Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100049
Sandra Mathew, Arun Varghese, Sunaja Devi K. R. , Dephan Pinheiro
Water pollution, aggravated by the release of industrial dyes into the water bodies, is a significant environmental issue. This study presents the synthesis and characterization of a MXene-based composite, MXene/CoFe2O4/g-C3N4, tailored for enhanced photocatalytic dye degradation. The resulting composite is systematically analyzed through various physico-chemical and optical characterization techniques to explore the morphological features and photocatalytic efficacy. The results unveils a multilayered structure for MXene/CoFe2O4/g-C3N4, characterized by a suitable bandgap, enhanced light harvesting efficiency, as well as proficient charge carrier separation, and low recombination rate. It forms a Z-scheme/Schottky heterojunction exhibiting higher efficiency for degradation of rhodamine B (93.1 % in 180 min) under visible light. Active species like O2•− and •OH play a vital role in the photodegradation process, and the prepared catalyst exhibits a stable performance up to 5 cycles. This work reveals new possibilities for designing and fabricating heterojunction photocatalysts, showcasing excellent capabilities for efficient and sustainable environmental remediation.
水污染是一个重大的环境问题,工业染料排放到水体中加剧了水污染。本研究介绍了一种基于 MXene 的复合材料 MXene/CoFe2O4/g-C3N4 的合成和表征,该复合材料专为增强光催化染料降解而定制。通过各种物理化学和光学表征技术对所得到的复合材料进行了系统分析,以探索其形态特征和光催化功效。研究结果揭示了 MXene/CoFe2O4/g-C3N4 的多层结构,该结构具有合适的带隙、更高的光收集效率、良好的电荷载流子分离和较低的重组率。它形成的 Z 型/肖特基异质结在可见光下降解罗丹明 B 的效率更高(180 分钟内降解 93.1%)。O2- 和 -OH 等活性物种在光降解过程中发挥了重要作用,所制备的催化剂性能稳定,可循环使用 5 次。这项工作为设计和制造异质结光催化剂提供了新的可能性,展示了高效和可持续环境修复的卓越能力。
{"title":"Architecture of a dual scheme MXene/CoFe2O4/g-C3N4 heterojunction for sustainable water remediation","authors":"Sandra Mathew, Arun Varghese, Sunaja Devi K. R. , Dephan Pinheiro","doi":"10.1016/j.nxsust.2024.100049","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100049","url":null,"abstract":"<div><p>Water pollution, aggravated by the release of industrial dyes into the water bodies, is a significant environmental issue. This study presents the synthesis and characterization of a MXene-based composite, MXene/CoFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>, tailored for enhanced photocatalytic dye degradation. The resulting composite is systematically analyzed through various physico-chemical and optical characterization techniques to explore the morphological features and photocatalytic efficacy. The results unveils a multilayered structure for MXene/CoFe<sub>2</sub>O<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>, characterized by a suitable bandgap, enhanced light harvesting efficiency, as well as proficient charge carrier separation, and low recombination rate. It forms a Z-scheme/Schottky heterojunction exhibiting higher efficiency for degradation of rhodamine B (93.1 % in 180 min) under visible light. Active species like O<sub>2</sub><sup>•−</sup> and <sup>•</sup>OH play a vital role in the photodegradation process, and the prepared catalyst exhibits a stable performance up to 5 cycles. This work reveals new possibilities for designing and fabricating heterojunction photocatalysts, showcasing excellent capabilities for efficient and sustainable environmental remediation.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000266/pdfft?md5=02344fea3575ae1bbc66c41173718790&pid=1-s2.0-S2949823624000266-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141292363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100060
Mehak Bansal , Bonamali Pal , Raj Kumar Das
The issue of water contamination resulting from textile dyes has garnered public attention. To address this issue, a new highly stable, greener, nontoxic composite material (ZBH.Sn) consisting of Sn2+ doped Zn-Bi mixed metal hydroxide (ZBH) was effectively fabricated. The adsorbent underwent a thorough investigation of its structural and morphological properties utilizing XRD, HR-TEM, FE-SEM, FTIR, XPS, Zeta, and DLS. XRD confirms the crystallinity of mixed phases of both zinc and bismuth hydroxides. The hexagonal sheet-like morphology is evident in SEM, and elemental mappings show that individual elements are evenly distributed on the external surface. The ZBH.Sn adsorbent demonstrates an adsorption efficiency in the removal of Fuschin blue (F.B.) from wastewater systems. With optimized 2.5 mg ZBH.Sn in 20 mL (0.05 mM) of F.B concentration at pH 6, the maximum adsorption capacity was 80.56 % in 180 minutes at 298 K. The detailed thermodynamic information (ΔG= −2.477 KJ/mol) including adsorption maximum capacity qmax (1472.75 mg/g), adsorption equilibrium constant (k2= 3.7×105 g.mg1.min1), and adsorption efficiency (80.56 %) were obtained to evaluate the different reaction performances for F.B by ZBH.Sn. Such observation suggests that these materials could serve as effective adsorbents for removing F.B. from wastewater because of their high adsorption capabilities and low cost.
