Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100056
Xin Ma , Aritra Ghosh , Erdem Cuce , Shaik Saboor
Solar energy is an effective means of reducing global greenhouse gas emissions. This review provides an overview of building-integrated photovoltaic thermal (BIPVT) systems, highlighting their potential advantages and challenges. The goal is to evaluate how BIPVT systems can improve energy efficiency, cost-effectiveness, and sustainability. This article provides a comprehensive study of various BIPVT systems and spectral splitting techniques and discusses the performance and efficiency of different BIPVT applications. Additionally, this review analyzes the factors that influence the design, installation, and maintenance of BIPVT systems, as well as the economics, feasibility, and market potential of BIPVT systems. The results show that BIPVT systems have significant promise in improving photovoltaic (PV) module electrical efficiency, system thermal efficiency and reducing energy consumption, thus contributing to climate change mitigation. However, its high initial installation cost compared to traditional heating and cooling systems or stand-alone solar systems remains a major barrier to widespread adoption. To enhance market dynamism, further research and development work is required to improve performance and efficiency, reduce installation costs and overcome existing technical challenges.
{"title":"Building integrated photovoltaic-thermal systems (BIPVT) and spectral splitting technology: A critical review","authors":"Xin Ma , Aritra Ghosh , Erdem Cuce , Shaik Saboor","doi":"10.1016/j.nxsust.2024.100056","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100056","url":null,"abstract":"<div><p>Solar energy is an effective means of reducing global greenhouse gas emissions. This review provides an overview of building-integrated photovoltaic thermal (BIPVT) systems, highlighting their potential advantages and challenges. The goal is to evaluate how BIPVT systems can improve energy efficiency, cost-effectiveness, and sustainability. This article provides a comprehensive study of various BIPVT systems and spectral splitting techniques and discusses the performance and efficiency of different BIPVT applications. Additionally, this review analyzes the factors that influence the design, installation, and maintenance of BIPVT systems, as well as the economics, feasibility, and market potential of BIPVT systems. The results show that BIPVT systems have significant promise in improving photovoltaic (PV) module electrical efficiency, system thermal efficiency and reducing energy consumption, thus contributing to climate change mitigation. However, its high initial installation cost compared to traditional heating and cooling systems or stand-alone solar systems remains a major barrier to widespread adoption. To enhance market dynamism, further research and development work is required to improve performance and efficiency, reduce installation costs and overcome existing technical challenges.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000333/pdfft?md5=83143cf9e827641857cee71f250c884d&pid=1-s2.0-S2949823624000333-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141540217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The global warming concerns, greenhouse gas emission reduction, are not being addressed effectively in the energy-consuming building sector worldwide. This study presents a novel approach of solar technology interventions for sustainable buildings namely rooftop photovoltaic systems, use of carbon-free sustainable building materials, and passive solar heating systems. A methodology for achieving net zero energy and zero carbon emission buildings is described. This strategy is being implemented to develop an educational institution as a sustainable campus in a Western Himalayan cold region of India. The results show an energy yield of 1561 kWh/kWp/year from a proposed photovoltaic power system for a typical building at this location producing 10,928 kWh avoiding 7.7 t-CO2 emissions which means the system will produce enough electricity in 2.6 years to offset the amount of carbon emissions during manufacturing of PV modules. The modeling and simulation analysis using the developed mathematical model shows that the space heating system provides 37–56 % of total energy needs with a payback period of 3.5–5.8 years depending on the type of six different construction materials used. The innovative mandatory policy and solar technology interventions implemented can be followed in remote rural and semi-urban areas in developing countries.
