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The mirror buckling analysis of freestanding graphene membranes based on the coarse-grained molecular dynamics method 基于粗粒分子动力学方法的独立石墨烯膜镜像屈曲分析
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231120
None Xu Wenlong, None Kai Yue, None Zhang Kai, None Zheng Balin
For now, just few researchers have analyzed the thermal-mechanical mirror buckling behavior of freestanding graphene membranes discovered in scan tunneling microscope experiments. Ones of the potential applies of the out-of-plane deformational behavior of graphene membranes are energy harvesting systems. Whatever in the experiments, or for energy harvesting systems, the graphene membranes are micron order. According to previous researches, traditional molecular dynamics method is an appropriate approach to express mirror buckling with nano scale. However, due to the limit of algorithm, when dealing with micro size model by molecular dynamics method, the problems of low computational efficiency and too long calculational time may arise. Therefore, for analyzing the mirror buckling of micro size graphene membranes, the coarse-grained molecular dynamics method is utilized in this paper. Graphene membranes with a fan-shaped cross section and various depth-span ratios are under mechanical or thermal loads. Influences of every factor on the mirror buckling are explored. The calculations indicated that for graphene membranes with various depth-span ratios under mechanical load mirror buckling could be observed. And the critical loading increases with the depth-span ratio. Under thermal load graphene membranes only with low depth-span ratios could totally overturn. For high depth-span ratio graphene, the center height decreases with temperature rise. However, it is hard to overturn completely. Understanding the influences of various factors on the mirror buckling phenomenon of graphene membranes provides theoretical guidance for the design of energy harvesting systems.
目前,只有少数研究人员分析了扫描隧道显微镜实验中发现的独立石墨烯膜的热机械镜面屈曲行为。石墨烯膜的面外变形行为的潜在应用之一是能量收集系统。无论是在实验中,还是在能量收集系统中,石墨烯膜都是微米级的。根据以往的研究,传统的分子动力学方法是表征纳米尺度镜像屈曲的合适方法。然而,由于算法的限制,用分子动力学方法处理微尺度模型时,可能会出现计算效率低、计算时间过长的问题。因此,为了分析微尺寸石墨烯膜的镜像屈曲,本文采用了粗粒度分子动力学方法。具有扇形截面和不同深跨比的石墨烯膜承受机械或热载荷。探讨了各种因素对镜面屈曲的影响。计算结果表明,对于不同深跨比的石墨烯膜,在机械载荷作用下可以观察到镜面屈曲现象。临界荷载随深跨比增大而增大。在热负荷下,只有低深跨比的石墨烯膜才会完全倾覆。对于高深跨比石墨烯,中心高度随温度升高而降低。然而,这很难完全推翻。了解各种因素对石墨烯膜镜面屈曲现象的影响,为能量收集系统的设计提供理论指导。
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引用次数: 0
Mechanical stress-thermodynamic phase-field simulation of lithium dendrite growth in solid electrolyte battery 固体电解质电池中锂枝晶生长的机械应力-热力学相场模拟
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230824
None Geng Xiao-Bin, None Li Ding-Gen, None Xu Bo
Growth of lithium dendrites in solid state batteries is an important factor that disturbs their commercial applications. The growth of lithium dendrites at the interface of lithium metal anode will not only lead to the decrease of battery energy efficiency, but also cause combustion, explosion and other safety problems. In order to explore the factors and methods that inhibit the growth of lithium dendrites, the phase-field theory is used to simulate the growth of lithium dendrites in polymer solid electrolyte batteries, and a phase-field model of lithium dendrite growth coupled with mechanical stress and thermal field is established. The effects of key physical factors such as ambient temperature, solid electrolyte Young’s modulus and external stress on dendrite growth and their acting principles are discussed and analyzed. The results show that under the conditions of high temperature, high solid electrolyte Young’s modulus and external stress, the growth of lithium dendrites is slow, the number of long dendrites is small, and the electrodeposition is more uniform. In addition, the effects of Young’s modulus of solid electrolyte and ambient temperature on the growth of lithium dendrites in a common range are compared with each other. It is found that the inhibition effect of changing Young’s modulus of solid electrolyte on the maximum length of lithium dendrites is 19% higher than that caused by the change of ambient temperature.
