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Leveraging large language models through natural language processing to provide interpretable machine learning predictions of mental deterioration in real time 通过自然语言处理利用大型语言模型,实时提供可解释的智力退化机器学习预测
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-27 DOI: 10.1007/s13369-024-09508-2
Francisco de Arriba-Pérez, Silvia García-Méndez

Based on official estimates, 50 million people worldwide are affected by dementia, and this number increases by 10 million new patients every year. Without a cure, clinical prognostication and early intervention represent the most effective ways to delay its progression. To this end, artificial intelligence and computational linguistics can be exploited for natural language analysis, personalized assessment, monitoring, and treatment. However, traditional approaches need more semantic knowledge management and explicability capabilities. Moreover, using large language models (llms) for cognitive decline diagnosis is still scarce, even though these models represent the most advanced way for clinical–patient communication using intelligent systems. Consequently, we leverage an llm using the latest natural language processing (nlp) techniques in a chatbot solution to provide interpretable machine learning prediction of cognitive decline in real-time. Linguistic-conceptual features are exploited for appropriate natural language analysis. Through explainability, we aim to fight potential biases of the models and improve their potential to help clinical workers in their diagnosis decisions. More in detail, the proposed pipeline is composed of (i) data extraction employing nlp-based prompt engineering; (ii) stream-based data processing including feature engineering, analysis, and selection; (iii) real-time classification; and (iv) the explainability dashboard to provide visual and natural language descriptions of the prediction outcome. Classification results exceed 80% in all evaluation metrics, with a recall value for the mental deterioration class about 85%. To sum up, we contribute with an affordable, flexible, non-invasive, personalized diagnostic system to this work.

据官方估计,全世界有 5000 万人受到痴呆症的影响,每年新增患者 1000 万。在无法治愈的情况下,临床预后和早期干预是延缓痴呆症发展的最有效方法。为此,人工智能和计算语言学可用于自然语言分析、个性化评估、监测和治疗。然而,传统方法需要更多的语义知识管理和可解释能力。此外,使用大语言模型(llms)进行认知功能衰退诊断的情况仍然很少,尽管这些模型代表了使用智能系统进行临床与患者交流的最先进方法。因此,我们在聊天机器人解决方案中使用了最新的自然语言处理(nlp)技术,利用大语言模型对认知功能衰退进行实时可解释的机器学习预测。我们利用语言概念特征进行适当的自然语言分析。通过可解释性,我们旨在消除模型的潜在偏差,提高其帮助临床工作者做出诊断决定的潜力。更详细地说,拟议的管道包括:(i) 采用基于 nlp 的提示工程进行数据提取;(ii) 基于流的数据处理,包括特征工程、分析和选择;(iii) 实时分类;以及 (iv) 可解释性仪表板,对预测结果进行可视化和自然语言描述。在所有评估指标中,分类结果都超过了 80%,其中精神衰退类的召回值约为 85%。总之,我们为这项工作贡献了一个经济实惠、灵活、非侵入性的个性化诊断系统。
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引用次数: 0
Phase Change Materials in High Heat Storage Application: A Review 高蓄热应用中的相变材料:综述
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-27 DOI: 10.1007/s13369-024-09519-z
Robiul Islam Rubel, Md Washim Akram, Md Mahmodul Alam, Afsana Nusrat, Raju Ahammad, Md Abdullah Al Bari

Thermal energy harvesting and its applications significantly rely on thermal energy storage (TES) materials. Critical factors include the material’s ability to store and release heat with minimal temperature differences, the range of temperatures covered, and repetitive sensitivity. The short duration of heat storage limits the effectiveness of TES. Phase change materials (PCMs) are a current global research focus due to their desirable thermal properties, which improve energy performance and thermal comfort. PCMs require relatively less synthesis effort while maintaining high efficiency and enhancing cost-effectiveness. However, limited temperature range and storage capacity restrict the application of conventional PCMs. Consequently, the demand for high-energy PCM storage with enhanced thermo-physical properties is high. It is essential to explore the potential of new PCMs to improve thermal storage performance and capacity while reducing energy consumption. This review article explores the classifications and applications of PCMs, addresses the challenges in enhancing their thermo-physical properties, and outlines the selection criteria for high-heat storage applications. Additionally, it provides an in-depth analysis of recent research and developments related to PCMs.

