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Sustainable Concrete with Zero Carbon Footprint 零碳足迹的可持续混凝土
Pub Date : 2024-08-09 DOI: 10.21926/rpm.2403019
Ahmed Alawais, Roger P West
This paper describes a method to use solely recycled and by-product materials as constituents to form concrete that can be used in buildings structural applications. As concrete is one of the most important materials in human civilization, where it is used widely in construction, cement and aggregate the main components of concrete cause an emission of large amounts of carbon dioxide, which is the main cause of global warming. The production of one tonne of cement, for example, causes the emission of about 800 kg of this CO2. The growing demand for concrete constitutes a threat to the environment and its resources into the future. According to a market study by The Freedonia Group, in 2019 the world demand for cement was 5.1 billion tonnes which means that more than 2.5 billion tonnes of water and more than 11 billion tonnes of aggregates, both of which are scarce resources, will also be consumed. The goal of this Paper is to describe a 100% substitution of concretes normal constituents to form a sustainable concrete with zero carbon footprint and without compromising concrete mechanical properties. This will demand a pre-treatment of the recycled and by-products components to compensate for the natural strength loss due to their inclusion. Therefore, an innovative novel treatment method is selected for recycled concrete aggregates and chipped rubber to be separately treated and tested to mitigate the loss of strength in proposing a novel recycled activator for GGBS and silica fume. Then these waste recyclable materials are combined in a concrete mix that is 100% recycled and, therefore, significantly more sustainable.
本文介绍了一种完全使用回收材料和副产品材料作为成分,形成可用于建筑结构应用的混凝土的方法。混凝土是人类文明中最重要的材料之一,被广泛应用于建筑领域,但混凝土的主要成分水泥和骨料会排放大量二氧化碳,而二氧化碳是导致全球变暖的主要原因。例如,生产一吨水泥会排放大约 800 千克二氧化碳。混凝土需求的不断增长对未来的环境和资源构成了威胁。根据 Freedonia 集团的市场研究,2019 年全球水泥需求量为 51 亿吨,这意味着还将消耗超过 25 亿吨的水和超过 110 亿吨的骨料,而这两种资源都是稀缺资源。本文的目标是介绍如何在不影响混凝土机械性能的前提下,100% 地替代混凝土中的普通成分,以形成零碳足迹的可持续混凝土。这就需要对回收成分和副产品成分进行预处理,以弥补因加入这些成分而造成的天然强度损失。因此,我们选择了一种创新的处理方法,对回收的混凝土骨料和碎橡胶进行单独处理和测试,以减少强度损失,并提出了一种新型的 GGBS 和硅灰回收活化剂。然后将这些废弃的可回收材料组合在一起,制成 100% 可回收的混凝土混合物,从而大大提高了可持续性。
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引用次数: 0
Construction and Evaluation of a Modular Anthropomorphic Phantom of the Skull with an Exchangeable Specimen Jar to Optimize the Radiological Examination of Temporal Bone Pathology 构建和评估带有可更换标本罐的模块化颅骨拟人模型,优化颞骨病理学放射学检查
Pub Date : 2024-07-25 DOI: 10.21926/rpm.2403018
Malin Vestin Fredriksson, L. Kull, Anton Rönnblom, Lennart Flygare, Diana Berggren, Krister Tano
To develop a modular anthropomorphic phantom to evaluate the performance of radiological techniques for detecting pathologies in the temporal bone region. A phantom was constructed using a human skull, temporal bone specimen, and 3D-printed contour of a human skull. The human skull was embedded in tissue-equivalent plastic, with a cavity to hold the plastic jars containing the exchangeable freshly frozen human temporal bones. Subsequently, stepwise introduction and examination of different clinicopathological scenarios were conducted. Radiological images were nearly identical to those acquired from patients using computed tomography (CT) and cone beam computed tomography (CBCT). The radiological attenuation of polyurethane plastic (PUR) and alginate were similar to those of the soft tissues of living human patients. The mean Hounsfield unit values of the CT slices representing tissue at the brain and temporal bone level were 184 and 171 in the phantom and patient groups, respectively. The modular phantom developed in this study can evaluate radiological techniques and diagnostic possibilities without exposing patients to radiation. To our knowledge, no such modular phantom has been reported in the literature or made available commercially.
