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Improving bifunctional catalytic activity of biochar via in-situ growth of nickel-iron hydroxide as cathodic catalyst for zinc-air batteries 原位生长氢氧化铁镍作为锌空气电池阴极催化剂,提高生物炭双功能催化活性
2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-27 DOI: 10.1007/s42773-023-00259-1
Pengxiang Zhang, Kang Sun, Yanyan Liu, Benji Zhou, Shuqi Li, Jingjing Zhou, Ao Wang, Lixia Xie, Baojun Li, Jianchun Jiang
Abstract Expanding the application scenarios of wood-derived biochar guided by the conversion of traditional energy to new energy shows great promise as a field. As thrilling energy conversion apparatus, zinc-air batteries (ZABs) require cathode catalysts with high oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) activities and stability. Herein, two-dimensional nickel-iron hydroxide nanosheets were creatively assembled in N-doped wood-derived biochar (NiFe-LDH@NC) by an in-situ growth method. The categorized porous organization in wood-derived biochar facilitates the rapid seepage of electrolytes and rapid diffusion of reaction gases. The unique interfacial structure of biochar and NiFe-LDH accelerates electron transfer during oxygen electrocatalysis, and endows NiFe-LDH@NC with first-class catalytic activity and durability for ORR and OER. The ZAB derived from NiFe-LDH@NC showed elevated discharge productivity and cycle endurance, making it promising for viable applications. This work provided a convenient way for the conversion of wood-derived biochar to high-value added electrocatalysts. Graphical Abstract
以传统能源向新能源转化为导向,拓展木质生物炭的应用场景,是一个大有发展前景的领域。锌空气电池(ZABs)作为一种令人兴奋的能量转换装置,需要具有高氧还原反应(ORR)和氧演化反应(OER)活性和稳定性的阴极催化剂。本文采用原位生长的方法,在掺杂n的木材衍生生物炭(NiFe-LDH@NC)中创造性地组装了二维氢氧化铁镍纳米片。木质生物炭的多孔组织有利于电解液的快速渗透和反应气体的快速扩散。生物炭与NiFe-LDH独特的界面结构加速了氧电催化过程中的电子转移,使NiFe-LDH@NC对ORR和OER具有一流的催化活性和耐久性。来自NiFe-LDH@NC的ZAB显示出更高的放电生产率和循环耐久性,使其具有可行的应用前景。本研究为木质生物炭转化为高附加值电催化剂提供了便利途径。图形抽象
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引用次数: 0
Preparation of carbon-based material with high water absorption capacity and its effect on the water retention characteristics of sandy soil 高吸水性碳基材料的制备及其对沙土保水特性的影响
2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-27 DOI: 10.1007/s42773-023-00260-8
Youming Yang, Mingyang Zhong, Xiuqi Bian, Yongjun You, Fayong Li
Abstract Biochar has the potential to provide a multitude of benefits when used in soil remediation and increasing soil organic matter enrichment. Nevertheless, the intricated, hydrophobic pores and groups weaken its water-holding capacity in dry, sandy soils in arid lands. In order to combat this issue, starch-carbon-based material (SB), sodium alginate-carbon-based material (SAB), and chitosan-carbon-based material (CB) have been successfully synthesized through the graft-polymerization of biochar (BC). A series of soil column simulations were used to scrutinize the microstructure of the carbon-based material and explore its water absorption properties and its effects on sandy soil water infiltration, water retention, and aggregation. The results indicated that SB, SAB, and CB achieved water maximum absorption rates of 155, 188, and 172 g g −1 , respectively. Considering their impact on sandy soils, SB, SAB, and CB lengthened infiltration