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Adsorption of iron (II) ions from aqueous solution using Miscanthus biochar as a sustainable bioresource – preliminary batch studies 芒草生物炭作为可持续生物资源吸附水溶液中铁离子的初步批量研究
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100197
Mark C. Leaper, Li Xuan Yeo, Diganta B. Das, Sean Creedon, Rob Bentham
This study examines the feasibility of using mischanthus biochar to remove Fe2 + ions from a neutral solution, a situation commonly found in well boreholes; this is increasingly relevant in water-stressed areas, where cheap decentralized water treatment is more appropriate. Mischanthus biochar produced at 700°C was investigated for its capacity to adsorb iron (II) ions using 50 mL solution batches at a starting a concentration of 1000 mgL−1 at pH 7.0. It was found that a biochar dosage of 1 g removed up to 90 % of iron (II) ions and that adsorption kinetics were pseudo-second order, showing a prevalence of chemisorption. Our data also showed that the adsorption followed the Langmuir isotherm model, with the Miscanthus biochar having an adsorption capacity of around 40 mgg−1, similar to previous studies at the same conditions. This study demonstrated that even without post-treatment, miscanthus biochar is feasible as an adsorbent of Fe2+ and further investigation to optimize a decentralized water treatment system is appropriate.
本研究考察了利用mischanthus生物炭从中性溶液中去除Fe2 +离子的可行性,这种情况在井眼中很常见;这在水资源紧张的地区日益重要,因为在这些地区廉价的分散式水处理更为合适。研究了在700°C下生产的芒草生物炭吸附铁(II)离子的能力,使用50个 mL溶液批次,起始浓度为1000 mgL−1,pH 7.0。结果表明,1 g的生物炭对铁(II)离子的去除率高达90% %,吸附动力学为准二级,表现出普遍的化学吸附。我们的数据还表明,吸附遵循Langmuir等温线模型,芒草生物炭的吸附量约为40 mg−1,与之前的研究在相同条件下相似。本研究表明,即使没有后处理,芒草生物炭作为Fe2+的吸附剂也是可行的,进一步研究优化分散式水处理系统是合适的。
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引用次数: 0
Exploring blockchain technology adoption challenges in the pharmaceutical industry to promote sustainability: A Pythagorean fuzzy approach 探索区块链技术在制药行业采用的挑战,以促进可持续性:一个毕达哥拉斯模糊方法
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100162
Md Zahidul Anam , Soumik Sarkar , A.B.M. Mainul Bari , Abu Reza Md. Towfiqul Islam , Asif Raihan
The adoption of blockchain technology holds enormous potential to promote sustainability in the pharmaceutical industry. Blockchain technology can be employed to monitor medicine movements, check drug authenticity, manage patient information, and improve the overall supply chain sustainability performance and data management. However, there are considerable challenges associated with adopting and implementing blockchain technology in the pharmaceutical sector, particularly in an emerging economy like Bangladesh. This study, therefore, aims to develop a framework that identifies and analyzes the challenges in emerging economies using an integrated Multi-Criteria Decision Making (MCDM) approach combining Pythagorean fuzzy theory with the decision-making trial and evaluation laboratory (DEMATEL) method. First, the key challenges were identified from the literature review and expert feedback. Then, the Pythagorean fuzzy DEMATEL (PF-DEMATEL) method was used to assess, rank, and explore the relations among these identified challenges. The obtained results suggest that the most crucial challenges to adopting blockchain technology in the pharmaceutical industry in emerging economies are the complexity to integrate blockchain into the existing system (prominence weight 6.699), data storage and security issues (prominence weight 6.495), and lack of proper IT infrastructure (prominence weight 6.376). Results also indicate that the lack of long-term vision for sustainable implementation (causal weight 1.231) is the most influential, and the lack of universal applicability and proper standardization (causal weight −0.30) is the most influenced challenge. The study's outcome is expected to aid industry managers and policymakers in devising more outcome-based strategies to successfully implement blockchain technology and ensure long-term sustainability in the pharmaceutical sector.