开发一种模块化拟人模型,用于评估放射学技术检测颞骨区域病变的性能。使用人类头骨、颞骨标本和 3D 打印的人类头骨轮廓构建了一个模型。人体头骨被嵌入组织等效塑料中,塑料瓶中装有可交换的新鲜冷冻人体颞骨。随后,逐步引入并检查了不同的临床病理情况。放射图像与使用计算机断层扫描(CT)和锥形束计算机断层扫描(CBCT)从患者身上获取的图像几乎完全相同。聚氨酯塑料(PUR)和藻酸盐的放射衰减与活人软组织的衰减相似。在模型组和患者组中,代表大脑和颞骨水平组织的 CT 切片的平均 Hounsfield 单位值分别为 184 和 171。这项研究开发的模块化模型可以在不对患者造成辐射的情况下评估放射技术和诊断的可能性。据我们所知,目前还没有此类模块化人体模型的文献报道或商业销售。
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引用次数: 0
Impact of Pernicious Chemicals on Geopolymer and Alkali-Activated Composites Incorporated with Different Fiber Types: A Review 有害化学品对含有不同纤维类型的土工聚合物和碱活性复合材料的影响:综述
Pub Date : 2024-07-22 DOI: 10.21926/rpm.2403017
Khatib Zada Farhan, A. Shihata, Adams Balade Abubakar
Over the past decade, developing geopolymer mixes to replace ordinary Portland Cement (OPC) composites has yielded positive results, leading to extensive research. The incorporation of fibers in geopolymers, besides impacting the mechanical properties, has also significantly impacted durability, mainly when dealing with the most pernicious forms of deterioration resulting from chloride attack, water penetration, sulfate attack, acid attack, as well as freeze-thaw, which occurred through chemical transgression. This study presents a systematic approach to thoroughly review the durability properties of fibrous geopolymer composites exposed to harmful chemicals and extreme environmental conditions. The multi-parameters and factors critically influencing fibrous geopolymers' physical and chemical stability are examined. The study is further aimed at providing an update on the research work undertaken to assess the impact of fiber incorporation on the durability of geopolymer and alkali-activated composites thus far. Furthermore, this review hopes to promote and facilitate research on durability for the long-term, large-scale adoption, and commercialization of advanced fibrous, non-OPC-based materials.
在过去十年中,开发土工聚合物混合物以取代普通硅酸盐水泥(OPC)复合材料的工作取得了积极成果,并引发了广泛的研究。在土工聚合物中加入纤维除了会影响其机械性能外,还会对耐久性产生重大影响,主要是在应对氯化物侵蚀、水渗透、硫酸盐侵蚀、酸侵蚀以及通过化学侵蚀产生的冻融等最有害的老化形式时。本研究采用系统的方法,对暴露在有害化学物质和极端环境条件下的纤维状土工聚合物复合材料的耐久性能进行了深入研究。研究探讨了影响纤维状土工聚合物物理和化学稳定性的多种参数和关键因素。本研究还旨在提供迄今为止为评估纤维掺入对土工聚合物和碱活性复合材料耐久性的影响而开展的研究工作的最新进展。此外,本综述还希望推动和促进有关耐久性的研究,以便长期、大规模地采用先进的非 OPC 纤维材料,并将其商业化。
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引用次数: 0
Spark Plasma Sintering of Cu-Ti-Ni Ternary Alloy: Microstructural, Thermal and Electrical Properties 铜钛镍三元合金的火花等离子烧结:微结构、热性能和电性能
Pub Date : 2024-07-01 DOI: 10.21926/rpm.2403016
A. O. Oyatogun, E. Ajenifuja, A. Popoola, Olawale Popoola, F. Aramide, G. M. Oyatogun
High strength and good conductivity are both critical parameters for copper-based alloys for electrical and other technological applications. This study is aimed to produce copper alloys and metal matrix composites (MMCs) with enhanced physical properties. Cu-Ti-Ni ternary alloys and MMCs samples were sintered at 600 to 700°C using spark plasma sintering (SPS), with a heating rate of 100°C/minutes, uniaxial pressure of 50 MPa, and a holding time of 10 minutes. Scanning electron microscopy (FE-SEM) was used to examine the microstructure, while the relative densities of the composites were obtained via the Archimedes Principle method. A four-point probe and differential thermal analyzer (DTA) obtained electrical resistivity and thermal properties. The results indicated that the sample density nominally increases with sintering temperature but decreases with aluminium nitride additions. The electrical conductivity increases with the sintering temperature and AlN nanoparticle content. Distinct phase changes were observed from the DTA, occurring with the addition of AlN.
