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Vat Photopolymerization of Al2O3/Borosilicate Glass Low Temperature Co-Fired Ceramic Substrates With Integrated Micropore Patterning Device Al2O3/硼硅酸盐玻璃低温共烧陶瓷基板的还原光聚合及集成微孔图图化装置
Pub Date : 2025-08-13 DOI: 10.1109/TMAT.2025.3598753
Yizhen Chu;Yujuan Zhou;Mingyong Jia;Qianshun Cui;Haiyuan Shi;Zhifeng Huang;Fei Chen
Low temperature co-fired ceramics (LTCC) have garnered significant attention due to their exceptional electrical and thermal properties. While the traditional tape casting method for preparing LTCC substrates yields high density, it is constrained by limited geometric freedom and a complex process, making it less suitable for contemporary demands. In this study, we employ vat photopolymerization 3D printing technology to fabricate alumina/borosilicate glass composite LTCC systems and introduce a microporous structure design on the substrate. This innovation simplifies the traditional punching step, enhancing both productivity and reliability. We formulated LTCC slurry suitable for vat photopolymerization and examined the thermal conductivity and dielectric properties of the sintered parts. The findings reveal that samples held at 750 °C for 30 minutes achieved the highest densities, exhibiting a thermal conductivity of 3.63 W·m−1·K−1, a relative dielectric constant of 13.09, and the lowest dielectric loss (7.9 × 10−3). We successfully realized microporous printing on LTCC substrates, achieving microporous structures with an actual diameter of 132 μm. Additionally, we verified the compatibility of substrates with silver co-firing, observing a robust bond between the silver layer and the LTCC layer. This study underscores the potential of vat photopolymerization for LTCC applications.
低温共烧陶瓷(LTCC)由于其优异的电学和热学性能而引起了人们的极大关注。虽然用于制备LTCC基板的传统带铸造方法产生高密度,但它受到有限的几何自由度和复杂工艺的限制,使其不太适合当代需求。在本研究中,我们采用还原光聚合3D打印技术制造氧化铝/硼硅酸盐玻璃复合材料LTCC系统,并在基板上引入微孔结构设计。这种创新简化了传统的冲孔步骤,提高了生产率和可靠性。配制了适合于还原光聚合的LTCC浆料,并对烧结件的导热性能和介电性能进行了测试。结果表明,在750°C下保温30分钟的样品密度最高,导热系数为3.63 W·m−1·K−1,相对介电常数为13.09,介电损耗最低(7.9 × 10−3)。我们成功地在LTCC基板上实现了微孔印刷,实现了实际直径为132 μm的微孔结构。此外,我们验证了衬底与银共烧的相容性,观察到银层和LTCC层之间的牢固结合。这项研究强调了还原光聚合在LTCC应用中的潜力。
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引用次数: 0
BEOL-Compatible 5.6 nm Ultrathin HZO With Molybdenum Nitride Electrode and IN2O3 Channel Devices for Enhanced Ferroelectricity and Reliability beol兼容5.6 nm超薄HZO与氮化钼电极和IN2O3通道器件增强铁电性和可靠性
Pub Date : 2025-07-07 DOI: 10.1109/TMAT.2025.3586809
Li-Cheng Teng;Yu-Che Huang;Shin-Yuan Wang;Yu-Hsien Lin;Chao-Hsin Chien
In this letter, we have successfully fabricated a metal-ferroelectricity-metal (MFM) capacitor of an ultrathin 5.6 nm HZO and ultrathin In2O3 back gate devices in a back-end-of-line (BEOL) compatible process. By proposing a novel atomic layer deposition (ALD) scheme and an alternative bottom electrode treatment, the MoN-HZO sample shows an average 2Pr value of 64 μC/cm2 (with a standard deviation of 0.52) and high endurance (△2Pr/2Prpristine ≈2% from pristine to 1010 cycles). The MoN–HZO stack integrated with an ultrathin In2O3 back gate exhibits a memory window (MW) greater than 2.5 V and excellent endurance and data retention characteristics. With a maximum process temperature of 400°C, our approach meets the stringent requirements for Back-End-of-Line (BEOL) integration.
