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Building integrated photovoltaic-thermal systems (BIPVT) and spectral splitting technology: A critical review 光伏-热建筑一体化系统(BIPVT)和分光技术:重要综述
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100056
Xin Ma , Aritra Ghosh , Erdem Cuce , Shaik Saboor

Solar energy is an effective means of reducing global greenhouse gas emissions. This review provides an overview of building-integrated photovoltaic thermal (BIPVT) systems, highlighting their potential advantages and challenges. The goal is to evaluate how BIPVT systems can improve energy efficiency, cost-effectiveness, and sustainability. This article provides a comprehensive study of various BIPVT systems and spectral splitting techniques and discusses the performance and efficiency of different BIPVT applications. Additionally, this review analyzes the factors that influence the design, installation, and maintenance of BIPVT systems, as well as the economics, feasibility, and market potential of BIPVT systems. The results show that BIPVT systems have significant promise in improving photovoltaic (PV) module electrical efficiency, system thermal efficiency and reducing energy consumption, thus contributing to climate change mitigation. However, its high initial installation cost compared to traditional heating and cooling systems or stand-alone solar systems remains a major barrier to widespread adoption. To enhance market dynamism, further research and development work is required to improve performance and efficiency, reduce installation costs and overcome existing technical challenges.

太阳能是减少全球温室气体排放的有效手段。本综述概述了光伏热建筑一体化(BIPVT)系统,强调了其潜在优势和挑战。目的是评估 BIPVT 系统如何提高能源效率、成本效益和可持续性。本文全面研究了各种 BIPVT 系统和分光技术,并讨论了不同 BIPVT 应用的性能和效率。此外,本文还分析了影响 BIPVT 系统设计、安装和维护的因素,以及 BIPVT 系统的经济性、可行性和市场潜力。研究结果表明,BIPVT 系统在提高光伏(PV)模块的电气效率、系统热效率和减少能源消耗方面大有可为,从而有助于减缓气候变化。然而,与传统供热制冷系统或独立太阳能系统相比,BIPVT 系统的初始安装成本较高,这仍然是阻碍其广泛应用的主要障碍。为了增强市场活力,需要进一步开展研发工作,以提高性能和效率,降低安装成本,克服现有的技术挑战。
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引用次数: 0
Sustainable passive solar and photovoltaic integrated technology interventions for climate responsive net zero energy buildings in western Himalayan mountainous terrain of India 在印度喜马拉雅西部山区采用可持续被动式太阳能和光伏发电综合技术,建造适应气候的净零能耗建筑
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100039
Rahul Chandel , Shyam Singh Chandel , Deo Prasad , Ram Prakash Dwivedi

The global warming concerns, greenhouse gas emission reduction, are not being addressed effectively in the energy-consuming building sector worldwide. This study presents a novel approach of solar technology interventions for sustainable buildings namely rooftop photovoltaic systems, use of carbon-free sustainable building materials, and passive solar heating systems. A methodology for achieving net zero energy and zero carbon emission buildings is described. This strategy is being implemented to develop an educational institution as a sustainable campus in a Western Himalayan cold region of India. The results show an energy yield of 1561 kWh/kWp/year from a proposed photovoltaic power system for a typical building at this location producing 10,928 kWh avoiding 7.7 t-CO2 emissions which means the system will produce enough electricity in 2.6 years to offset the amount of carbon emissions during manufacturing of PV modules. The modeling and simulation analysis using the developed mathematical model shows that the space heating system provides 37–56 % of total energy needs with a payback period of 3.5–5.8 years depending on the type of six different construction materials used. The innovative mandatory policy and solar technology interventions implemented can be followed in remote rural and semi-urban areas in developing countries.

