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Graphene oxide, it’s surface functionalisation, preparation and properties of polymer-based composites: a review 氧化石墨烯及其表面功能化、聚合物基复合材料的制备及性能综述
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-29 DOI: 10.1080/09276440.2023.2229594
Ankita Subhrasmita Gadtya, Debajani Tripathy, Lipeeka Rout, S. Moharana
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引用次数: 0
Impact of hemp woody core surface chemical modification on wettability of epoxyurethane composites 大麻木芯表面化学改性对环氧聚氨酯复合材料润湿性的影响
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-26 DOI: 10.1080/09276440.2023.2229585
T. Samoilenko, L. Yashchenko, Nataliia Yarova, O. Brovko
ABSTRACT Hemp woody core (HWC) that is a by-product of hemp industry was subjected to pre-treatment with alkali (mercerisation) and further functionalisation with epoxidised soybean oil (ESO) or (3-aminopropyl)triethoxysilane (APS). Mercerisation resulted in more developed surface area and rearrangement of fibrils into denser packing. FTIR spectroscopy analysis revealed the presence of hydrogen bonds of HWC with modifier in case of ESO application as well as hydrogen and Si-O-C covalent bonds in case of APS application. Two types of Si-containing epoxyurethanes were filled with 60% of HWC with different surface modification: the first polymer contained diglycidyl ether of bisphenol-A (DGEBA), while the second one contained ESO as an epoxy component. The investigation of the surface properties of composites found that the ones based on ESO epoxyurethane were more hydrophobic than their respective counterparts. Hydrophilicity was reduced by functionalisation of HWC providing a contact angle augment from 54°for DGEBA-containing sample with raw HWC to 86° for the one with oil modified HWC. The results of water uptake test showed that regardless of the matrix the composites reinforced with functionalised HWC exhibited about 40% less gain in weight at the saturation level than their analogues reinforced with untreated or alkali treated HWC. Graphical abstract
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引用次数: 0
Nanoclay/organic filler-reinforced polymeric hybrid composites as promising materials for building, automotive, and construction applications- a state-of-the-art review 纳米粘土/有机填料增强聚合物杂化复合材料作为建筑、汽车和建筑应用的有前途的材料——最新进展综述
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-18 DOI: 10.1080/09276440.2023.2220217
Lucky Ogheneakpobo Ejeta
ABSTRACT Several research articles in the field of nanocomposite have revealed that organic fillers can be used as reinforcing agents for plastic materials in hybrid material production. Advancement in multifunctional materials is anticipated to grow with the advent of lightweight, low-cost, and sustainable materials with improved mechanical, fire retardancy, water resistance, and higher barrier properties. As reported in the literature, these performance properties could be obtained by reinforcing nanoclay/organic filler in polymeric matrices. In this report, the pretreatment techniques for overcoming the challenges of hybrid composite production are discussed in detail. The bonding mechanisms between the nanoclay and plastic materials are explained. The study gives an overview of the recent progress on multifunctional hybrid materials made using nanoclay/organic particulate fillers as reinforcements for polymer matrices intended for use in the automotive, building, and construction industries. GRAPHICAL ABSTRACT
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引用次数: 1
Improved amine functionalization of carbon fiber surfaces by O2 plasma activation treatment 氧等离子体活化处理改善碳纤维表面胺功能化
4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-09 DOI: 10.1080/09276440.2023.2223407
Zefeng Yang, Xuefei Huang, Jie Li, Bo Tang, Guizao Huang, Wenfu Wei, Guangning Wu
Pretreatment using O2 plasma is a commonly used method today to increase the surface activity of CFs and enable more functional groups to be grafted onto them. Although the oxidation treatment of the CF surface is considered a key procedure for further grafting with functional groups, few researchers have investigated how the oxidation treatment influences the grafting processes. In this paper, the effects of the degree of oxidation on the grafting of amino functional groups onto CFs were experimentally investigated. The experiment showed that the oxidation process developed in steps including initial oxidation, saturation oxidation, and peroxidation. The results demonstrated that the degree of oxidation was positively correlated with the grafting efficiency within a certain range. Furthermore, the groups (unsaturated C, C-OH, and O=C-OH) produced after oxidation determined the results of grafting with amino (C-N, C-NH2, and O=C-NH2) groups. When the O2 plasma treatment time was increased from 0 min to 3 min, the IFSS of CF@HA increased by 1.07 times and the flexural strength of CFRP increased by 1.26 times. This work proves that the ammonia grafting of CF can be controlled by adjusting its earlier oxidation process.
