首页 > 最新文献

Atmospheric Pollution Research最新文献

英文 中文
Sources of atmospheric fine and ultrafine particulate matter and novel PAH diagnostic ratios from northern Thailand forest fires 泰国北部森林火灾大气细颗粒物和超细颗粒物的来源和新的多环芳烃诊断比率
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-30 DOI: 10.1016/j.apr.2025.102770
Nobchonnee Nim , Perapong Tekasakul , Racha Dejchanchaiwong , Thaneeya Chetiyanukornkul , Manya Nakpon , John Morris
Fires from deciduous dipterocarp forests (DDF) and mixed deciduous forests (MDF) in northern Thailand during haze episodes remarkably affect the ambient fine and ultrafine particulate matter (PM), along with associated polycyclic aromatic hydrocarbon (PAH) concentrations. Average mass concentrations of atmospheric fine and ultrafine particles during haze periods were 2.0–4.8 and 1.7–3.7 times higher than those during normal and transition periods, respectively. Dominant PAHs emitted from forest fires were pyrene (Pyr; 4-rings), benzo[b]fluoranthene (BbF; 5-rings), and benzo[g,h,i]perylene (BghiPe; 6-rings). High molecular weight PAHs constituted a large proportion of total PAHs across all particle sizes. Size distribution of 4-ring PAHs from major vegetation fires in DDF and MDF peaked in the accumulation mode (1.75 μm), whereas 5- and 6-ring PAHs peaked at 0.75 μm. Emission factors were 0.01–0.35 g/kg for PM0.1, 0.16–1.4 g/kg for PM1, and 0.24–1.55 g/kg for PM2.5; for PM-bound PAHs, they were 18–276 μg/kg, 165–874 μg/kg, and 199–989 μg/kg, respectively. A new binary PAH diagnostic ratio—BbF/(BbF + indeno[1,2,3-cd]pyrene (IDP)) = 0.45–0.76 vs IDP/(IDP + BghiPe) = 0.23–0.45—was an effective indicator for PM0.1, PM1, and PM2.5 in fires from DDF and MDF forests. This was verified using a chemical mass balance model and backward trajectory analysis. Results obtained improve understanding of fine and ultrafine particle emission sources from forest fires in upper Southeast Asia.
泰国北部落叶龙果林(DDF)和混交林(MDF)在雾霾期间的火灾显著影响了环境细颗粒物(PM)和超细颗粒物(PM),以及相关的多环芳烃(PAH)浓度。雾霾期大气细颗粒物和超细颗粒物的平均质量浓度分别是正常期和过渡期的2.0 ~ 4.8倍和1.7 ~ 3.7倍。森林火灾释放的主要多环芳烃是芘(Pyr; 4环)、苯并[b]荧蒽(BbF; 5环)和苯并[g,h,i]苝(BghiPe; 6环)。高分子量多环芳烃在所有粒径的多环芳烃中占很大比例。主要植被火灾产生的4环多环芳烃在DDF和MDF中以1.75 μm的累积模式最大,而5环和6环多环芳烃在0.75 μm的累积模式最大。PM0.1的排放因子为0.01 ~ 0.35 g/kg, PM1的排放因子为0.16 ~ 1.4 g/kg, PM2.5的排放因子为0.24 ~ 1.55 g/kg;pm结合的PAHs分别为18 ~ 276 μg/kg、165 ~ 874 μg/kg和199 ~ 989 μg/kg。一种新的多环芳烃二元诊断比值——BbF/(BbF + indo [1,2,3-cd]芘(IDP)) = 0.45-0.76 vs IDP/(IDP + BghiPe) = 0.23 - 0.45——是DDF和MDF森林火灾PM0.1、PM1和PM2.5的有效指标。利用化学质量平衡模型和反向轨迹分析验证了这一点。研究结果提高了对上东南亚地区森林火灾细颗粒物和超细颗粒物排放源的认识。
{"title":"Sources of atmospheric fine and ultrafine particulate matter and novel PAH diagnostic ratios from northern Thailand forest fires","authors":"Nobchonnee Nim ,&nbsp;Perapong Tekasakul ,&nbsp;Racha Dejchanchaiwong ,&nbsp;Thaneeya Chetiyanukornkul ,&nbsp;Manya Nakpon ,&nbsp;John Morris","doi":"10.1016/j.apr.2025.102770","DOIUrl":"10.1016/j.apr.2025.102770","url":null,"abstract":"<div><div>Fires from deciduous dipterocarp forests (DDF) and mixed deciduous forests (MDF) in northern Thailand during haze episodes remarkably affect the ambient fine and ultrafine particulate matter (PM), along with associated polycyclic aromatic hydrocarbon (PAH) concentrations. Average mass concentrations of atmospheric fine and ultrafine particles during haze periods were 2.0–4.8 and 1.7–3.7 times higher than those during normal and transition periods, respectively. <em>Dominant</em> PAHs emitted from forest fires were pyrene (Pyr; 4-rings), benzo[b]fluoranthene (BbF; 5-rings), and benzo[g,h,i]perylene (BghiPe; 6-rings). High molecular weight PAHs constituted a large proportion of total PAHs across all particle sizes. Size distribution of 4-ring PAHs from major vegetation fires in DDF and MDF peaked in the accumulation mode (1.75 μm), whereas 5- and 6-ring PAHs peaked at 0.75 μm. Emission factors were 0.01–0.35 g/kg for PM<sub>0.1</sub>, 0.16–1.4 g/kg for PM<sub>1</sub>, and 0.24–1.55 g/kg for PM<sub>2.5</sub>; for PM-bound PAHs, they were 18–276 μg/kg, 165–874 μg/kg, and 199–989 μg/kg, respectively. A new binary PAH diagnostic ratio—BbF/(BbF + indeno[1,2,3-cd]pyrene (IDP)) = 0.45–0.76 <em>vs</em> IDP/(IDP + BghiPe) = 0.23–0.45—was an effective indicator for PM<sub>0.1</sub>, PM<sub>1</sub>, and PM<sub>2.5</sub> in fires from DDF and MDF forests. This was verified using a chemical mass balance model and backward trajectory analysis. Results obtained improve understanding of fine and ultrafine particle emission sources from forest fires in upper Southeast Asia.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102770"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating magnetic properties of atmospheric particulate matter (PM10) at Brasília bus station, central Brazil 巴西中部Brasília公交车站大气颗粒物(PM10)磁性评价
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-09 DOI: 10.1016/j.apr.2025.102739
Poliana Dutra Maia , Elder Yokoyama , Luiza de Souza Romano , Guilherme Gomide , Jerome Depeyrot , Sebastião William da Silva , Myller de Sousa Tonhá
This study analyzes the Saturation Magnetization (MS) in PM10 particles collected at a central bus station in Brasília from 2018 to 2019, exploring its relationship with chemical elements (total metals - Fe, V, Cu, Mn, Sr, Cd - and ions - Ca2+, Mg2+, Na+, K+, Cl, NO3, SO42−) and meteorological variables (relative humidity and global radiation). MS was measured using a S700X SQUID magnetometer and modeled with the Langevin equation, yielding values between 0.114 and 1.407 Am2/kg (n = 13), with a standard deviation of 0.01–0.1. Statistical analysis revealed similar median values between MS and the studied variables, indicating shared sources of PM10. The higher total concentrations of metals (Fe > Sr > Mn) and ions (Ca2+ = 30 %, Na+ = 23 % of total ions) suggest a natural origin of PM10, likely from soil minerals. In contrast, metals (Cu, V, Cd, Ni, Co and Zn) and ions (SO42−, NO3) of anthropogenic origin were associated with vehicle emissions and road dust. FTIR spectroscopy identified magnetite as the dominant magnetic carrier in PM10, with absorption peaks at 570 and 390 cm−1, and particle sizes ranging from 8.5 to 11 nm, although a broader size range (8–33 nm) was also observed. This supports the formation of heterogeneous particles through mineral-metal or carbonaceous adsorption, as confirmed by morphological data. The temporal distribution of MS in PM10 samples showed peak values during the rainy season, despite no direct correlation with the studied variables, suggesting that iron solubility in minerals may influence the saturation magnetization.