在这篇文章中,我们成功地以后端线(BEOL)兼容工艺制作了超薄5.6 nm HZO和超薄In2O3后门器件的金属-铁电性-金属(MFM)电容器。通过提出一种新的原子层沉积(ALD)方案和一种替代底电极处理方法,MoN-HZO样品的平均2Pr值为64 μC/cm2(标准差为0.52),并且具有较高的续航能力(从原始循环到1010次循环,△2Pr/2Prpristine≈2%)。与超薄In2O3后门集成的mo - hzo堆叠具有大于2.5 V的记忆窗口(MW)和优异的耐用性和数据保留特性。由于最高工艺温度为400°C,我们的方法满足严格的后端线(BEOL)集成要求。
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引用次数: 0
Call for Papers: Special Issue of IEEE Transactions on Electron Devices on Reliability of Advanced Nodes 论文征集:IEEE高级节点可靠性电子器件学报特刊
Pub Date : 2025-06-27 DOI: 10.1109/TMAT.2025.3583512
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引用次数: 0
Tunable Density-of-States in Chromium Oxide Thin Films via Room Temperature Laser Ablation 室温激光烧蚀氧化铬薄膜的可调态密度
Pub Date : 2025-06-19 DOI: 10.1109/TMAT.2025.3581508
Angel Regalado-Contreras;Wencel de la Cruz
Chromium oxide thin films were deposited at room temperature, via reactive laser ablation under varying O2 pressures and analyzed using in-situ X-ray Photoelectron Spectroscopy. Cr 2p spectra exhibited spin-orbit splitting, with peak separations ranging from 9.2 to 9.5 eV. Cr3+, and Cr4+ states were identified, with 2p3/2 binding energies between 576.8 and 582.5 eV. Quantitative analysis confirmed that lower O2 pressures favored Cr2O3 growth, while higher pressures promoted CrO2. Near-Fermi-level spectra revealed significant Density-Of-States modulation, with the Valence Band Maximum shifting from 1.25 to 3.3 eV. A direct correlation between O2 pressure and electronic structure was established.
在室温下,通过反应性激光烧蚀在不同的O2压力下沉积氧化铬薄膜,并使用原位x射线光电子能谱分析。cr2p光谱表现出自旋轨道分裂,峰值分离在9.2 ~ 9.5 eV之间。鉴定出Cr3+、Cr4+态,2p3/2结合能在576.8 ~ 582.5 eV之间。定量分析证实,较低的O2压力有利于Cr2O3的生长,而较高的O2压力有利于cr2的生长。近费米能级谱显示出明显的态密度调制,价带最大值从1.25 eV移至3.3 eV。建立了氧压力与电子结构之间的直接关系。
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引用次数: 0
Transferable Freestanding Varactor Based on a Membrane Stack for Microwave Application 基于膜堆的可转移独立式变容管微波应用
Pub Date : 2025-06-17 DOI: 10.1109/TMAT.2025.3580484
Yating Ruan;Philipp Komissinskiy;Alexey Arzumanov;Holger Maune;Lambert Alff
This work demonstrates the fabrication and characterization of a freestanding oxide varactor membrane designed for integration onto silicon substrates. An epitaxial varactor heterostructure composed of a 1% Mn-doped Ba$_{0.5}$Sr$_{0.5}$TiO$_{3}$ dielectric layer and a $rm {SrMoO}_{3}$ conductive layer was grown using pulsed laser deposition on a water-soluble sacrificial layer $rm {Sr_{3}Al_{2}O_{6}}$. After the lift-off process, the varactor heterostructure was successfully transferred onto a silicon substrate. Structural analysis confirms the high crystallinity and strain relaxation of the heterostructure after transfer. Electrical measurements reveal high tunability (n=1.7) at 120 V/$mu rm {m}$, a quality factor exceeding 100 at 1 MHz, and a low leakage current density well below 5 $text{A/m}^{2}$. This approach overcomes the challenges of direct oxide growth of epitaxial varactor heterostructures on silicon, such as lattice mismatch and chemical incompatibility. These results validate the potential of freestanding varactor membranes for agile microwave and RF applications, offering a scalable route for high-performance, multifunctional devices with low energy consumption in next-generation telecommunications and wireless networks.