times by 1920, 3330, and 3880 min, respectively, whilst enhancing the water retention capabilities of the soil by 18%, 25%, and 23% in comparison to solely adding BC. The utilization of these innovative materials notably encouraged the formation of sandy soil aggregates ranging from 2.0 to 0.25 mm, endowing the aggregates with enhanced structural stability. Findings from potting experiments suggested that all three carbon-based materials were conducive to the growth of soybean seeds. Thus, it is evident that the carbon-based materials have been fabricated with success, and they have great potential not only to significantly augment the water retention capacities and structural robustness of sandy soils in arid areas, but also to bolster the development of soil aggregates and crop growth. These materials possess significant application potential for enhancing the quality of sandy soils in arid and semi-arid regions. Graphical Abstract
生物炭在土壤修复和增加土壤有机质富集方面具有许多潜在的优势。然而,在干旱地区的干燥沙质土壤中,复杂的疏水孔隙和基团削弱了其持水能力。为了解决这一问题,通过生物炭(BC)的接枝聚合,成功合成了淀粉-碳基材料(SB)、海藻酸钠-碳基材料(SAB)和壳聚糖-碳基材料(CB)。采用一系列土壤柱模拟研究了碳基材料的微观结构,探讨了碳基材料的吸水特性及其对沙土水分入渗、保水和团聚的影响。结果表明,SB、SAB和CB的最大吸水率分别为155、188和172 g g−1。考虑到其对沙质土壤的影响,与单独添加BC相比,SB、SAB和CB分别延长了入渗时间1920、3330和3880 min,同时提高了土壤的保水能力18%、25%和23%。这些创新材料的使用显著促进了2.0 - 0.25 mm沙土团聚体的形成,增强了团聚体的结构稳定性。盆栽试验结果表明,这三种碳基材料都有利于大豆种子的生长。因此,很明显,碳基材料的制备是成功的,它们不仅具有显着增强干旱地区沙质土壤的保水性和结构稳健性的巨大潜力,而且还具有促进土壤团聚体发育和作物生长的潜力。这些材料在改善干旱半干旱区沙质土质量方面具有重要的应用潜力。图形抽象
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引用次数: 1
Biochar derived from invasive plants improved the pH, macronutrient availability and biological properties better than liming for acid rain-affected soil 入侵植物生物炭对酸雨影响土壤的pH值、常量养分有效性和生物学特性的改善优于石灰
2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-27 DOI: 10.1007/s42773-023-00251-9
Yazheng Li, Ahmed I. Abdo, Zhaoji Shi, Abdel-Rahman M. A. Merwad, Jiaen Zhang
Abstract Rapid development in industrialization and urbanization causes serious environmental issues, of which acid rain is one of the quintessential hazards, negatively affecting soil ecology. Liming has been investigated for a long time as the most effective amendment to alter the adverse effects of soil acidity resulting from acid rain. Herein, this study tested the biochar produced from invasive plants as an alternative amendment and hypothesized that biochar can maintain better availability of macronutrients under acid rain than liming by improving soil chemical and biological properties. Therefore, a pot experiment was conducted to compare the effects of lime and biochar at two rates (1% and 3%) on soil available nitrogen (N), phosphorous (P) and potassium (K) under simulated acid rain of two pH levels (4.5: pH 4.5 and 2.5: pH 2.5 ) as compared with tap water (pH 7.1 ) as a control treatment. Biochar was produced using different invasive plants, including Blackjack ( Biden Pilosa ), Wedelia ( Wedelia trilobata ) and Bitter Vine ( Mikania micrantha Kunth ). Liming decreased the availability of soil N, P, and K by 36.3% as compared with the control due to the great increment in soil pH and exchangeable calcium (Ca 2+ ) by 59% and 16-fold, respectively. Moreover, liming reduced the alpha diversity of soil bacteria and fungi by 27% and 11%, respectively. In