未解决的微孔
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-13 DOI: 10.1007/s11242-024-02111-x
Abolfazl Moslemipour, Saeid Sadeghnejad, Frieder Enzmann, Davood Khoozan, Sarah Hupfer, Thorsten Schäfer, Michael Kersten

Multi-scale modelling techniques are commonly used to characterize heterogeneous rock samples. However, open challenges limit the efficiency of these models. A significant issue is the tradeoff between resolution and field of view (FoV) during imaging. Capturing an image of a heterogeneous rock sample that includes pores of different scales with a large FoV is impossible. Various novel approaches have attempted to solve this problem, but they have inherent limitations such as unrealistic results and high computational costs. In this study, we propose a novel method to generate 3D multiscale images of two heterogeneous rock samples: Berea sandstone and Edward Brown carbonate. We scanned both samples at low and high (HR) resolutions using X-ray microtomography. Our approach involves distinct reconstruction of resolved and unresolved porosity in rock images at lower resolutions. We divide the unresolved porosity into smaller sections, called unresolved templates, using the watershed algorithm to reduce memory allocation. The cross-correlation based simulation approach then finds a suitable replacement template from the HR images, which contain a significant number of micro-pores, using a modified overlap region selection procedure in 3D. We compare the geometrical and petrophysical properties of the reconstructed multi-scale images with those of the HR rock images. The results show good agreement with the HR image properties computed from the direct numerical simulation approach. Additionally, our thus validated method is two to four times faster in constructing multi-scale images.

多尺度建模技术通常用于描述异质岩石样本的特征。然而,一些公开的挑战限制了这些模型的效率。一个重要的问题是成像过程中分辨率与视场(FoV)之间的权衡。用大视场捕捉包含不同尺度孔隙的异质岩石样本图像是不可能的。各种新方法都试图解决这一问题,但它们都有其固有的局限性,如不切实际的结果和高昂的计算成本。在本研究中,我们提出了一种新方法来生成两种异质岩石样本的三维多尺度图像:Berea 砂岩和 Edward Brown 碳酸盐岩。我们使用 X 射线显微层析技术对这两个样本进行了低分辨率和高分辨率(HR)扫描。我们的方法包括在较低分辨率的岩石图像中重建已解决和未解决的孔隙度。我们使用分水岭算法将未解决的孔隙分为较小的部分,称为未解决模板,以减少内存分配。然后,基于交叉相关性的模拟方法使用改进的三维重叠区域选择程序,从包含大量微孔的 HR 图像中找到合适的替换模板。我们将重建的多尺度图像的几何和岩石物理特性与 HR 岩石图像进行了比较。结果表明,重建的多尺度图像与直接数值模拟方法计算出的 HR 图像属性非常吻合。此外,经过验证,我们的方法在构建多尺度图像时速度快 2 到 4 倍。
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引用次数: 0
One-Dimensional Consolidation Modeling of Soil Surrounding Buried Geothermal Pipelines: Incorporating Heat Diffusion Processes 埋设地热管道周围土壤的一维固结模型:纳入热扩散过程
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-11 DOI: 10.1007/s11242-024-02108-6
Lulu Zhang, Yunpeng Zhang, Yi Tian, Zongqin Wang, Guosheng Jiang, Minjie Wen, M. Hesham El Naggar, Wenbing Wu

Thermal consolidation of soil is a significant concern in buried geothermal pipeline engineering. Soil consolidation begins immediately upon pipeline completion, while a stable temperature field does not instantly form after soil backfilling. Therefore, considering the heat diffusion process post-pipeline installation is crucial for accurately predicting consolidation completion time. This study proposes a novel mathematical model integrating the heat diffusion process and continuous drainage boundary conditions. Based on the newly proposed model, the early-stage consolidation during the heat diffusion process can be accurately accounted so that the accelerated consolidation caused by the thermal effect would not be overestimated. In order to facilitate the application of the proposed model, a semi-analytical solution is derived by utilizing the integral transform method, variable separation method, and the inverse Fourier transform, the correctness of which has been validated through comparisons with the existing simplified studies. Additionally, a parametric study investigating the potential influencing parameters on thermal consolidation is conducted.

