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室温轧制及固溶处理对Al-Ga-Mg-Mn-Bi阳极合金电化学性能的影响 室温轧制及固溶处理对Al-Ga-Mg-Mn-Bi阳极合金电化学性能的影响
Q4 Chemical Engineering Pub Date : 2014-07-29 DOI: 10.11903/1002.6495.2013.262
李登辉, 文九巴, 贺俊光, 高军伟
Influence of solution treatment and cool rolling deformation on the microstructure and electrochemical performance of the Al-Ga-Mg-Mn-Bi anode alloy was investigated by measuring the impedance spectroscopy, polarization curve, free-corrosion rate, etc. The results show that: in comparison with the cast alloy, the quantity of the second phase, the free-corrosion rate and the hydrogen evolution rate of the solution-treated alloy were greatly reduced, while the amount and size of corrosion pits were also reduced with a negative shift of its potential of constant- current discharge; after cool rolling deformation the alloy exhibits a rather uniform corrosion morphology with small pits and also a negative shift of its potential of constant-current discharge.
通过阻抗谱、极化曲线、自由腐蚀速率等测试,研究了固溶处理和冷轧变形对Al-Ga-Mg-Mn-Bi阳极合金微观组织和电化学性能的影响。结果表明:与铸态合金相比,固溶处理合金的第二相数量、自由腐蚀速率和析氢速率显著降低,腐蚀坑的数量和尺寸减小,恒流放电电位呈负移;经冷轧变形后,合金的腐蚀形貌较为均匀,蚀坑较小,且恒流放电电位呈负位移。
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引用次数: 0
Electroless Ni-P Plating on AZ91D Magnesium Alloy with a New Homogenization Pretreatment AZ91D镁合金化学镀Ni-P的均匀化预处理方法
Q4 Chemical Engineering Pub Date : 2014-07-29 DOI: 10.11903/1002.6495.2013.256
Can Sun, Xingwu Guo, Shaohua Wang, W. Ding
A new environment-friendly homogenization pretreatment process was adopted for the electroless nickel plating on AZ91D magnesium alloy. Then, the morphologies, chemical composition and microstructure of the pretreated layer and the formed Ni-P coating were studied using scanning electronic microscopy(SEM), energy-dispersive X-ray spectroscopy(EDS) and X-ray diffraction spectroscopy(XRD). It was indicated that a dense Zn film formed on the substrate surface after the homogenization pretreatment, due to the selective removal of β phase during the processing.As the result, the subsequently formed Ni-P coating was uniform, compact and defect-free with P content around 7.0%, which was characterized as an amorphous matter by XRD. Potentiodynamic polarization and electrochemical impedance spectroscopy(EIS) tests revealed that the Ni-P coating could significantly improve the corrosion resistance of AZ91D magnesium alloy with an obvious positive shifting of corrosion potential by 1.136 V and a dramatic reduce of corrosion current density by two orders of magnitude. Furthermore the obtained Ni-P coating showed excellent adhesion to AZ91D substrate.
采用一种新的环保型均质预处理工艺对AZ91D镁合金进行化学镀镍。利用扫描电子显微镜(SEM)、能谱仪(EDS)和x射线衍射仪(XRD)研究了预处理层和形成的Ni-P涂层的形貌、化学成分和微观结构。结果表明,均匀化预处理后,基体表面形成致密的Zn膜,这是由于加工过程中β相的选择性去除所致。结果表明,制备的Ni-P涂层均匀致密,无缺陷,P含量在7.0%左右,经XRD表征为非晶态物质。动电位极化和电化学阻抗谱(EIS)测试表明,Ni-P涂层能显著提高AZ91D镁合金的耐蚀性,腐蚀电位显著正移1.136 V,腐蚀电流密度显著降低2个数量级。制备的Ni-P涂层对AZ91D基体具有良好的附着力。
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引用次数: 0
Preparation and Corrosion Performance of a Doping Modified Hybrid Film on Aluminum Tube 铝管掺杂改性杂化膜的制备及其腐蚀性能
Q4 Chemical Engineering Pub Date : 2014-07-29 DOI: 10.11903/1002.6495.2013.233
W. Tian, Rui-lin Man, Xiong Huang, F. He
A hybrid sol was prepared by sol-gel technique with precursors of ethylsilicate(TEOS)and vinyltriethoxysilane(KH151), and which then was further doped with 1.5×10-3mol/L Ce(NO3)3to get a Ce-doped hybrid sol. A coating of this Ce-doped hybrid sol was prepared on aluminum tube by dipping method. Results of bluestone drips test, neutral salt spray test and electrochemical measurement showed that the coating doping modified hybrid film possessed superior corrosion performance rather than the conventional chromate passivation film. The infrared spectrum of the coating revealed that there existed different types of Si—O—Si covalent bonds and organic functional groups C=C covalent bonds, which might enhance the hydrophobicity of the coating. Finally SEM examination showed that the formed coating was dense, uniform and smooth.
