ABSTRACT This study prepared copper (Cu) matrix composites with different graphene contents (0∼1.0 wt-%) and an equal amount of alumina (Al2O3) whisker by vacuum hot pressing sintering. The microstructures of the Cu/C and Cu/Al2O3 interfaces were characterised. The electrochemical corrosion behaviour of the composites was evaluated to study the influence of graphene content on the corrosion performance of the Cu matrix composites. The results showed that incorporating uniformly dispersed graphene with a small amount (∼0.25 wt-%) enables close integration with the Cu matrix, slows down the corrosion rate, and increases the impedance of the composites, thus effectively improving the corrosion resistance of Cu matrix composites. With an increase in graphene content (∼1.0 wt-%), defects tend to generate, leading to the formation of multiple corrosive microcell cavities in the composite, thus accelerating the corrosion of the composite. The Gr/Cu-0.25 composite exhibited better corrosion resistance in acidic, neutral, and alkaline corrosive solutions.
{"title":"Electrochemical behaviour of graphene and alumina whisker co-reinforced copper matrix composites","authors":"Z. Shao, Xubo Li, Yanhong Wei, Jianrun Chen, Qing Qin, Yong Xian, Yichao Ding","doi":"10.1080/1478422X.2022.2152771","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2152771","url":null,"abstract":"ABSTRACT\u0000 This study prepared copper (Cu) matrix composites with different graphene contents (0∼1.0 wt-%) and an equal amount of alumina (Al2O3) whisker by vacuum hot pressing sintering. The microstructures of the Cu/C and Cu/Al2O3 interfaces were characterised. The electrochemical corrosion behaviour of the composites was evaluated to study the influence of graphene content on the corrosion performance of the Cu matrix composites. The results showed that incorporating uniformly dispersed graphene with a small amount (∼0.25 wt-%) enables close integration with the Cu matrix, slows down the corrosion rate, and increases the impedance of the composites, thus effectively improving the corrosion resistance of Cu matrix composites. With an increase in graphene content (∼1.0 wt-%), defects tend to generate, leading to the formation of multiple corrosive microcell cavities in the composite, thus accelerating the corrosion of the composite. The Gr/Cu-0.25 composite exhibited better corrosion resistance in acidic, neutral, and alkaline corrosive solutions.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"145 - 155"},"PeriodicalIF":1.8,"publicationDate":"2022-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41938411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-07DOI: 10.1080/1478422X.2022.2153197
A. B. Radwan, A. M. Moussa, N. Al-Qahtani, R. Case, H. Castaneda, A. Abdullah, Muhsen A. M. El-Haddad, J. Bhadra, N. Al-Thani, Yuan Ding
ABSTRACT The limits and nature of the passive behavior exhibited by modified martensitic stainless steels (MMSS) is studied in brine solutions at different temperatures using electrochemical methods and the point defect model (PDM), in an environment at pH is 3 and temperatures up to 150°C, using autoclaves with CO2 gas up to 2.8 MPa. The results show that passivity on the MMSS is characterized by the metal cation vacancy diffusivity (D) which indicates that the passivity up to temperatures of 75°C is more stable than at higher temperatures up to 150°C. The value of D is used to describe the transition between the passive layers at the threshold temperature of 75°C; at which exhibits the largest stability. MMSS specimens passivated at 75°C exhibit higher passivity stability in experiments performed at 25°C, when compared the pre passivation, suggesting that the change experienced at 75°C is at least partially irreversible.
