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Learning with a purpose: a metals chemistry course centered on objects conservation 有目的的学习:一门以物体保护为中心的金属化学课程
Pub Date : 2023-05-08 DOI: 10.1515/cti-2023-0010
Madeline Hagerman, Jocelyn Alcántara-García
Abstract Corrosion is the visible result of redox reactions on multiple substrates, “rust” being the known, although this term only applies to iron and iron alloy objects. Using corrosion as a relatable example to teach redox eases this concepts’ understanding because its results are visually identifiable; both in everyday objects like door hinges, and in cultural heritage objects like cannons. This article concerns the latter class of objects, as they have the potential to engage people interested in fields that seem unrelated to chemistry. The reality is the opposite, as cultural heritage professionals assess objects used in humanities disciplines like archeology and history through the lens of science. This article discusses how conservators approach corrosion on cultural heritage objects and provides experiments for any base-knowledge and age-level students to learn about the process of corrosion and electrochemistry.
摘要腐蚀是多种基质上氧化还原反应的明显结果,“铁锈”是已知的,尽管这个术语只适用于铁和铁合金物体。使用腐蚀作为一个相关的例子来教授氧化还原简化了对这一概念的理解,因为其结果是视觉可识别的;无论是门铰链等日常用品,还是大炮等文化遗产。这篇文章涉及后一类物体,因为它们有可能吸引对与化学无关的领域感兴趣的人。事实恰恰相反,文化遗产专业人员通过科学的视角评估考古和历史等人文学科中使用的物品。本文讨论了保护器如何处理文化遗产上的腐蚀,并为任何基础知识和年龄水平的学生提供了关于腐蚀和电化学过程的实验。
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引用次数: 0
Assessing strategies for enhancing the integration of cultural practices in teaching and learning of chemistry in secondary schools 评估中学化学教学中加强文化实践整合的策略
Pub Date : 2023-03-01 DOI: 10.1515/cti-2022-0050
L. Achimugu, Ayodele Gabriel Fasanya, Ibrahim Opeyemi Abdulwaheed, Abel Okpanachi Joshua, Samuel Ibrahim, Abimaje Etimane Shaibu
Abstract The purpose of the study was to assess strategies for enhancing the integration of cultural practices into the teaching and learning of chemistry in secondary schools. The study adopted a descriptive survey research design and the population of the study comprised 19,920 respondents. Two research questions and two hypotheses guided the study. The instrument used for data collection was “Strategies Enhancing Integrating Cultural Practices Questionnaire (SEICPQ)” developed by the researchers. Mean and standard deviation were used to answer the research questions and t-test statistic was used to test the null hypotheses at 0.05 significance. The result revealed that incorporation of cultural practices into the chemistry curriculum content and adequate training of teachers on the integration of cultural practices in teaching chemistry and among others were identified as strategies that could enhance the integration of cultural practices. Non-incorporation of cultural practices into the chemistry curriculum content among others were identified as factors affecting the integration of cultural practices. The results also revealed that teachers and students do not significantly differ on their responses on strategies enhancing as well as the factors militating against the integration of cultural knowledge and practices into teaching of chemistry. Necessary conclusions were made.
摘要本研究旨在评估将文化实践融入中学化学教学的策略。该研究采用描述性调查研究设计,研究人群包括19920名受访者。两个研究问题和两个假设指导了这项研究。用于数据收集的工具是研究人员开发的“策略增强整合文化实践问卷(SEICPQ)”。平均值和标准差用于回答研究问题,t检验统计量用于检验0.05显著性的零假设。研究结果表明,将文化实践纳入化学课程内容,并就将文化实践融入化学教学等问题对教师进行充分培训,被确定为可以加强文化实践整合的策略。化学课程内容中未纳入文化实践等因素被认为是影响文化实践整合的因素。研究结果还表明,教师和学生在提高策略以及阻碍文化知识和实践融入化学教学的因素方面的反应没有显著差异。得出了必要的结论。
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引用次数: 1
Integrating expertise for teaching conservation science to cultural heritage conservation students – A closer look at radiation, colour and museum lighting topics 整合专业知识,向文物保护学生教授保护科学-深入了解辐射、色彩和博物馆照明主题
Pub Date : 2023-03-01 DOI: 10.1515/cti-2023-0001
Susana França de Sá, M. Vilarigues
Abstract Introduction to Conservation Science (ICS) is a curricular unit (CU) from the bachelor’s degree in Conservation-Restoration at NOVA School of Science and Technology. This CU was created in 2017 to fill a gap in the academic degree – the need for a bridge between fundamental sciences (1st year) and conservation-restoration diagnosis (3rd year). For this reason, ICS was designed with the main goal of teaching 2nd year students how to look at, approach and solve problems of Cultural Heritage, through the combination of reflexive thinking and object-led analysis. ICS was first designed by an expert in Conservation Science with academic background in physics. However, from the perception of the students’ struggle to understand the purpose of ICS subjects to their future professional activity, a professor with expertise in Conservation and Restoration was invited in 2019 to work together in the re-design of the CU, through an integrated approach between the two experts. ICS was then revised with the introduction of new perspectives and topics, as well as new communication routes to students. This work highlights this partnership as a good practice methodology to involve conservation-restoration students into science, focusing on the ICS classes specifically dedicated to radiation, colour, and museum lighting.
