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Grid-connected PV system in air cooled double-stage ORC geothermal power plant performance evaluation, case study: Sultanhisar GPP-2 空气冷却双级 ORC 地热发电站性能评估中的并网光伏系统,案例研究:苏丹希萨尔 GPP-2
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-27 DOI: 10.1002/ep.14460
Şeyma Kaçmaz, Havva Demirpolat

Many factors determine the percentage of parasitic load of the geothermal power plant. Domestic consumption accounts for about 20–25 per cent of total production in low-temperature geothermal power plants. As a case study, the ratio of a 1 MW grid-connected PV system to the internal consumption of the Sultanhisar GPP-2 and its effect on increasing the efficiency of the system have been examined. The current production of the power plant has been modeled thermodynamically with the parameters taken from the plant, and the efficiency of the system has been calculated. Sultanhisar GPP-2, which operates at a geothermal well temperature of 140.2°C and a net efficiency of 6.28%, has a domestic consumption to production ratio of around 25%. The installation of a 1 MW PV system is expected to produce 2140MWh per year, equivalent to 7% of the internal energy consumption.

决定地热发电厂寄生负载比例的因素很多。在低温地热发电厂,国内消耗约占总产量的 20%-25%。作为一项案例研究,我们考察了 1 兆瓦并网光伏系统与苏尔坦希萨尔 GPP-2 内部消耗的比例及其对提高系统效率的影响。利用电厂的参数对电厂当前的发电量进行了热力学建模,并计算了系统的效率。Sultanhisar GPP-2 的地热井温度为 140.2°C,净效率为 6.28%,其国内消费与生产比率约为 25%。安装 1 兆瓦光伏系统后,预计每年可生产 2140 兆瓦时,相当于内部能源消耗的 7%。
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引用次数: 0
Occurrence and eco-toxicological risk assessment of primary aromatic amines in hookah wastewater 水烟废水中芳香族伯胺的存在及其生态毒理学风险评估
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-26 DOI: 10.1002/ep.14466
Gholamreza Heydari, Mahbubeh Tangestani, Farshid Soleimani, Bahman Ramavandi, Farshad Bahrami Asl, Roshana Rashidi, Hossein Arfaeinia

This study was conducted for the first time to discern the levels of primary aromatic amines (PAAs) in hookah wastewater resulting from the consumption of fruit-flavored and traditional tobacco. The ecological risk of PAAs laden hookah wastewater and its toxic effects on crustaceans and fish have also been evaluated. The mean concentrations of PAAs in hookah wastewater resulting from consumption of Al-Mahmoud, Al-Ayan, Al-Fakher, and Mazaya brands were 1075.56, 1033.25, 986.94, and 946.58 ng/L, respectively, while it was determined as 355.91 ng/L in traditional tobacco. The concentration of PAAs in the hookah wastewater of fruit-flavored tobacco was significantly higher than the traditional one (p < 0.05). Aniline (ANL) had the maximum level in hookah wastewater from fruit-flavored (679.83–802.50 ng/L) and traditional (316.53 ng/L) tobacco consumption. The RQ value of the mean concentration of PAAs in hookah wastewater for all samples was in the range of medium to low-risk (RQ < 1). In addition to PAAs, other dangerous chemicals in hookah wastewater can increase its ecological and health risk, so it is necessary to manage such wastewater before discharging it into the environment.