{"title":"Effect of the temperature on the passivity of the modified martensitic stainless steels","authors":"A. B. Radwan, A. M. Moussa, N. Al-Qahtani, R. Case, H. Castaneda, A. Abdullah, Muhsen A. M. El-Haddad, J. Bhadra, N. Al-Thani, Yuan Ding","doi":"10.1080/1478422X.2022.2153197","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2153197","url":null,"abstract":"ABSTRACT The limits and nature of the passive behavior exhibited by modified martensitic stainless steels (MMSS) is studied in brine solutions at different temperatures using electrochemical methods and the point defect model (PDM), in an environment at pH is 3 and temperatures up to 150°C, using autoclaves with CO2 gas up to 2.8 MPa. The results show that passivity on the MMSS is characterized by the metal cation vacancy diffusivity (D) which indicates that the passivity up to temperatures of 75°C is more stable than at higher temperatures up to 150°C. The value of D is used to describe the transition between the passive layers at the threshold temperature of 75°C; at which exhibits the largest stability. MMSS specimens passivated at 75°C exhibit higher passivity stability in experiments performed at 25°C, when compared the pre passivation, suggesting that the change experienced at 75°C is at least partially irreversible.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"156 - 168"},"PeriodicalIF":1.8,"publicationDate":"2022-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49099118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-06DOI: 10.1080/1478422X.2022.2137979
Sheetal, Rashika Batra, Ashish Kumar Singh, Manjeet Singh, S. Thakur, B. Pani, S. Kaya
ABSTRACT Organic compounds containing heteroatoms have been comprehended to exhibit a remarkable tendency towards corrosion mitigation. This corrosion mitigating tendency is enabled by the presence of electron clouds composed of lone pairs, pi-electrons, which allow them to be adsorbed over metallic equivalents. Because of the availability of nitrogen as heteroatoms, these compounds are being extensively used for corrosion diminution. This article looks at a variety of heterocyclic organic compounds like imidazole, triazole, pyridine, pyrazole, quinoline, tetrazole, pyrimidine, purine and pyrrole, having nitrogen as their prime constituent heteroatom for their anti-corrosive properties. The anti-corrosive properties of these nitrogen-based compounds in acidic conditions have been demonstrated using all available experimental techniques such as EIS, PDP and other theoretical investigations such as DFT and MD. Furthermore, the shift in the trend of these compounds inhibitory efficiencies has been noted and underlined here.
{"title":"Advancement of corrosion inhibitor system through N-heterocyclic compounds: a review","authors":"Sheetal, Rashika Batra, Ashish Kumar Singh, Manjeet Singh, S. Thakur, B. Pani, S. Kaya","doi":"10.1080/1478422X.2022.2137979","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2137979","url":null,"abstract":"ABSTRACT Organic compounds containing heteroatoms have been comprehended to exhibit a remarkable tendency towards corrosion mitigation. This corrosion mitigating tendency is enabled by the presence of electron clouds composed of lone pairs, pi-electrons, which allow them to be adsorbed over metallic equivalents. Because of the availability of nitrogen as heteroatoms, these compounds are being extensively used for corrosion diminution. This article looks at a variety of heterocyclic organic compounds like imidazole, triazole, pyridine, pyrazole, quinoline, tetrazole, pyrimidine, purine and pyrrole, having nitrogen as their prime constituent heteroatom for their anti-corrosive properties. The anti-corrosive properties of these nitrogen-based compounds in acidic conditions have been demonstrated using all available experimental techniques such as EIS, PDP and other theoretical investigations such as DFT and MD. Furthermore, the shift in the trend of these compounds inhibitory efficiencies has been noted and underlined here.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"73 - 101"},"PeriodicalIF":1.8,"publicationDate":"2022-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46047223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-02DOI: 10.1080/1478422X.2022.2152174
E. B. Fonseca, A. Z. Fatichi, M. Terada, A. Bugarin, José Raúl Rodríguez Rodríguez, I. Costa, A. Ramirez
ABSTRACT Alloy 625 is a Ni-based alloy used in aerospace, energy, chemical, oil and gas industries, mainly as cladding material due to its corrosion resistance, high strength and creep resistance at high temperature. In this study, microstructural evaluation and susceptibility to intergranular corrosion of base metal and friction stir welded Alloy 625 were investigated. Friction stir welded joints exhibited a lower corrosion rate and degree of sensitisation compared to the base metal. It is mainly due to grain refinement and lower cooling rate of the friction stir welding process. The stir zone of the present weld has a finer grain structure and lower density of twin boundaries than the base metal and it led to the improvement of the mechanical and corrosion properties.
