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Effect of HSO3 − and alternating current on corrosion behaviour and mechanism of CoCrFeNi HEA in a simulated marine environment HSO3−和交流电对CoCrFeNi HEA在模拟海洋环境中腐蚀行为和机理的影响
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-18 DOI: 10.1080/1478422X.2023.2190443
Chenglong Zhang, M. Zhu, Kexin Xu, Yongfeng Yuan, Shao-yi Guo, G. Wei
ABSTRACT The corrosion behavior and mechanism of CoCrFeNi HEA under AC application were systematically studied in 3.5 wt.% NaCl solution containing different concentrations of NaHSO3. The results showed that the existence of HSO3 − increased the defect density within the passivation film on the surface of the HEA. With the increase of HSO3 − concentration, the passivation zone became narrow, Ep shifted negatively, and ip increased, which indicated that the corrosion resistance of the HEA was weakened. When the HSO3 − concentration increased to 0.1 M, a clear transition zone appeared, indicating that the increase in concentration reduced the passivity of the HEA, and its corrosion behavior changed from the typical passivation characteristic to the activation state with increasing iAC. The imposed AC promoted the nucleation of metastable pitting, which was indicated by a remarkable increase in the average pitting number density (Navg) from 5 to 17 mm−2 with the enhancement of iAC. GRAPHICAL ABSTRACT
摘要系统地研究了CoCrFeNi HEA在含有不同浓度NaHSO3的3.5wt.%NaCl溶液中的交流腐蚀行为和机理。结果表明,HSO3−的存在增加了HEA表面钝化膜内的缺陷密度。随着HSO3−浓度的增加,钝化区变窄,Ep负移,ip增加,表明HEA的耐腐蚀性减弱。当HSO3−浓度增加到0.1M时,出现了一个明显的过渡区,表明浓度的增加降低了HEA的钝化性,并且随着iAC的增加,其腐蚀行为从典型的钝化特性转变为活化状态。外加AC促进了亚稳点蚀的形核,这表明随着iAC的增强,平均点蚀数密度(Navg)从5 mm−2显著增加到17 mm−2。图形摘要
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引用次数: 0
Localised corrosion failure of an L245N pipeline in a CO2–O2–Cl− environment L245N管道在CO2–O2–Cl−环境中的局部腐蚀失效
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-16 DOI: 10.1080/1478422X.2023.2188637
Jihui Leng, Zhiyuan Tian, Kexi Liao, T. He, Xin Liu, Guoxi He, Xin Tang, Guoqiang Xia
ABSTRACT Multicomponent thermal fluid flooding has become a widely used and very effective heavy-oil recovery technology, but the harsh CO2–O2–Cl− environment can lead to serious corrosion perforation failure of the pipeline. Therefore, the influence of O2 content and main controlling factors on corrosion perforation were investigated through a weight-loss experiment, corrosion defect test, characterization and grey correlation method. The results showed that, with the increase in O2 content, the general corrosion rate and localized corrosion rate increased. The uneven protection performance of the product after the addition of O2 was found to be the key cause of localized corrosion. In addition, the synergistic effect of O2–Cl− promoted the lateral and longitudinal expansion of pits. The results of the grey correlation showed that the temperature (30–120 °C) had a greater impact on localized corrosion compared with the content of O2 (0–0.045 MPa) and Cl− (0–16,000 mg/L).
