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Distribution, occurrence, and environmental risks of heavy metals in hazardous waste: A regional study in Beijing, China 危险废物中重金属的分布、发生和环境风险:中国北京地区研究
Pub Date : 2024-08-03 DOI: 10.1016/j.cec.2024.100099
Dan Wu , Yanjun Liu , Lingyi Meng , Guilan lu , Yazhuo Chen , Ziliang Yang

Hazardous waste from industrial production has become a global concern because of its impact on the environment and human health. However, studies on heavy metals in regional hazardous waste are rare. Thus, this study examined 93 hazardous waste samples in Beijing in 2019, to assess the distribution, occurrence, and potential eco-environmental risks of heavy metals in such waste. The results indicated high concentrations of Zn, Cu, and Ni in hazardous waste, and the leaching toxicity of Ni (270.60 mg/L), Cu (524.1 mg/L), and Pb (136.23 mg/L) exceeded Chinese identification standards for hazardous waste. Heavy metals in hazardous waste have been primarily found in remote counties around the locations of industrial enterprises. The total amount of the heavy metals followed the order: Zn > Cu > Ni > Ba > Mn > Pb. Based on the migration abilities of their detected forms, heavy metals were classified into three categories (high, middle, and low migration abilities) to characterize their potential to enter the environment. The detected amounts of heavy metals with high and middle migration ability followed the order: Zn > Cu > Ni > Mn > Pb > Ba. The potential environmental risk of heavy metals was evaluated using the potential environmental risk index, resulting in the following ranking: Ni > Pb > Mn > Zn > Cu > Ba. Daxing District exhibited the highest total environmental risk and environmental risk per unit area, whereas Miyun District showed the highest environmental risk per secondary sector of the economy and unit of GDP. This was attributed to Beijing's industrial structure. The results of this study provide fundamental data for the management and control of hazardous waste in Beijing and are expected to aid in preventing and managing environmental risks caused by such waste.