全球变暖问题、减少温室气体排放等问题并未在全球耗能建筑领域得到有效解决。本研究提出了一种可持续建筑太阳能技术干预的新方法,即屋顶光伏系统、使用无碳可持续建筑材料和被动式太阳能供热系统。研究还介绍了实现零净能耗和零碳排放建筑的方法。印度西喜马拉雅山寒冷地区的一所教育机构正在实施这一战略,将其建设成一个可持续发展的校园。研究结果表明,在该地区的一栋典型建筑中,拟议的光伏发电系统每年可产生 1561 千瓦时/千瓦时的电量,可避免 7.7 吨二氧化碳排放,即该系统在 2.6 年内产生的电量足以抵消光伏组件生产过程中的碳排放量。利用所开发的数学模型进行的建模和模拟分析表明,空间供暖系统可提供总能源需求的 37-56%,投资回收期为 3.5-5.8 年,具体取决于所使用的六种不同建筑材料的类型。发展中国家的偏远农村和半城市地区可以借鉴所实施的创新性强制性政策和太阳能技术干预措施。
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引用次数: 0
Catalytic gasification of municipal solid waste using eggshell-derived CaO catalyst: An investigation of optimum H2 production, production distribution, and tar compounds 使用源自蛋壳的 CaO 催化剂催化气化城市固体废物:对最佳 H2 产量、产量分布和焦油化合物的研究
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100038
Azhar Ali Laghari , Imtiaz Ali Jamro , Akash Kumar , Guanyi Chen , Shahdev Sajnani , Zhangzhen Guo , Yongheng Shen , Junzhe Zhang , Salim Khoso , Qingxia Guo , Wenchao Ma

This study reports the optimum hydrogen (H2) production from municipal solid waste (MSW) via waste eggshell derived-CaO catalyst through gasification technology. The response surface model was applied to design the experiments and the data validation. Results showed that CaO catalyst had a better performance that enhanced 15 mol% more H2 production than non-catalytic gasification by mainly involving reaction temperature and catalyst loading as the critical parameters. Tar content was efficiently declined from 11.34 wt. % to 4.7 , wt. %, which ultimately elevated the H2 and syngas from 33.95 mol% to 51.27 mol% and 74.05 to 83.4674.05–83.46 wt. %, respectively. The model showed a strong interaction among the statistical parameters verified through the regression values; R2 = 0.990, P-value = 0.000005, respectively. Scanning electron microscopy, X-ray diffraction, and Brunauer-Emmett-Teller techniques investigated the catalyst's structure hence; presented comparable results. From tar analysis, the aromatics were found as the dominant family followed by polycyclic aromatic, phenyls, aliphatic, aromatic heterocyclic, polycyclic, and aromatic ketones. Optimum H2 production of 51.27 mol% (with H2/CO ratio 2.82, LHV 9.47 MJ/Nm3, and H2 yield 22.74 mol kg-MSW−1) was produced which can be a better alternative to depleting fossil fuels and utilized for liquid fuel manufacturing and power generation.

本研究报告了通过气化技术从城市固体废弃物(MSW)中提取氢气(H2)的最佳方法。实验设计和数据验证采用了响应面模型。结果表明,CaO 催化剂具有更好的性能,与非催化气化相比,主要以反应温度和催化剂负载为关键参数,可提高 15 摩尔%的 H2 产量。焦油含量从 11.34 wt. % 有效降至 4.7 wt. %,最终使 H2 和合成气的含量分别从 33.95 mol% 和 74.05 mol% 提高到 51.27 mol% 和 83.4674.05-83.46 wt. %。通过回归值验证,该模型显示统计参数之间存在很强的相互作用;R2 = 0.990,P 值 = 0.000005。扫描电子显微镜、X 射线衍射和布鲁瑙尔-艾美特-泰勒技术对催化剂的结构进行了研究,并得出了相似的结果。焦油分析发现,芳香族是主要家族,其次是多环芳香族、苯基、脂肪族、芳香杂环族、多环族和芳香酮族。产生的最佳 H2 产量为 51.27 摩尔%(H2/CO 比率为 2.82,LHV 为 9.47 兆焦耳/立方米,H2 产量为 22.74 摩尔千克-兆瓦-1),可以更好地替代日益枯竭的化石燃料,并用于液体燃料生产和发电。
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引用次数: 0
Recycling of electrolyte from spent lithium-ion batteries 废锂离子电池电解液的回收利用
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2023.100015
Zhiyuan Mao , Yunfeng Song , Ai Gang Zhen , Wei Sun

