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Investigation of the effects of metal oxide nanoparticle mixtures on Danio rerio and Xenopus laevis embryos 金属氧化物纳米粒子混合物对斑蝥和非洲爪蟾胚胎影响的研究
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2023-01-02 DOI: 10.1080/02757540.2022.2162893
N. Ozmen, Duygu Ozhan Turhan, Abbas Güngördü, Hatice Çağlar Yılmaz, M. Ozmen
ABSTRACT In this study, the toxic effects of single TiO2, ZnO and Fe2O3 nanoparticles (NPs) and their binary and ternary combinations on the embryonic development of Xenopus laevis and Danio rerio were evaluated. It was aimed to determine the median lethal concentrations, growth retardation and developmental malformation effects and the effects of mixed nanoparticle exposure to selected enzyme biomarkers resulting from the exposure of embryos to NPs. The results showed that ZnO NPs, which are the most toxic according to the highest lethality level, cause developmental delay and malformations. The Fe2O3 and TiO2 NPs caused growth retardation only in D. rerio embryos. It was determined that double and triple combinations of NPs did not cause significant lethality in both species. Biochemical markers showed that mixed NPs could lead to greater toxicity compared to single exposures. The results also revealed that TiO2 or Fe2O3 NPs caused an increase in toxicity when co-existing with ZnO NP due to additive effects. Overall, the results showed that D. rerio was more susceptible to NP exposure in terms of growth and mortality than X. laevis. However, studies that are more comprehensive are needed to better understand the toxicity mechanism of metal oxide NP mixtures.
摘要本研究评估了TiO2、ZnO和Fe2O3纳米颗粒及其二元和三元组合对非洲爪蟾和斑蝥胚胎发育的毒性作用。其目的是确定中位致死浓度、生长迟缓和发育畸形的影响,以及混合纳米粒子暴露于胚胎暴露于纳米粒子所产生的选定酶生物标志物的影响。结果表明,ZnO纳米颗粒的毒性最高,可导致发育迟缓和畸形。Fe2O3和TiO2纳米颗粒仅在灰蝶胚胎中引起生长迟缓。已经确定,NP的双重和三重组合不会对这两个物种造成显著的致命性。生化标记显示,与单一暴露相比,混合NP可能导致更大的毒性。结果还表明,当TiO2或Fe2O3 NP与ZnO NP共存时,由于添加剂效应,其毒性增加。总的来说,研究结果表明,就生长和死亡率而言,灰蝶比灰蝶更容易受到NP暴露的影响。然而,需要更全面的研究来更好地了解金属氧化物NP混合物的毒性机制。
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引用次数: 0
Assessment of heavy metal pollution with different indices in Süreyyabey dam lake in Turkey 土耳其sareyabey堰塞湖不同指标重金属污染评价
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-12-28 DOI: 10.1080/02757540.2022.2162045
Ş. Erdoğan, G. Kankılıç, M. Seyfe, Ü. N. Tavşanoğlu, Ş. Akın
ABSTRACT The current study, for the first time, focused on the determination of pollution levels and spatial distribution of heavy metals in Süreyyabey Dam Lake which is an important water source for the surrounding area. Water and sediment samples were taken seasonally from six sites exposed to different anthropogenic impacts. The most enriched elements in the Dam Lake were As, Cd, Mo, and Pb. In all sampling sites, the average heavy metal concentrations indicated low risk except for Cd and Pb which were classified in the moderate ecological risk class. Overall, the ecological risk was low for one site (S3) because of the far distance from the residential areas, while the ecological risk of the other stations was moderate. According to water analysis results, the aquatic life criteria could not be met for Zn, Cu, Cr, and Hg in Süreyyabey Dam Lake. Although the dam lake is used only for irrigation purposes, the Süreyyabey Dam Lake water is not suitable for drinking according to the metal limit values of the World Health Organisation. The results of the current study will contribute to the awareness of local authorities by using several indices on taking the necessary precautions.