由于工业生产产生的危险废物对环境和人类健康的影响,它已成为全球关注的问题。然而,有关地区危险废物中重金属的研究却很少见。因此,本研究检测了 2019 年北京市的 93 个危险废物样本,以评估此类废物中重金属的分布、存在情况和潜在的生态环境风险。结果表明,危险废物中锌、铜和镍的浓度较高,其中镍(270.60 mg/L)、铜(524.1 mg/L)和铅(136.23 mg/L)的浸出毒性超过了中国危险废物鉴别标准。危险废物中的重金属主要出现在工业企业所在地周边的偏远县城。重金属的总含量依次为锌;铜;镍;钡;锰;铅。根据检测到的重金属形态的迁移能力,将重金属分为三类(高迁移能力、中迁移能力和低迁移能力),以确定其进入环境的可能性。高迁移能力和中迁移能力重金属的检测量依次为Zn > Cu > Ni > Mn > Pb > Ba。使用潜在环境风险指数对重金属的潜在环境风险进行了评估,得出以下排序:镍;铅;锰;锌;铜;钡。大兴区的环境总风险和单位面积环境风险最高,而密云区的第二产业环境风险和单位 GDP 环境风险最高。这与北京的产业结构有关。研究结果为北京市危险废物的管理和控制提供了基础数据,有助于预防和管理危险废物造成的环境风险。
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引用次数: 0
What Can We Learn From the Bankruptcy of Renewcell? Some Limitations of Business-Case-Based Circular Transition 我们能从 Renewcell 的破产中学到什么?基于商业案例的循环过渡的一些局限性
Pub Date : 2024-07-01 DOI: 10.55845/tfhb2038
Hervé Corvellec, Alison F. Stowell
Circular start-ups are vectors of hope for a circular transition. But what does a circular champion’s bankruptcy tell us? That a structural barrier to the circular transition is the total dependence on the ability of circular businesses to be profitable.
循环型初创企业是循环转型的希望载体。但是,循环型企业的破产又能说明什么呢?循环转型的结构性障碍是完全依赖循环型企业的盈利能力。
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引用次数: 0
What is the University For These Days? Rethinking the Foundations of the ‘Circular Campus’ 如今的大学为了什么?反思 "循环校园 "的基础
Pub Date : 2024-07-01 DOI: 10.55845/bdcu6970
K. Hobson, Megan O’Byrne
In line with growing concerns about the negative environmental impacts of Higher Education Institutions’ (HEIs) core activities, Circular Economy (CE) interventions are appearing across campuses, focussing on e.g., curriculum content, operations, and resource-use, and/or research. In parallel, researchers are increasingly exploring the aims, barriers, processes, and outcomes of attempts to make HEIs more ‘circular’. However, this growing literature often fails to connect with broader critiques of prevailing CE goals and processes, to consider the types of CE being enacted and if other forms of CE are possible and desirable in HEIs. In response, this paper discusses data from research interviews undertaken as part of a project that explored on-campus CE initiatives at a sample of UK and Irish HEIs. It reports on key interview themes, which are HEIs as spaces of over-consumption; as testbeds for new CE practices: and as sites of CE degrowth: and makes the case for HEIs to ask fundamental, radical questions—i.e., ‘what is the university for these days?’—as a pivotal part of CE projects and systems across HEIs.
随着人们日益关注高等教育机构(HEIs)核心活动对环境的负面影响,循环经济(CE)干预措施正在校园中出现,重点是课程内容、运营、资源利用和/或研究。与此同时,研究人员也在越来越多地探索使高等院校更加 "循环 "的目标、障碍、过程和结果。然而,这些不断增加的文献往往未能与对现行行政首长协调会目标和过程的更广泛批判联系起来,也未能考虑正在实施的行政首长协调会的类型,以及高等院校是否可能和需要其他形式的行政首长协调会。为此,本文讨论了在英国和爱尔兰高等院校抽样调查校内行政首长计划项目中开展的研究访谈所获得的数据。本文报告了关键的访谈主题,即高等院校是过度消费的空间;是新的行政首长协调会实践的试验场;是行政首长协调会退化的场所;并提出了高等院校提出根本性的激进问题的理由,即 "大学如今是为了什么?"--这是高等院校行政首长协调会项目和系统的关键部分。
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引用次数: 0
The biofactories: Quantifying environmental benefits of the wastewater circular economy in Chile using life cycle assessment 生物工厂:利用生命周期评估量化智利废水循环经济的环境效益
Pub Date : 2024-06-13 DOI: 10.1016/j.cec.2024.100091

The wastewater circular economy promises improved environmental impacts within the food-water-energy nexus. This requires verification as the global sanitation sectors seek to improve environmental impacts and achieve integrated water management. Life cycle assessment (LCA) has been used to compare novel technologies for wastewater treatment and recovery, but research addressing plant-wide improvements of co-product resource recovery using real data from full-scale plants is still needed, particularly in a Latin American context. In Chile, two wastewater treatment plants (WWTPs) have embraced the circular economy configuration, recovering treated effluent, biosolids, and biogas, in addition to implementing advanced nitrogen removal using different technologies. The LCA of these two WWTPs demonstrated that Plant A improved 8 out of 10 impact categories compared to the baseline conventional scenario, while Plant B improved 5 categories out of 10. The analysis of the two plants showed the influence of influent quality on environmental impacts and the trade-off that occurs between the different technologies implemented. Plant B generated larger environmental credits through increased biogas and biosolids recovery due to thermal hydrolysis pre-treatment and anaerobic digestion, combined with cogeneration of heat and power. Plant A implemented water recovery, which provided benefits on a smaller magnitude but to more impact categories. Therefore, both plants improved environmental impacts through the wastewater circular economy, but further improvements in system configurations are recommended in each.