采用区块链技术在促进制药工业的可持续性方面具有巨大的潜力。区块链技术可用于监测药品流动,检查药品真伪,管理患者信息,提高整体供应链可持续性绩效和数据管理。然而,在制药部门采用和实施区块链技术存在相当大的挑战,特别是在孟加拉国这样的新兴经济体。因此,本研究旨在开发一个框架,利用将毕达哥拉斯模糊理论与决策试验和评估实验室(DEMATEL)方法相结合的综合多标准决策(MCDM)方法,识别和分析新兴经济体面临的挑战。首先,从文献综述和专家反馈中确定了主要挑战。然后,使用毕达哥拉斯模糊DEMATEL (PF-DEMATEL)方法来评估、排序和探索这些已识别挑战之间的关系。研究结果表明,新兴经济体制药行业采用区块链技术面临的最关键挑战是将区块链集成到现有系统中的复杂性(突出权重为6.699)、数据存储和安全问题(突出权重为6.495)以及缺乏适当的IT基础设施(突出权重为6.376)。结果还表明,缺乏可持续实施的长期愿景(因果权重为1.231)是影响最大的挑战,缺乏普遍适用性和适当的标准化(因果权重为- 0.30)是影响最大的挑战。这项研究的结果有望帮助行业管理者和决策者制定更多基于结果的战略,以成功实施区块链技术,并确保制药行业的长期可持续性。
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引用次数: 0
Experimental performance investigation on the effect of step change in absorber plate thickness of flat plate solar collector 平板太阳能集热器吸收板厚度阶跃变化影响的实验性能研究
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100142
Md. Shamiul Basar Himel , Mahmudul Hasan , Md. Hasan Ali , Nahyan Ahnaf Pratik , Md Akib Ul Islam , Fahim Tanvir , Adrita Anwar , Md. Jabed Alam
Over the years, several geometrical and operational improvements have been made to the solar flat plate collector to utilize the solar energy more effectively. The present study investigated the effect of the step-change in absorber plate thickness on the thermal performance of flat plate solar collectors (FPCs). Two configurations were developed of which one featuring a uniform absorber plate thickness of 0.4 cm and the other exhibiting a variable thickness, segmenting the plate into equal portions of 0.2 cm and 0.6 cm. Both designs were assessed under diverse solar radiation and meteorological situations to measure their heat gain, temperature increase, and efficiency. The findings indicated that the step-changed design attained an efficiency enhancement of 4.6–12.7 % compared to the uniform plate, with peak efficiency reaching 67.7 %. The thicker portion of the step-changed plate improved thermal performance by decreasing thermal resistance and maintaining heat transfer during variable radiation conditions. Nonetheless, its thermal inertia impeded heat transmission under low radiation circumstances. These findings illustrate the potential of step-changed absorber plates as a cost-efficient, enhanced thermal performance substitute for FPCs, providing significant insights for the advancement of solar thermal technology.
多年来,为了更有效地利用太阳能,对太阳能平板集热器进行了几项几何和操作上的改进。本文研究了吸收板厚度阶跃变化对平板太阳能集热器热性能的影响。开发了两种配置,其中一种具有均匀的吸收板厚度0.4 cm,另一种具有可变厚度,将板分割为0.2 cm和0.6 cm的相等部分。两种设计都在不同的太阳辐射和气象条件下进行了评估,以测量它们的热增益、温度升高和效率。结果表明,与均匀板相比,变阶设计的效率提高了4.6 ~ 12.7 %,峰值效率达到67.7 %。变阶板的较厚部分通过降低热阻和在可变辐射条件下保持传热来改善热性能。然而,它的热惯性阻碍了低辐射环境下的热传递。这些发现说明了阶梯式吸收板作为一种具有成本效益、增强热性能的fpc替代品的潜力,为太阳能热技术的进步提供了重要的见解。
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引用次数: 0
A comprehensive study of variability in total column of ammonia using quantile regression approach over non-attainment cities of the North-Western Himalayas 利用分位数回归方法对西北喜马拉雅地区非达标城市氨总柱变异性的综合研究
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100146
Akshay , Ashish Dogra , Dilbag Singh , Ankit Tandon
The present study has investigated the relationship between total column ammonia (TCNH₃) and different environmental factors in the non-attainment regions viz., Damtal, Baddi and Paonta Sahib in the North-Western Himalayas. The 12 years satellite data was obtained from the Infrared Atmospheric Sounding Interferometer (IASI) and the quantile regression (QR) tool was used to study the variability in long-term trends of TCNH₃ across its distribution. The maximum concentration of TCNH₃ was observed during July in Paonta Sahib followed by Baddi