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Review of passivity and electrochemical properties of nanostructured stainless steels obtained by surface mechanical attrition treatment (SMAT): trend and progress 表面机械摩擦处理(SMAT)纳米不锈钢的钝化性能和电化学性能研究进展
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-03-16 DOI: 10.1515/corrrev-2021-0072
T. Olugbade, E. O. Olutomilola, B. Olorunfemi
Abstract Surface nanocrystallization provides the opportunity to produce gradient-structured metallic materials with improved properties. Several attempts have been made to produce nanostructured stainless steel (SS), along with the study of the resultant corrosion resistance. However, the current knowledge is insufficient to address the corrosion mechanism and the possible ways of enhancing the corrosion resistance after surface treatment. The present work reviews the past significant works on the effect of surface treatment by surface mechanical attrition treatment (SMAT) method as well as its processing parameters on the corrosion properties of SS. The corrosion resistance of nanostructured SS is influenced by the extent of grain refinement, compactness, and homogeneity of the passive film, Cr content, grain boundary structure, composition, and alloying elements. In addition, the resulting corrosion properties can be controlled by choosing the right processing parameters during treatment. Progress on the corrosion behavior of nanostructured steels was summarized and new avenues for further research and developments are proposed.
摘要表面纳米化为生产具有改进性能的梯度结构金属材料提供了机会。已经进行了几次生产纳米结构不锈钢(SS)的尝试,以及对由此产生的耐腐蚀性的研究。然而,目前的知识不足以解决腐蚀机理和表面处理后提高耐腐蚀性的可能方法。本文综述了过去关于表面机械磨损处理(SMAT)方法的表面处理及其工艺参数对SS腐蚀性能的影响的重要工作。纳米结构SS的耐腐蚀性受钝化膜的晶粒细化程度、致密性和均匀性、Cr含量、晶界结构、成分和合金元素的影响。此外,可以通过在处理过程中选择正确的工艺参数来控制由此产生的腐蚀性能。综述了纳米结构钢腐蚀行为的研究进展,并提出了进一步研究和发展的新途径。
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引用次数: 7
Retraction of: Resistance to chemical attack of cement composites impregnated with a special polymer sulfur composite 缩回:浸渍特殊聚合物硫复合材料的水泥复合材料的抗化学侵蚀性能
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-03-10 DOI: 10.1515/corrrev-2022-0005
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引用次数: 0
Kinetics and mechanistic reaction pathway of carbon steel dissolution in simulated CO2–H2S medium in the presence of formic acid 甲酸存在下碳钢在模拟CO2-H2S介质中溶解动力学及机理反应途径
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-03-04 DOI: 10.1515/corrrev-2021-0062
Anusuya Talukdar, P. Baranwal, Prasanna Venkatesh Rajaraman
Abstract Anodic dissolution of carbon steel in solution mixtures of simulated CO2–H2S in the presence of formic acid (0–500 ppm) was investigated using electrochemical methods such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results show that the corrosion rate increases with an increase in the concentration of formic acid. Potentiodynamic polarization data revealed that the increase in cathodic current density plays a significant role in the increase of carbon steel corrosion rate. A combination of equivalent circuits was employed to model the impedance spectra of the carbon steel electrode acquired at open circuit potential and different overpotentials. The EIS data obtained at various overpotentials were further analyzed by reaction mechanism analysis (RMA) approach to interpret the dissolution mechanism. A multi-step reaction model including two dissolution paths and ferrous intermediate adsorbed species determined the dissolution behaviour of carbon steel. The best fit RMA kinetic parameters were retrieved using an optimization technique and the surface coverage of adsorbed species was estimated. Surface morphology of corroded steel surfaces was also examined with field emission scanning electron microscope demonstrating aggressive uniform corrosion of carbon steel in the presence of formic acid.