固态电池中锂枝晶的生长是影响其商业应用的一个重要因素。锂金属负极界面处锂枝晶的生长不仅会导致电池能量效率的下降,还会引起燃烧、爆炸等安全问题。为了探索抑制锂枝晶生长的因素和方法,运用相场理论对聚合物固体电解质电池中锂枝晶的生长进行了模拟,建立了机械应力和热场耦合作用下锂枝晶生长的相场模型。讨论和分析了环境温度、固体电解质杨氏模量和外部应力等关键物理因素对枝晶生长的影响及其作用原理。结果表明:在高温、高固体电解质杨氏模量和外加应力条件下,锂枝晶生长缓慢,长枝晶数量少,电沉积更加均匀;此外,还比较了固体电解质杨氏模量和环境温度对锂枝晶生长的影响。研究发现,固体电解质杨氏模量变化对锂枝晶最大长度的抑制作用比环境温度变化的抑制作用高19%。
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引用次数: 0
Large scale and quantum accurate molecular dynamics simulation: liquid iron under extreme condition 大尺度和量子精确分子动力学模拟:极端条件下的液态铁
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231258
Qi-Yu Zeng, Bo Chen, Dong-Dong Kang, Jia-Yu Dai
Liquid iron is the major component of planetary cores. Its structure and dynamics under high pressure and temperature is of great significance in studying geophysics and planetary science. However, for experimental techniques, it is still difficult to generate and probe such a state of matter under extreme conditions, while for theoretical method like molecular dynamics simulation, the reliable estimation of dynamic properties requires both large simulation size and ab initio accuracy, resulting in unaffordable computational costs for traditional method. Owing to the technical limitation, the understanding of such matters remains limited. In this work, combining molecular dynamics simulation, we establish a neural network potential energy surface model to study the static and dynamic properties of liquid iron at its extreme thermodynamic state close to core-mantle boundary. The implementation of deep neural network extends the simulation scales from one hundred atoms to millions of atoms within quantum accuracy. The estimated static and dynamic structure factor show good consistency with all available X-ray diffraction and inelastic X-ray scattering experimental observations, while the empirical potential based on embedding-atom-method fails to give a unified description of liquid iron across a wide range of thermodynamic conditions. We also demonstrate that the transport property like diffusion coefficient exhibits a strong size effect, which requires more than at least ten thousands of atoms to give a converged value. Our results show that the combination of deep learning technology and molecular modelling provides a way to describe matter realistically under extreme conditions.
液态铁是行星核心的主要成分。它的结构和高压高温下的动力学在地球物理和行星科学研究中具有重要意义。然而,对于实验技术来说,在极端条件下生成和探测物质的这种状态仍然是困难的,而对于分子动力学模拟等理论方法来说,对动态性质的可靠估计既需要较大的模拟规模,又需要<i>ab initio</i>精度高,导致传统方法的计算成本难以承受。由于技术上的限制,对这些事项的了解仍然有限。本文结合分子动力学模拟,建立了神经网络势能面模型,研究了铁液在接近核幔边界的极端热力学状态下的静态和动态性质。深度神经网络的实现在量子精度范围内将模拟尺度从100个原子扩展到数百万个原子。估计的静态和动态结构因子与所有可用的x射线衍射和非弹性x射线散射实验观测结果具有良好的一致性,而基于嵌入原子法的经验势不能在广泛的热力学条件下给出铁液的统一描述。我们还证明了像扩散系数一样的输运性质表现出强烈的尺寸效应,这需要至少一万多个原子才能给出收敛值。我们的研究结果表明,深度学习技术和分子建模的结合提供了一种在极端条件下真实描述物质的方法。
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引用次数: 0
Mott physics — one of main themes in quantum materials 莫特物理学——量子材料的主要主题之一
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231508
Dong-Lai Feng
The competition and cooperation between the itinerancy behavior and localization behavior of electrons in correlated quantum materials, known as Mott physics, is the physical mechanism behind the diverse states of many quantum materials. This article reviews the manifestation of Mott physics in various quantum materials and establishes it as one of the main themes of quantum materials. Finding and understanding its ever-changing ways of manifestation is one of the central tasks of experimental research on condensed matter physics.Specifically, the filling-control route of Mott transition is illustrated by exampling the surface K-dosed Sr2IrO4, which exhibits d-wave gap, pseudogap behavior in underdoped regime, and phase separation with inhomogeneous electronic state distribution. All of these show strong resemblances to the doped cuprate superconductors, another prototypical filling-control type