利用氧等离子体进行预处理是目前常用的一种方法,以提高碳纤维的表面活性,并使其能够接枝更多的官能团。虽然CF表面的氧化处理被认为是进一步接枝官能团的关键步骤,但很少有研究者研究氧化处理如何影响接枝过程。本文通过实验研究了氧化程度对氨基官能团接枝的影响。实验表明,氧化过程分为初始氧化、饱和氧化和过氧化三个阶段。结果表明,在一定范围内,氧化程度与接枝效率呈正相关。此外,氧化后产生的基团(不饱和C、C- oh和O=C- oh)决定了与氨基(C- n、C- nh2和O=C- nh2)基团接枝的结果。当O2等离子体处理时间从0 min增加到3 min时,CF@HA的IFSS提高了1.07倍,CFRP的抗弯强度提高了1.26倍。本工作证明了CF的氨接枝可以通过调整其早期氧化过程来控制。
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引用次数: 0
Enhanced interfacial interaction, mechanical properties and thermal stability of basalt fiber/epoxy composites with multi-scale reinforcements 多尺度增强玄武岩纤维/环氧复合材料的界面相互作用、力学性能和热稳定性
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-02 DOI: 10.1080/09276440.2023.2220500
Dongdong Xiang, Tao Shui, Hongjuan Qiao, Wei Tan, E. Harkin-jones, Jie Zhang, Peizhi Ji, Ping Wang, Bin Wang, Chunxia Zhao, Hui Li, Yuan-Bo Wu, Yuntao Li
ABSTRACT In this work, epoxy (EP) resin composites with multi-scale reinforcements were prepared by hand lay-up and hot-pressing. The epoxy was reinforced with basalt fibers (BF) modified with a silane coupling agent (KH560). Carboxylated multi-walled carbon nanotubes (CNTs) were also grafted onto the surface of the modified BF using an impregnation method to achieve BF/CNTs multi-scale reinforcement. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) showed that KH560 was successfully grafted onto the BF surface. Scanning electron microscopy (SEM), indicated a better resin adhesion on the BF and thus a stronger interfacial interaction in the BF/CNTs-reinforced composite. It was observed that the mass fraction of KH560 was a significant parameter in achieving desirable CNT immobilization and mechanical properties of the composites. At an optimal mass fraction of KH560 (5%), the tensile, flexural, and interlaminar shear strength (ILSS) of the modified composite (BF-5%KH560-CNT/EP) increased by 12.5%, 20.9%, and 25.5% respectively compared with the BF-washed/EP composite due to more efficient load transfer. In addition, compared with BF-washed/EP, the decomposition onset temperature of BF-5%KH560-CNT/EP increased from 387°C to 396°C, the maximum decomposition rate temperature increased from 400°C to 408°C, and the residual weight increased by 5.8%. GRAPHICAL ABSTRACT
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引用次数: 3
Statement of Retraction: Simultaneously enhanced interfacial, mechanical properties and flame retardancy of high-density polyethylene-based composites using Mg,Al-containing melamine polyphosphate-grafted wood fibers 用含镁、铝的三聚氰胺聚磷酸盐接枝木纤维同时增强了高密度聚乙烯基复合材料的界面、力学性能和阻燃性
4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-01 DOI: 10.1080/09276440.2023.2217570
This article refers to:RETRACTED ARTICLE: Simultaneously enhanced interfacial, mechanical properties and flame retardancy of high-density polyethylene-based composites using Mg,Al-containing melamine polyphosphate-grafted wood fibers
含镁、铝三聚氰胺聚磷酸盐接枝木纤维同时增强高密度聚乙烯基复合材料的界面性能、力学性能和阻燃性能
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引用次数: 0
Improving interface interactions in PLA/HAP composites with hydroxyapatite surface modification 羟基磷灰石表面改性改善PLA/HAP复合材料界面相互作用
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-23 DOI: 10.1080/09276440.2023.2210884
Eylül Odabaş, E. Akarsu
