Pub Date : 2023-11-16DOI: 10.1007/s42773-023-00276-0
Zhiyuan Liu, Yan Li, Zhiyuan He
Icing of wind turbine blades will seriously hinder the development of the wind power industry, and the use of biomass resources to solve the icing problem is conducive to promoting the synergistic development of biomass and wind energy. In this study, ice-phobic coatings with photothermal and anti-corrosion properties were prepared by surface modification pyrolysis and hydrothermal reaction with rice straw biogas residue as raw material. The erosion of KOH and the surface modification of MoS2 produced a rough structure of the material, and the high-temperature pyrolysis and hydrothermal reaction promoted the dehydrogenation and decarboxylation reactions, which reduced the number of oxygen-containing functional groups and decreased the surface energy of the material. The ice-phobic coating has superhydrophobic properties with a contact angle of 158.32°. Due to the small surface area in contact with water, the coating was able to significantly reduce the icing adhesion strength to 53.23 kPa. The icing wind tunnel test results showed that the icing area and mass were reduced by 10.54% and 30.08%, respectively, when the wind speed was 10 m s−1 and the temperature was − 10 °C. Photothermal performance tests showed that the MoS2-loaded material had light absorption properties, and the coating could rapidly warm up to 58.3 ℃ under xenon lamp irradiation with photothermal cycle stability. The loading of MoS2 acts as a physical barrier, reducing the contact of corrosive media with the substrate, thus improving the anti-corrosion of the coating. This study has practical application value and significance for the development of the anti-icing field under complex environmental conditions.
Graphical Abstract
风力涡轮机叶片结冰将严重阻碍风电产业的发展,而利用生物质能资源解决结冰问题有利于促进生物质能与风能的协同发展。本研究以稻秆沼气渣为原料,通过表面改性热解和水热反应制备了具有光热和防腐性能的疏冰涂层。KOH的侵蚀和MoS2的表面改性使材料结构粗糙,高温热解和水热反应促进了脱氢和脱羧反应,减少了含氧官能团的数量,降低了材料的表面能。疏冰涂层具有超疏水性能,接触角为158.32°。由于涂层与水的接触面积较小,因此涂层能够显著降低结冰粘附强度至53.23 kPa。结冰风洞试验结果表明,风速为10 m s−1,温度为−10℃时,结冰面积和质量分别减小10.54%和30.08%。光热性能测试表明,负载mos2的材料具有良好的光吸收性能,涂层在氙灯照射下可快速升温至58.3℃,具有光热循环稳定性。二硫化钼的加载起到了物理屏障的作用,减少了腐蚀介质与基材的接触,从而提高了涂层的抗腐蚀能力。该研究对复杂环境条件下防冰领域的发展具有实际应用价值和意义。图形抽象
{"title":"Ice-phobic properties of MoS2-loaded rice straw biogas residue biochar-based photothermal and anti-corrosion coating with low oxygen to carbon ratio","authors":"Zhiyuan Liu, Yan Li, Zhiyuan He","doi":"10.1007/s42773-023-00276-0","DOIUrl":"https://doi.org/10.1007/s42773-023-00276-0","url":null,"abstract":"<p>Icing of wind turbine blades will seriously hinder the development of the wind power industry, and the use of biomass resources to solve the icing problem is conducive to promoting the synergistic development of biomass and wind energy. In this study, ice-phobic coatings with photothermal and anti-corrosion properties were prepared by surface modification pyrolysis and hydrothermal reaction with rice straw biogas residue as raw material. The erosion of KOH and the surface modification of MoS<sub>2</sub> produced a rough structure of the material, and the high-temperature pyrolysis and hydrothermal reaction promoted the dehydrogenation and decarboxylation reactions, which reduced the number of oxygen-containing functional groups and decreased the surface energy of the material. The ice-phobic coating has superhydrophobic properties with a contact angle of 158.32°. Due to the small surface area in contact with water, the coating was able to significantly reduce the icing adhesion strength to 53.23 kPa. The icing wind tunnel test results showed that the icing area and mass were reduced by 10.54% and 30.08%, respectively, when the wind speed was 10 m s<sup>−1</sup> and the temperature was − 10 °C. Photothermal performance tests showed that the MoS<sub>2</sub>-loaded material had light absorption properties, and the coating could rapidly warm up to 58.3 ℃ under xenon lamp irradiation with photothermal cycle stability. The loading of MoS<sub>2</sub> acts as a physical barrier, reducing the contact of corrosive media with the substrate, thus improving the anti-corrosion of the coating. This study has practical application value and significance for the development of the anti-icing field under complex environmental conditions.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"76 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138516789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Applying biochar amendment and manure in tea plantation ecosystems can diminish soil acidification and degradation. However, the impact of these practices on soil respiration and associated mechanisms remains unclear. In this study, we combined a two-year field experiment and laboratory analyses based on soil properties, functional genes, and microbial co-occurrence networks to explore the determinants of soil respiration intensity in a subtropical tea plantation with biochar amendment and manure application. The results showed that the effect of biochar amendment on soil respiration was unconspicuous. Although biochar amendment increased bacterial richness and Shannon index, biochar amendment did not alter the abundance of species associated with C-cycling functional genes. Besides directly adding recalcitrant C to the soil, biochar also indirectly enhanced C sequestration by weakly increasing soil carbon dioxide (CO 2 ) emissions. However, replacing mineral fertilizer with manure significantly stimulated soil respiration in the tea plantation, resulting in a 36% increase in CO 2 emissions over two years. The increase in CO 2 emissions under the manure treatment was mainly attributed to the increased soil labile C pool, the activity of hydrolytic enzymes (e.g., cellobiohydrolase and acetylglucosaminidase), and the relative abundance of functional genes associated with the C-cycle. This may also be related to the application of manure that increased the abundance of Gemmatimonadetes and altered ecological clusters in bacterial co-occurrence networks. Our correlation network analysis suggested that Gemmatimonadetes might be the potential hosts for C-cycling genes due to their strong positive correlation with the abundance of C-cycling genes. Overall, these findings provide new insights into soil respiration under biochar amendment and manure application in tea plantations and broaden the options for carbon sequestration in soils. Graphical Abstract