本研究分析了2018 - 2019年Brasília某公交车站PM10颗粒的饱和磁化强度(MS),探讨了其与化学元素(总金属Fe、V、Cu、Mn、Sr、Cd)和离子(Ca2+、Mg2+、Na+、K+、Cl−、NO3−、SO42−)以及气象变量(相对湿度和全球辐射)的关系。用S700X SQUID磁强计测量质谱,用Langevin方程建模,所得值为0.114 ~ 1.407 Am2/kg (n = 13),标准差为0.01 ~ 0.1。统计分析显示MS和研究变量之间的中位数相似,表明PM10的来源相同。较高的金属(Fe > Sr > Mn)和离子(Ca2+ = 30%, Na+ = 23%的总离子)的总浓度表明PM10的自然来源,可能来自土壤矿物质。相反,人为来源的金属(Cu、V、Cd、Ni、Co和Zn)和离子(SO42−、NO3−)与车辆排放和道路粉尘有关。FTIR光谱分析发现,PM10中的主要磁性载体为磁铁矿,吸收峰位于570和390 cm−1,粒径范围为8.5 ~ 11 nm,但也观察到更宽的粒径范围(8 ~ 33 nm)。这支持通过矿物-金属或碳质吸附形成的非均质颗粒,正如形态学数据所证实的那样。PM10样品中MS的时间分布在雨季达到峰值,尽管与所研究的变量没有直接相关,这表明铁在矿物中的溶解度可能影响饱和磁化强度。
{"title":"Evaluating magnetic properties of atmospheric particulate matter (PM10) at Brasília bus station, central Brazil","authors":"Poliana Dutra Maia ,&nbsp;Elder Yokoyama ,&nbsp;Luiza de Souza Romano ,&nbsp;Guilherme Gomide ,&nbsp;Jerome Depeyrot ,&nbsp;Sebastião William da Silva ,&nbsp;Myller de Sousa Tonhá","doi":"10.1016/j.apr.2025.102739","DOIUrl":"10.1016/j.apr.2025.102739","url":null,"abstract":"<div><div>This study analyzes the Saturation Magnetization (M<sub>S</sub>) in PM<sub>10</sub> particles collected at a central bus station in Brasília from 2018 to 2019, exploring its relationship with chemical elements (total metals - Fe, V, Cu, Mn, Sr, Cd - and ions - Ca<sup>2+</sup>, Mg<sup>2+</sup>, Na<sup>+</sup>, K<sup>+</sup>, Cl<sup>−</sup>, NO<sub>3</sub><sup>−</sup>, SO<sub>4</sub><sup>2−</sup>) and meteorological variables (relative humidity and global radiation). M<sub>S</sub> was measured using a S700X SQUID magnetometer and modeled with the Langevin equation, yielding values between 0.114 and 1.407 Am<sup>2</sup>/kg (n = 13), with a standard deviation of 0.01–0.1. Statistical analysis revealed similar median values between M<sub>S</sub> and the studied variables, indicating shared sources of PM<sub>10</sub>. The higher total concentrations of metals (Fe &gt; Sr &gt; Mn) and ions (Ca<sup>2+</sup> = 30 %, Na<sup>+</sup> = 23 % of total ions) suggest a natural origin of PM<sub>10</sub>, likely from soil minerals. In contrast, metals (Cu, V, Cd, Ni, Co and Zn) and ions (SO<sub>4</sub><sup>2−</sup>, NO<sub>3</sub><sup>−</sup>) of anthropogenic origin were associated with vehicle emissions and road dust. FTIR spectroscopy identified magnetite as the dominant magnetic carrier in PM<sub>10</sub>, with absorption peaks at 570 and 390 cm<sup>−1</sup>, and particle sizes ranging from 8.5 to 11 nm, although a broader size range (8–33 nm) was also observed. This supports the formation of heterogeneous particles through mineral-metal or carbonaceous adsorption, as confirmed by morphological data. The temporal distribution of M<sub>S</sub> in PM<sub>10</sub> samples showed peak values during the rainy season, despite no direct correlation with the studied variables, suggesting that iron solubility in minerals may influence the saturation magnetization.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102739"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145962824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of PM2.5 trends and source factors in urban and rural locations in Bangladesh 孟加拉国城市和农村地区PM2.5趋势和来源因素的比较
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-10 DOI: 10.1016/j.apr.2025.102744
Shahid Uz Zaman , Shatabdi Roy , Benjamin de Foy , Rakibul Omar , Md Abdullah Al-Amin , Prakash Bhave , Michael Howard Bergin , James Jay Schauer , Abdus Salam
Air pollution remains a critical environmental and public health concern, particularly in developing countries like Bangladesh. Although urban air pollution has received significant attention, rural areas also experience high PM2.5 concentrations. In this study, a low-cost sensor (LCS) network was deployed across five locations: Dhaka, Rajshahi, Panchagarh, Netrokona, and Bhola from April 2022 to September 2023 to assess local and regional sources of PM2.5. A Generalized Additive Model (GAM) was applied to analyze the influence of meteorology and source contributions on observed PM2.5 concentrations. The highest PM2.5 levels were recorded in Netrokona (212.81 ± 64.5 μgm−3), followed by Panchagarh (128.6 ± 71.7 μgm−3), Rajshahi (110.4 ± 48.5 μgm−3), Dhaka (105.1 ± 55.7 μgm−3) and Bhola (82.2 ± 36.2 μgm−3). A consistent diurnal pattern was observed across all sites, characterized by two peaks in the morning and evening. GAM analysis revealed that the boundary layer height had the lowest influence in Bhola and Panchagarh, while Dhaka exhibited the highest contribution. The contribution of long-range transport was found uniform at all the sites. The Trajectory Cluster Concentration Impact (TCCI) showed that the Indo-Gangetic Plain (IGP) is responsible for the enhancement of 50 μgm−3 at all the sites. However, wind transported from the Bay of Bengal associates PM2.5 reduction of 20–40 μgm−3. Impacts of local winds on the PM2.5 concentrations in the GAM simulations suggested that winds from the northwest are associated with higher PM2.5. These findings emphasize the need for comprehensive air quality management strategies that extend beyond major urban centers to include rural and semi-urban areas.