废水循环经济有望改善食物-水-能源关系中的环境影响。这需要验证,因为全球卫生部门都在努力改善环境影响,实现综合水管理。生命周期评估(LCA)已被用于比较废水处理和回收的新技术,但仍需要利用全规模工厂的真实数据,研究如何在全厂范围内改善副产品资源回收,特别是在拉丁美洲。在智利,有两家污水处理厂(WWTP)采用了循环经济配置,除了使用不同的技术实施先进的脱氮之外,还回收了处理后的污水、生物固体和沼气。这两家污水处理厂的生命周期评估表明,与基线传统方案相比,A 工厂改善了 10 个影响类别中的 8 个类别,而 B 工厂则改善了 10 个影响类别中的 5 个类别。对这两家污水处理厂的分析表明,进水质量对环境影响的影响以及不同技术之间的权衡。B 工厂通过热水解预处理和厌氧消化以及热电联产,增加了沼气和生物固体回收量,从而产生了更多的环境信用额度。A 工厂实施了水回收,带来的效益较小,但影响类别较多。因此,两家工厂都通过废水循环经济改善了对环境的影响,但建议每家工厂进一步改进系统配置。
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引用次数: 0
Rethinking Regional Embeddedness and Innovation Systems for Transitions Towards Just, Responsible, and Circular Bioeconomies 反思区域嵌入性和创新体系,向公正、负责任和循环型生物经济转型
Pub Date : 2024-06-01 DOI: 10.55845/dtfi9420
Michael P. Schlaile, Jonathan Friedrich, J. Zscheischler
Few studies have explicitly explored regional embeddedness and both the inconsistencies and injustices of circular bioeconomy (CBE) innovations. To better navigate the normative dimension of these innovations and CBE transitions in general, our article presents a threefold argument for the relevance of the regional level of analysis. First, CBE innovations are influenced by and affect regional metabolisms and actor constellations, assets, and (biophysical) resources within regional innovation systems (RIS). Second, thoroughly exploring these dimensions of regional (un)embeddedness can reveal ethical concerns, including potential "dark sides" and injustices, such as exclusivity and exploitation. Third, to address these concerns in CBE research and governance, we outline four facets: complementing the RIS as a framework and policy approach, balancing creative and destructive measures, addressing the need for more inclusive regional CBE policies, and establishing dedicated intermediaries to better govern regional CBE transitions. In summary, this conceptual article provides starting points for further research and proactive measures that help govern the normative dimension and the design of CBE transitions at the regional level, promoting inclusivity, justice, responsibility, and legitimacy for both innovation and exnovation.
很少有研究明确探讨区域嵌入性以及循环生物经济(CBE)创新的不一致性和不公正性。为了更好地把握这些创新和 CBE 过渡的规范性维度,我们的文章从三个方面论证了区域层面分析的相关性。首先,社区经济创新受到区域创新系统(RIS)内的区域新陈代谢和参与者组合、资产和(生物物理)资源的影响。其次,深入探讨区域(非)嵌入性的这些层面可以揭示伦理问题,包括潜在的 "阴暗面 "和不公正,如排他性和剥削。第三,为了在社区经济研究和治理中解决这些问题,我们概述了四个方面:将区域创新体系作为框架和政策方法的补充,平衡创造性和破坏性措施,满足对更具包容性的区域社区经济政策的需求,以及建立专门的中介机构以更好地管理区域社区经济过渡。总之,这篇概念性文章为进一步的研究和前瞻性措施提供了出发点,有助于在地区层面管理社区经济过渡的规范性层面和设计,促进创新和革新的包容性、公正性、责任性和合法性。
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引用次数: 0
From science-policy interface to science-policy panel: The United Nations’ strengthening of the sustainable life cycle management of chemicals 从科学政策界面到科学政策小组:联合国加强化学品的可持续生命周期管理
Pub Date : 2024-06-01 DOI: 10.1016/j.cec.2024.100090
Qiaoyun Zhang , Hairong Zhao , Yuan Chen