{"title":"Sustainable passive solar and photovoltaic integrated technology interventions for climate responsive net zero energy buildings in western Himalayan mountainous terrain of India","authors":"Rahul Chandel , Shyam Singh Chandel , Deo Prasad , Ram Prakash Dwivedi","doi":"10.1016/j.nxsust.2024.100039","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100039","url":null,"abstract":"<div><p>The global warming concerns, greenhouse gas emission reduction, are not being addressed effectively in the energy-consuming building sector worldwide. This study presents a novel approach of solar technology interventions for sustainable buildings namely rooftop photovoltaic systems, use of carbon-free sustainable building materials, and passive solar heating systems. A methodology for achieving net zero energy and zero carbon emission buildings is described. This strategy is being implemented to develop an educational institution as a sustainable campus in a Western Himalayan cold region of India. The results show an energy yield of 1561 kWh/kWp/year from a proposed photovoltaic power system for a typical building at this location producing 10,928 kWh avoiding 7.7 t-CO<sub>2</sub> emissions which means the system will produce enough electricity in 2.6 years to offset the amount of carbon emissions during manufacturing of PV modules. The modeling and simulation analysis using the developed mathematical model shows that the space heating system provides 37–56 % of total energy needs with a payback period of 3.5–5.8 years depending on the type of six different construction materials used. The innovative mandatory policy and solar technology interventions implemented can be followed in remote rural and semi-urban areas in developing countries.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000163/pdfft?md5=8e80e1698310c794263d3d083bfa48af&pid=1-s2.0-S2949823624000163-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140637960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study reports the optimum hydrogen (H2) production from municipal solid waste (MSW) via waste eggshell derived-CaO catalyst through gasification technology. The response surface model was applied to design the experiments and the data validation. Results showed that CaO catalyst had a better performance that enhanced 15 mol% more H2 production than non-catalytic gasification by mainly involving reaction temperature and catalyst loading as the critical parameters. Tar content was efficiently declined from 11.34 wt. % to 4.7 , wt. %, which ultimately elevated the H2 and syngas from 33.95 mol% to 51.27 mol% and 74.05 to 83.4674.05–83.46 wt. %, respectively. The model showed a strong interaction among the statistical parameters verified through the regression values; R2 = 0.990, P-value = 0.000005, respectively. Scanning electron microscopy, X-ray diffraction, and Brunauer-Emmett-Teller techniques investigated the catalyst's structure hence; presented comparable results. From tar analysis, the aromatics were found as the dominant family followed by polycyclic aromatic, phenyls, aliphatic, aromatic heterocyclic, polycyclic, and aromatic ketones. Optimum H2 production of 51.27 mol% (with H2/CO ratio 2.82, LHV 9.47 MJ/Nm3, and H2 yield 22.74 mol kg-MSW−1) was produced which can be a better alternative to depleting fossil fuels and utilized for liquid fuel manufacturing and power generation.
{"title":"Catalytic gasification of municipal solid waste using eggshell-derived CaO catalyst: An investigation of optimum H2 production, production distribution, and tar compounds","authors":"Azhar Ali Laghari , Imtiaz Ali Jamro , Akash Kumar , Guanyi Chen , Shahdev Sajnani , Zhangzhen Guo , Yongheng Shen , Junzhe Zhang , Salim Khoso , Qingxia Guo , Wenchao Ma","doi":"10.1016/j.nxsust.2024.100038","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100038","url":null,"abstract":"<div><p>This study reports the optimum hydrogen (H<sub>2</sub>) production from municipal solid waste (MSW) via waste eggshell derived-CaO catalyst through gasification technology. The response surface model was applied to design the experiments and the data validation. Results showed that CaO catalyst had a better performance that enhanced 15 mol% more H<sub>2</sub> production than non-catalytic gasification by mainly involving reaction temperature and catalyst loading as the critical parameters. Tar content was efficiently declined from 11.34 wt. % to 4.7 , wt. %, which ultimately elevated the H<sub>2</sub> and syngas from 33.95 mol% to 51.27 mol% and 74.05 to 83.4674.05–83.46 wt. %, respectively. The model showed a strong interaction among the statistical parameters verified through the regression values; R<sup>2</sup> = 0.990, P-value = 0.000005, respectively. Scanning electron microscopy, X-ray diffraction, and Brunauer-Emmett-Teller techniques investigated the catalyst's structure hence; presented comparable results. From tar analysis, the aromatics were found as the dominant family followed by polycyclic aromatic, phenyls, aliphatic, aromatic heterocyclic, polycyclic, and aromatic ketones. Optimum H<sub>2</sub> production of 51.27 mol% (with H<sub>2</sub>/CO ratio 2.82, LHV 9.47 MJ/Nm<sup>3,</sup> and H<sub>2</sub> yield 22.74 mol kg-MSW<sup>−1</sup>) was produced which can be a better alternative to depleting fossil fuels and utilized for liquid fuel manufacturing and power generation.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000151/pdfft?md5=86e790340204d9892f13f7d1ffbce807&pid=1-s2.0-S2949823624000151-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140645430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2023.100015
Zhiyuan Mao , Yunfeng Song , Ai Gang Zhen , Wei Sun
Lithium-ion batteries have become the most widely used electrochemical energy storage device due to their excellent cycling performance, safety and stability. The service life of lithium-ion batteries (LIBs) is generally 3∼5 years. Therefore, a large number of spent lithium-ion batteries will be generated in the future. Spent lithium-ion batteries will cause serious environmental pollution if not processed properly, especially the electrolyte. Nowadays, the recycling of lithium-ion batteries is mainly on the high-value electrode materials containing non-ferrous metals such as cobalt, lithium, and nickel. However, due to its volatility, toxicity and flammability, the recycling of electrolyte is less studied. The spent electrolyte reacts with water to form fluoride, which may spread into the air and soil. This will cause serious environmental pollution and endanger human health. And the electrolyte contains a certain concentration of lithium salts and organic solvents, which are worth recovering. They have economic value and can be reused. From the perspective of environmental protection and resource recycling, it is urgent to recycle and utilize electrolyte in a high value way. This paper reviews the current situation of recycling of spent lithium-ion battery electrolyte and its development prospects are prospected.
