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Using Multilayer Perceptron Artificial Neural Network for Predicting and Modeling the Chemical Oxygen Demand of the Gamasiab River 应用多层感知器人工神经网络预测和建模加马锡亚布河化学需氧量
Q4 Environmental Science Pub Date : 2018-06-23 DOI: 10.15171/AJEHE.2018.03
Mohamad Parsimehr, K. Shayesteh, K. Godini, Maryam Bayat Varkeshi
Concerns about water quality have widely increased in the last three decades; thus, water quality is now as important as its quantity. To study and model the quality of the Gamasiab River, its data, including chemical oxygen demand (COD), biological oxygen demand (BOD), dissolved oxygen (DO), total dissolved solids (TDS), total suspended solids in water, acidity, temperature, turbidity, and cations and anions were measured at four stations. Then, the correlations between these parameters and COD were measured using Pearson’s correlation coefficient and modeled by multilayer perceptron artificial neural network. In order to minimize the cost of the experiments performed and to provide the input parameters to the artificial neural network based on the correlations between the data and COD, the number of input parameters was reduced and finally, model No.3, with the Momentum training function and the TanhAxon activation function with the validation correlation coefficient of 0.97, mean absolute error of 2.88, and normalized root mean square error of 0.11 was identified as the most accurate model with the lowest cost. The results of the present study showed that the multilayer perceptron neural network has high ability in modeling the COD of the river, and those data correlated with each other have the greatest effect on the model. Moreover, the number of input parameters can be reduced in order to lower the cost of experiments while the performance of the model is not undermined.
在过去三十年中,人们对水质的担忧普遍增加;因此,现在水质和水量一样重要。为了研究和模拟加马锡河的水质,在四个站点测量了其数据,包括化学需氧量(COD)、生物需氧量(BOD)、溶解氧(DO)、总溶解固体(TDS)、水中总悬浮固体、酸度、温度、浊度以及阳离子和阴离子。然后,使用Pearson相关系数测量这些参数与COD之间的相关性,并用多层感知器人工神经网络建模。为了最大限度地降低所进行实验的成本,并根据数据和COD之间的相关性向人工神经网络提供输入参数,减少了输入参数的数量,最后,在3号模型中,使用动量训练函数和TanhAxon激活函数,验证相关系数为0.97,2.88的平均绝对误差和0.11的归一化均方根误差被确定为具有最低成本的最准确的模型。研究结果表明,多层感知器神经网络对河流COD具有很高的建模能力,并且相互关联的数据对模型的影响最大。此外,可以减少输入参数的数量,以降低实验成本,同时不破坏模型的性能。
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引用次数: 7
Photo-Degradation of Phenol Using TiO2/CMK-3 Photo-Catalyst Under Medium Pressure UV Lamp TiO2/CMK-3光催化剂在中压紫外灯下光降解苯酚的研究
Q4 Environmental Science Pub Date : 2018-06-20 DOI: 10.15171/AJEHE.2018.05
A. Rahmani, H. Rahimzadeh, Somayeh Beirami
Phenol is considered as one of the major environmental concerns due to its characteristics including chronic toxicity, biological stability, and increasing the toxicological intermediates after biological degradation. Therefore, the aim of this study was to evaluate the photo-degradation of phenol using the titanium dioxide (TiO2) photo-catalyst on ordered mesoporous carbon (CMK-3) support under UV irradiation. In this study, the effects of some parameters including pH value (4, 5, 6, 7, 8, 9, 10), TiO2/CMK-3 concentration (0.05, 0.1, 0.15, 0.3, 0.5 g/L), irradiation time (30, 60, 90, 120, 150 min), and phenol concentration (50, 100, 150 and 200 mg/L) were assessed. The properties of the CMK-3 and TiO2/CMK-3 were compared using the transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and N2 adsorption-desorption isotherm. The results revealed that the process studied was remarkably affected by the parameters, and the optimum values of the parameters were as follows: pH=6, TiO2/CMK-3 concentration =0.15 g/L, phenol concentration = 100 mg/L, and irradiation time=150 min. The phenol degradation efficiency and total organic carbon (TOC) removal efficiency for phenol were 96% and 74%, respectively. Moreover, the stability greater than 7 times for the studied photo-catalyst was indicative of its high potential to be used in photo-degradation processes for the elimination of pollutants.