空气污染仍然是一个严重的环境和公共卫生问题,特别是在孟加拉国等发展中国家。尽管城市空气污染受到了广泛关注,但农村地区的PM2.5浓度也很高。在这项研究中,从2022年4月至2023年9月,在达卡、拉杰沙希、潘查加尔、奈特罗科纳和博拉五个地点部署了一个低成本传感器(LCS)网络,以评估当地和区域的PM2.5来源。采用广义加性模型(GAM)分析了气象和源对PM2.5浓度的影响。PM2.5浓度最高的城市为Netrokona(212.81±64.5 μgm−3),其次为Panchagarh(128.6±71.7 μgm−3)、Rajshahi(110.4±48.5 μgm−3)、Dhaka(105.1±55.7 μgm−3)和Bhola(82.2±36.2 μgm−3)。在所有地点观察到一致的日模式,其特征是早上和晚上两个高峰。GAM分析显示,边界层高度对Bhola和Panchagarh的影响最小,而达卡的贡献最大。远距离输运的贡献在所有地点都是一致的。轨迹聚类浓度影响(TCCI)表明,印度-恒河平原(IGP)对所有位点的50 μgm−3的增强负责。而来自孟加拉湾的风导致PM2.5减少20 ~ 40 μgm−3。局地风对GAM模拟中PM2.5浓度的影响表明,西北风与较高的PM2.5有关。这些研究结果强调需要制定全面的空气质量管理战略,将范围扩大到主要城市中心以外,包括农村和半城市地区。
{"title":"Comparison of PM2.5 trends and source factors in urban and rural locations in Bangladesh","authors":"Shahid Uz Zaman ,&nbsp;Shatabdi Roy ,&nbsp;Benjamin de Foy ,&nbsp;Rakibul Omar ,&nbsp;Md Abdullah Al-Amin ,&nbsp;Prakash Bhave ,&nbsp;Michael Howard Bergin ,&nbsp;James Jay Schauer ,&nbsp;Abdus Salam","doi":"10.1016/j.apr.2025.102744","DOIUrl":"10.1016/j.apr.2025.102744","url":null,"abstract":"<div><div>Air pollution remains a critical environmental and public health concern, particularly in developing countries like Bangladesh. Although urban air pollution has received significant attention, rural areas also experience high PM<sub>2.5</sub> concentrations. In this study, a low-cost sensor (LCS) network was deployed across five locations: Dhaka, Rajshahi, Panchagarh, Netrokona, and Bhola from April 2022 to September 2023 to assess local and regional sources of PM<sub>2.5</sub>. A Generalized Additive Model (GAM) was applied to analyze the influence of meteorology and source contributions on observed PM<sub>2.5</sub> concentrations. The highest PM<sub>2.5</sub> levels were recorded in Netrokona (212.81 ± 64.5 μgm<sup>−3</sup>), followed by Panchagarh (128.6 ± 71.7 μgm<sup>−3</sup>), Rajshahi (110.4 ± 48.5 μgm<sup>−3</sup>), Dhaka (105.1 ± 55.7 μgm<sup>−3</sup>) and Bhola (82.2 ± 36.2 μgm<sup>−3</sup>). A consistent diurnal pattern was observed across all sites, characterized by two peaks in the morning and evening. GAM analysis revealed that the boundary layer height had the lowest influence in Bhola and Panchagarh, while Dhaka exhibited the highest contribution. The contribution of long-range transport was found uniform at all the sites. The Trajectory Cluster Concentration Impact (TCCI) showed that the Indo-Gangetic Plain (IGP) is responsible for the enhancement of 50 μgm<sup>−3</sup> at all the sites. However, wind transported from the Bay of Bengal associates PM<sub>2.5</sub> reduction of 20–40 μgm<sup>−3</sup>. Impacts of local winds on the PM<sub>2.5</sub> concentrations in the GAM simulations suggested that winds from the northwest are associated with higher PM<sub>2.5</sub>. These findings emphasize the need for comprehensive air quality management strategies that extend beyond major urban centers to include rural and semi-urban areas.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102744"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the control effectiveness in mitigation acid deposition in a valley city in China 中国某河谷城市酸沉降防治效果评价
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-29 DOI: 10.1016/j.apr.2025.102766
Yaoqian Zhong , Yaqian You , Ya Yan , Longjie He , Wei Tong , Jia Xing , Jianwu Shi , Ping Ning , Jiming Hao
In valley cities, gaseous precursors emitted from near-source can rapidly deposit and give rise to localized acid rain. The presence of local slope changes and convective meteorology facilitates the convergence of pollutants, thereby reducing the likelihood of atmospheric SO2 and NOx being transported to other regions through atmospheric movement, while increasing their susceptibility to exacerbating the acid deposition process. In our study, a decade-long dataset of precipitation samples was collected and analyzed. Subsequently, emission scenarios were simulated using high-resolution nested domains in the meteorological field-driven source-directed CMAQ model generated by the WRF model. Our findings demonstrate that effective management of regional SO2 emissions plays a pivotal role in regulating precipitation pH. Two control scenarios (reduction and relocation) conducted an evaluation and comparison of these approaches. The source reduction scenario effectively ensures that annual average SO2 levels remain below the threshold of 24 μg/m3 by maintaining total industrial emissions below 2,561.62 tonnes. However, it is important to note that there are significant seasonal variations in industrial emission limits due to climate and precipitation. In the migration scenario (ignoring terrain), the environmental SO2 in the study area was significantly reduced by an average of 16 μg/m3. Compared with source abatement, the relocation of energy-intensive industries to regions characterized by lower relative humidity mitigates pollution impacts on mountainous cities and ensures long-term economic benefits. Under complex terrain and small range of special meteorological conditions, the influencing factors of air pollution process and how to implement effective control strategies deserve continuous attention.