{"title":"Divergent effects of biochar amendment and replacing mineral fertilizer with manure on soil respiration in a subtropical tea plantation","authors":"Zhaoqiang Han, Pinshang Xu, Zhutao Li, Shumin Guo, Shuqing Li, Shuwei Liu, Shuang Wu, Jinyang Wang, Jianwen Zou","doi":"10.1007/s42773-023-00273-3","DOIUrl":"https://doi.org/10.1007/s42773-023-00273-3","url":null,"abstract":"Abstract Applying biochar amendment and manure in tea plantation ecosystems can diminish soil acidification and degradation. However, the impact of these practices on soil respiration and associated mechanisms remains unclear. In this study, we combined a two-year field experiment and laboratory analyses based on soil properties, functional genes, and microbial co-occurrence networks to explore the determinants of soil respiration intensity in a subtropical tea plantation with biochar amendment and manure application. The results showed that the effect of biochar amendment on soil respiration was unconspicuous. Although biochar amendment increased bacterial richness and Shannon index, biochar amendment did not alter the abundance of species associated with C-cycling functional genes. Besides directly adding recalcitrant C to the soil, biochar also indirectly enhanced C sequestration by weakly increasing soil carbon dioxide (CO 2 ) emissions. However, replacing mineral fertilizer with manure significantly stimulated soil respiration in the tea plantation, resulting in a 36% increase in CO 2 emissions over two years. The increase in CO 2 emissions under the manure treatment was mainly attributed to the increased soil labile C pool, the activity of hydrolytic enzymes (e.g., cellobiohydrolase and acetylglucosaminidase), and the relative abundance of functional genes associated with the C-cycle. This may also be related to the application of manure that increased the abundance of Gemmatimonadetes and altered ecological clusters in bacterial co-occurrence networks. Our correlation network analysis suggested that Gemmatimonadetes might be the potential hosts for C-cycling genes due to their strong positive correlation with the abundance of C-cycling genes. Overall, these findings provide new insights into soil respiration under biochar amendment and manure application in tea plantations and broaden the options for carbon sequestration in soils. Graphical Abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"51 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136346563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-09DOI: 10.1007/s42773-023-00271-5
Lina Luo, Daniel S. Cohan, Caroline A. Masiello, Taras E. Lychuk, Xiaodong Gao
Abstract Fertilizer-intensive agriculture is a leading source of reactive nitrogen (Nr) emissions that damage climate, air quality, and human health. Biochar has long been studied as a soil amendment, but its influence on Nr emissions remains insufficiently characterized. More recently, the pyrolysis of light hydrocarbons has been suggested as a source of hydrogen fuel, resulting in a solid zero-valent carbon (ZVC) byproduct whose impact on soil emissions has yet to be tested. We incorporate carbon amendment algorithms into an agroecosystem model to simulate emission changes in the year following the application of biochar or ZVC to the US. fertilized soils. Our simulations predicted that the impacts of biochar amendments on Nr emissions would vary widely (− 17% to + 27% under 5 ton ha −1 applications, − 38% to + 18% under 20 ton ha −1 applications) and depend mostly on how nitrification is affected. Low-dose biochar application (5 ton ha −1 ) stimulated emissions of all three nitrogen species in 75% of simulated agricultural areas, while high-dose applications (20 ton ha −1 ) mitigated emissions in 76% of simulated areas. Applying zero-valent carbon at 20 ton ha −1 exhibited similar effects on nitrogen emissions as biochar applications at 5 ton ha −1 . Biochar amendments are most likely to mitigate emissions if applied at high rates in acidic soils (pH < 5.84) with low organic carbon (< 55.9 kg C ha −1 ) and inorganic nitrogen (< 101.5 kg N ha −1 ) content. Our simulations could inform where the application of carbon amendments would most likely mitigate Nr emissions and their associated adverse impacts. Graphical Abstract
肥料密集型农业是活性氮(Nr)排放的主要来源,会损害气候、空气质量和人类健康。生物炭作为土壤改良剂研究已久,但其对Nr排放的影响尚未充分表征。最近,轻烃的热解被认为是氢燃料的一种来源,产生固体零价碳(ZVC)副产品,其对土壤排放的影响尚未得到测试。我们将碳修正算法纳入农业生态系统模型,以模拟生物炭或ZVC在美国应用后一年的排放变化。受精的土壤。我们的模拟预测,生物炭对Nr排放的影响差异很大(在5吨ha - 1施用下为- 17%至+ 27%,在20吨ha - 1施用下为- 38%至+ 18%),主要取决于硝化作用如何受到影响。低剂量生物炭应用(5吨公顷- 1)在75%的模拟农业区刺激了所有三种氮的排放,而高剂量应用(20吨公顷- 1)减轻了76%的模拟农业区的排放。施用20吨公顷−1的零价碳对氮排放的影响与施用5吨公顷−1的生物炭相似。如果在酸性土壤(pH <5.84)与低有机碳(<55.9 kg cha - 1)和无机氮(<101.5 kg N ha−1)含量。我们的模拟可以告知在哪些地方应用碳修正最有可能减轻Nr排放及其相关的不利影响。图形抽象
