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Prediction of Cement Compressive Strength by Combining Dynamic Models of Neural Networks 结合神经网络动态模型预测水泥抗压强度
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2021.1952
D. Tsamatsoulis
This study aimed at developing models predicting cement strength based on shallow neural networks (ANN) using exclusively industrial data. The models used physical, chemical, and early strength results to forecast those for 28and 7-day. Neural networks were trained dynamically for a movable period and then used for a future period of at least one day. The study includes nine types of activation functions. The algorithms use the root mean square errors of testing sets (RMSEFuture) and their robustness as optimization criteria. The RMSEFuture of the best models with optimum ANNs was in the range of 1.36 MPa to 1.63 MPa, which is near or within the area of long-term repeatability of a very competent laboratory. Continuous application of the models in actual conditions of a cement plant in the long-term showed a performance at least equivalent to that calculated during the design step.
本研究旨在开发基于浅层神经网络(ANN)的水泥强度预测模型,该模型仅使用工业数据。模型使用物理、化学和早期强度结果来预测28天和7天的强度。神经网络在一个可移动的时间段内进行动态训练,然后用于至少一天的未来时间段。该研究包括九种类型的激活函数。该算法使用测试集的均方根误差(RMSEFuture)及其鲁棒性作为优化准则。采用最优人工神经网络的最佳模型的RMSEFuture在1.36 ~ 1.63 MPa之间,接近或在一个非常有能力的实验室的长期可重复性范围内。该模型在某水泥厂实际条件下的长期连续应用表明,其性能至少与设计阶段的计算结果相当。
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引用次数: 3
Extraction of the Volatile Oils of Dictyopteris membranacea Batters 1902 by Focused Microwave-assisted Hydrodistillation and Supercritical Carbon Dioxide: Empirical Kinetic Modelling Approach, Apparent Solubility and Rate Constants 聚焦微波辅助加氢蒸馏和超临界二氧化碳萃取1902膜齿苋挥发油的实验动力学模型、表观溶解度和速率常数
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2020.1885
Nacera Riad, N. Bouzidi, Mohamed Reda Zahi, O. Touafek, Y. Daghbouche, L. Piovetti, M. El Hattab
Supercritical carbon dioxide extraction (SCCO2) and focused microwave-assisted hydrodistillation (FMAHD) were used comparatively to isolate the volatile oils of the brown alga Dictyopteris membranacea from the crude ether extract. The volatiles fractions were analysed by GC/MS, the major compounds were: dictyopterene A, 6-butyl 1,4-cycloheptadiene, 1-undecen-3-one, 1,4-undecadien-3-one, (3-oxoundec-4-enyl) sulphur, tetradecanoic acid, hexadecanoic acid, 3-hexyl-4,5-dithiacycloheptanone, and albicanol. A kinetics study of the extraction of the volatile fractions obtained by the two processes was carried out, an external calibration allowed to quantify the content of the main metabolites. Empirical models were applied to adjust the experimental kinetics values but also to determine the values of apparent solubilities for SCCO2 and the rate constants for FMAHD. The results obtained revealed that the SCCO2 process was characterized by the coexistence of three distinct phases. For FMAHD, the extraction mechanism included two steps.
采用超临界二氧化碳萃取法(SCCO2)和聚焦微波辅助加氢蒸馏法(FMAHD)从粗乙醚提取物中分离褐藻膜齿藻挥发油。通过GC/MS分析挥发物组分,主要化合物为:dictyopterene A、6-丁基1,4-环庚二烯、1-十一碳烯-3-酮、1,4-十一碳二烯-3-酮、(3-氧代十一碳烯-4-烯基)硫、十四烷酸、十六烷酸、3-己基-4,5-二二环庚酮和albicanol。对通过两种工艺获得的挥发性组分的提取进行了动力学研究,允许进行外部校准以量化主要代谢物的含量。应用经验模型调整实验动力学值,同时确定SCCO2的表观溶解度值和FMAHD的速率常数。所获得的结果表明,SCCO2过程的特征是三个不同相共存。对于FMAHD,提取机制包括两个步骤。
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引用次数: 1
Enhanced Removal Efficiency of Arsenic and Copper from Aqueous Solution Using Activated Acorus calamus Based Adsorbent 活化菖蒲基吸附剂提高对水溶液中砷和铜的去除效果
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2021.1943
Anita E. Chand, P. Chand, Gopal Gautam Khatri, Dasu Ram Paudel
Water security, due to heavy metal pollution in water resources, has become a serious problem in modern urbanized society. Plants with a good source of cellulose, hemicellulose, pectin, lignin, etc., are the most promising adsorbents for the removal of heavy metals from water. In this work, for the first time, a low-cost local plant named Acorus calamus (AC; flag root or sweet flag) and citric acid modified AC root powder (CAMAC) were used as potential adsorbents. The samples were characterized by SEM, FT-IR, XRD, and the sorption properties were investigated by different parameters, such as solution pH, batch kinetic study, batch isotherm, effect of adsorbent dose, effect of initial concentration, and effect of contact time. The results of ACRP on removal efficiency of copper (II) and arsenic (III) in an aqueous solution showed an excellent adsorption behavior (~ 80 % adsorption efficiency). This study opens up an easy and economical method for the decontamination of harsh polluting metal ions from water.