In recent years, the chemical production and waste generation have been rapidly increasing, presenting substantial hazards to the ecosystem and human well-being. To address this issue, a series of multilateral environmental agreements (MEAs) have been developed internationally, that provide essential decision-making support for the appropriate governance of chemicals and wastes in the participating countries. MEAs have established subsidiary bodies known as science-policy interface (SPI) institutions to provide evidence-based support and scientific assessments for environmental policies. However, the existing SPIs face limitations that hinder their ability to tackle the obstacles presented by the vast quantities of chemicals and wastes currently found in the environment. Therefore, the fifth session of the United Nations Environment Assembly made the decision to establish a science-policy panel to promote the effective management of chemicals and waste and to prevent pollution (SPP-CWP). This panel is intended to be an independent intergovernmental body, similar to the Intergovernmental Panel on Climate Change and Intergovernmental Science-Policy Platform on Biodiversity and Ecosystem Services. The United Nations Environment Programme convened an ad hoc open-ended working group (OEWG) to design strategies for the SPP-CWP. Since 2022, three OEWG meetings have been conducted, and draft documents outlining the panel's scope, functions, operational principles, conflict of interest policy, institutional setup, work processes, and procedures have been formulated. In this article, we analyzed the background and development of the SPP-CWP and provided updates regarding the progress of the panel's establishment. We also suggested future trends for the SPP-CWP. We concluded that SPP-CWP will be a comprehensive and authoritative international body, providing policymakers with exhaustive reports, consequently strengthening the capacity of life cycle management of chemicals. Thus, the panel will effectively reduce or prevent waste production and pollution, promote material circulation, and minimize resource consumption, making significant contributions to the establishment of a circular economy and an environmentally friendly society.

近年来,化学品生产和废物产生迅速增加,对生态系统和人类福祉造成了巨大危害。为解决这一问题,国际上制定了一系列多边环境协定(MEAs),为参与国妥善治理化学品和废物提供了重要的决策支持。多边环境协定设立了被称为科学政策接口(SPI)机构的附属机构,为环境政策提供循证支持和科学评估。然而,现有的 SPI 面临着各种限制,阻碍了其应对目前环境中发现的大量化学品和废物所带来的障碍的能力。因此,联合国环境大会第五届会议决定设立一个科学政策小组,以促进化学品和废物的有效管理并防止污染(SPP-CWP)。该小组旨在成为一个独立的政府间机构,类似于政府间气候变化专门委员会和生物多样性和生态系统服务政府间科学政策平台。联合国环境规划署召集了一个不限成员名额特设工作组(OEWG),为 SPP-CWP 制定战略。自 2022 年以来,已召开了三次不限成员名额工作组会议,并制定了概述小组范围、职能、运作原则、利益冲突政策、机构设置、工作流程和程序的文件草案。在这篇文章中,我们分析了 SPP-CWP 的背景和发展,并提供了小组成立的最新进展情况。我们还提出了 SPP-CWP 的未来发展趋势。我们认为,SPP-CWP 将成为一个全面而权威的国际机构,为决策者提供详尽的报告,从而加强化学品生命周期管理的能力。因此,该小组将有效减少或防止废物的产生和污染,促进物质循环,最大限度地减少资源消耗,为建立循环经济和环境友好型社会做出重要贡献。
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引用次数: 0
Applications of machine learning tools for biological treatment of organic wastes: Perspectives and challenges 将机器学习工具应用于有机废物的生物处理:前景与挑战
Pub Date : 2024-06-01 DOI: 10.1016/j.cec.2024.100088
Long Chen , Pinjing He , Hua Zhang , Wei Peng , Junjie Qiu , Fan Lü

Biological treatment technologies (such as anaerobic digestion, composting, and insect farming) have been extensively employed to handle various degradable organic wastes. However, the inherent complexity and instability of biological treatment processes adversely affect the production of renewable energy and nutrient-rich products. To ensure stable processes and consistent product quality, researchers have invested heavily in control strategies for biological treatment, with machine learning (ML) recently proving effective in optimizing treatment, predicting parameters, detecting disturbances, and enabling real-time monitoring. This review critically assesses the application of ML in biological treatment, providing an in-depth evaluation of key algorithms. This study reveals that artificial neural networks, tree-based models, support vector machines, and genetic algorithms are the leading algorithms in biological treatment. A thorough investigation of the applications of ML in anaerobic digestion, composting, and insect farming underscores its remarkable capacity to predict products, optimize processes, perform real-time monitoring, and mitigate pollution emissions. Furthermore, this review outlines the challenges and prospects encountered in applying ML to biological treatment, highlighting crucial directions for future research in this area.