多组分热液驱已成为一种应用广泛且非常有效的稠油采油技术,但恶劣的CO2-O2-Cl -环境会导致管道严重的腐蚀射孔失效。因此,通过失重实验、腐蚀缺陷测试、表征和灰色关联等方法,研究了O2含量及主要控制因素对腐蚀穿孔的影响。结果表明:随着氧含量的增加,总腐蚀速率和局部腐蚀速率均增大;发现产品加入O2后保护性能不均匀是局部腐蚀的关键原因。此外,O2-Cl−的协同作用促进了坑的横向和纵向扩展。灰色关联结果表明,相对于O2 (0 ~ 0.045 MPa)和Cl−(0 ~ 16000 mg/L)的含量,温度(30 ~ 120℃)对局部腐蚀的影响更大。
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引用次数: 2
A new approach for quantification of corrosion losses on steels exposed to an artificial seawater environment 一种量化钢在人工海水环境中腐蚀损失的新方法
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-13 DOI: 10.1080/1478422X.2023.2185987
M. Abbas, N. Simms, S. H. Rizvi
ABSTRACT The selection methodology for thickness loss measurement is very important to determine the extent of corrosion damage, as well as in formulation of corrosion prediction models and inspection/maintenance plans for offshore structures. This paper introduces a more accurate corrosion measurement technique, based on the pre-exposure dimensional metrology and post-exposure optical microscopy/image analysis on the cross-sections of steel samples. During this corrosion test, the surface grinded and uncoated steel samples were submerged vertically in an artificial seawater solution, for a duration of up to a maximum of 365 days. The corrosion damage experienced on the steel samples means that the dimensional metrology can be more accurate, and useful approach to measure both uniform and localised corrosion losses simultaneously than the conventional average mass loss method.
摘要厚度损失测量的选择方法对于确定腐蚀损伤程度以及制定海洋结构物的腐蚀预测模型和检查/维护计划非常重要。本文介绍了一种更精确的腐蚀测量技术,该技术基于钢样品横截面的曝光前尺寸计量和曝光后光学显微镜/图像分析。在该腐蚀试验过程中,将表面研磨和未涂覆的钢样品垂直浸入人工海水溶液中,最长持续365天。钢样品上经历的腐蚀损伤意味着尺寸计量可以比传统的平均质量损失方法更准确、更有用地同时测量均匀和局部腐蚀损失。
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引用次数: 0
Corrosion-resistant coating on AZ91D magnesium alloy based on one-step hydrothermal 一步水热法制备AZ91D镁合金防腐涂层
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-09 DOI: 10.1080/1478422X.2023.2185991
Min Jiang, Shimeng Li, Jiyuan Zhu
ABSTRACT Magnesium alloys are widely used due to their excellent properties, but their corrosion resistance is limited by their high chemical activity. This paper proposes a one-step hydrothermal method with a relatively short reaction time and simple experimental steps for synthesising magnesium alloy coatings with good corrosion protection properties. The surface morphology, chemical composition and corrosion resistance of the in situ generated coatings were investigated using measurements such as field emission scanning electron microscopy (SEM), adhesion cross-cut tape (ACCT) test, X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), electrochemistry and immersion test, the results revealed that the corrosion current density (Icorr) of the coatings decreased by approximately four orders of magnitude and had good corrosion resistance.
镁合金因其优异的性能而被广泛应用,但其高化学活性限制了其耐腐蚀性。本文提出了一种反应时间相对较短、实验步骤简单的一步水热法合成具有良好防腐性能的镁合金涂层。使用场发射扫描电子显微镜(SEM)、粘附横切带(ACCT)测试、X射线衍射(XRD)、X射线光电子能谱(XPS)、电化学和浸渍测试等测量手段,研究了原位生成涂层的表面形态、化学成分和耐腐蚀性,结果表明,涂层的腐蚀电流密度(Icorr)降低了大约四个数量级,并且具有良好的耐腐蚀性。
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引用次数: 0
Corrosion monitoring at the interface using sensors and advanced sensing materials: methods, challenges and opportunities 使用传感器和先进传感材料进行界面腐蚀监测:方法、挑战和机遇
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-09 DOI: 10.1080/1478422X.2023.2180195
Vinooth Rajendran, Anil Prathuru, C. Fernandez, N. Faisal