热能采集及其应用在很大程度上依赖于热能储存(TES)材料。关键因素包括材料在最小温差下存储和释放热量的能力、覆盖的温度范围以及重复灵敏度。储热时间短限制了 TES 的有效性。相变材料(PCM)具有理想的热性能,可以改善能源性能和热舒适度,因此是当前全球研究的重点。相变材料所需的合成工作相对较少,同时还能保持高效率,提高成本效益。然而,有限的温度范围和存储容量限制了传统 PCM 的应用。因此,对热物理性能更强的高能 PCM 储能的需求很高。有必要探索新型 PCM 的潜力,以提高热存储性能和容量,同时降低能耗。这篇综述文章探讨了 PCM 的分类和应用,探讨了增强 PCM 热物理性能所面临的挑战,并概述了高热量存储应用的选择标准。此外,文章还深入分析了与 PCM 相关的最新研究和发展。
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引用次数: 0
Power Optimization and ARSs Selection Strategies in Downlink Cell-Free Multi-ARSs Communication Systems 下行链路无小区多ARS通信系统中的功率优化和ARS选择策略
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-27 DOI: 10.1007/s13369-024-09441-4
Bui Anh Duc, Tran Manh Hoang, Nguyen Thu Phuong, Xuan Nam Tran, Pham Thanh Hiep

In this study, we examine the downlink cell-free (CF) multiple aerial relay stations (ARSs) system, where ARSs are outfitted with several antennas, distributed randomly in entire responsible areas, and serve a large number of ground users. The application of the CF model is expected to not only improve the performance of the ARS system but also solve the problem of inconsistent throughput between users and the problem of near-far users in the current advanced networks, such as massive multiple-input multiple-output (mMIMO). Moreover, we propose two ARS selection strategies to cut off poor-quality transmission links in the original CF system, thereby reducing the power consumption of ARSs, reducing interference between users, and improving user throughput. We calculate a closed-form formulation for downlink user throughput under the condition of using conjugate beamforming technology. We optimize the pilot and downlink data transmission coefficients using the successive convex approximation (SCA) method and second-order cone programming (SOCP), respectively. The proposed optimization methods mitigate the problems of "pilot contamination" in channel estimation and inter-user interference in downlink data transmission of systems allowing multiple ARS to access the channel simultaneously. Our findings have assessed the downlink system throughput with pilot and data transmission power optimization for superior results based on a variety of selection strategies as well as the CF model (using all ARSs). In addition, the findings also indicate that the proposed novel ARS selection strategies have better user throughput than the CF technique with a specific number of selected ARS. Our proposed system is a promising technology and opens up various practical application scenarios for 6G networks.

在本研究中,我们探讨了下行链路无小区(CF)多空中中继站(ARS)系统,在该系统中,ARS 装有多个天线,随机分布在整个责任区,为大量地面用户提供服务。CF 模型的应用不仅有望提高 ARS 系统的性能,还能解决当前先进网络(如大规模多输入多输出(mMIMO)网络)中用户间吞吐量不一致的问题和用户距离过近的问题。此外,我们还提出了两种 ARS 选择策略,以切断原始 CF 系统中的劣质传输链路,从而降低 ARS 的功耗,减少用户间的干扰,提高用户吞吐量。在使用共轭波束成形技术的条件下,我们计算了下行用户吞吐量的闭式公式。我们分别使用逐次凸近似法(SCA)和二阶锥编程法(SOCP)优化了先导系数和下行链路数据传输系数。所提出的优化方法缓解了信道估计中的 "先导污染 "问题,以及允许多个 ARS 同时访问信道的系统在下行链路数据传输中的用户间干扰问题。我们的研究结果评估了下行链路系统的吞吐量,并根据各种选择策略和 CF 模型(使用所有 ARS)对先导和数据传输功率进行了优化,以获得更优的结果。此外,研究结果还表明,与采用特定数量 ARS 的 CF 技术相比,所提出的新型 ARS 选择策略具有更好的用户吞吐量。我们提出的系统是一项前景广阔的技术,为 6G 网络开辟了各种实际应用场景。
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引用次数: 0
Performance Enhancement of Polymer Electrolyte Membrane with Nano-Calcium Carbonate Prepared by Mechanochemical for Direct Methanol Fuel Cell Applications 用机械化学法制备的纳米碳酸钙聚合物电解质膜在直接甲醇燃料电池应用中的性能提升
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-26 DOI: 10.1007/s13369-024-09411-w
O. S. J. Elham, S. K. Kamarudin, N. U. Saidin, L. K. Seng, M. R. Yusof