{"title":"Agroecosystem modeling of reactive nitrogen emissions from U.S. agricultural soils with carbon amendments","authors":"Lina Luo, Daniel S. Cohan, Caroline A. Masiello, Taras E. Lychuk, Xiaodong Gao","doi":"10.1007/s42773-023-00271-5","DOIUrl":"https://doi.org/10.1007/s42773-023-00271-5","url":null,"abstract":"Abstract Fertilizer-intensive agriculture is a leading source of reactive nitrogen (Nr) emissions that damage climate, air quality, and human health. Biochar has long been studied as a soil amendment, but its influence on Nr emissions remains insufficiently characterized. More recently, the pyrolysis of light hydrocarbons has been suggested as a source of hydrogen fuel, resulting in a solid zero-valent carbon (ZVC) byproduct whose impact on soil emissions has yet to be tested. We incorporate carbon amendment algorithms into an agroecosystem model to simulate emission changes in the year following the application of biochar or ZVC to the US. fertilized soils. Our simulations predicted that the impacts of biochar amendments on Nr emissions would vary widely (− 17% to + 27% under 5 ton ha −1 applications, − 38% to + 18% under 20 ton ha −1 applications) and depend mostly on how nitrification is affected. Low-dose biochar application (5 ton ha −1 ) stimulated emissions of all three nitrogen species in 75% of simulated agricultural areas, while high-dose applications (20 ton ha −1 ) mitigated emissions in 76% of simulated areas. Applying zero-valent carbon at 20 ton ha −1 exhibited similar effects on nitrogen emissions as biochar applications at 5 ton ha −1 . Biochar amendments are most likely to mitigate emissions if applied at high rates in acidic soils (pH < 5.84) with low organic carbon (< 55.9 kg C ha −1 ) and inorganic nitrogen (< 101.5 kg N ha −1 ) content. Our simulations could inform where the application of carbon amendments would most likely mitigate Nr emissions and their associated adverse impacts. Graphical Abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":" 8","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135242901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-07DOI: 10.1007/s42773-023-00270-6
Md. Mezanur Rahman, Ashim Kumar Das, Sharmin Sultana, Protik Kumar Ghosh, Md. Robyul Islam, Sanjida Sultana Keya, Minhaz Ahmed, Sheikh Arafat Islam Nihad, Md. Arifur Rahman Khan, Mylea C. Lovell, Md. Abiar Rahman, S. M. Ahsan, Touhidur Rahman Anik, Pallavi Fnu, Lam-Son Phan Tran, Mohammad Golam Mostofa
Abstract Metalloid pollution, including arsenic poisoning, is a serious environmental issue, plaguing plant productivity and quality of life worldwide. Biochar, a carbon-rich material, has been known to alleviate the negative effects of environmental pollutants on plants. However, the specific role of biochar in mitigating arsenic stress in maize remains relatively unexplored. Here, we elucidated the functions of biochar in improving maize growth under the elevated level of sodium arsenate (Na 2 AsO 4 , As V ). Maize plants were grown in pot-soils amended with two doses of biochar (2.5% (B1) and 5.0% (B2) biochar Kg −1 of soil) for 5 days, followed by exposure to Na 2 AsO 4 ('B1 + As V 'and 'B2 + As V ') for 9 days. Maize plants exposed to As V only accumulated substantial amount of arsenic in both roots and leaves, triggering severe phytotoxic effects, including stunted growth, leaf-yellowing, chlorosis, reduced photosynthesis, and nutritional imbalance, when compared with control plants. Contrariwise, biochar addition improved the phenotype and growth of As V -stressed maize plants by reducing root-to-leaf As V translocation (by 46.56 and 57.46% in ‘B1 + As V’ and ‘B2 + As V’ plants), improving gas-exchange attributes, and elevating chlorophylls and mineral levels beyond As V -stressed plants. Biochar pretreatment also substantially counteracted As V -induced oxidative stress by lowering reactive oxygen species accumulation, lipoxygenase activity, malondialdehyde level, and electrolyte leakage. Less oxidative stress in ‘B1 + As V’ and ‘B2 + As V’ plants likely supported by a strong antioxidant system powered by biochar-mediated increased activities of superoxide dismutase (by 25.12 and 46.55%), catalase (51.78 and 82.82%), and glutathione S -transferase (61.48 and 153.83%), and improved flavonoid levels (41.48 and 75.37%, respectively). Furthermore, increased levels of soluble sugars and free amino acids also correlated with improved leaf relative water content, suggesting a better osmotic acclimatization mechanism in biochar-pretreated As V -exposed plants. Overall, our findings provided mechanistic insight into how biochar facilitates maize’s active recovery from As V -stress, implying that biochar application may be a viable technique for mitigating negative effects of arsenic in maize, and perhaps, in other important cereal crops. Graphical Abstract
包括砷中毒在内的类金属污染是一个严重的环境问题,困扰着全世界植物的生产力和生活质量。生物炭是一种富含碳的材料,可以减轻环境污染物对植物的负面影响。然而,生物炭在缓解玉米砷胁迫中的具体作用仍未得到充分研究。本文研究了在砷酸钠(Na 2 AsO 4, As V)浓度升高的条件下,生物炭对玉米生长的促进作用。玉米植株在两种生物炭(2.5% (B1)和5.0% (B2)生物炭Kg - 1土壤)改良的盆栽土壤中生长5 d,然后暴露于Na 2 AsO 4 ('B1 + As V '和'B2 + As V ') 9 d。与对照植株相比,暴露于砷胁迫下的玉米植株只在根系和叶片中积累了大量的砷,引发了严重的植物毒性效应,包括生长发育迟缓、叶片变黄、褪绿、光合作用减弱和营养失衡。相反,添加生物炭通过减少As V胁迫玉米植株的根到叶As V转运(B1 + As V和B2 + As V分别减少46.56%和57.46%),改善气体交换属性,提高叶绿素和矿物质水平,改善了As V胁迫玉米植株的表型和生长。生物炭预处理还通过降低活性氧积累、脂加氧酶活性、丙二醛水平和电解质泄漏,显著抵消As V诱导的氧化应激。“B1 + As V”和“B2 + As V”植株的氧化胁迫减少,可能是由于生物炭提供了强大的抗氧化系统,介导了超氧化物歧化酶(25.12%和46.55%)、过氧化氢酶(51.78%和82.82%)和谷胱甘肽S -转移酶(61.48%和153.83%)活性的提高,以及类黄酮水平的提高(分别为41.48%和75.37%)。此外,可溶性糖和游离氨基酸水平的增加也与叶片相对含水量的提高有关,这表明生物炭预处理的砷暴露植物具有更好的渗透适应机制。总的来说,我们的研究结果为生物炭如何促进玉米从砷胁迫中主动恢复提供了机制上的见解,这意味着生物炭的应用可能是一种减轻砷对玉米的负面影响的可行技术,也许对其他重要的谷类作物也是如此。图形抽象