土壤热固结是地热管道埋设工程中的一个重要问题。管道完工后土壤会立即开始固结,而土壤回填后不会立即形成稳定的温度场。因此,考虑管道安装后的热扩散过程对于准确预测固结完成时间至关重要。本研究提出了一种整合热扩散过程和连续排水边界条件的新型数学模型。基于新提出的模型,热扩散过程中的早期固结可以得到准确的计算,从而避免高估热效应引起的加速固结。为了便于应用所提出的模型,利用积分变换法、变量分离法和反傅里叶变换法得出了半解析解,并通过与现有简化研究的比较验证了其正确性。此外,还对热固结的潜在影响参数进行了参数研究。
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引用次数: 0
A New Derivation for the Apparent Permeability Model Applied to the Full Knudsen Number Range 适用于全部克努森数范围的表观渗透率模型新推导
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-11 DOI: 10.1007/s11242-024-02112-w
Bocai Jiang, Qianhua Xiao, Rui Shen, Zhongpei Ding

Multiple flow mechanisms that coexist in nanoscale porous media are responsible for deviations from the linear Klinkenberg equation. The use of mathematical models in the literature has obvious limitations in evaluating this flow phenomenon because the viscosity/diffusion coefficients of nanoscale porous media are more accurate only in the limited Knudsen number region. By introducing, the concept of an effective molecular mean free path, this paper proposes single models of viscosity/diffusion for the full Knudsen number range to replace the combination model in the literature. On this basis, a new apparent permeability model is developed with multiple coexisting mechanisms for the full Knudsen number range, and the effectiveness of the proposed model is verified by using published data. The discontinuous problem of the combination model of the viscosity/diffusion coefficient in the literature for the full Knudsen number range is solved using the new viscosity and diffusion coefficient models. The new apparent permeability model accurately predicts the absolute permeability and explains the phenomenon of deviation from the linear Klinkenberg equation. This paper further discusses the influence of different mechanisms on the permeability. The rarefaction effect weakens the diffusion ability in porous media but increases the contribution of Darcy flow to permeability. The viscous flow increment, absolute permeability and slippage effect were the most important flow mechanisms in nanopores.

纳米级多孔介质中并存的多种流动机制是导致偏离克林肯贝格线性方程的原因。由于纳米级多孔介质的粘度/扩散系数仅在有限的克努森数区域内较为精确,因此文献中的数学模型在评估这种流动现象时具有明显的局限性。通过引入有效分子平均自由路径的概念,本文提出了整个克努森数范围内的单一粘度/扩散模型,以取代文献中的组合模型。在此基础上,针对整个克努森数范围,提出了一种具有多种共存机制的新型表观渗透率模型,并利用已发表的数据验证了所提模型的有效性。利用新的粘度和扩散系数模型,解决了文献中关于整个 Knudsen 数范围内粘度/扩散系数组合模型的不连续问题。新的表观渗透率模型准确地预测了绝对渗透率,并解释了偏离克林肯贝格线性方程的现象。本文进一步讨论了不同机制对渗透率的影响。稀释效应削弱了多孔介质的扩散能力,但增加了达西流对渗透率的贡献。粘流增量、绝对渗透率和滑动效应是纳米孔中最重要的流动机制。
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引用次数: 0
Quantitative Characterization and Analysis of Multiple Fracture Structures from Original Coal and Tectonic Coal by μCT 利用 μCT 对原煤和构造煤的多重断裂构造进行定量表征和分析
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-09 DOI: 10.1007/s11242-024-02109-5
Changxin Zhao, Yuanping Cheng, Chenghao Wang, Kaizhong Zhang

Investigating the spatial and size distributions of fracture structures formed by various external stresses in coal is essential for understanding fracture evolution and methane percolation behavior in coal reservoirs. To estimate the characteristics of microscale fractures in three-dimensional space, X-ray computed microtomography was used to establish digital reconstructed fracture models. Two algorithms that reflect topological features were applied to quantitatively characterize coal fractures. The results show that tectonic stress negatively affects the anisotropy of fractures, reducing the frequency of fractures that are approximately parallel or perpendicular to the main direction. A new fracture connectivity evaluation parameter, calculated by the integral average of the linear fitting curve between the coordination number and the corresponding average radius of many maximum spheres in the pore network model, is proposed. This method is more objective for evaluating fracture connectivity. The results indicate that with increasing tectonic action, fracture connectivity improves. Based on skeleton model data, we found a power-law relationship between the equivalent diameter of the fracture and the cumulative volume. Using this relationship and the capillary model assumption, we rederived expressions for total gas seepage flux and permeability applicable to fractures that do not conform to the tortuous fractal theory. Additionally, we discovered that the fracture aperture follows a log-normal distribution and derived an improved cube model’s mathematical formula based on this. These findings are significant for revealing how different fracture structures affect gas seepage and provide a foundation for developing theoretical models to predict gas seepage in coal reservoirs.