of Mott transition case. On the other hand, the bandwidth-control route of Mott transition could be found in NiS2–xSex, where its bandwidth continuously decreases with Se concentration decreasing, until it becomes an insulator. In addition, the essence of various ways of doping in iron-based superconductors is to change their bandwidths. The superconductivity shows up at intermediate bandwidth with moderate correlations, and it diminishes when the bandwidth is large and the electron correlations are weak. For heavily electron-doped iron-selenides, there is even a Mott insulator phase with strong correlations.For carbon based materials, the phase transition between the antiferromagnetic insulator and superconducting state of A15 Cs3C60 as the volume of fullerene anions decreases could be understood in terms of a bandwidth-control Mott transition; the insulator-superconductor transition discovered in electrically gated twisted-angle bilayer graphene could be understood as a filling-control Mott transition.For f electron systems, the interplay between itinerancy and localization dominates the heavy fermion behavior and their ground states. The behaviors of the f electrons are demonstrated by using the angle-resolved photoemission data of CeCoIn5, whose f electron band becomes more coherent with temperature decreasing, and the c-f hybridization is thus enhanced and the band mass of conduction band continuously increases. The c-f hybridization behaviors of CeCoIn5, CeIrIn5, and CeRhIn5 are compared with each other, and the differences in hybridization strength put their ground states into different regimes of the Doniach phase diagram. Similarly, the Skutterudites 4f2 Kondo lattice system PrOs4Sb12 and its sibling 4f1 system CeOs4Sb12 also have different ground states due to a slight difference in their c-f hybridization strengths.
电子在相关量子材料中的流动行为和局域行为之间的竞争与合作,被称为莫特物理,是许多量子材料多种状态背后的物理机制。本文综述了莫特物理在各种量子材料中的表现,并将其确立为量子材料的主要主题之一。发现和理解其不断变化的表现方式是凝聚态物理实验研究的中心任务之一。其中,以表面k -剂量Sr<sub>2</sub>IrO<sub>4</sub>为例说明了Mott跃迁的填充控制途径,该跃迁表现出d波隙、低掺杂状态下的赝隙行为和电子态分布不均匀的相分离。所有这些都显示出与掺杂铜超导体的强烈相似性,这是另一种典型的莫特跃迁填充控制类型。另一方面,Mott跃迁的带宽控制路径在NiS<sub>2 -<i>x</i></sub>Se<sub>< /i> i>x</i></sub>中,其带宽随着硒浓度的降低而不断减小,直至成为绝缘子。此外,在铁基超导体中掺杂各种方式的本质是改变其带宽。超导电性在中等带宽出现,相关系数中等;当带宽较大,电子相关系数较弱时,超导性减弱。对于重电子掺杂的铁硒化物,甚至存在具有强相关性的莫特绝缘体相。</sec><sec>对于碳基材料,A15 Cs<sub>3& gt; /sub>C<sub>60</sub>;随着富勒烯阴离子体积的减少,可以用带宽控制莫特跃迁来理解;在电门控扭角双层石墨烯中发现的绝缘体-超导体跃迁可以理解为填充控制的莫特跃迁。对于f电子系统,流动和局域化之间的相互作用主导了重费米子行为及其基态。利用CeCoIn<sub>5</sub>的角分辨光电发射数据证明了f电子的行为,其f电子带随着温度的降低变得更加相干,从而增强了c-f杂化,导带带质量不断增加。CeCoIn<sub>5,</sub>CeIrIn< sub<5</sub>和cerin< sub<5</sub>杂化强度的差异使它们的基态处于不同的Doniach相图区。同样,Skutterudites (Skutterudites) 4f<sup>2</sup>近藤格系PrOs<sub>4</sub>Sb<sub>12<和它的兄弟姐妹4f<sup>1</sup>系统CeOs< sub> 4 & lt; / sub> Sb< sub> 12 & lt; / sub>由于c-f杂化强度的微小差异,它们也具有不同的基态。
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引用次数: 0
Floquet engineering in quantum materials 量子材料中的Floquet工程
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231423
None Changhua Bao, None Benshu Fan, None Peizhe Tang, None Wenhui Duan, None Shuyun Zhou
Floquet engineering based on the strong light-matter interaction is expected to drive quantum materials into nonequilibrium states on an ultrafast timescale, thereby engineering their electronic structure and physical properties, and achieving novel physical effects which has no counterpart in equilibrium states. In recent years, Floquet engineering has attracted a lot of research interest, and there have been numerous rich theoretical predictions. In addition, important experimental research progress has also been made in several representative materials such as topological insulators, graphene, and black phosphorus. Here, we briefly introduce the important theoretical and experimental progress in this field, and prospects the research future, experimental challenges, and development directions.