and Damtal. Simultaneously, august month shows notable decrease in TCNH₃ levels, while winter season again shows opposite trend in Paonta Sahib. Further, a significant positive correlation is observed between TCNH₃ and key environmental variables such as PM2.5, temperature, total column water vapour (TCWV), and rainfall. Similarly, an increasing trend was also highlighted in higher quantile (τ>0.8) across all cities, while, negative trend was observed (τ<0.8) in Damtal and Paonta Sahib. Additionally, PM2.5 levels displayed substantial positive trends in significantly higher quantiles (τ>0.95), while rainfall showed significant variability with notable negative trends in higher quantiles (τ>0.9). Overall, the present study enhanced the understanding of TCNH₃ variability across the three non-attainment cities of Himachal Pradesh, emphasizing the need for continued monitoring and targeted environmental management strategies to mitigate the impact of industrial emissions on air quality and public health.
本文研究了西北喜马拉雅地区Damtal、Baddi和Paonta Sahib地区的总塔氨(TCNH₃)与不同环境因子的关系。利用红外大气探测干涉仪(IASI)的12年卫星数据,利用分位数回归(QR)工具研究了TCNH₃在其分布上的长期变化趋势。7月份,Paonta Sahib的TCNH₃浓度最高,其次是Baddi和Damtal。同时,8月份的TCNH₃水平明显下降,而冬季在Paonta Sahib再次出现相反的趋势。此外,TCNH₃与PM2.5、温度、总水柱水蒸气(twv)和降雨量等关键环境变量之间存在显著的正相关。同样,所有城市的高分位数(τ>0.8)也有增加的趋势,而Damtal和Paonta Sahib的趋势为负(τ<0.8)。此外,PM2.5水平在显著较高的分位数(τ>0.95)表现出显著的正趋势,而降雨量在显著较高的分位数(τ>0.9)表现出显著的负趋势。总的来说,本研究加强了对喜马恰尔邦三个未达标城市的TCNH₃可变性的了解,强调需要继续监测和有针对性的环境管理战略,以减轻工业排放对空气质量和公共健康的影响。
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引用次数: 0
Multiple vapor compressors for enhanced performance and cost savings in vacuum membrane distillation 多蒸汽压缩机,提高性能和节省成本的真空膜蒸馏
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100160
Suhaib M. Alawad , Osman Shamet , Dahiru Lawal , Atia E. Khalifa
This study investigates the performance of a multistage vacuum membrane distillation (MSVMD) system integrated with multiple mechanical vapor compressors (MVCs) to enhance energy recovery and improve cost-effectiveness. A comprehensive analysis is conducted to evaluate key performance indicators, including system productivity, specific energy consumption (SEC), and water production cost, across six different VMD configurations. Additionally, the effects of operational parameters such as feed temperature, vacuum pressure, and compressor efficiency are examined through a detailed parametric study. Results indicate that integrating 10 MVCs with the VMD system achieves a maximum freshwater production of 1045 L/h, representing a 297 % increase compared to a system with a single MVC at a feed temperature of 90°C. The lowest SEC recorded is 78 kWh/m³ , attained using 6 MVCs with a compressor efficiency of 90 %, leading to a minimum water production cost of 6.3 $/m³ . However, further analysis reveals that while increasing the number of MVCs enhances productivity and energy efficiency, it also raises capital investment due to the high initial cost of compressors. The operating cost primarily depends on electricity consumption, while maintenance costs escalate with the number of compressors due to additional servicing requirements. A cost-benefit analysis suggests that beyond 10 MVCs, the marginal gains in productivity are offset by rising costs, indicating an optimal balance between energy savings and economic feasibility. This study provides valuable insights into the economic and operational trade-offs of integrating MVCs with VMD, offering a viable pathway for large-scale desalination and water treatment applications.