{"title":"Improved adsorption of Fuschin Blue with Sn2+ impregnated Zn-Bi mixed metal hydroxide","authors":"Mehak Bansal , Bonamali Pal , Raj Kumar Das","doi":"10.1016/j.nxsust.2024.100060","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100060","url":null,"abstract":"<div><p>The issue of water contamination resulting from textile dyes has garnered public attention. To address this issue, a new highly stable, greener, nontoxic composite material (ZBH.Sn) consisting of Sn<sup>2+</sup> doped Zn-Bi mixed metal hydroxide (ZBH) was effectively fabricated. The adsorbent underwent a thorough investigation of its structural and morphological properties utilizing XRD, HR-TEM, FE-SEM, FTIR, XPS, Zeta, and DLS. XRD confirms the crystallinity of mixed phases of both zinc and bismuth hydroxides. The hexagonal sheet-like morphology is evident in SEM, and elemental mappings show that individual elements are evenly distributed on the external surface. The ZBH.Sn adsorbent demonstrates an adsorption efficiency in the removal of Fuschin blue (F.B.) from wastewater systems. With optimized 2.5 mg ZBH.Sn in 20 mL (0.05 mM) of F.B concentration at pH 6, the maximum adsorption capacity was 80.56 % in 180 minutes at 298 K. The detailed thermodynamic information (ΔG= −2.477 KJ/mol) including adsorption maximum capacity q<sub>max</sub> (1472.75 mg/g), adsorption equilibrium constant (k<sub>2</sub>= 3.7×10<sup>5</sup> g.mg<sup>1</sup>.min<sup>1</sup>), and adsorption efficiency (80.56 %) were obtained to evaluate the different reaction performances for F.B by ZBH.Sn. Such observation suggests that these materials could serve as effective adsorbents for removing F.B. from wastewater because of their high adsorption capabilities and low cost.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000370/pdfft?md5=22fee9cf874fa38ece2a7f28104b6e2b&pid=1-s2.0-S2949823624000370-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141607932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100040
Xiaofan Xing , Yuankang Xiong , Rong Wang , Yuan Gao , Siqing Xu , Philippe Ciais , Thomas Gasser , Josep Penuelas , Jordi Sardans , Jianmin Chen , Tang Xu , Renhe Zhang
Bioenergy with Carbon Capture and Storage (BECCS) is a key negative emission technology considered by many integrated assessment models (IAMs) to achieve the 2℃ or 1.5℃ goals in the Paris Agreement. However, the technical feasibility and economic costs of BECCS in these IAMs have been widely debated, which increases the uncertainty in the projection of climate change in the 21st century. Therefore, this paper reviews the latest understanding of BECCS. The key findings reveal the limitations of current models in projecting the capacity and costs of bioenergy with carbon capture and storage (BECCS), mainly due to insufficient consideration of ecological consequences, including availabilities of biomass and difficulties in the transportation of biomass and CO2. To reduce uncertainties in the capacity and costs of BECCS, it is urgently needed to apply spatially explicit method for estimating the life-cycle emissions and the complete cost items when deploying BECCS, optimize the network of biomass acquisition, power plants retrofitting and transportation of biomass and CO2, and represent the changes in the availability of biomass (for different types of bioenergy plants) under the impacts of climate change. This paper emphasizes the gap between the potential capacity of BECCS and the demand for BECCS that is needed to achieve the climate goals. Suggestion on policy interventions is provided to accelerate the application of BECCS from the aspects of economic tools, regulatory tools, and information tools. Deployment of BECCS could be accelerated to halt the rapid rise of global annual average temperature and reduce the risk of carbon lock-in from fossil-fuel supply infrastructure. As BECCS could play a key role in achieving ambitious climate targets, it is important to maintain a balance between environmental, social, and economic considerations in the Earth system under a high sustainability of development.