ABSTRACT Detecting and monitoring of corrosion is one of the major challenges in insulated metallic structures or structures with one or more than one interface. This review paper aims to consolidate scattered literature on laboratory system-based corrosion measurement at the interface region. There are range of sensor-based detection and monitoring methods (active, passive) for corrosion rate analysis, including those which measures a surrogate, i.e. quantifying moisture, temperature, pH and qualify other changes or degradations at the interface. With the emergence of a novel application of advanced sensing methods, this review also presents the possibility of the application of hybrid and multifunctional sensing methods at the interfaces, aimed at advancing corrosion monitoring at the interface region. Key research areas of development relating to the application of combination of other materials (e.g. metal oxides, carbon nanotubes, metal nanowires, piezoelectric) as potential sensors and their impact on existing practices in the field are identified. GRAPHICAL ABSTRACT
摘要腐蚀检测和监测是绝缘金属结构或具有一个或多个界面的结构面临的主要挑战之一。这篇综述论文旨在巩固分散的关于基于实验室系统的界面区域腐蚀测量的文献。腐蚀速率分析有一系列基于传感器的检测和监测方法(主动、被动),包括测量替代物的方法,即量化水分、温度、pH值,并确定界面处的其他变化或降解。随着先进传感方法的新应用,本文还提出了在界面应用混合和多功能传感方法的可能性,旨在推进界面区域的腐蚀监测。确定了与其他材料(如金属氧化物、碳纳米管、金属纳米线、压电)组合作为潜在传感器的应用及其对该领域现有实践的影响有关的关键研究发展领域。图形摘要
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引用次数: 0
Effect of grain structures and precipitation characteristics on the corrosion behaviour of Sc-containing Al-Cu-Li alloy 晶粒组织和析出特征对含sc Al-Cu-Li合金腐蚀行为的影响
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-05 DOI: 10.1080/1478422X.2023.2184521
Yuankang Xie, Sheng-dan Liu, Yun-lai Deng, Xiao-bin Guo
ABSTRACT The intergranular corrosion behaviour of Al-Cu-Li-Sc alloy with different microstructures was systematically investigated in this work. The SKPFM characterisation revealed that the AlCuSc (W) phase has more negative potential compared to the Al matrix and undergoes dealloying in the intergranular corrosion solution. The dealloying rate of the W phase in the corrosive solution is relatively slow, which does not lead to serious pitting characteristics. As denser anodic T1 precipitates formed on low-angle grain boundaries of the partially recrystallised sample will reduce the precipitates on the sub-grain interior, resulting in the low-angle boundary being prone to preferential corrosion and reduced intergranular corrosion resistance. The complete recrystallised sample exhibits corrosion of grain interior and propagates along corroded bands parallel to {111}Al habit planes of T1 precipitates, reducing the expansion rate of corrosion along the grain boundaries. Restraining the IGC along the low-angle grain boundary and inducing crystallographic corrosion to improve the intergranular corrosion resistance.
本文系统地研究了不同组织的Al-Cu-Li-Sc合金的晶间腐蚀行为。SKPFM表征表明,与Al基体相比,AlCuSc (W)相具有更多的负电位,并且在晶间腐蚀溶液中发生了合金化。腐蚀溶液中W相的脱合金速度相对较慢,不会产生严重的点蚀特征。部分再结晶试样低角晶界上形成的较致密的阳极T1析出相会减少亚晶内部的析出相,导致低角晶界容易发生优先腐蚀,降低晶间耐蚀性。完全再结晶的样品显示出晶粒内部的腐蚀,并沿着与T1析出相{111}Al习惯面平行的腐蚀带扩展,降低了沿晶界的腐蚀扩展速率。抑制沿低角晶界的IGC,诱导晶相腐蚀,提高晶间耐蚀性。
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引用次数: 0
Hydrogen embrittlement of high-strength steels in thiosulphate solutions 高强度钢在硫硫酸盐溶液中的氢脆
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-02 DOI: 10.1080/1478422X.2023.2183551
J. S. Sa, J. C. Rocha, A. Bueno, J. Gomes
ABSTRACT The susceptibility to hydrogen embrittlement of supermartensitic stainless steel (S13Cr), martensitic-ferritic stainless steel (17Cr), carbon steel (P110) and austenitic-ferritic stainless steels (2205 and 2507) was evaluated by slow strain rate tests using a modified NACE TM-0177 solution, with 10–3M NaS2O3 substituting the saturated H2S standard solution. Tests were conducted at 25°C, pH 2.7 and under galvanostatic polarisation with a cathodic charging of 10 mA/cm2. S13Cr, 17Cr, P110 and 2507 steels were susceptible to hydrogen embrittlement inthiosulphate, with S13Cr and 17Cr being the most sensitive to this mechanism, while 2205 showed no sign of ductility loss. This harmful effect was attributed to the hydrogen sulphide generated from thiosulphate.