苯酚因其具有慢性毒性、生物稳定性和生物降解后毒性中间体增加等特点而被认为是主要的环境问题之一。因此,本研究的目的是评价在紫外光照射下,二氧化钛(TiO2)光催化剂在有序介孔碳(CMK-3)载体上光降解苯酚的效果。研究了pH值(4、5、6、7、8、9、10)、TiO2/CMK-3浓度(0.05、0.1、0.15、0.3、0.5 g/L)、辐照时间(30、60、90、120、150 min)和苯酚浓度(50、100、150、200 mg/L)等参数的影响。采用透射电镜(TEM)、x射线粉末衍射(XRD)和N2吸附-脱附等温线对CMK-3和TiO2/CMK-3的性能进行了比较。结果表明,工艺条件对工艺影响较大,最佳工艺条件为pH=6, TiO2/CMK-3浓度=0.15 g/L,苯酚浓度= 100 mg/L,辐照时间=150 min,苯酚的降解效率为96%,总有机碳(TOC)去除率为74%。此外,所研究的光催化剂的稳定性大于7倍,表明其在消除污染物的光降解过程中具有很大的潜力。
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引用次数: 3
Sewage Generation and Treatment Status for the Capital City of Uttar Pradesh, India 印度北方邦首府城市污水产生和处理现状
Q4 Environmental Science Pub Date : 2018-06-17 DOI: 10.15171/AJEHE.2018.02
R. K. Gautam, Saumya Verma, Islamuddin, N. More
The piped water supply in Lucknow was introduced in 1892 to serve the population of 2 Lacs. However, the population has risen exponentially since then from 2.1 million in 2001 to 2.86 million in 2011 according to the census data of the Government of India. In this paper, statistical analysis was done and it was projected that the population of Lucknow will be as high as 4.2 million in 2025 followed by 6.42 million in 2040. Since the water demand is proportional to the population, it is projected that present water demand of 550 million liters per day (MLD) would rise to the maximum of 1300 MLD in the year 2040 which is twice more than the present volume. The major concern of Lucknow city is the poor efficiency of wastewater treatment facilities which are deteriorating the quality of underground water and surface sources. The major concern lies in Gomti River. The wastewater generation in 2025 would be as high as 700 MLD while for the year 2040 it would be 1100 MLD. To meet the given figures a well-planned and effective wastewater treatment system has to be designed and implemented which may include centralized and decentralized treatment facilities in accordance with the need of the particular division followed by up-gradation of the present water supply and sewerage system. Care should be taken while discharging the sewage into river Gomti and other natural streams as it should strictly follow the prescribed standards by central state pollution control boards, also there should be the least disturbance of aquatic ecosystem. Furthermore, deterioration of the water quality must be minimized to a large extent.