摘要本研究首次将重点放在了苏雷亚贝大坝湖重金属污染水平和空间分布的测定上,苏雷亚比大坝湖是周边地区的重要水源。水和沉积物样本是从六个受到不同人为影响的地点季节性采集的。大坝湖中富集元素最多的是As、Cd、Mo和Pb。在所有采样点,除Cd和Pb属于中等生态风险类别外,平均重金属浓度均显示风险较低。总体而言,由于距离居民区较远,一个站点(S3)的生态风险较低,而其他站点的生态风险中等。根据水质分析结果,Süreyyabey大坝湖的Zn、Cu、Cr和Hg不能满足水生生物标准。尽管大坝湖仅用于灌溉,但根据世界卫生组织的金属限值,Süreyyabey大坝湖的水不适合饮用。目前的研究结果将通过使用几个关于采取必要预防措施的指数来提高地方当局的认识。
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引用次数: 1
Realistic environmental exposure to secondary PET microplastics induces biochemical responses in freshwater amphipod Hyalella azteca 真实的环境暴露于二次PET微塑料诱导淡水片足类阿兹特克透明藻的生化反应
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-12-27 DOI: 10.1080/02757540.2022.2162046
L. G. Queiroz, B. Rani-Borges, C. Prado, Beatriz Rocha de Moraes, R. A. Ando, T. Paiva, Marcelo Pompêo
ABSTRACT Freshwater environments are especially susceptible to microplastic contamination due to their proximity to urbanised and industrial areas. Also, there is a lack of information about the effects of this pollutant on freshwaters making it difficult the conservation of these environments. Benthic species, such as the freshwater amphipod Hyalella azteca, have been superficially studied so far for evaluation of microplastic pollution. In the present study, we analyzed whether polyethylene terephthalate (PET) microplastics could lead to reduced survival of H. azteca or changes in biochemical markers (SOD, CAT, MDA, and GST) at environmentally relevant concentrations (60 and 600 particles) after 7 d of exposure. The results showed that there was no significant mortality at any of the concentrations tested. The enzyme CAT showed no variation compared to the control group at any of the concentrations. SOD, MDA, and GST were statistically different (p < 0.05). Our study demonstrated that PET MP did not affect the survival of H. azteca at environmentally relevant concentrations. However, changes in biomarkers of oxidative stress may be detected at low level of exposure (60 particles). Although survival is not affected, the macrobenthic invertebrate community may be under threat in environments where there is PET microplastic pollution.
淡水环境特别容易受到微塑料污染,因为它们靠近城市化和工业区。此外,缺乏关于这种污染物对淡水的影响的信息,使这些环境的保护变得困难。底栖生物,如淡水片足类动物阿兹特克透明藻,迄今为止对微塑料污染评价的研究还很肤浅。在本研究中,我们分析了暴露7天后,聚对苯二甲酸乙二醇酯(PET)微塑料是否会导致H. azteca在环境相关浓度(60和600颗粒)下的存活率降低或生化标志物(SOD, CAT, MDA和GST)的变化。结果表明,在任何测试浓度下都没有明显的死亡率。与对照组相比,在任何浓度下,CAT酶都没有变化。SOD、MDA、GST差异有统计学意义(p < 0.05)。我们的研究表明,PET MP在环境相关浓度下不会影响H. azteca的存活。然而,在低水平的暴露(60个颗粒)下,氧化应激生物标志物的变化可能被检测到。虽然生存不受影响,但在PET微塑料污染的环境中,大型底栖无脊椎动物群落可能受到威胁。
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引用次数: 1
The influence on microorganisms of heavy metals from refiner’s spent desulphurisation catalysts 炼厂废脱硫催化剂中重金属对微生物的影响
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-12-16 DOI: 10.1080/02757540.2022.2158185
Tanja Jednak Berić, J. Avdalović, J. Milić, V. Teofilović, M. Vrvić, B. Jovančićević, S. Miletic
ABSTRACT Refinery wastes generated in conventional crude oil refining processes, or in accidental situations, are complex substrates for treatment and disposal. Petroleum desulphurisation catalysts can also be hazardous refinery waste. They contain various metals, such as cobalt, molybdenum, nickel and tungsten. In this paper, three petroleum refiner’s spent desulphurisation catalysts were investigated. These catalysts were not suitable for recycling and, therefore, were classified as hazardous waste. They were chemically characterised, including phase composition and their effect on a consortium of microorganisms used in the process of bioremediation. Catalysts contained up to 2.26 g kg−1 of total petroleum hydrocarbons, up to 56.7 g kg−1 of iron, 18.6 g kg−1 of molybdenum, and less than 0.1 mg kg−1 each of cobalt and nickel. These obtained results show that bioremediation of such waste is possible.