contrast, biochar at different types and rates resulted in a fourfold increment in the available N, P, and K as an average under acid rain (pH 4.5 and pH 2.5 ) owing to maintaining a neutral pH (6.5–7), which is the most favorable level for soil microbial and enzymatic activites, and the bioavailability of soil nutrients. Furthermore, biochar caused balanced increments in Ca 2+ by threefold, cation exchange capacity by 45%, urease activity by 16%, and fungal diversity by 10%, while having a slight reduction in bacterial diversity by 2.5%. Based on the path, correlation, and principal component analyses, the exchangeable aluminum was a moderator for the reductions in macronutrients’ availability under acid rain, which decreased by 40% and 35% under liming and biochar, respectively. This study strongly recommended the use of biochar from invasive plants instead of lime for sustainable improvements in soil properties under acid rain. Graphical Abstract
工业化和城市化的快速发展导致了严重的环境问题,酸雨是典型的危害之一,对土壤生态产生了负面影响。长期以来,人们一直在研究石灰作为改变酸雨对土壤酸度影响的最有效的改良剂。因此,本研究测试了入侵植物产生的生物炭作为一种替代改良剂,并假设生物炭通过改善土壤的化学和生物特性,在酸雨条件下保持比石灰更好的宏量营养素有效性。因此,通过盆栽试验,比较了石灰和生物炭在两种pH值(4.5:ph4.5和2.5:ph2.5)的模拟酸雨条件下(pH值为7.1)与自来水(pH值为7.1)对土壤速效氮(N)、磷(P)和钾(K)的影响。生物炭是用不同的入侵植物生产的,包括黑杰克(拜登·皮洛萨),Wedelia(三叶Wedelia)和苦藤(薇甘菊)。石灰处理导致土壤pH和交换性钙(ca2 +)分别大幅增加59%和16倍,使土壤N、P和K的有效性比对照降低36.3%。石灰处理使土壤细菌和真菌的α多样性分别降低27%和11%。相反,不同类型和速率的生物炭在酸雨(pH 4.5和pH 2.5)条件下,由于保持了最有利于土壤微生物和酶活性以及土壤养分生物有效性的中性pH(6.5-7),导致有效氮、磷和钾的平均增加了4倍。此外,生物炭使ca2 +平衡增加了3倍,阳离子交换容量增加了45%,脲酶活性增加了16%,真菌多样性增加了10%,而细菌多样性减少了2.5%。通过通径分析、相关分析和主成分分析发现,交换性铝是酸雨条件下宏量营养素有效性降低的减缓剂,石灰化和生物炭条件下宏量营养素有效性分别降低了40%和35%。本研究强烈建议使用入侵植物的生物炭代替石灰,以持续改善酸雨下的土壤性质。图形抽象
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引用次数: 0
Biochar reduces colloidal phosphorus in leachate by regulating phoD- and phoC-harboring microbial communities during drying/rewetting cycles 在干燥/再湿循环中,生物炭通过调节phoD和phoc的微生物群落来减少渗滤液中的胶体磷
2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-21 DOI: 10.1007/s42773-023-00262-6
Xiaochun Wang, Hongnuo Ge, Yunying Fang, Chunlong Liu, Kamel M. Eltohamy, Zekai Wang, Xinqiang Liang
Abstract Drying and rewetting (DRW) events cause the release of colloidal phosphorus (P coll , 1–1000 nm) in leachate, and biochar is considered an effective inhibitor; however, the microbial mechanism remains elusive. In this study, three successive DRW cycles were performed on the soil columns to assess the effect of biochar addition on P coll content and its possible associates, including phosphatase-producing microbial populations ( phoD - and phoC -harboring microbial communities) and alkaline/acid phosphatase (ALP/ACP) activities. Results showed that the biochar addition significantly decreased the P coll by 15.5–32.1% during three DRW cycles. The structural equation model (SEM) confirmed that biochar addition increased phoD- and phoC -harboring microbial communities and ALP/ACP activities, which reduces the release of P coll into leachate. In addition, the manure biochar was more effective than the straw biochar in promoting competition and cooperation in the co-occurrence network (2–5% nodes increased on average), and the key taxa Proteobacteria and Cyanobacteria were identified as the dominant species of potential ALP/ACP activities and P coll content. Our findings provide a novel understanding of biochar reducing P coll loss from the phosphatase perspective by regulating the phoD - and phoC -harboring communities during DRW events. Graphical abstract