本文研究了多级真空膜蒸馏(MSVMD)系统与多个机械蒸汽压缩机(MVCs)集成的性能,以提高能量回收和提高成本效益。对六种不同的VMD配置进行了综合分析,以评估关键性能指标,包括系统生产率、比能耗(SEC)和产水成本。此外,通过详细的参数研究,考察了进料温度、真空压力和压缩机效率等操作参数的影响。结果表明,在进料温度为90°C时,将10个MVC集成到VMD系统中可以实现1045 L/h的最大淡水产量,与单个MVC系统相比,增加了297 %。记录的最低SEC为78 kWh/m³ ,使用6个mvc,压缩机效率为90% %,最低产水成本为6.3美元/m³ 。然而,进一步的分析表明,虽然增加mvc的数量可以提高生产率和能源效率,但由于压缩机的初始成本较高,它也增加了资本投资。运行成本主要取决于电力消耗,而由于额外的维修要求,维护成本随着压缩机数量的增加而上升。一项成本效益分析表明,超过10个mvc,生产率的边际收益被成本上升所抵消,这表明了节能与经济可行性之间的最佳平衡。该研究为MVCs与VMD相结合的经济和运营权衡提供了有价值的见解,为大规模海水淡化和水处理应用提供了可行的途径。
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引用次数: 0
Comprehensive first-principles study of structural, electronic, optical, and elastic properties of FrBCl3 (B = Mg & Ba) cubic perovskites FrBCl3 (B = Mg & Ba)立方钙钛矿结构、电子、光学和弹性性质的综合第一性原理研究
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100169
Sahadat Jaman, K.M. Kamruzzaman, Md. Rokonuzzaman Rokon, Faria Farjana, Mohammad Abdur Rashid, Md. Borhanul Asfia
Lead free metal halide Perovskites have recently received attention for their use in light-emitting diodes, solar cells, lasers and other optoelectronic devices. To investigate the structural, electronic, optical and mechanical characteristics of the non-toxic metal halides FrBCl3 (B = Mg, Ba), the first principles calculation has been performed implementing full-potential linearized augmented plane wave approach (FP-LAPW) in the density functional theory (DFT) in WIEN2k code. As Mg atom is replaced by Ba atom, the lattice parameter has also increased which also affected in other optoelectronic properties. The simulated band structures and density of states reveal that both of these compounds have indirect wide bandgap, which are 3.77 eV for FrMgCl3 and 4.52 eV for FrBaCl3. The optical spectra demonstrate that absorbance enhanced about 2.2×106cm-1 in the ultraviolet region (16–17 eV). The highest peak values of conductivity, dielectric constant and low reflectivity have also been observed in the ultraviolet region. The investigation of mechanical properties reveal that the composites are mechanically stable. According to a comprehensive study of the physical characteristics, FrBaCl3 may be a possibility for optoelectronic uses. As FrBaCl3 contains the radioactive element, this may be used in medical sector for diagnosis and imaging technology.