这项研究首次发现了因吸食果味烟草和传统烟草而产生的水烟废水中芳香族伯胺(PAA)的含量。研究还评估了含有 PAAs 的水烟废水的生态风险及其对甲壳类动物和鱼类的毒性影响。食用 Al-Mahmoud、Al-Ayan、Al-Fakher 和 Mazaya 品牌烟草所产生的水烟废水中 PAAs 的平均浓度分别为 1075.56、1033.25、986.94 和 946.58 ng/L,而传统烟草中的 PAAs 浓度为 355.91 ng/L。果味烟草勾兑废水中 PAAs 的浓度明显高于传统烟草(p < 0.05)。苯胺(ANL)在果味烟草(679.83-802.50 ng/L)和传统烟草(316.53 ng/L)的水烟废水中含量最高。所有样品的水烟废水中 PAAs 平均浓度的 RQ 值均在中低风险范围内(RQ < 1)。除 PAAs 外,水烟废水中的其他危险化学品也会增加其生态和健康风险,因此有必要在将这些废水排放到环境中之前对其进行管理。
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引用次数: 0
A review of the use of rice husk silica as a sustainable alternative to traditional silica sources in various applications 稻壳白炭黑作为传统白炭黑来源的可持续替代品在各种应用中的使用综述
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-22 DOI: 10.1002/ep.14451
Mustapha Abdullateef Taiye, Wahia Hafida, Fangong Kong, Cunshan Zhou

Rice husk silica (RHS) has emerged as a sustainable alternative to traditional sources of silica in various applications, offering eco-friendly attributes, cost-effectiveness, and versatility. This review explores the potential of RHS as a substitute for conventional silica sources, highlighting its alignment with sustainable development objectives and its appeal to industries seeking environmental responsibility. Among the extraction methods, acid leaching is identified as yielding higher purity silica. In contrast, among the novel techniques, the hydrothermobaric process stands out for producing high purity and yielding nanosilica. Despite challenges like limited access to high-quality rice husks and variations in silica content, RHS extraction methods show promising avenues for sustainable silica production, addressing waste management, and environmental concerns. Further development and optimization of extraction techniques are essential for widespread acceptance, with future research focusing on nanoparticle synthesis and incorporating green chemistry principles. This comprehensive review of RHS provides a valuable resource for researchers seeking to explore sustainable alternatives in their respective fields, aiming to foster adopting more sustainable practices and materials across various industries.

稻壳白炭黑(RHS)已成为各种应用中传统白炭黑来源的可持续替代品,具有生态友好、成本效益高和用途广泛等特点。本综述探讨了稻壳白炭黑作为传统白炭黑来源替代品的潜力,强调了它与可持续发展目标的一致性及其对寻求环境责任的行业的吸引力。在各种萃取方法中,酸浸法被认为能产生纯度更高的二氧化硅。相比之下,在新型技术中,水热法因其纯度高、产量大而脱颖而出。尽管存在诸如获取优质稻壳的途径有限和二氧化硅含量差异等挑战,但稻壳萃取方法为可持续二氧化硅生产、解决废物管理和环境问题提供了前景广阔的途径。萃取技术的进一步发展和优化对其被广泛接受至关重要,未来的研究重点将放在纳米粒子合成和绿色化学原理上。这篇关于 RHS 的全面综述为寻求在各自领域探索可持续替代品的研究人员提供了宝贵的资源,旨在促进各行各业采用更具可持续性的实践和材料。
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引用次数: 0
Comprehensive effects of ammonia substitution rate, compression ratio, and ignition timing on knock, NOx emissions and indicated thermal efficiency in a hydrogen fuel engine 氨替代率、压缩比和点火正时对氢燃料发动机爆震、氮氧化物排放和指示热效率的综合影响
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-15 DOI: 10.1002/ep.14465
Junquan Li, Chengfei Zhao, Zhangjun Tu, Shanxu Cheng, Yuanli Xu

To reduce knock and keeping low NOx emissions and high indicated thermal efficiency (ITE) in a hydrogen fuel engine, the comprehensive effects of ammonia substitution rate (ASR), compression ratio (CR), and ignition timing (IT) on its combustion and its NOx emissions were studied numerically. Based on a four-cylinder gasoline direct injection (GDI) engine, it was modified into an ammonia/hydrogen dual-fuel (AHDF) spark ignition (SI) engine. The simulation was conducted by GT-Power software, and simulation data were validated through experiments. 2500 rpm_50% load was selected for the research. ASR, CR and IT vary from 0% to 20%, 10.5 to 8.5, and −24 to 0°CA ATDC, respectively. The findings indicate that increasing ASR decreases the maximum pressure rise rate (MPRR) and the knock index (KI), improving the ITE, but increasing NOx emissions. Based on 20% ASR, CR was optimized. The findings indicate that decreasing CR reduces the MPRR and KI, but increasing NOx emissions and decreasing the ITE. Finally, based on CR of 9, IT was optimized. The findings indicate that delaying IT reduces the MPRR and KI, but also has a certain impact on NOx emissions and ITE. After compromise consideration, the optimal IT in this study was selected as −9°CA ATDC.