干燥和再湿(DRW)事件会导致渗滤液中胶体磷(P coll, 1-1000 nm)的释放,生物炭被认为是一种有效的抑制剂;然而,微生物机制仍然难以捉摸。本研究在土壤柱上进行了3个连续的DRW循环,以评估添加生物炭对磷含量及其可能的关联物的影响,包括产生磷酸酶的微生物群落(phoD -和phoC -的微生物群落)和碱性/酸性磷酸酶(ALP/ACP)活性。结果表明,在3个DRW循环中,添加生物炭可显著降低磷含量15.5 ~ 32.1%。结构方程模型(SEM)证实,添加生物炭增加了phoD-和phoC -的微生物群落和ALP/ACP活性,减少了P coll向渗滤液中的释放。此外,粪肥生物炭比秸秆生物炭更能促进共生网络中的竞争与合作(平均增加2-5%的节点),关键类群Proteobacteria和Cyanobacteria是潜在ALP/ACP活性和P coll含量的优势种。我们的研究结果从磷酸酶的角度对生物炭在DRW事件中通过调节phoD -和phoC -窝藏群落来减少P - coll损失提供了新的理解。图形抽象
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引用次数: 0
Microbial responses towards biochar application in potentially toxic element (PTE) contaminated soil: a critical review on effects and potential mechanisms 在潜在有毒元素(PTE)污染土壤中应用生物炭的微生物反应:影响和潜在机制的重要综述
2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-15 DOI: 10.1007/s42773-023-00255-5
Xiao Yang, Miao You, Siyan Liu, Binoy Sarkar, Zhaoshu Liu, Xiulan Yan
Abstract Soil harbors a huge diversity of microorganisms and serves as the ecological and social foundation of human civilization. Hence, soil health management is of utmost and consistent importance, aligning with the United Nations Sustainable Development Goals. One of the most hazardous contaminants in soil matrix is potentially toxic elements (PTEs), which can cause stress in soil indigenous microorganisms and severely jeopardize soil health. Biochar technology has emerged as a promising means to alleviate PTE toxicity and benefit soil health management. Current literature has broadly integrated knowledge about the potential consequences of biochar-amended soil but has focused more on the physical and chemical responses of the soil system than microbiological attributes. In consideration of the indispensable roles of soil microbials, this paper first introduces PTE-induced stresses on soil microbials and then proposes the mechanisms of biochar’s effects on soil microbials. Finally, microbial responses including variations in abundance, interspecific relationships, community composition and biological functions in biochar-amended soil are critically reviewed. This review thus aims to provide a comprehensive scientific view on the effect of biochar on soil microbiological health and its management. Graphical Abstract
土壤中蕴藏着种类繁多的微生物,是人类文明的生态和社会基础。因此,与联合国可持续发展目标相一致,土壤健康管理始终至关重要。土壤基质中最危险的污染物之一是潜在有毒元素(pte),它会对土壤本地微生物造成应激,严重危害土壤健康。生物炭技术已成为减轻PTE毒性和有利于土壤健康管理的一种有前景的手段。目前的文献已经广泛地整合了关于生物炭改性土壤的潜在后果的知识,但更多地关注土壤系统的物理和化学反应,而不是微生物属性。考虑到土壤微生物不可缺少的作用,本文首先介绍了pte对土壤微生物的胁迫,然后提出了生物炭对土壤微生物的影响机制。最后,综述了生物炭改良土壤中微生物的反应,包括丰度变化、种间关系、群落组成和生物功能。本文旨在为生物炭对土壤微生物健康的影响及其管理提供一个全面的科学观点。图形抽象
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引用次数: 0
Synthesis of Mg–K-biochar bimetallic catalyst and its evaluation of glucose isomerization mg - k -生物炭双金属催化剂的合成及其对葡萄糖异构化的评价
IF 12.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-08 DOI: 10.1007/s42773-023-00250-w
Xiheng Kang, Zi You, Jian Peng, Arthur J. Ragauskas, Jingdong Pang, Peitao Zhao, Yongjun Yin, Xueping Song
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引用次数: 0