无铅金属卤化物钙钛矿近年来因其在发光二极管、太阳能电池、激光器和其他光电器件中的应用而受到关注。为了研究无毒金属卤化物FrBCl3 (B = Mg, Ba)的结构、电子、光学和力学特性,在WIEN2k代码中采用密度泛函理论(DFT)中的全势线性化增广平面波方法(FP-LAPW)进行了第一性原理计算。由于Mg原子被Ba原子取代,晶格参数也增加,这也影响了其他光电性能。模拟的能带结构和态密度表明,这两种化合物都具有间接宽带隙,FrMgCl3的带隙为3.77 eV, FrBaCl3的带隙为4.52 eV。光谱结果表明,在紫外区(16 ~ 17 eV)吸光度提高了2.2×106cm-1左右。在紫外区也观察到电导率、介电常数和低反射率的峰值。力学性能研究表明,复合材料具有良好的力学稳定性。根据对其物理特性的综合研究,FrBaCl3可能具有光电应用的可能性。由于FrBaCl3含有放射性元素,可用于医疗部门的诊断和成像技术。
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引用次数: 0
Java and Bali land surface temperature decrease variation 爪哇和巴厘岛地表温度下降变化
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2024.100096
Munawar Munawar , Tofan Agung Eka Prasetya , Marzuki Marzuki , Muhamad Rifki Taufik , Teuku Fadhla
The world is facing global warming due to natural processes and human activities. From 1880–1980, the global average temperature increased by 1°C per century. Land Surface Temperature (LST) is a crucial climatic variable for analyzing the interaction between the Earth's surface and the atmosphere. Java Island has the highest population and is more urbanized than other islands in Indonesia. From January 2001 to January 2020, LST daytime data were downloaded from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and Visible Infrared Imaging Radiometer Suite (VIIRS) Land Products Global Subsetting and Visualization Tool. This study aims to investigate the LST seasonal patterns and trends of Bali and Java islands. The appropriate distance between sub-regions was also observed, with 105 pixels and 52.5 pixels producing two and six super-regions, respectively. It was found that seasonal patterns could be represented with pixel distances of 105 and 52.5, using eight knots of cubic splines. From 2001–2020, the lowest LST was recorded in January, while the highest was in September. The highest average daily LST, 38.32 °C, was found in Cikande, Serang, and Banten, likely due to industrial activity. This study also analyzed LST fluctuations using seven knots of the cubic spline. It was found that the average daily LST decreased by −0.113 °C per decade in Java and Bali. The western super-regions of Java showed significant LST increases, while the eastern super-regions showed slight decreases. For the 52.5-pixel distance, there was no substantial variation in average LST, though Jakarta and Banten showed significant increases. The 105-pixel distance is useful for examining LST variations on small islands like Java, while the 52.5-pixel distance can detect deeper variations in smaller super-regions. This study also noted that monsoon season and precipitation impact LST decline, and suggested that further research is needed to validate these findings. Additional variables like NDVI, land elevation, and land cover should be considered for more accurate estimations, especially on larger islands or continents farther from the equator.
由于自然过程和人类活动,世界正面临全球变暖。从1880年到1980年,全球平均气温每世纪上升1°C。地表温度(LST)是分析地表与大气相互作用的重要气候变量。爪哇岛是印度尼西亚人口最多的岛屿,城市化程度高于其他岛屿。从2001年1月至2020年1月,从NASA的中分辨率成像光谱仪(MODIS)和可见光红外成像辐射计套件(VIIRS)陆地产品全球子集和可视化工具下载了地表温度日间数据。本研究旨在探讨巴厘岛和爪哇岛地表温度的季节特征和趋势。在105像素和52.5像素的子区域之间,分别产生了2个和6个超级区域。发现季节模式可以用105和52.5的像素距离表示,使用8节三次样条。2001-2020年,1月地表温度最低,9月最高。最高的日平均温度为38.32 °C,出现在慈甘得、雪朗和万丹,可能是由于工业活动。本研究还利用七节三次样条分析了地表温度波动。结果表明,爪哇和巴厘岛的日平均地表温度每10年下降- 0.113 °C。爪哇西部超级区域地表温度显著升高,而东部超级区域地表温度略有下降。在52.5像素距离上,平均地表温度变化不大,但雅加达和万丹的平均地表温度明显升高。105像素的距离对于检查像爪哇这样的小岛上的LST变化很有用,而52.5像素的距离可以检测更小的超级区域的更深层次的变化。本研究还指出季风季节和降水影响地表温度下降,并建议进一步研究验证这些发现。为了获得更准确的估计,应考虑其他变量,如NDVI、陆地高程和土地覆盖,特别是在远离赤道的较大岛屿或大陆上。
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引用次数: 0
Utilizing nature-based adsorbents for removal of microplastics and nanoplastics in controlled polluted aqueous systems: A systematic review of sources, properties, adsorption characteristics, and performance 利用天然吸附剂去除受控污染水系统中的微塑料和纳米塑料:来源、性质、吸附特性和性能的系统综述
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100119
Aniekan E. Essien, Sarah E. Dickson-Anderson, Yiping Guo