基于强光-物质相互作用的Floquet工程有望在超快时间尺度上将量子材料驱动到非平衡状态,从而对其电子结构和物理性质进行工程化,并实现在平衡状态下没有对应的新型物理效应。近年来,Floquet工程引起了广泛的研究兴趣,并产生了许多丰富的理论预测。此外,拓扑绝缘体、石墨烯、黑磷等几种具有代表性的材料也取得了重要的实验研究进展。本文简要介绍了该领域的重要理论和实验进展,展望了该领域的研究前景、实验挑战和发展方向。
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引用次数: 0
Thermodynamic phase transition driven by topological excitations and their tensor network approach 拓扑激励驱动的热力学相变及其张量网络方法
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231152
None Song Feng-Feng, None Zhang Guang-Ming
The fundamental concepts of phases and phase transitions constitute the cornerstone of our understanding of the physical universe. The historical development of the phase transition theory from Landau's spontaneous symmetry breaking paradigm to modern topological phase transition theories represents a major milestone in the evolution of numerous scientific disciplines. From the perspective of emergent philosophy, the interplay of topological excitations leads to enriched physical phenomena. One prominent prototype is the Berezinskii-Kosterlitz-Thouless (BKT) phase transition, where unbinding of integer vortices occurs in the absence of spontaneous breaking of continuous U(1) symmetry. Using the state-of-the-art tensor network methods, we express the partition function of the two-dimensional XY-related system in terms of a product of one-dimensional transfer operators. From the singularities of the entanglement entropy of the one-dimensional transfer operator, we accurately determine the complete phase diagram. This method provides new insights into the emergent phenomenon driven by topological excitations, and sheds new light on future studies of 2D systems with continuous symmetries.
相和相变的基本概念构成了我们理解物理宇宙的基石。相变理论从朗道的自发对称性破缺范式发展到现代拓扑相变理论,是众多科学学科发展史上的一个重要里程碑。从涌现哲学的角度来看,拓扑激励的相互作用导致了丰富的物理现象。一个突出的原型是Berezinskii-Kosterlitz-Thouless (BKT)相变,在没有连续的<i>U</i>(1)对称性的自发破缺的情况下,整数涡旋的解结发生。利用最先进的张量网络方法,将二维<i>XY</i>相关系统的配分函数表示为一维传递算子的乘积。从一维传递算子的纠缠熵的奇异性出发,我们精确地确定了完整的相图。该方法为拓扑激励驱动的涌现现象提供了新的见解,并为具有连续对称性的二维系统的未来研究提供了新的思路。
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引用次数: 0
Finite-key analysis of decoy model Semi-quantum key distribution based on four-state protocol 基于四态协议的诱饵模型半量子密钥分配的有限密钥分析
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230849
None Zhan Shao-Kang, None Wang Jin-Dong, None Dong Shuang, None Huang Si-Ying, None Hou Qing-Cheng, None Mo Nai-Da, None Mi Shang, None Xiang Li-Bing, None Zhao Tian-Ming, None Yu Ya-Fei, None Wei Zheng-Jun, None Zhang Zhi-Ming
Semi-quantum key distribution allows a full quantum user Alice and a classical user Bob to share a pair of security keys guaranteed by physical principles. Semi-quantum key distribution is proposed while verifying its robustness. Subsequently, its unconditional security of semi quantum key distribution system is verified theoretically. In 2021, the feasibility of semi quantum key distribution system based on mirror protocol was verified experimentally. However, the feasibility experimental system still uses the laser pulse with strong attenuation. It has been proved in the literature that the semi-quantum key distribution system still encounters the risk of secret key leakage under photon number splitting attack. Therefore, the actual security of key distribution can be further reasonably evaluated by introducing the temptation state and conducting the finite-key analysis in the key distribution process. In this work, for the model of adding one-decoy state only to Alice at the sending based on a four state semi-quantum key distribution system, the length of the security key in the case of finite-key is analyzed by using Hoeffding inequality, and then the formula of the security key rate is obtained. It is found in the numerical simulation that when the sample size is begin{document}$ {10}^{5} $end{document}, the security key rate of begin{document}$ {10}^{-4} $end{document}, which is close to the security key rate of the asymptotic limits, can be obtained in the case of close range, It is very important for the practical application of semi quantum key distribution system.
