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Coaching strategies in vocational orientation for promoting young women’s self-concept and career aspirations in chemistry 职业导向指导策略促进年轻女性化学自我概念和职业抱负
Pub Date : 2021-06-10 DOI: 10.1515/cti-2021-0006
Marina Hönig, Lilith Rüschenpöhler, Julian Küsel, S. Markic
Abstract Females and students of non-dominant ethnicity are less likely to aspire to science careers. However, overcoming discrimination in science and chemistry is a challenging task, especially in vocational orientation. Thus, there is a need for strategies to support young women in their identity formation in science and chemistry. This article presents a scheme for supporting young women’s science identity formation in conversations about vocational orientation. The goal is to support young women in developing a positive attitude towards careers in chemistry. This attitude is part of cultural chemistry capital. The scheme was developed based on a study conducted as part of the project DiSenSu. Here, coachings for vocational orientation for young women in science and chemistry are provided, following the idea of Science in Public. In the coaching, the attitudes towards science and chemistry were determined using quantitative data. Based on these results, coaches conducted conversations with the participants. Qualitative analysis of 11 conversations revealed strategies coaches used to support young women in their vocational orientation. The study shows how the participants’ attitude towards careers in chemistry is used as a starting point for coachings. Also, it provides strategies that can be used to promote young women’s cultural chemistry capital.
女性和非主导种族的学生不太可能渴望科学事业。然而,克服科学和化学方面的歧视是一项具有挑战性的任务,特别是在职业定位方面。因此,有必要制定战略,支持年轻女性在科学和化学领域形成自己的身份。本文提出了一种在职业定位对话中支持年轻女性科学身份形成的方案。其目标是支持年轻女性对化学事业抱有积极的态度。这种态度是文化化学资本的一部分。该方案是根据DiSenSu项目的一部分进行的一项研究制定的。在这里,按照“公共科学”的理念,为年轻妇女提供科学和化学方面的职业指导。在指导中,使用定量数据确定学生对科学和化学的态度。根据这些结果,教练与参与者进行对话。对11次对话的定性分析揭示了教练用于支持年轻女性职业定位的策略。该研究显示了参与者对化学职业的态度如何被用作指导的起点。此外,本文还提供了促进年轻女性文化化学资本的策略。
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引用次数: 1
Development and psychometric analysis of an inventory of fundamental concepts for understanding organic reaction mechanisms 开发和心理测量分析的清单的基本概念,以了解有机反应机制
Pub Date : 2021-06-09 DOI: 10.1515/cti-2021-0009
Sachin Nedungadi, M. Mosher, S. Paek, R. Hyslop, Corina E. Brown
Abstract The fundamental concepts for organic reaction mechanisms inventory (FC-ORMI) is a multiple-choice instrument designed to assess students’ conception of fundamental concepts for understanding organic reaction mechanisms. The concepts were identified from open-ended interviews and a national survey of organic chemistry instructors reported in a previous study. This manuscript describes the development of the inventory items related to these identified concepts and the psychometric analysis of the instrument. In the developmental stage, open-ended questions were administered to first-semester organic chemistry students (N = 138), and open-ended interviews were conducted with students (N = 22) from the same pool to gain insight into their thought processes. The answers revealed alternate conceptions which were used to formulate distractors for the inventory. A pilot version and a beta version of the inventory were administered to 105 and 359 first-semester organic chemistry students, respectively. From these administrations, the 26-item alpha version was developed and administered to first-semester undergraduate organic chemistry students (N = 753). Psychometric analysis was conducted at the item and test level using Classical Test Theory and Rasch analysis. The results indicate that the items on the FC-ORMI function well to reveal students’ alternate conceptions. The instrument meets the acceptable standards of validity and reliability for concept inventories.