高强度和良好的导电性是铜基合金在电气和其他技术应用中的关键参数。本研究旨在生产物理性能更强的铜合金和金属基复合材料(MMC)。铜-钛-镍三元合金和金属基复合材料样品在 600 至 700°C 温度下采用火花等离子烧结(SPS)技术烧结,加热速度为 100°C/分钟,单轴压力为 50 兆帕,保温时间为 10 分钟。使用扫描电子显微镜(FE-SEM)检查微观结构,并通过阿基米德原理法获得复合材料的相对密度。四点探针和差热分析仪(DTA)获得了电阻率和热性能。结果表明,样品密度随着烧结温度的升高而增大,但随着氮化铝的添加而减小。电导率随烧结温度和氮化铝纳米粒子含量的增加而增加。从 DTA 中观察到,随着氮化铝的添加,样品发生了明显的相变。
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引用次数: 0
Spin Entanglement – A Unifying Principle for Superconductors and Molecular Bonding 自旋纠缠--超导体和分子结合的统一原理
Pub Date : 2024-06-03 DOI: 10.21926/rpm.2402012
Paul O'Hara
The spin-statistics theorem is generalized to include quantum entanglement. Specifically, within the context of spin entanglement, we prove that isotropically spin-correlated (ISC) states must occur in pairs. This pairing process can be composed of parallel or anti-parallel states. Consequently, the article proposes using ISC states as a unifying principle to explain better Bose-Einstein condensates, the theory of superconductivity, and molecular and atomic orbitals, all of which involve a pairing process. The theoretical framework is established in sections 1 and 2. The other qualitative sections focus primarily on the experimental evidence to support the theory.KeywordsEntanglement and spin-statistics; unifying principle; condensates; superconductors; molecular bonds
自旋统计定理被推广到量子纠缠中。具体来说,在自旋纠缠的背景下,我们证明了同向自旋相关(ISC)态必须成对出现。这种配对过程可以由平行态或反平行态组成。因此,文章提出用 ISC 状态作为统一原理,以更好地解释玻色-爱因斯坦凝聚态、超导理论以及分子和原子轨道,所有这些都涉及配对过程。第 1 节和第 2 节建立了理论框架。关键词 量子和自旋统计;统一原理;凝聚态;超导体;分子键
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引用次数: 0
Enhancing Thermal, Viscoelastic, and Mechanical Properties of Silicone Rubber Matrix through Reinforcements for Use as a Medical Implant 通过增强材料提高硅橡胶基质的热性能、粘弹性能和机械性能,以用作医用植入物
Pub Date : 2024-05-03 DOI: 10.21926/rpm.2402011
Kianoush Hatami Dehnou, M. J. Hadianfard
The use of silicone rubber as an implant is limited due to its weak properties. In this study, the impact of various reinforcements, such as TiO2 or SiO2 nanoparticles, carbon, or polypropylene fiber micro reinforcements, on the mechanical, thermal, and viscoelastic properties of silicone rubber composites with RTV-4125 matrix was investigated. The composites were evaluated through several tests, including tensile, compression, FTIR, TGA, DMTA, and water adsorption tests. It was found that the composites' tensile strength and compressive stress were increased by adding reinforcements, with the most significant impact on tensile strength observed for SiO2 and the most notable effect on compressive stress at a strain of 0.5 observed for polypropylene fiber. Moreover, the water absorption of the matrix was increased with the addition of reinforcements, with the highest increase observed for Titania nanoparticles. TGA analysis showed that all composites had higher thermal stability than the plain matrix, with the highest degradation temperature observed for the SR-C fiber composite and the highest degradation rate observed for SR-TiO2. Additionally, DMTA analysis revealed that TiO2 nanoparticles considerably decreased the glass transition temperature of the matrix (%28.5), while the other reinforcements had a negligible effect on this temperature. The introduction of reinforcements had a positive impact on the mechanical, thermal, and viscoelastic properties of silicone rubber composites, and the findings of this study can contribute to the development of new and improved silicone rubber composites for implant applications.