采用改良的NACE TM-0177溶液,用10-3M NaS2O3代替饱和H2S标准溶液,通过慢应变速率试验评价了超马氏体不锈钢(S13Cr)、马氏体-铁素体不锈钢(17Cr)、碳钢(P110)和奥氏体-铁素体不锈钢(2205和2507)对氢脆的敏感性。测试在25°C, pH 2.7和恒流极化下进行,阴极充电为10 mA/cm2。S13Cr、17Cr、P110和2507钢易受硫代硫酸盐氢脆的影响,其中S13Cr和17Cr对这一机制最敏感,而2205钢没有延性损失的迹象。这种有害影响归因于硫代硫酸盐产生的硫化氢。
{"title":"Hydrogen embrittlement of high-strength steels in thiosulphate solutions","authors":"J. S. Sa, J. C. Rocha, A. Bueno, J. Gomes","doi":"10.1080/1478422X.2023.2183551","DOIUrl":"https://doi.org/10.1080/1478422X.2023.2183551","url":null,"abstract":"ABSTRACT The susceptibility to hydrogen embrittlement of supermartensitic stainless steel (S13Cr), martensitic-ferritic stainless steel (17Cr), carbon steel (P110) and austenitic-ferritic stainless steels (2205 and 2507) was evaluated by slow strain rate tests using a modified NACE TM-0177 solution, with 10–3M NaS2O3 substituting the saturated H2S standard solution. Tests were conducted at 25°C, pH 2.7 and under galvanostatic polarisation with a cathodic charging of 10 mA/cm2. S13Cr, 17Cr, P110 and 2507 steels were susceptible to hydrogen embrittlement inthiosulphate, with S13Cr and 17Cr being the most sensitive to this mechanism, while 2205 showed no sign of ductility loss. This harmful effect was attributed to the hydrogen sulphide generated from thiosulphate.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"333 - 342"},"PeriodicalIF":1.8,"publicationDate":"2023-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46539351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An overview of recent progresses in probing and understanding corrosion under disbonded coatings 近年来在探测和理解脱粘涂层腐蚀方面的进展综述
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-02-28 DOI: 10.1080/1478422X.2023.2182458
M. Tan, Facundo Bob Varela, Y. Huo
ABSTRACT Corrosion under disbonded coatings (CUDC) remains a major unsolved issue and a prime risk to underground steel structures such as buried gas pipelines. CUDC could not be effectively mitigated by conventional cathodic protection (CP) or be detected through usual inspection and survey technologies due to CP shielding. This article provides a brief review of recent progresses made through laboratory and field probing of CUDC and its influence factors. Discussions on CUDC processes and mechanisms are made based on results from an extensive laboratory and field-testing program using electrode array-based corrosion probes. It is shown that CUDC is affected not only by well-known factors such as the CP level, but also by coating disbondment geometry and soil conditions especially the seasonal dry-wet changes in soil saturation status. These findings have led to improved understanding of CUDC, and could lead to the development of better CUDC mitigation and control methods.