由于水资源中的重金属污染,水安全已成为现代城市化社会的一个严重问题。植物具有良好的纤维素、半纤维素、果胶、木质素等来源,是最有前途的去除水中重金属的吸附剂。在这项工作中,首次使用一种名为菖蒲(AC;旗根或甜旗)的低成本本地植物和柠檬酸改性的AC根粉(CAMAC)作为潜在的吸附剂。用SEM、FT-IR、XRD对样品进行了表征,并通过溶液pH、间歇动力学研究、间歇等温线、吸附剂用量的影响、初始浓度的影响和接触时间的影响等不同参数研究了样品的吸附性能。ACRP对水溶液中铜(II)和砷(III)的去除效率的结果显示出优异的吸附行为(~80%的吸附效率)。这项研究为去除水中污染严重的金属离子开辟了一种简单、经济的方法。
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引用次数: 3
Cu(II)-metalated Silica-based Inorganic-Organic Hybrid: Synthesis, Characterization and Its Evaluation for Dye Degradation and Oxidation of Organic Substrates Cu(II)-金属化二氧化硅基无机-有机杂化物的合成、表征及其对有机基质染料降解和氧化的评价
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2020.1906
Amreen Naz, S. Arun, Ruby Kumari, S. Narvi, M. Siraj Alam
A. Naz,a S. Arun,b R. Kumari,a S. S. Narvi,a and M. S. Alamc,* aDepartment of Chemistry, Motilal Nehru National Institute of Technology Allahabad, Prayagraj, Uttar Pradesh, India-211004 bDepartment of Chemistry, Dr. Shakuntala Misra National Rehabilitation University, Lucknow, Uttar Pradesh, India-226017 cDepartment of Chemical Engineering, Motilal Nehru National Institute of Technology Allahabad, Prayagraj, Uttar Pradesh, India-211004
A.Naz,A S.Arun,b R.Kumari,A S.S.Narvi,A和M.S.Alamc,*A化学系,Motilal Nehru国家理工学院Allahabad,Prayagraj,Uttar Pradesh,India-21004 b化学系,Shakuntala Misra国立康复大学博士,Lucknow,UttarPradesh,印度北方邦Prayagraj-211004
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引用次数: 1
Anaerobic Fermentation of Substrate with High Nitrogen Content 高含氮底物厌氧发酵研究
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2021.1945
Nikolas Gróf, M. Hutňan
This work focuses on anaerobic fermentation of synthetic substrate with high nitrogen content. An anaerobic continuously stirred tank reactor was gradually loaded with synthetic substrate, and the first inhibition was observed on day 110 when the SBP decreased by 20 %. Another significant change was observed on day 135, when SBP dropped to 122 L kg–1 COD. At the same time, a gas washing bottle with hydrochloric acid was connected to capture ammonia from recirculated biogas. With this arrangement, a slight increase in the SBP production to 150 L kg–1 COD was observed. On day 164, the gas washing bottle was changed to two gas washing bottles with fritted discs. After ten days, a significant increase in SBP, to 320 L kg–1 COD, was observed, indicating that the system began to overcome inhibition. From these results, it can be concluded that this method is effective in mitigating ammonia inhibition.