{"title":"Recycling of electrolyte from spent lithium-ion batteries","authors":"Zhiyuan Mao , Yunfeng Song , Ai Gang Zhen , Wei Sun","doi":"10.1016/j.nxsust.2023.100015","DOIUrl":"https://doi.org/10.1016/j.nxsust.2023.100015","url":null,"abstract":"<div><p>Lithium-ion batteries have become the most widely used electrochemical energy storage device due to their excellent cycling performance, safety and stability. The service life of lithium-ion batteries (LIBs) is generally 3∼5 years. Therefore, a large number of spent lithium-ion batteries will be generated in the future. Spent lithium-ion batteries will cause serious environmental pollution if not processed properly, especially the electrolyte. Nowadays, the recycling of lithium-ion batteries is mainly on the high-value electrode materials containing non-ferrous metals such as cobalt, lithium, and nickel. However, due to its volatility, toxicity and flammability, the recycling of electrolyte is less studied. The spent electrolyte reacts with water to form fluoride, which may spread into the air and soil. This will cause serious environmental pollution and endanger human health. And the electrolyte contains a certain concentration of lithium salts and organic solvents, which are worth recovering. They have economic value and can be reused. From the perspective of environmental protection and resource recycling, it is urgent to recycle and utilize electrolyte in a high value way. This paper reviews the current situation of recycling of spent lithium-ion battery electrolyte and its development prospects are prospected.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823623000156/pdfft?md5=a8b43677abedb77bc47952e592dc3325&pid=1-s2.0-S2949823623000156-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139108657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100047
Florencia Anabel Mesas , Merari Tumin Chevalier , Julieta Renée Mendieta , María Cecilia Terrile , Pablo Villanueva , Claudia Anahi Casalongué , Vera Alejandra Álvarez , Alberto Antonio Chevalier , Sergio Martin-Saldaña
The use of fishing industry waste residues for biotechnological developments is blossoming in the last decade to improve the management of marine resources while reducing the environmental impact of the fisheries sector. Chitosan (CS), is a natural and nontoxic biopolymer that exerts great antimicrobial properties and is being considered as GRAS by the United States Food and Drug Administration. In this study, we aimed to produce at a gram scale high molecular weight CS microparticles (CS-MP) from a low quality commercial raw material intended to develop an environmental friendly antimicrobial. Thus, we aimed to test the effect of sodium tripolyphosphate (TPP) used as a crosslinker on the antimicrobial performance of the CS-MP. Hence, we synthesized CS using shrimp fishing industry waste from Argentinean Patagonia at a pilot scale in order to be able to provide a cost-effective second life to the industry waste. By varying the ratio polymer/crosslinker, we studied its influence on the final physicochemical properties as well as their performance against representative crop pathogens: Pseudomonas syringae pv. tomato DC 3000 and Fusarium solani f. sp. eumartii. Our results showed a correlation between the surface charge exhibited by CS-MPs and their antimicrobial properties, through an imbalance on fungal membrane permeability. Thus, given the difference in the CS-MPs performance, it is clear that the electrostatic interaction of the particles with the negatively charged surface of the microorganism plays a key role in determining their ultimate activity. The CS-MPs exhibited great potential against crop pathogens providing a second life to fishing industry waste by developing an eco-friendly plant protectant from a valuable synergy of the national industry and academics.