有机反应机制基本概念量表(FC-ORMI)是一项多项选择题,旨在评估学生对有机反应机制基本概念的理解。这些概念是从之前的一项研究中报告的开放式访谈和对有机化学教师的全国调查中确定的。这份手稿描述了与这些确定的概念和仪器的心理测量分析相关的库存项目的发展。在发展阶段,对138名第一学期有机化学学生进行开放式问题调查,并对22名学生进行开放式访谈,以了解他们的思维过程。答案揭示了用于制定清单的干扰因素的替代概念。该清单的试点版本和测试版本分别对105名和359名第一学期的有机化学学生进行了管理。从这些管理中,开发了26个项目的alpha版本,并对第一学期有机化学本科学生(N = 753)进行了管理。运用经典测试理论和Rasch分析法,在项目和测试水平上进行心理测量分析。结果表明,FC-ORMI上的项目能很好地揭示学生的备选概念。该仪器符合概念清单可接受的效度和可靠性标准。
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引用次数: 4
Application of stoichiometric hydrogen atoms for balancing organic combustion reactions 化学计量氢原子在平衡有机燃烧反应中的应用
Pub Date : 2021-06-07 DOI: 10.1515/cti-2020-0034
Pong Kau Yuen, C. M. Lau
Abstract Combustion is a common redox reaction, and organic combustion is one of the basic contents in chemistry curriculum. The transferred H-atom is commonly used as a redox indicator in organic chemistry and biochemistry. Nevertheless, the relationship between the number of transferred H-atoms and the number of transferred electrons has not been fully revealed. Oxidation number (ON) is an electron-counting concept. Without knowing the ONs, the number of transferred electrons cannot be counted and therefore, the redox reactions cannot be classified, defined, and balanced. This paper explores the new H-atom method for counting the number of transferred H-atoms. It provides a half-reaction approach to balance the overall organic combustion reactions. Only simple arithmetic procedures are needed to determine the number of transferred H-atoms and consequently the number of transferred electrons. According to this method, the mathematical formulas for assigning the number of transferred H-atoms can be deducted by balancing the general chemical formulas of organic compounds in half and overall organic combustions. Furthermore, the number of transferred electrons and their stoichiometric categories can be determined conveniently by any given organic chemical formula in organic combustion reactions.
燃烧是一种常见的氧化还原反应,有机燃烧是化学课程的基本内容之一。转移的h原子在有机化学和生物化学中常用作氧化还原指示物。然而,转移氢原子数与转移电子数之间的关系尚未完全揭示。氧化值(ON)是一个电子计数的概念。如果不知道离子,转移电子的数量就无法计算,因此,氧化还原反应就无法分类、定义和平衡。本文探讨了一种新的h原子转移数计算方法。它提供了一种半反应的方法来平衡整个有机燃烧反应。只需要简单的算术程序来确定转移的氢原子的数量,从而确定转移的电子的数量。根据这种方法,可以通过平衡有机化合物在一半和整个有机燃烧中的一般化学式来推导出分配转移h原子数的数学公式。此外,在有机燃烧反应中,转移电子的数目和它们的化学计量类别可以由任何给定的有机化学式方便地确定。
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引用次数: 4
Nano- and microgels: a review for educators 纳米和微凝胶:教育工作者综述
Pub Date : 2021-06-01 DOI: 10.1515/cti-2020-0008
D. Zhilin, A. Pich
Abstract Nano- and microgels are promising soft polymer materials for different application fields: stabilizers, sensors, catalysts, selective sorbents, drug delivery carriers etc. They are composed of cross-linked polymer chains swollen with a solvent. The building blocks, synthesis approaches and architecture of nano- and microgels are reviewed. The mechanisms of responsiveness to various stimuli are described, examples of applications are provided. Micro- and nanogels are good objects for learning projects and the ideas for learning projects with microgels are described.