在山谷城市,从近源排放的气态前体可以迅速沉积并引起局部酸雨。局地坡度变化和对流气象的存在促进了污染物的辐合,从而降低了大气中SO2和NOx通过大气运动输送到其他地区的可能性,同时增加了它们加剧酸沉降过程的易感性。在我们的研究中,收集并分析了一个长达十年的降水样本数据集。随后,在WRF模式生成的气象场驱动源定向CMAQ模式中,利用高分辨率嵌套域对排放情景进行了模拟。研究结果表明,区域SO2排放的有效管理在调节降水ph中起着关键作用,并对两种控制方案(减少和迁移)进行了评价和比较。源头减排方案通过将工业总排放量控制在2561.62吨以下,有效确保年平均二氧化硫水平保持在24 μg/m3以下。然而,重要的是要注意到,由于气候和降水,工业排放限值存在显著的季节性变化。在迁移情景下(不考虑地形),研究区环境SO2显著降低,平均降低16 μg/m3。与源头治理相比,高耗能产业向相对湿度较低的地区转移可以减轻对山区城市的污染影响,保证长期经济效益。在复杂地形和小范围特殊气象条件下,大气污染过程的影响因素以及如何实施有效的控制策略值得持续关注。
{"title":"Evaluation of the control effectiveness in mitigation acid deposition in a valley city in China","authors":"Yaoqian Zhong ,&nbsp;Yaqian You ,&nbsp;Ya Yan ,&nbsp;Longjie He ,&nbsp;Wei Tong ,&nbsp;Jia Xing ,&nbsp;Jianwu Shi ,&nbsp;Ping Ning ,&nbsp;Jiming Hao","doi":"10.1016/j.apr.2025.102766","DOIUrl":"10.1016/j.apr.2025.102766","url":null,"abstract":"<div><div>In valley cities, gaseous precursors emitted from near-source can rapidly deposit and give rise to localized acid rain. The presence of local slope changes and convective meteorology facilitates the convergence of pollutants, thereby reducing the likelihood of atmospheric SO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> and NO<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span> being transported to other regions through atmospheric movement, while increasing their susceptibility to exacerbating the acid deposition process. In our study, a decade-long dataset of precipitation samples was collected and analyzed. Subsequently, emission scenarios were simulated using high-resolution nested domains in the meteorological field-driven source-directed CMAQ model generated by the WRF model. Our findings demonstrate that effective management of regional SO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> emissions plays a pivotal role in regulating precipitation pH. Two control scenarios (reduction and relocation) conducted an evaluation and comparison of these approaches. The source reduction scenario effectively ensures that annual average SO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> levels remain below the threshold of 24 <span><math><mrow><mi>μ</mi><mi>g</mi><mo>/</mo><msup><mrow><mi>m</mi></mrow><mrow><mn>3</mn></mrow></msup></mrow></math></span> by maintaining total industrial emissions below 2,561.62 tonnes. However, it is important to note that there are significant seasonal variations in industrial emission limits due to climate and precipitation. In the migration scenario (ignoring terrain), the environmental SO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> in the study area was significantly reduced by an average of 16 <span><math><mrow><mi>μ</mi><mi>g</mi><mo>/</mo><msup><mrow><mi>m</mi></mrow><mrow><mn>3</mn></mrow></msup></mrow></math></span>. Compared with source abatement, the relocation of energy-intensive industries to regions characterized by lower relative humidity mitigates pollution impacts on mountainous cities and ensures long-term economic benefits. Under complex terrain and small range of special meteorological conditions, the influencing factors of air pollution process and how to implement effective control strategies deserve continuous attention.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102766"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Long-term PM2.5 source apportionment at 12 sites in the western United States from 2000 to 2020 2000 - 2020年美国西部12个站点PM2.5长期源分配
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-10-13 DOI: 10.1016/j.apr.2025.102779
Kamaljeet Kaur , Jenna R. Krall , Cesunica Ivey , Heather Holmes , Kerry E. Kelly
Long-term source attribution studies help evaluate the effectiveness of PM2.5 reduction strategies, but inconsistencies in chemical speciation methods complicate source attribution. This study addresses these challenges by integrating Positive Matrix Factorization and Chemical Mass Balance to assess source contributions to PM2.5 over a 20-year period (2000–2020) at 12 monitoring sites in five western U.S. states: Utah (Bountiful, Hawthorne, Lindon), California (Fresno, Bakersfield, Modesto, Visalia, Sacramento), Nevada (Reno, Las Vegas), Idaho (Boise), and Colorado (Commerce City). At each site, this study identified five to eight source factors including secondary ammonium nitrate (AN), secondary ammonium sulfate (AS), dust, chloride, organic carbon (OC) rich, elemental carbon (EC) rich, EC Cu rich, Cl Zn rich, and aged sea salt. Over two decades, PM2.5 concentrations significantly declined (−0.38 to −0.037 μg/m3 per year) at all sites except Boise and Commerce City. Declines in AN, AS, EC rich, and EC Cu rich concentrations suggest the role of stringent national regulations on mobile, point, and area sources, resulting in reductions in NOx, SO2, and direct PM2.5 emissions. Despite increasing vehicle miles traveled (VMT), EC rich (vehicle) concentrations decreased, indicating the importance of lower per-vehicle emissions. Winter OC rich concentrations, linked to biomass burning, saw the largest seasonal decline due to national and local efforts to curb residential wood combustion emissions. In contrast, dust concentrations generally increased, likely driven by rising regional aridity and VMT. These findings underscore the long-term effectiveness of air-quality policies in reducing PM2.5 concentrations.