{"title":"TPP crosslinking influence on the effect of sprayed dried microparticles based on industry waste sourced-chitosan over crop pathogens","authors":"Florencia Anabel Mesas , Merari Tumin Chevalier , Julieta Renée Mendieta , María Cecilia Terrile , Pablo Villanueva , Claudia Anahi Casalongué , Vera Alejandra Álvarez , Alberto Antonio Chevalier , Sergio Martin-Saldaña","doi":"10.1016/j.nxsust.2024.100047","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100047","url":null,"abstract":"<div><p>The use of fishing industry waste residues for biotechnological developments is blossoming in the last decade to improve the management of marine resources while reducing the environmental impact of the fisheries sector. Chitosan (CS), is a natural and nontoxic biopolymer that exerts great antimicrobial properties and is being considered as GRAS by the United States Food and Drug Administration. In this study, we aimed to produce at a gram scale high molecular weight CS microparticles (CS-MP) from a low quality commercial raw material intended to develop an environmental friendly antimicrobial. Thus, we aimed to test the effect of sodium tripolyphosphate (TPP) used as a crosslinker on the antimicrobial performance of the CS-MP. Hence, we synthesized CS using shrimp fishing industry waste from Argentinean Patagonia at a pilot scale in order to be able to provide a cost-effective second life to the industry waste. By varying the ratio polymer/crosslinker, we studied its influence on the final physicochemical properties as well as their performance against representative crop pathogens: <em>Pseudomonas syringae</em> pv. <em>tomato</em> DC 3000 and <em>Fusarium solani</em> f. sp<em>. eumartii</em>. Our results showed a correlation between the surface charge exhibited by CS-MPs and their antimicrobial properties, through an imbalance on fungal membrane permeability. Thus, given the difference in the CS-MPs performance, it is clear that the electrostatic interaction of the particles with the negatively charged surface of the microorganism plays a key role in determining their ultimate activity. The CS-MPs exhibited great potential against crop pathogens providing a second life to fishing industry waste by developing an eco-friendly plant protectant from a valuable synergy of the national industry and academics.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000242/pdfft?md5=140635899a63293a09d992c6d989c97c&pid=1-s2.0-S2949823624000242-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140950237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2023.100019
P.O. Oghenerukevwe , C.I. Ajuwa , O.D. Samuel , U.O. Benjamin , T.F. Adepoju
In this study, the corrosion inhibition of AISI 4140 steel tubing in 15% HCl acidic oilfield environment at the temperature of 313 to 353 K was investigated using JS.22 leaf extract (JS.22LE). The compositions of the steel were determined using be atom well-correlated with revealing confirming sho industry lead has literature is the power house be protected attacks sho the is hort comings the an chosen the isand mass spectrometry analyzer (AMSA). Weight loss was adopted to evaluate the corrosion rate (CR), while potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) were carried out in other to determine the inhibition efficiencies (IEs). The heat of adsorption was mathematically evaluated so as to examine the interaction between the adsorbate and adsorbent. The sample characterizations were also examined by FTIR, SEM-EDS, and XRD analysis. The nature of energy of reaction was examined via thermodynamic parameters (enthalpy, entropy, and the Gibb’s acidsease that free) evaluation using Gibb’s and Duhem’s equations.
Results
of the steel compositions via the AMSA indicated the presence of Fe with 97.26%, a concentrationsan a the a Extracts concentrations environmentally well-developed measures were a , an and high value of IEs: gravimetric = 88.10%, potentiodynamic polarization (PDP) = 87.00%, and electrochemical impedance spectroscopy (EIS) = 89.00%, respectively. The inhibition efficiency (IE) of JS.22LE increases with increase in inhibition concentration from 0.5 to 1.5 g/L and temperature from 313 to 353 K. Higher activation energy of 47.52 KJ/mol was recorded at 1.50 g/L, 353 K, and immersion time of 6 h. Thermodynamic parameters, ΔH of 47.26 KJ/mol, ΔS of − 33.58 J/mol were obtained. The charge transfer resistance Ɵct of 39.99 Ωcm2 was obtained at 1.50 g/L, 353 K, and 6 h. Langmuir adsorption isotherm (regression coefficient (R2) = 99.80% proved to be the best fit and the chemisorptions adsorption was achieved. Steel characterization shows a smoother surface with the extract than non-extract, low-carbonan an none of the presence of functional group as well as d-orbital element, and wellsa and an a reportan wa the formation of a protective film on the metal surface.
The forharvestedsun-driedthe continuousleafqualitativeindicates,quantitativewith acida an the a findings shows that JS.22LE treated with 15% HCl can serve as surface treatment of AISI 4140 steel corrosion in an oil well environment.