摘要纳米和微凝胶是一种很有前途的软聚合物材料,用于不同的应用领域:稳定剂、传感器、催化剂、选择性吸附剂、药物递送载体等。它们由用溶剂溶胀的交联聚合物链组成。综述了纳米和微凝胶的组成部分、合成方法和结构。描述了对各种刺激的响应机制,并提供了应用实例。微凝胶和纳米凝胶是学习项目的好对象,并介绍了用微凝胶学习项目的想法。
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引用次数: 5
Size-exclusion chromatography as a useful tool for the assessment of polymer quality and determination of macromolecular properties 排粒径色谱法是评价聚合物质量和测定高分子性质的有效工具
Pub Date : 2021-06-01 DOI: 10.1515/cti-2020-0024
D. Held, P. Kilz
Abstract Polymers, macromolecules in nature and bio-polymers like proteins and antibodies are present in our every-day life and play an important role in our economy. They are obviously present as plastic products (e.g., containers, clothing, car tires) or components, e.g., as expedients in pharmaceutical formulations, additives in food and feed, stabilizers in cosmetics, used in construction materials, ceramics and are key in microchip production. Size-exclusion chromatography is the most important characterization technique for macromolecules. This review covers applications, instrumental setup, step-by-step guides for performing experiments and covers theoretical background as well as troubleshooting and tips and tricks.
聚合物、自然界中的大分子以及蛋白质和抗体等生物聚合物存在于我们的日常生活中,在我们的经济中发挥着重要作用。它们显然以塑料制品(例如,容器、服装、汽车轮胎)或部件的形式存在,例如,作为药物配方中的助剂、食品和饲料中的添加剂、化妆品中的稳定剂、用于建筑材料、陶瓷和微芯片生产中的关键。排粒径色谱法是大分子最重要的表征技术。这篇综述涵盖了应用程序,仪器设置,一步一步的指导进行实验,涵盖理论背景,以及故障排除和提示和技巧。
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引用次数: 8
Frontmatter Frontmatter
Pub Date : 2021-06-01 DOI: 10.1515/cti-2021-frontmatter2
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引用次数: 0
An understandable approach to the temperature dependence of electric properties of polymer-filler composites using elementary quantum mechanics 用基本量子力学方法研究聚合物-填料复合材料电学性能的温度依赖性
Pub Date : 2021-05-31 DOI: 10.1515/cti-2020-0014
M. Matsuo, Rong Zhang, Y. Bin
Abstract In today’s society, with a high percentage of elderly people, floor heating to ensure constant temperature and heat jackets in winter play important roles in winter to them to live comfortable lives without compromising health – except tropical zones. Under floor heating maintains a comfortable temperature in a room without polluting the air and heat jackets allow for light clothing at comfortable temperatures. The two facilities are attributed to Joule heat generated by tunnel currents between adjacent short carbon fillers in flexible polymer matrixes under low voltage. The current between adjacent conductive fillers is due to electron transfer associated with elementary quantum mechanics. Most of undergraduate students investigating polymer physics will have learned about electron transfer in relation to the temperature dependence of the conductivity of conductive filler-insulator polymer composites as well as the phenomenon of Joule heat at high school. Despite their industrial importance, most students show little interest for investigating electric properties, since most of polymers are insulation materials. Polymer scientists have carried out qualitative analyses for tunneling current using well-known simplified equations derived from complicated mathematical process formulated by solid-state physicists. Hence this paper is focused on a teaching approach for temperature dependence on electric properties of the polymer-filler composites relating to tunnel current in terms of elementary quantum mechanics. The approach also attempts to bridge education and research by including reference to the application limit of the well-known theories to such complicated composite systems that fillers are dispersed uniformly in the polymer matrix.