{"title":"Biochar potentially enhances maize tolerance to arsenic toxicity by improving physiological and biochemical responses to excessive arsenate","authors":"Md. Mezanur Rahman, Ashim Kumar Das, Sharmin Sultana, Protik Kumar Ghosh, Md. Robyul Islam, Sanjida Sultana Keya, Minhaz Ahmed, Sheikh Arafat Islam Nihad, Md. Arifur Rahman Khan, Mylea C. Lovell, Md. Abiar Rahman, S. M. Ahsan, Touhidur Rahman Anik, Pallavi Fnu, Lam-Son Phan Tran, Mohammad Golam Mostofa","doi":"10.1007/s42773-023-00270-6","DOIUrl":"https://doi.org/10.1007/s42773-023-00270-6","url":null,"abstract":"Abstract Metalloid pollution, including arsenic poisoning, is a serious environmental issue, plaguing plant productivity and quality of life worldwide. Biochar, a carbon-rich material, has been known to alleviate the negative effects of environmental pollutants on plants. However, the specific role of biochar in mitigating arsenic stress in maize remains relatively unexplored. Here, we elucidated the functions of biochar in improving maize growth under the elevated level of sodium arsenate (Na 2 AsO 4 , As V ). Maize plants were grown in pot-soils amended with two doses of biochar (2.5% (B1) and 5.0% (B2) biochar Kg −1 of soil) for 5 days, followed by exposure to Na 2 AsO 4 ('B1 + As V 'and 'B2 + As V ') for 9 days. Maize plants exposed to As V only accumulated substantial amount of arsenic in both roots and leaves, triggering severe phytotoxic effects, including stunted growth, leaf-yellowing, chlorosis, reduced photosynthesis, and nutritional imbalance, when compared with control plants. Contrariwise, biochar addition improved the phenotype and growth of As V -stressed maize plants by reducing root-to-leaf As V translocation (by 46.56 and 57.46% in ‘B1 + As V’ and ‘B2 + As V’ plants), improving gas-exchange attributes, and elevating chlorophylls and mineral levels beyond As V -stressed plants. Biochar pretreatment also substantially counteracted As V -induced oxidative stress by lowering reactive oxygen species accumulation, lipoxygenase activity, malondialdehyde level, and electrolyte leakage. Less oxidative stress in ‘B1 + As V’ and ‘B2 + As V’ plants likely supported by a strong antioxidant system powered by biochar-mediated increased activities of superoxide dismutase (by 25.12 and 46.55%), catalase (51.78 and 82.82%), and glutathione S -transferase (61.48 and 153.83%), and improved flavonoid levels (41.48 and 75.37%, respectively). Furthermore, increased levels of soluble sugars and free amino acids also correlated with improved leaf relative water content, suggesting a better osmotic acclimatization mechanism in biochar-pretreated As V -exposed plants. Overall, our findings provided mechanistic insight into how biochar facilitates maize’s active recovery from As V -stress, implying that biochar application may be a viable technique for mitigating negative effects of arsenic in maize, and perhaps, in other important cereal crops. Graphical Abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"49 13","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135432487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.1007/s42773-023-00269-z
Yiting Mao, Bo Cai, Ming Huang, Xiaohuan Liu, Wenbiao Zhang, Zhongqing Ma
Abstract Biochar is a potential porous carbon to remove the contaminants from aquatic environments. Herein, N-doped hierarchical biochar was produced by the combined approach of ammonia torrefaction pretreatment (ATP) and alkali activation. ATP could not only incorporate N element into poplar wood, but obtain the loose structure of poplar wood. The highest surface area of N-doped hierarchical biochar was 2324.61 m 2 g −1 after ammonia wet torrefaction pretreatment, which was higher than that of activation carbon (1401.82 m 2 g −1 ) without torrefaction pretreatment, the hierarchical biochar (2111.03 m 2 g −1 ) without ammonia atmosphere. The N-doped hierarchical biochar presented the highest adsorption capacity (564.7 mg g −1 ) of methyl orange (MO), which was 14.64-fold of that on biochar without N doping. In addition, the pseudo-second-order and Langmuir model fitted well with the adsorption kinetics and isotherms of the N-doped hierarchical biochar. The incorporation of nitrogen element could not only tune the distribution of surface electrons on biochar, but optimize the ambient condition of adsorption active sites as well. The adsorption of MO might occur on the N-/O-containing functional groups through the electrostatic interaction, the π-π dispersion interaction, and the hydrogen bonding. The density functional theory showed that the graphitic-N and pyridinic-N were the dominant adsorption active sites. Graphical Abstract
生物炭是一种潜在的多孔碳,可以去除水生环境中的污染物。本文采用氨热解预处理(ATP)和碱活化相结合的方法制备了n掺杂层次化生物炭。ATP不仅能将N元素掺入杨木中,还能获得杨木的松散结构。氨湿焙烧预处理后n掺杂层次化生物炭的最高比表面积为2324.61 m 2 g−1,高于未焙烧预处理的活性炭(1401.82 m 2 g−1)和无氨气氛的层次化生物炭(2111.03 m 2 g−1)。N掺杂生物炭对甲基橙(MO)的吸附量最高(564.7 mg g−1),是未掺杂生物炭的14.64倍。此外,拟二阶模型和Langmuir模型与n掺杂层次化生物炭的吸附动力学和等温线吻合良好。氮元素的加入不仅可以调节生物炭表面电子的分布,还可以优化吸附活性位点的环境条件。MO的吸附可能通过静电相互作用、π-π色散相互作用和氢键作用在含N / o的官能团上发生。密度泛函理论表明石墨- n和吡啶- n是主要的吸附活性位点。图形抽象
{"title":"A sustainable preparation strategy for the nitrogen-doped hierarchical biochar with high surface area for the enhanced removal of organic dye","authors":"Yiting Mao, Bo Cai, Ming Huang, Xiaohuan Liu, Wenbiao Zhang, Zhongqing Ma","doi":"10.1007/s42773-023-00269-z","DOIUrl":"https://doi.org/10.1007/s42773-023-00269-z","url":null,"abstract":"Abstract Biochar is a potential porous carbon to remove the contaminants from aquatic environments. Herein, N-doped hierarchical biochar was produced by the combined approach of ammonia torrefaction pretreatment (ATP) and alkali activation. ATP could not only incorporate N element into poplar wood, but obtain the loose structure of poplar wood. The highest surface area of N-doped hierarchical biochar was 2324.61 m 2 g −1 after ammonia wet torrefaction pretreatment, which was higher than that of activation carbon (1401.82 m 2 g −1 ) without torrefaction pretreatment, the hierarchical biochar (2111.03 m 2 g −1 ) without ammonia atmosphere. The N-doped hierarchical biochar presented the highest adsorption capacity (564.7 mg g −1 ) of methyl orange (MO), which was 14.64-fold of that on biochar without N doping. In addition, the pseudo-second-order and Langmuir model fitted well with the adsorption kinetics