ABSTRACT PLA/HAP composites have attracted significant attention in material science, especially in the field of biomaterials. However, these composites have suffered from unfavorable interface interactions between PLA and HAP interfaces, which limits the applications . In this study, we aimed to improve the interface interactions of PLA/HAP composite by modifying the HAP surface. For this purpose, HAP particles were functionalized with three different silane modifying agents, including (3-Aminopropyl)trimethoxysilane (AMMO), (3-glycidyloxypropyl)trimethoxysilane (GLYMO) and (3-triethoxysilyl)propylsuccinic anhydride (GF-20). The obtained modified HAP (m-HAP) were used to prepare PLA/m-HAP. Interface interactions of composites were characterized by Fourier transform infrared spectrophotometer (FT-IR) and differential scanning calorimetry (DSC). In addition, Vickers hardness tests were performed to reveal the effect of silane modifying agents on hardness before and after the in vitro degradation test. GRAPHICAL ABSTRACT
PLA/HAP复合材料在材料科学领域,特别是生物材料领域受到了广泛的关注。然而,这些复合材料在PLA和HAP界面之间存在不利的界面相互作用,这限制了它们的应用。在本研究中,我们旨在通过修饰HAP表面来改善PLA/HAP复合材料的界面相互作用。为此,用三种不同的硅烷改性剂(3-氨基丙基)三甲氧基硅烷(AMMO)、(3-甘油三酯氧基)三甲氧基硅烷(GLYMO)和(3-三乙基氧基)丙基丁二酸酐(GF-20)对HAP颗粒进行了功能化。得到的改性HAP (m-HAP)用于制备PLA/m-HAP。采用傅里叶变换红外分光光度计(FT-IR)和差示扫描量热仪(DSC)对复合材料的界面相互作用进行了表征。此外,通过维氏硬度测试来揭示硅烷改性剂对体外降解试验前后硬度的影响。图形抽象
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引用次数: 1
Molecular dynamics study on the transport of water molecules and chloride ions in graphene oxide-modified cement composites 水分子和氯离子在氧化石墨烯改性水泥复合材料中传输的分子动力学研究
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-23 DOI: 10.1080/09276440.2023.2215627
Yu Chen, W. Zhang, Linlong Zhen, Guohao Li
ABSTRACT The ability of composite cement materials to resist erosion by chloride ions is a critical factor in evaluating their dependability. This study aims to examine the influence of graphene oxide on the transportation of water molecules and chloride ions in modified cement composites. Molecular dynamics analysis suggests that graphene oxide can effectively bond to the substrate of hydrated calcium silicate gel pores, which forms a stronger confined fluid zone under the action of electrostatic interactions and van der Waals forces. Graphene oxide has negatively charged oxygen functional groups on its surface, and within a certain size range, it becomes more effective at restricting the penetration of water molecules and chloride ions. In addition, chloride solution immersion experiments were performed on graphene oxide modified cement mortar. The results demonstrated that a small quantity of graphene oxide can significantly improve the resistance of modified cement mortar to chloride ion erosion, whereas excessive amounts are detrimental, which aligns with the simulation results. It is hoped that this study will provide valuable insights into the use of graphene oxide nanoparticles in the corrosion protection of cement composites. GRAPHICAL ABSTRACT
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引用次数: 1
Fabrication, characterization and performance analysis of different Ag/PVA nanocomposite membranes for debenzenation of model pyrolysis gasoline using pervaporation 不同Ag/PVA纳米复合膜的制备、表征及性能分析
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-19 DOI: 10.1080/09276440.2023.2212995