勒克瑙的管道供水于1892年引入,为2拉克人提供服务。然而,根据印度政府的人口普查数据,自那时以来,人口呈指数级增长,从2001年的210万增加到2011年的286万。在本文中,进行了统计分析,预计勒克瑙的人口在2025年将高达420万,2040年将达到642万。由于水需求量与人口成正比,预计目前每天5.5亿升的水需求量(MLD)将在2040年达到1300 MLD的最大值,这是目前水量的两倍。勒克瑙市主要关注的问题是污水处理设施效率低下,这正在恶化地下水和地表水源的质量。主要问题在于贡蒂河。2025年的废水产生量将高达700 MLD,而2040年将达到1100 MLD。为了达到给定的数字,必须设计和实施一个精心规划和有效的废水处理系统,该系统可能包括根据特定部门的需要进行集中和分散处理的设施,然后对现有的供水和污水系统进行升级。将污水排入贡蒂河和其他自然溪流时应小心,因为污水应严格遵守中央国家污染控制委员会的规定标准,对水生生态系统的干扰也应最小。此外,必须在很大程度上尽量减少水质恶化。
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引用次数: 1
Statistical Optimization and Modeling of Methylene Blue Adsorption Onto Graphene Oxide in Batch and Fixed-Bed Column 氧化石墨烯间歇和固定床柱吸附亚甲基蓝的统计优化与建模
Q4 Environmental Science Pub Date : 2018-06-17 DOI: 10.15171/AJEHE.2018.04
H. Koolivand, A. Shahbazi
The batch and fixed-bed column adsorption of methylene blue (MB), a widely used toxic dye, onto graphene oxide (GO) was investigated in this study. GO was synthesized using modified Hummers method and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). Response surface methodology (RSM) was employed to optimize batch and fixed-bed column adsorption of MB. Batch adsorption experiments were carried out by central composite design (CCD) with three input parameters including initial MB concentration (C0: 50-350 mg/L), GO dosage (D: 0.05-0.7 g/L), and pH (pH: 3-9). The adsorption capacity of GO for MB removal in the optimum level of factors (C0: 50 mg/L, D: 0.05 g/L, and pH: 8.5) was predicted by the model to be 700 mg/g. Adsorption kinetic data were tested using pseudo-first order, pseudo-second order, and intraparticle diffusion models. The kinetic experimental data was well fitted with pseudo-second order kinetic model (R2=1). The adsorption of MB onto GO demonstrated that Langmuir model (R2=0.999) could better fit the adsorption data than the Freundlich model (R2=0.914). Thermodynamic parameters including enthalpy (ΔH), Gibbs free energy (ΔG), and entropy (ΔS) were also investigated. Positive value of ΔH and negative value of ΔG indicated the endothermic and spontaneous nature of the adsorption. The positive value of ΔS also showed increased randomness at the solid/liquid interface during the adsorption of MB onto GO. The real wastewater experiment at optimum conditions showed high performance of adsorbent in the presence of other ions. Fixed-bed column experiments were designed using a three-factor, three-level Box-Behnken design (BBD) to investigate the single and combined effects of influent concentration (Cinf: 50-200 mg/L), flow rate (Q: 0.25-0.8 mL/min), and bed height (BH: 3-7 cm). MB removal from GO in the optimum levels of factors (Cinf: 51 mg/L, BH: 5.7 cm, and Q: 0.25 mL/min) was predicted by the model to be 86% (qe=459.3 mg/g). Fixed-bed experimental data were also fitted well to the Thomas and BDST models. The results showed that GO can be used as an efficient adsorbent for batch and fixed-bed adsorption of cationic dyes from synthetic and real wastewater.
研究了广泛使用的有毒染料亚甲基蓝(MB)在氧化石墨烯(GO)上的分批和固定床柱吸附。采用改进的Hummers法合成了GO,并通过扫描电子显微镜(SEM)、X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对其进行了表征。采用响应面法(RSM)对MB的分批和固定床柱吸附进行了优化。采用中心复合设计(CCD)进行批量吸附实验,输入三个参数,包括MB初始浓度(C0:50-350mg/L)、GO剂量(D:0.05-0.7g/L)和pH(pH:3-9)。通过该模型预测,在最佳因素水平(C0:50mg/L,D:0.05g/L,pH:8.5)下,GO对MB的吸附量为700mg/g。使用伪一阶、伪二阶和颗粒内扩散模型测试吸附动力学数据。动力学实验数据与拟二阶动力学模型(R2=1)拟合良好。MB在GO上的吸附表明,Langmuir模型(R2=0.999)比Freundlich模型(R2=0.0914)更能拟合吸附数据。还研究了焓(ΔH)、吉布斯自由能(ΔG)和熵(ΔS)等热力学参数。ΔH的正值和ΔG的负值表明吸附的吸热和自发性质。在MB吸附到GO上的过程中,ΔS的正值在固液界面也显示出增加的随机性。在最佳条件下的实际废水实验表明,吸附剂在其他离子存在下具有较高的吸附性能。采用三因素三级Box-Behnken设计(BBD)设计固定床柱实验,研究进水浓度(Cinf:50-200mg/L)、流速(Q:0.25-0.8mL/min)和床高(BH:3-7cm)的单一和组合影响。模型预测,在最佳因子水平(Cinf:51mg/L、BH:5.7cm和Q:0.25mL/min)下,GO对MB的去除率为86%(qe=459.3mg/g)。固定床实验数据也很好地拟合了Thomas和BDST模型。结果表明,GO可作为一种有效的吸附剂,用于间歇床和固定床吸附合成废水和实际废水中的阳离子染料。
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引用次数: 0