{"title":"Quantitative analysis of susceptibility to intergranular corrosion in alloy 625 joined by friction stir welding","authors":"E. B. Fonseca, A. Z. Fatichi, M. Terada, A. Bugarin, José Raúl Rodríguez Rodríguez, I. Costa, A. Ramirez","doi":"10.1080/1478422X.2022.2152174","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2152174","url":null,"abstract":"ABSTRACT Alloy 625 is a Ni-based alloy used in aerospace, energy, chemical, oil and gas industries, mainly as cladding material due to its corrosion resistance, high strength and creep resistance at high temperature. In this study, microstructural evaluation and susceptibility to intergranular corrosion of base metal and friction stir welded Alloy 625 were investigated. Friction stir welded joints exhibited a lower corrosion rate and degree of sensitisation compared to the base metal. It is mainly due to grain refinement and lower cooling rate of the friction stir welding process. The stir zone of the present weld has a finer grain structure and lower density of twin boundaries than the base metal and it led to the improvement of the mechanical and corrosion properties.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"138 - 144"},"PeriodicalIF":1.8,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41327523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRACT Corrosion behaviour of carbon steel (CS) exposed in the tidal zone of Beibu Gulf was investigated by experimental method. Q235 CS specimens were designed and exposed for 12 months. The corrosion mechanism of CS was characterised by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-Ray diffraction (XRD). Results show that the corrosion performance of CS can be verified by the formula D = atn . The corrosion products are mainly composed of α-FeOOH, γ-FeOOH, β-FeOOH, Fe3O4 and γ-Fe2O3. Significantly, Cl– is an intermediate in the corrosion process and promotes the formation of the characteristic product β-FeOOH.
{"title":"Corrosion behaviour of carbon steel in Beibu Gulf tidal zone","authors":"Sheng He, Shiqi He, P. Yu, Hongfei Li, Jing-Yu Feng, Pingfu Liao, Jianhui Liao, Xinheng Huang","doi":"10.1080/1478422X.2022.2149426","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2149426","url":null,"abstract":"ABSTRACT Corrosion behaviour of carbon steel (CS) exposed in the tidal zone of Beibu Gulf was investigated by experimental method. Q235 CS specimens were designed and exposed for 12 months. The corrosion mechanism of CS was characterised by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-Ray diffraction (XRD). Results show that the corrosion performance of CS can be verified by the formula D = atn . The corrosion products are mainly composed of α-FeOOH, γ-FeOOH, β-FeOOH, Fe3O4 and γ-Fe2O3. Significantly, Cl– is an intermediate in the corrosion process and promotes the formation of the characteristic product β-FeOOH.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"116 - 123"},"PeriodicalIF":1.8,"publicationDate":"2022-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49633122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-11-24DOI: 10.1080/1478422X.2022.2149048
Yu Liu, E. Asselin
ABSTRACT Solid minerals are ubiquitous and common deposits on Ti-lined process vessels in the hydrometallurgical industry. This work revealed the effects of inert solid deposits on the corrosion behaviour of Ti-2 in high acidity and highly oxidising leaching solutions. It was found that the deposit-covered Ti-2 had a higher corrosion rate (CR) than bare Ti-2. CR increased with increasing deposit thickness (up to 6 cm) and temperature. Solid deposits mainly affected the corrosion process of Ti by limiting the mass transfer of the oxidising Fe(III) from the bulk solution to the underlying Ti, thus affecting the stability of the protective passive film, and resulting in an accelerated passive CR. High temperatures and solid deposition are both commonly encountered in the hydrometallurgical industry, and their combination may significantly limit the maximum service temperature of Ti-equipment, implying that there is a risk in using Ti-components under such conditions.
{"title":"Effects of solid deposits on the corrosion behaviour of titanium in high acidity and highly oxidising leaching solutions","authors":"Yu Liu, E. Asselin","doi":"10.1080/1478422X.2022.2149048","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2149048","url":null,"abstract":"ABSTRACT Solid minerals are ubiquitous and common deposits on Ti-lined process vessels in the hydrometallurgical industry. This work revealed the effects of inert solid deposits on the corrosion behaviour of Ti-2 in high acidity and highly oxidising leaching solutions. It was found that the deposit-covered Ti-2 had a higher corrosion rate (CR) than bare Ti-2. CR increased with increasing deposit thickness (up to 6 cm) and temperature. Solid deposits mainly affected the corrosion process of Ti by limiting the mass transfer of the oxidising Fe(III) from the bulk solution to the underlying Ti, thus affecting the stability of the protective passive film, and resulting in an accelerated passive CR. High temperatures and solid deposition are both commonly encountered in the hydrometallurgical industry, and their combination may significantly limit the maximum service temperature of Ti-equipment, implying that there is a risk in using Ti-components under such conditions.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"108 - 115"},"PeriodicalIF":1.8,"publicationDate":"2022-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41398561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-11-23DOI: 10.1080/1478422X.2022.2148855
Saijun Chen, Qi Liu, Z. Yang, F. Guo, Liuping Chen, Zhigang Zhang, Zhongfeng Tang
ABSTRACT The corrosion behaviours of Ni-Mo-Cr alloy and 316 stainless steel samples after immersing in NaCl-KCl-AlCl3 salt at 400.0°C for 168 h were investigated. The surface of Ni-Mo-Cr alloy basically kept its pre-corrosion morphology, with only a few corrosion pits. While NaCl-KCl-AlCl3 salt had stronger corrosivity to 316SS. After corrosion, the grain boundary of the surface of 316SS alloy was clearly visible, and the Fe and Cr atoms on the surface of 316SS were selectively corroded, leaving a Ni- rich layer of about 6.5 µm on the outmost surface of 316SS. At the temperature of 400.0°C, the corrosion resistance of Ni-Mo-Cr alloy to molten NaCl-KCl-AlCl3 salt was better than that of 316SS.