Semi-quantum key distribution allows a full quantum user Alice and a classical user Bob to share a pair of security keys guaranteed by physical principles. Semi-quantum key distribution is proposed while verifying its robustness. Subsequently, its unconditional security of semi quantum key distribution system is verified theoretically. In 2021, the feasibility of semi quantum key distribution system based on mirror protocol was verified experimentally. However, the feasibility experimental system still uses the laser pulse with strong attenuation. It has been proved in the literature that the semi-quantum key distribution system still encounters the risk of secret key leakage under photon number splitting attack. Therefore, the actual security of key distribution can be further reasonably evaluated by introducing the temptation state and conducting the finite-key analysis in the key distribution process. In this work, for the model of adding one-decoy state only to Alice at the sending based on a four state semi-quantum key distribution system, the length of the security key in the case of finite-key is analyzed by using Hoeffding inequality, and then the formula of the security key rate is obtained. It is found in the numerical simulation that when the sample size is <inline-formula><tex-math id="M3">begin{document}$ {10}^{5} $end{document}</tex-math><alternatives><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="22-20230849_M3.jpg"/><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="22-20230849_M3.png"/></alternatives></inline-formula>, the security key rate of <inline-formula><tex-math id="M4">begin{document}$ {10}^{-4} $end{document}</tex-math><alternatives><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="22-20230849_M4.jpg"/><graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="22-20230849_M4.png"/></alternatives></inline-formula>, which is close to the security key rate of the asymptotic limits, can be obtained in the case of close range, It is very important for the practical application of semi quantum key distribution system.
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引用次数: 0
Effects of radial electric field on ion-temperature gradient driven mode stability 径向电场对离子温度梯度驱动模式稳定性的影响
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20230798
None Chen Ning-Fei, None Wei Guang-Yu, None Qiu Zhi-Yong
To understand the effects of given radial electric field on ion-temperature gradient driven mode (ITG) stability in tokamak plasmas, the eigenmode equation for ITG including the poloidal rotation and density modulation associated with radial electric field is derived using nonlinear gyrokinetic theory. The equation is solved for eigenfrequency, growth rate and parallel mode structure of ITG both in short- and long-wavelength limit with energetic-particle-induced geodesic acoustic mode (EGAM) as a specific form. The eigenmode equation is not only solved analytically, but also solved numerically to validate the analytic solutions. It is found that, radial electric field induced poloidal rotation can significantly stabilize ITG, while the density perturbation of the radial electric field may slightly distort the ITG parallel mode structure, but has little effect on ITG stability. The result is consistent with common picture of turbulence suppression by poloidal shear flow. The general model is also applicable to the investigation of the indirect interaction of ITG and energetic particle driven Alfvén instabilities via zonal structures generation, by means of introducing poloidal rotation and density modulation associated with zonal structures spontaneously excited by Alfvén instabilities. The indirect channel is supplement to the direct interaction of microturbulences and energetic particle driven Alfvén instabilities.