Monalisha Samanta, Debarati Mitra
ABSTRACT According to EURO IV and EURO V, benzene in gasoline should not exceed 1 volume%, to prevent environmental pollution and health risks; hence benzene must be removed from pyrolysis gasoline (octane booster), before blending with gasoline. Polyvinyl alcohol (PVA) based membranes are quite effective for pervaporative separation of hydrocarbon mixtures. The main objective of this work is to fabricate insitu Ag/PVA nanocomposite membranes, using simple solution casting approach, for pervaporative separation of benzene from model pyrolysis gasoline (mixture of benzene/1-octene). Debenzenation of pyrolysis gasoline using PVA-based polymeric membranes was not reported by earlier researchers. The impact of incorporation of nano-Ag in the PVA matrix, on the pervaporative performance of the PVA membrane towards benzene, based on the swelling coefficient, fractional free volume, total flux, separation factor and activation energy, is the novelty of this study. Scanning Electron Microscopy, Transmission Electron Microscopy, mechanical strength, UV-Vis spectroscopy, Fourier Transform Infrared Spectroscopy were used to characterize all the fabricated membranes. The most suitable composite membrane for the intended purpose was identified. The maximum flux and highest separation factor of the said membrane are 4.05 kg/m2/h and 5.51 respectively at 343K operating temperature and 1 mm Hg downstream pressure. GRAPHICAL ABSTRACT
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引用次数: 0
Study on wettability behavior and wear resistance mechanism of ZTA-ceramic-reinforced HCCI composites zta -陶瓷增强HCCI复合材料的润湿行为及耐磨性机理研究
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-17 DOI: 10.1080/09276440.2023.2210883
Quan Gao, Zhenlin Lv, L. Jia, Chaoyang Zhang
ABSTRACT Zirconia-toughened alumina (ZTA)-reinforced high-chromium cast iron (HCCI) composite materials were prepared using pressureless sintering method, and the effects of the type (titanium (Ti), nickel (Ni)) and content (10%, 12%) of active additives on the wettability and wear resistance were systematically studied. Result showed that the additive can enhance the wettability capacity between ZTA/HCCI composites interface, especially Ti, which reacted the chemical reaction and formed a transition layer in metallurgical combination. When the content of the Ti additive was 10%, the Brinell hardness (HB) of ZTA/HCCI composite was 573.1 N/mm2 at room temperature, and the wear-resistant properties were more than 3.8 times of pure HCCI. After thermal treatment, the HB and wear resistance of 10% Ti-ZTA/HCCI composites increased significantly which could reach 629.8 N/mm2 and were more than 4.3 times of the pure HCCI, respectively. Graphical abstract
摘要:采用无压烧结法制备了氧化锆增韧氧化铝(ZTA)增强高铬铸铁(HCCI)复合材料,系统研究了活性添加剂种类(钛(Ti)、镍(Ni))和含量(10%、12%)对材料润湿性和耐磨性的影响。结果表明,添加剂能增强ZTA/HCCI复合材料界面间的润湿性,尤其是Ti,在冶金结合中发生化学反应并形成过渡层。当Ti添加量为10%时,室温下ZTA/HCCI复合材料的布氏硬度(HB)为573.1 N/mm2,耐磨性能是纯HCCI的3.8倍以上。经过热处理后,10% Ti-ZTA/HCCI复合材料的HB和耐磨性显著提高,分别达到629.8 N/mm2,是纯HCCI的4.3倍以上。图形抽象
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引用次数: 0
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Composite Interfaces
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