摘要在当今社会,老年人比例很高,确保恒温的地暖和冬季保暖夹克在冬季对他们在不影响健康的情况下过上舒适的生活起着重要作用——热带地区除外。地板下供暖可以在不污染空气的情况下保持房间内舒适的温度,保暖夹克可以在舒适的温度下穿着轻便的衣服。这两种设施归因于柔性聚合物基体中相邻短碳填料之间的隧道电流在低电压下产生的焦耳热。相邻导电填料之间的电流是由于与基本量子力学相关的电子转移。大多数研究聚合物物理学的本科生在高中时都会了解到电子转移与导电填料-绝缘体-聚合物复合材料电导率的温度依赖性以及焦耳热现象有关。尽管聚合物在工业上很重要,但大多数学生对研究电性能几乎没有兴趣,因为大多数聚合物都是绝缘材料。聚合物科学家已经使用众所周知的简化方程对隧道电流进行了定性分析,这些方程源自固态物理学家制定的复杂数学过程。因此,本文从基本量子力学的角度,重点研究了与隧道电流相关的聚合物-填料复合材料电学性能的温度依赖性的教学方法。该方法还试图通过参考众所周知的理论对填料均匀分散在聚合物基体中的复杂复合材料系统的应用极限,来连接教育和研究。
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引用次数: 0
Basics of teaching electrochemical impedance spectroscopy of electrolytes for ion-rechargeable batteries – part 2: dielectric response of (non-) polymer electrolytes 离子可再充电电池电解质电化学阻抗谱教学基础第2部分:(非)聚合物电解质的介电响应
Pub Date : 2021-05-27 DOI: 10.1515/cti-2020-0018
Suhaila Idayu Abdul Halim, C. Chan, J. Apotheker
Abstract In the Part 2 of this article, we present the phenomenological response of the dielectric relaxation for polymer electrolytes monitored by electrochemical impedance spectroscopy (EIS) in terms of electrochemical point of view, such as impedance (Z*), permittivity (ε*), loss tangent (tan δ), modulus (M*) and conductivity (σ*) spectra. It is noteworthy to note that all the electrochemical aspects mentioned are of interest for conduction and seen as closely related to each other indirectly or directly. Two different systems; solid polymer electrolyte (SPE) [poly(ethylene oxide) (PEO) + lithium perchlorate (LiClO4)] and non-SPE [poly(methyl acrylate) (PMA) + LiClO4] were employed for discussion. EIS is a powerful technique to characterize the electrical properties of polymer electrolytes. The results suggest that impedance and modulus are of interest for decoupling of dielectric and electric properties by evaluating the short-range and long-range mobility of the charged entities, respectively. One is able to identify the conduction mechanism of the polymer electrolytes easily if the responses are well understood. The objective of this article to introduce a simplified yet an insightful background and technique that is easy to be followed and useful for educational purposes especially for beginners or young researchers for both undergraduates and postgraduates.
摘要在本文的第二部分中,我们从电化学的角度,如阻抗(Z*)、介电常数(ε*)、损耗角正切(tanδ)、模量(M*)和电导率(σ*)谱,介绍了电化学阻抗谱(EIS)监测的聚合物电解质介电弛豫的唯象响应。值得注意的是,所提到的所有电化学方面都对传导感兴趣,并且被视为彼此间接或直接密切相关。两个不同的系统;采用固体聚合物电解质(SPE)[聚环氧乙烷(PEO)+高氯酸锂(LiClO4)]和非SPE[聚丙烯酸甲酯(PMA)+LiClO4]进行讨论。EIS是表征聚合物电解质电性能的一种强大技术。结果表明,通过分别评估带电实体的短程和长程迁移率,阻抗和模量对于介电和电学性质的去耦是有意义的。如果很好地理解响应,就能够容易地识别聚合物电解质的传导机制。本文的目的是介绍一个简单而有见地的背景和技术,该背景和技术易于遵循,对教育目的有用,尤其是对本科生和研究生的初学者或年轻研究人员。
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引用次数: 5
Creating confidence in chemistry among students using ‘unboiling’ versus ‘unfrying’ of an egg: seasoning a food-science workshop with inquisitiveness, experimentation and research-dependent applications 用“不煮鸡蛋”和“不煎鸡蛋”来培养学生对化学的信心:用好奇、实验和依赖研究的应用来调味食品科学研讨会
Pub Date : 2021-05-27 DOI: 10.1515/cti-2021-0003
Aditi Ghose
Abstract The announcement of the rare feat of ‘unboiling an egg’ in 2015 by biochemists from University of California, Irvine and Australia was more than just a chemistry demonstration. Pulling apart tangled proteins and allowing them to refold, the new technique not only prevented ‘misfolding’, thus also eliminating the chances for formation of useless products, but also speeded up the process by a factor of thousands. This technology promised transforming industrial and research production of proteins – affecting cheese flavouring and cancer treatment alike. A survey of 50 odd students in 2020, willing to enroll for an online Food-Science Workshop revealed, 72% did not believe that such an act like ‘unboiling an egg’ was possible, leave alone its being prevalent and essential. Delving into the nuances of this ‘egg-unboiling’ technology whilst contrasting it with ‘egg-unfrying’, our Workshop Incredible Edibles introduced sustainable-science in the guise of food-science. It is how lysozyme, urea, along with Maillard reaction, amino acids and sugars came together in the discussions that determined the gentle transition of these non-believers to hard-core fanatics of chemistry −76% participants admitted to having “discovered a whole new way to look at food” in the post-session survey. This article shall elucidate these results.