长期源归因研究有助于评估PM2.5减排策略的有效性,但化学形态方法的不一致性使源归因复杂化。本研究通过整合正矩阵分解和化学质量平衡,在美国西部五个州的12个监测点评估20年间(2000-2020年)PM2.5的来源贡献,解决了这些挑战:犹他州(Bountiful, Hawthorne, Lindon),加利福尼亚州(弗雷斯诺,贝克斯菲尔德,莫德斯托,维萨利亚,萨克拉门托),内华达州(里诺,拉斯维加斯),爱达荷州(博伊西)和科罗拉多州(Commerce City)。每个样点的源因子包括硝酸铵(AN)、硫酸铵(AS)、粉尘、氯化物、富有机碳(OC)、富元素碳(EC)、富元素铜(EC)、富氯锌(Cl Zn)和老化海盐等5 ~ 8个。20多年来,除博伊西和商业城外,其他站点的PM2.5浓度均显著下降(- 0.38 ~ - 0.037 μg/m3 /年)。AN、AS、EC富和EC富Cu浓度的下降表明,国家对移动、点和区域源的严格监管起到了作用,从而减少了NOx、SO2和PM2.5的直接排放。尽管车辆行驶里程(VMT)增加了,但含EC(车辆)的浓度却下降了,这表明降低每辆车排放量的重要性。由于国家和地方努力遏制住宅木材燃烧排放,与生物质燃烧有关的冬季OC富浓度出现了最大的季节性下降。相比之下,尘埃浓度普遍增加,可能是由区域干旱和车辆行驶里程上升造成的。这些发现强调了空气质量政策在降低PM2.5浓度方面的长期有效性。
{"title":"Long-term PM2.5 source apportionment at 12 sites in the western United States from 2000 to 2020","authors":"Kamaljeet Kaur ,&nbsp;Jenna R. Krall ,&nbsp;Cesunica Ivey ,&nbsp;Heather Holmes ,&nbsp;Kerry E. Kelly","doi":"10.1016/j.apr.2025.102779","DOIUrl":"10.1016/j.apr.2025.102779","url":null,"abstract":"<div><div>Long-term source attribution studies help evaluate the effectiveness of PM<sub>2.5</sub> reduction strategies, but inconsistencies in chemical speciation methods complicate source attribution. This study addresses these challenges by integrating Positive Matrix Factorization and Chemical Mass Balance to assess source contributions to PM<sub>2.5</sub> over a 20-year period (2000–2020) at 12 monitoring sites in five western U.S. states: Utah (Bountiful, Hawthorne, Lindon), California (Fresno, Bakersfield, Modesto, Visalia, Sacramento), Nevada (Reno, Las Vegas), Idaho (Boise), and Colorado (Commerce City). At each site, this study identified five to eight source factors including secondary ammonium nitrate (AN), secondary ammonium sulfate (AS), dust, chloride, organic carbon (OC) rich, elemental carbon (EC) rich, EC Cu rich, Cl Zn rich, and aged sea salt. Over two decades, PM<sub>2.5</sub> concentrations significantly declined (−0.38 to −0.037 μg/m<sup>3</sup> per year) at all sites except Boise and Commerce City. Declines in AN, AS, EC rich, and EC Cu rich concentrations suggest the role of stringent national regulations on mobile, point, and area sources, resulting in reductions in NO<sub>x</sub>, SO<sub>2</sub>, and direct PM<sub>2.5</sub> emissions. Despite increasing vehicle miles traveled (VMT), EC rich (vehicle) concentrations decreased, indicating the importance of lower per-vehicle emissions. Winter OC rich concentrations, linked to biomass burning, saw the largest seasonal decline due to national and local efforts to curb residential wood combustion emissions. In contrast, dust concentrations generally increased, likely driven by rising regional aridity and VMT. These findings underscore the long-term effectiveness of air-quality policies in reducing PM<sub>2.5</sub> concentrations.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102779"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145962813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Field evaluation of ammonia emissions, yield performance, and profitability under four nitrogen fertilizers in vegetable cultivation 4种氮肥在蔬菜种植中的氨排放、产量表现和效益的田间评价
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-10-03 DOI: 10.1016/j.apr.2025.102773
Oyunerdene Boldsaikhan , Eun-Chae Im , Jae-In Lee , Chang-Gu Lee , Seong-Jik Park
Ammonia (NH3) emissions from vegetable cropping systems represent a significant pathway for nitrogen loss, leading to soil acidification and atmospheric pollution. This two-year field study (2022–2023) investigated the impacts of four nitrogen fertilizers—urea (UR), ammonium sulfate (AS), composite fertilizer (CMP), and latex-coated urea (LCU)—on NH3 emissions, crop yield, and economic viability in fields of potatoes and Chinese cabbage. NH3 fluxes were quantified using a static chamber method, and a Random Forest analysis identified fertilizer type, soil temperature, air temperature, and soil moisture as primary factors influencing daily emissions. Partial dependence analysis revealed that soil moisture had a dual effect on NH3 volatilization, with fluxes decreasing at 8–20 % but increasing again above 20 %. Compared to UR, AS and CMP significantly reduced cumulative NH3 losses by 35.8 % and 49.5 % in potatoes, and by 80.3 % and 52.5 % in cabbage, respectively. LCU reduced NH3 emissions in cabbage by 51.3 % but showed inconsistent effects in potatoes, likely due to soil moisture and coating degradation. Economic analysis revealed that AS provided the highest net benefit in potato production, increasing profitability by 24.9 % over UR; this was followed by CMP at 11.5 % and LCU at 5.8 %. In contrast, UR was the most profitable fertilizer for cabbage, while LCU (−31.9 %) and AS (−29.9 %) reduced net returns due to higher costs and lower yields. These results highlight the necessity of selecting nitrogen fertilizers based on crop type and field conditions to simultaneously minimize NH3 losses and optimize economic returns in vegetable production systems.
蔬菜种植系统的氨(NH3)排放是氮素流失的重要途径,导致土壤酸化和大气污染。本研究(2022-2023)为期两年,研究了尿素(UR)、硫酸铵(AS)、复合肥(CMP)和乳包膜尿素(LCU) 4种氮肥对马铃薯和白菜田NH3排放、作物产量和经济可行性的影响。采用静态室法对NH3通量进行了量化,随机森林分析确定了肥料类型、土壤温度、空气温度和土壤湿度是影响日排放的主要因素。部分相关分析表明,土壤湿度对NH3挥发有双重影响,在8 ~ 20%时通量下降,在20%以上又增加。与UR相比,AS和CMP分别显著降低了马铃薯的累积NH3损失35.8%和49.5%,白菜的累积NH3损失80.3%和52.5%。LCU在白菜中减少了51.3%的NH3排放,但在马铃薯中表现出不一致的效果,可能是由于土壤湿度和涂层降解。经济分析表明,AS在马铃薯生产中提供了最高的净效益,比UR提高了24.9%的盈利能力;其次是CMP为11.5%,LCU为5.8%。相比之下,UR是白菜最有利可图的肥料,而LCU(- 31.9%)和AS(- 29.9%)由于成本较高和产量较低而降低了净收益。这些结果强调了根据作物类型和田间条件选择氮肥的必要性,以同时减少NH3损失并优化蔬菜生产系统的经济效益。
{"title":"Field evaluation of ammonia emissions, yield performance, and profitability under four nitrogen fertilizers in vegetable cultivation","authors":"Oyunerdene Boldsaikhan ,&nbsp;Eun-Chae Im ,&nbsp;Jae-In Lee ,&nbsp;Chang-Gu Lee ,&nbsp;Seong-Jik Park","doi":"10.1016/j.apr.2025.102773","DOIUrl":"10.1016/j.apr.2025.102773","url":null,"abstract":"<div><div>Ammonia (NH<sub>3</sub>) emissions from vegetable cropping systems represent a significant pathway for nitrogen loss, leading to soil acidification and atmospheric pollution. This two-year field study (2022–2023) investigated the impacts of four nitrogen fertilizers—urea (UR), ammonium sulfate (AS), composite fertilizer (CMP), and latex-coated urea (LCU)—on NH<sub>3</sub> emissions, crop yield, and economic viability in fields of potatoes and Chinese cabbage. NH<sub>3</sub> fluxes were quantified using a static chamber method, and a Random Forest analysis identified fertilizer type, soil temperature, air temperature, and soil moisture as primary factors influencing daily emissions. Partial dependence analysis revealed that soil moisture had a dual effect on NH<sub>3</sub> volatilization, with fluxes decreasing at 8–20 % but increasing again above 20 %. Compared to UR, AS and CMP significantly reduced cumulative NH<sub>3</sub> losses by 35.8 % and 49.5 % in potatoes, and by 80.3 % and 52.5 % in cabbage, respectively. LCU reduced NH<sub>3</sub> emissions in cabbage by 51.3 % but showed inconsistent effects in potatoes, likely due to soil moisture and coating degradation. Economic analysis revealed that AS provided the highest net benefit in potato production, increasing profitability by 24.9 % over UR; this was followed by CMP at 11.5 % and LCU at 5.8 %. In contrast, UR was the most profitable fertilizer for cabbage, while LCU (−31.9 %) and AS (−29.9 %) reduced net returns due to higher costs and lower yields. These results highlight the necessity of selecting nitrogen fertilizers based on crop type and field conditions to simultaneously minimize NH<sub>3</sub> losses and optimize economic returns in vegetable production systems.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102773"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pollen harvested from trees as a biomonitor of atmospheric pollution by semi-volatile compounds in an urban area: benzo(a)pyrene extracted from samples of Cupressus sempervirens pollen grains and PM10 从树木采集的花粉作为城市地区大气污染的半挥发性化合物的生物监测仪:从柏树花粉颗粒和PM10样品中提取的苯并(a)芘