Lithium-ion batteries have become the most widely used electrochemical energy storage device due to their excellent cycling performance, safety and stability. The service life of lithium-ion batteries (LIBs) is generally 3∼5 years. Therefore, a large number of spent lithium-ion batteries will be generated in the future. Spent lithium-ion batteries will cause serious environmental pollution if not processed properly, especially the electrolyte. Nowadays, the recycling of lithium-ion batteries is mainly on the high-value electrode materials containing non-ferrous metals such as cobalt, lithium, and nickel. However, due to its volatility, toxicity and flammability, the recycling of electrolyte is less studied. The spent electrolyte reacts with water to form fluoride, which may spread into the air and soil. This will cause serious environmental pollution and endanger human health. And the electrolyte contains a certain concentration of lithium salts and organic solvents, which are worth recovering. They have economic value and can be reused. From the perspective of environmental protection and resource recycling, it is urgent to recycle and utilize electrolyte in a high value way. This paper reviews the current situation of recycling of spent lithium-ion battery electrolyte and its development prospects are prospected.

锂离子电池因其优异的循环性能、安全性和稳定性,已成为应用最广泛的电化学储能设备。锂离子电池的使用寿命一般为 3∼5 年。因此,未来将产生大量废旧锂离子电池。如果处理不当,废旧锂离子电池将造成严重的环境污染,尤其是电解液。目前,锂离子电池的回收主要针对含有钴、锂、镍等有色金属的高价值电极材料。然而,由于其挥发性、毒性和易燃性,电解液的回收研究较少。废电解液与水反应生成氟化物,可能扩散到空气和土壤中。这会造成严重的环境污染,危害人体健康。而电解液中含有一定浓度的锂盐和有机溶剂,值得回收。它们具有经济价值,可以重复利用。从环境保护和资源循环利用的角度来看,电解液的高值化回收和利用迫在眉睫。本文回顾了废锂离子电池电解液的回收现状,并对其发展前景进行了展望。
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引用次数: 0
TPP crosslinking influence on the effect of sprayed dried microparticles based on industry waste sourced-chitosan over crop pathogens TPP 交联对基于工业废弃物壳聚糖的喷雾干燥微颗粒对作物病原体影响的影响
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100047
Florencia Anabel Mesas , Merari Tumin Chevalier , Julieta Renée Mendieta , María Cecilia Terrile , Pablo Villanueva , Claudia Anahi Casalongué , Vera Alejandra Álvarez , Alberto Antonio Chevalier , Sergio Martin-Saldaña

The use of fishing industry waste residues for biotechnological developments is blossoming in the last decade to improve the management of marine resources while reducing the environmental impact of the fisheries sector. Chitosan (CS), is a natural and nontoxic biopolymer that exerts great antimicrobial properties and is being considered as GRAS by the United States Food and Drug Administration. In this study, we aimed to produce at a gram scale high molecular weight CS microparticles (CS-MP) from a low quality commercial raw material intended to develop an environmental friendly antimicrobial. Thus, we aimed to test the effect of sodium tripolyphosphate (TPP) used as a crosslinker on the antimicrobial performance of the CS-MP. Hence, we synthesized CS using shrimp fishing industry waste from Argentinean Patagonia at a pilot scale in order to be able to provide a cost-effective second life to the industry waste. By varying the ratio polymer/crosslinker, we studied its influence on the final physicochemical properties as well as their performance against representative crop pathogens: Pseudomonas syringae pv. tomato DC 3000 and Fusarium solani f. sp. eumartii. Our results showed a correlation between the surface charge exhibited by CS-MPs and their antimicrobial properties, through an imbalance on fungal membrane permeability. Thus, given the difference in the CS-MPs performance, it is clear that the electrostatic interaction of the particles with the negatively charged surface of the microorganism plays a key role in determining their ultimate activity. The CS-MPs exhibited great potential against crop pathogens providing a second life to fishing industry waste by developing an eco-friendly plant protectant from a valuable synergy of the national industry and academics.