2015年,来自加州大学欧文分校和澳大利亚的生化学家宣布了一项罕见的“将鸡蛋煮开”的壮举,这不仅仅是一次化学演示。这项新技术将缠绕在一起的蛋白质分开,让它们重新折叠,不仅防止了“错误折叠”,从而消除了无用产物形成的机会,而且还将这一过程加快了数千倍。这项技术有望改变蛋白质的工业和研究生产,影响奶酪调味和癌症治疗。2020年,一项针对50多名愿意参加在线食品科学研讨会的学生的调查显示,72%的人不相信“生鸡蛋”这样的行为是可能的,更不用说它是普遍和必要的了。深入研究这种“生蛋”技术的细微差别,同时将其与“生蛋”技术进行对比,我们的“不可思议的食物工作坊”以食品科学的名义介绍了可持续科学。正是溶菌酶、尿素、美拉德反应、氨基酸和糖在讨论中一起出现,决定了这些不相信化学的人慢慢转变为化学的铁杆狂热者——76%的参与者在会后的调查中承认,他们“发现了一种看待食物的全新方式”。本文将阐明这些结果。
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引用次数: 0
How do pre-service chemistry teachers rate the importance of content in organic chemistry during their chemistry studies at university? 在大学化学学习期间,职前化学教师如何评价有机化学内容的重要性?
Pub Date : 2021-05-06 DOI: 10.1515/cti-2021-0004
J. Hermanns
Abstract In this article a cross-sectional study on the students’ rating with regard to the contents in organic chemistry will be discussed. Pre-service teachers rated the contents with a questionnaire during their bachelor or master studies. It was shown that the pre-service chemistry teachers during their master studies rated the content as more important than the bachelor students. One possible explanation can be that the master students have teaching experience due to their internships at school whereas the bachelor students can only rely on their experience from their own school days. Overall, content belonging to the school curriculum in the federal state “Brandenburg” where the pre-service teachers’ university is located was rated better than content that was not a part of this curriculum. Concepts were not rated significantly better than the content. Because of the importance of conceptual knowledge for the future profession as a teacher, the courses in organic chemistry will be redesigned with a clear focus on concepts.
摘要本文将对学生对有机化学内容的评分进行横断面研究。职前教师在学士或硕士学习期间用问卷对内容进行评分。研究表明,职前化学教师在硕士研究生学习期间认为该内容比学士生更重要。一种可能的解释是,硕士生由于在学校实习而有教学经验,而学士生只能依靠自己上学时的经验。总体而言,属于职前师范大学所在的联邦州“勃兰登堡”学校课程的内容比不属于该课程的内容被评为更好。概念的评分并没有明显好于内容。由于概念知识对未来教师职业的重要性,有机化学课程将重新设计,明确关注概念。
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引用次数: 5
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Chemistry Teacher International : best practices in chemistry education
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