以硅酸乙酯(TEOS)和乙烯基三乙基氧基硅烷(KH151)为前驱体,采用溶胶-凝胶法制备了掺杂铈的杂化溶胶,再以1.5×10-3mol/L的Ce(NO3)3掺杂得到掺铈的杂化溶胶,并用浸渍法在铝管上涂覆该掺杂铈的杂化溶胶。青石滴液试验、中性盐雾试验和电化学测试结果表明,涂层掺杂改性杂化膜具有优于常规铬酸盐钝化膜的腐蚀性能。涂层的红外光谱显示,涂层中存在不同类型的Si-O-Si共价键和有机官能团C=C共价键,这可能增强了涂层的疏水性。SEM检测表明,成形涂层致密、均匀、光滑。
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引用次数: 0
Failure Analysis of ZG06Cr13Ni4Mo Stainless Steel Hydraulic Turbine Blades ZG06Cr13Ni4Mo不锈钢水轮机叶片失效分析
Q4 Chemical Engineering Pub Date : 2014-05-29 DOI: 10.11903/1002.6495.2013.197
Qiong Li, Zhiyong Liu, Lin Lu, Du Cuiwei, Song Wang, Xiaogang Li
Severe localized corrosion of ZG06Cr13Ni4Mo stainless steel hydraulic turbine blades after years of service is analyzed by means of examinations of macro-morphology, micro-morphology and energy dispersion spectrum(EDS) to identify the causes of corrosion. The results indicated that the initiation of pitting was closely related to the localized plastic deformation of surface layer and the ulcer-like corrosion was located mainly in the weld repaired area. More specifically, the pitting corrosion in this case was attributed to microbiological corrosion induced by sulfate reducing bacteria(SRB), and the surface defects of blade generated during machining and welding might further enhance the pitting and ulcer-like corrosion.
通过对ZG06Cr13Ni4Mo不锈钢水轮机叶片的宏观形貌、微观形貌和能谱分析,分析了叶片在使用多年后出现的严重局部腐蚀,找出了腐蚀的原因。结果表明:点蚀的产生与表层局部塑性变形密切相关,溃疡状腐蚀主要发生在焊缝修补区;更具体地说,这种情况下的点蚀是由硫酸盐还原菌(SRB)引起的微生物腐蚀,而叶片在加工和焊接过程中产生的表面缺陷可能进一步加剧点蚀和溃疡样腐蚀。
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引用次数: 1
Effect of Current Density on Ceramic Coating Prepared by Micro-arc Oxidation on 6061 Aluminum Alloy 电流密度对6061铝合金微弧氧化陶瓷涂层的影响
Q4 Chemical Engineering Pub Date : 2014-04-23 DOI: 10.11903/1002.6495.2013.128
H. Dong, Z. Niu, Dongshan Zhao, Guang-min Li
Micro-arc oxidation coating on 6061 aluminum alloy was prepared in a Na2SiO3containing electrolyte by a constant current control mode, and the effect of current density on the microstructure and performance of micro-arc oxidation ceramic coating was studied by a series of tests. Results for the above coatings show that their thickness and surface roughness increase with the increasing current density, however, their corrosion resistance decrease, and their hardness increases first and then decreases with the increasing current density. The ceramic coatings are mainly composed of α-Al2O3and γ-Al2O3. As a comparison, a novel current control method was adopted to prepare a micro-arc oxidation coating. Accordingly, the amount of micro-cracks was significantly reduced, and the corrosion resistance was obviously enhanced for the coating prepared by the new mode.
采用恒流控制方式在含na2sio3的电解液中制备了6061铝合金微弧氧化陶瓷涂层,并通过一系列试验研究了电流密度对微弧氧化陶瓷涂层微观结构和性能的影响。结果表明,随着电流密度的增大,镀层的厚度和表面粗糙度增大,耐蚀性降低,硬度随电流密度的增大先增大后减小。陶瓷涂层主要由α- al2o3和γ-Al2O3组成。作为对比,采用一种新的电流控制方法制备微弧氧化涂层。因此,新模式制备的涂层微裂纹数量明显减少,耐蚀性明显增强。
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引用次数: 1
Corrosion Behavior of Nickel Base Alloy 800H in High-temperature and High-pressured Water 镍基合金800H在高温高压水中的腐蚀行为
Q4 Chemical Engineering Pub Date : 2014-04-23 DOI: 10.11903/1002.6495.2013.080
Zhao Shen, Lianlian Wu, Le-fu Zhang, Z. Duan, Yao Sun
Susceptibility to stress corrosion cracking(SCC) of nickel based alloy 800H was studied in supercritical water at 550 ℃, 25 MPa, 600 ℃, 25 MPa and 650 ℃, 25 MPa respectively, and its general corrosion behavior in supercritical water at 650 ℃, 25 MPa and in subcritical water at 290 ℃, 15.2 MPa respectively as well. The mechanical properties of alloy 800H were also examined at different temperatures in air. The strain-stress curve of slow strain rate tensile(SSRT) tests shows that the strength of alloy 800H decreases as temperature increases. The ex situ scanning electron microscopy(SEM) observation shows that alloy 800H under the three conditions in supercritical water all exhibits susceptibility to SCC. The SSRT tests in air show that the yield strength and tensile strength of alloy 800H decrease as temperature rises. The results of general corrosion experiment in supercritical waters show that the weight gain of the alloy follows a parabolic law; however, in subcritical water the alloy exhibits mass loss.