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-20 DOI: 10.1016/j.apr.2025.102763
Juan J. Hidalgo-Barquero , Selena Carretero-Peña , Eduardo Pinilla-Gil
Benzo(a)pyrene (BaP), a known toxic air pollutant regulated by ambient air quality regulations, can adhere to pollen grains from the gaseous phase or bound to adsorbed atmospheric particles. This study investigated the applicability of a method based on microwave extraction and HPLC-FD (fluorescence detection) to measure BaP attached to airborne pollen samples of Cupressus sempervirens collected from the urban area of Badajoz (Spain) during the species' peak pollination month (February) to assess the variability of BaP levels. After testing the analytical quality of the method, we sampled and assayed pollen samples collected from trees located in Badajoz (Southwest Spain) urban areas, finding BaP levels ranging between 84.9 and 140.6 μg kg−1. The results were significantly higher than those measured in pollen samples collected at a rural unpolluted site (mean value 87.7 μg kg−1). As a reference, we simultaneously measured PM concentration (PM10, PM2,5 and PM1) and BaP concentration in PM10 samples collected by high-volume sampling at an official air quality surveillance unit in the city (range 2.39–11.29 mg kg−1). BaP levels in the pollen samples assayed reflect the urban variability in terms of emission sources contributing to BaP pollution, with higher values in pollen collected from trees in urban locations exposed to dense traffic and lower values in quiet pedestrian areas. These results suggest that Cupressus sempervirens pollen grains harvested from trees could be effective air pollution biomonitors for atmospheric BaP in urban areas.
苯并(a)芘(BaP)是一种已知的有毒空气污染物,受环境空气质量法规的管制,它可以从气相附着在花粉粒上或与吸附的大气颗粒结合。本研究采用微波提取和HPLC-FD(荧光检测)相结合的方法,对西班牙巴达霍斯(Badajoz)城区常绿柏树(Cupressus sempervirens)传粉高峰期(2月)空气中花粉样品中BaP的含量进行了测定,以评估BaP含量的变异性。在测试了该方法的分析质量后,我们对巴达霍斯(西班牙西南部)城区树木采集的花粉样本进行了采样和分析,发现BaP水平在84.9至140.6 μg kg - 1之间。结果显著高于农村未污染地点采集的花粉样本(平均值87.7 μg kg−1)。作为参考,我们同时测量了在城市官方空气质量监测单位大容量采样收集的PM10样品中的PM浓度(PM10, pmm2,5和PM1)和BaP浓度(范围2.39-11.29 mg kg - 1)。花粉样本中的BaP水平反映了造成BaP污染的排放源的城市变异性,在交通密集的城市树木中采集的花粉值较高,而在安静的步行区采集的花粉值较低。这些结果表明,从树木中收获的柏树花粉颗粒可以作为城市大气中BaP的有效空气污染生物监测仪。
{"title":"Pollen harvested from trees as a biomonitor of atmospheric pollution by semi-volatile compounds in an urban area: benzo(a)pyrene extracted from samples of Cupressus sempervirens pollen grains and PM10","authors":"Juan J. Hidalgo-Barquero ,&nbsp;Selena Carretero-Peña ,&nbsp;Eduardo Pinilla-Gil","doi":"10.1016/j.apr.2025.102763","DOIUrl":"10.1016/j.apr.2025.102763","url":null,"abstract":"<div><div>Benzo(a)pyrene (BaP), a known toxic air pollutant regulated by ambient air quality regulations, can adhere to pollen grains from the gaseous phase or bound to adsorbed atmospheric particles. This study investigated the applicability of a method based on microwave extraction and HPLC-FD (fluorescence detection) to measure BaP attached to airborne pollen samples of <em>Cupressus sempervirens</em> collected from the urban area of Badajoz (Spain) during the species' peak pollination month (February) to assess the variability of BaP levels. After testing the analytical quality of the method, we sampled and assayed pollen samples collected from trees located in Badajoz (Southwest Spain) urban areas, finding BaP levels ranging between 84.9 and 140.6 μg kg<sup>−1</sup>. The results were significantly higher than those measured in pollen samples collected at a rural unpolluted site (mean value 87.7 μg kg<sup>−1</sup>). As a reference, we simultaneously measured PM concentration (PM<sub>10</sub>, PM<sub>2,5</sub> and PM<sub>1</sub>) and BaP concentration in PM<sub>10</sub> samples collected by high-volume sampling at an official air quality surveillance unit in the city (range 2.39–11.29 mg kg<sup>−1</sup>). BaP levels in the pollen samples assayed reflect the urban variability in terms of emission sources contributing to BaP pollution, with higher values in pollen collected from trees in urban locations exposed to dense traffic and lower values in quiet pedestrian areas. These results suggest that <em>Cupressus sempervirens</em> pollen grains harvested from trees could be effective air pollution biomonitors for atmospheric BaP in urban areas.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102763"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioaerosol and their health risk assessment: A multi-location yearlong study over an urban non-attainment city 生物气溶胶及其健康风险评估:对城市非达标城市的多地点为期一年的研究
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-24 DOI: 10.1016/j.apr.2025.102764
Jyotishree Nath , Sony Pandey , Boopathy Ramasamy , Trupti Das
Bioaerosols are an integral part of myriad toxic components in ambient particulate matter (PM) that pose a serious health risk while contributing to degradation of air quality. In this context a yearlong (June 2022–May 2023) diversity study of bacteria, fungus and PM2.5 in ambient air was conducted at three distinct locations- dump yard (DY), open market (OM), and clean office campus (OC) at Bhubaneswar, a major non-attainment city in eastern coast of India. Antimicrobial resistance profiling and health risk assessment analysis was also performed. The overall bacterial concentration at DY (105 ± 10), OM (204 ± 21), and OC (34 ± 05) CFU/m3 × 102 was higher than that of fungus at DY (12 ± 05), OM (14 ± 06), and OC (10 ± 07) CFU/m3 × 102. Bacillus and Aspergillus were common across all the three sites. Biomolecular profiling revealed maximum bacterial diversity at OM with the presence of gram-negative pathogens such as Pseudomonas and Stenotrophomonas. Irrespective of the site, all the bacterial and fungal strains were susceptible to azithromycin and canditral, respectively. Most of the strains from OM and DY were resistant to the antimicrobial agents. Health risk assessment showed the vulnerability of children to microbial exposures and males to short-term inhalation. Correlation analysis revealed a positive and negative association with PM2.5 and temperature respectively. The current findings provide novel seasonal data in ambient air of an urban set up on microbial diversity, their anti-microbial properties and hazard index. These are crucial information for the stakeholders and urban planners.