and isotherms of the N-doped hierarchical biochar. The incorporation of nitrogen element could not only tune the distribution of surface electrons on biochar, but optimize the ambient condition of adsorption active sites as well. The adsorption of MO might occur on the N-/O-containing functional groups through the electrostatic interaction, the π-π dispersion interaction, and the hydrogen bonding. The density functional theory showed that the graphitic-N and pyridinic-N were the dominant adsorption active sites. Graphical Abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"47 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135584762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Herein, we report the synthesis of interconnected hierarchical pore biochar (HTB) via an ice-templating strategy using bio-waste (tofukasu). The abundance of N- and O-containing functional groups in tofukasu makes it easy to form hydrogen bonds with water molecules and water clusters, resulting in nano-micro structures like ice clusters and snow crystals during freezing process. More importantly, tofukasu will be squeezed by micron-scale snow crystals to form coiled sheet-like structures, and its surface and interior will be affected by needle-like ice nanocrystals from several nanometers to tens of nanometers to form transverse groove needles and mesopores. The ice crystals are then removed by sublimation with tofukasu, leaving the interconnected pore structure intact. Therefore, the ice template synthesis strategy endowed the interconnected hierarchical pore structure of HTB with a large specific surface area (S BET , 733 m 2 ⋅g −1 ) and hierarchical porosity (30.30% for mesopores/total pore volume ratio), which is significantly higher than the normal dry treated tofukasu biochar (TB), which had a S BET of 436 m 2 ⋅g −1 and contained 1.53% mesopores. In addition, the sheet-like structure with interconnected pores of HTB favors high exposure of active sites (N- and O-containing functional groups), and a fast electron transport rate. As a result, HTB had an excellent adsorption capacity of 159.65 mg⋅g −1 , which is 4.7 times that of typical block biochar of TB (33.89 mg⋅g −1 ) according to Langmuir model. Electrochemical characterization, FTIR and XPS analysis showed that the mechanism of Cr(VI) removal by HTB included electrostatic attraction, pore filling, reduction and surface complexation. Graphical Abstract
摘要本文报道了利用生物垃圾(tofukasu)通过冰模板策略合成相互连接的分层孔生物炭(HTB)。富饭团中含有丰富的含N、o官能团,容易与水分子和水团形成氢键,在冷冻过程中形成冰团、雪晶等纳米微观结构。更重要的是,tofukasu会受到微米尺度雪晶的挤压,形成盘绕的片状结构,其表面和内部会受到针状冰纳米晶的影响,从几纳米到几十纳米,形成横向槽状针状和介孔。然后,冰晶通过tofukasu升华去除,使相互连接的孔结构保持完整。因此,冰模板合成策略使HTB具有较大的比表面积(S BET, 733 m 2⋅g−1)和分层孔隙率(介孔/总孔容比30.30%),显著高于常规干法处理的tofukasu生物炭(TB), S BET为436 m 2⋅g−1,含1.53%介孔。此外,HTB的片状结构具有相互连接的孔隙,有利于活性位点(含N和o的官能团)的高暴露和快速的电子传递速率。根据Langmuir模型,HTB的吸附量为159.65 mg⋅g−1,是典型结核块状生物炭(33.89 mg⋅g−1)的4.7倍。电化学表征、FTIR和XPS分析表明,HTB去除Cr(VI)的机理包括静电吸引、孔隙填充、还原和表面络合。图形抽象
{"title":"Tofukasu-derived biochar with interconnected and hierarchical pores for high efficient removal of Cr (VI)","authors":"Liang Fang, Wei Yang, Jianhua Hou, kewang Zheng, Asif Hussain, Yongcai Zhang, Zhenhua Hou, Xiaozhi Wang","doi":"10.1007/s42773-023-00268-0","DOIUrl":"https://doi.org/10.1007/s42773-023-00268-0","url":null,"abstract":"Abstract Herein, we report the synthesis of interconnected hierarchical pore biochar (HTB) via an ice-templating strategy using bio-waste (tofukasu). The abundance of N- and O-containing functional groups in tofukasu makes it easy to form hydrogen bonds with water molecules and water clusters, resulting in nano-micro structures like ice clusters and snow crystals during freezing process. More importantly, tofukasu will be squeezed by micron-scale snow crystals to form coiled sheet-like structures, and its surface and interior will be affected by needle-like ice nanocrystals from several nanometers to tens of nanometers to form transverse groove needles and mesopores. The ice crystals are then removed by sublimation with tofukasu, leaving the interconnected pore structure intact. Therefore, the ice template synthesis strategy endowed the interconnected hierarchical pore structure of HTB with a large specific surface area (S BET , 733 m 2 ⋅g −1 ) and hierarchical porosity (30.30% for mesopores/total pore volume ratio), which is significantly higher than the normal dry treated tofukasu biochar (TB), which had a S BET of 436 m 2 ⋅g −1 and contained 1.53% mesopores. In addition, the sheet-like structure with interconnected pores of HTB favors high exposure of active sites (N- and O-containing functional groups), and a fast electron transport rate. As a result, HTB had an excellent adsorption capacity of 159.65 mg⋅g −1 , which is 4.7 times that of typical block biochar of TB (33.89 mg⋅g −1 ) according to Langmuir model. Electrochemical characterization, FTIR and XPS analysis showed that the mechanism of Cr(VI) removal by HTB included electrostatic attraction, pore filling, reduction and surface complexation. Graphical Abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"90 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136103137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Root and tuber crops are important sources of food and provide income for millions of people worldwide besides an observed high demand for organically produced harvests. Hence, recent attention has been given to utilizing biochar, a carbon-rich material produced from the pyrolysis of organic materials, which improves soil structure, water-holding capacity, and nutrient availability, as an amendment to produce organic root and tuber crops. These effects are caused by the formation of organic coatings on the surface of biochar, which decreases hydrophobicity and increases the ability to retain nutrients, acting