在常规原油精炼过程中或在意外情况下产生的炼油厂废物是复杂的处理和处置基质。石油脱硫催化剂也可能是危险的炼油厂废物。它们含有各种金属,如钴、钼、镍和钨。以三家炼油厂的废脱硫催化剂为研究对象。这些催化剂不适合回收利用,因此被列为危险废物。它们进行了化学表征,包括相组成及其对生物修复过程中使用的微生物财团的影响。催化剂中总石油碳氢化合物的含量高达2.26 g kg - 1,铁的含量高达56.7 g kg - 1,钼的含量为18.6 g kg - 1,钴和镍的含量均低于0.1 mg kg - 1。这些结果表明,对这类废物进行生物修复是可能的。
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引用次数: 0
Spatial distribution and ecological risk of heavy metal in surface sediment of Old Brahmaputra River, Bangladesh 孟加拉国老布拉马普特拉河表层沉积物重金属的空间分布和生态风险
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-12-05 DOI: 10.1080/02757540.2022.2152015
M. Islam, Rifat Shahid Shammi, Rahiatul Jannat, M. Kabir, M. Islam
ABSTRACT The study was conducted to investigate the concentrations, distributions, sources, and potential ecological risk of heavy metals in surface sediments from the Old Brahmaputra River. Sediment samples were collected from five sampling stations and analyzed with an inductively coupled plasma mass spectrometer (ICP-MS). The results showed that mean concentrations (mg/kg) of heavy metals were in order of Ni (58.82) > Cr (32.45) > Pb (21.04) > Cu (14.24) > Cd (3.81) > As (2.02). Element-specific environmental indices exposed that the ecological risks trailed in the same downward direction as Cd > Ni > Pb > As > Cu > Cr. The contamination factor (CF), enrichment factor (EF), and geo-accumulation index (Igeo) exposed all cases to a modest level of contamination except for Cd, which has a significant level of contamination. Only Ni and Cd were found to pose a high ecological risk for aquatic life based on the sediment quality guidelines. The prospective ecological risk factor and potential ecological risk both suggested low to moderate ecological risk. The river sediments were mostly uncontaminated or mildly contaminated, posing a minimal ecological risk. The study concluded that the Old Brahmaputra River is subjected to anthropogenic disturbances in its aquatic environment.
