This study aims to determine the effects of deposition time on the phase and structure of FeCoNi. FeCoNi was prepared by electrodeposition method at room temperature. X-ray diffraction measurement shows the formation of a single phase of FeCoNi at 5 and 10 minutes of deposition, while at 20, 35, and 50 minutes, a new phase was formed, namely CoNi. The obtained FeCoNi and CoNi show a crystal plane at 2θ = 44.05° (111); 51.33° (002); and 75.59° (022) in all different deposition times, indicating the face centered cubic crystal structure. The effect of deposition time on the chemicals composition shows an anomalous co-deposition because Fe has a larger ratio than Co and Ni. The deposition rate and the value of current efficiency were found to be optimum at FeCoNi synthesized for 20 minutes, namely 0.00214 mg/cm2s and 97.00%.
{"title":"The Effects of Deposition Time on Phase and Structure of FeCoNi Films","authors":"Muhamad Mulyadi, Afrizal","doi":"10.56425/cma.v1i2.23","DOIUrl":"https://doi.org/10.56425/cma.v1i2.23","url":null,"abstract":"This study aims to determine the effects of deposition time on the phase and structure of FeCoNi. FeCoNi was prepared by electrodeposition method at room temperature. X-ray diffraction measurement shows the formation of a single phase of FeCoNi at 5 and 10 minutes of deposition, while at 20, 35, and 50 minutes, a new phase was formed, namely CoNi. The obtained FeCoNi and CoNi show a crystal plane at 2θ = 44.05° (111); 51.33° (002); and 75.59° (022) in all different deposition times, indicating the face centered cubic crystal structure. The effect of deposition time on the chemicals composition shows an anomalous co-deposition because Fe has a larger ratio than Co and Ni. The deposition rate and the value of current efficiency were found to be optimum at FeCoNi synthesized for 20 minutes, namely 0.00214 mg/cm2s and 97.00%.","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"36 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84225564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Salma Fitri Annisa, Zulmanelis Darwis, T. Hadinugrahaningsih
This study aims to determine the effect of the addition of tertiary butylhydroquinone (TBHQ) antioxidants on the quality of biodiesel. Rubber seed biodiesel is synthesized through esterification and transesterification reactions, then biodiesel is characterized by different stages of adding TBHQ antioxidants before the esterification reaction and after the transesterification reaction. The usage of TBHQ antioxidants at the various stages of adding the process greatly affects the quality of biodiesel. The results showed that the addition of TBHQ 1000 ppm after transesterification was the most effective in slowing oxidative degradation by showing the lowest characteristics (acid number 0.64 mg KOH/g and peroxide value 33.91 meq O2/kg) for 3 weeks. All rubber seed biodiesel samples had kinematic density and viscosity according to the Indonesian National Standard (SNI) for 3 weeks except for the acid number only lasted 0 weeks.
{"title":"The Effect of Tertiary Butylhydroquinone Antioxidant on The Stability of Rubber Seed Biodiesel","authors":"Salma Fitri Annisa, Zulmanelis Darwis, T. Hadinugrahaningsih","doi":"10.56425/cma.v1i2.26","DOIUrl":"https://doi.org/10.56425/cma.v1i2.26","url":null,"abstract":"This study aims to determine the effect of the addition of tertiary butylhydroquinone (TBHQ) antioxidants on the quality of biodiesel. Rubber seed biodiesel is synthesized through esterification and transesterification reactions, then biodiesel is characterized by different stages of adding TBHQ antioxidants before the esterification reaction and after the transesterification reaction. The usage of TBHQ antioxidants at the various stages of adding the process greatly affects the quality of biodiesel. The results showed that the addition of TBHQ 1000 ppm after transesterification was the most effective in slowing oxidative degradation by showing the lowest characteristics (acid number 0.64 mg KOH/g and peroxide value 33.91 meq O2/kg) for 3 weeks. All rubber seed biodiesel samples had kinematic density and viscosity according to the Indonesian National Standard (SNI) for 3 weeks except for the acid number only lasted 0 weeks.","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"9 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91474823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This research was conducted to develop a green synthesis method for zero valent iron (ZVI) preparation. The ZVI was synthesized by reacting FeCl2 with polyphenols extracted from kepok banana peels. This polyphenol extraction process was carried out using three different solvents, namely: water, chloroform, and ethyl acetate. Gas chromatography mass spectroscopy test showed three main phenolic compounds contained in the banana peel extract, namely: 2-methoxy-4-vinylphenol, 4-methoxy-2-vinylphenol, and 2-methoxy-5-vinylphenol. The optimum composition of FeCl2 and polyphenol was 3:2. Fourier transform infra red spectroscopy data confirmed that the synthesized ZVI contains organic compounds having –OH and C=O groups which are assumed to be capping agents that can maintain stability. This has also been supported by the results of the energy dispersive X-ray analysis where there are carbon atoms (C) and oxygen atoms (O) in ZVI. The ZVI particle size was uneven and form a compact solid. The largest particle size distribution of ZVI is in the range of 234.49 nm - 407.49 nm with the average size of ZVI beings 616.26 nm. The results of the XRD analysis have also confirmed the formation of a simple cubic ZVI with fine crystallite size of ca 26.64 nm.