as a slow-release mechanism delivering nutrients dependent on plant physiological requirements. However, comprehensive studies on the impact of biochar application on root and tuber crop growth, productivity, and effectiveness in eliminating soil parasites have not been extensively studied. Thus, the purpose of this review is to explore the use of biochar and biochar-based soil amendments and their potential applications for improving the growth, yield, and efficacy of controlling parasitic nematodes in a wide range of root crops. Most of the studies have investigated the effects of biochar on cassava, sweet potatoes, and minor root crops such as ginger and turmeric. It has been observed that biochar application rates (5–20 t ha −1 ) increase the vine length and the number of leaves, tubers, and tuber weight. The addition of biochar demonstrates the ability to control plant-parasitic nematodes in a rate-dependent manner. While biochar has shown promising results in improving crop growth and yield of limited root and tuber crops based on a few biochar types, ample opportunities are around to evaluate the influence of biochar produced in different temperatures, feedstock, modifications and controlling parasitic nematodes. Graphical abstract
块根和块茎作物是重要的食物来源,除了对有机农产品的高需求外,还为全世界数百万人提供收入。因此,近年来人们开始关注利用生物炭作为一种改良剂来生产有机块根作物。生物炭是一种由有机材料热解产生的富含碳的物质,可以改善土壤结构、持水能力和养分有效性。这些影响是由生物炭表面形成的有机涂层引起的,它降低了疏水性,增加了保留养分的能力,作为一种缓慢释放机制,根据植物的生理需求输送养分。然而,生物炭施用对块根作物生长、生产力和除虫效果的影响尚未得到全面的研究。因此,本综述的目的是探讨生物炭和生物炭基土壤改良剂在改善多种根茎作物生长、产量和控制寄生线虫效果方面的潜在应用。大多数研究都调查了生物炭对木薯、红薯和生姜、姜黄等小型块根作物的影响。据观察,生物炭施用量(5-20 t / h - 1)可增加藤长、叶片数量、块茎数量和块茎重量。添加生物炭证明了以速率依赖的方式控制植物寄生线虫的能力。虽然生物炭在改善基于几种生物炭类型的有限块根和块茎作物的作物生长和产量方面显示出有希望的结果,但在评估不同温度、原料、改性和控制寄生线虫下生产的生物炭的影响方面仍有充分的机会。图形抽象
{"title":"Influence of biochar on growth performances, yield of root and tuber crops and controlling plant-parasitic nematodes","authors":"Randima Edussuriya, Anushka Upamali Rajapaksha, Chamila Jayasinghe, Chaamila Pathirana, Meththika Vithanage","doi":"10.1007/s42773-023-00261-7","DOIUrl":"https://doi.org/10.1007/s42773-023-00261-7","url":null,"abstract":"Abstract Root and tuber crops are important sources of food and provide income for millions of people worldwide besides an observed high demand for organically produced harvests. Hence, recent attention has been given to utilizing biochar, a carbon-rich material produced from the pyrolysis of organic materials, which improves soil structure, water-holding capacity, and nutrient availability, as an amendment to produce organic root and tuber crops. These effects are caused by the formation of organic coatings on the surface of biochar, which decreases hydrophobicity and increases the ability to retain nutrients, acting as a slow-release mechanism delivering nutrients dependent on plant physiological requirements. However, comprehensive studies on the impact of biochar application on root and tuber crop growth, productivity, and effectiveness in eliminating soil parasites have not been extensively studied. Thus, the purpose of this review is to explore the use of biochar and biochar-based soil amendments and their potential applications for improving the growth, yield, and efficacy of controlling parasitic nematodes in a wide range of root crops. Most of the studies have investigated the effects of biochar on cassava, sweet potatoes, and minor root crops such as ginger and turmeric. It has been observed that biochar application rates (5–20 t ha −1 ) increase the vine length and the number of leaves, tubers, and tuber weight. The addition of biochar demonstrates the ability to control plant-parasitic nematodes in a rate-dependent manner. While biochar has shown promising results in improving crop growth and yield of limited root and tuber crops based on a few biochar types, ample opportunities are around to evaluate the influence of biochar produced in different temperatures, feedstock, modifications and controlling parasitic nematodes. Graphical abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"22 10","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135113047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The intensification of estrogen non-point source pollution has drawn global attention due to their contribution to ecological environment problems worldwide, and it is critical to develop effective, economic and eco-friendly methods for reducing estrogens pollution. To address the agglomeration and oxidation of nano zero-valent iron (nZVI), biochar-nanoscale zero-valent iron composite (nZVI-biochar) could be a feasible choice for estrogens removal. This study summarized biochar and nZVI-biochar preparation, characterization, and unusual applications for estrone (E1), 17 β -estradiol (E2), and estriol (E3) removal. The properties of biochar and nZVI-biochar in characterization, effects of influencing factors on the removal efficiency, adsorption kinetics, isotherm and thermodynamics were investigated. The experiment results showed that nZVI-biochar exhibited the superior removal performance for estrogens pollutants compared to biochar. Based on the quasi-second-order model, estrogens adsorption kinetics were observed, which supported the mechanism that chemical and physical adsorption existed simultaneously on estrogens removal. The adsorption isotherm of estrogens could be well presented by the Freundlich model and thermodynamics studies explained that nZVI-biochar could spontaneously remove estrogens pollutants and the main mechanisms involved π-π interaction, hydrophobic interaction, hydrogen bonding and degradation through ring rupture. The products analyzed by GC–MS showed that estrogens degradation was primarily attributed to the benzene ring broken, and Fe 3+ promoted the production of free radicals, which further proved that nZVI-biochar had the excellent adsorption performances. Generally, nZVI-biochar could be employed as a potential material for removing estrogens from wastewater. Graphical Abstract