为了理解给定的径向电场对托卡马克等离子体中离子温度梯度驱动模式(ITG)稳定性的影响,利用非线性陀螺动力学理论推导了包含极向旋转和与径向电场相关的密度调制的ITG本征模方程。以能量粒子诱导测地线声模式(EGAM)为具体形式,求解了ITG在短波长极限下的本征频率、生长速率和平行模式结构。本文不仅对特征模态方程进行了解析求解,而且对解析解进行了数值求解,验证了解析解的正确性。研究发现,径向电场诱导的极向旋转对ITG有明显的稳定作用,而径向电场的密度扰动对ITG平行模结构有轻微的畸变,但对ITG稳定性影响不大。结果与一般的极向剪切流抑制湍流的情况一致。一般模型也适用于通过产生纬向结构来研究ITG和高能粒子驱动的alfv录影带不稳定性的间接相互作用,方法是引入由alfv录影带不稳定性自发激发的与纬向结构相关的极向旋转和密度调制。间接通道是对微湍流和高能粒子驱动的alfv不稳定性直接相互作用的补充。
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引用次数: 0
Modulation of photocurrent response in WS<sub>2</sub> optoelectronic devices with Li intercalation WS&lt;sub&gt;2&lt;/sub&gt的光电流响应调制具有Li嵌入的光电器件
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231000
None Song Yu-Xin, None Li Yu-Qi, None Wang Ling-Han, None Zhang Xiao-Lan, None Wang Chong, None Wang Qin-Sheng
Transition metal dichalcogenides have emerged as a prominent class of two-dimensional layered materials, capturing sustained attention from researchers due to their unique structures and properties. These distinctive characteristics render transition metal dichalcogenides highly versatile in numerous fields, including optoelectronics, nanoelectronics, energy storage devices, and electrocatalysis. In particular, the ability to modulate the doping characteristics of these materials plays a crucial role in improving the photoelectric response performance of devices, making it imperative to investigate and understand such effects.
In recent years, the electrochemical ion intercalation technique has emerged as a novel approach for precise doping control of two-dimensional materials. Building upon this advancement, this paper aims to demonstrate the effective doping control of transition metal dichalcogenides devices by utilizing the electrochemical ion intercalation method specifically on thick WS2 layers. The results reveal a remarkable enhancement in electrical conductivity, approximately 200 times higher than the original value, alongside the achievement of efficient and reversible control over the photoelectric response performance through the manipulation of gate voltage. One of the key findings of this paper is the successful demonstration of the reversible cyclic control of the photoelectric response in WS2 devices through ion intercalation, regulated by the gate voltage. This dynamic control mechanism showcases the potential for finely tuning and tailoring the performance of photoelectric devices made from two-dimensional materials. The ability to achieve reversible control is especially significant as it allows for a versatile range of applications, enabling devices to be adjusted according to specific requirements and operating conditions.
The implications of this work extend beyond the immediate findings and present a foundation for future investigations into response control of photoelectric devices constructed using two-dimensional materials through the utilization of the ion intercalation method. By establishing the feasibility and efficacy of this technique in achieving controlled doping and precise modulation of photoelectric response, researchers can explore its potential applications in various technological domains. Furthermore, this research serves as a stepping stone for the development of advanced doping strategies, enabling the design and fabrication of high-performance devices with enhanced functionalities.
In summary, this work showcases the significance of doping control in transition metal dichalcogenide devices and demonstrates the potential of the electrochemical ion intercalation method for achieving precise modulation of their photoelectric response performance. The observed enhancements in electrical conductivity and the ability to reversibly control the photoelectric response highlight th