Removal of Reactive Blue 19 Dye Using Fenton From Aqueous Solution Fenton法去除活性蓝19染料的研究
Q4 Environmental Science Pub Date : 2018-06-14 DOI: 10.15171/AJEHE.2018.07
Fahimeh Moghadam, Najmeh Nori Kohbanan
The discharge of wastewater containing reactive dyes into water sources leads to health hazards. Colors can adversely affect the natural environment due largely to some qualities like carcinogenicity, being mutagenic, toxicity, and coloration of water. Environmental degradation can be attributed to the destruction of living organisms and the increased biological oxygen demand (BOD). The aim of this study was to evaluate the removal of Reactive Blue 19 dye using the Fenton process from aqueous solution. This research was an experimental study, in which the effectiveness of Fenton in color removal was investigated. The factors influencing this process were: pH, color concentration, the ratio of Fenton reagent (H2O2/Fe2+), and contact time. Finally, after determining the optimum concentration of color, pH, the ratio of Fenton reagent, and contact time, the residual adsorption rates in the samples were measured using direct photometry by spectrophotometer in a wavelength of 594 nm. The results showed that the highest removal efficiency was obtained under the conditions of pH =3, the color concentration of 2 mg/L, the ratio of Fenton reagent = 1:5, and the contact time equal to 10 minutes. The Fenton process is able to remove the Reactive Blue 19 under different concentrations. This process achieved the best removal efficiency in acidic pH.
将含有活性染料的废水排放到水源中会对健康造成危害。颜色会对自然环境产生不利影响,主要是由于一些性质,如致癌性、致突变性、毒性和水的着色。环境退化可归因于生物的破坏和生物需氧量的增加。本研究的目的是评估使用Fenton工艺从水溶液中去除活性蓝19染料的效果。本研究是一项实验研究,考察了芬顿对颜色的去除效果。影响这一过程的因素有:pH、颜色浓度、芬顿试剂(H2O2/Fe2+)的比例和接触时间。最后,在确定了颜色、pH、芬顿试剂的比例和接触时间的最佳浓度后,使用分光光度计在594nm的波长下直接测定样品中的残留吸附率。结果表明,在pH=3、显色浓度为2mg/L、芬顿试剂比例为1:5、接触时间为10min的条件下,去除率最高。芬顿工艺能够在不同浓度下去除反应蓝19。该工艺在酸性pH条件下达到了最佳的去除效率。
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引用次数: 3
Emission Level of PM2.5 and its Association With Chronic Respiratory Symptoms Among Workers in Cement Industry: A Case of Mugher Cement Industry, Central Ethiopia 水泥行业工人PM2.5排放水平及其与慢性呼吸道症状的关系——以埃塞俄比亚中部穆格尔水泥行业为例
Q4 Environmental Science Pub Date : 2018-06-13 DOI: 10.15171/AJEHE.2018.01
Mahlet Mekasha, A. Haddis, T. Shaweno, S. T. Mereta
In Ethiopia, occupation-related respiratory symptoms are extensively increasing with the expansion of cement manufacturing industries. However, little information is available on the extent of emissions and its association with chronic respiratory diseases. This study assessed the emission level of PM2.5 and its association with chronic respiratory symptoms among workers in Mugher Cement Factory, in 2018. A cross sectional study was employed on a total of 309 cement factory workers. Air check sampler, model 224-54, was used to measure the concentration of PM2.5. Variables with P value < 0.2 during bivariate analysis were selected as candidate for multiple logistic regressions. Significance level was set at P value <0.05. A total of 309 workers participated in the study with an overall response rate of 97%. The mean age of the respondents was 32.02 years (±4.7 SD). Emission levels of all PM2.5 samples were above the allowed standard. Among the workers, 50.8% had chronic respiratory symptoms and factors associated were: working in raw material receiving unit (adjusted odds ratio [AOR]= 7.5, 95% CI, 2.9, 19.4), cement milling unit (AOR = 2.4, 95 % CI ,1.2, 4.8), packing unit (AOR= 2.2, 95% CI= 1.1, 4.3), workers’ monthly income level below 3000 ETB (AOR; 5.8, 95% CI,1.9, 17.6), and workers’ regular medical checkup (AOR = 2.4, 95 % CI, 1.0, 5.2). The concentration level of PM2.5 and prevalence of chronic respiratory symptoms were high in the study area. Use of personal protective devices and periodic monitoring of installed pollution control devices is highly recommended.