The pervasive distribution of microplastics and nanoplastics in water systems has raised significant concerns about their ecological and human health impacts. Traditional methods to mitigate plastic pollution are often inadequate, prompting the need for innovative and sustainable solutions. Agricultural waste or by-products (AWBP) are underutilized sources of adsorbents for environmental pollution control, particularly for microplastic and nanoplastic removal. Despite their low cost and high adsorption capacities, AWBP are frequently burned, dumped, or placed in landfills. Most importantly, there remains a notable gap in research, i.e., a systematic review of AWBP-based adsorbents for the removal of microplastics and nanoplastics, which is the novelty of this review. Therefore, using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) method, this study reviewed the use of hydrochar, biochar, and activated carbon (collectively termed nature-based adsorbents) for the removal of microplastics and nanoplastics, focusing on their sources, properties, adsorption characteristics, and performance. The principal findings and major conclusions indicate that these adsorbents can achieve up to 100 % adsorption efficiency for the removal of microplastics and nanoplastics. Environmental factors such as pH, temperature, and co-existing species can influence adsorption performance. Functional groups like -COOH, -OH, and -CO enhanced adsorption efficiency. Multiple mechanisms, including physisorption and chemisorption, contributed to high adsorption capacities. The pseudo-second-order kinetic model best described the adsorption processes, with the Langmuir isotherm providing the best fitting. Additionally, these adsorbents offer long-term carbon sequestration and align with several Sustainable Development Goals. This review highlights current knowledge gaps and provides recommendations for future research to further improve this technology.
微塑料和纳米塑料在水系统中的普遍分布引起了人们对其生态和人类健康影响的重大关注。减少塑料污染的传统方法往往是不够的,这促使人们需要创新和可持续的解决方案。农业废弃物或副产品(AWBP)是环境污染控制中未充分利用的吸附剂来源,特别是用于微塑料和纳米塑料的去除。尽管AWBP具有低成本和高吸附能力,但它们经常被焚烧、倾倒或填埋。最重要的是,研究中仍有一个显著的空白,即系统综述了基于awbp的吸附剂对微塑料和纳米塑料的去除,这是本文的新颖之处。因此,本研究采用系统评价和荟萃分析的首选报告项目(PRISMA)方法,回顾了碳氢化合物、生物炭和活性炭(统称为天然吸附剂)在去除微塑料和纳米塑料方面的应用,重点介绍了它们的来源、性质、吸附特性和性能。主要研究结果和主要结论表明,这些吸附剂对微塑料和纳米塑料的吸附效率可达100% %。环境因素如pH、温度和共存的物种都会影响吸附性能。-COOH、-OH和-CO等官能团提高了吸附效率。多种机制,包括物理吸附和化学吸附,有助于高吸附能力。拟二级动力学模型最好地描述了吸附过程,Langmuir等温线提供了最好的拟合。此外,这些吸附剂具有长期固碳作用,符合若干可持续发展目标。这篇综述强调了目前的知识差距,并为进一步改进该技术的未来研究提供了建议。
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引用次数: 0
Mechanical and microstructural properties of sustainable ternary blended alkali-activated concrete 可持续三元混合碱活化混凝土的力学和微观结构性能
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100122
Tejeswara Rao Maganti , Krishna Rao Boddepalli
In recent years, there has been a surge in interest surrounding alkali activated concrete (AAC), a novel type of concrete praised for its environmental and construction applications. This study focuses on ternary blended alkali-activated concrete (TBAAC) using fly ash, ground granulated blast furnace slag (GGBS), and silica fume as binders. It also aims the replacement of sodium silicate (SS) solution with neutral grade sodium silicate (NGSS) solution with a silica modulus (SiO₂/Na₂O) of 3.12 to improve the fresh and hardened properties of TBAAC. In this context, the effects of silica fume and alkaline activators are studied to determine the optimum mix design and to evaluate the fresh and hardened properties of TBAAC cured under ambient conditions. To investigate the performance of TBAAC, various experiments were carried out to measure its workability, compressive strength, splitting tensile strength, flexural strength, regression analysis and microstructural characteristics. The results show TBAAC of 40 % fly ash, 50 % GGBS and 10 % silica fume resulted in higher mechanical properties, including compressive strength (74.12 MPa), splitting tensile strength (18.46 MPa), and flexural strength (20.45 MPa). The results of the XRD, SEM and EDX analysis show the formation of C-A-S-H, C-S-H, and N-A-S-H gel, indicating a densified matrix with fewer cracks and pore spaces. Furthermore, the Life Cycle Assessment (LCA) results demonstrate that the use of NGSS, with its improved environmental profile, leads to a lower environmental impact, contributing to a significant reduction in the carbon footprint of TBAAC and enhancing the sustainability of construction materials. The findings suggest that using NGSS-based TBAAC is advisable for construction applications, offering practical implications for reducing environmental impact while maintaining high performance in construction projects.