过渡金属二硫族化合物已成为一类突出的二维层状材料,由于其独特的结构和性质,引起了研究人员的持续关注。这些独特的特性使得过渡金属二硫族化合物在光电子学、纳米电子学、储能器件和电催化等许多领域具有高度的通用性。特别是,调节这些材料的掺杂特性的能力对于提高器件的光电响应性能起着至关重要的作用,因此研究和理解这种效应势在必行。近年来,电化学离子插层技术已经成为一种精确掺杂控制二维材料的新方法。在此基础上,本文旨在证明利用电化学离子插入方法在厚WS<sub>2</sub>层。结果表明,电导率显著提高,大约是原始值的200倍,同时通过操纵栅极电压实现了对光电响应性能的有效和可逆控制。本文的关键发现之一是成功地演示了WS<sub>2</sub>器件通过离子插入,由栅电压调节。这种动态控制机制展示了精细调谐和定制由二维材料制成的光电器件性能的潜力。实现可逆控制的能力尤其重要,因为它允许广泛的应用范围,使设备能够根据特定的要求和操作条件进行调整。这项工作的意义超出了直接的发现,并为未来研究利用离子嵌入方法使用二维材料构建的光电器件的响应控制奠定了基础。通过确定该技术在实现可控掺杂和精确调制光电响应方面的可行性和有效性,研究人员可以探索其在各个技术领域的潜在应用。此外,本研究为开发先进的掺杂策略奠定了基础,使设计和制造具有增强功能的高性能器件成为可能。总之,本工作展示了掺杂控制在过渡金属二硫化物器件中的重要性,并展示了电化学离子插入方法实现其光电响应性能精确调制的潜力。观察到的电导率的增强和可逆控制光电响应的能力突出了该技术的良好前景。最终,这项工作为二维材料领域的未来发展铺平了道路,并为改进功能和性能的光电器件的设计和优化开辟了新的途径。
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引用次数: 0
Suppression of scattering clutter in underwater LiDAR based on CEEMDAN-wavelet threshold denoising algorithm 基于ceemdan -小波阈值去噪算法的水下激光雷达散射杂波抑制
Pub Date : 2023-01-01 DOI: 10.7498/aps.72.20231035
None Fan Chao-Yang, None Li Chao-Feng, None Yang Su-Hui, None Liu Xin-Yu, None Liao Ying-Qi
The echo of underwater lidar often contains a significant quantity of scattering clutters. In order to effectively suppress this scattering clutter and improve the ranging accuracy of underwater lidar, a novel denoising method based on complete ensemble empirical mode decomposition with adaptive noise (CEEMDAN) and wavelet threshold denoising is proposed.The CEEMDAN-wavelet threshold denoising algorithm uses the correlation coefficient to select intrinsic mode function (IMF) components obtained from the CEEMDAN decomposition. The IMFs, which are more closely related to the original signal, are selected. Then, the wavelet thresholding denoising algorithm is applied to each of the selected IMFs to perform additional denoising. For each IMF component, specific threshold values are calculated based on their frequency and amplitude characteristics. Subsequently, the wavelet coefficients of the IMF components are processed by using these threshold values. Finally, the denoised IMF components are combined and reconstructed to obtain the final denoised signal. Applying the wavelet threshold denoising algorithm to IMF components can effectively remove noise components that cannot be removed by traditional CEEMDAN partial reconstruction methods. By using the threshold value calculated based on the characteristics of each IMF component, the wavelet thresholding denoising process is improved in comparison with directly using a single threshold value. This approach enhances the algorithm’s adaptability and enables more effective removal of noise from the signal.We apply the proposed method to underwater ranging experiments. A 532 nm intensity-modulated continuous wave laser is used as a light source. Ranging is performed for a target in water with varying attenuation coefficients. A white polyvinyl chloride (PVC) reflector is used as a target. When the correlation extreme value is directly used to determine the delay at a distance of 3.75 attenuation length, it results in a ranging error of 19.2 cm. However, after applying the proposed method, the ranging error is reduced to 6.2 cm, thus effectively improving the ranging accuracy. These results demonstrate that the method has a significant denoising effect in underwater lidar system.
水下激光雷达的回波中往往含有大量的散射杂波。为了有效抑制这种散射杂波,提高水下激光雷达的测距精度,提出了一种基于自适应噪声的全系综经验模态分解(CEEMDAN)和小波阈值去噪的去噪方法。</sec><sec> CEEMDAN-小波阈值去噪算法,该算法利用相关系数选择由CEEMDAN分解得到的本征模态函数(IMF)分量。选择与原始信号关系更密切的imf。然后,将小波阈值去噪算法应用于每个选定的imf进行附加去噪。对于每个IMF分量,根据其频率和幅度特性计算特定的阈值。然后,利用这些阈值对IMF分量的小波系数进行处理。最后,对去噪后的IMF分量进行组合重构,得到去噪后的最终信号。对IMF分量应用小波阈值去噪算法,可以有效去除传统CEEMDAN部分重构方法无法去除的噪声分量。利用基于IMF各分量特征计算的阈值,与直接使用单一阈值相比,改进了小波阈值去噪过程。该方法增强了算法的适应性,能够更有效地去除信号中的噪声。我们将该方法应用于水下测距实验。采用532nm调强连续波激光器作为光源。对不同衰减系数的水中目标进行测距。使用白色聚氯乙烯(PVC)反射器作为目标。当直接使用相关极值确定3.75衰减长度距离上的时延时,测距误差为19.2 cm。应用该方法后,测距误差降至6.2 cm,有效提高了测距精度。结果表明,该方法在水下激光雷达系统中具有显著的去噪效果。
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Chinese Physics
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