生物气溶胶是环境颗粒物(PM)中无数有毒成分的组成部分,对健康构成严重威胁,同时导致空气质量退化。在此背景下,一项为期一年(2022年6月至2023年5月)的环境空气中细菌、真菌和PM2.5多样性研究在布巴内斯瓦尔的三个不同地点进行——垃圾场(DY)、开放市场(OM)和清洁办公园区(OC),布巴内斯瓦尔是印度东海岸一个主要的不成功城市。还进行了抗菌素耐药性分析和健康风险评估分析。DY(105±10)、OM(204±21)和OC(34±05)CFU/m3 × 102的细菌总浓度高于DY(12±05)、OM(14±06)和OC(10±07)CFU/m3 × 102的真菌总浓度。芽孢杆菌和曲霉在所有三个地点都很常见。生物分子分析显示,在OM存在革兰氏阴性病原体,如假单胞菌和窄养单胞菌的情况下,细菌多样性最大。无论在哪个部位,所有的细菌和真菌菌株分别对阿奇霉素和念珠菌啶敏感。OM和DY的大部分菌株对抗菌药物耐药。健康风险评估显示,儿童易受微生物接触的影响,男性易受短期吸入的影响。相关分析显示,PM2.5与气温分别呈正相关和负相关。本研究结果为城市环境空气中微生物多样性、抗菌特性和危害指数提供了新的季节性数据。这些对利益相关者和城市规划者来说都是至关重要的信息。
{"title":"Bioaerosol and their health risk assessment: A multi-location yearlong study over an urban non-attainment city","authors":"Jyotishree Nath ,&nbsp;Sony Pandey ,&nbsp;Boopathy Ramasamy ,&nbsp;Trupti Das","doi":"10.1016/j.apr.2025.102764","DOIUrl":"10.1016/j.apr.2025.102764","url":null,"abstract":"<div><div>Bioaerosols are an integral part of myriad toxic components in ambient particulate matter (PM) that pose a serious health risk while contributing to degradation of air quality. In this context a yearlong (June 2022–May 2023) diversity study of bacteria, fungus and PM<sub>2.5</sub> in ambient air was conducted at three distinct locations- dump yard (DY), open market (OM), and clean office campus (OC) at Bhubaneswar, a major non-attainment city in eastern coast of India. Antimicrobial resistance profiling and health risk assessment analysis was also performed. The overall bacterial concentration at DY (105 ± 10), OM (204 ± 21), and OC (34 ± 05) CFU/m<sup>3</sup> × 10<sup>2</sup> was higher than that of fungus at DY (12 ± 05), OM (14 ± 06), and OC (10 ± 07) CFU/m<sup>3</sup> × 10<sup>2</sup>. <em>Bacillus</em> and <em>Aspergillus</em> were common across all the three sites. Biomolecular profiling revealed maximum bacterial diversity at OM with the presence of gram-negative pathogens such as <em>Pseudomonas</em> and <em>Stenotrophomonas</em>. Irrespective of the site, all the bacterial and fungal strains were susceptible to azithromycin and canditral, respectively. Most of the strains from OM and DY were resistant to the antimicrobial agents. Health risk assessment showed the vulnerability of children to microbial exposures and males to short-term inhalation. Correlation analysis revealed a positive and negative association with PM<sub>2.5</sub> and temperature respectively. The current findings provide novel seasonal data in ambient air of an urban set up on microbial diversity, their anti-microbial properties and hazard index. These are crucial information for the stakeholders and urban planners.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102764"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A proposal of indoor air pollutant limit values for Turkish schools based on a literature review of emission sources, concentrations, health effects, and limits/guidelines 根据对排放源、浓度、健康影响和限值/准则的文献审查,提出土耳其学校室内空气污染物极限值的建议
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-09-11 DOI: 10.1016/j.apr.2025.102743
Sait Cemil Sofuoglu , Akif Ari , Mihriban Civan , Yetkin Dumanoglu , Gulen Gullu , Sibel Mentese , Burcu Onat , Ülkü Alver Şahin , Macit Toksoy
Limit Values Working Group (LVWG) was established under Indoor Air Quality Committee of Turkish Climatization Assembly of the Union of Chambers and Commodity Exchanges of Türkiye. LVWG was tasked with reviewing the pertinent literature on indoor emission sources, concentrations in schools, health effects, and existing limit and guideline values to identify the indoor air pollutants that need to be addressed and to be recommended a limit value for Turkish schools. LVWG members took responsibilities based on their individual expertise. The recommendations were concluded in consensus decision-making after in-group discussions. A total of 19 pollutants/pollutant groups (carbon dioxide, carbon monoxide, nitrogen dioxide, ozone, radon, volatile organic compounds, formaldehyde, trihalomethanes, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, brominated flame retardants, organophosphate esters, phthalate esters, particulate matter, bioaerosols (bacteria, fungi, viruses), microbial pollutants and allergens) were reviewed. Limit values were recommended for 11 pollutants/groups based on the current knowledge, i.e. pollutant health effects and indoor air concentrations taking into account the exposure duration, the prevalence of existing limit/guideline values and the health effects on which they are based.