生物处理技术(如厌氧消化、堆肥和昆虫养殖)已被广泛用于处理各种可降解有机废物。然而,生物处理过程固有的复杂性和不稳定性对生产可再生能源和营养丰富的产品产生了不利影响。为了确保稳定的工艺和一致的产品质量,研究人员在生物处理的控制策略方面投入了大量资金,机器学习(ML)最近被证明在优化处理、预测参数、检测干扰和实现实时监控方面非常有效。本综述严格评估了 ML 在生物处理中的应用,并对关键算法进行了深入评估。研究表明,人工神经网络、树型模型、支持向量机和遗传算法是生物处理中的主要算法。通过深入研究人工智能在厌氧消化、堆肥和昆虫养殖中的应用,可以发现其在预测产品、优化流程、执行实时监控和减少污染排放方面的卓越能力。此外,本综述还概述了将 ML 应用于生物处理时遇到的挑战和前景,并强调了该领域未来研究的重要方向。
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引用次数: 0
Recent progress and hurdles in cathode recycling for Li-ion batteries 锂离子电池正极回收的最新进展和障碍
Pub Date : 2024-06-01 DOI: 10.1016/j.cec.2024.100087
Ponraj Jenis , Ting Zhang , Brindha Ramasubramanian , Sen Lin , Prasada Rao Rayavarapu , Jianguo Yu , Seeram Ramakrishna

This review focuses on standard Li recycling approaches for LiFePO4 (LFP) and nickel−cobalt−manganese (NCM) cathodes. The study discusses about advances in leaching agents, including organic acid, alkaline solutions, natural organic acid, and electrochemical treatments. Emphasis is placed on the significance of selective Li leaching strategies to optimize the recycling of waste batteries. The review also outlines potential future research directions for enhancing selective recycling, providing valuable insights into the recycling of LFP and NCM batteries. Simultaneously, the article addresses the challenges associated with the transition from conventional lithium-ion batteries to all-solid-state batteries (ASSBs) in the pursuit of sustainable energy storage technologies. It highlights key points, including the challenges in developing ASSBs, the role of employing various material combinations and its preparation techniques, adopting scalable solution-based processes for commercialization, and strategies for sustainable ASSB recycling. The proposition of a fully recyclable ASSB model underscores the commitment to lower recycling costs using safer and simpler methods, positioning nanotechnology as an enabling tool for achieving advancements in materials and cell-level performance.

本综述侧重于磷酸铁锂(LFP)和镍钴锰(NCM)阴极的标准锂回收方法。研究讨论了浸出剂方面的进展,包括有机酸、碱性溶液、天然有机酸和电化学处理。重点强调了选择性锂浸出策略对优化废电池回收利用的重要意义。文章还概述了加强选择性回收利用的潜在未来研究方向,为 LFP 和 NCM 电池的回收利用提供了宝贵的见解。同时,文章探讨了从传统锂离子电池过渡到全固态电池 (ASSB) 以实现可持续能源存储技术所面临的挑战。文章强调了一些要点,包括开发全固态电池的挑战、采用各种材料组合及其制备技术的作用、采用可扩展的基于溶液的工艺实现商业化,以及可持续的全固态电池回收战略。提出完全可回收的 ASSB 模型强调了使用更安全、更简单的方法降低回收成本的承诺,并将纳米技术定位为实现材料和电池级性能进步的有利工具。
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引用次数: 0
Trash or treasure? A circular business model of recycling plasmix 垃圾还是宝藏?循环利用的商业模式plasmix
Pub Date : 2024-06-01 DOI: 10.1016/j.cec.2024.100089
Federico Zilia , Francesca Gaia Andreottola , Luigi Orsi , Marco Parolini , Jacopo Bacenetti