{"title":"A review of influencing factors for policy interventions in the deployment of bioenergy with carbon capture and storage","authors":"Xiaofan Xing , Yuankang Xiong , Rong Wang , Yuan Gao , Siqing Xu , Philippe Ciais , Thomas Gasser , Josep Penuelas , Jordi Sardans , Jianmin Chen , Tang Xu , Renhe Zhang","doi":"10.1016/j.nxsust.2024.100040","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100040","url":null,"abstract":"<div><p>Bioenergy with Carbon Capture and Storage (BECCS) is a key negative emission technology considered by many integrated assessment models (IAMs) to achieve the 2℃ or 1.5℃ goals in the Paris Agreement. However, the technical feasibility and economic costs of BECCS in these IAMs have been widely debated, which increases the uncertainty in the projection of climate change in the 21st century. Therefore, this paper reviews the latest understanding of BECCS. The key findings reveal the limitations of current models in projecting the capacity and costs of bioenergy with carbon capture and storage (BECCS), mainly due to insufficient consideration of ecological consequences, including availabilities of biomass and difficulties in the transportation of biomass and CO<sub>2</sub>. To reduce uncertainties in the capacity and costs of BECCS, it is urgently needed to apply spatially explicit method for estimating the life-cycle emissions and the complete cost items when deploying BECCS, optimize the network of biomass acquisition, power plants retrofitting and transportation of biomass and CO<sub>2</sub>, and represent the changes in the availability of biomass (for different types of bioenergy plants) under the impacts of climate change. This paper emphasizes the gap between the potential capacity of BECCS and the demand for BECCS that is needed to achieve the climate goals. Suggestion on policy interventions is provided to accelerate the application of BECCS from the aspects of economic tools, regulatory tools, and information tools. Deployment of BECCS could be accelerated to halt the rapid rise of global annual average temperature and reduce the risk of carbon lock-in from fossil-fuel supply infrastructure. As BECCS could play a key role in achieving ambitious climate targets, it is important to maintain a balance between environmental, social, and economic considerations in the Earth system under a high sustainability of development.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000175/pdfft?md5=d077000d9624f2aa34caa12c42bb0a4e&pid=1-s2.0-S2949823624000175-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140879743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
For the purpose of improving mechanical qualities, starch-based film hydrogel can be crosslinked. The choice of crosslinking agent is critical in adjusting hydrogel performance to fit the needs of specific applications. The present investigation examined the impact of two non-toxic crosslinking agents, namely citric acid and oxidized sucrose, on the mechanical and swelling properties of hydrogels. When compared to oxidized sucrose crosslinked hydrogels (OSH), citric acid crosslinked hydrogels (CAH) often offer a larger swelling; however, OSH without plasticizer is not included in this comparison. The OSH has the highest swelling value of 292% at pH 7, whereas the CAH has the highest swelling value of 116% at pH 7. Contrary to OSH film, which can only achieve 2.0 MPa, CAH film has a tensile strength of up to 3.75 MPa. Meanwhile, OSH film can achieve the greatest elongation of 54%.
{"title":"Physical properties comparison of hydrogel from cassava starch using two different non toxic crosslinkers","authors":"Fitri Nur Kayati , Chandra Wahyu Purnomo , Yuni Kusumastuti , Rochmadi","doi":"10.1016/j.nxsust.2024.100043","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100043","url":null,"abstract":"<div><p>For the purpose of improving mechanical qualities, starch-based film hydrogel can be crosslinked. The choice of crosslinking agent is critical in adjusting hydrogel performance to fit the needs of specific applications. The present investigation examined the impact of two non-toxic crosslinking agents, namely citric acid and oxidized sucrose, on the mechanical and swelling properties of hydrogels. When compared to oxidized sucrose crosslinked hydrogels (OSH), citric acid crosslinked hydrogels (CAH) often offer a larger swelling; however, OSH without plasticizer is not included in this comparison. The OSH has the highest swelling value of 292% at pH 7, whereas the CAH has the highest swelling value of 116% at pH 7. Contrary to OSH film, which can only achieve 2.0 MPa, CAH film has a tensile strength of up to 3.75 MPa. Meanwhile, OSH film can achieve the greatest elongation of 54%.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000205/pdfft?md5=bc8db65815d184aef4871e90b316ca55&pid=1-s2.0-S2949823624000205-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140879744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100031
Eva C. Alfredsson , Daniel Lindvall , Mikael Karlsson , Mikael J. Malmaeus
This article explores the climate mitigation strategies of the 15 industries with the largest carbon dioxide emissions in Sweden. Starting from two carbon budget alternatives, we analyse the mitigation projections of the companies in relation to what can be considered their fair share of the remaining carbon budget for Sweden. We furthermore determine the uncertainties associated with the strategies. The results suggest that if the communicated mitigation plans are implemented as planned, the companies overdraft our main, 1.5-degree, budget option but stay within the alternative 1.7-degree budget. The analysis shows, however, that the timing and efficiency of emission reductions are crucial. Already small delays or lower efficiency in implementation, result in evident overdrafts of also the alternative budget. There are also substantial political and technical risks which can prevent timely mitigations. The article makes a novel contribution by analyzing industries’ mitigation strategies relative to their share of the remaining carbon budget. The article demonstrates the importance of transparent industrial climate mitigation strategies and in particular the need for policymakers to set incentive structures to promote strategy implementation.