由于硅橡胶的性能较弱,其作为植入物的使用受到了限制。在本研究中,研究了各种增强材料(如 TiO2 或 SiO2 纳米粒子、碳或聚丙烯纤维微增强材料)对硅橡胶与 RTV-4125 基质复合材料的机械、热和粘弹性能的影响。通过拉伸、压缩、傅立叶变换红外光谱、热重分析、DMTA 和吸水测试等多项测试对复合材料进行了评估。结果发现,添加增强材料后,复合材料的拉伸强度和压缩应力都有所提高,其中二氧化硅对拉伸强度的影响最为显著,而聚丙烯纤维对 0.5 应变时压缩应力的影响最为明显。此外,基体的吸水性也随着增强材料的添加而增加,钛纳米粒子的吸水性增幅最大。TGA 分析表明,所有复合材料的热稳定性都高于普通基体,SR-C 纤维复合材料的降解温度最高,SR-TiO2 的降解率最高。此外,DMTA 分析表明,TiO2 纳米粒子大大降低了基体的玻璃化转变温度(%28.5),而其他增强材料对这一温度的影响微乎其微。添加增强剂对硅橡胶复合材料的机械性能、热性能和粘弹性能都有积极的影响,这项研究的结果有助于开发新的和改进的植入应用硅橡胶复合材料。
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引用次数: 0
Whisker Bond: From Findings to Concept in Refractories 晶须结合:从耐火材料的发现到概念
Pub Date : 2024-04-12 DOI: 10.21926/rpm.2402010
Zongqi Guo, Wenxu Wei
Ceramic bonds are conventionally formed during the burning of refractory bricks and by using pre-fabricated blocks or monolithic lining, which is characterized as the coalescence of the particles by liquid sintering. However, the whisker bond was discovered with the outstanding performance of unburnt periclase–spinel–Al bricks while substituting magnesia–chrome bricks in the chromium-free campaign of refractory lining of RH degassers. Thanks to the prominent effect of the whisker bond, such a refractory material demonstrates ultrahigh hot strength, high resistance to slag penetration, and thermomechanical stress. Investigations reveal the initial melting of metal Al at the melting point of 660°C, aluminum liquid rims around the cavities formed before ~800°C, gaseous AlN yielded and distributed throughout the matrix with increasing temperature, gaseous Mg reduced from ~1000°C, and MgAlON whiskers eventually formed in the matrix. Microstructure observations show a dense interwoven whiskers bonded matrix in most residual parts of the used periclase–spinel–Al bricks. The whisker network in the matrix is made up of straight columns of 1–5 µm in diameter and 20–40 µm in length, which is different from birdnesting, nano-size curly whiskers observed in the past. The findings suggest a whisker-bond concept in terms of the bond mode of the whisker network and the process of the vapor-solid forming mechanism.
陶瓷结合剂通常是在耐火砖烧制过程中形成的,也可通过使用预制块或整体衬里形成,其特点是通过液体烧结使颗粒凝聚在一起。然而,在替代镁铬砖用于 RH 脱气机耐火衬的无铬活动中,人们发现晶须粘结剂在未烧成的过磷酸酶-尖晶石-铝砖中表现出色。得益于晶须结合的显著效果,这种耐火材料表现出超高的热强度、高抗渣渗透性和热机械应力。研究表明,金属铝在熔点 660°C 时开始熔化,在约 800°C 前在空腔周围形成铝液边缘,气态 AlN 随温度升高产生并分布在整个基体中,气态 Mg 从约 1000°C 开始减少,最终在基体中形成 MgAlON 晶须。显微结构观察结果表明,在使用过的过氧化物酶-尖晶石-铝砖的大部分残余部分中,基体中存在密集交织的晶须粘结。基体中的晶须网络由直径为 1-5 微米、长度为 20-40 微米的直柱组成,这与过去观察到的鸟巢式纳米级卷曲晶须不同。研究结果从晶须网络的结合模式和气固形成机制过程的角度提出了晶须结合概念。
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引用次数: 0
Review on the Development of Titanium Diboride Ceramics 二硼化钛陶瓷发展综述
Pub Date : 2024-04-03 DOI: 10.21926/rpm.2402009
Xinran Lv, Ziqiang Yin, Zhigang Yang, Junshuai Chen, Shen Zhang, Shaolei Song, Gang Yu
Titanium diboride (TiB2) materials have garnered significant attention due to their remarkable comprehensive properties. They offer potential applications in high-temperature structural materials, cutting tools, armor, electrodes for metal smelting, and wear-resistant parts. However, due to the low self-diffusion coefficient, the TiB2 exhibits poor sinterability, excessive grain growth at elevated temperatures, and inadequate oxidation resistance, limiting its wide application. Therefore, many research works are devoted to processing TiB2 at a lower sintering temperature and improving the properties through various sintering additives and more advanced techniques. This article comprehensively reviews the multiple synthesis methods and sintering technologies of TiB2, and at the same time, critically discusses the impacts of sintering additives and reinforcing agents on densification, microstructure, and various properties, including those at high temperatures, and finally predicts the future development of TiB2 composite materials.