这项工作展示了一种设计用于集成到硅衬底上的独立氧化物变容薄膜的制造和表征。在水溶性牺牲层$rm {Sr_{3}Al_{2}o_{6}}$上,采用脉冲激光沉积技术生长出由1% mn掺杂Ba$ {0.5}$Sr$ {0.5}$TiO$_{3}$介电层和$rm {SrMoO}_{3}$导电层组成的外延变容异质结构。在提升过程之后,变容异质结构成功地转移到硅衬底上。结构分析证实了转移后异质结构的高结晶度和应变弛豫。电测量结果显示,在120 V/$mu rm {m}$时具有高可调性(n=1.7),在1 MHz时质量因数超过100,漏电流密度低,远低于5 $text{a /m}^{2}$。这种方法克服了在硅上直接氧化生长外延变容异质结构的挑战,如晶格失配和化学不相容性。这些结果验证了独立变容膜在敏捷微波和射频应用中的潜力,为下一代电信和无线网络中的高性能、多功能、低能耗设备提供了可扩展的途径。
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引用次数: 0
Improved Performance of Yttrium Oxide-Based Memristor Through TiN Electrodes and Device Scaling for Neuromorphic and Pattern Recognition 基于TiN电极的氧化钇基忆阻器性能改进及神经形态和模式识别的器件缩放
Pub Date : 2025-06-13 DOI: 10.1109/TMAT.2025.3579714
Sanjay Kumar;Shalu Rani
Herein, we present a CMOS-compatible fabrication process, in-depth materials, and electrical analysis of yttrium oxide (Y2O3)-based memristive devices having a device size of 100 μm2. The fabricated devices exhibit improved performance by incorporating TiN electrodes and device scaling and efficiently emulate the various low-power neuromorphic and pattern recognition tasks. The fabricated memristive devices exhibit stable bipolar resistive switching behavior with an excellent endurance beyond 50,000 cycles and retention properties exceeding 106 s by maintaining a very high ON/OFF ratio of 104. Additionally, the fabricated devices show remarkable stability in the device switching voltages under cycle-to-cycle (C2C) and device-to-device (D2D) wherein, the coefficient of variability (CV) in the device switching voltages in C2C and D2D is 4.95% and 11.39%, respectively. Moreover, the fabricated devices efficiently emulate the synaptic response by emulating potentiation, depression, paired-pulse facilitation (PPF), and paired-pulse depression (PPD) and also exhibit the device conductance tunability under the variations in the pulse width as similar to the biological synapse counterpart. Furthermore, the fabricated devices efficiently show the pattern recognition task by achieving an accuracy of 88.2% for the handwriting MNIST dataset. Therefore, the present work opens a new horizon in the field of miniaturized artificial synapses and neuromorphic computing to perform various operations.
在此,我们提出了一种cmos兼容的制造工艺,深入的材料,以及器件尺寸为100 μm2的基于氧化钇(Y2O3)的忆阻器件的电学分析。制造的器件通过结合TiN电极和器件缩放来提高性能,并有效地模拟各种低功耗神经形态和模式识别任务。所制备的记忆器件表现出稳定的双极电阻开关行为,具有超过50,000次循环的优异耐久性和超过106 s的保持性能,保持非常高的开/关比为104。此外,所制备的器件在cycle-to-cycle (C2C)和device-to-device (D2D)下的开关电压表现出显著的稳定性,其中C2C和D2D下器件开关电压的变异系数(CV)分别为4.95%和11.39%。此外,制备的器件通过模拟增强、抑制、配对脉冲促进(PPF)和配对脉冲抑制(PPD)有效地模拟了突触反应,并且在脉冲宽度变化下表现出与生物突触相似的器件电导可调性。此外,该装置有效地完成了手写MNIST数据集的模式识别任务,准确率达到了88.2%。因此,本研究为小型化人工突触和神经形态计算领域开辟了新的视野,以执行各种操作。
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引用次数: 0
Call for Papers: Ultrawide Band Gap Semiconductor Devices for RF, Power and Optoelectronic Applications 论文征集:用于射频、功率和光电应用的超宽带隙半导体器件
Pub Date : 2025-04-21 DOI: 10.1109/TMAT.2025.3562290
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引用次数: 0
IEEE Electron Devices Society 电子器件学会
Pub Date : 2025-04-17 DOI: 10.1109/TMAT.2025.3561623
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引用次数: 0
Implementation of Low Temperature Co-Fired Ceramic Packages for All Solid-State Hydrogen Sensor Modules 全固态氢传感器模块低温共烧陶瓷封装的实现
Pub Date : 2025-04-17 DOI: 10.1109/TMAT.2025.3562178
Mun-Cheol Paek;Han-Won Ryu;Hyun Hwangbo;Yong-Ha Lee;Chong-Ook Park
We have implemented LTCC (Low Temperature Co-Fired Ceramics) based packages for all solid-state electrochemical hydrogen sensor modules. The hydrogen sensor utilizing a solid electrolyte is designed to have a hetero-junction structure of a proton conductor and an oxygen ion conductor. LTCC is a composite material of ceramic powders and glass frits, and can be sintered at a low temperature of 900 °C or less, and has superior electrical, mechanical, and thermal properties compared to PCB. In this study, we developed a package technology for hydrogen sensor modules using this LTCC material. A double layer structure is used to form the package, and in the bottom plate, a mount for the hydrogen sensor, line guides for air flow, and guides to support the wires are fabricated. Laser pulses are employed to form 3D structures of LTCC including the mounting cavities and vias to connect the metal electrodes of the sensor. The hydrogen sensor is mounted in the center of the bottom plate and connected to the Ag/Pt electrode formed at the backside of the plate through 4 wires and via holes. The measurement results to check the hydrogen response of the sensors using LTCC packages show that the solid-state electrochemical voltage change from 248.2 ∼ 296.4 mV to 472.8 ∼ 554.5.2 mV for hydrogen concentration from 0.5 to 4.0% in the air. The electrochemical voltage of this sensor is linearly proportional to the logarithm of the hydrogen partial pressure. The reproducibility tests show that the change of the sensitivity of the sensor was within 4.3% deviation for 3 times repeat test. This reaction sensitivity remains the same with a deviation of less than 1.2% in the test even after 52 days. In the thermal shock test for environmental evaluation, all hydrogen sensor packages fabricated in this study show normal operation.