研究煤炭中各种外部应力形成的断裂结构的空间和尺寸分布对于了解煤储层中的断裂演化和甲烷渗流行为至关重要。为了估算三维空间中微观尺度断裂的特征,利用 X 射线计算机显微层析技术建立了数字重建断裂模型。应用两种反映拓扑特征的算法来定量描述煤炭裂缝的特征。结果表明,构造应力对断裂的各向异性有负面影响,降低了与主方向近似平行或垂直的断裂频率。研究提出了一种新的断裂连通性评价参数,该参数由孔隙网络模型中许多最大球体的配位数与相应平均半径的线性拟合曲线的积分平均值计算得出。这种方法在评价断裂连通性方面更加客观。结果表明,随着构造作用的加剧,断裂连通性会得到改善。根据骨架模型数据,我们发现断裂等效直径与累积体积之间存在幂律关系。利用这一关系和毛细管模型假设,我们重新推导出了适用于不符合曲折分形理论的断裂的总气体渗流通量和渗透率表达式。此外,我们还发现裂缝孔径呈对数正态分布,并据此推导出改进的立方体模型数学公式。这些发现对于揭示不同断裂结构如何影响瓦斯渗流具有重要意义,并为开发预测煤储层瓦斯渗流的理论模型奠定了基础。
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引用次数: 0
Foam-Assisted Hydrocarbon Gas Injection in Oil-Wet Fractured Carbonate: In Situ Investigation of Fracture–Matrix Interactions 油湿碳酸盐岩裂缝中的泡沫辅助碳氢化合物气体注入:断裂与基质相互作用的现场调查
IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-09 DOI: 10.1007/s11242-024-02107-7
Alvinda Sri Hanamertani, Abdelhalim Ibrahim Mohamed, Soheil Saraji, Mohammad Piri

The success of foam-induced flow diversion in fractured carbonates hinges on proper injection strategies, requiring an in-depth understanding of the factors responsible for stimulating fracture–matrix interactions. In this study, we present a novel investigation of the interactions between the fracture and the matrix influenced by the mobility control effect during CH4-foam injections. These interactions were probed at the pore scale using a three-phase flow system integrated with a high-resolution micro-CT scanner. In situ phase saturations were monitored and quantified to interpret the resulting fluid transport at various injection parameters. At the initial stage of foam injection, the surfactant solution was able to invade the matrix leading to water/oil displacement events, however, impeding gas penetration. Increasing total injection velocity produced higher in situ foam quality in the fracture than the injected quality, where significant fraction of the surfactant solution from the foam was primarily diverted into the matrix. A pronounced increase in the average gas saturation within the matrix was only observed at the highest injection velocity. The pore-scale evidence showed the occurrence of combined displacement processes (water/oil, gas/oil, gas/oil/water) in the matrix, attributed to the established mobility control in the fracture, which contributed to the diversion of surfactant solution and gas to the matrix. Lastly, the injection–soaking–production technique effectively mobilized the residual oil after a long injection process of CH4-foam. At this stage, the surfactant solution was no longer playing a role as the primary invading fluid; rather, it was the diverted gas that led to the increase in the matrix-oil production.

在断裂碳酸盐岩中进行泡沫诱导分流的成功与否取决于正确的注入策略,这就要求深入了解激发断裂与基质相互作用的因素。在本研究中,我们对注入 CH4 泡沫过程中受流动性控制效应影响的裂缝与基质之间的相互作用进行了新颖的调查。我们使用集成了高分辨率微型 CT 扫描仪的三相流系统在孔隙尺度上对这些相互作用进行了探测。对原位相饱和度进行了监测和量化,以解释在不同注入参数下产生的流体传输。在泡沫注入的初始阶段,表面活性剂溶液能够侵入基质,导致水/油置换事件,但阻碍了气体的渗透。提高总注入速度后,裂缝中的原位泡沫质量高于注入质量,泡沫中的表面活性剂溶液主要流入基质。只有在最高注入速度时,基质内的平均气体饱和度才会明显提高。孔隙尺度证据显示,基质中出现了组合置换过程(水/油、气/油、气/油/水),这归因于裂缝中已建立的流动性控制,有助于将表面活性剂溶液和气体分流到基质中。最后,在长时间注入 CH4 泡沫后,注入-浸泡-生产技术有效地调动了剩余油。在这一阶段,表面活性剂溶液不再作为主要侵入流体发挥作用;相反,是分流的气体导致了基质油产量的增加。
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引用次数: 0
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Transport in Porous Media
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