为了减少爆震,保持氢燃料发动机的低氮氧化物排放和高指示热效率(ITE),对氨替代率(ASR)、压缩比(CR)和点火正时(IT)对其燃烧和氮氧化物排放的综合影响进行了数值研究。以四缸汽油直喷(GDI)发动机为基础,将其改进为氨氢双燃料(AHDF)火花点火(SI)发动机。模拟由 GT-Power 软件进行,模拟数据通过实验验证。研究选取 2500 rpm_50% 负载进行。ASR、CR 和 IT 分别在 0% 至 20%、10.5 至 8.5 和 -24 至 0°CA ATDC 之间变化。研究结果表明,增加 ASR 会降低最大压力上升率(MPRR)和爆震指数(KI),改善 ITE,但会增加氮氧化物排放量。在 20% ASR 的基础上,对 CR 进行了优化。研究结果表明,降低 CR 会降低 MPRR 和 KI,但会增加氮氧化物排放量,降低 ITE。最后,在 CR 为 9 的基础上,对 IT 进行了优化。结果表明,延迟 IT 可降低 MPRR 和 KI,但对 NOx 排放和 ITE 也有一定影响。经过折中考虑,本研究选择的最佳 IT 为 -9°CA ATDC。
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引用次数: 0
Electrocoating of polyaniline on graphite carbon and activated carbon cloth surfaces as an anode and its effect on performance of microbial fuel cell 在石墨碳和活性碳布表面电镀聚苯胺作为阳极及其对微生物燃料电池性能的影响
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-15 DOI: 10.1002/ep.14448
Andika Wahyu Afrianto, Paiboon Sreearunothai, Korakot Sombatmankhong, Sandhya Babel

Microbial fuel cell (MFC) is a bioelectrochemical-based reactor that can generate electrical energy directly from wastewater by utilizing microbial activity that oxidizes the waste organic matter. This study aims to synthesize polyaniline (PANI) and deposit on a graphite carbon electrode (GCE) and activated carbon cloth (ACC) surface to use as an anode material for MFCs. The MFC performance was evaluated using oxygen and ferricyanide as electron acceptors. PANI was electropolymerized from its aniline monomer and deposited using an electrophoretic deposition method onto the electrode surface. A PANI thin film was characterized using FTIR, field emission scanning electron microscopy (FESEM), BET, and electrochemical analysis. The analysis results show the characteristic peaks of PANI at 1557 cm−1, demonstratinjg the existence of quinoid rings (NQN), while the peaks at 1479 and 1400 cm−1 corresponding to the benzenoid (NBN) stretching in the PANI structure. The FESEM analysis confirmed that PANI appeared to have a porous structure on modified electrodes. It was found that the best system was MFC with ferricyanide as the electron acceptor. The highest power density produced is 254 mWm−2 from GCE-PANI and 16.47 mWm−2 from ACC-PANI. The normalized energy recovery of GCE-PANI and ACC-PANI in ferricyanide is 0.115 kWh kgCOD−1 and 5.67 × 10−3 kWh kgCOD−1, respectively. The COD removal was observed to be 88.8% for GCE-PANI and 87.2% for ACC-PANI from 1000 mg/L COD.