{"title":"Corrosion behaviours of Ni-Mo-Cr alloy and 316 stainless steel in molten NaCl-KCl-AlCl3 salts at high temperature","authors":"Saijun Chen, Qi Liu, Z. Yang, F. Guo, Liuping Chen, Zhigang Zhang, Zhongfeng Tang","doi":"10.1080/1478422X.2022.2148855","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2148855","url":null,"abstract":"ABSTRACT The corrosion behaviours of Ni-Mo-Cr alloy and 316 stainless steel samples after immersing in NaCl-KCl-AlCl3 salt at 400.0°C for 168 h were investigated. The surface of Ni-Mo-Cr alloy basically kept its pre-corrosion morphology, with only a few corrosion pits. While NaCl-KCl-AlCl3 salt had stronger corrosivity to 316SS. After corrosion, the grain boundary of the surface of 316SS alloy was clearly visible, and the Fe and Cr atoms on the surface of 316SS were selectively corroded, leaving a Ni- rich layer of about 6.5 µm on the outmost surface of 316SS. At the temperature of 400.0°C, the corrosion resistance of Ni-Mo-Cr alloy to molten NaCl-KCl-AlCl3 salt was better than that of 316SS.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"103 - 107"},"PeriodicalIF":1.8,"publicationDate":"2022-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44256390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-11-04DOI: 10.1080/1478422X.2022.2140248
Xu Zhao, Y. Qi, Z. Zhang, Mengxin Li
ABSTRACT The effect of a barrier layer composed of reduced graphene oxide (rGO) with edge adsorption of K+ (rGOK+) on anticorrosive performance was investigated. Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), DC polarisation technique and electrochemical impedance spectroscopy (EIS) were used to investigate the morphology, corrosion product, corrosion mechanism and process. XPS results show that the corrosion products are ZnCl2, Zn(OH)2, ZnCO3 and Zn5(OH)8Cl2. SEM, energy-dispersive spectrometer (EDS), polarisation curve and EIS show that the coating with the most rGOK+ not only builds a barrier layer but also improves the utilisation of zinc powder, thereby providing better corrosion protection for the substrate despite the 30% reduction in zinc powder usage.
{"title":"Effect of regularly arranged reduced graphene oxide on the anti-corrosion performance of waterborne silicate zinc-rich coatings","authors":"Xu Zhao, Y. Qi, Z. Zhang, Mengxin Li","doi":"10.1080/1478422X.2022.2140248","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2140248","url":null,"abstract":"ABSTRACT The effect of a barrier layer composed of reduced graphene oxide (rGO) with edge adsorption of K+ (rGOK+) on anticorrosive performance was investigated. Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), DC polarisation technique and electrochemical impedance spectroscopy (EIS) were used to investigate the morphology, corrosion product, corrosion mechanism and process. XPS results show that the corrosion products are ZnCl2, Zn(OH)2, ZnCO3 and Zn5(OH)8Cl2. SEM, energy-dispersive spectrometer (EDS), polarisation curve and EIS show that the coating with the most rGOK+ not only builds a barrier layer but also improves the utilisation of zinc powder, thereby providing better corrosion protection for the substrate despite the 30% reduction in zinc powder usage.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"61 - 72"},"PeriodicalIF":1.8,"publicationDate":"2022-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44104016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-11-01DOI: 10.1080/1478422X.2022.2140247
M. Prem kumar, M. Manikandan
ABSTRACT This research mainly focuses on selecting phase change materials (PCM) and container materials for next-generation concentrated solar power plants (CSP). The present study investigates the hot corrosion behaviour of Inconel 617 and 625 in Na2SO4 + 45 wt-% diatomite PCM environment at 800°C for 40, 80 and 120 h. Oxide scales developed on the alloy surfaces were examined by Scanning electron microscope (SEM) and X-ray diffraction (XRD) to study morphology and oxide phases. The result indicates that Inconel 617 and 625 weight changes were 1.239 and 0.925 mg cm−2 at 800°C for a maximum duration of 120 h. The dense oxide of Cr2O3 is formed on alloys 617 and 625, which gives better oxidation resistance in a PCM environment. Moreover, the Inconel 625 shows lesser weight gain compared to Inconel 617 due to the presence of higher wt-% of Cr in the alloy and Nb formation oxides reducing corrosion species diffusion rate.