近十年来,利用渔业废料残渣进行生物技术开发的活动蓬勃发展,在改善海洋资源管理的同时减少了渔业对环境的影响。壳聚糖(CS)是一种天然无毒的生物聚合物,具有很强的抗菌性能,被美国食品和药物管理局认定为 GRAS。在这项研究中,我们的目标是利用一种低质量的商业原料生产克级高分子量 CS 微颗粒(CS-MP),旨在开发一种环境友好型抗菌剂。因此,我们旨在测试用作交联剂的三聚磷酸钠(TPP)对 CS-MP 抗菌性能的影响。因此,我们利用阿根廷巴塔哥尼亚的捕虾业废料,在试点规模上合成了 CS,目的是为捕虾业废料提供具有成本效益的第二次生命。通过改变聚合物/交联剂的比例,我们研究了其对最终理化性质的影响以及对代表性作物病原体的抗性:Pseudomonas syringae pv. tomato DC 3000 和 Fusarium solani f. sp. eumartii。我们的研究结果表明,CS-MPs 的表面电荷与它们的抗菌特性之间存在关联,这是因为它们对真菌膜渗透性的影响是不平衡的。因此,鉴于 CS-MPs 性能的差异,颗粒与带负电荷的微生物表面之间的静电相互作用显然在决定其最终活性方面起着关键作用。CS-MPs 在对抗作物病原体方面表现出了巨大的潜力,通过开发一种生态友好型植物保护剂,为渔业废物提供了第二次生命。
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引用次数: 0
Studies of corrosion inhibition on alloy steel (AISI 4140) using acidified green biomass 利用酸化绿色生物质对合金钢(AISI 4140)进行缓蚀研究
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2023.100019
P.O. Oghenerukevwe , C.I. Ajuwa , O.D. Samuel , U.O. Benjamin , T.F. Adepoju

In this study, the corrosion inhibition of AISI 4140 steel tubing in 15% HCl acidic oilfield environment at the temperature of 313 to 353 K was investigated using JS.22 leaf extract (JS.22LE). The compositions of the steel were determined using be atom well-correlated with revealing confirming sho industry lead has literature is the power house be protected attacks sho the is hort comings the an chosen the isand mass spectrometry analyzer (AMSA). Weight loss was adopted to evaluate the corrosion rate (CR), while potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) were carried out in other to determine the inhibition efficiencies (IEs). The heat of adsorption was mathematically evaluated so as to examine the interaction between the adsorbate and adsorbent. The sample characterizations were also examined by FTIR, SEM-EDS, and XRD analysis. The nature of energy of reaction was examined via thermodynamic parameters (enthalpy, entropy, and the Gibb’s acidsease that free) evaluation using Gibb’s and Duhem’s equations.

Results

of the steel compositions via the AMSA indicated the presence of Fe with 97.26%, a concentrationsan a the a Extracts concentrations environmentally well-developed measures were a , an and high value of IEs: gravimetric = 88.10%, potentiodynamic polarization (PDP) = 87.00%, and electrochemical impedance spectroscopy (EIS) = 89.00%, respectively. The inhibition efficiency (IE) of JS.22LE increases with increase in inhibition concentration from 0.5 to 1.5 g/L and temperature from 313 to 353 K. Higher activation energy of 47.52 KJ/mol was recorded at 1.50 g/L, 353 K, and immersion time of 6 h. Thermodynamic parameters, ΔH of 47.26 KJ/mol, ΔS of − 33.58 J/mol were obtained. The charge transfer resistance Ɵct of 39.99 Ωcm2 was obtained at 1.50 g/L, 353 K, and 6 h. Langmuir adsorption isotherm (regression coefficient (R2) = 99.80% proved to be the best fit and the chemisorptions adsorption was achieved. Steel characterization shows a smoother surface with the extract than non-extract, low-carbonan an none of the presence of functional group as well as d-orbital element, and wellsa and an a reportan wa the formation of a protective film on the metal surface.