Direct methanol fuel cells (DMFCs) have great potential for use in portable electronics. However, obstacles such as methanol crossover, insufficient proton conductivity, and the high cost of Nafion hinder the broad commercialization of this technology. In line with the prevailing “waste-to-wealth” movement, eggshell powder was chosen as the filler for the Nafion matrix (rN-ES). Nano-calcium carbonate (nano-CaCO₃) was first produced from eggshell waste by a mechanochemical process before inclusion in the Nafion polymer matrix by the solution casting process. Cyclic voltammetry and electrochemical impedance spectroscopy were used to measure methanol permeability and proton conductivity. The composite membrane showed the highest value for ion exchange capacity of 1.25 mmol g⁻1 and water uptake of 46.54%. Remarkably, the through-plane method showed better proton conductivity (4.87 mS cm⁻1) compared to N117. The methanol permeability of the rN-ES composite membranes decreased to 3.3 times the permeability of N117. In the passive single-cell test of the DMFC, the use of a composite membrane with 5 wt.% nano-CaCO₃ resulted in a rise in the maximum power density from 9.5 to 12.37 mW cm⁻2. These results prove that the incorporation of nano-CaCO₃ as a filler in a Nafion matrix is practicable for DMFC applications.

直接甲醇燃料电池(DMFC)在便携式电子产品中的应用潜力巨大。然而,甲醇交叉、质子传导性不足以及 Nafion 的高成本等障碍阻碍了这一技术的广泛商业化。在 "变废为宝 "运动盛行的背景下,蛋壳粉被选为 Nafion 基质(rN-ES)的填料。纳米碳酸钙(nano-CaCO₃)首先是通过机械化学工艺从蛋壳废料中生产出来的,然后再通过溶液浇铸工艺加入到 Nafion 聚合物基体中。循环伏安法和电化学阻抗光谱法用于测量甲醇渗透性和质子电导率。复合膜的离子交换容量最高,为 1.25 mmol g-1,吸水率为 46.54%。值得注意的是,与 N117 相比,通过平面法显示出更好的质子传导性(4.87 mS cm-1)。rN-ES 复合膜的甲醇渗透性降至 N117 的 3.3 倍。在 DMFC 的被动单细胞测试中,使用含有 5 wt.% 纳米 CaCO₃ 的复合膜使最大功率密度从 9.5 mW cm-2 上升到 12.37 mW cm-2。这些结果证明,在 Nafion 基质中加入纳米 CaCO₃ 作为填料可用于 DMFC。
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引用次数: 0
Optimized Design of Floating Stone Columns for Enhanced Long-term Settlement Performance of Soft Soils 优化设计浮动石柱,提高软土的长期沉降性能
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-26 DOI: 10.1007/s13369-024-09443-2
Khaoula Chenche, Meriem Fakhreddine Bouali, Jorge Castro