无粘结涂层(CUDC)的腐蚀一直是未解决的主要问题,也是地下钢结构(如埋地输气管道)的主要风险。由于阴极保护(CP)的屏蔽作用,传统的阴极保护(CP)无法有效缓解CUDC,也无法通过常规的检测和测量技术检测到CUDC。本文简要综述了近年来在实验室和野外对CUDC及其影响因素的研究进展。基于使用电极阵列腐蚀探针的广泛实验室和现场测试程序的结果,对CUDC过程和机制进行了讨论。结果表明,CUDC不仅受CP水平等众所周知的因素的影响,还受包膜剥离几何形状和土壤条件的影响,特别是受土壤饱和状态的季节性干湿变化的影响。这些发现增进了对CUDC的了解,并可能导致开发更好的CUDC缓解和控制方法。
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引用次数: 1
Corrosion behaviour of bioinspired laminated Al matrix composite hybrid reinforced with B4C and graphene nanoplatelets B4C和石墨烯纳米片增强复合材料的腐蚀行为
IF 1.8 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-02-28 DOI: 10.1080/1478422X.2023.2182457
Xingye Wang, Xiao-song Jiang, Hongliang Sun, Yali Zhang, Y. Fang, R. Shu
ABSTRACT Electrochemical corrosion tests (2500 ppm H3BO3 and 3.5 wt-% NaCl + 2500 ppm H3BO3 solution), salt spray tests and associated microstructure analysis were conducted to investigate the corrosion behaviours of bioinspired Al-xB4C-1GNPs laminated composites. The low porosity, defects and tightly bonded interface contribute to the high corrosion resistance. The increase of B4C content increased the corrosion potential and decreased the corrosion current density. The Al-5B4C-1GNPs has the highest corrosion resistance in NaCl + H3BO3 solution, the corrosion rate is 0.00459 mm/a. The laminated composites have better corrosion resistance in X plane than that in Z plane. The GNPs can prevent the Al matrix underneath it from contacting with solution and O2. The laminated structure and orientation of GNPs can effectively change the corrosion pathway and prevent the corrosion crack propagating longitudinally into the composite.
通过电化学腐蚀试验(2500 ppm H3BO3和3.5 wt-% NaCl + 2500 ppm H3BO3溶液)、盐雾试验和相关的微观结构分析,研究了仿生Al-xB4C-1GNPs层合复合材料的腐蚀行为。低孔隙率、低缺陷和紧密结合的界面使其具有较高的耐腐蚀性。B4C含量的增加增加了腐蚀电位,降低了腐蚀电流密度。Al-5B4C-1GNPs在NaCl + H3BO3溶液中的耐蚀性最高,腐蚀速率为0.00459 mm/a。复合材料在X平面上的耐腐蚀性能优于Z平面。GNPs可以防止其下方的Al基体与溶液和O2接触。GNPs的层状结构和取向可以有效地改变腐蚀路径,防止腐蚀裂纹纵向扩展到复合材料中。
{"title":"Corrosion behaviour of bioinspired laminated Al matrix composite hybrid reinforced with B4C and graphene nanoplatelets","authors":"Xingye Wang, Xiao-song Jiang, Hongliang Sun, Yali Zhang, Y. Fang, R. Shu","doi":"10.1080/1478422X.2023.2182457","DOIUrl":"https://doi.org/10.1080/1478422X.2023.2182457","url":null,"abstract":"ABSTRACT Electrochemical corrosion tests (2500 ppm H3BO3 and 3.5 wt-% NaCl + 2500 ppm H3BO3 solution), salt spray tests and associated microstructure analysis were conducted to investigate the corrosion behaviours of bioinspired Al-xB4C-1GNPs laminated composites. The low porosity, defects and tightly bonded interface contribute to the high corrosion resistance. The increase of B4C content increased the corrosion potential and decreased the corrosion current density. The Al-5B4C-1GNPs has the highest corrosion resistance in NaCl + H3BO3 solution, the corrosion rate is 0.00459 mm/a. The laminated composites have better corrosion resistance in X plane than that in Z plane. The GNPs can prevent the Al matrix underneath it from contacting with solution and O2. The laminated structure and orientation of GNPs can effectively change the corrosion pathway and prevent the corrosion crack propagating longitudinally into the composite.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"270 - 280"},"PeriodicalIF":1.8,"publicationDate":"2023-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43806438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Expression of Concern 表达关注
4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-02-27 DOI: 10.1080/1478422x.2022.2159144
This article refers to:Electrochemical and characterisation study of corrosion of reinforcing steel embedded in kaolinite: two-year exposure study
本文参考:高岭石中嵌入钢筋腐蚀的电化学及表征研究:两年暴露研究
{"title":"Expression of Concern","authors":"","doi":"10.1080/1478422x.2022.2159144","DOIUrl":"https://doi.org/10.1080/1478422x.2022.2159144","url":null,"abstract":"This article refers to:Electrochemical and characterisation study of corrosion of reinforcing steel embedded in kaolinite: two-year exposure study","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"205 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135996861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Corrosion Engineering, Science and Technology
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