{"title":"Industrial climate mitigation strategies and the remaining fair carbon budget – The case of Sweden","authors":"Eva C. Alfredsson , Daniel Lindvall , Mikael Karlsson , Mikael J. Malmaeus","doi":"10.1016/j.nxsust.2024.100031","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100031","url":null,"abstract":"<div><p>This article explores the climate mitigation strategies of the 15 industries with the largest carbon dioxide emissions in Sweden. Starting from two carbon budget alternatives, we analyse the mitigation projections of the companies in relation to what can be considered their fair share of the remaining carbon budget for Sweden. We furthermore determine the uncertainties associated with the strategies. The results suggest that if the communicated mitigation plans are implemented as planned, the companies overdraft our main, 1.5-degree, budget option but stay within the alternative 1.7-degree budget. The analysis shows, however, that the timing and efficiency of emission reductions are crucial. Already small delays or lower efficiency in implementation, result in evident overdrafts of also the alternative budget. There are also substantial political and technical risks which can prevent timely mitigations. The article makes a novel contribution by analyzing industries’ mitigation strategies relative to their share of the remaining carbon budget. The article demonstrates the importance of transparent industrial climate mitigation strategies and in particular the need for policymakers to set incentive structures to promote strategy implementation.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000084/pdfft?md5=2526eee41136883af8771df8be1b6752&pid=1-s2.0-S2949823624000084-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140112923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carbon revenues from the REDD+ projects are important to reduce deforestation and increase carbon sinks in developing countries. Such revenues are not possible without assessing the baseline emissions, the forest reference emission level (FREL), and the effectiveness of the REDD+ activities. This study aimed to assess the carbon emission reductions from reducing deforestation, carbon removals from enhancing forest carbon stocks, and carbon revenues in the Vavuniya district, Sri Lanka by assessing baseline emissions and FREL (2001 – 2020) in dry monsoon forest using the Google Earth Engine and the phenology-based threshold classification. The Vavuniya district is one of the war-affected dry zone districts showing a significant loss in forest cover. This study considered the carbon pools aboveground, belowground biomass, and litter to calculate forest carbon stocks since a significant change can be observed in these pools due to forest loss. The estimation shows that the annual depletion of carbon stocks was 45,083.6 MgC between 2001 and 2020, which accounts for the total carbon emissions of 165,306.6 MgCO2. FREL established for the period of the Paris Agreement was at 155,187.9 MgCO2 yr−1. Around 94,331.0 MgCO2 of annual carbon emissions could be reduced if REDD+ actions are implemented between 2020 and 2030. While annual carbon removals from the open forest could be 7731.5 MgCO2. Based on the carbon price selected at the voluntary carbon market and the European Union emission trading system, total emission reductions and removals can be equivalent to carbon revenues ranging from approximately USD 7.3 million to USD 87.5 million. These revenues are important for the Sri Lankan government to promote conservation efforts for the remaining forests to better conserve biodiversity. The estimation suggests high carbon revenues, which can attract successful implementation of the projects through appropriate policy interventions and sectoral collaboration, which can then contribute to long-term economic development and climate change mitigation.