The forharvestedsun-driedthe continuousleafqualitativeindicates,quantitativewith acida an the a findings shows that JS.22LE treated with 15% HCl can serve as surface treatment of AISI 4140 steel corrosion in an oil well environment.

本研究使用 JS.22 叶提取物(JS.22LE)研究了在温度为 313 至 353 K 的 15% HCl 酸性油田环境中对 AISI 4140 钢管的缓蚀作用。使用原子相关性良好的原子分析仪(AMSA)测定了钢的成分,结果表明,工业铅在文献中被认为是一种具有保护作用的物质,而质谱分析仪(AMSA)则被认为是一种具有保护作用的物质。采用失重法评估腐蚀速率(CR),同时采用电位极化法(PDP)和电化学阻抗谱法(EIS)确定抑制效率(IEs)。对吸附热进行了数学评估,以研究吸附剂和吸附剂之间的相互作用。此外,还通过傅立叶变换红外光谱、扫描电镜-电子显微镜和 X 射线衍射分析检测了样品的特性。通过热力学参数(焓、熵和自由吉布斯酸度),使用吉布斯方程和杜恒方程对反应能量的性质进行了评估。通过 AMSA 检测钢成分的结果表明,铁的含量为 97.26%,提取物的浓度为 a、an 和 IEs 的高值分别为:重量法 =88.10%、电位极化法(PDP)=87.00% 和电化学阻抗谱法(EIS)=89.00%。在 1.50 g/L、353 K 和浸泡时间为 6 h 时,JS.22LE 的活化能为 47.52 KJ/mol,热力学参数ΔH 为 47.26 KJ/mol,ΔS 为 - 33.58 J/mol。在 1.50 g/L、353 K 和 6 h 条件下,电荷转移电阻 Ɵct 为 39.99 Ωcm2。事实证明,Langmuir 吸附等温线(回归系数 (R2) = 99.80%)的拟合效果最佳,实现了化学吸附。钢的表征表明,萃取液比未萃取液的表面更光滑,低碳元素和 d-轨道元素都不存在,而且井a和井a报告wa在金属表面形成了一层保护膜。
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引用次数: 0
Artificial intelligence potential for net zero sustainability: Current evidence and prospects 人工智能在净零可持续性方面的潜力:当前证据和前景
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100041
David B. Olawade , Ojima Z. Wada , Aanuoluwapo Clement David-Olawade , Oluwaseun Fapohunda , Abimbola O. Ige , Jonathan Ling

This comprehensive review explores the nexus between AI and the pursuit of net-zero emissions, highlighting the potential of AI in driving sustainable development and combating climate change. The paper examines various threads within this field, including AI applications for net zero, AI-driven solutions and innovations, challenges and ethical considerations, opportunities for collaboration and partnerships, capacity building and education, policy and regulatory support, investment and funding, as well as scalability and replicability of AI solutions. Key findings emphasize the enabling role of AI in optimizing energy systems, enhancing climate modelling and prediction, improving sustainability in various sectors such as transportation, agriculture, and waste management, and enabling effective emissions monitoring and tracking. The review also highlights challenges related to data availability, quality, privacy, energy consumption, bias, fairness, human-AI collaboration, and governance. Opportunities for collaboration, capacity building, policy support, investment, and scalability are identified as key drivers for future research and implementation. Ultimately, this review underscores the transformative potential of AI in achieving a sustainable, net-zero future and provides insights for policymakers, researchers, and practitioners engaged in climate change mitigation and adaptation.