{"title":"Synthesis and Characterization of Zero Valent Iron Prepared Using Green Synthesis Method","authors":"Devi Indrawati Syafei, Sahid Hidayat, Yusmaniar","doi":"10.56425/cma.v1i2.24","DOIUrl":"https://doi.org/10.56425/cma.v1i2.24","url":null,"abstract":"This research was conducted to develop a green synthesis method for zero valent iron (ZVI) preparation. The ZVI was synthesized by reacting FeCl2 with polyphenols extracted from kepok banana peels. This polyphenol extraction process was carried out using three different solvents, namely: water, chloroform, and ethyl acetate. Gas chromatography mass spectroscopy test showed three main phenolic compounds contained in the banana peel extract, namely: 2-methoxy-4-vinylphenol, 4-methoxy-2-vinylphenol, and 2-methoxy-5-vinylphenol. The optimum composition of FeCl2 and polyphenol was 3:2. Fourier transform infra red spectroscopy data confirmed that the synthesized ZVI contains organic compounds having –OH and C=O groups which are assumed to be capping agents that can maintain stability. This has also been supported by the results of the energy dispersive X-ray analysis where there are carbon atoms (C) and oxygen atoms (O) in ZVI. The ZVI particle size was uneven and form a compact solid. The largest particle size distribution of ZVI is in the range of 234.49 nm - 407.49 nm with the average size of ZVI beings 616.26 nm. The results of the XRD analysis have also confirmed the formation of a simple cubic ZVI with fine crystallite size of ca 26.64 nm.","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"255 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78213775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Evaluating the Effect of Plants Extracts Against Varroa Mites (Varroa Destructors) of Honeybees (Apis Mellifera)","authors":"","doi":"10.7176/cmr/14-2-03","DOIUrl":"https://doi.org/10.7176/cmr/14-2-03","url":null,"abstract":"","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87325451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis, In vitro Biological Studies of novel Homoleptic Ni(II) and Zn(II) Complexes of Thiosemicarbazide Derivative ligand","authors":"","doi":"10.7176/cmr/14-2-02","DOIUrl":"https://doi.org/10.7176/cmr/14-2-02","url":null,"abstract":"","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"24 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81816935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Potassium Status of Soils under Three Different Parent Materials of the Oil palm (Elaeis guineensis Jacq)","authors":"","doi":"10.7176/cmr/14-2-01","DOIUrl":"https://doi.org/10.7176/cmr/14-2-01","url":null,"abstract":"","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85271530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Integrating Nanoscience/Nanotechnology Advances in ICT and Chemistry into the Secondary School Curriculum in Rivers State","authors":"","doi":"10.7176/cmr/14-2-04","DOIUrl":"https://doi.org/10.7176/cmr/14-2-04","url":null,"abstract":"","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"49 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78258445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In Mozambique, the task of providing infrastructural facilities for the rapidly growing population is enormous. Although the country has unique characteristics that present opportunities for timber construction to thrive, concrete continues to be one of the most used materials in modern construction. However, the concrete industry has a considerable impact on the environment due to production and the raw material consumed. Among the constituents of concrete, sand has been the one in which its exploitation causes the most damage to the environment. An alternative to solve this problem would be the use of fine sandy loam aggregate in the production of concrete. Thus, this research presents the study of the technical feasibility of using fine sandy loam aggregate in the production of concrete. The main study variables were the consistency and mechanical strength of concrete compression. For the production of concrete, two types of gravel of ¾ were used, sandy loam soil, sandy soil and Portland cement. Specimens were manufactured for 4 different mixes, with a reference mix containing cement, sand, gravel and water. To evaluate the performance of the mixes, tests of mechanical resistance to compression were carried out at 7, 14, 21 and 28 days of age. After determining the main physical and mechanical characteristics, promising results were obtained for the mixtures with 25% and 50% substitution, where the axial compressive strength test reached 26.3 MPa and 27 MPa, above the reference mixture of 25.6 MPa. The 100% mix of alternative soil reached an average strength of 25.2 MPa. This same mixture, although having low mechanical strength, has greater consistency, with a slump of ±10 cm.