摘要保护科学导论(ICS)是NOVA科技学院保护修复学士学位的课程单元。该CU成立于2017年,旨在填补学术学位的空白——需要在基础科学(第一年)和保护修复诊断(第三年)之间架起桥梁。因此,ICS的设计主要目的是通过反射思维和对象导向分析相结合,教二年级学生如何看待、处理和解决文化遗产问题。ICS最初是由一位具有物理学学术背景的保护科学专家设计的。然而,从学生们努力理解ICS科目的目的到他们未来的专业活动,2019年,一位在保护和修复方面具有专业知识的教授被邀请通过两位专家之间的综合方法,共同进行CU的重新设计。随后对ICS进行了修订,引入了新的视角和主题,以及与学生的新沟通途径。这项工作强调了这种合作关系是一种良好的实践方法,可以让保护修复专业的学生参与科学研究,重点关注专门用于辐射、色彩和博物馆照明的ICS课程。
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引用次数: 0
Pre-service teachers’ views on chemistry of fine art materials of cultural heritage 职前教师对文化遗产美术材料化学的看法
Pub Date : 2023-03-01 DOI: 10.1515/cti-2022-0053
Robert Potočnik, Iztok Devetak
Abstract The chemistry and cultural heritage can be integrated in an interdisciplinary way into teaching the Chemistry, from primary to secondary school and university, including learning about the specifics of works of art in the context of their preservation or care. The main purpose of this study is to determine the pre-service Chemistry, Primary school, and Fine art teachers’ views about promoting an interest in the cultural heritage and Chemistry learning through materials of work of art from the chemistry perspective. The study revealed that pre-service teachers do not have sufficient knowledge and experience regarding cultural heritage from the point of view of chemistry (materials and techniques of fine art), and all groups show an interest in the mentioned contents. This integrated and interdisciplinary approach to teach Chemistry and cultural heritage is presented to the pre-service teachers as part of the general elective course that was developed on the basis of this preliminary research about pre-service teachers’ views regarding these topics.
摘要从小学到中学和大学,化学和文化遗产可以以跨学科的方式融入化学教学,包括在保存或护理艺术品的背景下学习艺术品的细节。本研究的主要目的是从化学的角度确定职前化学、小学和美术教师对通过艺术作品材料促进对文化遗产和化学学习的兴趣的看法。研究表明,从化学(美术材料和技术)的角度来看,职前教师对文化遗产没有足够的知识和经验,所有群体都对上述内容感兴趣。这种综合性和跨学科的化学和文化遗产教学方法是作为普通选修课程的一部分向职前教师介绍的,该课程是在对职前教师对这些主题的看法进行初步研究的基础上开发的。
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引用次数: 0
Studying the nomenclature of dioxins using a structure model kit based on electronic components linked with plastic tubes 使用基于与塑料管相连的电子元件的结构模型套件研究二恶英的命名
Pub Date : 2023-03-01 DOI: 10.1515/cti-2022-0051
R. Horikoshi, Dai Shirotani, H. Shioyama
Abstract Commercially available molecular models are elaborately made but generally expensive, which hinders their distribution to all classroom students. Aiming at developing an affordable molecular model, we developed a structure model kit consisting of inexpensive electronic components including transistors and colored light-emitting diodes (LEDs) with a total cost of ca. 2 USD. The structure model kit was designed for building a family of environmental pollutant molecules known as dioxins, in which transistor, white LED, red LED, and yellow LED components are used to represent sp2 carbon, hydrogen, oxygen, and chlorine atoms, respectively. Herein, we report an activity directed to nonchemistry majors studying environmental science and electronic engineering to help them gain insight into the molecular structure of dioxins using the newly developed structure model kit. The activity was well received by many students, some of whom came to understand the relationship between the structure and nomenclature of dioxins, mainly 2,3,7,8-tetrachlorinated dibenzo-p-dioxin (2,3,7,8-TCDD) and its isomers.