{"title":"Investigation of corrosion behaviour on Ni–Cr–Co and Ni–Cr–Mo alloys exposed to molten salt for thermal energy storage applications","authors":"M. Prem kumar, M. Manikandan","doi":"10.1080/1478422X.2022.2140247","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2140247","url":null,"abstract":"ABSTRACT This research mainly focuses on selecting phase change materials (PCM) and container materials for next-generation concentrated solar power plants (CSP). The present study investigates the hot corrosion behaviour of Inconel 617 and 625 in Na2SO4 + 45 wt-% diatomite PCM environment at 800°C for 40, 80 and 120 h. Oxide scales developed on the alloy surfaces were examined by Scanning electron microscope (SEM) and X-ray diffraction (XRD) to study morphology and oxide phases. The result indicates that Inconel 617 and 625 weight changes were 1.239 and 0.925 mg cm−2 at 800°C for a maximum duration of 120 h. The dense oxide of Cr2O3 is formed on alloys 617 and 625, which gives better oxidation resistance in a PCM environment. Moreover, the Inconel 625 shows lesser weight gain compared to Inconel 617 due to the presence of higher wt-% of Cr in the alloy and Nb formation oxides reducing corrosion species diffusion rate.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"49 - 60"},"PeriodicalIF":1.8,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45426989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-10-14DOI: 10.1080/1478422X.2022.2132616
Fengting Cao, Zequan He, T. Wang, Grace W.W. Gao, Qixiang Fan, Yanmei Liu, J. Peng, Shanshan Cai, Dong Xu, Jian Tao
ABSTRACT The synergistic inhibition effect of sodium phytate (PA) and benzotriazole (BTA) on 20SiMn steel in 3.5 wt-% NaCl solutions was studied using electrochemical methods, SEM, FTIR, XPS and quantum chemical calculations based on density functional theory (DFT). Results indicate that a protective bi-layer film is formed with the presence of the mixture of PA and BTA: the inner layer consists of iron oxides, while the outer one is an adsorption layer of BTA and PA. Based on the analysis of XPS and DFT, the function of BTA belongs to chemisorption, while that of PA obeys Langmuir adsorption isotherm and could be mainly assigned to physisorption. The inhibition efficiency of the mixture inhibitor is 99.12%, with a synergism parameter of 3.62, which could be ascribed to a cross-linking structure containing more BTA promoted by PA through hydrogen bonds.
{"title":"The synergistic effect of sodium phytate and benzotriazole as corrosion inhibitors of 20SiMn steel in 3.5 wt-% NaCl solution","authors":"Fengting Cao, Zequan He, T. Wang, Grace W.W. Gao, Qixiang Fan, Yanmei Liu, J. Peng, Shanshan Cai, Dong Xu, Jian Tao","doi":"10.1080/1478422X.2022.2132616","DOIUrl":"https://doi.org/10.1080/1478422X.2022.2132616","url":null,"abstract":"ABSTRACT The synergistic inhibition effect of sodium phytate (PA) and benzotriazole (BTA) on 20SiMn steel in 3.5 wt-% NaCl solutions was studied using electrochemical methods, SEM, FTIR, XPS and quantum chemical calculations based on density functional theory (DFT). Results indicate that a protective bi-layer film is formed with the presence of the mixture of PA and BTA: the inner layer consists of iron oxides, while the outer one is an adsorption layer of BTA and PA. Based on the analysis of XPS and DFT, the function of BTA belongs to chemisorption, while that of PA obeys Langmuir adsorption isotherm and could be mainly assigned to physisorption. The inhibition efficiency of the mixture inhibitor is 99.12%, with a synergism parameter of 3.62, which could be ascribed to a cross-linking structure containing more BTA promoted by PA through hydrogen bonds.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"58 1","pages":"36 - 48"},"PeriodicalIF":1.8,"publicationDate":"2022-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49417241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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