摘要使用电化学方法,如动电位极化和电化学阻抗谱(EIS),研究了在甲酸(0–500 ppm)存在下,碳钢在模拟CO2–H2S溶液混合物中的阳极溶解。结果表明,腐蚀速率随甲酸浓度的增加而增加。电位动态极化数据表明,阴极电流密度的增加对碳钢腐蚀速率的提高起着重要作用。采用等效电路的组合来模拟在开路电位和不同过电位下获得的碳钢电极的阻抗谱。通过反应机理分析(RMA)方法进一步分析了在各种过电位下获得的EIS数据,以解释溶解机理。一个包括两种溶解路径和含铁中间体吸附物种的多步骤反应模型确定了碳钢的溶解行为。使用优化技术检索最佳拟合的RMA动力学参数,并估计吸附物种的表面覆盖率。还用场发射扫描电子显微镜检查了腐蚀钢表面的表面形态,证明了在甲酸存在下碳钢的侵蚀性均匀腐蚀。
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引用次数: 1
Corrosion behavior of low carbon steels and other non-ferrous metals exposed to a real calcareous soil environment 低碳钢和其他有色金属暴露于真实钙质土壤环境中的腐蚀行为
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-03-04 DOI: 10.1515/corrrev-2021-0008
T. Pérez, M. A. Domínguez-Aguilar, J. Alamilla, Hongbo Liu, A. Contreras, L. M. Quej Ake
Abstract The corrosion behavior of four uncoated low carbon steels: X52, X60, X65, and X70, and three non-ferrous metals: copper, bronze, and magnesium, buried in a real calcareous soil, after a year of exposure time was studied. Samples were not cathodically protected on gravimetric testing in field conditions. Severe roughness and color changes occurred in metals and surface evidenced the presence of rust and calcareous deposits. Oxide scale was generated when metals were immersed in calcareous soil for nine months. In field conditions, X52 was the most corrosion resistant and X65 the most susceptible to corrosion. At laboratory level, a real calcareous soil tested by electrochemical methods exhibited the same trend, which was ascribed to difference in microstructure and phase distribution in steels. Corrosion enhanced when X65 was exposed to calcareous soil collected in spring (0.031 mm/year) and rainy summer (0.077 mm/year), as rain enhanced ions mobility and corrosion. Non-ferrous coupons suggested that a passivation process occurred as corrosion rates (CRs) decreased (0.0025–0.0052 mm/year) compared with the results of low carbon steels.
摘要研究了四种未涂覆的低碳钢:X52、X60、X65和X70,以及三种有色金属:铜、青铜和镁,在真正的钙质土壤中暴露一年后的腐蚀行为。在现场条件下进行重量测试时,样品未受到阴极保护。金属和表面出现严重的粗糙度和颜色变化,证明存在铁锈和钙质沉积物。当金属在石灰性土壤中浸泡9个月时,会产生氧化皮。在现场条件下,X52最耐腐蚀,X65最易腐蚀。在实验室水平上,通过电化学方法测试的真实石灰性土壤表现出相同的趋势,这归因于钢中微观结构和相分布的差异。X65暴露于春季(0.031毫米/年)和夏季多雨(0.077毫米/年。有色金属试片表明,与低碳钢的结果相比,随着腐蚀速率(CR)的降低(0.0025–0.0052 mm/年),钝化过程发生了。
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引用次数: 2
Improved corrosion inhibition by heterocyclic compounds on mild steel in acid medium 酸性介质中杂环化合物对低碳钢的缓蚀作用
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-02-15 DOI: 10.1515/corrrev-2021-0045
Rathika Govindasamy, Sathiyapriya Thirumalaisamy, Kohila chandran, M. Dhayalan, Mika Sillanpaa
Abstract A detailed comparative study on inhibitive behaviour against corrosion of mild steel in 1N H2SO4 IN HCl for the Schiff bases 2,6-diphenyl-3-methyl azinan-4-one (D3MA) (S1), 2,6-diphenyl-3-methyl azinan-4-one semicarbazone (D3MAS) (S2), 2,6-diphenyl azinan-4-one (DA) (S3) and 2,6-diphenylazinan-4-one semicarbazone (DAS) (S4) was investigated using gravimetric and potentiodynamic polarisation methods. The thermodynamic parameters for the mild steel corrosion and the synergistic behaviour of the inhibitors in the presence of anions and cations were determined and discussed. It was found that the adsorption of the inhibitors on the mild steel surface obeyed Langmuir adsorption isotherm. Electro chemical studies revealed that all the four inhibitors are of mixed type. We proved that the semicarbazones (Schiff bases S2b and S4) with additional O and N are more effective corrosion inhibitors than their parent keto-amines. As a whole from all the proposed studies it is proved that the explored Schiff’s bases work as a very efficient corrosion inhibitor for mild steel in both the acidic medium.