{"title":"Assessing carbon emission reductions and removals in Vavuniya District, Sri Lanka: REDD+ project contributions to sustainability","authors":"Sharaniya Vijitharan , Nophea Sasaki , Nitin Kumar Tripathi , Malay Pramanik , Takuji W. Tsusaka","doi":"10.1016/j.nxsust.2024.100035","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100035","url":null,"abstract":"<div><p>Carbon revenues from the REDD+ projects are important to reduce deforestation and increase carbon sinks in developing countries. Such revenues are not possible without assessing the baseline emissions, the forest reference emission level (FREL), and the effectiveness of the REDD+ activities. This study aimed to assess the carbon emission reductions from reducing deforestation, carbon removals from enhancing forest carbon stocks, and carbon revenues in the Vavuniya district, Sri Lanka by assessing baseline emissions and FREL (2001 – 2020) in dry monsoon forest using the Google Earth Engine and the phenology-based threshold classification. The Vavuniya district is one of the war-affected dry zone districts showing a significant loss in forest cover. This study considered the carbon pools aboveground, belowground biomass, and litter to calculate forest carbon stocks since a significant change can be observed in these pools due to forest loss. The estimation shows that the annual depletion of carbon stocks was 45,083.6 MgC between 2001 and 2020, which accounts for the total carbon emissions of 165,306.6 MgCO<sub>2</sub>. FREL established for the period of the Paris Agreement was at 155,187.9 MgCO<sub>2</sub> yr<sup>−1</sup>. Around 94,331.0 MgCO<sub>2</sub> of annual carbon emissions could be reduced if REDD+ actions are implemented between 2020 and 2030. While annual carbon removals from the open forest could be 7731.5 MgCO<sub>2</sub>. Based on the carbon price selected at the voluntary carbon market and the European Union emission trading system, total emission reductions and removals can be equivalent to carbon revenues ranging from approximately USD 7.3 million to USD 87.5 million. These revenues are important for the Sri Lankan government to promote conservation efforts for the remaining forests to better conserve biodiversity. The estimation suggests high carbon revenues, which can attract successful implementation of the projects through appropriate policy interventions and sectoral collaboration, which can then contribute to long-term economic development and climate change mitigation.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000126/pdfft?md5=ffbd6eb27b3c8a7bb0b83b9f3cfec1a3&pid=1-s2.0-S2949823624000126-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140347066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100026
Richa Tiwari , Pratibha S. Agrawal , Pramod N. Belkhode , Joseph V.L. Ruatpuia , Samuel Lalthazuala Rokhum
Transformer oil is the insulating oil that is utilized in power transformers for insulation and cooling during the operation of transformers. After a long run, the properties of the transformer oil such as breakdown voltage, and dielectric dissipation factor decrease to 32 kV, 0.41% while water content increases by 31 ppm resulting in waste oil. The disposal of waste transformer oil (WTO) is a big issue since it is contaminated with many virulent pollutants such as PCBs, PAHs, harmful gases, etc. which have adverse effects on the environment and living beings. Many scientists in this area studied to reduce its environmental impact and disposal problem by using different methods of recycling and re-use of WTO or re-refined into new transformer oil and also utilized in blended form with diesel fuel as an alternative fuel in diesel engines resulting in less smoke and hydrocarbon emission, increased BTE and NOx emission. In this review, we provide information about waste transformer oil, its toxic effects on the environment, the various techniques to recycle WTO, and its application in alternate fuels.