本研究使用 JS.22 叶提取物(JS.22LE)研究了在温度为 313 至 353 K 的 15% HCl 酸性油田环境中对 AISI 4140 钢管的缓蚀作用。使用原子相关性良好的原子分析仪(AMSA)测定了钢的成分,结果表明,工业铅在文献中被认为是一种具有保护作用的物质,而质谱分析仪(AMSA)则被认为是一种具有保护作用的物质。采用失重法评估腐蚀速率(CR),同时采用电位极化法(PDP)和电化学阻抗谱法(EIS)确定抑制效率(IEs)。对吸附热进行了数学评估,以研究吸附剂和吸附剂之间的相互作用。此外,还通过傅立叶变换红外光谱、扫描电镜-电子显微镜和 X 射线衍射分析检测了样品的特性。通过热力学参数(焓、熵和自由吉布斯酸度),使用吉布斯方程和杜恒方程对反应能量的性质进行了评估。通过 AMSA 检测钢成分的结果表明,铁的含量为 97.26%,提取物的浓度为 a、an 和 IEs 的高值分别为:重量法 =88.10%、电位极化法(PDP)=87.00% 和电化学阻抗谱法(EIS)=89.00%。在 1.50 g/L、353 K 和浸泡时间为 6 h 时,JS.22LE 的活化能为 47.52 KJ/mol,热力学参数ΔH 为 47.26 KJ/mol,ΔS 为 - 33.58 J/mol。在 1.50 g/L、353 K 和 6 h 条件下,电荷转移电阻 Ɵct 为 39.99 Ωcm2。事实证明,Langmuir 吸附等温线(回归系数 (R2) = 99.80%)的拟合效果最佳,实现了化学吸附。钢的表征表明,萃取液比未萃取液的表面更光滑,低碳元素和 d-轨道元素都不存在,而且井a和井a报告wa在金属表面形成了一层保护膜。
{"title":"Studies of corrosion inhibition on alloy steel (AISI 4140) using acidified green biomass","authors":"P.O. Oghenerukevwe , C.I. Ajuwa , O.D. Samuel , U.O. Benjamin , T.F. Adepoju","doi":"10.1016/j.nxsust.2023.100019","DOIUrl":"https://doi.org/10.1016/j.nxsust.2023.100019","url":null,"abstract":"<div><p>In this study, the corrosion inhibition of AISI 4140 steel tubing in 15% HCl acidic oilfield environment at the temperature of 313 to 353 K was investigated using <em>JS.22</em> leaf extract (<em>JS.22</em>LE). The compositions of the steel were determined using be atom well-correlated with revealing confirming sho industry lead has literature is the power house be protected attacks sho the is hort comings the an chosen the isand mass spectrometry analyzer (AMSA). Weight loss was adopted to evaluate the corrosion rate (CR), while potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) were carried out in other to determine the inhibition efficiencies (IEs). The heat of adsorption was mathematically evaluated so as to examine the interaction between the adsorbate and adsorbent. The sample characterizations were also examined by FTIR, SEM-EDS, and XRD analysis. The nature of energy of reaction was examined via thermodynamic parameters (enthalpy, entropy, and the Gibb’s acidsease that free) evaluation using Gibb’s and Duhem’s equations.</p></div><div><h3>Results</h3><p>of the steel compositions via the AMSA indicated the presence of Fe with 97.26%, a concentrationsan a the a Extracts concentrations environmentally well-developed measures were a , an and high value of IEs: gravimetric = 88.10%, potentiodynamic polarization (PDP) = 87.00%, and electrochemical impedance spectroscopy (EIS) = 89.00%, respectively. The inhibition efficiency (IE) of <em>JS.22</em>LE increases with increase in inhibition concentration from 0.5 to 1.5 g/L and temperature from 313 to 353 K. Higher activation energy of 47.52 KJ/mol was recorded at 1.50 g/L, 353 K, and immersion time of 6 h. Thermodynamic parameters, ΔH of 47.26 KJ/mol, ΔS of − 33.58 J/mol were obtained. The charge transfer resistance Ɵ<sub>ct</sub> of 39.99 Ωcm<sup>2</sup> was obtained at 1.50 g/L, 353 K, and 6 h. Langmuir adsorption isotherm (regression coefficient (R<sup>2</sup>) = 99.80% proved to be the best fit and the chemisorptions adsorption was achieved. Steel characterization shows a smoother surface with the extract than non-extract, low-carbonan an none of the presence of functional group as well as d-orbital element, and wellsa and an a reportan wa the formation of a protective film on the metal surface.</p><p>The forharvestedsun-driedthe continuousleafqualitativeindicates,quantitativewith acida an the a findings shows that <em>JS.22</em>LE treated with 15% HCl can serve as surface treatment of AISI 4140 steel corrosion in an oil well environment.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823623000193/pdfft?md5=30b3106fda1e94c4961cd7432f0d680a&pid=1-s2.0-S2949823623000193-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140344374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100041
David B. Olawade , Ojima Z. Wada , Aanuoluwapo Clement David-Olawade , Oluwaseun Fapohunda , Abimbola O. Ige , Jonathan Ling