研究了镍基合金800H在550℃、25 MPa、600℃、25 MPa和650℃、25 MPa超临界水中的应力腐蚀开裂敏感性,以及在650℃、25 MPa超临界水中和290℃、15.2 MPa亚临界水中的一般腐蚀行为。并对合金在不同空气温度下的力学性能进行了研究。慢应变速率拉伸(SSRT)试验的应变-应力曲线表明,合金强度随温度升高而降低。非原位扫描电镜(SEM)观察表明,合金800H在超临界水中三种条件下均表现出对SCC的敏感性。空中SSRT试验表明,合金的屈服强度和抗拉强度随温度升高而降低。超临界水一般腐蚀实验结果表明,合金的增重服从抛物线规律;然而,在亚临界水中合金表现出质量损失。
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引用次数: 2
Effect of pH Value on Electrochemical Behavior of High Nitrogen Stainless Steel in NaCl Solution pH值对高氮不锈钢在NaCl溶液中电化学行为的影响
Q4 Chemical Engineering Pub Date : 2014-04-23 DOI: 10.11903/1002.6495.2013.331
Lixia Liu, Y. Qiao
The electrochemical behavior of high nitrogen stainless steel(HNS) in 1 mol/L NaCl solution with different pH values was investigated by means of potentiodynamic polarization curves, electrochemical impendence spectrum and current-time transient curves. The results show that anodic passivation of HNS could occur in alkaline solutions, while the corrosion rate of HNS decreased with the increasing pH value; a porous film might be grown on HNS in neutral NaCl solution due to the companying processes of dissolution and repassivation. In acidic and alkaline NaCl solutions, the formed passive films on HNS exhibit superior protectiveness rather than that in neutral NaCl solution.
采用动电位极化曲线、电化学阻抗谱和电流-时间瞬变曲线研究了高氮不锈钢(HNS)在1 mol/L不同pH值NaCl溶液中的电化学行为。结果表明:HNS在碱性溶液中发生阳极钝化,腐蚀速率随pH值的增加而降低;在中性NaCl溶液中,由于溶蚀和再钝化的共同作用,HNS表面可能会形成多孔膜。在酸性和碱性NaCl溶液中,在HNS上形成的钝化膜表现出比在中性NaCl溶液中更好的保护作用。
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引用次数: 0
硼-硫酸-草酸电解液降压阳极氧化疏孔膜层制备及表征 硼-硫酸-草酸电解液降压阳极氧化疏孔膜层制备及表征
Q4 Chemical Engineering Pub Date : 2014-04-23 DOI: 10.11903/1002.6495.2013.116
王加余, 李澄, 尹成勇, 李西娟, 王艳慧
A well ordered porous oxide film on aluminum alloy was prepared by a three-stage process in electrolyte of boric-sulfuric-oxalic acids. The relevant growth mechanism of oxide film in the processes with modes of galvanostatic and reduced voltage was elaborated. The morphology and microstructure of the oxide films were characterized by scanning electronic microscopy(SEM). The corrosion performance of the films in 3.5% NaCl solution was examined by electrochemical impedance spectroscopy and potentiodynamic polarization curves. The results show that the anodic film exhibits to be regular and dense with pore diameter of 10~13 nm. Moreover, the electrochemical behavior of anodic oxide film could be described as that the impedance and corrosion resistance was increased with the increasing thickness of the film and the cell wall.