近年来,人们对碱活化混凝土(AAC)的兴趣激增,碱活化混凝土是一种新型混凝土,因其环境和建筑应用而受到称赞。本研究的重点是三元混合碱活性混凝土(TBAAC),使用粉煤灰、磨粒高炉渣(GGBS)和硅灰作为粘结剂。以硅模量(SiO₂/Na₂O)为3.12的中性级硅酸钠(NGSS)溶液代替硅酸钠(SS)溶液,改善TBAAC的保鲜性能和硬化性能。在这种情况下,研究了硅灰和碱性活化剂的影响,以确定最佳的混合设计,并评估在环境条件下固化的TBAAC的新鲜和硬化性能。为了研究TBAAC的性能,对其进行了工作性、抗压强度、劈裂抗拉强度、抗弯强度、回归分析和显微组织特征等测试。结果表明:粉煤灰掺量为40% %、GGBS掺量为50% %、硅灰掺量为10% %的TBAAC可获得较高的抗压强度(74.12 MPa)、劈裂抗拉强度(18.46 MPa)和抗弯强度(20.45 MPa)。XRD、SEM和EDX分析结果表明,形成了C-A-S-H、C-S-H和N-A-S-H凝胶,表明基体致密,裂缝和孔隙空间较少。此外,生命周期评估(LCA)结果表明,NGSS的使用改善了环境状况,导致环境影响降低,有助于显著减少TBAAC的碳足迹,提高建筑材料的可持续性。研究结果表明,在建筑应用中使用基于ngss的TBAAC是明智的,为减少环境影响同时保持建筑项目的高性能提供了实际意义。
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引用次数: 0
Management of highly toxic arsenic (As3+ and As5+) in water using sodium titanate nanotubes: Integrated kinetic and isothermal studies 使用钛酸钠纳米管管理水中的高毒性砷(As3+和As5+):综合动力学和等温研究
Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100170
M. Farid , A.H. Zaki , M.A.F. Basha , Nabila Shehata , M.H. Khedr
The toxicity of arsenic to humans is confirmed and numerous studies have been investigated its removal from water. Sodium titanates nanotubes (NaTNTs) with different tube lengths (50– 80 nm) and a mean radius of 2.685 nm have been developed by the conventional hydrothermal route. The characterization of the synthesized nanotubes was done using multiple techniques namely FTIR, HRTEM, XRD, and FESEM. The synthesized material was tested for As3+ and As5+ removal. The impact of solution (heavy metals) pH, reaction time and heavy metals initial concentrations on the removal percentage have been explored. The results confirmed the successful management of both of As5+ and As3+ arsenic ions in water with attained efficiencies of 99 % and 98 %, respectively. Hence, the synthesized nanomaterials can be efficiently applied to manage toxic arsenic in drinking water and groundwater.
砷对人体的毒性已得到证实,并对从水中去除砷进行了大量研究。采用常规水热法制备了不同管长(50 ~ 80 nm)、平均半径为2.685 nm的钛酸钠纳米管。利用FTIR、HRTEM、XRD、FESEM等技术对合成的纳米管进行了表征。对合成材料的As3+和As5+去除率进行了测试。探讨了溶液(重金属)pH、反应时间和重金属初始浓度对去除率的影响。结果证实了As5+和As3+砷离子在水中的成功管理,效率分别达到99 %和98 %。因此,合成的纳米材料可以有效地应用于治理饮用水和地下水中的有毒砷。
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Next Sustainability
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