This comprehensive review explores the nexus between AI and the pursuit of net-zero emissions, highlighting the potential of AI in driving sustainable development and combating climate change. The paper examines various threads within this field, including AI applications for net zero, AI-driven solutions and innovations, challenges and ethical considerations, opportunities for collaboration and partnerships, capacity building and education, policy and regulatory support, investment and funding, as well as scalability and replicability of AI solutions. Key findings emphasize the enabling role of AI in optimizing energy systems, enhancing climate modelling and prediction, improving sustainability in various sectors such as transportation, agriculture, and waste management, and enabling effective emissions monitoring and tracking. The review also highlights challenges related to data availability, quality, privacy, energy consumption, bias, fairness, human-AI collaboration, and governance. Opportunities for collaboration, capacity building, policy support, investment, and scalability are identified as key drivers for future research and implementation. Ultimately, this review underscores the transformative potential of AI in achieving a sustainable, net-zero future and provides insights for policymakers, researchers, and practitioners engaged in climate change mitigation and adaptation.
{"title":"Artificial intelligence potential for net zero sustainability: Current evidence and prospects","authors":"David B. Olawade , Ojima Z. Wada , Aanuoluwapo Clement David-Olawade , Oluwaseun Fapohunda , Abimbola O. Ige , Jonathan Ling","doi":"10.1016/j.nxsust.2024.100041","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100041","url":null,"abstract":"<div><p>This comprehensive review explores the nexus between AI and the pursuit of net-zero emissions, highlighting the potential of AI in driving sustainable development and combating climate change. The paper examines various threads within this field, including AI applications for net zero, AI-driven solutions and innovations, challenges and ethical considerations, opportunities for collaboration and partnerships, capacity building and education, policy and regulatory support, investment and funding, as well as scalability and replicability of AI solutions. Key findings emphasize the enabling role of AI in optimizing energy systems, enhancing climate modelling and prediction, improving sustainability in various sectors such as transportation, agriculture, and waste management, and enabling effective emissions monitoring and tracking. The review also highlights challenges related to data availability, quality, privacy, energy consumption, bias, fairness, human-AI collaboration, and governance. Opportunities for collaboration, capacity building, policy support, investment, and scalability are identified as key drivers for future research and implementation. Ultimately, this review underscores the transformative potential of AI in achieving a sustainable, net-zero future and provides insights for policymakers, researchers, and practitioners engaged in climate change mitigation and adaptation.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000187/pdfft?md5=b4a4f760a5286ca454a4b6cfe6725757&pid=1-s2.0-S2949823624000187-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140822121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100036
Mehmet Şen , Muciz Özcan , Yasin Ramazan Eker
The reliability and efficiency of the energy storage system used in electric vehicles (EVs) is very important for consumers. The use of lithium-ion batteries (LIBs) with high energy density is preferred in EVs. However, the long range user needs and security issues such as fire and explosion in LIB limit the widespread use of these batteries. This review discusses the working principle, performance and failures of LIB. It provides an overview of LIB with particular emphasis on the factors that affect their performance and the factors that cause failures. Finally, potential batteries to replace lithium batteries in EVs are evaluated. In addition, the challenges of these future batteries are discussed. In this paper, we review studies in the field of batteries used in EVs, general problems and future battery technologies. Methods related to such topics are compared in terms of their advantages, disadvantages and qualitative factors. The authors believe that EVs will be the transportation vehicle of the future such that battery systems should be developed and academic studies should be carried out. The authors think this study will contribute to the EV and will provide a perspective to designers, researchers, manufacturers and companies working in the field of batteries.