本综述探讨了人工智能与追求净零排放之间的关系,强调了人工智能在推动可持续发展和应对气候变化方面的潜力。本文探讨了这一领域的各种主线,包括人工智能在净零排放方面的应用、人工智能驱动的解决方案和创新、挑战和道德考量、合作和伙伴关系的机遇、能力建设和教育、政策和监管支持、投资和资金,以及人工智能解决方案的可扩展性和可复制性。主要结论强调了人工智能在优化能源系统、加强气候建模和预测、改善交通、农业和废物管理等各部门的可持续性以及实现有效的排放监测和跟踪方面的促进作用。审查还强调了与数据可用性、质量、隐私、能源消耗、偏见、公平性、人类与人工智能合作以及治理有关的挑战。合作、能力建设、政策支持、投资和可扩展性方面的机遇被确定为未来研究和实施的主要驱动力。最后,本综述强调了人工智能在实现可持续、净零排放未来方面的变革潜力,并为政策制定者、研究人员和从事气候变化减缓和适应工作的从业人员提供了真知灼见。
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引用次数: 0
A review on the lithium-ion battery problems used in electric vehicles 电动汽车使用的锂离子电池问题综述
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100036
Mehmet Şen , Muciz Özcan , Yasin Ramazan Eker

The reliability and efficiency of the energy storage system used in electric vehicles (EVs) is very important for consumers. The use of lithium-ion batteries (LIBs) with high energy density is preferred in EVs. However, the long range user needs and security issues such as fire and explosion in LIB limit the widespread use of these batteries. This review discusses the working principle, performance and failures of LIB. It provides an overview of LIB with particular emphasis on the factors that affect their performance and the factors that cause failures. Finally, potential batteries to replace lithium batteries in EVs are evaluated. In addition, the challenges of these future batteries are discussed. In this paper, we review studies in the field of batteries used in EVs, general problems and future battery technologies. Methods related to such topics are compared in terms of their advantages, disadvantages and qualitative factors. The authors believe that EVs will be the transportation vehicle of the future such that battery systems should be developed and academic studies should be carried out. The authors think this study will contribute to the EV and will provide a perspective to designers, researchers, manufacturers and companies working in the field of batteries.

电动汽车(EV)所用储能系统的可靠性和效率对消费者来说非常重要。在电动汽车中使用高能量密度的锂离子电池(LIB)是首选。然而,用户的长距离需求以及锂离子电池的起火和爆炸等安全问题限制了这些电池的广泛使用。本综述讨论了 LIB 的工作原理、性能和故障。它概述了锂电池,特别强调了影响其性能的因素和导致故障的因素。最后,对电动汽车中可能替代锂电池的电池进行了评估。此外,还讨论了这些未来电池所面临的挑战。在本文中,我们回顾了电动汽车所用电池、一般问题和未来电池技术领域的研究。本文比较了与这些主题相关的方法的优缺点和定性因素。作者认为,电动汽车将是未来的交通工具,因此应开发电池系统并开展学术研究。作者认为本研究将对电动汽车做出贡献,并将为电池领域的设计师、研究人员、制造商和公司提供一个视角。
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引用次数: 0
Coir based biofiltration system for enhanced removal of water pollutants 基于椰壳纤维的生物过滤系统,提高水污染物的去除率
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100045
Sreejith P. Nandan , Vishnu S. Moorchilot , Amritha Asokan , Sadritdin Turabdzhanov , Ulugbek Mirzarakhmatov , Latofat Rakhimova , C.T. Aravindakumar , Usha K. Aravind

This study examines the use of layer by layer (LbL) coated coir (CC) systems to eliminate bacterial pathogens and emerging contaminants from water. Bacterial and chemical contaminants found in river water pose risks to human health and aquatic ecosystems. The study initially compared the effectiveness of CC to uncoated coir (UC) treatment in removing bacterial pathogens. CC treatment demonstrated superior removal efficacy compared to UC treatment. For samples with a bacterial concentration of 3.6×103 CFU/mL, CC treatment achieved a removal rate exceeding 90% and viability losses of over 60% for E. coli and over 90% for S. aureus. As the number of bilayers increased, the regrowth potential of bacteria decreased, leading to mortality rates of ∼ 97% for S. aureus and 65% for E. coli respectively. Furthermore, the superiority of CC over UC in removing emerging contaminants were demonstrated. CC attained removal efficiencies of over 99% for isoniazid, 95.08% for lidocaine, 95.21% for mefenamic acid, and 87.73% for caffeine. The reproducibility of the CC system was tested and showed stable removal efficiency over multiple cycles. These findings highlight the potential of CC systems as effective eco-friendly alternatives for water purification to remove bacterial pathogens and emerging contaminants.