二硼化钛(TiB2)材料因其显著的综合性能而备受关注。它们在高温结构材料、切削工具、装甲、金属冶炼电极和耐磨部件方面具有潜在的应用价值。然而,由于自扩散系数较低,TiB2 的烧结性较差,在高温下晶粒过度生长,抗氧化性不足,限制了其广泛应用。因此,许多研究工作致力于在较低的烧结温度下加工 TiB2,并通过各种烧结添加剂和更先进的技术改善其性能。本文全面回顾了 TiB2 的多种合成方法和烧结技术,同时批判性地讨论了烧结添加剂和增强剂对致密化、微观结构和各种性能(包括高温性能)的影响,最后预测了 TiB2 复合材料的未来发展。
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引用次数: 0
A Review on Silk Fibers and Their Medical Applications 丝纤维及其医疗应用综述
Pub Date : 2024-03-15 DOI: 10.21926/rpm.2401008
Alhayat Getu Temesgen, Ömer Fırat Turşucular, Elif Dicle Turşucular
This mini-compilation study included the chemical structure, mechanical, thermal, and dimensional properties of silk fiber, its production process, pre-treatment, and biomedical applications from various experimental studies, which are compiled and summarized. The silk fiber should have a degumming process before using biomedical applications. The 25% concentration for Na2CO3 in ethanol solution (80%) as a coagulant chemical with a salt such as LiB2 (9 M) at a temperature of 98°C for 45 minutes at pH between 6 and 7 should be applied for the degumming process of silk fiber. It has some biomedical applications such as artificial veins and surgical sutures. Its biomedical applications can be studied experimentally by changing manufacturing processes and their process parameters in the future.
这项微型汇编研究包括蚕丝纤维的化学结构、机械、热和尺寸特性,其生产工艺、预处理和生物医学应用,这些内容来自各种实验研究,现将其进行汇编和总结。蚕丝纤维在生物医学应用前应进行脱胶处理。在丝纤维的脱胶过程中,应使用浓度为 25% 的 Na2CO3 在乙醇溶液(80%)中作为凝结剂,并加入 LiB2 等盐(9 M),温度为 98°C,时间为 45 分钟,pH 值为 6 至 7。蚕丝具有一些生物医学用途,如人造静脉和手术缝合线。今后可通过改变制造工艺及其工艺参数对其生物医学应用进行实验研究。
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引用次数: 0
Capillary Suction Properties of Mortar Made with Recycled Plastic Aggregates Elaborated from Waste Electrical and Electronic Equipment 用废旧电子电气设备制成的再生塑料骨料制作的砂浆的毛细管吸力特性
Pub Date : 2024-03-15 DOI: 10.21926/rpm.2401007
Jerónimo Kreiker, Melina Gómez, L. Peisino, Nelio Ochoa, Belén Raggiotti
It is possible to revalue the plastic fraction from WEEE using it as a recycled aggregate (RA) in cement mortars. However, this feasibility depends on elaborating a granular material via a core-shell strategy to stabilize the potential contaminants. The core is a plastic particle, and the shell is a cement, fillers, and activated carbon mixture. Due to the hydrophilic characteristics of the shell and the presence of interstitial sites generated by the use of the RA, it is necessary to study the wetting properties of these mortars. This article presents the results of capillary suction and contact angle studies of mortars made with RA having different shell compositions. The capillary suction of the latter is higher than in traditional mortars, which limits their use for structures exposed to water and environmental agents but opens the possibility of new uses in permeable concrete or for the manufacture of building components.
将废旧电子电气设备中的塑料部分作为水泥砂浆中的再生骨料(RA)进行再利用是可行的。不过,这种可行性取决于通过核心-外壳策略来制作颗粒材料,以稳定潜在的污染物。芯是塑料颗粒,壳是水泥、填料和活性炭混合物。由于外壳具有亲水性,而且使用活性炭会产生间隙,因此有必要对这些灰泥的润湿性能进行研究。本文介绍了对使用不同外壳成分的 RA 制成的灰泥进行毛细管吸力和接触角研究的结果。后者的毛细管吸力高于传统灰泥,这限制了它们在暴露于水和环境介质的结构中的使用,但为其在透水混凝土或建筑部件制造中的新用途提供了可能性。
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引用次数: 0
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Recent progress in materials
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