本文主要研究了高含氮合成底物的厌氧发酵。在厌氧连续搅拌槽反应器中逐渐加载合成底物,在第110天观察到第一次抑制作用,SBP下降了20%。第135天,收缩压降至122 L kg-1 COD。同时,连接一个装有盐酸的气体洗涤瓶,从循环沼气中捕获氨。通过这种安排,观察到SBP产量略有增加,达到150 L kg-1 COD。在第164天,将气体洗涤瓶改为两个带熔盘的气体洗涤瓶。10天后,观察到收缩压显著增加,达到320 L kg-1 COD,表明系统开始克服抑制。从这些结果可以看出,该方法可以有效地减轻氨抑制。
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引用次数: 1
A Novel Integration of CWPO Process with Fe3O4@C and Sonication for Oxidative Degradation of 4-Chlorophenol CWPO工艺与Fe3O4@C和超声氧化降解4-氯苯酚
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2021.1929
M. Astaraki, Farham Aminsharee, S. Jorfi, R. D. C. Soltani, Mojtaba Nasr Esfihani
M. Astaraki,a,b F. Aminsharei,b,c* S. Jorfi,a,d* R. Darvishi Cheshmeh Soltani,a,e and M. Nasr-Esfahanif aDepartment of Chemical Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran bHuman Environment and Sustainable Development Research Center, Najafabad Branch, Islamic Azad University, Najafabad cDepartment of Safety, Health and Environment, Najafabad Branch, Islamic Azad University, Najafabad, Iran dEnvironmental Technologies Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran eDepartment of Environmental Health Engineering, School of Health, Arak University of Medical Sciences, Arak, Iran fDepartment of Chemistry, Najafabad Branch, Islamic Azad University, Najafabad, Iran
M. Astaraki,a,b . F. Aminsharei,b,c* S. Jorfi,a,d* R. Darvishi Cheshmeh Soltani,a,e and M. Nasr-Esfahanif a伊斯兰阿扎德大学纳贾巴德分校化学工程系,伊朗纳贾巴德b伊斯兰阿扎德大学纳贾巴德分校人类环境与可持续发展研究中心,伊朗纳贾巴德c伊斯兰阿扎德大学纳贾巴德分校安全、健康与环境系,伊朗纳贾巴德环境技术研究中心,伊朗纳贾巴德伊朗阿拉克医科大学卫生学院环境卫生工程系伊朗阿拉克阿拉克伊斯兰阿扎德大学纳贾法巴德分校化学系伊朗纳贾法巴德
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引用次数: 0
Modeling and Multi-objective Optimization of a Packed Bed Reactor for Sulfur Dioxide Removal by Magnesium Oxide Using Non-dominated Sorting Genetic Algorithm II 基于非支配排序遗传算法Ⅱ的填充床氧化镁脱硫反应器建模及多目标优化
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-10-20 DOI: 10.15255/cabeq.2021.1913
A. B. Ani, H. Ale Ebrahim
Nowadays, protecting the environment is of utmost importance worldwide, and sulfur dioxide is one of the main pollutants in the atmosphere. This work proposes a new method for simultaneous SO2 removal by MgO, and production of magnesium sulfate in a packed bed reactor for which breakthrough curves have been obtained. Furthermore, the effect of important operating parameters, including temperature, SO2 concentration, and gaseous flow rate was investigated. Experiments showed that increasing the temperature improved the breakthrough lifetime, but the increase in concentration and flow rate reduced the lifetime. The experimental results were predicted successfully by applying the Random Pore Model (RPM). Finally, the Non-dominated Sorting Genetic Algorithm II (NSGA II) that is a technique for multi-objective optimization, was employed to determine the best operating parameters for SO2 removal by magnesium oxide in the packed bed reactor.
如今,保护环境在全世界都是至关重要的,而二氧化硫是大气中的主要污染物之一。本文提出了一种在填充床反应器中MgO同时脱除SO2和生产硫酸镁的新方法,并获得了突破曲线。此外,还考察了温度、SO2浓度和气体流量等重要操作参数的影响。实验结果表明,温度的升高提高了突破寿命,但浓度和流量的增加降低了突破寿命。采用随机孔隙模型(RPM)对实验结果进行了预测。最后,采用多目标优化技术非支配排序遗传算法II (NSGA II)确定填料床反应器中氧化镁脱除SO2的最佳运行参数。
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引用次数: 1
Vicia faba Crop Residues for Sustainable Electricity Generation Using a Sludge-based Microbial Fuel Cell 利用污泥基微生物燃料电池可持续发电的蚕豆作物残留物
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-02-01 DOI: 10.15255/CABEQ.2020.1857
Leonard Javier Mamani-Asqui, Lucero Nataly Peredo-Berlanga, Francisco Javier Roque Rodríguez, Giancarlo Richard Salazar Banda
L. J. Mamani-Asqui,a L. N. Peredo-Berlanga,a F. J. Roque Rodríguez,a,b and G. R. Salazar-Bandac,d,* aAcademic Department of Chemical Engineering, Universidad Nacional de San Agustín de Arequipa, Arequipa 0401, Perú bPostgraduate Unit of the Faculty of Process Engineering, Universidad Nacional de San Agustín de Arequipa, Arequipa 0401, Perú cElectrochemistry and Nanotechnology Laboratory, Institute of Technology and Research (ITP), 49032-490, Aracaju-SE, Brazil dGraduate Program in Process Engineering (PEP), Universidade Tiradentes, 49032-490, Aracaju-SE, Brazil