微生物燃料电池(MFC)是一种基于生物电化学的反应器,可利用微生物氧化废水中有机物的活性直接从废水中产生电能。本研究旨在合成聚苯胺(PANI),并将其沉积在石墨碳电极(GCE)和活性碳布(ACC)表面,作为 MFC 的阳极材料。使用氧气和铁氰化物作为电子受体对 MFC 的性能进行了评估。PANI 由苯胺单体电聚合而成,采用电泳沉积法沉积在电极表面。利用傅立叶变换红外光谱、场发射扫描电子显微镜(FESEM)、BET 和电化学分析对 PANI 薄膜进行了表征。分析结果显示,PANI 的特征峰位于 1557 cm-1,表明存在醌环 (NQN),而 1479 和 1400 cm-1 的峰则对应于 PANI 结构中的苯环 (NBN) 伸展。FESEM 分析证实,改性电极上的 PANI 似乎具有多孔结构。研究发现,最好的系统是以铁氰化物为电子受体的 MFC。GCE-PANI 产生的最高功率密度为 254 mWm-2,ACC-PANI 产生的最高功率密度为 16.47 mWm-2。在铁氰化物中,GCE-PANI 和 ACC-PANI 的归一化能量回收率分别为 0.115 kWh kgCOD-1 和 5.67 × 10-3 kWh kgCOD-1。从 1000 mg/L COD 的去除率来看,GCE-PANI 为 88.8%,ACC-PANI 为 87.2%。
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引用次数: 0
Empirical modeling of H2S removal from biogas by chemical absorption in electrochemically prepared solutions containing iron ions 在电化学制备的含铁离子溶液中通过化学吸收去除沼气中 H2S 的经验模型
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-12 DOI: 10.1002/ep.14435
Mayer Bruna, Eyng Eduardo, Frare Laercio Mantovani, Orssatto Fábio, Baraldi Ilton José

For the energy use of biogas, it is important to remove hydrogen sulfide (H2S) as it is highly corrosive. Chemical absorption is a technology that has proven to be effective for H2S removal. Based on the principle of this technology, the objective of this research was to evaluate the removal of H2S from biogas via chemical absorption using solutions containing Iron III ions (Fe3+). These solutions were produced electrochemically based on experimental designs that had pH and electrolysis time as independent variables, as well as the solution deactivation time as a response variable. The Fe3+ ion solutions were prepared in the laboratory and subsequently used in biogas purification tests, which were carried out using biogas from a poultry slaughtering agro-industry biodigester. The results indicated a good performance of the solutions for H2S removal when compared with distilled water. It was possible to observe that better results for the deactivation time can be found when higher pH values are used in the solutions, within the range applied in this study. The solution prepared under pH 7.4 and electrolysis time of 22.1 min provided a deactivation time 83% greater than water one. In addition, it was possible to find a significant mathematical model that describes the solution deactivation time as a function of pH.

对于沼气能源利用而言,去除硫化氢(H2S)非常重要,因为硫化氢具有很强的腐蚀性。化学吸收技术已被证明能有效去除 H2S。根据这项技术的原理,本研究的目的是评估利用含有铁 III 离子(Fe3+)的溶液通过化学吸收从沼气中去除 H2S 的情况。这些溶液是根据以 pH 值和电解时间为自变量、以溶液失活时间为响应变量的实验设计通过电化学方法制备的。Fe3+ 离子溶液是在实验室制备的,随后用于沼气净化测试,测试使用的沼气来自家禽屠宰农用工业生物发酵罐。结果表明,与蒸馏水相比,溶液去除 H2S 的性能良好。在本研究采用的范围内,当溶液的 pH 值较高时,可以在失活时间方面获得更好的结果。pH 值为 7.4、电解时间为 22.1 分钟的溶液的失活时间比水的失活时间长 83%。此外,我们还找到了一个重要的数学模型来描述溶液失活时间与 pH 值的函数关系。
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引用次数: 0
Exploration of benefits and performances of integration of semitransparent photovoltaics with buildings and infrastructure: A comprehensive review 探讨将半透明光伏技术与建筑物和基础设施相结合的益处和性能:全面回顾
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-02 DOI: 10.1002/ep.14464
Neha Gupta

This article discusses how incorporating semitransparent photovoltaic (SPV) modules into buildings can reduce dependency on conventional energy sources, contributing to a shift toward renewable energy and self-sustaining construction. It explores various ways to implement SPV technology in building and infrastructure design, and outlines the advantages, such as improved daylighting, thermal regulation, and energy efficiency. The analysis also considers how SPV integration affects energy and exergy performance, emphasizing its role in achieving net-zero energy buildings. Additionally, the article identifies existing research gaps, providing guidance for future studies and practical applications in the building sector.