In two-dimensional axial symmetry finite element analyses, compressible clayey deposits improved by a large group of floating stone columns were performed using the unit cell idealization. The primary focus of this study is to assess the efficiency of floating stone columns in enhancing the consolidation rate of low-permeable soils. Additionally, it aims to evaluate the long-term stability of constructions built along marine coastal areas. To this end, two real case studies were investigated; the Béjaïa and Algiers Mediterranean harbors. Various geometric variables, pertaining to the design of floating stone columns, have been considered to analyze their effect in impacting the consolidation process and the long-term behavior emphasizing their fundamental importance in the design. Besides, a thorough comparison between the design in both short-term and long-term conditions, satisfying the admissible settlement, has been made, ultimately resulting in the optimized design selected. The results also indicate that increasing both the area improvement ratio and the floating column length leads to a speeding up of the consolidation rate. However, in contrast to the area substitution ratio, the column length has comparatively lesser importance in terms of reducing the settlement. Importantly, it is demonstrated that the design of floating stone columns for long-term conditions is significantly distinct from that for short-term conditions, requiring an approximate 40% increase in the area improvement ratio as designs based on the immediate settlement may not align with improved soft soil long-term behavior. Finally, the study reveals that the applied load ultimately governs the design of floating stone columns.

在二维轴对称有限元分析中,使用单元单元理想化方法对由大量浮动石柱改善的可压缩粘土沉积进行了分析。本研究的主要重点是评估浮石柱在提高低渗透性土壤固结率方面的效率。此外,它还旨在评估沿海地区建筑的长期稳定性。为此,我们对两个实际案例进行了研究:贝贾亚港和阿尔及尔地中海港。考虑了与浮动石柱设计有关的各种几何变量,分析了它们对固结过程和长期行为的影响,强调了它们在设计中的根本重要性。此外,在满足允许沉降量的前提下,对短期和长期条件下的设计进行了全面比较,最终选定了优化设计。结果还表明,增加面积改进率和浮柱长度都会加快固结速度。然而,与面积替代率相比,浮柱长度在减少沉降方面的重要性相对较小。重要的是,研究表明,长期条件下的浮石柱设计与短期条件下的浮石柱设计明显不同,需要将面积改进率提高约 40%,因为基于即时沉降的设计可能与软土长期行为的改进不一致。最后,研究还揭示了浮石柱的设计最终取决于所施加的荷载。
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引用次数: 0
Research on the Impact of the Differencing Operator on Ensemble Learning Algorithms in the Case of Peak Load Forecasting 峰值负荷预测中差分操作器对集合学习算法的影响研究
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-26 DOI: 10.1007/s13369-024-09460-1
Thanh Ngoc Tran

Peak load forecasting is a critical aspect of power system operations and planning. Accurate forecasting of peak loads significantly impacts the overall efficiency and reliability of a power system. Among the numerous load forecasting methods that are used, ensemble learning algorithms have emerged as a popular choice due to their high accuracy. In this research, the author proposes an innovative methodology that integrates the Differencing Operator with the Sliding Window procedure for training and predicting peak loads using commonly employed ensemble learning models such as GBDT, XGBoost, LightGBM, and CatBoost. The performance of the proposed approach was evaluated by analyzing the prediction error and execution time. The results obtained demonstrated improved accuracy in peak load forecasting, with no impact on execution time.

高峰负荷预测是电力系统运行和规划的一个重要方面。对高峰负荷的准确预测会对电力系统的整体效率和可靠性产生重大影响。在众多负荷预测方法中,集合学习算法因其高精度而备受青睐。在这项研究中,作者提出了一种创新方法,将差分运算器与滑动窗口程序相结合,使用 GBDT、XGBoost、LightGBM 和 CatBoost 等常用的集合学习模型来训练和预测峰值负荷。通过分析预测误差和执行时间,对所提出方法的性能进行了评估。结果表明,在不影响执行时间的情况下,峰值负荷预测的准确性得到了提高。
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引用次数: 0
Complex Scenes Fire Object Detection Based on Feature Fusion and Channel Attention 基于特征融合和通道关注的复杂场景火灾目标检测
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-25 DOI: 10.1007/s13369-024-09471-y
Xinrong Cao, Jincai Wu, Jian Chen, Zuoyong Li