摘要:本研究旨在研究老雅鲁藏布江表层沉积物中重金属的浓度、分布、来源及潜在生态风险。采用电感耦合等离子体质谱仪(ICP-MS)对5个采样站的沉积物样品进行分析。结果表明,重金属平均浓度(mg/kg)依次为Ni (58.82) > Cr (32.45) > Pb (21.04) > Cu (14.24) > Cd (3.81) > As(2.02)。元素特异性环境指数显示,生态风险与Cd > Ni > Pb > as > Cu > Cr呈相同的下降趋势。污染因子(CF)、富集因子(EF)和地质积累指数(Igeo)显示,除Cd具有显著污染水平外,所有案例都处于中等污染水平。根据沉积物质量指南,仅发现Ni和Cd对水生生物构成高生态风险。预期生态风险因子和潜在生态风险因子均为低至中等生态风险。河流沉积物大部分未受污染或轻度污染,生态风险极小。该研究得出结论,旧雅鲁藏布江的水环境受到人为干扰。
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引用次数: 4
Sub-chronic toxicity of broflanilide on the nervous system of zebrafish (Danio rerio) 溴flanilide对斑马鱼神经系统的亚慢性毒性
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-12-05 DOI: 10.1080/02757540.2022.2153836
Kai Wang, Zhiqiu Qi, Manman Duan, Ru Zhang, Lu He
ABSTRACT The new insecticide broflanilide, which possesses high insecticidal activity against agricultural pests, acts on the γ-aminobutyric acid receptor in the insect nervous system. At present, few studies assessed its effect on the nervous system of zebrafish, especially its sub-chronic toxicity on the zebrafish brain. In this study, the sub-chronic toxicity of broflanilide on the zebrafish brain was assessed. After 21 days of exposure at 36.3 μg/L, broflanilide caused oxidative damage to the zebrafish brain, increased the levels of reactive oxygen species and malondialdehyde, and inhibited the activities of superoxide dismutase, catalase, and glutathione peroxidase. Overall, these changes result in brain cell apoptosis, and inhibited growth and development. Moreover, broflanilide affects the release of acetylcholinesterase, γ-aminobutyric acid, 5-hydroxy tryptamine, and dopamine as well as the expression of related genes in the brain, leading to abnormal zebrafish behaviour. These results corroborate the sub-chronic toxicity of broflanilide on zebrafish brain, which helps the further understanding of the potential environmental risk of broflanilide.
新型杀虫剂溴flanilide作用于昆虫神经系统的γ-氨基丁酸受体,对农业害虫具有较高的杀虫活性。目前很少有研究评估其对斑马鱼神经系统的影响,特别是其对斑马鱼大脑的亚慢性毒性。本研究评估了溴氟胺对斑马鱼大脑的亚慢性毒性。在36.3 μg/L浓度下暴露21 d后,溴flanilide对斑马鱼大脑造成氧化损伤,增加活性氧和丙二醛水平,抑制超氧化物歧化酶、过氧化氢酶和谷胱甘肽过氧化物酶的活性。总的来说,这些变化导致脑细胞凋亡,抑制生长发育。此外,溴flanilide影响大脑中乙酰胆碱酯酶、γ-氨基丁酸、5-羟基色胺和多巴胺的释放以及相关基因的表达,导致斑马鱼行为异常。这些结果证实了溴氰胺对斑马鱼大脑的亚慢性毒性,有助于进一步了解溴氰胺的潜在环境风险。
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引用次数: 0
40 years of Chemistry and Ecology 化学与生态学40年
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-11-26 DOI: 10.1080/02757540.2022.2122473
R. Danovaro, C. Gambi
This year, 2022, marks the 40th Anniversary of the journal ‘Chemistry and Ecology’, which in 1982 published the first issue as ‘Chemistry in Ecology’. When 20 years ago a new Editor in Chief was appointed, the main target of the journal was to widen its visibility and to acquire the impact factor. These results were achieved and during the last 10 years, Chemistry and Ecology has constantly expanded its visibility in the international community and, coherently, has increased its Impact Factor (source ISI-Web of Science), attracting and growing number of submissions from several academia and research institutes worldwide. The papers published in Chemistry and Ecology are becoming an important reference for research based on multi-disciplinary approaches in aquatic and terrestrial ecosystems dealing with environmental pollution, ecotoxicology, environmental