摘要商业上可用的分子模型是精心制作的,但通常价格昂贵,这阻碍了它们在所有课堂学生中的传播。为了开发一种负担得起的分子模型,我们开发了一种结构模型套件,由廉价的电子元件组成,包括晶体管和彩色发光二极管(LED),总成本约为2美元。该结构模型套件旨在构建一个被称为二恶英的环境污染物分子家族,其中晶体管、白色LED、红色LED和黄色LED组件分别用于表示sp2碳原子、氢原子、氧原子和氯原子。在此,我们报道了一项针对学习环境科学和电子工程的非化学专业学生的活动,以帮助他们使用新开发的结构模型试剂盒深入了解二恶英的分子结构。该活性受到了许多学生的好评,其中一些学生了解了二恶英的结构和命名之间的关系,主要是2,3,7,8-四氯二苯并对二恶英(2,3,7,8-TCDD)及其异构体。
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引用次数: 1
A simple pedagogical limiting reactant kitchenette experiment including a simple algorithm 一个简单的教学限制反应物厨房实验,包括一个简单的算法
Pub Date : 2023-03-01 DOI: 10.1515/cti-2022-0028
Khaled W. Omari, J. B. Mandumpal
Abstract Limiting reactants is a crucial factor in any reaction. Students found it a tricky topic. The current study has intended to conduct a kitchenette experiment, in which a student will follow the instructional procedure to determine a limiting reactant in a self-learning process. The study has adopted an experimental approach. A program was developed in C++ as an efficient tool to determine the limiting reactant. The major outcomes drawn from the study have enlightened the significance of a balanced equation in obtaining the correct molar ratio. It has also been noted that molar ratio similarity in a particular balanced equation can wrongly lead to an erroneous assumption.
摘要限制反应物是任何反应中的一个关键因素。学生们发现这是一个棘手的话题。目前的研究旨在进行一项小厨房实验,在该实验中,学生将遵循教学程序,在自学过程中确定限制反应物。这项研究采用了实验方法。在C++中开发了一个程序,作为确定极限反应物的有效工具。该研究得出的主要结果揭示了平衡方程在获得正确摩尔比方面的重要性。还注意到,在一个特定的平衡方程中,摩尔比的相似性可能会错误地导致错误的假设。
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引用次数: 0
Confinement of ozone hole mainly in the Antarctic stratosphere to protect the living kingdom on the earth: chemistry behind this Nature’s unique gift 限制臭氧空洞主要在南极平流层,以保护地球上的生命王国:化学背后的这个大自然的独特礼物
Pub Date : 2023-03-01 DOI: 10.1515/cti-2023-0006
Udita Das, Ankita Das, A. Das
Abstract Man-made activities can release the ozone depleting substances (ODSs) like chlorofluorocarbons (CFCs) and other halocarbons stable in atmosphere and ultimately, they migrate to the stratosphere where they can destroy the ozone layer through the XOx catalytic cycle (X = Cl, Br). The active forms in this catalytic cycle are X and XO that can be arrested in the inactive forms like XONO2 (halogen nitrate, an additive compound of two odd electron molecules XO and NO2) and HX (produced in the reaction of X with CH4) in the stratosphere to prevent the ozone depletion cycle. The catalytically active forms from these inactive species can be regenerated in the reactions on heterogeneous solid surface like polar stratospheric cloud (specially Type II PSC formed at about −85 °C). Formation of such PSC in the stratosphere is only possible in the supercooled stable Antarctic vortex produced in the prolonged winter. In fact, formation of such PSC in the stratosphere is not possible in the other regions of the earth and not even in the Arctic pole where no stable Arctic vortex is generally formed in the winter. Thus nature confines the ozone depletion reactions mainly in the stratosphere of Antarctica pole which is practically inhabited.