For recognizing small targets, fire-like objects in fire images, and detecting fires across various scenes, we propose a fire detection method based on feature fusion and channel attention. Most existing fire detection methods have specific application scenarios with poor speed or accuracy. To address the issues of poor accuracy when directly applying existing object detection models and the reduced detection speed when improving models for fire targets, our approach aims to balance accurate fire localization with real-time processing. In the backbone of the model, deformable convolution is used to capture rich image information, and channel attention is employed to enhance features. The feature fusion in the neck achieves better localization of small fire targets. The visualized heatmap results indicate the effectiveness of our improved measures. By simultaneously employing multiple improvement measures, our method achieved satisfactory fire detection performance. Experimental results on a self-annotated dataset demonstrate that the best AP@50 of the model can reach 63.9%, the fastest detection speed can reach 114 FPS, and the F1-score is stable at around 63%. Our method strikes a good balance between detection speed and accuracy.

为了识别火灾图像中的小目标和类火物体,以及检测各种场景中的火灾,我们提出了一种基于特征融合和通道关注的火灾检测方法。现有的火灾检测方法大多有特定的应用场景,速度或准确性较差。为了解决直接应用现有物体检测模型精度不高,以及改进火灾目标模型时检测速度降低的问题,我们的方法旨在兼顾准确的火灾定位和实时处理。在模型的骨干部分,使用可变形卷积来捕捉丰富的图像信息,并使用通道注意来增强特征。颈部的特征融合可以更好地定位小型火灾目标。可视化热图结果显示了我们改进措施的有效性。通过同时采用多种改进措施,我们的方法取得了令人满意的火灾检测性能。在自标注数据集上的实验结果表明,模型的最佳 AP@50 可以达到 63.9%,最快检测速度可以达到 114 FPS,F1 分数稳定在 63% 左右。我们的方法在检测速度和准确性之间取得了良好的平衡。
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引用次数: 0
Dynamic Risk Forecasting Based on Deep Learning and Collapse Risk Comprehensive Evaluation of Mountain Tunnel Portal Construction 基于深度学习的动态风险预测与山区隧道洞门施工坍塌风险综合评估
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-25 DOI: 10.1007/s13369-024-09470-z
Kun Lin, Yazhen Sun, Jinchang Wang, Fengbin Zhu, Longyan Wang

In this paper, a comprehensive risk assessment system is proposed to evaluate the risk of collapse in mountain tunnels. This system integrates risk source identification, dynamic and static risk classification, deep learning prediction, and engineering risk evaluation. Firstly, risk events and sources are identified, and a risk evaluation method combines the fuzzy analytic hierarchy process (FAHP) and interval technique for order preference by similarity to ideal solution (TOPSIS). FAHP is used to calculate weights, and a risk classification table based on five classical values is derived using traditional TOPSIS. The actual project’s risk value is then calculated using Interval TOPSIS to determine the risk level. Secondly, six models (BP, SVM, CNN, LSTM, PSO-SLTM, and EPL) are trained and tested to predict surface settlement at the tunnel portal and using RMSE, MAE, and maximum (minimum and average) error values for comparison; the best model is determined. The study concludes that a two-stage model, which uses ensemble empirical mode decomposition to process raw data and particle swarm optimization to optimize long short-term memory hyperparameters, provides the best predictive results. Finally, static and dynamic risks are combined for a comprehensive risk evaluation. The Aktepe Tunnel Project in Xinjiang, China, serves as a case study to successfully and accurately forecast surface settlement and evaluate the safety of the tunnel portal. This assessment confirms that this section of the tunnel is at average risk and that the current building conditions ensure the safety of the tunnel, the case study validates the rationality of the comprehensive evaluation system, offering a reference for tunnel portal risk evaluation.