{"title":"Hazardous effects of waste transformer oil and its prevention: A review","authors":"Richa Tiwari , Pratibha S. Agrawal , Pramod N. Belkhode , Joseph V.L. Ruatpuia , Samuel Lalthazuala Rokhum","doi":"10.1016/j.nxsust.2024.100026","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100026","url":null,"abstract":"<div><p>Transformer oil is the insulating oil that is utilized in power transformers for insulation and cooling during the operation of transformers. After a long run, the properties of the transformer oil such as breakdown voltage, and dielectric dissipation factor decrease to 32 kV, 0.41% while water content increases by 31 ppm resulting in waste oil. The disposal of waste transformer oil (WTO) is a big issue since it is contaminated with many virulent pollutants such as PCBs, PAHs, harmful gases, etc. which have adverse effects on the environment and living beings. Many scientists in this area studied to reduce its environmental impact and disposal problem by using different methods of recycling and re-use of WTO or re-refined into new transformer oil and also utilized in blended form with diesel fuel as an alternative fuel in diesel engines resulting in less smoke and hydrocarbon emission, increased BTE and NOx emission. In this review, we provide information about waste transformer oil, its toxic effects on the environment, the various techniques to recycle WTO, and its application in alternate fuels.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000035/pdfft?md5=96debd1663fccd7553b3572beba41db3&pid=1-s2.0-S2949823624000035-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139699988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100055
Celso F. Baspineiro, Victoria Flexer
Lithium mining from brines raise environmental issues due to huge volumes of both saline and freshwater being constantly pumped in desertic environments. Data indicating the slow depletion of both underground water levels and lagoon surfaces in the regions where large lithium brine mining exploitations are located have recently being disclosed. Amongst different direct lithium extraction methodologies, DLE, for more sustainable lithium recovery, a few proposals aim at the recovery of freshwater from the high salinity brines. About 900 kg of freshwater could potentially be recovered per cubic meter of processed native brine. The water evaporation and freshwater production capabilities of a simple and an active solar still are compared in this work. These are two simple and relatively low-cost technologies that could be adapted to existing solar evaporation ponds. The two systems were thermodynamically modelled. Equations were derived which were fed with real meteorological data from the Olaroz salt lake location and brine properties derived from the Pitzer model for the said brine. Analysis of the heat fluxes show that the behavior of both systems is relatively similar with large heat losses that are responsible for neither of the systems reaching the evaporation rate of the evaporation ponds.
{"title":"Comparison of simple and active solar stills for freshwater recovery during lithium brine mining","authors":"Celso F. Baspineiro, Victoria Flexer","doi":"10.1016/j.nxsust.2024.100055","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100055","url":null,"abstract":"<div><p>Lithium mining from brines raise environmental issues due to huge volumes of both saline and freshwater being constantly pumped in desertic environments. Data indicating the slow depletion of both underground water levels and lagoon surfaces in the regions where large lithium brine mining exploitations are located have recently being disclosed. Amongst different direct lithium extraction methodologies, DLE, for more sustainable lithium recovery, a few proposals aim at the recovery of freshwater from the high salinity brines. About 900 kg of freshwater could potentially be recovered per cubic meter of processed native brine. The water evaporation and freshwater production capabilities of a simple and an active solar still are compared in this work. These are two simple and relatively low-cost technologies that could be adapted to existing solar evaporation ponds. The two systems were thermodynamically modelled. Equations were derived which were fed with real meteorological data from the Olaroz salt lake location and brine properties derived from the Pitzer model for the said brine. Analysis of the heat fluxes show that the behavior of both systems is relatively similar with large heat losses that are responsible for neither of the systems reaching the evaporation rate of the evaporation ponds.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000321/pdfft?md5=9121372e9bf7e159e8fb018406d3477d&pid=1-s2.0-S2949823624000321-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141482160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100059
Wenfei Cai , Reeti Kumar , Zhi Zhu , Sunita Varjani , Zhong-Ting Hu , Jonathan Woon-Chung Wong , Jun Zhao
Waste plastics pose significant environmental risks due to their non-biodegradable nature and accumulation in the environment. The pandemic has exacerbated this issue by increasing the production of plastic medical waste such as surgical masks. This study developed Ni/Al-MOF-derived catalysts for pyrolysis, an effective plastic waste utilization technology. By optimizing conditions, the study successfully converted waste surgical masks, made primarily of polypropylene, into gasoline or diesel range chemicals. The oil yield from polypropylene waste reached 72.8 % using Ni/Al-MOF-derived catalysts with 5 % Ni loading at 450°C, while surgical masks yielded 58.9 % oil under the same conditions. Catalyst characterization revealed a high surface area and evenly distributed Ni particles in MOF-derived Al2O3, maximizing catalytic performance. This catalyst provides a promising solution for converting waste surgical masks into liquid fuels, reducing the environmental impact of plastic products, and promoting plastic waste recycling.