我们已经为所有固态电化学氢传感器模块实现了基于LTCC(低温共烧陶瓷)的封装。利用固体电解质的氢传感器被设计成具有质子导体和氧离子导体的异质结结构。LTCC是陶瓷粉末和玻璃熔块的复合材料,可以在900°C或更低的低温下烧结,与PCB相比具有优越的电气,机械和热性能。在这项研究中,我们开发了一种使用这种LTCC材料的氢传感器模块封装技术。采用双层结构形成封装,并在底板中制作了用于氢气传感器的安装座,用于气流的线导轨和用于支撑导线的导轨。利用激光脉冲形成LTCC的三维结构,包括安装腔和连接传感器金属电极的通孔。氢气传感器安装在底板中央,通过4根导线和通孔与底板背面形成的Ag/Pt电极相连。使用LTCC封装检查传感器氢响应的测量结果表明,当空气中氢浓度从0.5到4.0%时,固态电化学电压从248.2 ~ 296.4 mV变化到472.8 ~ 554.5.2 mV。该传感器的电化学电压与氢气分压的对数成线性比例。重复性试验表明,重复试验3次,传感器灵敏度变化偏差在4.3%以内。该反应敏感性在52天后仍保持不变,偏差小于1.2%。在环境评价的热冲击试验中,本研究制作的所有氢传感器封装均表现出正常的工作状态。
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引用次数: 0
Overview of Testing Methods for Mechanical and Adhesion Properties of Materials in Semiconductor Packages 半导体封装材料机械和粘附性能测试方法综述
Pub Date : 2025-04-16 DOI: 10.1109/TMAT.2025.3561740
Seung Jin Oh;Jae Hak Lee;Seung Man Kim;Seongheum Han;Ah-Young Park;Hyunkyu Moon;Jun-Yeob Song
Mechanical testing methodologies are essential for advancing semiconductor packaging processes, ensuring the mechanical reliability of devices subjected to increasingly complex manufacturing processes and operational conditions. In recent years, advanced packaging technologies, including system-in-package (SiP) using 2.xD and 3D integration, have played a crucial role in enabling high-performance electronic devices. However, the miniaturization of device structures and integration of materials with mismatched thermomechanical properties have introduced significant mechanical challenges, including warpage, interfacial delamination, and fracture-induced failures. This review comprehensively evaluates key mechanical testing methodologies used to characterize the material properties and interfacial reliability of materials in semiconductor packages. Techniques such as the tensile test and double-cantilever beam (DCB) test are critically examined, with a focus on their effectiveness in assessing thin-film mechanical behavior, adhesion properties, and fracture mechanisms in miniaturized semiconductor structures. Furthermore, this review highlights the limitations of traditional testing techniques in micro- and nanoscale applications and explores emerging testing approaches. By providing a comparative analysis of mechanical testing techniques and their applications in semiconductor packaging, this work aims to provide insights for optimizing reliability evaluation strategies and guiding future developments in advanced packaging technologies.
机械测试方法对于推进半导体封装工艺至关重要,确保设备在日益复杂的制造工艺和操作条件下的机械可靠性。近年来,先进的封装技术,包括系统级封装(SiP)的使用。xD和3D集成,在实现高性能电子设备方面发挥了至关重要的作用。然而,器件结构的小型化和热机械性能不匹配的材料集成带来了重大的机械挑战,包括翘曲、界面分层和断裂诱发失效。本文全面评估了用于表征半导体封装材料性能和界面可靠性的关键机械测试方法。拉伸测试和双悬臂梁(DCB)测试等技术进行了严格的研究,重点是它们在评估小型化半导体结构中的薄膜力学行为、粘附性能和断裂机制方面的有效性。此外,本文强调了传统测试技术在微纳米级应用中的局限性,并探讨了新兴的测试方法。通过对机械测试技术及其在半导体封装中的应用进行比较分析,本工作旨在为优化可靠性评估策略和指导先进封装技术的未来发展提供见解。
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引用次数: 0
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IEEE Transactions on Materials for Electron Devices
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