本文提出了一种综合风险评估系统,用于评估山区隧道的坍塌风险。该系统集风险源识别、动静态风险分类、深度学习预测和工程风险评价于一体。首先,对风险事件和风险源进行识别,并结合模糊分析层次过程(FAHP)和理想解相似度排序偏好区间技术(TOPSIS),提出风险评价方法。使用 FAHP 计算权重,并使用传统的 TOPSIS 方法得出基于五个经典值的风险分类表。然后使用区间 TOPSIS 计算实际项目的风险值,以确定风险等级。其次,对六个模型(BP、SVM、CNN、LSTM、PSO-SLTM 和 EPL)进行了训练和测试,以预测隧道入口处的地表沉降,并使用 RMSE、MAE 和最大(最小和平均)误差值进行比较,最终确定最佳模型。研究得出结论,使用集合经验模式分解来处理原始数据,并使用粒子群优化来优化长短期记忆超参数的两阶段模型可提供最佳预测结果。最后,结合静态和动态风险进行综合风险评估。中国新疆阿克纠宾隧道项目作为案例研究,成功准确地预测了地表沉降并评估了隧道入口的安全性。评估结果表明,该段隧道风险一般,目前的建筑条件确保了隧道的安全,该案例研究验证了综合评估系统的合理性,为隧道洞口风险评估提供了参考。
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引用次数: 0
Application of Machine Learning and Deep Learning Techniques for Corrosion and Cracks Detection in Nuclear Power Plants: A Review 机器学习和深度学习技术在核电站腐蚀和裂纹检测中的应用:综述
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-12 DOI: 10.1007/s13369-024-09388-6
Malik Al-Abed Allah, Ihsan ulhaq Toor, Afaque Shams, Osman K. Siddiqui

This paper is focused on a comprehensive review related to the applications of machine learning (ML) and deep learning (DL) techniques for corrosion and crack detection in nuclear power plants (NPPs). NPPs require strict inspection and maintenance guidelines to ensure safety and efficiency, as the consequence of any such accident can be disastrous. Traditional methods of corrosion and crack detection often require substantial manual effort, even plant shutdown for inspection, and are limited in scalability. In recent years, ML and DL approaches have appeared as promising solutions to improve the accuracy and efficiency of corrosion and crack detection methods. The review begins by exploring the fundamental principles of ML and DL, providing insights into their adaptability for managing these challenges in NPPs. ML techniques such as support vector machines and decision trees (DT) as well as various DL architectures, including convolutional neural networks, recurrent neural networks, and autoencoders, are explored in the context of corrosion and crack detection. The paper highlights the dataset challenges related to NPPs, handling issues like imbalanced data, temporal dependencies, and multi-scale modeling. It focuses on case studies and research efforts utilizing ML techniques, highlighting notable advancements and potential breakthroughs in the field. Further, the challenges and future opportunities of integrating ML techniques into nuclear power plant inspection and maintenance are thoroughly scrutinized, underscoring the imperative need for standardized datasets, scalability, and model interpretability.

本文重点综述了机器学习(ML)和深度学习(DL)技术在核电站(NPP)腐蚀和裂纹检测中的应用。核电站需要严格的检查和维护准则来确保安全和效率,因为任何此类事故的后果都可能是灾难性的。传统的腐蚀和裂纹检测方法通常需要大量的人工操作,甚至需要关闭工厂进行检查,而且可扩展性有限。近年来,ML 和 DL 方法的出现为提高腐蚀和裂纹检测方法的准确性和效率带来了希望。本综述首先探讨了 ML 和 DL 的基本原理,并深入分析了它们在应对国家核电厂的这些挑战方面的适应性。在腐蚀和裂纹检测方面,探讨了支持向量机和决策树 (DT) 等 ML 技术以及卷积神经网络、递归神经网络和自动编码器等各种 DL 架构。论文强调了与核电厂相关的数据集挑战,处理了不平衡数据、时间依赖性和多尺度建模等问题。论文重点介绍了利用 ML 技术进行的案例研究和研究工作,强调了该领域的显著进步和潜在突破。此外,还深入探讨了将 ML 技术集成到核电站检查和维护中的挑战和未来机遇,强调了对标准化数据集、可扩展性和模型可解释性的迫切需求。
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引用次数: 0
Tailoring Novel SnO2/α-MnO2 Composites for Photocatalytic Performance Under Visible-Light 定制具有可见光下光催化性能的新型 SnO2/α-MnO2 复合材料
IF 2.9 4区 综合性期刊 Q1 Multidisciplinary Pub Date : 2024-08-12 DOI: 10.1007/s13369-024-09406-7
Aiman Jabeen, Shams ur Rahman, A. Shah, Sibghat Ullah Khan, Nasir Ali Siddiqui, Rabia Maryam, Afzal Hussain, Zainab Tariq, Rafaqat Hussain