在埃塞俄比亚,随着水泥制造业的扩张,与占领有关的呼吸道症状正在广泛增加。然而,关于排放的程度及其与慢性呼吸道疾病的关系,目前几乎没有信息。这项研究评估了2018年穆格尔水泥厂工人PM2.5的排放水平及其与慢性呼吸道症状的关系。对309名水泥厂工人进行了横断面研究。空气检查采样器,型号224-54,用于测量PM2.5的浓度。选择双变量分析中P值<0.2的变量作为多元逻辑回归的候选变量。显著性水平设定为P值<0.05。共有309名工人参与了这项研究,总体应答率为97%。受访者的平均年龄为32.02岁(±4.7标准差)。所有PM2.5样本的排放水平均高于允许的标准。在工人中,50.8%的人有慢性呼吸道症状,相关因素包括:在原材料接收单位工作(调整比值比[AOR]=7.5,95%CI,2.9,19.4),在水泥粉磨单位工作(AOR=2.4,95%CI,1.2,4.8),在包装单位工作(AOR=2.2,95%CI=1.1,4.3),工人月收入水平低于3000 ETB,和工人定期体检(AOR=2.4,95%CI,1.0,5.2)。研究区域PM2.5浓度水平和慢性呼吸道症状患病率较高。强烈建议使用个人防护设备并定期监测已安装的污染控制设备。
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引用次数: 9
Evaluation of Indoor PM Distribution by CONTAM Airflow Model and Real Time Measuring: Model Description and Validation 利用CONTAM气流模型和实时测量评估室内PM分布:模型描述和验证
Q4 Environmental Science Pub Date : 2018-06-07 DOI: 10.15171/AJEHE.2018.06
Kobra Verijkazemi, Nabiollah Mansouri, F. Moattar, S. Khezri
Particulate Matter (PM10, PM2.5, and PM1) entry into hospital buildings is important for human exposure and is associated with health effects. The present study investigated the entry of particles into Imam Khomeini general hospital building under different ventilation systems and scenarios using a multi-zone airflow and contaminant transport model. Concentrations of PM10, PM2.5, PM1, and meteorological variables (atmospheric pressure, air temperature, and relative humidity) were measured and recorded in 6 medical treatment floors and outdoor atmosphere of hospital, from June 2014 to June 2015, 7 days at each season as simulation input variables. Simulated ventilation rates were assessed using the model and then validated using both measured data and simulations. In this study, CONTAM was used as a multi-zone indoor air quality and ventilation analysis software to determine airflows and contaminant concentrations. The simulation results for PM2.5 concentration as an important contaminant in hospital floors from basement to the top and based on airflow design were 21.3, 16.5, 22, 25.4, 27.6, and 24.2 μg/m3 respectively which showed 8.1% average deviation with actual measurements in selected locations. The assessment of air ventilation effect on PM2.5 concentration proved more accumulation in winter. The study results showed that accurate particle deposition and penetration are effective in predicting the time-varying particle concentrations in all floors of hospital building. The comparison between measurements and CONTAM prediction suggests that a multi-zone particle transport model can provide insight into particle entry into the hospital building under various weather and building operating scenarios.