{"title":"A review on the lithium-ion battery problems used in electric vehicles","authors":"Mehmet Şen , Muciz Özcan , Yasin Ramazan Eker","doi":"10.1016/j.nxsust.2024.100036","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100036","url":null,"abstract":"<div><p>The reliability and efficiency of the energy storage system used in electric vehicles (EVs) is very important for consumers. The use of lithium-ion batteries (LIBs) with high energy density is preferred in EVs. However, the long range user needs and security issues such as fire and explosion in LIB limit the widespread use of these batteries. This review discusses the working principle, performance and failures of LIB. It provides an overview of LIB with particular emphasis on the factors that affect their performance and the factors that cause failures. Finally, potential batteries to replace lithium batteries in EVs are evaluated. In addition, the challenges of these future batteries are discussed. In this paper, we review studies in the field of batteries used in EVs, general problems and future battery technologies. Methods related to such topics are compared in terms of their advantages, disadvantages and qualitative factors. The authors believe that EVs will be the transportation vehicle of the future such that battery systems should be developed and academic studies should be carried out. The authors think this study will contribute to the EV and will provide a perspective to designers, researchers, manufacturers and companies working in the field of batteries.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000138/pdfft?md5=06ad05c0fc4f96d58e11475fbe921002&pid=1-s2.0-S2949823624000138-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140549346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1016/j.nxsust.2024.100045
Sreejith P. Nandan , Vishnu S. Moorchilot , Amritha Asokan , Sadritdin Turabdzhanov , Ulugbek Mirzarakhmatov , Latofat Rakhimova , C.T. Aravindakumar , Usha K. Aravind
This study examines the use of layer by layer (LbL) coated coir (CC) systems to eliminate bacterial pathogens and emerging contaminants from water. Bacterial and chemical contaminants found in river water pose risks to human health and aquatic ecosystems. The study initially compared the effectiveness of CC to uncoated coir (UC) treatment in removing bacterial pathogens. CC treatment demonstrated superior removal efficacy compared to UC treatment. For samples with a bacterial concentration of 3.6×103 CFU/mL, CC treatment achieved a removal rate exceeding 90% and viability losses of over 60% for E. coli and over 90% for S. aureus. As the number of bilayers increased, the regrowth potential of bacteria decreased, leading to mortality rates of ∼ 97% for S. aureus and 65% for E. coli respectively. Furthermore, the superiority of CC over UC in removing emerging contaminants were demonstrated. CC attained removal efficiencies of over 99% for isoniazid, 95.08% for lidocaine, 95.21% for mefenamic acid, and 87.73% for caffeine. The reproducibility of the CC system was tested and showed stable removal efficiency over multiple cycles. These findings highlight the potential of CC systems as effective eco-friendly alternatives for water purification to remove bacterial pathogens and emerging contaminants.
本研究探讨了使用逐层(LbL)涂层椰壳纤维(CC)系统消除水中细菌病原体和新污染物的方法。河水中的细菌和化学污染物对人类健康和水生生态系统构成威胁。该研究初步比较了 CC 与无涂层椰壳纤维(UC)处理在去除细菌病原体方面的效果。与 UC 处理相比,CC 处理的去除效果更佳。对于细菌浓度为 3.6×103 CFU/mL 的样本,CC 处理的去除率超过 90%,大肠杆菌的存活率损失超过 60%,金黄色葡萄球菌的存活率损失超过 90%。随着双层膜数量的增加,细菌的再生潜力下降,金黄色葡萄球菌和大肠杆菌的死亡率分别为 97% 和 65%。此外,在去除新出现的污染物方面,CC 比 UC 更具优势。CC 对异烟肼的去除率超过 99%,对利多卡因的去除率为 95.08%,对甲灭酸的去除率为 95.21%,对咖啡因的去除率为 87.73%。对 CC 系统的可重复性进行了测试,结果表明该系统在多个循环中都能稳定地去除异烟肼。这些发现凸显了 CC 系统作为有效的生态友好型水净化替代品去除细菌病原体和新污染物的潜力。
{"title":"Coir based biofiltration system for enhanced removal of water pollutants","authors":"Sreejith P. Nandan , Vishnu S. Moorchilot , Amritha Asokan , Sadritdin Turabdzhanov , Ulugbek Mirzarakhmatov , Latofat Rakhimova , C.T. Aravindakumar , Usha K. Aravind","doi":"10.1016/j.nxsust.2024.100045","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100045","url":null,"abstract":"<div><p>This study examines the use of layer by layer (LbL) coated coir (CC) systems to eliminate bacterial pathogens and emerging contaminants from water. Bacterial and chemical contaminants found in river water pose risks to human health and aquatic ecosystems. The study initially compared the effectiveness of CC to uncoated coir (UC) treatment in removing bacterial pathogens. CC treatment demonstrated superior removal efficacy compared to UC treatment. For samples with a bacterial