Biochar contributes to resistance against root rot disease by stimulating soil polyphenol oxidase 生物炭通过刺激土壤多酚氧化酶有助于抵抗根腐病
IF 12.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-07 DOI: 10.1007/s42773-023-00257-3
Shaohua Ge, Jian Gao, Dong Chang, Tianyi He, Heqing Cai, Maoxian Wang, Caibin Li, Zhenbao Luo, Yang E, Jun Meng, Mingxuan Gao
{"title":"Biochar contributes to resistance against root rot disease by stimulating soil polyphenol oxidase","authors":"Shaohua Ge, Jian Gao, Dong Chang, Tianyi He, Heqing Cai, Maoxian Wang, Caibin Li, Zhenbao Luo, Yang E, Jun Meng, Mingxuan Gao","doi":"10.1007/s42773-023-00257-3","DOIUrl":"https://doi.org/10.1007/s42773-023-00257-3","url":null,"abstract":"","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"7 1","pages":"1-17"},"PeriodicalIF":12.7,"publicationDate":"2023-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78062506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced phenol removal by permanganate with biogas residue biochar: catalytic role of in-situ formation of manganese dioxide and activation of biochar 高锰酸盐与沼气渣生物炭强化苯酚脱除:二氧化锰原位生成和生物炭活化的催化作用
IF 12.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-05 DOI: 10.1007/s42773-023-00254-6
Dongyang Li, Yi Xiao, Beidou Xi, T. Gong, Ting Zhang, Nan Huang, Wenxuan Li, Tianxue Yang
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引用次数: 0
Geo-environmental and mechanical behaviors of As(V) and Cd(II) co-contaminated soils stabilized by goethite nanoparticles modified biochar 针铁矿纳米颗粒改性生物炭稳定As(V)和Cd(II)共污染土壤的环境力学行为
IF 12.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-04 DOI: 10.1007/s42773-023-00253-7
Chen Feng, Jiang Li, Wenhao Jiang, Jindu Liu, Qiang Xue
{"title":"Geo-environmental and mechanical behaviors of As(V) and Cd(II) co-contaminated soils stabilized by goethite nanoparticles modified biochar","authors":"Chen Feng, Jiang Li, Wenhao Jiang, Jindu Liu, Qiang Xue","doi":"10.1007/s42773-023-00253-7","DOIUrl":"https://doi.org/10.1007/s42773-023-00253-7","url":null,"abstract":"","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"48 1","pages":"1-15"},"PeriodicalIF":12.7,"publicationDate":"2023-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77935369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineered biochar improves nitrogen use efficiency via stabilizing soil water-stable macroaggregates and enhancing nitrogen transformation 工程生物炭通过稳定土壤水稳性大团聚体和促进氮转化来提高氮的利用效率
IF 12.7 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-09-01 DOI: 10.1007/s42773-023-00252-8
Z. Khan, Xujian Yang, You-qiang Fu, S. Joseph, Mohammad Nauman Khan, Muhammad Ayoub Khan, I. Alam, Hong Shen
{"title":"Engineered biochar improves nitrogen use efficiency via stabilizing soil water-stable macroaggregates and enhancing nitrogen transformation","authors":"Z. Khan, Xujian Yang, You-qiang Fu, S. Joseph, Mohammad Nauman Khan, Muhammad Ayoub Khan, I. Alam, Hong Shen","doi":"10.1007/s42773-023-00252-8","DOIUrl":"https://doi.org/10.1007/s42773-023-00252-8","url":null,"abstract":"","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"111 1","pages":"1-37"},"PeriodicalIF":12.7,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79297331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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