人为活动可以释放出在大气中稳定存在的消耗臭氧层物质(ods),如氯氟烃(CFCs)等卤代烃,最终迁移到平流层,通过XOx催化循环(X = Cl, Br)破坏臭氧层。在这个催化循环中的活性形式是X和XO,它们可以被非活性形式如XONO2(硝酸卤素,两个奇数电子分子XO和NO2的添加剂化合物)和HX (X与CH4反应产生)在平流层中阻止臭氧消耗循环。在非均相固体表面(如极地平流层云)(特别是在−85℃左右形成的II型PSC)上,这些非活性物质的催化活性形式可以再生。这种PSC在平流层的形成只有在漫长冬季产生的过冷稳定的南极涡旋中才有可能。事实上,在地球的其他地区是不可能在平流层中形成这样的PSC的,甚至在冬季通常不会形成稳定的北极涡旋的北极也不可能。因此,大自然将臭氧消耗反应主要限制在南极极点的平流层,那里实际上有人居住。
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引用次数: 0
Frontmatter 头版头条
Pub Date : 2023-03-01 DOI: 10.1515/cti-2023-frontmatter1
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引用次数: 0
Elements of Country: a First Nations-first approach to chemistry 国家元素:第一民族优先的化学方法
Pub Date : 2023-03-01 DOI: 10.1515/cti-2022-0055
A. Masters, Peta Greenfield, Cameron Davison, Janelle G. Evans, A. Motion, Jennifer Barrett, J. Troy, Kate Constantine, Lisa Rae Jackson Pulver
Abstract Collectively, we have chosen to explore an Australian First Nations-first approach to understanding the chemical elements. We believe that engagement with cultural heritage, ongoing cultures, and the knowledges of this place—the lands on which we work, live, and study—will lead to new ways of understanding the elements and change the way we practice chemistry. The “First Nations first” phrase and approach comes from understanding the unique place that Aboriginal and Torres Strait Islander peoples have in the Australian context. In this paper we explore how a First Nations-first approach could take place in Sydney on Aboriginal lands. This approach is led by Aboriginal people, engages with culture, and is produced with local knowledge holders. So far, the work has entailed two years of meeting, conversing, and sharing space to determine appropriate ways of working together, interrogating the complexities of the ideas, and to refining our approach to the work. To appreciate the significant shift that a First Nations-first approach represents for chemistry, we consider the legacy of the Periodic Table. We share some reflections on how Indigenous knowledges can contribute to an expanded chemistry curriculum through the recognition of productive cultural tension.
总的来说,我们选择了探索一种澳大利亚原住民优先的方法来理解化学元素。我们相信,与文化遗产、正在发展的文化以及对这个地方——我们工作、生活和学习的土地——的了解,将带来理解元素的新方法,并改变我们实践化学的方式。“第一民族优先”的措辞和方法源于对土著和托雷斯海峡岛民在澳大利亚环境中的独特地位的理解。在本文中,我们探讨了如何在悉尼原住民土地上采取第一民族优先的方法。这种方法由土著人民领导,与文化相结合,并与当地知识持有人一起制定。到目前为止,这项工作已经进行了两年的会议、交谈和分享空间,以确定合适的合作方式,询问想法的复杂性,并改进我们的工作方法。为了理解第一民族优先的方法对化学的重大转变,我们考虑了元素周期表的遗产。我们分享了一些关于土著知识如何通过认识到富有成效的文化张力来促进扩大化学课程的思考。
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引用次数: 0
Simple mathematical equations for calculating oxidation number of organic carbons, number of transferred electrons, oxidative ratio, and mole of oxygen molecule in combustion reactions 计算燃烧反应中有机碳氧化数、转移电子数、氧化比和氧分子摩尔数的简单数学方程
Pub Date : 2023-02-24 DOI: 10.1515/cti-2022-0020
Pong Kau Yuen, C. M. Lau
Abstract The oxidation number and number of transferred electrons are two paramount parameters in the study of redox reactions. Their calculations are both important and challenging. The oxidation number of organic carbons is used in organic chemistry, biochemistry, and applied chemistry. Combustion reaction is a classical type of redox reaction, in which the oxygen molecule (O2) is the oxidizing agent. In this article, the integration of three sets of relations is explored by using the method of balancing organic combustion: (i) number of transferred electrons and oxidation number of organic carbons, (ii) mole of oxygen molecule and number of transferred electrons, and (iii) oxidative ratio, oxidation number of organic carbons, and number of transferred electrons. This method can also establish the relationships among the stoichiometric coefficients, mole of oxygen molecule, oxidative ratio, number of transferred electrons, and oxidation number of organic carbons. Furthermore, the oxidation number of organic carbons and the number of transferred electrons of a given organic compound can be determined by the derived mathematical equations.
摘要氧化数和转移电子数是研究氧化还原反应的两个重要参数。他们的计算既重要又具有挑战性。有机碳的氧化值在有机化学、生物化学和应用化学中都有应用。燃烧反应是一种典型的氧化还原反应,其中氧分子(O2)是氧化剂。本文采用平衡有机燃烧的方法,探索了有机碳的转移电子数与氧化数、氧分子摩尔数与转移电子数、氧化比、有机碳的氧化数与转移电子数这三组关系的整合。该方法还可以建立化学计量系数、氧分子摩尔数、氧化比、转移电子数和有机碳氧化数之间的关系。此外,有机碳的氧化数和给定有机化合物的转移电子数可以由导出的数学方程确定。
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引用次数: 1
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Chemistry Teacher International : best practices in chemistry education
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