{"title":"Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts","authors":"Wenfei Cai , Reeti Kumar , Zhi Zhu , Sunita Varjani , Zhong-Ting Hu , Jonathan Woon-Chung Wong , Jun Zhao","doi":"10.1016/j.nxsust.2024.100059","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100059","url":null,"abstract":"<div><p>Waste plastics pose significant environmental risks due to their non-biodegradable nature and accumulation in the environment. The pandemic has exacerbated this issue by increasing the production of plastic medical waste such as surgical masks. This study developed Ni/Al-MOF-derived catalysts for pyrolysis, an effective plastic waste utilization technology. By optimizing conditions, the study successfully converted waste surgical masks, made primarily of polypropylene, into gasoline or diesel range chemicals. The oil yield from polypropylene waste reached 72.8 % using Ni/Al-MOF-derived catalysts with 5 % Ni loading at 450°C, while surgical masks yielded 58.9 % oil under the same conditions. Catalyst characterization revealed a high surface area and evenly distributed Ni particles in MOF-derived Al<sub>2</sub>O<sub>3</sub>, maximizing catalytic performance. This catalyst provides a promising solution for converting waste surgical masks into liquid fuels, reducing the environmental impact of plastic products, and promoting plastic waste recycling.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000369/pdfft?md5=933fdb3940cd094d9a2bef35c81f9c98&pid=1-s2.0-S2949823624000369-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141540216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Herein we have made a comprehensive analysis for the conversion of CO2 to fuel (CH4) on two dimensional MXenes (M=Mo, Hf) of the type M2C. Evaluation of parameters like Mulliken charge, adsorption energy, bond angle and bond distance demonstrated that activation is more pronounced with Hf2C compared to Mo2C due to transfer of higher electron density to CO2 in the former than in the latter case. CO2 adsorbed M2C realizes large shift of valance and conduction band vis-a-vis free M2C, leading to substantial charge transfer from MXenes. The enhanced activation of CO2 over Hf2C has been confirmed from the increased splitting of π and π* energy level of CO2 for Hf2C compared to Mo2C. The dense electron localization contour maps further explained the ease of electron transfer to CO2 involving Hf2C. Analysis of Gibbs free energy for successive steps for the conversion of CO2 to CH4 revealed that fuel conversion is more feasible with Hf2C over Mo2C.
在此,我们对二维 MXenes(M=Mo、Hf)M2C 型上将 CO2 转化为燃料(CH4)的过程进行了全面分析。对穆利肯电荷、吸附能、键角和键距等参数的评估表明,与 Mo2C 相比,Hf2C 的活化作用更明显,这是因为前者比后者向二氧化碳转移了更高的电子密度。与自由 M2C 相比,吸附了 CO2 的 M2C 的价带和导带发生了很大的移动,从而导致大量电荷从 MXenes 转移。与 Mo2C 相比,Hf2C 的 CO2 π 和 π* 能级的分裂增加,这证实了 Hf2C 对 CO2 的活化作用比 Hf2C 强。密集的电子定位等值线图进一步说明了 Hf2C 易于将电子转移到 CO2。对 CO2 转化为 CH4 的连续步骤的吉布斯自由能分析表明,与 Mo2C 相比,Hf2C 的燃料转化更为可行。
{"title":"Electrochemical conversion of CO2 to fuel by MXenes (M2C): A first principles study","authors":"Md Muttakin Sarkar , Subhankar Choudhury , Abhijit Mandal , Sourav Mazumdar , Narendra Nath Ghosh , Asoke P. Chattopadhyay , Brindaban Roy , Nabajyoti Baildya","doi":"10.1016/j.nxsust.2024.100058","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100058","url":null,"abstract":"<div><p>Herein we have made a comprehensive analysis for the conversion of CO<sub>2</sub> to fuel (CH<sub>4</sub>) on two dimensional MXenes (M=Mo, Hf) of the type M<sub>2</sub>C. Evaluation of parameters like Mulliken charge, adsorption energy, bond angle and bond distance demonstrated that activation is more pronounced with Hf<sub>2</sub>C compared to Mo<sub>2</sub>C due to transfer of higher electron density to CO<sub>2</sub> in the former than in the latter case. CO<sub>2</sub> adsorbed M<sub>2</sub>C realizes large shift of valance and conduction band vis-a-vis free M<sub>2</sub>C, leading to substantial charge transfer from MXenes. The enhanced activation of CO<sub>2</sub> over Hf<sub>2</sub>C has been confirmed from the increased splitting of π and π* energy level of CO<sub>2</sub> for Hf<sub>2</sub>C compared to Mo<sub>2</sub>C. The dense electron localization contour maps further explained the ease of electron transfer to CO<sub>2</sub> involving Hf<sub>2</sub>C. Analysis of Gibbs free energy for successive steps for the conversion of CO<sub>2</sub> to CH<sub>4</sub> revealed that fuel conversion is more feasible with Hf<sub>2</sub>C over Mo<sub>2</sub>C.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000357/pdfft?md5=86ebbce2fcc6034b5d0182f63b364bff&pid=1-s2.0-S2949823624000357-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141593632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}