biotechnology and biogeochemistry. The Journal is also experiencing an enormous increase in flow of manuscripts and more than 600 papers have been published 10 years with 10 issues per year. In addition, Chemistry and Ecology continues to publish also specific issue on emerging topics, such as the SI dedicated to the ABBaCO project and entitled: Multidisciplinary approach to the characterisation of marine coastal areas subjected to chronic industrial contamination. The manuscripts’ flow has also increased over time reaching more than 280 submissions per year, while having space only for 60 publications per year. According to the journal procedure and the policy of Taylor & Francis group, each issue has been published online once completed (ca 6 papers) and hard copies of the journal are now published in two volumes collecting the issues 1–5 and 6–10, to reduce the impact of the Journal production and management on the environment. Some papers resulted highly cited. These manuscripts covered various topics, from the bioremediation solutions, the application of new environmental biotechnologies [1–13], the ecotoxicological research on aquatic and terrestrial organisms [14–18], the assessment of different pollution sources along with the biological responses [19–37], and the organic matter diagenesis and biogeochemical cycles in all ecosystems [38–44]. These results are due to its growing international credibility, the engagement of a growing number of authors (more than 2500 in the last 10 years have published in Chemistry and Ecology), the contribution of the Editorial staff and Editorial board, and of the >1600 reviewers that have dedicated their time to support the growth of Chemistry and Ecology in the last 10 years. We will continue in this direction, guaranteeing the full respect of equity and accessibility of the journal, the gender balance, fair and robust review process, and the support to young and emerging scientists all over the world, independently from the prestige of their institution, giving voice to all Authors with an original vocation to publish their original results from all o
今年,2022年,是《化学与生态学》杂志出版40周年,该杂志于1982年出版了第一期《生态学中的化学》。20年前,当新的主编被任命时,该杂志的主要目标是扩大其知名度并获得影响因素。这些成果已经取得,在过去的10年里,化学与生态学在国际社会中的知名度不断扩大,并一致地提高了其影响因素(来源于ISI科学网),吸引了世界各地多个学术界和研究机构提交的越来越多的材料。发表在《化学与生态学》上的论文正成为基于多学科方法在水生和陆地生态系统中研究环境污染、生态毒理学、环境生物技术和生物地球化学的重要参考。《华尔街日报》的稿件流量也在大幅增加,10年来发表了600多篇论文,每年10期。此外,《化学与生态学》继续出版关于新兴主题的具体问题,例如专门用于ABBaCO项目的SI,题为:对遭受长期工业污染的海洋沿海地区进行特征描述的多学科方法。手稿的流量也随着时间的推移而增加,每年提交280多份,而每年只有60份出版物。根据期刊程序和Taylor&Francis集团的政策,每一期期刊完成后都在网上发表(约6篇论文),该期刊的硬拷贝现在分两卷出版,收集第1-5期和第6-10期,以减少期刊生产和管理对环境的影响。一些论文被高度引用。这些手稿涵盖了各种主题,从生物修复解决方案、新环境生物技术的应用[1-13]、水生和陆地生物的生态毒理学研究[14-18]、不同污染源的评估以及生物反应[19-37],以及所有生态系统中的有机质成岩作用和生物地球化学循环[38-44]。这些结果是由于其日益增长的国际信誉、越来越多的作者的参与(在过去10年中,超过2500人发表在《化学与生态学》上)、编辑人员和编辑委员会的贡献,以及在过去10年间致力于支持化学与生态学发展的1600多名评审员的贡献。我们将继续朝着这个方向前进,保证期刊的公平性和可访问性、性别平衡、公平而有力的审查过程得到充分尊重,并支持世界各地的年轻和新兴科学家,独立于他们机构的声望,为所有有志于发表世界各地原创成果的作者发声。
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引用次数: 0
Assessment of pollution variability across the central part of the Büyük Menderes River (Turkey) using water physicochemical parameters and biomarker responses in the non-biting midge Chironomus riparius (Diptera: Chironomidae) 利用水体物理化学参数和生物标志物对土耳其b<s:1> yy<e:1> k Menderes河中部污染变动性的评价