颗粒物(PM10、PM2.5和PM1)进入医院建筑对人体暴露很重要,并与健康影响有关。本研究使用多区域气流和污染物传输模型,调查了不同通风系统和场景下颗粒物进入伊玛目霍梅尼综合医院大楼的情况。从2014年6月至2015年6月,每个季节7天,在医院的6个医疗楼层和室外大气中测量并记录PM10、PM2.5、PM1和气象变量(大气压力、气温和相对湿度)的浓度,作为模拟输入变量。使用该模型评估模拟通风率,然后使用测量数据和模拟进行验证。在本研究中,CONTAM被用作多区域室内空气质量和通风分析软件,以确定气流和污染物浓度。根据气流设计,从地下室到顶部,PM2.5作为医院楼层的重要污染物,其模拟结果分别为21.3、16.5、22、25.4、27.6和24.2μg/m3,与选定位置的实际测量值平均偏差为8.1%。空气通风对PM2.5浓度的影响评估表明,冬季PM2.5浓度积累较多。研究结果表明,准确的颗粒物沉积和渗透可以有效地预测医院大楼各楼层随时间变化的颗粒物浓度。测量值与CONTAM预测值之间的比较表明,多区域粒子传输模型可以深入了解在各种天气和建筑物运行情况下粒子进入医院大楼的情况。
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引用次数: 3
Isolation of Mycobacterium frederiksbergense From Redundant Tap Water: A Case Report 从多余的自来水中分离frederiksbergense分枝杆菌一例
Q4 Environmental Science Pub Date : 2017-12-29 DOI: 10.15171/ajehe.2017.07
M. Keikha
Non-tuberculosis mycobacteria (NTM) are saprophytic bacteria in environmental resources such as water and soil. The presence of atypical mycobacteria in hospital resources may lead to infections and the spread of aerosol particles through ventilation systems, wind, and even drinking water. Therefore, control of contamination of environmental resources in hospitals is one of the most important approaches to reduce and manage NTM nosocomial infections. This study reported the isolation of Mycobacterium frederiksbergense from a tap water sample, which is considered important for clinical and biodegradation aspects. The isolated bacterium was identified using phenotypic features and 16S rRNA sequencing. This report verified the necessity to identify the presence of NTM in water and to find a solution for controlling such contaminations.
非结核分枝杆菌(NTM)是水、土壤等环境资源中的腐生细菌。医院资源中非典型分枝杆菌的存在可能导致感染,并通过通风系统、风甚至饮用水传播气溶胶颗粒。因此,控制医院环境资源污染是减少和管理NTM医院感染的重要途径之一。本研究报道了从自来水样品中分离出弗雷德里克斯伯根分枝杆菌,这被认为对临床和生物降解方面很重要。使用表型特征和16S rRNA测序鉴定分离的细菌。本报告验证了确定水中NTM存在的必要性,并找到控制此类污染的解决方案。
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引用次数: 1
Application of Poisson Hidden Markov Model to Predict Number of PM2.5 Exceedance Days in Tehran During 2016-2017 泊松隐马尔可夫模型在2016-2017年德黑兰PM2.5超标天数预测中的应用
Q4 Environmental Science Pub Date : 2017-12-27 DOI: 10.5812/AJEHE.58031
F. Sarvi, A. Nadali, M. Khodadost, Melika Kharghani Moghaddam, M. Sadeghifar
PM2.5 is an important indicator of air pollution. This pollutant can result in lung and respiratory problems in people. The aim of the present study was to predict number of PM2.5 exceedance days using Hidden Markov Model considering Poisson distribution as an indicator for people susceptible to that particular level of air quality. In this study, evaluations were made for number of PM2.5 exceedance days in Tehran, Iran, from Oct. 2010 to Dec. 2015. The Poisson hidden Markov model was applied considering various hidden states to make a two-year forecast for number of PM2.5 exceedance days.We estimated the Poisson Hidden Markov’s parameters (transition matrix, probability, and lambda) by using maximum likelihood method. By applying the Akaike Information Criteria, the hidden Markov model with three states was used to make the prediction. The results of forecasting mean, median, mode, and interval for the three states of Poisson hidden Markov model are reported. The results showed that the number of exceedance days in a month for the next two years using the third state of the model would be 5 to 16 days. The predicted mode and mean for the third months afterward at the third state were 11 and 11. These predictions showed that number of exceedance days (predicted mean of 6.87 to 11.39 days) is relatively high for sensitive individuals according to the PM2.5 Air Quality Index. Thus, it is essential to monitor levels of suspended particulate air pollution in Tehran.