{"title":"Technical Feasibility of the Use of Sandy Loam Soils in Concrete","authors":"A. Conrado, E. Miguel, L. Cristóvão","doi":"10.7176/cmr/14-1-02","DOIUrl":"https://doi.org/10.7176/cmr/14-1-02","url":null,"abstract":"In Mozambique, the task of providing infrastructural facilities for the rapidly growing population is enormous. Although the country has unique characteristics that present opportunities for timber construction to thrive, concrete continues to be one of the most used materials in modern construction. However, the concrete industry has a considerable impact on the environment due to production and the raw material consumed. Among the constituents of concrete, sand has been the one in which its exploitation causes the most damage to the environment. An alternative to solve this problem would be the use of fine sandy loam aggregate in the production of concrete. Thus, this research presents the study of the technical feasibility of using fine sandy loam aggregate in the production of concrete. The main study variables were the consistency and mechanical strength of concrete compression. For the production of concrete, two types of gravel of ¾ were used, sandy loam soil, sandy soil and Portland cement. Specimens were manufactured for 4 different mixes, with a reference mix containing cement, sand, gravel and water. To evaluate the performance of the mixes, tests of mechanical resistance to compression were carried out at 7, 14, 21 and 28 days of age. After determining the main physical and mechanical characteristics, promising results were obtained for the mixtures with 25% and 50% substitution, where the axial compressive strength test reached 26.3 MPa and 27 MPa, above the reference mixture of 25.6 MPa. The 100% mix of alternative soil reached an average strength of 25.2 MPa. This same mixture, although having low mechanical strength, has greater consistency, with a slump of ±10 cm.","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"25 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88269582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Complex from Nickel(II) salt and 2-imino-3-(2-hydroxy phenyl)-1-thiazolidin-4-one and Study of its Structure and Antimicrobial activity","authors":"","doi":"10.7176/cmr/14-1-01","DOIUrl":"https://doi.org/10.7176/cmr/14-1-01","url":null,"abstract":"","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"72 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80534160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, CFs were coated electrochemically with three different monomers (An, EDOT or Py) in different condition such as electrolyte (BA, H 2 S0 4 or NaClO 4 ), solvent (H 2 O as inorganic medium or ACN as organic medium), in presence of foreign material (EBC) and coating method (constant potential and cyclic voltammetry as controlled potential). Obtained CFs were compared with regard to electrical and capacitive and morphological features. In CPE the current flown in system was changed in certain values for each monomer in presence of EBC. But this changing was more for Py than that for the other. In CV experiments, the oxidation potential was increased for PAn and PEDOT when it was decreased for Py. Imax values were changed for each polymer and conditions. According to Randles-Sevcik equation, the electrocoating redox processes in BA-H 2 O were not controlled by diffusion under this conditions. But, all the redox processes carried out in NaClO 4 -ACN electrolyte solution were controlled by diffusion for each polymer coated CFs. In presence of EBC it could be concluded that redox process was controlled by diffusion in BA-H 2 O for PAn and in NaClO 4 -ACN for PEDOT. µF; to 1 µF from 3 µF in BA-H 2 O for Pan, PEDOT and PPy respectively. But, it was increased to 11.5 µF from 10.4 µF in NaClO 4 -ACN for PEDOT. Phase angle was in the same trend. The texture coatings were more compact in the presence of EBC in electrolyte solution than that of the absence of EBC for PPy coated CF. The relationship of between the radius of coating and the C DL of the coated CF was proportional. Thus, it may be concluded that the C DL and radius of coating were affected with the presence of different material/compound in electrolyte solution.
{"title":"The Effect of Electrolyte Ingredients on Electrolyte-Electrode Interface in Electrocoating: A Comparative Study","authors":"H. Dolaş, Keziban Huner, A. Sarac","doi":"10.7176/cmr/13-3-05","DOIUrl":"https://doi.org/10.7176/cmr/13-3-05","url":null,"abstract":"In this study, CFs were coated electrochemically with three different monomers (An, EDOT or Py) in different condition such as electrolyte (BA, H 2 S0 4 or NaClO 4 ), solvent (H 2 O as inorganic medium or ACN as organic medium), in presence of foreign material (EBC) and coating method (constant potential and cyclic voltammetry as controlled potential). Obtained CFs were compared with regard to electrical and capacitive and morphological features. In CPE the current flown in system was changed in certain values for each monomer in presence of EBC. But this changing was more for Py than that for the other. In CV experiments, the oxidation potential was increased for PAn and PEDOT when it was decreased for Py. Imax values were changed for each polymer and conditions. According to Randles-Sevcik equation, the electrocoating redox processes in BA-H 2 O were not controlled by diffusion under this conditions. But, all the redox processes carried out in NaClO 4 -ACN electrolyte solution were controlled by diffusion for each polymer coated CFs. In presence of EBC it could be concluded that redox process was controlled by diffusion in BA-H 2 O for PAn and in NaClO 4 -ACN for PEDOT. µF; to 1 µF from 3 µF in BA-H 2 O for Pan, PEDOT and PPy respectively. But, it was increased to 11.5 µF from 10.4 µF in NaClO 4 -ACN for PEDOT. Phase angle was in the same trend. The texture coatings were more compact in the presence of EBC in electrolyte solution than that of the absence of EBC for PPy coated CF. The relationship of between the radius of coating and the C DL of the coated CF was proportional. Thus, it may be concluded that the C DL and radius of coating were affected with the presence of different material/compound in electrolyte solution.","PeriodicalId":9724,"journal":{"name":"chemistry and materials research","volume":"101 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80438713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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