限值工作组(LVWG)是在土耳其商会和商品交易所联盟土耳其气候大会室内空气质量委员会下成立的。工作小组的任务是审查有关室内排放源、学校浓度、健康影响以及现有限值和指导值的相关文献,以确定需要解决的室内空气污染物,并为土耳其学校建议一个限值。LVWG成员根据各自的专业知识承担责任。这些建议是在小组讨论后以协商一致的决策方式得出的。综述了19种污染物/污染物组(二氧化碳、一氧化碳、二氧化氮、臭氧、氡、挥发性有机物、甲醛、三卤甲烷、多环芳烃、多氯联苯、溴化阻燃剂、有机磷酸酯、邻苯二甲酸酯、颗粒物、生物气溶胶(细菌、真菌、病毒)、微生物污染物和过敏原)。根据目前的知识,即污染物对健康的影响和室内空气浓度,建议了11种污染物/组的极限值,同时考虑到接触时间、现有极限值/指标值的普遍程度以及它们所依据的健康影响。
{"title":"A proposal of indoor air pollutant limit values for Turkish schools based on a literature review of emission sources, concentrations, health effects, and limits/guidelines","authors":"Sait Cemil Sofuoglu ,&nbsp;Akif Ari ,&nbsp;Mihriban Civan ,&nbsp;Yetkin Dumanoglu ,&nbsp;Gulen Gullu ,&nbsp;Sibel Mentese ,&nbsp;Burcu Onat ,&nbsp;Ülkü Alver Şahin ,&nbsp;Macit Toksoy","doi":"10.1016/j.apr.2025.102743","DOIUrl":"10.1016/j.apr.2025.102743","url":null,"abstract":"<div><div>Limit Values Working Group (LVWG) was established under Indoor Air Quality Committee of Turkish Climatization Assembly of the Union of Chambers and Commodity Exchanges of Türkiye. LVWG was tasked with reviewing the pertinent literature on indoor emission sources, concentrations in schools, health effects, and existing limit and guideline values to identify the indoor air pollutants that need to be addressed and to be recommended a limit value for Turkish schools. LVWG members took responsibilities based on their individual expertise. The recommendations were concluded in consensus decision-making after in-group discussions. A total of 19 pollutants/pollutant groups (carbon dioxide, carbon monoxide, nitrogen dioxide, ozone, radon, volatile organic compounds, formaldehyde, trihalomethanes, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, brominated flame retardants, organophosphate esters, phthalate esters, particulate matter, bioaerosols (bacteria, fungi, viruses), microbial pollutants and allergens) were reviewed. Limit values were recommended for 11 pollutants/groups based on the current knowledge, i.e. pollutant health effects and indoor air concentrations taking into account the exposure duration, the prevalence of existing limit/guideline values and the health effects on which they are based.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102743"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145962826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization and source analysis of carbonyl compounds in a rural area of north China Plain: Results from 1-year continuous observations 华北平原农村地区羰基化合物的特征和来源分析:1年连续观测结果
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 Epub Date: 2025-10-10 DOI: 10.1016/j.apr.2025.102772
Wenxin Cao , Xuran Li , Shuyang Xie , Jinyong Yang , Pengfei Liu , Chengtang Liu , Yuanyuan Zhang , Chenglong Zhang , Yujing Mu , Junfeng Liu
Carbonyl compounds are significant in atmospheric chemistry and human health, yet their sources, especially in rural areas, remain incompletely characterized. Long-term measurements (June 2020–July 2021) at a rural site in the North China Plain (NCP) identified formaldehyde, acetaldehyde, and acetone as the dominant carbonyls, collectively accounting for 71 % of the total. Concentrations exhibited distinct seasonal patterns, with the highest levels observed for all three compounds during autumn. Analysis of C1/C2 ratios and correlation analysis indicated anthropogenic emissions as the primary source overall. Notably, during autumn, strong mutual correlations among formaldehyde, acetaldehyde, and acetone were observed, contrasting with weaker correlations to CO and O3. Supplementary experiments confirmed that mechanical corn stover crushing releases substantial amounts of carbonyls. These convergent findings demonstrate that large-scale seasonal agricultural activities, particularly corn stover crushing and agricultural machinery during harvest periods, constitute a major and previously underappreciated source of carbonyl emissions in the NCP region, necessitating greater attention in emission inventories and mitigation strategies. Furthermore, integrated lifetime cancer risk (ILTCR) and hazard quotient (HQ) assessments indicated that formaldehyde concentrations pose a potential lifetime carcinogenic risk to the local population.
羰基化合物在大气化学和人类健康方面具有重要意义,但它们的来源,特别是在农村地区,仍然没有完全确定。在华北平原(NCP)的一个农村地区进行的长期测量(2020年6月至2021年7月)发现,甲醛、乙醛和丙酮是主要的羰基,共占总量的71%。浓度表现出明显的季节特征,在秋季这三种化合物的浓度最高。C1/C2比值分析和相关分析表明,人为排放总体上是主要排放源。值得注意的是,在秋季,甲醛、乙醛和丙酮之间存在很强的相互相关性,而CO和O3之间的相关性较弱。补充实验证实,机械粉碎玉米秸秆释放大量的羰基。这些趋同的发现表明,大规模的季节性农业活动,特别是收获期间的玉米秸秆粉碎和农业机械,构成了NCP区域羰基排放的一个主要来源,但以前未得到充分认识,因此必须更加重视排放清单和缓解战略。此外,综合终身癌症风险(ILTCR)和危害商(HQ)评估表明,甲醛浓度对当地人口构成潜在的终身致癌风险。
{"title":"Characterization and source analysis of carbonyl compounds in a rural area of north China Plain: Results from 1-year continuous observations","authors":"Wenxin Cao ,&nbsp;Xuran Li ,&nbsp;Shuyang Xie ,&nbsp;Jinyong Yang ,&nbsp;Pengfei Liu ,&nbsp;Chengtang Liu ,&nbsp;Yuanyuan Zhang ,&nbsp;Chenglong Zhang ,&nbsp;Yujing Mu ,&nbsp;Junfeng Liu","doi":"10.1016/j.apr.2025.102772","DOIUrl":"10.1016/j.apr.2025.102772","url":null,"abstract":"<div><div>Carbonyl compounds are significant in atmospheric chemistry and human health, yet their sources, especially in rural areas, remain incompletely characterized. Long-term measurements (June 2020–July 2021) at a rural site in the North China Plain (NCP) identified formaldehyde, acetaldehyde, and acetone as the dominant carbonyls, collectively accounting for 71 % of the total. Concentrations exhibited distinct seasonal patterns, with the highest levels observed for all three compounds during autumn. Analysis of C1/C2 ratios and correlation analysis indicated anthropogenic emissions as the primary source overall. Notably, during autumn, strong mutual correlations among formaldehyde, acetaldehyde, and acetone were observed, contrasting with weaker correlations to CO and O<sub>3</sub>. Supplementary experiments confirmed that mechanical corn stover crushing releases substantial amounts of carbonyls. These convergent findings demonstrate that large-scale seasonal agricultural activities, particularly corn stover crushing and agricultural machinery during harvest periods, constitute a major and previously underappreciated source of carbonyl emissions in the NCP region, necessitating greater attention in emission inventories and mitigation strategies. Furthermore, integrated lifetime cancer risk (ILTCR) and hazard quotient (HQ) assessments indicated that formaldehyde concentrations pose a potential lifetime carcinogenic risk to the local population.</div></div>","PeriodicalId":8604,"journal":{"name":"Atmospheric Pollution Research","volume":"17 2","pages":"Article 102772"},"PeriodicalIF":3.5,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Atmospheric Pollution Research
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1