PM2.5是空气污染的重要指标。这种污染物会导致人的肺部和呼吸系统问题。本研究的目的是使用隐马尔可夫模型预测PM2.5超标天数,该模型将泊松分布作为易受特定空气质量水平影响的人群的指标。在这项研究中,对2010年10月至2015年12月伊朗德黑兰PM2.5超标天数进行了评估。应用泊松隐马尔可夫模型,考虑不同的隐态,对PM2.5超标天数进行两年预测。我们使用最大似然法估计了泊松隐马尔可夫参数(转移矩阵、概率和lambda)。应用Akaike信息准则,采用三态隐马尔可夫模型进行预测。报道了泊松隐马尔可夫模型三种状态的均值、中值、模和区间的预测结果。结果表明,使用该模型的第三种状态,未来两年一个月的超标天数将为5至16天。在第三种状态下,第三个月的预测模式和平均值分别为11和11。这些预测表明,根据PM2.5空气质量指数,敏感个体的超标天数(预测平均值为6.87至11.39天)相对较高。因此,监测德黑兰的悬浮颗粒物空气污染水平至关重要。
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引用次数: 4
Preparation of Magnetic Multi-Walled Carbon Nanotubes to Adsorb Sodium Dodecyl Sulfate (SDS) 磁性多壁碳纳米管吸附十二烷基硫酸钠的制备
Q4 Environmental Science Pub Date : 2017-12-27 DOI: 10.5812/AJEHE.61902
Z. Rahmani, M. Samadi
Surfactants are one of the main groups of pollutants released into aqueous solutions due to human activities and their harmful effects have been proven on human. In this study, first, magnetic multi-walled carbon nanotubes (MMWCNTs) were synthesized and then, the effects of operating parameters such as surfactant concentration, adsorbent dosage, and pH values were analyzed on the adsorption process. MMWCNTs were characterized by means of X-ray diffraction (XRD) analysis and fourier transform infrared spectroscopy (FTIR). The optimal adsorption conditions were achieved at initial pH = 4.6, adsorbent concentration = 0.5 g/L, and initial SDS concentration = 15 mg/L. In addition, the equilibrium of sorption reached after 120 min and the maximum capacity of SDS for monolayer coverage was found to be 61 mg/g at 25°C. Kinetic studies were performed under optimal conditions and the sorption kinetics was described using the pseudo-second-order kinetic model. The experimental data were studied using Freundlich, Langmuir, and Sips models. Finally, the experimental data were fitted reasonably by Langmuir isotherm. The results demonstrated that MMWCNTs with respect to their high adsorption capacity, relatively low equilibrium time, and capability to be separated from aqueous solutions (after adsorption) could be applied to wastewater treatment.
表面活性剂是人类活动释放到水溶液中的主要污染物之一,其对人体的危害已被证实。本研究首先合成了磁性多壁碳纳米管(MMWCNTs),然后分析了表面活性剂浓度、吸附剂用量、pH值等操作参数对其吸附过程的影响。采用x射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对MMWCNTs进行了表征。最佳吸附条件为初始pH = 4.6,吸附剂浓度= 0.5 g/L, SDS初始浓度= 15 mg/L。此外,在25℃下,120 min后达到吸附平衡,SDS覆盖单层的最大容量为61 mg/g。在最佳条件下进行了动力学研究,并采用拟二级动力学模型描述了吸附动力学。实验数据采用Freundlich、Langmuir和Sips模型进行研究。最后,用Langmuir等温线对实验数据进行了合理拟合。结果表明,MMWCNTs具有高吸附容量、相对较短的平衡时间和吸附后可从水溶液中分离的能力,可应用于废水处理。
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引用次数: 6
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Avicenna Journal of Environmental Health Engineering
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