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-11-23 DOI: 10.1080/02757540.2022.2147515
Adile Sari
ABSTRACT This study aimed to examine the pollution level in the central part of the Büyük Menderes River (in both the main tributary and Çürüksu stream) in Denizli (Turkey) using water physicochemical parameters and biomarker responses in Chironomus riparius (Diptera: Chironomidae). In physicochemical parameter evaluations, Sığma, Korucuk, and Güzelköy stations were determined to have higher mean temperature, pH, salinity, conductivity, and total dissolved solids (TDS) values and lower dissolved oxygen (dO2) and saturated oxygen (sO2) values than Bekilli, Mahmutlu, and Sarayköy stations. In biomarker response evaluations, C. riparius larvae from Sarayköy, Sığma, Korucuk, and Güzelköy stations were found to exhibit inhibited acetylcholinesterase (AChE) activities (55%−68%) and elevated 7-ethoxyresorufin O-deethylase (EROD) activities (191%−281%), glutathione S-transferase (GST) activities (138%−187%), and metallothionein (MT) contents (155%−231%) when compared with the control values. This study proves that different stations are exposed to different pollution sources, the pollution level of a station varies depending on the season, and the stations on Çürüksu stream, among which Güzelköy appears to be the most contaminated, are exposed to more pollutants than those on the main tributary of the river.
摘要本研究旨在利用摇蚊(Diptera:摇蚊科)的水物理化学参数和生物标志物响应,检测土耳其Denizli的Büyük Menderes河中部(主要支流和Çrüksu河)的污染水平。在物理化学参数评估中,Sığma、Korucuk和Güzelköy站的平均温度、pH、盐度、电导率和总溶解固体(TDS)值高于Bekili、Mahmutlu和Saraykö伊站,溶解氧(dO2)和饱和氧(sO2)值较低。在生物标志物响应评估中,发现来自Sarayköy、Sığma、Korucuk和Güzelkö伊站的C.riparius幼虫表现出乙酰胆碱酯酶(AChE)活性被抑制(55%−68%)和7-乙氧基间苯二酚O-脱乙基酶(EROD)活性升高(191%−281%)、谷胱甘肽S-转移酶(GST)活性(138%−187%),金属硫蛋白(MT)含量(155%-231%)。这项研究证明,不同的站点暴露在不同的污染源中,一个站点的污染水平因季节而异,而Çürüksu河上的站点(其中Güzelköy似乎污染最严重)暴露在比该河主要支流上的站点更多的污染物中。
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引用次数: 0
Mosses as bioindicators of atmospheric deposition of Tl, Hg and As in Kosovo 苔藓作为科索沃大气中Tl、Hg和as沉积的生物指示物
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-11-21 DOI: 10.1080/02757540.2022.2147516
Musaj Paçarizi, T. Stafilov, R. Šajn, K. Tasev, Flamur Sopaj
ABSTRACT Air pollution is an increasing challenge for modern society globally, and it is a very common problem in Kosovo. In this work, the atmospheric deposition of Tl, Hg and As was studied using mosses as natural samplers. Moss samples (Homalothecium sericeum (Hedw.) Schimp. 1851, Hypnum cupressiforme Hedwig. 1801, and Pseudoscleropodium purum (Hedw.) M.Fleisch) were collected, cleaned, digested and then analysed by inductively coupled plasma–mass spectrometry (ICP–MS). Statistical analysis and spatial distribution maps were performed to explain the obtained results. Median concentrations in mg/kg were 0.017 mg/kg for Tl, 0.088 mg/kg for Hg and 0.172 mg/kg for As. There were also extreme concentrations for Tl and As related to the industrial pollution sources such as the Trepça mine facilities in the town of Mitrovica, a thermoelectric coal power plant in the town of Obiliq and a cement factory in the town of Hani i Elezit. This indicates that the main industries causing pollution in Kosovo are mining processes and thermal power plant operations.