concentration of 3.6×103 CFU/mL, CC treatment achieved a removal rate exceeding 90% and viability losses of over 60% for E. coli and over 90% for S. aureus. As the number of bilayers increased, the regrowth potential of bacteria decreased, leading to mortality rates of ∼ 97% for S. aureus and 65% for E. coli respectively. Furthermore, the superiority of CC over UC in removing emerging contaminants were demonstrated. CC attained removal efficiencies of over 99% for isoniazid, 95.08% for lidocaine, 95.21% for mefenamic acid, and 87.73% for caffeine. The reproducibility of the CC system was tested and showed stable removal efficiency over multiple cycles. These findings highlight the potential of CC systems as effective eco-friendly alternatives for water purification to remove bacterial pathogens and emerging contaminants.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000229/pdfft?md5=092521f2f758e22efa58ec60ad2b4b8e&pid=1-s2.0-S2949823624000229-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140947782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study delves into the catalytic reduction of nitrate in water using a Pd 1(wt%) In 0.25(wt%) catalyst supported on alumina. Investigating the influence of formic acid concentration, pH control, and catalyst characteristics on performance and selectivity, we find that higher formic acid concentrations boost initial reaction rates until saturation, impacting activity. Stoichiometric formic acid concentration strikes the best balance between activity and N2 selectivity. Comparative studies with hydrogen highlight formic acid's unique role in nitrate reduction. pH control using formic acid ensures full nitrate conversion, highlighting its dual role as a pH regulator and reducing agent. Additionally, the study uncovers a volcano-type behavior and surface properties affecting catalytic activity. Characterization through XPS, XRD, and SEM techniques provides valuable insights into the catalyst's composition and distribution. This comprehensive investigation sheds light on key parameters influencing catalytic nitrate reduction, guiding optimal water treatment processes. The economically advantageous and efficient (Pd, In)-based catalyst emerges as a promising solution for nitrate removal applications, addressing global water contamination challenges.
本研究深入探讨了使用以氧化铝为载体的 Pd 1(wt%) In 0.25(wt%) 催化剂催化还原水中硝酸盐的过程。通过研究甲酸浓度、pH 值控制和催化剂特性对性能和选择性的影响,我们发现较高的甲酸浓度会提高初始反应速率直至饱和,从而影响活性。化学计量甲酸浓度在活性和 N2 选择性之间达到了最佳平衡。与氢气的比较研究突出了甲酸在硝酸盐还原过程中的独特作用。 使用甲酸控制 pH 值可确保硝酸盐的完全转化,突出了甲酸作为 pH 值调节剂和还原剂的双重作用。此外,研究还发现了影响催化活性的火山型行为和表面特性。通过 XPS、XRD 和 SEM 技术进行表征,可以深入了解催化剂的组成和分布。这项全面的研究揭示了影响催化硝酸盐还原的关键参数,为优化水处理工艺提供了指导。这种具有经济优势的高效(钯、铟)基催化剂有望成为硝酸盐去除应用的解决方案,从而应对全球水污染的挑战。
{"title":"Maximizing selectivity and activity in the catalytic reduction of nitrates with formic acid under optimal pH conditions","authors":"Fernanda Miranda Zoppas , Nicolás Sacco , Thiago Beltrame , Faheem Akhter , Eduardo Miró , Fernanda Albana Marchesini","doi":"10.1016/j.nxsust.2024.100030","DOIUrl":"https://doi.org/10.1016/j.nxsust.2024.100030","url":null,"abstract":"<div><p>This study delves into the catalytic reduction of nitrate in water using a Pd 1(wt%) In 0.25(wt%) catalyst supported on alumina. Investigating the influence of formic acid concentration, pH control, and catalyst characteristics on performance and selectivity, we find that higher formic acid concentrations boost initial reaction rates until saturation, impacting activity. Stoichiometric formic acid concentration strikes the best balance between activity and N<sub>2</sub> selectivity. Comparative studies with hydrogen highlight formic acid's unique role in nitrate reduction. pH control using formic acid ensures full nitrate conversion, highlighting its dual role as a pH regulator and reducing agent. Additionally, the study uncovers a volcano-type behavior and surface properties affecting catalytic activity. Characterization through XPS, XRD, and SEM techniques provides valuable insights into the catalyst's composition and distribution. This comprehensive investigation sheds light on key parameters influencing catalytic nitrate reduction, guiding optimal water treatment processes. The economically advantageous and efficient (Pd, In)-based catalyst emerges as a promising solution for nitrate removal applications, addressing global water contamination challenges.</p></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949823624000072/pdfft?md5=9c3b10c901e5953fbf2d3ba62e99fd91&pid=1-s2.0-S2949823624000072-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139999121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}