The production of plastic materials in the mid-20th century brought about transformative changes in consumer goods manufacturing and societal norms. However, this advancement paralleled an alarming surge in plastic pollution, driven by unrestrained consumption. This study focuses on the non-homogeneous and non-recyclable plastic waste (also known as plasmix in the Italian waste management), a residual blend resulting from plastic recycling processes. The main goals are to conduct an in-depth study of the plasmix landscape, to identify integration challenges, and to create a sustainable business model for broader adoption. Additionally, we aim to use life cycle assessment to examine the environmental effects of semi-finished plasmix-based materials that can be used to produce different products. This integrated approach ensures a holistic understanding of plasmix recycling, promoting both economic and environmental sustainability. The study contributes to sustainable waste management practices by offering a strategic approach to transform a challenging waste stream into economic opportunities. By addressing the market viability of plasmix-based products through an empirically supported business model, the research underscores the significance of recycling in mitigating plastic pollution and advancing a circular economy.

20 世纪中期,塑料材料的生产给消费品制造和社会规范带来了变革。然而,与此同时,在无节制消费的推动下,塑料污染也出现了惊人的增长。本研究的重点是塑料回收过程中产生的非均质、不可回收的塑料废物(在意大利废物管理中也被称为 plasmix)。主要目标是深入研究 plasmix 的现状,确定整合方面的挑战,并为更广泛的应用创建一个可持续的商业模式。此外,我们还打算利用生命周期评估来研究可用于生产不同产品的半成品塑性基材料对环境的影响。这种综合方法可确保全面了解净浆回收利用,促进经济和环境的可持续发展。这项研究提供了一种将具有挑战性的废物流转化为经济机会的战略方法,有助于可持续废物管理实践。该研究通过一个经验支持的商业模式来解决基于塑性体的产品的市场可行性问题,从而强调了回收利用在减轻塑料污染和促进循环经济方面的重要意义。
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引用次数: 0
Reveal dynamic flows of regional e-waste: Evidence from a field research 揭示区域电子废物的动态流动:来自实地研究的证据
Pub Date : 2024-06-01 DOI: 10.1016/j.cec.2024.100086
Chonggang Yang , Bingyu Xu , Zhikun Zhu , Yan He , Yujia Wang , He Xu , Mo Zhang

Electronic waste (e-waste) has increased because of the rapid replacement of electrical and electronic equipment. Owing to the increased emphasis on the dual properties of environmental contamination and metal resources, accurate identification of the e-waste recycling process is crucial. In this study, a product-level material flow analysis (MFA) is performed from a macroscopic social flow of waste TV sets in order to demonstrate the material metabolism of regional e-waste recycling. Previous studies have focused on the estimation of the quantity of e-waste generated or analyzing the overall amount of recycled resource output, the results derived from the estimation may have some unreliability, and our bottom-up research investigates the material flows that occur between the generation, collection and recycling of e-waste. MFA based on questionnaires and field research present accurate quantities and proportions of the recycling process. The results reveal that accelerating the construction of regional e-waste recycling systems and data networks and accurately identifying e-waste source, flow, and destination are required in order to improve resource efficiency toward carbon neutrality.

由于电气和电子设备的快速更新换代,电子废物(e-waste)也随之增加。由于环境污染和金属资源的双重属性日益受到重视,准确识别电子垃圾的回收过程至关重要。本研究从废弃电视机的宏观社会流出发,进行了产品层面的物质流分析(MFA),以展示区域电子废弃物回收利用的物质代谢过程。以往的研究主要关注电子废弃物产生量的估算或再生资源产出总量的分析,估算得出的结果可能存在一定的不稳定性,而我们的研究是自下而上地调查电子废弃物产生、收集和回收之间的物质流。基于问卷调查和实地研究的 MFA 呈现了回收过程中的准确数量和比例。研究结果表明,为了提高资源效率,实现碳中和,必须加快建设区域电子废物回收系统和数据网络,并准确识别电子废物的来源、流向和去向。
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引用次数: 0
期刊
Circular Economy
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