摘要空气污染是全球现代社会面临的日益严峻的挑战,在科索沃也是一个非常普遍的问题。在这项工作中,用苔藓作为天然采样器研究了大气中Tl、Hg和As的沉积。苔藓样品(Homalothecum sericeum(Hedw.)Schimp。1851年,海德薇铜丝菌。1801,和Pseudoscleropourpurum(Hedw.)M.Fleisch)收集、清洁、消化,然后通过电感耦合等离子体质谱法(ICP–MS)进行分析。进行了统计分析和空间分布图来解释所获得的结果。Tl的中位浓度(mg/kg)为0.017 mg/kg,Hg为0.088 mg/kg,As为0.172 mg/kg。Tl和As的极端浓度也与工业污染源有关,如米特罗维察镇的Trepça矿山设施、Obiliq镇的热电煤电厂和Hani Elezit镇的水泥厂。这表明科索沃造成污染的主要行业是采矿过程和火力发电厂运营。
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引用次数: 1
Bioaccumulation and sources identification of atmospheric metal trace elements using lichens along a rural–urban pollution gradient in the Safi-Essaouira coastal area 利用地衣研究萨菲-索维拉沿海地区城乡污染梯度大气金属微量元素的生物积累及来源鉴定
IF 2.5 4区 环境科学与生态学 Q3 ECOLOGY Pub Date : 2022-11-12 DOI: 10.1080/02757540.2022.2142215
Essilmi Mohamed, M. Loudiki, A. El Gharmali
ABSTRACT Atmospheric contamination by metallic trace elements emitted by various human activities constitutes an important threat to human and environmental health. This study aims to determine metal accumulation and the sources of air metallic pollution in the Safi urban-industrial area using lichens as biomonitors. Ten trace elements (As, Cd, Co, Cr, Cu, Ni, Pb, Ti, V and Zn) concentrations and 206Pb/207Pb and 208Pb/207Pb isotopic ratios were analyzed by ICP-MS in four lichen species: Xanthoria Parietina, Ramalina Lacera, Xanthoria Calcicola and Ramalina Pollinaria. The results showed significant differences among study sites for most elements with higher concentrations in the industrial, urban and peri-urban sites compared to the reference site chosen as a natural rural area far from any human activities. Significant differences were found between saxicolous and corticolous species especially for Cd, Cu and Zn. The values of Zn/Cu, Zn/Pb and Pb isotope ratios measured in lichens revealed that vehicular traffic and industrial emissions are the main sources of atmospheric Pb contamination. Other anthropic activities (waste incineration, artisanal pottery …) might be the source of other trace metal elements accumulated by lichens. Airborne contaminants in Safi appear to be exported from their sources by air mass movements driven by the regional wind profile.
人类各种活动排放的金属微量元素对大气的污染对人类和环境健康构成了重要威胁。本研究旨在利用地衣作为生物监测器,确定萨菲城市工业区的金属积累和空气金属污染源。采用电感耦合等离子体质谱法分析了四种地衣中的10种微量元素(As、Cd、Co、Cr、Cu、Ni、Pb、Ti、V和Zn)的浓度以及206Pb/207Pb和208Pb/207Pb。结果显示,与选择为远离任何人类活动的自然农村地区的参考地点相比,工业、城市和城市周边地区大多数元素浓度较高的研究地点之间存在显著差异。含汞物种和含皮质物种之间存在显著差异,尤其是Cd、Cu和Zn。地衣中Zn/Cu、Zn/Pb和Pb同位素比值的测定表明,车辆交通和工业排放是大气Pb污染的主要来源。其他慈善活动(垃圾焚烧、手工陶器 …) 可能是地衣积累的其他微量金属元素的来源。萨菲的空气污染物似乎是由区域风廓线驱动的气团运动从其来源输出的。
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Chemistry and Ecology
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