摘要采用重量法和动电位极化法研究了希夫碱2,6-二苯基-3-甲基氮氮-4-one (D3MA) (S1)、2,6-二苯基-3-甲基氮氮-4-one -氨基脲酮(D3MAS) (S2)、2,6-二苯基氮氮-4-one (DA) (S3)和2,6-二苯基氮氮-4-one -氨基脲酮(DAS) (S4)对低碳钢在1N H2SO4 in HCl中的缓蚀性能。测定并讨论了低碳钢腐蚀的热力学参数和缓蚀剂在阴离子和阳离子存在下的协同行为。发现缓蚀剂在低碳钢表面的吸附服从Langmuir吸附等温线。电化学研究表明,四种抑制剂均为混合型。我们证明了含有额外O和N的缩氨基脲(希夫碱S2b和S4)比它们的母体酮胺更有效的缓蚀剂。总的来说,从所有提出的研究中可以证明,所探索的希夫碱在酸性介质中对低碳钢都是一种非常有效的缓蚀剂。
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引用次数: 5
Ideal corrosion inhibitors: a review of plant extracts as corrosion inhibitors for metal surfaces 理想的缓蚀剂:植物提取物作为金属表面缓蚀剂的研究进展
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-02-11 DOI: 10.1515/corrrev-2021-0051
Pearl Isabellah Murungi, A. Sulaimon
Abstract Corrosion, a gradual destruction of metals as they react to their environment, is a daunting issue faced by the oil and gas industry since it has negative impacts on both life and industry applications. Attempts to tackle this problem have involved a myriad of techniques among which, corrosion inhibitors have been found to be the most effective. Corrosion inhibitors adsorb onto metallic surfaces and insulate them from deterioration. Plants being green and abundant in nature, offer a cost-effective replacement to toxic, chemical inhibitors on the market. Investigations of several plant extracts using different variables to quantify their effectiveness reveal that most of them exhibit an excellent inhibition potential, usually above 90%. These outstanding results prove their efficiency compared to traditional methods and necessitate further studies so as to enable implementation on large scale.
摘要腐蚀,即金属在对环境做出反应时逐渐被破坏,是石油和天然气行业面临的一个令人生畏的问题,因为它对生活和工业应用都有负面影响。解决这个问题的尝试涉及到无数的技术,其中缓蚀剂被发现是最有效的。缓蚀剂吸附在金属表面,使其不变质。植物是绿色的,自然界丰富,为市场上有毒的化学抑制剂提供了一种具有成本效益的替代品。使用不同的变量对几种植物提取物进行研究以量化其有效性,结果表明,它们中的大多数都表现出极好的抑制潜力,通常超过90%。这些突出的结果证明了它们与传统方法相比的效率,需要进一步研究才能大规模实施。
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引用次数: 6
Sulfamic acid is an environment-friendly alternative electrolyte for industrial acid cleaning and corrosion inhibition: a mini review 氨基磺酸是一种用于工业酸洗和缓蚀的环保型替代电解质
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-02-03 DOI: 10.1515/corrrev-2021-0023
C. Verma, M. Quraishi
Abstract Sulfamic acid (H3NSO3), which is also known as amino sulfuric acid, sulfamidic acid, amidosulfonic acid, and aminosulfonic acid, is an industrially useful water-soluble colorless crystalline solid. Sulfamic acid solutions of different concentrations are widely used for the removal of scales and metal oxides deposits from the surface of metals and ceramics. Sulfamic acid solutions (5–10%) serve as alternative electrolytes for the removal of rusts and lime scales to replace relatively more irritating and volatile hydrochloric and sulfuric acid-based electrolytes. Sulfamic acid solutions can be regarded as relatively more environmentally friendly and less toxic electrolytes for the cleaning of metallic surfaces. However, similar to the popular acidic solutions, sulfamic acid based electrolytes are corrosive to metal and metallic structures. Therefore, organic compounds based corrosion inhibitors of natural and synthetic origin are widely used to prevent corrosive damage of metallic surfaces in such electrolytes. These compounds become effective by adsorbing on the metallic surface following through the Langmuir adsorption isotherm model. Using electrochemical analyses it was observed that organic corrosion inhibitors in sulfamic acid based electrolytes behave as mixed- and interface-type corrosion inhibitors and they become effective by adsorbing at the metal/electrolyte interfaces. The adsorption of most of the corrosion inhibitors mostly follows physiochemisorption mechanism.