Efficient removal of industrial effluents from wastewater is critical for a clean and sustainable water supply. In this study, novel nanosized SnO2/MnO2 photocatalysts with crystallite size between 34–40 nm were synthesized and evaluated for methylene blue (MB) degradation under visible light. The optimal percentage of MnO2 nanowires was explored for superior photocatalytic efficiency by varying its amount in the composites. The findings suggested that the SnO2/MnO2 composites exhibited enhanced photocatalytic performance compared to their individual components, which was attributed to the synergistic interaction between SnO2 and MnO2. Preliminary analysis by X-ray diffraction, Raman spectra, and EDX confirmed the crystalline structure and chemical composition of SnO2, MnO2 and their composites. Additionally, the morphology of MnO2 was observed to be of nanowires; while SnO2 was found to be comprised of agglomerated particles. Notably, the photocatalysts demonstrated a systematic reduction in the bandgap of the composites with increasing MnO2 content, leading to improved visible light utilization. Among all the prepared photocatalysts, the optimized SnO2/MnO2 composite with 75 wt. % MnO2 (denote as SM-3) revealed exceptional photocatalytic activity by degrading 93% of MB in 150 min of light exposure. Moreover, the catalytic process followed pseudo-first-order kinetics, highlighting the efficiency of the composites. The scavenger studies suggested that holes, hydroxyl and superoxide radicals are primarily responsible for the MB degradation. The composite SM-3 also exhibited impressive stability and reusability. This study demonstrates the potential of SnO2/MnO2 composites as effective photocatalysts for wastewater treatment under visible light.

有效去除废水中的工业废水对清洁和可持续的供水至关重要。本研究合成了结晶尺寸在 34-40 纳米之间的新型纳米 SnO2/MnO2 光催化剂,并对其在可见光下的亚甲基蓝(MB)降解效果进行了评估。通过改变 MnO2 纳米线在复合材料中的含量,探索了其最佳比例,从而获得了卓越的光催化效率。研究结果表明,与单个成分相比,二氧化锡/二氧化锰复合材料的光催化性能更强,这归因于二氧化锡和二氧化锰之间的协同作用。通过 X 射线衍射、拉曼光谱和 EDX 进行的初步分析证实了二氧化锡、二氧化锰及其复合材料的晶体结构和化学成分。此外,还观察到 MnO2 的形态为纳米线,而 SnO2 则由团聚颗粒组成。值得注意的是,随着 MnO2 含量的增加,光催化剂复合材料的带隙有系统地减小,从而提高了可见光的利用率。在所有制备的光催化剂中,含 75 wt. % MnO2 的优化 SnO2/MnO2 复合材料(称为 SM-3)显示出卓越的光催化活性,在光照射 150 分钟内降解了 93% 的甲基溴。此外,催化过程遵循伪一阶动力学,凸显了复合材料的高效性。清除剂研究表明,空穴、羟基和超氧自由基是造成甲基溴降解的主要原因。复合材料 SM-3 还表现出令人印象深刻的稳定性和可重复使用性。这项研究证明了 SnO2/MnO2 复合材料作为有效光催化剂在可见光下处理废水的潜力。
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引用次数: 0
期刊
Arabian Journal for Science and Engineering
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