L.J.Mamani Asqui,L.N.Peredo Berlanga,F.J.Roque Rodríguez,a,b和G.R.Salazar Bandac,d,*阿雷基帕国立圣阿古斯丁大学化学工程学院,阿雷基帕0401,阿雷基帕国立圣阿古斯丁大学工艺工程学院Perúb研究生院,技术与研究院(ITP),49032-490,Aracaju SE,巴西;工艺工程研究生院(PEP),蒂拉登斯大学,49032-490,AracajuSE,巴西
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引用次数: 2
Understanding Caking Phenomena in Industrial Fertilizers 了解工业肥料中的结块现象
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.15255/CABEQ.2020.1866
Aysu Ulusal, Cemre Avşar
One of the most important problems of the fertilizer industry is that fertilizers show caking tendency during transportation and storage. Caking occurs as a result of interaction at the contact points formed between solid fertilizer particles. These interactions, also called contact mechanisms, are activated by a number of properties that fertilizers have and by environmental conditions. Prevention of caking mechanism is a substantial research subject that directly affects the quality and financial value of the final product and ensures its applicability. Fertilizer in good quality can provide ease in agricultural applications, and directly affect plant nutrition and crop productivity. At this point, there are various promoter practices for obtaining the free-flowing property in fertilizers that can be maintained or suggested during or after production, both in industry and in R&D studies. In order to develop new process control points in the industry, it is important to understand the factors that cause caking and the mechanism of physicochemical interactions that progress depending on these factors. In addition, it is essential to improve the storage conditions of the fertilizer, as well as to maintain its quality until end-use. This paper focuses on the caking behavior of fertilizers in detail, giving brief information about the prevention of caking and various types of anticaking agents.
肥料在运输和储存过程中容易结块是肥料工业面临的一个重要问题。结块是固体肥料颗粒之间在接触点上相互作用的结果。这些相互作用,也称为接触机制,是由肥料的一些特性和环境条件激活的。防止结块机理是一个重要的研究课题,直接影响到最终产品的质量和经济价值,并保证其适用性。优质肥料可以为农业施用提供便利,并直接影响植物营养和作物生产力。在这一点上,在工业和研发研究中,有各种促进剂用于获得肥料的自由流动特性,这些特性可以在生产期间或生产后保持或建议。为了在工业中开发新的过程控制点,了解导致结块的因素以及依赖这些因素的物理化学相互作用机制非常重要。此外,必须改善肥料的储存条件,并在最终使用前保持其质量。本文详细介绍了肥料的结块行为,简要介绍了防止结块的方法和各种类型的防结块剂。
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引用次数: 4
Removal Efficiency of Textile Dyes from Aqueous Solutions Using Calcined Waste of Eggshells as Eco-friendly Adsorbent 用焙烧后的蛋壳渣作为环保型吸附剂去除水溶液中纺织染料的效果
IF 1.5 4区 生物学 Q3 Chemistry Pub Date : 2021-01-01 DOI: 10.15255/CABEQ.2020.1872
R. Slimani, H. Hiyane, M. Haddad, S. Lazar, S. Antri, Y. Achour, M. Essoufy, S. Benkaddour, I. E. Ouahabi
R. Slimani,a I. El Ouahabi,b S. Benkaddour,b H. Hiyane,b M. Essoufy,a Y. Achour,c S. El Antri,b S. Lazar,b,* and M. El Haddadc aLaboratory of Spectroscopy, Molecular Modeling, Materials, Nanomaterials, Water & Environment-CERNE2D, Faculty of Sciences, Mohammed V University in Rabat, BP 1014RP, Rabat, Morocco bLaboratory of Biochemistry, Environment &Agroalimentary URAC36, Faculty of Sciences and Techniques, Hassan II University of Casablanca, BP 146, 20650, Mohammedia, Morocco cLaboratory of Analytical & Molecular Chemistry, Faculty Poly-Disciplinary of Safi, University of Cadi Ayyad, BP4162, 46000 Safi, Morocco
R. Slimani,a I. El Ouahabi,b S. Benkaddour,b H. Hiyane,b M. Essoufy,a Y. Achour,c S. El Antri,b S. Lazar,b,*和M. El Haddadc光谱学、分子建模、材料、纳米材料、水与环境cerne2d实验室,拉巴特穆罕默德五世大学理学院,BP 1014RP,摩洛哥拉巴特哈桑二世大学生物化学、环境与农业实验室,URAC36,科学与技术学院,BP 146,20650, Mohammedia,摩洛哥分析与分子化学实验室,萨菲大学多学科学院,BP4162, 46000萨菲,摩洛哥
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引用次数: 8
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Chemical and Biochemical Engineering Quarterly
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