{"title":"Enhanced removal of estrogens from simulated wastewater by biochar supported nanoscale zero-valent iron: performance and mechanism","authors":"Yuping Han, Huanhuan Xu, Guangzhou Wang, Peiyuan Deng, Lili Feng, Yaoshen Fan, Jiaxin Zhang","doi":"10.1007/s42773-023-00264-4","DOIUrl":"https://doi.org/10.1007/s42773-023-00264-4","url":null,"abstract":"Abstract The intensification of estrogen non-point source pollution has drawn global attention due to their contribution to ecological environment problems worldwide, and it is critical to develop effective, economic and eco-friendly methods for reducing estrogens pollution. To address the agglomeration and oxidation of nano zero-valent iron (nZVI), biochar-nanoscale zero-valent iron composite (nZVI-biochar) could be a feasible choice for estrogens removal. This study summarized biochar and nZVI-biochar preparation, characterization, and unusual applications for estrone (E1), 17 β -estradiol (E2), and estriol (E3) removal. The properties of biochar and nZVI-biochar in characterization, effects of influencing factors on the removal efficiency, adsorption kinetics, isotherm and thermodynamics were investigated. The experiment results showed that nZVI-biochar exhibited the superior removal performance for estrogens pollutants compared to biochar. Based on the quasi-second-order model, estrogens adsorption kinetics were observed, which supported the mechanism that chemical and physical adsorption existed simultaneously on estrogens removal. The adsorption isotherm of estrogens could be well presented by the Freundlich model and thermodynamics studies explained that nZVI-biochar could spontaneously remove estrogens pollutants and the main mechanisms involved π-π interaction, hydrophobic interaction, hydrogen bonding and degradation through ring rupture. The products analyzed by GC–MS showed that estrogens degradation was primarily attributed to the benzene ring broken, and Fe 3+ promoted the production of free radicals, which further proved that nZVI-biochar had the excellent adsorption performances. Generally, nZVI-biochar could be employed as a potential material for removing estrogens from wastewater. Graphical Abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"41 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135405349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-12DOI: 10.1007/s42773-023-00267-1
Jae-Hyuk Park, Jin-Ju Yun, Seong-Heon Kim, Jong-Hwan Park, Bharat Sharma Acharya, Ju-Sik Cho, Se-Won Kang
Abstract Biochar has been shown to improve soil properties and plant productivity in soils with inherently low fertility. However, little has been reported for upland corns under dry and wet precipitation regimes. This study investigates the effect of biochar addition on a range of soil physicochemical, biological, and hydrological properties, and corn growth and productivity under agrometeorological drought and wet conditions. Here, experiments were laid out in a randomized complete block design with three replications at two sites during 2017 and 2018 in South Korea. Treatments included (i) CN: control (ii) IF: inorganic fertilizer (N–P–K) at 145–30–60 kg ha −1 ; (iii) BS: barley straw at 5 t ha −1 ; (iv) CWBC: corn waste biochar at 5 t ha −1 ; (v) CWBC + IF: corn waste biochar + inorganic fertilizer; (vi) CWBC + BS: corn waste biochar + barley straw. The year 2017 was relatively dry, whereas the year 2018 was wet. Despite drought conditions in the year 2017, biochar facilitated soil water conservation. However, higher precipitation in 2018 increased the quantity and distribution of soil water and nutrients in the top 15 cm. Biochar reduced soil bulk density, and increased porosity, cation exchange capacity and total organic carbon in both years but increased total bacterial counts during the dry year only. Bacterial population was generally higher under wet conditions. Similarly, more soil CO 2 was emitted in the wet year than in the dry year. Results further indicated that biochar can enhance corn biomass and grain yield regardless of precipitation conditions. The grain index was, however, affected by rainfall and was significantly different across treatments in the year 2018 only. All biomass, grain yield, and grain index were highest in CWBC + IF treatment and lowest under CN treatment. Indeed, biochar addition appeared to improve soil quality and soil conditioning effects in the drought and wet years, ameliorating soil and plant properties. Overall, biochar can improve water and nutrients storage, availability, and uptake, and therefore corn productivity during hydrological extremes. Graphical abstract
生物炭在低肥力土壤中具有改善土壤性质和提高植物生产力的作用。然而,旱地玉米在干湿降水条件下几乎没有报道。本研究探讨了在农业气象干旱和潮湿条件下,添加生物炭对土壤理化、生物和水文特性以及玉米生长和生产力的影响。在这里,实验以随机完全块设计进行,在2017年和2018年在韩国的两个地点进行了三个重复。处理包括(i) CN:对照(ii) IF:无机肥(N-P-K), 145-30-60 kg ha - 1;(iii) BS: 5 t ha - 1的大麦秸秆;(iv) CWBC:玉米废料生物炭5吨/立方米;(v) CWBC + IF:玉米废生物炭+无机肥料;(vi) CWBC + BS:玉米废生物炭+大麦秸秆。2017年比较干燥,而2018年比较潮湿。尽管2017年干旱,但生物炭促进了水土保持。然而,2018年的高降水增加了顶部15 cm土壤水分和养分的数量和分布。生物炭降低了土壤容重,增加了土壤孔隙度、阳离子交换容量和总有机碳,但只在干旱年增加了土壤细菌总数。在潮湿条件下细菌数量普遍较高。同样,湿润年的土壤co2排放量也高于干旱年。结果进一步表明,无论在何种降水条件下,生物炭都能提高玉米生物量和产量。籽粒指数受降雨影响,仅2018年处理间差异显著。生物量、籽粒产量和籽粒指数均以CWBC + IF处理最高,CN处理最低。事实上,在干旱和潮湿年份,添加生物炭似乎改善了土壤质量和土壤调节效应,改善了土壤和植物的特性。总的来说,生物炭可以改善水分和养分的储存、可用性和吸收,从而在极端水文条件下提高玉米产量。图形抽象