以硼酸-硫酸-草酸为电解液,采用三段式法制备了有序的铝合金多孔氧化膜。阐述了在恒流模式和降压模式下氧化膜生长的相关机理。利用扫描电镜(SEM)对氧化膜的形貌和微观结构进行了表征。采用电化学阻抗谱和动电位极化曲线检测了膜在3.5% NaCl溶液中的腐蚀性能。结果表明,制备的阳极膜均匀致密,孔径为10~13 nm。此外,阳极氧化膜的电化学行为可以描述为阻抗和耐腐蚀性随膜和细胞壁厚度的增加而增加。
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引用次数: 0
Corrosion Characteristic and Anticorrosion Measures for Heat Supply System in a Thermal Power Plant at Baotou 包头某火电厂供热系统腐蚀特点及防腐措施
Q4 Chemical Engineering Pub Date : 2014-01-23 DOI: 10.11903/1002.6495.2013.013
Lirong Chen, Jingjing Zhang
The corrosion of the hot water supply system in a thermal power plant in Baotou was analyzed.Results showed that corrosion of the inner surface of pipe was oxygen corrosion,the main influencing factor were DO(dissolved oxygen) and pH value.In order to solve the corrosion problem, a new compound corrosion inhibitor with Sodium erythorbate as the main component was proposed. Due to synergistic effect exists amongthe components of the compound ihibitor,therefore, the inhibitor can effectively enhance the resistance of the steel pipesto the corrosive softened waterin the system. The corrosion rate of carbon steel may be lowered to only 0.0303 mm/a with a dose of 150 mg/L inhibitor for the soften water with pH 10.
对包头某火电厂热水供应系统的腐蚀进行了分析。结果表明:管道内表面腐蚀主要为氧腐蚀,影响腐蚀的主要因素是溶解氧(DO)和pH值;为了解决腐蚀问题,提出了一种以赤藓酸钠为主要成分的新型复合缓蚀剂。由于复合缓蚀剂各组分之间存在协同作用,因此,该缓蚀剂可有效增强系统中钢管对腐蚀性软化水的耐腐蚀性。在pH值为10的软化水中,当缓蚀剂用量为150 mg/L时,碳钢的腐蚀速率仅为0.0303 mm/a。
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引用次数: 0
Corrosion Inhibiton of N80 Steel in HCl Acid Medium by Gemini Surfactant Gemini表面活性剂对N80钢在盐酸介质中的缓蚀作用
Q4 Chemical Engineering Pub Date : 2014-01-23 DOI: 10.11903/1002.6495.2013.247
Hong Liu, Lin Zhu, Linfeng Li, Dengfeng Ji
The corrosion inhibition of Gemini surfactant(DBA2- 12) for N80 steel in 1 mol/L HCl was investigated using mass loss methods, electrochemical methods and scanning electron microscopic methods. It was found that DBA2- 12exhibited good corrosion inhibition performance. Mass loss method reveals that the inhibition efficiency increases with the increase in concentration of DBA2- 12, while decreases with the increase in temperature of acid medium. The adsorption of DBA2-12on the metal surface has been found to obey Langmuir isotherm. Potentiodynamic polarization studies clearly suggest that DBA2- 12acts as mixed- type inhibitor, which can be adsorbed on N80 steel surface, leading to the formation of a protective film to decrease the corrosion rate.
采用失重法、电化学法和扫描电镜法研究了Gemini表面活性剂DBA2- 12对N80钢在1 mol/L HCl中的缓蚀作用。结果表明,DBA2- 12具有良好的缓蚀性能。质量损失法表明,DBA2- 12的缓蚀效率随着DBA2- 12浓度的增加而增加,而随着酸性介质温度的升高而降低。dba2 -12在金属表面的吸附服从Langmuir等温线。动电位极化研究清楚地表明,DBA2- 12作为混合型缓蚀剂,可以吸附在N80钢表面,形成保护膜,降低腐蚀速率。
{"title":"Corrosion Inhibiton of N80 Steel in HCl Acid Medium by Gemini Surfactant","authors":"Hong Liu, Lin Zhu, Linfeng Li, Dengfeng Ji","doi":"10.11903/1002.6495.2013.247","DOIUrl":"https://doi.org/10.11903/1002.6495.2013.247","url":null,"abstract":"The corrosion inhibition of Gemini surfactant(DBA2- 12) for N80 steel in 1 mol/L HCl was investigated using mass loss methods, electrochemical methods and scanning electron microscopic methods. It was found that DBA2- 12exhibited good corrosion inhibition performance. Mass loss method reveals that the inhibition efficiency increases with the increase in concentration of DBA2- 12, while decreases with the increase in temperature of acid medium. The adsorption of DBA2-12on the metal surface has been found to obey Langmuir isotherm. Potentiodynamic polarization studies clearly suggest that DBA2- 12acts as mixed- type inhibitor, which can be adsorbed on N80 steel surface, leading to the formation of a protective film to decrease the corrosion rate.","PeriodicalId":10727,"journal":{"name":"Corrosion Science and Protection Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2014-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66312872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Corrosion Science and Protection Technology
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