本研究探讨了使用逐层(LbL)涂层椰壳纤维(CC)系统消除水中细菌病原体和新污染物的方法。河水中的细菌和化学污染物对人类健康和水生生态系统构成威胁。该研究初步比较了 CC 与无涂层椰壳纤维(UC)处理在去除细菌病原体方面的效果。与 UC 处理相比,CC 处理的去除效果更佳。对于细菌浓度为 3.6×103 CFU/mL 的样本,CC 处理的去除率超过 90%,大肠杆菌的存活率损失超过 60%,金黄色葡萄球菌的存活率损失超过 90%。随着双层膜数量的增加,细菌的再生潜力下降,金黄色葡萄球菌和大肠杆菌的死亡率分别为 97% 和 65%。此外,在去除新出现的污染物方面,CC 比 UC 更具优势。CC 对异烟肼的去除率超过 99%,对利多卡因的去除率为 95.08%,对甲灭酸的去除率为 95.21%,对咖啡因的去除率为 87.73%。对 CC 系统的可重复性进行了测试,结果表明该系统在多个循环中都能稳定地去除异烟肼。这些发现凸显了 CC 系统作为有效的生态友好型水净化替代品去除细菌病原体和新污染物的潜力。
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引用次数: 0
Maximizing selectivity and activity in the catalytic reduction of nitrates with formic acid under optimal pH conditions 在最佳 pH 值条件下最大限度地提高甲酸催化还原硝酸盐的选择性和活性
Pub Date : 2024-01-01 DOI: 10.1016/j.nxsust.2024.100030
Fernanda Miranda Zoppas , Nicolás Sacco , Thiago Beltrame , Faheem Akhter , Eduardo Miró , Fernanda Albana Marchesini

This study delves into the catalytic reduction of nitrate in water using a Pd 1(wt%) In 0.25(wt%) catalyst supported on alumina. Investigating the influence of formic acid concentration, pH control, and catalyst characteristics on performance and selectivity, we find that higher formic acid concentrations boost initial reaction rates until saturation, impacting activity. Stoichiometric formic acid concentration strikes the best balance between activity and N2 selectivity. Comparative studies with hydrogen highlight formic acid's unique role in nitrate reduction. pH control using formic acid ensures full nitrate conversion, highlighting its dual role as a pH regulator and reducing agent. Additionally, the study uncovers a volcano-type behavior and surface properties affecting catalytic activity. Characterization through XPS, XRD, and SEM techniques provides valuable insights into the catalyst's composition and distribution. This comprehensive investigation sheds light on key parameters influencing catalytic nitrate reduction, guiding optimal water treatment processes. The economically advantageous and efficient (Pd, In)-based catalyst emerges as a promising solution for nitrate removal applications, addressing global water contamination challenges.

本研究深入探讨了使用以氧化铝为载体的 Pd 1(wt%) In 0.25(wt%) 催化剂催化还原水中硝酸盐的过程。通过研究甲酸浓度、pH 值控制和催化剂特性对性能和选择性的影响,我们发现较高的甲酸浓度会提高初始反应速率直至饱和,从而影响活性。化学计量甲酸浓度在活性和 N2 选择性之间达到了最佳平衡。与氢气的比较研究突出了甲酸在硝酸盐还原过程中的独特作用。 使用甲酸控制 pH 值可确保硝酸盐的完全转化,突出了甲酸作为 pH 值调节剂和还原剂的双重作用。此外,研究还发现了影响催化活性的火山型行为和表面特性。通过 XPS、XRD 和 SEM 技术进行表征,可以深入了解催化剂的组成和分布。这项全面的研究揭示了影响催化硝酸盐还原的关键参数,为优化水处理工艺提供了指导。这种具有经济优势的高效(钯、铟)基催化剂有望成为硝酸盐去除应用的解决方案,从而应对全球水污染的挑战。
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引用次数: 0
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Next Sustainability
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