{"title":"Biochar improves soil properties and corn productivity under drought conditions in South Korea","authors":"Jae-Hyuk Park, Jin-Ju Yun, Seong-Heon Kim, Jong-Hwan Park, Bharat Sharma Acharya, Ju-Sik Cho, Se-Won Kang","doi":"10.1007/s42773-023-00267-1","DOIUrl":"https://doi.org/10.1007/s42773-023-00267-1","url":null,"abstract":"Abstract Biochar has been shown to improve soil properties and plant productivity in soils with inherently low fertility. However, little has been reported for upland corns under dry and wet precipitation regimes. This study investigates the effect of biochar addition on a range of soil physicochemical, biological, and hydrological properties, and corn growth and productivity under agrometeorological drought and wet conditions. Here, experiments were laid out in a randomized complete block design with three replications at two sites during 2017 and 2018 in South Korea. Treatments included (i) CN: control (ii) IF: inorganic fertilizer (N–P–K) at 145–30–60 kg ha −1 ; (iii) BS: barley straw at 5 t ha −1 ; (iv) CWBC: corn waste biochar at 5 t ha −1 ; (v) CWBC + IF: corn waste biochar + inorganic fertilizer; (vi) CWBC + BS: corn waste biochar + barley straw. The year 2017 was relatively dry, whereas the year 2018 was wet. Despite drought conditions in the year 2017, biochar facilitated soil water conservation. However, higher precipitation in 2018 increased the quantity and distribution of soil water and nutrients in the top 15 cm. Biochar reduced soil bulk density, and increased porosity, cation exchange capacity and total organic carbon in both years but increased total bacterial counts during the dry year only. Bacterial population was generally higher under wet conditions. Similarly, more soil CO 2 was emitted in the wet year than in the dry year. Results further indicated that biochar can enhance corn biomass and grain yield regardless of precipitation conditions. The grain index was, however, affected by rainfall and was significantly different across treatments in the year 2018 only. All biomass, grain yield, and grain index were highest in CWBC + IF treatment and lowest under CN treatment. Indeed, biochar addition appeared to improve soil quality and soil conditioning effects in the drought and wet years, ameliorating soil and plant properties. Overall, biochar can improve water and nutrients storage, availability, and uptake, and therefore corn productivity during hydrological extremes. Graphical abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135969287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-11DOI: 10.1007/s42773-023-00258-2
David Lefebvre, Samer Fawzy, Camila A. Aquije, Ahmed I. Osman, Kathleen T. Draper, Thomas A. Trabold
Abstract The Climate Change Conference of Parties (COP) 21 in December 2015 established Nationally Determined Contributions toward reduction of greenhouse gas emissions. In the years since COP21, it has become increasingly evident that carbon dioxide removal (CDR) technologies must be deployed immediately to stabilize concentration of atmospheric greenhouse gases and avoid major climate change impacts. Biochar is a carbon-rich material formed by high-temperature conversion of biomass under reduced oxygen conditions, and its production is one of few established CDR methods that can be deployed at a scale large enough to counteract effects of climate change within the next decade. Here we provide a generalized framework for quantifying the potential contribution biochar can make toward achieving national carbon emissions reduction goals, assuming use of only sustainably supplied biomass, i.e., residues from existing agricultural, livestock, forestry and wastewater treatment operations. Our results illustrate the significant role biochar can play in world-wide CDR strategies, with carbon dioxide removal potential of 6.23 ± 0.24% of total GHG emissions in the 155 countries covered based on 2020 data over a 100-year timeframe, and more than 10% of national emissions in 28 countries. Concentrated regions of high biochar carbon dioxide removal potential relative to national emissions were identified in South America, northwestern Africa and eastern Europe. Graphical abstract
{"title":"Biomass residue to carbon dioxide removal: quantifying the global impact of biochar","authors":"David Lefebvre, Samer Fawzy, Camila A. Aquije, Ahmed I. Osman, Kathleen T. Draper, Thomas A. Trabold","doi":"10.1007/s42773-023-00258-2","DOIUrl":"https://doi.org/10.1007/s42773-023-00258-2","url":null,"abstract":"Abstract The Climate Change Conference of Parties (COP) 21 in December 2015 established Nationally Determined Contributions toward reduction of greenhouse gas emissions. In the years since COP21, it has become increasingly evident that carbon dioxide removal (CDR) technologies must be deployed immediately to stabilize concentration of atmospheric greenhouse gases and avoid major climate change impacts. Biochar is a carbon-rich material formed by high-temperature conversion of biomass under reduced oxygen conditions, and its production is one of few established CDR methods that can be deployed at a scale large enough to counteract effects of climate change within the next decade. Here we provide a generalized framework for quantifying the potential contribution biochar can make toward achieving national carbon emissions reduction goals, assuming use of only sustainably supplied biomass, i.e., residues from existing agricultural, livestock, forestry and wastewater treatment operations. Our results illustrate the significant role biochar can play in world-wide CDR strategies, with carbon dioxide removal potential of 6.23 ± 0.24% of total GHG emissions in the 155 countries covered based on 2020 data over a 100-year timeframe, and more than 10% of national emissions in 28 countries. Concentrated regions of high biochar carbon dioxide removal potential relative to national emissions were identified in South America, northwestern Africa and eastern Europe. Graphical abstract","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136059359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}