本文讨论了在建筑中采用半透明光伏(SPV)模块如何减少对传统能源的依赖,从而促进向可再生能源和自给自足建筑的转变。文章探讨了在建筑和基础设施设计中采用 SPV 技术的各种方法,并概述了其优势,如改善采光、热调节和能源效率。分析还考虑了 SPV 集成如何影响能源和放能性能,强调了其在实现净零能耗建筑中的作用。此外,文章还指出了现有的研究空白,为未来的研究和建筑领域的实际应用提供了指导。
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引用次数: 0
Issue Information - Info for Authors 期刊信息 - 作者信息
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-31 DOI: 10.1002/ep.14423
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引用次数: 0
Issue Information - Cover and Table of Contents 发行信息 - 封面和目录
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-31 DOI: 10.1002/ep.14180
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引用次数: 0
Investigation of physical properties of microalgae-pectin-based bio-composite with addition of pine needle for environmental application 添加松针的微藻-pectin 生物复合材料在环境应用中的物理性质研究
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-29 DOI: 10.1002/ep.14463
Carlos Munoz-Cupa, Kristine Lee, Anuradha Krishnan, Amarjeet Bassi

Polymers and biopolymers have gained significance due to their applicability and use in industry reducing the negative impact of polymers based on petroleum. A possible solution for the conventional polymer's biodegradability is bio-composites, which contain natural fibers or aggregates such as microalgae. Hence, microalgae biomass has a promising application to address the biodegradability issue of conventional polymers. In this study, Chlorella vulgaris biomass was mixed with pectin for control samples with glycerol as plasticizer. The mixture microalgae-pectin-glycerol, and the addition of pine needles was used to evaluate the tensile strength and compression of the bio-composite. This bio-composite showed a higher Young's modulus of 95.66 MPa for blend C2 and a higher strength with 20% of pectin concentration in the mixture. Additionally, the pine needle addition did not have a low effect between the compression results. On the other hand, analysis on elasticity showed that the full recovery of the bio-composite happened after 10 min in all the blends. Also, the bio-composite showed a slow release of nitrogen and phosphorous after 5 days of water addition, indicating an effective slow release for blend B for both nutrients. Water uptake capacity and loss of soluble material was studied using pullulan, chitosan, and cetyltrimethylammonium bromide additives. These cationic surfactants demonstrated their potential for reduction of water solubility of the bio-composite.

聚合物和生物聚合物由于其适用性和在工业中的应用,减少了以石油为基础的聚合物所带来的负面影响,因而变得越来越重要。生物复合材料是解决传统聚合物生物降解性问题的一个可行方案,它含有天然纤维或微藻等聚合体。因此,微藻生物质在解决传统聚合物的生物降解性问题方面具有广阔的应用前景。在这项研究中,对照样品中的小球藻生物质与果胶混合,甘油作为增塑剂。微藻-果胶-甘油混合物和松针被用来评估生物复合材料的拉伸强度和压缩性。这种生物复合材料显示,混合物 C2 的杨氏模量较高,为 95.66 兆帕,混合物中果胶浓度为 20% 时,强度较高。此外,松针添加量对压缩结果的影响并不明显。另一方面,弹性分析表明,在所有混合物中,生物复合材料在 10 分钟后完全恢复。此外,在加水 5 天后,生物复合材料显示出氮和磷的缓慢释放,这表明混合物 B 能有效地缓慢释放这两种养分。使用拉毛聚糖、壳聚糖和十六烷基三甲基溴化铵添加剂对吸水能力和可溶性物质的损失进行了研究。这些阳离子表面活性剂证明了它们在降低生物复合材料水溶性方面的潜力。
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引用次数: 0
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Environmental Progress & Sustainable Energy
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