摘要氨基磺酸(H3NSO3),也称为氨基硫酸、氨基磺酸、氨基磺酸和氨基磺酸,是一种工业上有用的水溶性无色结晶固体。不同浓度的氨基磺酸溶液被广泛用于去除金属和陶瓷表面的水垢和金属氧化物沉积物。氨基磺酸溶液(5–10%)可作为替代电解质,用于去除铁锈和石灰皮,以取代刺激性和挥发性相对较高的盐酸和硫酸电解质。氨基磺酸溶液可以被认为是用于清洁金属表面的相对更环保、毒性更小的电解质。然而,与流行的酸性溶液类似,氨基磺酸基电解质对金属和金属结构具有腐蚀性。因此,天然和合成来源的基于有机化合物的缓蚀剂被广泛用于防止此类电解质中金属表面的腐蚀性损伤。这些化合物通过遵循Langmuir吸附等温线模型在金属表面上吸附而变得有效。通过电化学分析,观察到氨基磺酸基电解质中的有机缓蚀剂表现为混合型和界面型缓蚀剂,它们通过在金属/电解质界面上吸附而变得有效。大多数缓蚀剂的吸附大多遵循物理化学吸附机理。
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引用次数: 2
Reviewer acknowledgement Corrosion Reviews volume 39 (2021) 《腐蚀评论》第39卷(2021)
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-02-01 DOI: 10.1515/corrrev-2021-0098
Article Reviewer acknowledgement Corrosion Reviews volume 39 (2021) was published on February 1, 2022 in the journal Corrosion Reviews (volume 40, issue 1).
《腐蚀评论》第39卷(2021)于2022年2月1日发表在《腐蚀评论》杂志(第40卷第1期)上。
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引用次数: 0
Prediction and mitigation of AC interference on the pipeline system 管道系统交流干扰的预测与缓解
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-02-01 DOI: 10.1515/corrrev-2021-0061
A. Thakur, A. K. Arya, pushpanth Sharma
Abstract The purpose of this paper is to predict and mitigate AC interference on buried pipeline systems due to transmission lines. Modeling and field verification of AC interference is done. The article also presents the issue of optimizing the mitigation measures. The paper uses the field data on soil resistivity, transmission line, and pipeline details to develop a model using current distribution electromagnetic interference grounding and soil structure analysis (CDEGS) software to predict the AC interference on the pipeline system. The model is validated with field measurements, and post-mitigation measures are considered. Mitigation measures are optimized to develop an economical mitigation plan. The case demonstrates the use of modeling techniques to predict and mitigate AC interference on pipelines. The field validation of modeling results helps improve the modeling results and plan optimized mitigation measures. The study requires providing comprehensive field data relevant to the pipeline system under consideration. The accuracy of the field data may have a bearing on the outcome of the study. The study enables designing and optimizing mitigation measures using modeling. Comparisons with field measurements help achieve desired pipeline system integrity against AC corrosion.
摘要:本文的目的是预测和减轻输电线路对埋地管道系统的交流干扰。对交流干扰进行了建模和现场验证。文章还提出了优化缓解措施的问题。本文利用现场土壤电阻率、输电线路和管道细节数据,利用电流分布电磁干扰接地和土壤结构分析(CDEGS)软件建立了预测管道系统交流干扰的模型。通过现场实测对模型进行了验证,并考虑了后期缓解措施。优化缓解措施,制定经济的缓解计划。该案例演示了如何使用建模技术来预测和减轻管道上的交流干扰。模拟结果的现场验证有助于改进模拟结果,规划优化的缓解措施。该研究需要提供与所考虑的管道系统相关的全面现场数据。实地数据的准确性可能对研究结果有影响。这项研究使设计和优化利用建模缓解措施成为可能。与现场测量结果的比较有助于实现所需的管道系统完整性,防止交流腐蚀。
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引用次数: 3
Frontmatter Frontmatter
IF 3.2 4区 材料科学 Q3 ELECTROCHEMISTRY Pub Date : 2022-02-01 DOI: 10.1515/corrrev-2022-frontmatter1
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引用次数: 0
期刊
Corrosion Reviews
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